Kvpy

Regional Head Quarters: FIITJEE TOWERS, No.
3, First Lane, (Next Apex Plaza), Nungambakkam High Road, Nungambakkam, Chennai 600 034.

FIITJEE Chennai Centre
P
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Time: 1.5 Hours Maximum Marks: 60

Please read the instructions carefully. You are allotted 5 minutes specifically for this
purpose.
You are not allowed to leave the examination hall before end of the test.
Name of the candidate:_________________________________________________
Batch :___________________ Date of Examination:__________
Enrollment Number : ___________________________________________________
General
1. This booklet is your Question Paper.
2. All questions are single answer type.
3. This Question Paper contains 12 subjective questions.
4. Each question carries +5 marks.

Any Student who indulges in Malpractice will be terminated immediately

KVPY MOCK TEST-PAPER-2(SUB)-CLASS-XI . P - 2 - PCMB

Regional Head Quarters: FIITJEE TOWERS, No.3, First Lane, (Next Apex Plaza), Nungambakkam High Road, Nungambakkam, Chennai 600 034.

USEFUL DATA
PHYSICS
Acceleration due to gravity : g = 10 m/s
2

Planck constant : h = 6.6
34
10 J s

Charge of electron : e = 1.6
19
10 C

Mass of electron :
31
9.1 10 m kg
e

=
Permittivity of free space :
12 2 2
8.85 10 /
0
C N m

=

Density of water :
water
3 3
10 / kg m =
Atmospheric pressure :
5 2
10 / Pa N m =
Gas constant : R = 8.314 J
1 1
K mol

CHEMISTRY
Gas Constant R = 8.314 J
1 1
K mol

= 0.0821 Lit atm
1 1
K mol

= 1.987 2 Cal
1 1
K mol

Avogadros Number
a
N = 6.023
23
10
Plancks constant h = 6.625
34
10 . J s

= 6.625
27
10 . erg s

1 Faraday = 96500 coulomb
1 calorie = 4.2 joule
1 amu = 1.66
27
10 kg

1 eV =
19
1.6 10 J

Atomic No: H = 1, He = 2, Li = 3, Be = 4, B = 5, C = 6, N = 7, O = 8, F = 9, Ne = 10, Na = 11,
Mg = 12, Si = 14, Al = 13, P = 15, S = 16, Cl = 17, Ar = 18, K = 19, Ca = 20,
Cr = 24, Mn = 25, Fe = 26, Co = 27, Ni = 28, Cu = 29, Zn = 30, As = 33, Br = 35,
Ag = 47, Sn = 50, I = 53, Xe = 54, Ba = 56, Pb = 82, U = 92.
Atomic masses: H = 1, He = 4, Li = 7, Be = 9, B = 11, C = 12, N = 14, O = 16, F = 19, Na = 23,
Mg = 24, Si = 28, Al = 27, P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52,
Mn = 55, Fe = 56, Co= 59, Ni = 58.7, Cu = 63.5, Zn = 65.4, As = 75, Br = 80,
Ag = 108, Sn = 118.7, I = 127, Xe = 131, Ba = 137, Pb = 207, U = 238.

1. A ball of mass m hits a wedge vertically with speed v
0
, which is
placed, on a smooth horizontal surface. Find the maximum
compression in the spring, if the collision is perfectly elastic and no
friction any where.

M
m
45
0
v0

2. A pulley fixed to the ceiling of a lift carries a thread whose ends are attached
to the masses of 4kg and 2kg. The lift starts going down with on acceleration
of a
0
= 4 m/s
2
relative to ground. Calculate
(a) The acceleration of the load 4kg relative to the ground and relative to
lift.
(b) The force exerted by the pulley on the ceiling of the lift
(Thread and pulley are massless, g=10 m/s
2
)

a0
4 kg 2 kg

3. A small disc of mass m slides down a smooth hill of height h
without initial velocity and gets onto a planck of mass M lying
on the horizontal plane at the base of the hill, as shown in the
figure. Due to friction between the disc and the plank, the disc
slows down and ultimately, both move together.
(a) Find the common velocity of the disc and the planck.
(b) Find the work done by the friction
(c) Find the distance moved by the disc with respect to the
planck before they start moving together.
m
M
h



4. The average person can see the red colour imparted by the complex [Fe(SCN)]
2+
to an aqueous
solution if the concentration of the complex is 6 10
6
M or greater. What minimum concentration of
KSCN would be required to make it possible to detect 1 ppm(by mass) of Fe
3+
in a natural water
sample. The instability constant for [Fe(SCN)]
2+
Fe
3+
+ SCN
is 7.142 10
3
. The density of
natural water can be assumed to be 1g/cc.

5. The type of hybridization and shape of following molecules/ion are
a)
2
ClF
__________ and __________ (1 Mark)

b) ( )
3
3
N CH __________ and __________ (1 Mark)
c)
2 3
PF Br __________ and __________ (1 Mark)
d)
4
TeCl __________ and __________ (1 Mark)
e) XeOF
4

__________ and __________ (1 Mark)

6. a) How many number of angular and spherical nodes are present in the following orbitals
4d ______________ (1 mark)
2s______________ (1 mark)
3p______________ (1 mark)

b) Predict total spin for each configuration
i) 1s
2
2s
2
2p
6
______________ (1/2 mark)
ii) 1s
2
2s
2
2p
5
______________ (1/2 mark)
iii) 1s
2
______________ (1/2 mark)
iv) 1s
2
2s
2
2p
3
______________ (1/2 mark)

7. Let ABC be a triangle with AB = AC. If D is the mid point of BC, E foot of perpendicular drawn from
D to AC and F is mid point of DE. Prove that AF is perpendicular to BE.

8. A
i
, H
i
, G
i
(i = 1, 2, 3, ......, n) are respectively n arithmetic means, n harmonic means and n geometric
means inserted between two positive numbers a and b. Prove that
( )
n
1
n 2 1
2
n 2 1 n 2 1
H ...... H . H
G ...... G . G
n
A ..... A A
(
(
+ + +
.

9. Consider two lines L
1
: a
1
x + b
1
y + c
1
= 0 and L
2
: a
2
x + b
2
y + c
2
= 0, where c
1
, c
2
0. Intersecting at a
point P. A line L
3
is drawn through the origin meeting the line L
1
and L
2
in A and B respectively such
that PA = PB. Similarly one more line L
4
is drawn through the origin meeting the lines L
1
and L
2
in
A
1
and B
1
respectively such that PA
1
= PB
1
. Obtain the combined equations of lines L
3
and L
4
.

10. Explain prophase I of meiosis.

11. Brief note on the digestion of food in the stomach.

12. Explain the process of urine formation with the help of the diagram.


Space for Rough Work



KVPY MOCK TEST PAPER 2 (SUB) CLASS XI
SOLUTIONS

1.Sol. The ball rebounds horizontally. Let say with speed v
and the wedge with V.
Momentum conservation mv = MV
v =
m
MV

Restitution
M
45
0
V
45
0
45
0
v

1 =
0 0
v
V v
45 cos v
45 cos v 45 cos V +
=
+

v + V = v
0

0
v V
m
MV
= +

0
v
m
V ) M m (
=
+
V =
M m
mv
0
+

2 2
kx
2
1
MV
2
1
= x = v
k
M
=
M m
mv
k
M
0
+

2.sol. Free body diagrams :

f1
P
MAg
f1 f2
MBg
f2
f2
MCg
Q
f1
Cylinder A
Cylinder B Cylinder C
C A

For the cylinder B
M
B
g (f
1
+ f
2
) = M
B
a
B

f
1
+ f
2
= 25 2.5a
B
. . . (i)
Taking torque about point P for cylinder A

P
= I
P

A
= f
1
2r
1
+ M
A
g r
[
2
1
2 (0.2)
2
+ 2 (0.2)
2
]
A
= f
1
0.4 + 2 10 0.2
0.1 2
A
= 0.4 f
1
+ 4 . . . (ii)
Taking torque about point Q for cylinder C

Q
= I
Q

C
= f
2
2r
2
+ M
c
.g r
2

[
2 2
c 2
1
1 (0.1) 1 (0.1) ] f 2 0.1 1 10 0.1
2
+ = + ]
0.015
c
= 0.2 f
2
+ 1 . . . (iii)
Also, a
B
=
A
0.4

A
=
B B
1
a 2.5a
0.4
=
and a
B
=
C
0.2


C
= 5 a
B

Putting values of
A

C
in (ii) and (iii) ,
0.12 2.5 a
B
= 0.4 f
1
+ 4 0.3 a
B
= 0.4 f
1
+ 4 . . . (iv)
0.015 5a
B
= 0.2 f
2
+ 1 0.15 a
B
= 0.4f
2
+ 2 . . . (v)
from (iv) and (v)
(0.3 + 0.15)a
B
= 0.4(f
1
+ f
2
) + 6
0.45 a
B
= 0.4 (25 2.5 a
B
) + 6
a
B
=
16
1.45
= 11.03 m/s
2

3.sol. (a) Velocity of the disc at the foot of the
hill is v
0
= 2gh . When it slides on the
plank, friction opposes its motion and
favours the motion of the plank as shown
in the figure.
N
N
f
ms
f

Let their common velocity be V, then
for m, V = v
0
- gt
for M, V =
mgt
M

Eliminating t from the above two equations,
V =
mv
m M
0
+

(b) Using Work - Energy theorem
W
f
= K
f
- K
i

W
f
=
1
2
(m + M)V
2
-
1
2
mv
0
2

= -
1
2
mMv
m M
0
2
+
= -
mMgh
m M +

(c) Acceleration of the disc w.r.t the plank is
a
rel
= g +
m
M
g = g
m M
M
+
|
\
|
.
|

x
rel
=
( ) ( )
u
a
Mv
g m M
Mh
m M
rel
rel
2
0
2
2 2
=
+
=
+

4.sol Initial concentration of Fe
3+
=
3 3
10 g 10
moles / litre
1L 56

= (1 Mark)

Let initial concentration of SCN
be a M
[Fe(SCN)]
2+
Fe
3+
+ SCN

Initial 0 1.78 10
5
aM
At eqm. x (1.78 10
5
x) (a x)
x = 6 10
6
M (2 Mark)



6 5 6
6
(a 6 10 )(1.78 10 6 10 )
6 10

= 7.14210
-3

a = 3.637 10
3
M
(1 Mark)

5.sol a)
2
ClF
:- Hybridization
3
sp d =
shape = Linear

Cl F F
b)
( )
3
3
N CH :- Hybridization
3
sp =
shape =Pyramidal
N
CH
3
CH
3
CH
3
c)
2 3
PF r B :-Hybridization
3
sp d =
shape =Trigonal bi pyramidal
P
F Br
Br
F
Br

d)
4
TeCl : Hybridization
3
sp d =
shape =see saw shape

Te
Cl
Cl
Cl
Cl

(e) XeOF
4
:-
Hybridization sp
3
d
2

Structure octahedral
Shape:- square pyramidal
O
Xe
F
F
F
F

6.sol a) Angular nodes special nodes
4d (l) (n-l-1)
2 1
2s 0 1
3p 1 1
b) (i) 0 (ii)
2
1
(iii) 0 (iv)
2
3



7. Coordinates of point E is
|
|
.
|
\
|
+ +
2 2
2
2 2
2
b a
b a
,
b a
ab

Coordinates of point F is
|
|
.
|
\
|
+ + ) b a ( 2
b a
,
) b a ( 2
ab
2 2
2
2 2
2

Slope of AF =
ab
b 2 a
ab
b 2 b a
) b a ( 2
ab
b
) b a ( 2
b a
2 2
2
3 2
2 2
2
2 2
2
+
=
+
=
+
+

D
A(0, b)
B(a, 0) C(a, 0)
E
F

Slope of BE =
2 2
2 2
2
2 2
2
b 2 a
ab
a
b a
ab
b a
b a
+
=
+
+
+

As Product of slopes of AF and BE = 1
AF and BE are perpendicular.

8. We have
2
b a
n
A ...... A A
n 2 1
+
=
+ + +

( ) ab G ...... G G n
1
n 2 1
=
and
ab 2
b a
2
b
1
a
1
n
H
1
.......
H
1
H
1
n 2 1
+
=
+
=
+ + +

Hence | |n
2
n 2 1
n 2 1
n 2 1
G ....... G G
H
1
....
H
1
H
1
n
1
ab
ab 2
b a
n
A ...... A A
(
+ + + =
+
=
+ + +

= ( ) | | ( ) | |
n
1
n 2 1
n
1
2
n 2 1
n 2 1
n
1
2
n 2 1
H
1
....
H
1
.
H
1
G ....... G G
n
H
1
....
H
1
H
1
G ....... G G
(
+ + +

| |
n
1
n 2 1
2
n 2 1 n 2 1
H ......... H H
G ....... G G
n
A ...... A A
(
(
+ + +
.



9. Draw lines L
5
and L
6
through P parallel to L
3
and L
4
respectively.
A
1
PM = PAB = PBA ( AP = BP)
= B
1
PM i.e. L
5

PM is the bisector of L
1
and L
2

L
4
L
3
L
5
L
6
L
1
: a
1
x+ b
1
y+ c
1
=0
L
2
: a
2
x+ b
2
y+ c
2
=0
A
N
O
B
1
B
A
1
M
P

Again APN = PA
1
B
1
= PB
1
A
1
= BPN ( A
1
P = B
1
P)
PN i.e. L
6
is the bisector of L
1
and L
2

Now joint equation of L
5
and L
6
is
2
2
2
2
2 2 2
2
1
2
1
1 1 1
b a
c y b x a
b a
c y b x a
+
+ +
=
+
+ +

Joint equation of L
3
and L
4
is
2
2
2
2
2 2
2
1
2
1
1 1
b a
y b x a
b a
y b x a
+
+
=
+
+
[ L
3
and L
4
are parallel to L
5
and L
6
respectively and
pass through origin ]
(a
1
x + b
1
y)
2
( )
2
2
2
2
b a + = (a
2
x + b
2
y)
2
( )
2
1
2
1
b a + .

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