Assignment Structure of atom ASSIGNMENT -2, (CHEMISTRY XI) : 2013-2014 Q.

.1 Calculate the wavelength of a photon in amgstrom units having energy of one electron volt. (ans : 12.42 x 103) Q.2 Calculate and compare the energies of two radiations one with wavelength 800pm and the other with wavelength 400pm. (ans: E2=2E1) Q.3 In a hydrogen atom, an electron jumps from third orbit to first orbit. Find out the frequency of the spectral line. [ans:2.9248 x 1015 s-1(Hz)] Q.4 In a hydrogen atom, the energy of an electron in first Bohrs orbit is - 13.12 x 105 J mol-1. What is the energy required for its excitation to Bohrs second orbit? (ans :9.84 x 105 j mol-1)

Q.5 The atomic spectrum of Li2+ arises due to the transition of an electron from n2 to n1 level. If n1+n2 is
4 and n2-n1 is 2, calculate the wavelength (in nm) of the transition for this series in Li2+. (ans:11.4 nm) Q.6 The ionisation energy of hydrogen atom is 1.312 x 106 J mol-1. Calculate the energy required to excite an electron in a hydrogen atom from the ground state to the first excited state. (Avogadros constant=6.022 x 1023 mol-1) (ans :1.635 x 10-18 J atom-1) Q.7 The ionisation energy of He+ ion is 19.6 x 10-18 J atom-1. Calculate the energy of the first excited state of Li2+ ion. (ans : -4.41 x 10-17 J atom-1) Q.8 Calculate the de Broglie wavelength of an electron moving with 1% of the speed of light. (ans :2.43 x 10-10m) Q.9 The kinetic energy of an electron is 4.55 x 10-25 J. The mass of an electron is 9.1 x 10_31 kg. Calculate velocity, momentum and the wavelength of the electron. (ans :7.28 x 10-7m) Q.10 Calculate the kinetic energy of a moving electron which has wavelength of 4.8pm. (ans: 1.051 x 10-14J) Q.11 when would wavelength associated with an electron become equal to the wavelength associated with an proton? ( me = 9.1095 x 10-28 g and mp= 1.6725 x 10-24 g) (Ans: ve= 1836 vp) Q.12 An electron is moving with a kinetic energy of 2.275 x 10-25 J. Calculate its de Broglie wavelength. (ans : 1.04 x 10-6 m s-1) Q.13 Calculate the wavelength of 100 kg rocket moving with a velocity of 300 km per hour. (ans:7.95 x 10-35 m) Q.14 Calculate the uncertainity in the momentum of an electron if it is confined to a linear region 1 x 10-19 meter . (ans: 1.45 x 10-2m) Q.15 A proton is accelerated to one tenth of velocity of light. if its velocity can be measured with a precision of + 0.5%, what must be uncertainity in its position? (ans: 2.1 x 10-31m) Q.16 The uncertainity in measuring the speed of an accelerated electron is 1.2 x 105 m s-1. Calculate the uncertainity in finding its location while it is still in motion. (given: me=9.31 x 10-31 kg) (ans:4.72 x 10 -10 m)

Q.17 Calculate the uncertainity in velocity of a cricket ball of mass 150 g if uncertainity in position is of the order of 1. (Ans: 3.51 x 10-24 m s -1) Q.18 Show that Heisenbergs uncertainity principle is of negligible significance for an object of mass 10-6 kg (given: h/4=0.528 x 10-34 kg m2 s-1) (Ans: 0.528 x 10-28 m2 s-1) Q.19 The uncertainity in the position and velocity of a particle are 10-10 m and 5.27 x 10-24 ms-1 respectively. Calculate the mass of the particle. (Ans: 0.1 kg) Q.20 The speed of an electron moving at 600 m s -1 is measured to the accuracy of 0.005%. What will be the minimum error in determining its position. (Ans: 1.93 x 10-3 m) Q.21 (a) An atomic orbital has n=3, what are the possible values of l? (b)An atomic orbital has l=3, what are the possible values of ml? Q.22 From the following sets of quantum numbers, states which are possible. Explain why the others are not possible. (i) n=0,l=0,ml=0.s=+1/2 (ii)n=1,l=o ,ml=0,s=-1/2 (iii) n=1,l=1,ml=0,s=+1/2 (iv)n=1,l=o ,ml=+1,s=+1/2 Q.23 An electron is present in 4f sub-shell. Write the possible values for all the quantum numbers. Q.24 Arrange the electrons represented by the following sets of quantum numbers in decreasing order of energy. (i)n=4.l=0,ml=0,s=+1/2 (ii)n=3,l=1,ml = 1,s= -1/2 (iii)n=3.l=2,ml =0,s=+1/2 (iv)n=3,l=o, ml =o, s= -1/2 Q.25 The mass no. of an element is twice its atomic number. If there are four electrons in 2p orbitals , ,write the electronic configuration of the element and name it. Q.26 Write down the electronic configuration of the following and report the numbers of unpaired electrons in each case. (a)Mn4+ (b)Fe3+ (c)Cr2+ (d)Zn2+ Q.27 Name the tripositive ion which is represented by the configuration: 1s2 2s2 2p6 3s2 3p6 3d5 Q.28 Write the electronic configuration of the elements (I ) 919 F (ii)3618 Ar (iii) 3216S Point out the element with (a) Maximum nuclear charge (b) Minimum number of neutrons(c) Maximum mass no. (d)Maximum no. of unpaired electrons. [Ans (a) Ar (b) F (c) Ar (d) S] Q.29 Write down all the four quantum nos. for (i) 19th electron of 24Cr (ii) 21st electron for 21Sc. Q.30 Light of wavelength 5000 falls on a metal surface of work function 1.9eV. Find (a) the energy of photons (b) kinetic energy of photoelectrons. (Ans: 9.3 x 10-20J) Q.31 when a certain metal was irradiated with light of frequency 1.6 x 106 Hz, the photoelectrons emitted had twice the kinetic energy as photoelectrons emitted when the same metal was irradiated with light of frequency 1.0 x 106 Hz. Calculate the threshold frequency (v0) for the metal. (Ans: 4 x 1015Hz) Made by: Mrs. Padmini Aggarwal