Chemistry 161 Exam I October 3, 2012

Student Name (Print): ____________________ Recitation Section Number:

!!

Recitation Instructor: __________________

The exam booklet has 25 questions for credit and one additional question to check the color of your exam booklet. Please answer all 26 questions on the OpScan sheet. There is no penalty for guessing. If you do not find the exact answer, bubble in the best choice. A proctor will check your picture ID, OpScan form, signature and calculator during the exam. The use of calculators with permanent memories (graphing calculators), cell phones, pagers, PDAs or other electronic devices other than a basic scientific calculator is expressly forbidden. The last page of the booklet contains a periodic table along with other useful data. The use of any other notes or information on this test or taking extra time to bubble in your answers will be considered a violation of the Academic Honesty provisions of the student code. Exam scores will be posted as soon as possible. On the Opscan Form: (Use a #2 pencil or darker) 1. Sign your name across the top of the form. 2. Code the following information (blacken circles) Your Name (Last Name First) Your Ru ID Number [Start under Box A and continue to Box I] Your Recitation Section Number in K & L [For sections 01-09, bubble 0 under box K] Your Exam Form Number under box P Section Numbers and Initials of instructors are listed on the next page BL = B. Langowski, DS = D. Siegel, GG = G. Govindarajoo, HS = H. Sangari RP = R. Porcja, NS = N. Shankar, RA = R. Agarwal PK = P. Kimmel ET = E.Tavss YS = Y. Shin, HZ = H. Zhang, KS = K. Sethi, EH = E. Hove, NM = N. Marky Periods: 1: 8:55- 9:50 (Busch/Liv) 3: 12:15-1:10 (Busch/Liv) 4: 1:55-1:50 5: 3:35-4:30 9:30-10:25 (Douglass/Cook), 12:50-1:45 (Cook/Douglass) 6: 5:15-6:10 8: 8:25 PM to 9:20 PM

2: 10:35-11:30 (Busch/Liv) 11:10-12:05 (Cook/Douglass)

3. In the Birthdate section bubble 1112

Your EXAM FORM is 1

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Per. M3 M5 M5 W3 W5 W5 F3 F5 F5

Instr ET PK GG RA DS RA HS HS NS

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Per. M1 M3 M3 W1 W1 W3 Th1 Th1 Th3 Th3 Th3 M6 M6 M6 W6 W6 M8 M8

Instr NS GG NS KS HZ GG KS NS KS NS HS PK RP BL RP BL BL YS

Sec 37 40 41 50 51 52 53 54 55 56 57 58

Per. M8 M2 W2 M1 M4 W1 W1 Th1 F2 M2 W2 T3

Instr RP EH KS ET ET RA HS HS HS NM PK PK

Please bubble 99 12 13 14 15 16 17 18 M2 W2 W2 Th2 M2 W2 M1 DS HZ DS KS NS NM EH

Your EXAM FORM is 1

1 Which of the following answers represents the result of the calculation shown below rounded to the correct number of significant digits? Note: None of the numbers is exact. (95.6 x 2.7654) (13.523 - 12.98) A. 5 x 102 B. 4.9 x 102 C. 4.87 x 102 D. 4.869 x 102 E. 4.8687 x 102 2 How many protons, neutrons and electrons are in 130Te2 ? A. B. C. D. E. Protons 50 52 52 50 52 Neutrons 78 54 78 52 80 Electrons 52 78 54 78 52

! 3 In the n = 4 principal shell, what is the maximum number of electrons that could have ms = +! ? A. 1 B. 4 C. 8 D. 16 E. 32 4 How many calcium atoms can be contained in a calcium sphere with a radius of 2.00 cm? g 4! r 3 Volume of a sphere = . Density of calcium = 1.55 3 cm 3 A. 5.03 x 1023 B. 1.95 x 1023 C. 3.13 x 1025 D. 3.90 x 1023 E. 7.80 x 1023 !

The density of a certain metal is measured using the following data. Mass of graduated cylinder +water Volume of water 35.28 g 4.20 mL

The metal bar is then placed in the cylinder, displacing some of the water. Mass of graduated cylinder + metal bar + water Volume of water + metal bar Calculate the density of the metal based on this data. A. 6.70 B. 7.67 C. 8.40 D. 11.3 E. 4.52 ! 6
g mL g mL g mL g mL g mL

56.39 g 7.35 mL

A hypothetical element Q (atomic mass: 197.52 u) consists of two stable isotopes: isotope A (isotopic mass: 196.00 u) and isotope B (isotopic mass: 198.14 u). What is the percent abundance of isotope B?

A. 99.8% B. 71.0% C. 25.6 % D. 45.9 % E. 58.3 % ! 7 If 0.579 moles of photons of a light strike a material and the material absorbs a total of 73.9 kJ, what is the wavelength of the light? A. 516 nm B. 852 nm C. 937 nm D. 367 nm E. 671 nm !

8 Which of the following are exact numbers? V. There are 7 days in a week W. The mass of the cube of magnesium is 75.98 g X. 276 tickets are available for the concert Y. 1 cm is equal to 10 mm Z. 150 mL of water was added to the lemon juice concentrate A. V and Y B. X, Y and Z C. V, X and Y D. V, W, X, Y and Z E. V, Y and Z ! 9 What is the frequency of light emitted when an electron jumps from state n = 3 to the ground state in a hydrogen atom? A. 3.29 x 1015 s1 B. 3.65 x 1014 s1 C. 2.92 x 1015 s1 D. 1.51 x 1015 s1 E. 5.72 x 1015 s1 ! 10 Which of the following examples of matter has the incorrect classification? A. Sugar: Compound B. Tin: Element C. Chicken noodle soup: Heterogeneous mixture D. Carbon dioxide gas: Homogeneous mixture E. Pure distilled water: Compound !

11 Three individuals each made 4 measurements of the length of a steel rod. The actual length of the rod is 7.54 m. The results of the measurements are shown below: Individual Length (m) X 7.24, 7.89, 7.60, 7.22 Y 7.31, 7.32, 7.30, 7.32 Z 7.52, 7.56, 7.58, 7.49 Which of the following statements represents the results shown above? A. Y was most accurate and Z is the most precise B. X and Z were both equally accurate and precise C. X was most accurate and Y was most precise D. Z was the most accurate and X was most precise E. Z was the most accurate and Y is the most precise ! 12 Select physical change(s) from the following. I. Solid iodine subliming into gas at room temperature II. Burning of leaves III. Tarnishing of silver IV. Metal sodium forming hydrogen gas when in contact with water A. I only B. none of the above C. II, III and IV D. I and III E. I and II ! 13 A certain metal has a threshold frequency of 1.87 x 1014 s-1. What is the wavelength of light that would eject an electron with kinetic energy of 2.54 x 10-19 J when the light strikes an emitter with this metal coating? A. 526 nm B. 782 nm C. 1610 nm D. 1530 nm E. 976 nm !

14 A certain element has successive ionization energies I1, I2, I3, I4, I5 with values, respectively: 1086
kJ , mol

2353

kJ , mol

4621

kJ , mol

6223

kJ , mol

37831

kJ mol

This element is in what group of the periodic table? A. 1A B. 2A C. 3A D. 4A E. 5A ! 15 For selenium: 1st and 2nd ionization energies = 941 Electron affinity = 195
kJ mol kJ kJ and 2044 respectively mol mol

Which of the following statements are correct? X. 2985 kJ/mol is absorbed when 2 electrons are removed from Se(g) Y. 941 kJ/mol is released when one electron is removed from Se(g) Z. 195 kJ/mol is released when one electron is added to Se(g) A. X only B. Y only C. Z only D. X and Z only E. X, Y and Z ! 16 Which of the following ions represented by Lewis dot symbols possess a charge of -2?

A. II and III B. III and IV C. II and V D. I and III E. III, IV and V !

17

Select the atom/ion that has the incorrect configuration listed next to it. A. P: [Ne]3s23p3 B. Ag: [Kr]5s14d10 C. Sr2+: [Kr] D. Ti2+: [Ar]4s2 E. Y: [Kr] 5s24d1 !

18 Which of the following is the answer for the following conversion? 1.0 km3 = ______________ cm3 A. 1.0 x 103 B. 1.0 x 105 C. 1.0 x 108 D. 1.0 x 1010 E. 1.0 x 1015 ! 19 Which of the following pairs is isoelectronic? A. Li+ and K+ B. Na+ and Ne C. I and Cl D. S2- and Ne E. Al3+ and B3+ ! 20 Which one of the following sets of quantum numbers represents an electron in a 4d orbital?
! !

A. B. C. D. E.

n 4 4 4 4 4

l 1 2 3 0 2

ml !1 !3 !2 0 0

ms +! !! +! +! !!

! 21 Which of the following atoms has the ground state electron configuration with the most unpaired electrons? A. P B. Cl C. Cr D. Co E. Ni !

22 Rank the following according to increasing lattice energy. (Lowest first, highest last) MgO, CaCl2, KBr, KCl, MgCl2 A. MgO < CaCl2 < MgCl2 < KBr < KCl B. KBr < KCl < CaCl2 < MgCl2 < MgO C. KBr< CaCl2 < KCl < MgO < MgCl2 D. KCl < MgCl2 < KBr < CaCl2 < MgO E. MgO < MgCl2 < KBr < KCl < CaCl2 ! 23 In each of the following pairs, select the species with the smaller radius. W: X: Y: Z: W K+ Cl K+ K+ Cl ! 24 What is the de Broglie wavelength for a neutron traveling at 700. Mass of neutron: 1.675 x 10-27 kg A. B. C. D. E. 266 nm 37.4 nm 0.377 nm 1.77 nm 0.565 nm
m ? s
! !

K+ Br Ca S

Cl

Br Mg2+ F
!

A. B. C. D. E.

X Br Br Br Br Br
!

Y Z 2+ Mg F Mg2+ F Ca S Mg2+ F Ca S

25 A sheet of copper has a total area of 24.5 inch2 and a mass of 4.57 g. g Density of copper is 8.96 . 2.54 cm = 1 inch (exact conversion) cm 3 What is the thickness of the sheet? A. 6.97 x 103 cm B. 1.27 x 103 cm C. 8.19 x 103 cm D. 3.23 x 103 cm E. 2.89 x 102 cm ! 26 What is the color of your exam? A. B. C. D. White Blue Yellow Pink