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UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS General Certificate of Education Ordinary Level

CHEMISTRY Paper 1 Multiple Choice

5070/11
May/June 2013 1 hour Multiple Choice Answer Sheet Soft clean eraser Soft pencil (type B or HB is recommended)

Additional Materials:

*4644508399*

READ THESE INSTRUCTIONS FIRST Write in soft pencil. Do not use staples, paper clips, highlighters, glue or correction fluid. Write your name, Centre number and candidate number on the Answer Sheet in the spaces provided unless this has been done for you. DO NOT WRITE IN ANY BARCODES. There are forty questions on this paper. Answer all questions. For each question there are four possible answers A, B, C and D. Choose the one you consider correct and record your choice in soft pencil on the separate Answer Sheet. Read the instructions on the Answer Sheet very carefully. Each correct answer will score one mark. A mark will not be deducted for a wrong answer. Any rough working should be done in this booklet. A copy of the Periodic Table is printed on page 16. Electronic calculators may be used.

This document consists of 13 printed pages and 3 blank pages.


IB13 06_5070_11/4RP UCLES 2013

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2 1 In which method of separation are Rf values used? A B C D 2 chromatography crystallisation filtration fractional distillation

The diagrams show the arrangement of particles in three solids: krypton, potassium and sodium chloride.
+ + + e + e e e e e

In which order are the solids shown? A B C D 3 krypton; potassium; sodium chloride krypton; sodium chloride; potassium sodium chloride; krypton; potassium sodium chloride; potassium; krypton

In which pair do neither of the gases change the colour of damp blue litmus paper? A B C D ammonia and hydrogen ammonia and hydrogen chloride carbon dioxide and chlorine carbon dioxide and sulfur dioxide

Naturally-occurring bromine has a relative atomic mass of 80 and consists entirely of two isotopes of relative atomic masses 79 and 81. What can be deduced about naturally-occurring bromine from this information only? A B C D Bromine contains the two isotopes in equal proportions. Bromine has different oxidation states. Bromine isotopes have different numbers of protons. Bromine is radioactive.

Which compound has molecules each of which contains only two covalent bonds? A CH4 B H2O C MgCl 2 D Na2O

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3 6 What can be deduced about two gases that have the same relative molecular mass? A B C D 7 They have the same boiling point. They have the same number of atoms in one molecule. They have the same rate of diffusion at room temperature and pressure. They have the same solubility in water at room temperature.

An ionic bond is formed by A B C D electron sharing between metals and non-metals. electron sharing between non-metals. electron transfer between non-metals. electron transfer from metals to non-metals.

Both magnesium oxide, MgO, and aluminium oxide, Al 2O3, are solids at room temperature, 25 C. MgO has a melting point of 2852 C and a boiling point of 3600 C. Al 2O3 has a melting point of 2072 C and a boiling point of 2880 C. Over which temperature range will both pure compounds conduct electricity? A B C D 25 to 2852 C 2072 to 2852 C 2852 to 2880 C 2880 to 3600 C

Which substance conducts an electric current but remains chemically unchanged? A B C D aluminium aqueous sodium chloride molten lead(II) bromide pure ethanoic acid

10 Which statement most clearly indicates that diamond and graphite are forms of carbon? A B C D Both are crystalline solids. Complete combustion of equal masses of both solids produces equal masses of carbon dioxide as the only product. Graphite conducts electricity whereas diamond is an insulator. Under suitable conditions graphite can be partially converted into diamond.

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4 11 In an experiment, 1 cm3 of a gaseous hydrocarbon X required 4 cm3 of oxygen for complete combustion to give 3 cm3 of carbon dioxide. All gas volumes are measured at r.t.p. Which formula represents X? A C2H2 B C2H4 C C3H4 D C3H8

12 What is the concentration of a solution containing 1.0 g of sodium hydroxide in 250 cm3 of solution? A B C D 0.025 mol / dm3 0.10 mol / dm3 0.25 mol / dm3 1.0 mol / dm3

13 The diagrams show an electrolysis experiment using inert electrodes.

liquid Y

before electrolysis

after electrolysis

Which could be liquid Y? A B C D aqueous copper(II) sulfate concentrated aqueous sodium chloride dilute sulfuric acid ethanol

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5 14 Which substance, when added to water, does not make a solution that is a good conductor of electricity? A B C D barium nitrate calcium chloride lead(II) nitrate zinc carbonate

15 A simple cell is shown below.

voltmeter V

zinc electrode

copper electrode

electrolyte

Which statement about the process occurring when the cell is in operation is correct? A B C D Cu2+ ions are formed in solution. Electrons travel through the solution. The reaction Zn Zn2+ + 2e occurs. Zinc increases in mass.

16 The usual conditions for the Haber process are 250 atm pressure, 450 C and an iron catalyst. Which change in conditions would give the reactants more energy? A B C D addition of more catalyst a decrease in pressure an increase in concentration of the reactants an increase in temperature

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6 17 Chlorine can be manufactured by the following reaction. 4HCl (g) + O2(g) A mixture in dynamic equilibrium is formed. Which change to the mixture will increase the amount of chlorine at equilibrium? A B C D adding a catalyst adding more HCl (g) decreasing the pressure increasing the temperature 2H2O(g) + 2Cl 2(g) H is negative

18 Equations for reactions of iron and iron compounds are shown. Fe + 2HCl FeCl 2 + H2 2FeCl 2 + Cl 2 2FeCl 3 FeSO4 + Mg Fe + MgSO4 FeSO4 + 2NaOH Fe(OH)2 + Na2SO4 How many of these are redox reactions? A 1 B 2 C 3 D 4

19 Which is a use of sulfuric acid? A B C D as a bleach in the manufacture of ammonia in the manufacture of fertilisers in the manufacture of sulfur trioxide

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7 20 The table shows the solubility of some compounds of metal Q in cold water. salt carbonate chloride sulfate What is metal Q? A B C D barium lead magnesium sodium solubility in cold water insoluble soluble insoluble

21 A metal M forms a chloride which dissolves in cold water and has an oxide which dissolves in both strong acids and strong alkalis. What is M? A B C D iron lead sodium zinc

22 Which element has a variable oxidation state, can act as a catalyst and forms coloured compounds? A B C D carbon iron lead nitrogen

23 An atom of which element has the same electronic configuration as the strontium ion? A B C D calcium krypton rubidium selenium

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8 24 The boiling points of gaseous elements increase as the size of their atoms increases. Which of these noble gases has the highest boiling point? A B C D argon helium krypton neon

25 The sentence describes two metals and their oxides. Metal X could be copper because its oxide is 1 and metal Y could be 2 because its oxide is amphoteric. Which words correctly complete gaps 1 and 2? 1 A B C D acidic basic acidic basic 2 aluminium aluminium magnesium magnesium

26 Which gas could be used to convert copper(II) oxide to copper? A B C D carbon dioxide hydrogen nitrogen oxygen

27 Aluminium and copper are often used to make coins but iron is not. Which statement explains this? A B C D Iron is above both aluminium and copper in the reactivity series. Iron is more expensive to manufacture than aluminium or copper. Iron is rarer than both aluminium and copper. Iron reacts with water.

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9 28 In the electrolysis of molten aluminium oxide for the extraction of aluminium, the following three reactions take place. 1 2 3 Al 3+ + 3e Al 2O2 O2 + 4e C + O2 CO2

Which reactions take place at the positive electrode? A 1 only B 2 only C 1 and 3 only D 2 and 3 only

29 Which two substances are removed from the bottom of the blast furnace? 1 2 3 4 A 1 and 3 coke iron limestone slag B 1 and 4 C 2 and 3 D 2 and 4

30 An alloy of copper and zinc is added to an excess of dilute hydrochloric acid. The resulting mixture is then filtered. Which observations are correct? filtrate A B C D colourless solution colourless solution blue solution blue solution residue none red-brown grey none

31 Which aqueous reagent liberates ammonia from ammonium nitrate on warming? A B C D calcium nitrate potassium hydroxide sodium chloride sulfuric acid

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10 32 An aqueous solution of a compound X reacts with aqueous zinc chloride to form a white precipitate which dissolves when X is in excess, aluminium sulfate solution to form a white precipitate which is insoluble when X is in excess. What is the identity of X? A B C D ammonia barium chloride silver nitrate sodium hydroxide

33 CFC compounds were commonly used as aerosol propellants. The structure of one CFC compound is shown.
F F C F Cl C H H

Which element in this compound causes a depletion of ozone in the atmosphere? A B C D carbon chlorine fluorine hydrogen

34 Which gas is most likely to react with limestone? A B C D ammonia carbon monoxide methane sulfur dioxide

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11 35 The diagram shows the structure of an ester.


O CH3CH2CH2 C O CH2CH2CH3

What are the starting materials for making this compound? A B C D butanol and butanoic acid butanol and propanoic acid propanol and butanoic acid propanol and propanoic acid

36 Which information is correct regarding the formation of ethanol by the process of fermentation? substances fermented A B C D carbohydrates carbohydrates hydrocarbons hydrocarbons gas evolved during fermentation carbon dioxide carbon monoxide carbon dioxide carbon monoxide

37 Nylon, poly(ethene) and Terylene are macromolecules. In which of these macromolecules is the C=O group present in the linkage? A B C D nylon and Terylene only nylon only poly(ethene) and Terylene only Terylene only

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12 38 Which partial structure is correct for the product of polymerisation of butene, CH2=CHCH2CH3?
A CH2 C H CH3 H C H
n

B CH3 H C H C H H C H
n

C H C H H C H H C H H C H
n

D CH3 H C C
n

CH3 H

39 Glucose is a simple sugar. Glycine is an amino acid. In the diagram, which two arrows correctly show the hydrolysis products of a carbohydrate and of a protein?
a carbohydrate 2 3 a protein 4 glycine 1 glucose

1 and 3

1 and 4

2 and 3

2 and 4

40 When crude oil is distilled several products are obtained. What is the correct order of their boiling points? highest boiling point A B C D diesel lubricating oil paraffin (kerosene) petrol (gasoline) paraffin (kerosene) diesel petrol (gasoline) paraffin (kerosene) petrol (gasoline) paraffin (kerosene) lubricating oil diesel lowest boiling point lubricating oil petrol (gasoline) diesel lubricating oil

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University of Cambridge International Examinations is part of the Cambridge Assessment Group. Cambridge Assessment is the brand name of University of Cambridge Local Examinations Syndicate (UCLES), which is itself a department of the University of Cambridge.

Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every reasonable effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included, the publisher will be pleased to make amends at the earliest possible opportunity.

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DATA SHEET The Periodic Table of the Elements


Group III
1

I H
Hydrogen

II

IV

VI

VII

0
4

He
Helium

1 11 12 14 16 19

2 20

Li
Boron Carbon

Be
5 27 28 6 7

N
Nitrogen

O
Oxygen

F
Fluorine

Ne
Neon

Lithium

Beryllium

8 31 32

9 35.5

10 40

23

24

Na
Aluminium

Mg
13 51 52 55 56 59 59 64 65 70

Al
14

Si
Silicon

P
Phosphorus

S
Sulfur

Cl
Chlorine

Ar
Argon

Sodium

Magnesium

11

12

15 73 75

16 79

17 80

18 84

39

40

45

48

K
Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc

Ca
23 93 96 101 103 106 108 112 24 25 26 27 28 29 30

Sc

Ti

Cr

Mn

Fe

Co

Ni

Cu

Zn
31

Ga
Gallium

Ge
Germanium

As
Arsenic

Se
Selenium

Br
Bromine

Kr
Krypton

Potassium

Calcium

Scandium

Titanium

19

20

21

22

32 115 119

33 122

34 128

35 127

36 131

16

85

88

89

91

Rb
Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver

Sr
41 181 184 186 190 192 195 197 42 43 44 45 46 47

Zr

Nb

Mo

Tc

Ru

Rh

Pd

Ag
48

Cd
Cadmium

In
Indium

Sn
Tin

Sb
Antimony

Te
Tellurium

I
Iodine

Xe
Xenon

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49 201

Rubidium

Strontium

Yttrium

Zirconium

37

38

39

40

50 204 207

51 209

52

53

54

133

137

139

178

Cs
Tantalum Iridium Tungsten Rhenium Osmium Platinum

Ba
73 77 74 75 76 78

La Ta W Re Os Pt

Hf

Ir
79

Au
Gold

Hg
Mercury

Tl
Thallium

Pb
Lead

Bi
Bismuth

Po
Polonium

At
Astatine

Rn
Radon

Caesium

Barium

Lanthanum

Hafnium

55

56

57

72

80

81

82

83

84

85

86

226

227

Fr
140 141 144 150

Ra

Ac
152 157 159 162 165 167 169 173 175

Francium

Radium

Actinium

87

88

89

*58-71 Lanthanoid series 90-103 Actinoid series Ce


Cerium Praseodymium Neodymium Promethium

Pr
59 60 238 61

Nd

Pm
62

Sm
Samarium

Eu
Europium

Gd
Gadolinium

Tb
Terbium

Dy
Dysprosium

Ho
Holmium

Er
Erbium

Tm
Thulium

Yb
Ytterbium

Lu
Lutetium

58 232

63

64

65

66

67

68

69

70

71

a = relative atomic mass

Key Th
Thorium Protactinium Uranium

X Pa
91 92

X = atomic symbol
90

U
93

Np
Neptunium

Pu
Plutonium

Am
Americium

Cm
Curium

Bk
Berkelium

Cf
Californium

Es
Einsteinium

Fm
Fermium

Md
Mendelevium

No
Nobelium

Lr
Lawrencium

b = proton (atomic) number

94

95

96

97

98

99

100

101

102

103

The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.).

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