Marta Garca-Mat*, Isabel Santacruz*, ngeles G. De la Torre, Miguel A.G. Aranda Departamento de Qumica Inorgnica, Cristalografa y Mineraloga, Facultad de Ciencias, Campus de Teatinos s/n, University of Malaga, 29071 Malaga, Spain *e-mails: martagmate@uma.es, isantacruz@uma.es
Introduccin
Calcium sulfoaluminate (CSA) cements are receiving increasing attention since their manufacture produces less CO2 than ordinary Portland cement (OPC) [1]. These binders may have quite variable compositions, but all of them contain Yeelimite phase, also called Kleins salt or tetracalcium trialuminate sulfate (C4A3S) as the main phase [2]. They may also have minor amount of phases such as C2S, CA, C4AF, CS, CSH2 [3], where C=CaO, S=SiO2, A=Al2O3, F=Fe2O3, S=SO3, M=MgO, T=TiO2 and H=H2O. The mortar and concretes derived from these cements show high strength developments at early-ages [4] and could also be used for radioactive element encapsulation [5]. Another environmental strategy for reducing the negative impact of the cement industry is related with the reduction of the clinker content in concretes [6]. This is possible by the partial substitution of cement by supplementary cementitious materials (SCMs) mainly from power stations or metal industry (fly ash, slag or silica fume). The environmental benefits of the use of waste materials are two folds: the clinker reduction will produce lower CO2 emissions; and the valorization of an useless product. Furthermore, fly ash improves some properties of OPC mortars and concretes due to the pozzolanic reaction and its role as a micro-filler. Objetive This work deals with the study of the potential pozzolanic effect of fly ash (FA) on CSA cement pastes and mortars. This will allow the fabrication of environmentally friendly cements (by the use of CSA clinker and its partial substitution with by-products), and mortars with improved mechanical properties at long ages.
DTA-TGA
0 wt% FA, w/b=0.50
28 days
X10E 3 3 .0
Gypsum
Gypsum
Mullite
Quartz
Mullite
Gypsum
C4A3S
Mullite
Mullite
2 .0
C4A3S
C4A3S
28d
wt%
Gibbsite
CO2
C o u n ts
0 .0
1 .0
30.0
40.0
7d
Gibbsite
AFt
CSA Clinker
Gypsum 25 wt%
Fly Ash
(Lada, Spain)
3d
10 20
Vaterite
AFt
days
30
40
0.50 Water/binder 0.65 (without FA) (w/b) Sand Hydration time: Mortar 3, 7, 28 days To be 6 months, 1 year
28d
CSH2 C4A3S
-C2S FW
CO2 Gibbsite
wt%
Cement Pastes
7d
Amorphous
Rietveld methodology Compressive Strength LXRD Amorphous quantification (G-factor) Calorimetry TDA-TGA Porosimetry
measured
AFt
3d
10 20
Gibbsite Vaterite
30 40
AFt
days
Rietveld
15 wt% FA, w/b=0.50
3 days
1.0x10-2
8.0x10
-3
300
0 wt% FA, w/b=0.50 15 wt% FA, w/b=0.50 30 wt% FA, w/b=0.50
28d
6.0x10
-3
2.0x10-3 0.0 0 2
1.5
2.0
AFt
50 0
10
12
14
10
12
14
time (days)
time (days)
3d
10 20
Vaterite
Gibbsite
days
Porosimetry (pastes)
Compressive Strength (MPa)
Open Porosit y* (vol %) 20.3 14.7 17.4 18.8
30
40
PASTE 0 wt% FA, w/b=0.65 0 wt% FA, w/b=0.50 15 wt% FA, w/b=0.50 30 wt% FA, w/b=0.50
80 60 40 20 0
AFt
28d
wt%
-C2S FW
AFt
AFt
4.0x10-3
AFt
7d
Amorphous
AFt Gibbsite AFt Gibbsite Gypsum AFt AFt C A 4 3S AFt AFt Vaterite AFt Quartz Vaterite AFt
AFt
7d
Amorphous
AFt
AFt Gibbsite
3d
1 3
Vaterite
days
10 20
days
3d3
2 7
3 28
30
40
- Pastes ( 28 days). By Increasing FA content: Normal heat flow decreases (due to the lower hydraulic active matter) Amorphous/non-diffractive matter content increases. Weight loss decreases (for the same w/b) according to TGA. Open porosity increases. - Mortars ( 28 days). By Increasing FA content: Compressive strength values decrease. However, it may be expected a different behaviour at longer hydration times (6 months).
Conclusions
References
[1] Gartner E., Cem. Concr. Res. 2004, 34, 1489. [2] lvarez-Pinazo G., Cuesta A., Garca-Mat M., Santacruz I., Losilla E.R., De la Torre A.G., Len-Reina L., Aranda M.A.G., Cem. Concr. Res., 2012, 42, 960. [3] Sahu S., Majling J., Cem. Concr. Res., 1993, 23, 1331. [4] Glasser F.P., Zhang L., Cem. Concr. Res., 2001, 31, 1881. [5] Zhou Q., Milestone N.B., Hayes M., J. Hazard. Mater., 2006, 136, 120. [6] Bensted J., Barnes P., Structure and performance of cements. 2002, 2nd ed. New York: Spon Press.
Acknowledgements
This work has been supported by Spanish Ministry of Science and Innovation through MAT2010-16213 research grant, which is cofunded by FEDER, and Ramn y Cajal Fellowship (RYC-2008-03523).
AFt
Gypsum
Gypsum
AFt Gibbsite AFt Gibbsite Gypsum AFt AFt C4A3S AFt AFt Vaterite AFt Quartz Vaterite AFt Gypsum AFt Gypsum
wt%
AF t
8.0x10-3
6.0x10-3
250