Solutions Code AC204

SECTION I (1) (a) AgCl(s) +e- (Ag(s) + Cl = 0.22V Cl2 + e- Cl = 1.36V Wt get Ag(s) + Cl2(g) AgCl(s) Cell = 1.44V by = = = F -(1) 96500 x 1.4 -110 kJ/mol.

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(2)

(b)
+

OMe +

OMe +

OH

O MeO

H O MeO MeO

(3) Sol.

(a)s From salts of magnesium, magnesium cannot be extracted by other chemical methods as magnesium itself acts as a reducing agent and Mg obtained at cathode during electrotypes of its salt solution reacts with water forming Mg MgCl2 Mg2+ + 2Clat cathode :- Mg2+ + 2e- Mg at as ode :- 2Cl- Cl2 + 2e-

(4)

(c) Based on theory (a) 2 M O4- + 16N+ 2Cl- 2 Mn2+ + Cl2 + 8N2O (a) Ph c cn
excess

(5)

(6)

PhC CHCl2 ||

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O NaOH PhCCH || || O O Internal cannizaro OH(-) H I Ph C CO | || OH O ()

SECTION II (1) Sol. (a, b) Ksp = 1.1 x 10-11 = (1.4 x 10-4)x+y so we have, (by comparing values) so, = = Hence, =4

(2) Sol.

(a, b, c) a, b and c are correctly method. (d) tetrahedral, CO stronger legend so pairing of electrons occurs.

(3) Sol.

(a, b, c, d) A(g) t=0 400 2B(g) 0 + C(g) 0

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t=20 400-P Given,

2P

400 P + 2P + P = 1000 400 + 2P = 1000 P = 300mm k= k= min-1 = 4

T = 10 min Value of k = 0.0693 min-1 400 200 100 50

10 min 10 min 10 min

After After After After (4)

30 30 30 30

min min min min

partial pressure of A is 50 mm partial pressure of B is 700 mm partial pressure of C is 350 mm total pressure becomes 1150 mm

(a, d)

SECTION III (1) (2) (c) (a)

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Sol.

Potassium and cesium have low ionization energies and, therefore, their valence shell electrons can be easily eject off by the energy of light. (b) (c)

(3) (4)

SECTION IV Paragraph: (1) Sol. (a) pOH of the buffer = - log Kb + log = NH3 + HCl NH4Cl [Salt] = [Base] = 0.1 + 0.06 = 0.16 M1 0.1 0.06 = 0.04 M -log 1.8 x 10-5 + log

(2)

= log Kb + log = 4.75 + 0.602 = 5.352 = 14 5.352 = 8.648 = 9.25 8.648 = 0.602

(3)

NH4Cl + NaOH [Salt] =

+ NaCl + OH-

0.1 0.06 = 0.04M

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[Base]=

0.1 + 0.06 = 0.16M

= - log Kb + log = 4.75 + log = 4.148

= 14 4.148 = 9.852 = 9.852 9.25 = 0.602

Paragraph: (1) Sol. (c) In Cannizaro reaction, the best hydride donor is H

C O
O

CH3

This reaction is intermolecular Cannizaro reaction. Both oxidation and reduction takes place in the same molecule.

CCHO O Conc. NaOH Ph CHCOONa OH

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(3)

(b) Aldehyde is more reactive than kete group. Hence with one equivalent of glycol, acetal formation takes place with aldehyde group only. O O

One equivalent

CHO

OCH2 CH OCH2 (X) CH3OH NaBH4 H OH

OH

CHO (Z) Paragraph: (1) (2) (3) (b) (d) From the graph From the graph The slope of the line shown in graph. (Y)

CH

OCH2 OCH2

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