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MATERIAL SAFETY DATA SHEET

Product Trade Name:


Revision Date:

MICRO MATRIX CEMENT RETARDER


05-Jan-2009

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING


Statement of Hazardous Nature Manufacturer/Supplier Hazardous according to criteria of WorkSafe Halliburton Australia Pty. Ltd. 53-55 Bannister Road Canning Vale WA 6155 Australia ACN Number: 009 000 775 Telephone Number: 61 (08) 9455 8300 Fax Number: 61 (08) 9455 5300 Product Emergency Telephone Australia: 08-64244950 Papua New Guinea: 05 1 281 575 5000 NewZealand: 06-7559274 Fire, Police & Ambulance - Emergency Telephone Australia: 000 Papua New Guinea: 000 New Zealand: 111 Identification of Substances or Preparation Product Trade Name: Synonyms: Chemical Family: UN Number: Dangerous Goods Class: Subsidiary Risk: Hazchem Code: Poisons Schedule: Application: Prepared By MICRO MATRIX CEMENT RETARDER None Blend , UN3265 8 None 2X S5 Cement Retarder Chemical Compliance Telephone: 1-580-251-4335 e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS
SUBSTANCE Organophosphonic acid Phosphonic acid CAS Number 13598-36-2 PERCENT 10 - 30% 1 - 5% Australia NOHSC Not applicable Not applicable ACGIH TLV-TWA Not applicable Not applicable

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Total to 100%

3. HAZARDS IDENTIFICATION
Hazard Overview Hazard Ratings Flammability: Toxicity: Body Contact: Reactivity: Chronic: 0 0 3 0 0 May cause eye and skin burns. May be harmful if swallowed.

Scale: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4

4. FIRST AID MEASURES


Inhalation Skin If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops or if breathing becomes difficult. In case of contact, immediately flush skin with plenty of soap and water for at least 15 minutes. Get medical attention. Remove contaminated clothing and launder before reuse. In case of contact, or suspected contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention immediately after flushing. Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek medical attention. Never give anything by mouth to an unconscious person. Not Applicable

Eyes Ingestion Notes to Physician

5. FIRE FIGHTING MEASURES


Suitable Extinguishing Media Unsuitable Extinguishing Media Special Exposure Hazards Water fog, carbon dioxide, foam, dry chemical. None known. Decomposition in fire may produce toxic gases. Do not allow runoff to enter waterways.

Special Protective Equipment for Full protective clothing and approved self-contained breathing apparatus required for fire fighting personnel. Fire-Fighters

6. ACCIDENTAL RELEASE MEASURES


Personal Precautionary Measures Use appropriate protective equipment. Environmental Precautionary Measures Procedure for Cleaning / Absorption Prevent from entering sewers, waterways, or low areas. Isolate spill and stop leak where safe. Contain spill with sand or other inert materials. Scoop up and remove.

7. HANDLING AND STORAGE


Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after use. Launder contaminated clothing before reuse.
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Storage Information

Store away from alkalis. Store in a cool well ventilated area. Keep container closed when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION


Engineering Controls Respiratory Protection Hand Protection Skin Protection Eye Protection Other Precautions Use in a well ventilated area. Local exhaust ventilation should be used in areas without good cross ventilation. Organic vapor/acid gas respirator. Impervious rubber gloves. Rubber apron. Chemical goggles; also wear a face shield if splashing hazard exists. Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES


Physical State: Color: Odor: pH: Specific Gravity @ 20 C (Water=1): Density @ 20 C (kg/l): Bulk Density @ 20 C (kg/m3): Boiling Point/Range (C): Freezing Point/Range (C): Pour Point/Range (C): Flash Point/Range (C): Flash Point Method: Autoignition Temperature (C): Flammability Limits in Air - Lower (g/m3): Flammability Limits in Air - Lower (%): Flammability Limits in Air - Upper (g/m3): Flammability Limits in Air - Upper (%): Vapor Pressure @ 20 C (mmHg): Vapor Density (Air=1): Percent Volatiles: Evaporation Rate (Butyl Acetate=1): Solubility in Water (g/100ml): Solubility in Solvents (g/100ml): VOCs (g/l): Viscosity, Dynamic @ 20 C (centipoise): Viscosity, Kinematic @ 20 C (centistrokes): Partition Coefficient/n-Octanol/Water: Molecular Weight (g/mole): Decomposition Temperature (C): Liquid Clear light yellow Mild aromatic 2 1.15 1.15 Not Determined Not Determined -9 Not Determined Not DeterminedMin: > 100 PMCC Not Determined Not Determined Not Determined Not Determined Not Determined Not Determined Not Determined 71 Not Determined Miscible Not Determined Not Determined Not Determined Not Determined Not Determined > 600 Not Determined

10. STABILITY AND REACTIVITY


Stability Data: Hazardous Polymerization: Conditions to Avoid Incompatibility (Materials to Avoid) Stable Will Not Occur None anticipated Strong alkalis.
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Hazardous Decomposition Products Additional Guidelines

Oxides of nitrogen. Phosphines. Chlorine. Carbon monoxide and carbon dioxide. Not Applicable

11. TOXICOLOGICAL INFORMATION


Principle Route of Exposure Inhalation Skin Contact Eye Contact Ingestion Aggravated Medical Conditions Eye or skin contact, inhalation. Causes severe respiratory irritation. May cause skin burns. Causes severe eye irritation May cause eye burns. Causes burns of the mouth, throat and stomach. Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are chronic health hazards. Other Information Toxicity Tests Oral Toxicity: Dermal Toxicity: Inhalation Toxicity: Primary Irritation Effect: Carcinogenicity Genotoxicity: Reproductive / Developmental Toxicity: LD50: 2910 mg/kg (Rat) LD50: 6310 mg/kg (Rabbit) Not determined Draize Rating (Eye): 43.6/110 (Rabbit) Moderate Draize Rating (Skin): 3.3/8.0 (Rabbit) Moderate Not determined Not determined Not determined None known.

12. ECOLOGICAL INFORMATION


Mobility (Water/Soil/Air) Persistence/Degradability Bio-accumulation Not determined Slowly biodegradable Not Determined

Ecotoxicological Information
TLM96: > 330 mg/l (Oncorhynchus mykiss) TLM96: > 330 mg/l (Lepomis macrochirus) TLM96: 8132 mg/l (Cyprinodon variegatus) Acute Crustaceans Toxicity: Not determined Not determined Acute Algae Toxicity: Acute Fish Toxicity: Chemical Fate Information Other Information Not determined Not applicable
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13. DISPOSAL CONSIDERATIONS


Disposal Method Contaminated Packaging Disposal should be made in accordance with federal, state, and local regulations. Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION Land Transportation


ADR UN3265,Corrosive Liquid, Acidic, Organic, N.O.S.(Contains Phosphonic Acid), 8, III

Air Transportation
ICAO/IATA UN3265,Corrosive Liquid, Acidic, Organic, N.O.S., 8, III (Contains Phosphonic Acid Solution)

Sea Transportation
IMDG UN3265,Corrosive Liquid, Acidic, Organic, N.O.S.(Contains Phosphonic Acid), 8, III EmS F-A, S-B

Other Shipping Information


EPG: IERG: Labels: 8A1 37 Corrosive

15. REGULATORY INFORMATION


Chemical Inventories Australian AICS Inventory US TSCA Inventory EINECS Inventory Classification Risk Phrases R36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases S2 Keep out of reach of children. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. Not Determined All components listed on inventory or are exempt. This product, and all its components, complies with EINECS Xi - Irritant.

16. OTHER INFORMATION


The following sections have been revised since the last issue of this MSDS Not applicable

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Contact
Australian Poisons Information Centre 24 Hour Service: - 13 11 26 Police or Fire Brigade: - 000 (exchange): New Zealand Poisons Information System Deunedin: -(03) 479 1200 (Normal Hours) -(03) 474 0999 (Emergency) Additional Information For additional information on the use of this product, contact your local Halliburton representative. For questions about the Material Safety Data Sheet for this or other Halliburton products, contact Chemical Compliance at 1-580-251-4335.

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Disclaimer Statement

This information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtained from various sources including the manufacturer and other third party sources. The information may not be valid under all conditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of any material is the sole responsibility of the user. ***END OF MSDS***

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