DAV PUBLIC SCHOOL BALLABGARH

CHEMISTRY ASSIGNMENT 1 CLASS XI(2013-14) UNIT:-1,2

Q1. Calculate the number of atoms & volume of 1gm of He gas at NTP.(1.5056X1023 ,5.6 lts) Q2.Weight of one atom of an element is 6.644x10-23g. Calculate g atom of element in 40 kg (103). Q3.How many atoms of S are present in 49 g H2SO4 (0.5 g atom). Q4. Calculate the no. of Cl- & Ca2+ ions in 222g anhydrous CaCl2 (2n Ca 2+, 4n of Cl- ) Q5. Calculate the no. of atoms of oxygen present in 88g CO2 . What would be the wt. of CO having same no. of oxygen atoms. (112g of CO). Q6. Calculate no. of oxalic acid molecules in 100 ml of 0.02N oxalic acid ( 6.022x1020 ) Q7. Find the wt. of H2So4 in 1200 ml of a solution of 0.2N strength (11.76g) Q8.what wt. of Na2CO3 of 95% purity would be required to neutralize 4.6 ml of 0.235N H2SO4acid(0.978g) Q9. The density of 3m solution of Na2S2O3 is 1.2 g/ml calculate a) By weight of Na2S203 (37.92) b) Mole fractions of Na2S203 (0.06) c) Molarities of Na+ & s203 2- (3.685,7.732) Q10. Calculate molality of 1lt solution of 93% H2so4 by volume the density of solution is 1.84 g/ml (10.42m) Q11. In commercial manufacture of nitric acid. How many moles of No2 produce 7.33mol of HNO3 . in the reaction 3NO2 (g)+H20(l) --- 2HNO3 (aq)+N0(G) (10.995)

Q12. What volume of oxygen at STP is required to effect complete combustion of 200 cm3 of acetylene and what would be the volume of carbon di oxide formed (500 cm3, 400cm3) Q13. What mass of slaked lime would be required to decompose completely 4 grams of ammonium chloride & what would be the mass of each product Ca(OH)2 +2 NH4Cl CaCl2+2NH3+2H20(4.15g &1.3458g 2.766,1.271g) Q14.How much marble of 96.65% purity would be required to prepare 10 L of CO2 at STP when marble is acted upon by HCl (46.62g) Q15. 2.38 g of uranium was heated strongly in a current of air . the resulting oxide weighed 2.806g . Determine the empirical formula & molecular formula.(u=238 O=16) Q16.A compound contains 4.07% hydrogen,24.27% carbon &71.65% chlorine .its molar mass is 98.96g . what are its empirical and molecular formula. .(CH2Cl,C2H4Cl2) Q17. Butyric acid contains only C,H&O. a 4.24mg sample of butyric acid is completely burned . it gives 8.4mg of CO2&3.46 mg of H20.the molecular mass of butyric acid was determined by experiment to be 88 amu what is molecular formula (C4H8O2) Q18.The wavelength of a beam of light is 2.5um. what is (1) Wavelength in cm (2) Its frequency (3) Its wave number and its energy of one of photon ans. ans. (25x10-4cm)

ans. 1.2x1013 s-1 4x102

Q19.A proton is accelerated to one tenth of velocity of light. if its velocity can be measured with a precision of +-1%,what would must be its uncertainty in position? 1.06x10-13 Q20.The velocity associated with a proton is moving is a potential difference of 1000v is ms-1. If hockey ball of mass 0.1 kg is moving with velocity, calculate the wavelength associated with this.(1.2x10-38m) Q21.when would wavelength associated with an electron becomes equal to wavelength associated with proton?(mass of electron = 9.109x10-31kg,mass of proton = 1.6725x10-27) (velocity of electron=1836velocity of proton). Q22. Calculate the wavelength of an electron that has been accelerated in a particle accelerator through a potential difference of 100 million volts. (1ev=1.6x10-19c, me=9.1x10-31kg, h=6.6x10-34js) (1.22x10-13m)