SAMPLE PAPER - II ClassXII Chemistry Time :3 Hrs.

General Instructions : 1. 2. 3. 4. 5. 6. 7. 1. All questions are compulsory. There is no overall choice in the questions paper, however internal choices are provided in some questions. Questions no. 1 to 8 are very short answer type questions and carry 1 mark each. Question no. 9 to 18 are short answer type question and carry 2 marks each. Question no. 19to 27 are short answer question of 3 marks each. Question no. 28 to 30 are long answer question of 5 marks each. use of log table is permitted. A compound containing 2 atoms, X and Y crystallize in a cubic lattice with atoms X at the corners of the unit cell and atoms Y at the body centers. Write the Formula of the compound. 2. Why is ferric chloride preferred over Potassium chloride in case of a cut leading to bleeding ? 3. 4. What is the role of a depressant in the froth floatation process ? Which will have higher B. pt. 0.1 M Nacl or 0.1 M baCl2 solutions in water ? Predict the shape of Cl F3 on the basis of VSEPR theory. Write the structure of 3-methyl pent-3-en-2-one. K2PtCl6 is a well known compound while K2NiCl6 is not known . why ?

M.M. 70

5.

6. 7.

8.

In the following pairs of organic compound identify the compound that will undergo SN1 reaction faster Cl CH2Cl

9.

The boiling point elevation of 0.6 g actic acid in 100 g of bengene is 0.1265 K. What conclusion can you draw about the molecular state of the solute in solution ? Kb for benzene is 2.53 degree per motal.

10.

Consider the following reaction, 2NO(g) + 2H2 (g)

N2(g) +2H2o (g)

Rate = K [NO]2 [H2] Propose a mechanism of this reaction. 11. Distinguish between the following pairs of compound with a siutable chemical test (a) (b) 12. Ethanol and phenol N-methylethanamine and ethanamine

Distinguish between any two of the following pairs (a) (b) (b) (c) Essential and non-essential amino acids a-Helix a b and -pleated sheet structure structure Amylose and amylopectin.

13.

Account for the following (a) (b) Tertiary amines are weaker base than secondary amines in aqueous solutions. Ketones are less reactive towards nucleophilic substitution reaction than aldehydes.

14.

The chioce of a reducing agent in a partcular case depends on thermodynamic factor. How far do you agree with this statement ?

15.

(a) (b)

Distinguish between ideal and non-ideal solutions. State Henery's law.

16.

Explain the following name reaction (a) (b) Cannizaro reaction. (Reimer-Tiemann Reaction) Amino acids are amphoteric in nature. Why? What happens when glucose is treated with Br2 water. OR

17.

(a) (b)

17.

On electrolysis in acidic solutions amino acid migrate towards cathode while in alkaline solution these these migrate towards anode. Explain.

18.

What happens when ethanol is heated with conc. H2SO4 at 140o c ? Write the mechanism of the rxn .

19.

Write names of monomers of the following polymers and classify them as homopolymer or copolymer Buna S, Bakelite, teflon.

20.

NaCl lattice has fcc structure. By X-ray diffraction, it is determined that the distance between Na+ and Cl- ion is 282 pm.calculate the density of NaCl.

21.

The activation energy of a first order reaction is 30 kJ/mol at 25o

c.The

activation energy of the same same reaction in the presence of a catayst is 24kJ/mol at 25o c How many times the rate of a reaction change in the presence of a catayst at 25o c

22.

(a) (b)

Explain the prepration of silver sol with a suitable diagram. Name the method of preparation. What is meant by shape selective catalysis ? Name the catalyst used in obtaining gasoline from alcohol.

23.

(a) (b)

Write the structured formula of XeF2. Give reasons : (i) (ii) Nitric oxide become brown . When released in air. Of all nobel gases only xenon forms chemical compounds.

24.

(a) (b) (c)

Arrange HOCl , HOBr and HOI in increasing acid strength. Why does PCl5 fume in moisture ? Write only the reactions involved in the manufacture of HNO3 by Oswtald's process. Write IUPAC name of [Co(en) 2Cl 2]+ Describe the type of Hyloridization, shape and magnetic properly of [Fe(H2O) 6]2+ [OR] [Ni(CO4)]

25.

(a) (b)

(Atomic number : Fe=26, Co= 27, Ni=28) 26. (a) (b) (c) 27. Name a compound that acts as both antiseptic as well as disinfectant Why is bithional added to the toilet soap. What type of drug is chloramphenicol ?

An alkene (A) on ozonolysis yields acetone and an aldehyde. The aldehyde is easily oxidized to an acid (B). When (B) is treated with Br2 in presence (C) of phosphorus, if yields a compound C which on hydrolysis gives a hydroxy acid (D) . This acid can also be obtained from acetone by the reaction with HCN followed by hydrolysis. Identy the compound A to D giving suitable reasons and relevant reactions.

Or An organic compound (A) with molecular formed C8H8 O forms an Orange- red precipitate with 2,4-DNP reagent and gives yellow precipitate on heating with iodine in the presence of sodium hydroxide. It neither reduces Tollen's or Fehlings reagent nor, dos it decolorize bromine water or Baeyer's reagent. On drastic oxidation with chromic acid , it gives a carboxylic acid (B) having molecular formula C7H6O2. Identify the compounds (A) and (B) and explain the reactions involved. 28. (a) consider cell, Zn(s) I Zn2+(aq) (1.0M) II Cu2+(aq) (1.0 M) I Cu(s) (i) (ii) (iii) Given : (b) Write the cell reaction Calculate emf of the cell Is the cell reaction spontaneous or not E = 0.76V E Cu2+/Cu = 0.34V Zn2+/Zn

Predict the products of electrolysis in each of the following (i) (ii) An aqueous solution of AgNo3 using silver electrodes. An aqueous solution of CuCl2 using platinum electrodes. Or

28.

(a)

Resistance of a conducting cell filled with 0.1 MKcl solutions is 100 . If the resistance of the same cell when filled with 0.02 M kCl solution is 520 calculate the conductivity and molor conductivity of 0.02 solution. Conductivity of 0.1 M KCl solution id 1.29 S m-1. M KCl

(b) 29. (a) (b)

State two advantages of H2-O2 fuel cell over ordinary cell. What is lanthanoid contraction ? What is its effect on the chemistry of the elements which follow the lanthanides ? What happens when Cr 2 O 72- reacts with Fe 2+ in acidic medium ? Write relevant balanced equation.

(c) (d)

Cu+ salts are colorless while Cu2+ salts are colored. why ? Calculate magnetic moments of a divalent ion in aqueous solution if its atomic number is 25. Or How would you account for the following : (i) (ii) The transition elements have high enthapies of atomisation. The transition metals and their compounds act as good catalysts in many processes.

(a)

(b)

Black solid (A) reacts with KOH Or K2 CO3 in presence of air o give (B) which forms green solutions. when Cl2 gas is passed through green solutions, the colour of solution changes to purple due to formation of C. identify A,B,C and write chemical equations.

30.

(a)

Write IUPAC name of OH O CH3-CH-CH2-C--H

(b) (c)

Convert benayl alcohol to phenyl etahnoic acid Which of the following compounds would under go aldol condensation,. Which cannizaro reaction and which neither ? give reason. Methanal, 2- methyl pentanal, butan 1-ol OR

(a)

Arrange CH3 CH2 CH (Br) COOH, CH3 CH (Br) CH2 COOH (CH3)2 CH COOH, CH3 CH2 CH2 COOH increasing order of acid strength.

(b) (c)

Convert Ethanol to 3-Hydroxy Butanol Give reasons (i) (ii) (iii) Boiling points of aldehydes & ketones are lower than that of corresponding acids CHCl3 should be stored in dark brown colored bottle. CHCl3 is a chlorine compound but it does not give white precipitate with silver nitrate solution

Sample paper 2 ClassXII Marking Scheme Chemistry Time :3 Hrs.

1. X= 8 x 1/8 =1 Y=1 Formula =XY 2. 3. 4. 5. Because fe3+ has a highercharge than k+ and thus has more coagulating power They prevent certain particales from forming the from 0.1 M BaCl2 T-shaped 1 1 1 1

M.M. 70

6.

CH3 CC =CH-CH3
O CH3

7. 8.

AS sum of first four IE is less in Pt than in Ni

CH2 CI

9. Tb = Kb.Mi Tb = Kb MB= Kb X WB X 1000 MB X W A WB X 1000

Tb X WA

2.53 x 0.6 x 1000 = = 120 0.1265x 100

I= :

Normal molecular mass Observed molecular mass

60 = 0.5 120

I= 0.5, solute exists as a dimer in solution

10.

2 NO(g)+ H2(g)

slow

N2(g) +H2O2

H2O2+H2(g) fast 2H2O(g) 11. (a) (b) 12. 13. Iodoform test or neutral FeCl3 test or any other Hinsberg test. 1+1 1 1 1 1 1 1 1+1

I mark for each correct difference (a) (b) Correct reason Correct reason

14. 15.

Correct reason (a) (b) Correct differences (any 2) Correct statements

16. 17.

Correct reactions (a) (b) Correct reason Correct reaction OR Correct explanation wrt acidic and alkaline solution each

18.

2C2 H5 OH

conc. H2SO4 140 C

C2 H5 O C2 H5 H CH3 CH2OH

CH3CH2OH

H+ H2O CH3CH2OH

CH3 CH2 O CH2 CH3

-H+

CH3CH2OCH2CH3

19.

Buna S Bakelete Tefflon

Copolymer Copolymer Homopolymer

Bultadiene Phenol

& &

Styrene Formaldehyde

Tetrafluoroethene

() mark for each correct answer

20.

Z= 4 d=

Fec structure

1/2 1/2 (1/2+1/2) 4 X 58.5

a= 2 x 282 = .564 Pm

ZxM 3 = = 2.16 53 g m a A X/c N

0

(564)3 x 10-10 x 6.023 x 1023

1 1/2

21.

log K2 = K1

Ea - Ea (c) 2.303 RT

(30000-24000) 2.303 x 8.314 x 298 = 1.0516 K2 K1 K2 22. (a) (b) 23. (a) = antilog (1.0516) = 11.27 K1 Proper explanation of Bredig's Arc method along with its diagram Explanation of selective catalysis ZSM -5 1 1 1

F XE

(b)

(i) (ii)

Due to its formation of NO2 Due to its comparable ionization energy with oxygen

24.

(a) (b) (c)

HOI, HOBr, HOCL Due to formation of HCl 4HN3+(g)5O2(g) 2NO(g)+O2(g) Pt 500 K,9 bar 4NO(g)+6H2O(g)

1 1

25.

(a)

2NO2(g) Dichlorido bis (ethane-1, 2,- diamine) cobatt (III) ion 2HNO3(g)+ NO(g) 3NO2(g)+H2O(l)

(b)

[Fe(H 20) 6]

2+

Hybridization Sp d A ShapeOctahedral Magnetic property paramagnetic OR (2)

[NI(CO)4]

HybridizationSp Magnetic

Shape Tetrahedral Property Diamagnetic 1 1 1

26.

(a) (b) (c)

Phenol To impart antiseptic properties Broad spectrum antibiotic

27. A + O3 Aldehyde P CH3C CH3 + Aldehyde [o] acid (B) H2O

B+Br2

(C)

Hydroxy acid (D) CN

OH H2O H+ COOH CH3CCH3 H (O D)

CH3CHCH= CCH3 CH3 CH3 CH3 CooH CH CH3 CooH CH3 C CH3 Br
CooH

1/2

B C D

1/2 1/2

1 mark for explanatioN

CH3 C CH3 OH

COCH3 Cl + H2 N. HN (A) H3C C H2O N

NO2 NO2 NO2 NH NO2

COOH

COCH3 H2 CrO4 NaOH I2 (A) Zn(s) + Cu2+(ag) Zn

2+ (ag)

COONA

+ CHI3

(B)

+ Cu(s)

1 Cell const 129 m 1 = = 248 Sm K= R 520 1 1 S cm = 0.248 10 1 129m =124 S cm 2 mol 1 l = C

CR2 07 +6FE

2-

2+

+14 H

2 Cr3++ 6Fe3+ + 7H2O

= 5 (5+ 2)

=35 BM

C6 H5 CH2 OH 28. (a) (i) (ii) (iii) (b) (i) 1.10 v

HBr

C 6 H5 CH2 Br K CN C6 H5 CH2 CN H2O |H

+

1 1 1

C6 H5 CH2 COOH

Reaction is spontaneous Cathode : Ag sets deposit Ag++eAnode Ag Ag e- + Ag+ CU2+2eClPcc Cl+Cl

-

CU E + Cl Cl2 Or NaOH Aldol Condensation

-1 -1

(ii)

Cathode : Anode :

(a)

Cell constant = K x R = 1.29 x 100 = 129 m = 1.29 cm 3 CH3CHCH2CHO OH

(b)

2 Advantage (1+1) Correct answer 2 1

29.

(a) (b)