FirstExamination Form 4 IntroductiontoAnalyticalChemistryR.LopezdelaVega BubbleintheformnumberinthesectionentitledGradeorEducinthescantron. MULTIPLECHOICE.Choosetheonealternativethatbestcompletesthestatementoranswersthequestion. 1) Asolutionispreparedbydissolving49.3gofKBrinenoughwatertoform473mLofsolution. Calculatethemass%ofKBrinthesolutionifthedensityis1.12g/mL. A) 11.7% B) 9.31% C) 8.57% D) 10.1% E) 10.4% 2) Determinethemolalityofasolutionpreparedbydissolving0.500molesofCaF2in11.5moles H2O. A) 4.

14m B) 5.31m C) 4.35m D) 1.88m E) 2.41m 3) 1)

2)

3) WhatprecipitateismostlikelyformedfromasolutioncontainingBa+2,Na+1,OH-1,and CO 3-2. A) Ba(OH)2 B) Na2CO 3 C) BaCO3 D) NaOH 4) WhichofthefollowingisaSTRONGacid? A) C6H5CO 2H B) NH4+ C) HClO4 D) H2O E) HCN 5) InthestandardizationofaofaHClsolutionversusKHP(potassiumHydrogenPhathallate),a

4)

5)

technician failed to dry the KHP completely. Did this error cause his reported concentration of hydrochloric acid to be too high, too low, or correct?
A) toohigh B) toolow C) correct D) Choosethisanswerifmoreinformationisneeded E) Choosethisansweronlyifnoneoftheaboveanswerswouldbecorrect. 6) Amoonrockmustbesampled.Itiscomposedof3substanceswhicharedistributedinsucha waythatpocketsofsubstanceAareseentopredominaeontheoutsideoftherockwhile substancesBandCpredominateontheinsideoftherock.Thisrockwouldbeconsidered: A) homogeneous B) randomheterogeneous C) segregatedhomogeneous D) segregatedheterogeneous E) Choosethisansweronlyifnoneoftheaboveanswersarecorrect. 7) WhichofthefollowingwouldmostlikelybedesignatedasTD? A) Atransferpipette B) Avolumetricflask C) Aburet D) MorethanoneoftheabovewouldbedesignatedasTD E) NoneoftheabovewouldbedesignatedasTD. D1 6)

7)

Form 4
8) Identifytheweakestacid. A) HBr B) HI C) HF D) HCl E) notenoughinformationisavailable 9) A1.00Lsampleofwatercontains0.0036gofCl ions.Determinetheconcentrationof chlorideionsinppmifthedensityofthesolutionis1.00g/mL. A) 7.2ppm B) 1.8ppm C) 2.8ppm D) 5.4ppm E) 3.6ppm 10) IdentifyHCl. A) weakelectrolyte,strongacid B) strongelectrolyte,weakacid C) strongelectrolyte,strongacid D) weakelectrolyte,weakacid E) nonelectrolyte 11) Allanalyticalinstrumentshavesomelevelofvariabilitythatweassociatewiththe 8)

9)

10)

11)

followingstatements,except:
A) Determinateerror B) Bellshapecurve C) Normaldistribution D) Gaussiandistribution E) Choosethisansweronlyifnoneoftheabovearecorrect. 12) Whichofthefollowingareconsideredacceptableinanalyticalchemistry? A) grosserror B) determinateerror C) randomerror D) morethanoneoftheaboveisconsideredacceptable E) Itisnecesarytoremovealloftheaboveinordertocarryoutananalysisproperlay. 13) Calculatethepropagationoferrorinthefollowingcalculation: 12)

13)

20.0 ( 3.0%) + 20.0 ( 10.0%) =

A) 40.0(1%) B) Notenoughinformationisprovidedtoanswerthisquestionproperly. C) 40(5%) D) 40.0(5%) E) Choosethisansweronlyifnoneoftheaboveanswersarecorrect.

D2

Form 4
14) Howcanyoureducetherangeofaconfidenceinterval? A) decreasen B) increasen C) increaseoutliers D) increasevariance E) Choosethisansweronlyifnoneoftheaboveanswersarecorrect. 15) Whatistheconcentrationofnitrateionsina0.125MMg(NO3)2 solution? A) 0.375M B) 0.0625M C) 0.125M D) 0.160M 14)

15) E) 0.250M 16)

16) Accordingtothefollowingreaction,whatvolumeof0.244MKClsolutionisrequiredtoreact exactlywith50.0mLof0.210MPb(NO 3)2solution? 2KCl(aq)+Pb(NO 3)2(aq)PbCl2(s)+2KNO3(aq) A) 43.0mL B) 58.1mL C) 116mL D) 97.4mL E) 86.1mL

17) Precisionisbestexemplifiedbythefollowingstatement(s): A) Themedianofthesetofmeasurements B) Theclosenessofthevaluestotheacceptedortruevalue C) Theclosenessofrepeatedvalues D) Alloftheabove E) Donotchoosethisanswer 18) Accuracyisbestexemplifiedbywhichofthefollowingstatments? A) Theclosenessofthevaluestotheacceptedortruevalue B) Theclosenessofrepeatedvalues C) Themedianofthesetofmeasurements D) Themodeofasetofmeasurements E) Alloftheabovearecorrect. 19) Whatistheintervalwherethepopulationaveragemaybefoundwitha95%confidence

17)

18)

19)

forthefollowingsampledatacollected:20.0,21.0,22.0,20,24,22,23.(dfmeansdegrees offreedom) (t-valueat95%Confidence3df=3.182,4df=2.776,5df=2.571,6df=2.447,7df=2.365) A) 21.7(6.4%) B) 23.1(1.383) C) (19.0to24.0)

D) moreinformationisneededtosolvethisproblem E) Choosethisansweronlyifnoneoftheabovearecorrect. 20) Calculatethemolalityofasolutionformedbydissolving27.8gofLiIin500.0mLofwater. A) 0.394m B) 0.556m C) 0.254m D) 0.241m E) 0.415m 21) Thefollowingnumberhashowmanysignificantfigures,20.020? A) 5 B) 6 C) 4 D) 3 E) 2 20)

21)

D3

Form 4
22) Givethenetionicequationforthereaction(ifany)thatoccurswhenaqueoussolutionsof Al(C2H3O2)3andLiNO3aremixed. A) Al3+(aq)+3NO 3-(aq)+Li+(aq)+C2H3O2-(aq)Al(NO3)3(aq)+LiC2H3O2(s) B) Li+(aq)+C 2H3O2-(aq)LiC2H3O2(s) C) Al3+(aq)+3NO3-(aq)Al(NO3)3(s) D) 3Li+(aq)+(C2H3O2)33-(aq)Li3(C2H3O2)3(s) E) Noreactionoccurs. 23) Samplingisconsideredoneofthemostcriticalpartsofananalysisbecause: A) resultsobtainedfromacompromisedsamplemaybeerroneous B) resultsareonlyasreliableasthelaboratorysample C) thelaboratorysamplemustberepresentativeofthebulksample D) morethanoneoftheaboveiscorrect E) noneoftheabovearecorrect. 23) 22)

D4

AnswerKey Testname:QUANTEXAM1

1) B 2) E 3) C 4) C 5) NoCorrectAnswerWasProvided. 6) D 7) D 8) C 9) E 10) C 11) A 12) C 13) C 14) B 15) E 16) E 17) C 18) A 19) NoCorrectAnswerWasProvided. 20) E 21) B 22) E 23) C

D5

Exam 1 form 4 1- Five high precision pH measurements of gastric juices are carried out and the following values are obtained. Sample number 1 2 3 4 5 pH 1.655 1.607 1.601 1.625 1.695 Concentration of H+ 0.0221 0.0247 0.0251 0.0237 0.0202

Use the Q test and Grubbs test to determine if any outlier should be thrown out. (show your work) 2Sample number 1 2 3 4 5 30.100 0.105 0.120 0.122 0.127 Calculate the purity (as % Na2CO3) of a 500 mg sample which required 19.25 mL of 0.1650 M Calculate the 90% and 99% confidence limits for the determination of lead in glazed ppm lead

pottery.

HCl solution for complete neutralization. First determine the reaction which is occurring in the analysis.