Disusun oleh :
HILDA ROSALINA
Kelas : 3 KIA
DIAGRAM BLOK
NaOH = 75 %
Na2S = 25 %
H2O
Selulosa = 43 %
Hemiselulosa = 25%
3,5 ton
BLOW TANK
Lignin = 16%
Ekstraktif = 1 %
Air
= 15 %
Selulosa
Hemiselulosa
STRAINER
T
Tiol
A
C5H10O5Na
R
Y
Selulosa
Selulosa
Hemiselulosa
Hemiselulosa
Lignin
Lignin
Tiol
Tiol
C5H10O5Na
C5H10O5Na
H2O
Selulosa
Hemiselulosa
Lignin
Tiol
H2O
C5H10O5Na
Ekstraktif
H2O
NaOH
Na2S
kayu
= 3,5 = 3500 kg
NaOH = 75%
Na2S = 25%
Hemiselulosa (C6H12O6)
Lignin
Kayu = 3500 kg
Selulosa (C6H10O5 CH3) = 43 %
C6H10O5Na
Hemiselulosa (C6H12O6) = 25 %
H2O
Lignin
= 16 %
Tiol (mercaptan)
Ekstraktif
=1%
H2O
= 15 %
NaOH
Na2S
Lignin
Ekstraktif
H2O
CH3 OH
Diketahui Bahan Baku Kayu yang telah menjadi chips = 3,5 ton
= 3500 kg
a. Selulosa (C6H10O5 CH3)
Gr
= 43 % x 3500 kg = 1505 kg
Mol
b. Hemiselulosa (C6H12O6)
Gr
= 25 % x 3500 kg = 875 kg
Mol
c. Lignin
Gr
= 16 % x 3500 kg = 560 kg
d. Ekstraktif
Gr
= 1 % x 3500 kg = 35 kg
e. H2O
Gr
= 15 % x 3500 kg = 525 kg
Cairan Pemasak
R Na + ROH
(sellulosa)
R R +Na2S
Dalam hal ini, Sellulosa diasumsikan dengan C6H10O5 CH3 , dan Hemisellulosa
diasumsikan dengan glukosa C5H11O5COH
Reaksi ke-1
C6H10O5 CH3
Mula-mula : 8, 503
Bereaksi
: 5, 952
sisa
2,551
BM
177
Massa
: 451,527 kg
70 %
NaOH
C6H10O5 Na + CH3OH
262,500
5, 952
5, 952
5,952 kmol
256,548
5,952
5,952
185
32
40
10261,920 kg
1101,120 kg
190,464 kg
Reaksi ke-2
C5H11O5COH
Mula-mula : 4, 861 kmol
Na2S
44,871kmol
70%
C5H11O5CSHNa2 - O2
-
Bereaksi
: 3, 402 kmol
3,402 kmol
3,402 kmol
Sisa
: 1,459 kmol
41,469 kmol
3,402 kmol
BM
: 180 kg/kmol
78 kg/kmol
258 kg/kmol
Massa
: 262,620 kg
3234,582 kg
877,716 kg
Input (kg)
Output (kg)
1505
451,527
Hemiselulosa (C5H11O5COH)
875
262,620
Lignin
560
310
250
ekstraktif
35
35
Air
525
25
500
NaOH
10500
10261,960
Na2S
3500
3234,582
C6H10O5 Na
1101,120
CH3OH
190,432
C5H11O5CSHNa2) - O2
877,716
TOTAL
3500
14000
14056,974
3442,983
17500
17500
NaOH = 10500 kg
Na2S
= 3500 kg
Total = 14000 kg
sellulosa
= 1505 kg
hemiSellulosa = 875 kg
sellulosa
= 451,527kg
Lignin
= 560 kg
Ekstraktif
= 35 kg
H2O
= 525 k9
Total
= 3500 kg
C6H10O5Na
= 1101,120 kg
Lignin
= 250 kg
H2O
= 500 kg
Total
= 3442,983kg
DIGESTER
1
hemiSellulosa = 262,620 kg
NaOH
= 10261,960 kg
Na2S
= 3234,582 kg
Lignin
= 310 kg
Ekstraktif
= 35 kg
H2O
= 25 kg
CH3 OH
= 190,432 kg
Total
= 14056,974 kg
Hemisellulosa = 13 %
2
STRAINER
3442,983kg
Sellulosa
= 16 %
Sellulosa
= 15 %
80 % Tiol (marcaptan) = 23 %
C6H10O5Na
= 30 %
Lignin
= 10 %
H2O
=9%
3 20 %
HemiSellulosa = 9 %
Tiol (marcaptan) = 6 %
C6H10O5Na
= 13%
Lignin
= 34 %
H2O
= 22 %
Hemisellulosa = 25 %
Sellulosa
= 16 %
Tiol (marcaptan) = 14 %
C6H10O5Na
= 16 %
Lignin
= 23 %
H2O
= 6 %
Pada strainer, terjadi pemisahan antara pulp dan black liquor dengan perbandingan 80 % dan
20% ,
Sehingga :
pulp yang di hasilkan 80% x 3442,983 kg = 2754,38 kg
black liquor
= 13 % x 2754,386 kg
= 358,070 kg
Sellulosa
= 15 % x 2754,386 kg
= 413,158 kg
Tiol (marcaptan)
= 23 % x 2754,386 kg
= 633,509 kg
C6H10O5Na
= 30 % x 2754,386 kg
= 826,316 kg
Lignin
= 10 % x 2754,386 kg
= 275,440 kg
H2O
= 9 % x 2754,386 kg
= 247,895 kg
Hemisellulosa
= 25 % x 688,596
= 172,149 kg
Sellulosa
= 16 % x 688,596
= 110,175 kg
Tiol (marcaptan)
= 14 % x 688,596
= 96,403 kg
C6H10O5Na
= 16 % x 688,596
= 110,175 kg
Lignin
= 23 % x 688,596
= 158,377 kg
H2O
= 6 % x 688,596
= 41,316 kg
Komposisi
Input (kg)
1
Output (kg)
2
Hemiselulosa
selulosa
tiol
C6H10O5Na
lignin
Air (H2O)
550,8773
309,8685
206,579
447,5878
1170,614
757,4563
358,070
413,158
633,509
826,316
275,440
247,895
172,150
110,175
96,403
110,175
158,377
41,316
TOTAL
3442,983
2754,388
688,595
3442,983
= 309,8685 kg
Selulosa
Selulosa
= 413,158 kg
Hemiselulosa
= 358,070 kg
Tiol
= 633,509 kg
C6H10O5Na
= 826,316 kg
Lignin
=275,440 kg
H2O
= 247,895 kg
Total
= 2754,388 kg
Hemiselulosa = 550,8773 kg
Tiol
= 206,579 kg
C6H10O5Na
= 447,5878 kg
Lignin
= 1170,614 kg
H2O
= 757,4563 kg
Total
Total
= 605,
= 3442,983 kg
STRAINER
Selulosa
= 110,175 kg
Hemiselulosa
=172,149 kg
Tiol
= 96,403 kg
C6H10O5Na
= 110,175 kg
Lignin
= 158,377 kg
H2O
= 41,316 kg
Total
= 688,595 kg
kg
= 413,158 kg
= 633,509 kg
C6H10O5Na
= 826,316 kg
= 413,158 kg
Hemiselulosa
= 358,070 kg
Tiol
= 633,509 kg
BLOW TANK
C6H10O5Na
= 826,316 kg
Lignin
=275,440 kg
Total
= 2506,493 kg
=275,440 kg
H2O
= 247,895 kg
Total
= 2754,388 kg
kg
Selulosa
= 358,070 kg
Tiol
Lignin
H2O = 247,895 kg
H2O = 250 kg
Selulosa
= 413,158 kg
Hemiselulosa
= 358,070 kg
2506,493 kg
Tiol
= 633,509 kg
C6H10O5Na
= 826,316 kg
Lignin
=275,440 kg
ROTARY
DRUM
FILTER
75 %
Hemisellulosa = 15%
Sellulosa
= 36 %
Tiol (marcaptan) = 20 %
C6H10O5Na
= 27 %
H20
=2%
25 %
Hemisellulosa = 13 %
Sellulosa
= 14 %
Tiol (marcaptan) = 27 %
C6H10O5Na
= 28 %
Lignin
= 10 %
H2O
=8%
Pada Rotary Drum Filter , terjadi pemisahan antara pulp dan black liquor dengan
perbandingan 75 % dan 25 % ,
Sehingga :
Pulp
Black liquor
= 15% x 2067,370 kg
= 310,106 kg
Sellulosa
= 36 % x 2067,370 kg
= 744,253 kg
Tiol (marcaptan)
= 20 % x 2067,370 kg
= 413,472 kg
C6H10O5Na
= 27 % x 2067,370 kg
= 558,190 kg
H2O
= 2 % x 2067,370 kg
= 41,3474 kg
= 89,586 kg
Sellulosa
= 96,4772 kg
= 14 % x 689,123 kg
= 186,063 kg
C6H10O5Na
= 28 % x 689,123 kg
= 192,954 kg
Lignin
= 10 % x 689,123 kg
= 68,9123 kg
H2O
= 8 % x 689,123 kg
= 55,1298 kg
Output (kg)
Komposisi
1
selulosa
hemiselulosa
tiol
C6H10O5Na
lignin
H2 O
2
-
413,158
358,070
633,509
826,316
275,440
2506,493
TOTAL
250
250
2756,493
96,4772
89,586
744,253
310,106
186,063
192,954
68,9123
55,1298
689,123
413,472
558,190
41,3474
2067,370
2756,493
Selulosa
= 413,158 kg
Hemiselulosa
= 358,070 kg
Tiol
= 633,509 kg
C6H10O5Na
1
= 826,316 kg
Lignin
= 275,440 kg
Total
H2O = 250 kg
2
ROTARY
1
DRUM
FILTER
Selulosa
= 744,253 kg
Hemiselulosa
= 310,106 kg
Tiol
= 186,063 kg
C6H10O5Na
= 413,472 kg
H2O
= 41,3474 kg
Total
= 2067,370 kg
= 2506,493 kg
Selulosa
= 96,4772 kg
Hemiselulosa
= 89,586 kg
Tiol
= 186,063 kg
C6H10O5Na
= 192,954 kg
Lignin
= 68,9123 kg
H2O
= 55,1298 kg
Total
= 689,123 kg