45 minutes
Additional Materials: Multiple Choice Answer Sheet Soft clean eraser Soft pencil (type B or HB is recommended)
0620/01
w w w e tr .X m ap eP s er om .c
READ THESE INSTRUCTIONS FIRST Write in soft pencil. Do not use staples, paper clips, highlighters, glue or correction fluid. Write your name, Centre number and candidate number on the answer sheet in the spaces provided unless this has been done for you. There are forty questions on this paper. Answer all questions. For each question there are four possible answers A, B, C, and D. Choose the one you consider correct and record your choice in soft pencil on the separate answer sheet. Read the instructions on the answer sheet very carefully. Each correct answer will score one mark. A mark will not be deducted for a wrong answer. Any rough working should be done in this booklet. A copy of the Periodic Table is printed on page 16. You may use a calculator.
[Turn over
2 1 Some students are asked to describe differences between gases and liquids. Three of their suggestions are: 1 2 3 gas molecules are further apart; gas molecules are smaller; liquid molecules vibrate around fixed positions.
A coloured liquid vaporises easily at room temperature. Some of the liquid is placed at the bottom of a sealed gas jar. Which diagram shows the appearance of the jar after several hours?
A B C coloured vapour coloured vapour coloured liquid coloured vapour D
Measurements are made on some pure water. its boiling point, b.p. its freezing point, f.p. its pH Sodium chloride is now dissolved in the water and the measurements repeated. Which measured values change? b.p. A B C D f.p. pH
UCLES 2004
0620/01/M/J/04
Which properties does a Group VI element have? forms covalent bonds A B C D forms ionic bonds conducts electricity when solid
UCLES 2004
0620/01/M/J/04
[Turn over
Which diagram shows the electronic structure of another element in the same group in the Periodic Table?
A e e e e e e e e e e e B e e e e e e e e
C e e e e e e
D e e e e e e e e
In the diagrams, circles of different sizes represent atoms of different elements. Which diagram can represent hydrogen chloride gas?
A B C D
UCLES 2004
0620/01/M/J/04
5 8 How many electrons are shared between the atoms in a molecule of methane, CH4, and in a molecule of water, H2O? methane A B C D 9 4 4 8 8 water 2 4 2 4
The oxide Pb3O4 reacts with dilute nitric acid to form lead(II) nitrate, lead(IV) oxide and another product. What is the equation for this reaction? A B C D Pb3O4 Pb3O4 Pb3O4 + 4HNO3 2Pb(NO3)2 + PbO2 + 2HNO3 2PbNO3 + 4HNO3 Pb(NO3)4 + PbO4 + 2PbO + 2H2O + H2 + 2H2O
+ 2PbO2 + H2
10 The compound ethyl mercaptan, C2H5SH, has a very unpleasant smell. What is its relative molecular mass? A 34 B 50 C 61 D 62
11 The proton number of helium is 2. What information does this give about helium? A B C D Its atom has two electrons. Its atom is twice as heavy as a hydrogen atom. It is a Group II element. Its molecule has two atoms.
UCLES 2004
0620/01/M/J/04
[Turn over
Which change would cause the bulb to light? A B C D add more solid copper(II) sulphate to the beaker add water to dissolve the copper(II) sulphate replace the carbon electrodes with copper electrodes reverse the connections to the electrodes
13 The following electrolysis circuit is set up, using inert electrodes P, Q, R and S.
At which of the electrodes is a Group VII element produced? A P only B P and R C Q only D Q and S
14 When it is used as a fuel, hydrogen combines with substance X. What is X? A B C D carbon methane nitrogen oxygen
UCLES 2004
0620/01/M/J/04
7 15 The table compares the strengths of the bonds for reactions of the type below. X2 + Y2 2XY Which reaction is most exothermic? bonds in X2 A B C D strong strong weak weak bonds in Y2 strong strong weak weak bonds in XY strong weak strong weak
16 In an experiment, copper(II) oxide is changed to copper by a gas X. What happens to the copper(II) oxide and what is X? copper(II) oxide A B C D oxidised oxidised reduced reduced gas X carbon dioxide carbon monoxide carbon dioxide carbon monoxide
17 In an experiment, a 2 g lump of zinc and 2 g of powdered zinc are added separately to equal volumes of dilute sulphuric acid. The solid line on the graph shows the volume of gas given off when the 2 g lump is used. Which dotted line is obtained when the zinc is powdered?
A B volume of gas C D
time
UCLES 2004
0620/01/M/J/04
[Turn over
8 18 Which process is endothermic? A B C D adding water to anhydrous copper(II) sulphate burning magnesium to make the oxide heating water to make steam neutralising acidic industrial waste
19 An aqueous solution contains either aluminium sulphate or zinc sulphate. Which aqueous reagent can be used to confirm which salt is present? A B C D ammonia barium chloride sodium hydroxide sulphuric acid
20 Compound X does not dissolve in water, does not react with water, is used to control soil acidity.
21 Aqueous sodium hydroxide is added to two different solutions with the results shown.
X green precipitate formed Y light blue precipitate formed
ee
Which atoms are metals? A 1 and 2 only B 1 and 3 only C 2 and 3 only D 1, 2 and 3
23 Which property do all metals have? A B C D They are hard. They conduct electricity. They form acidic oxides. They react with water.
Why is argon used instead of air in the light bulb? A B C D Argon is a good conductor of electricity. Argon is more reactive than air. The filament glows more brightly. The filament lasts for a longer time.
UCLES 2004
0620/01/M/J/04
[Turn over
10 25 Which element is likely to be a transition metal? melting point in oC A B C D 98 328 651 1240 density in g / cm3 1.0 11.3 1.7 7.4 colour of oxide white yellow white black
26 Three metals are extracted as shown in the table. metal X Y Z method of extraction electrolyse molten metal oxide heat metal oxide with carbon occurs naturally as the metal
What is the order of reactivity of the metals? most reactive A B C D X X Y Z Y Z Z X least reactive Z Y X Y
27 Haematite is reduced to iron in the blast furnace. haematite + carbon monoxide iron + X What is X? A B C D carbon carbon dioxide hydrogen oxygen
28 Which object is least likely to contain aluminium? A B C D a bicycle frame a hammer a saucepan an aeroplane body
0620/01/M/J/04
UCLES 2004
11 29 A sample of clean, dry air is passed over hot copper until all the oxygen in the air reacts with the copper.
clean dry air copper
heat
The volume of air decreases by 30 cm3. What was the starting volume of the sample of air? A 60 cm3 B 100 cm3 C 150 cm3 D 300 cm3
30 The pH of some aqueous sodium hydroxide is measured. The solution is then distilled as shown.
thermometer
flask NaOH(aq)
heat
distillate collected
How do the pH values of the distillate and of the solution left in the flask compare with the original? pH of the distillate A B C D pH of the solution left in the flask higher lower higher lower
UCLES 2004
0620/01/M/J/04
[Turn over
12 31 Which two gases produced from the burning of petrol in motor vehicles contribute to the formation of acid rain? A B C D carbon dioxide and carbon monoxide carbon monoxide and sulphur dioxide carbon monoxide and nitrogen dioxide nitrogen dioxide and sulphur dioxide
32 An old railway carriage is being restored. Metal strips are secured on to the outside of the wooden carriage by means of screws. After a few weeks open to the wind and rain, the screws are heavily corroded but the metal strips are not.
metal strip metal screw
wood
Aluminium is more reactive than both steel and copper. Which two metals would give this result? screws A B C D aluminium copper copper steel strips steel aluminium steel aluminium
oxygen, O2
UCLES 2004
before treatment
after treatment
NH4Cl(aq)
(NH4)2SO4(aq)
NaNO3(aq)
Na2SO4(aq)
UCLES 2004
0620/01/M/J/04
[Turn over
WINE
a candle burning
a dog panting
fermenting grapes
Which gas do they all produce? A B C D carbon dioxide hydrogen methane oxygen
36 What is formed when calcium carbonate is heated? A B C D calcium and carbon calcium and carbon dioxide calcium oxide and carbon calcium oxide and carbon dioxide
UCLES 2004
0620/01/M/J/04
15 38 Four fractions obtained from crude oil (petroleum) are listed below. Which fraction is paired with a correct use? fraction A B C D bitumen diesel lubricating paraffin use making waxes fuel for aircraft making roads fuel for oil stoves
Why do these substances all belong to the same homologous series? A B C D They all contain an even number of carbon atoms. They all contain the same functional group. They are all hydrocarbons. They are all saturated.
40 The table shows some suggested reactions involving ethanol. Which suggestions about the reactants and products are correct? reaction A B C D reactants ethanol and oxygen ethene and steam glucose and oxygen glucose and water products carbon dioxide and water ethanol and hydrogen ethanol and carbon dioxide ethanol and oxygen
UCLES 2004
0620/01/M/J/04
I H
Hydrogen
II
IV
VI
VII
0
4
He
Helium
1 11 12 14 16 19
2 20
Li
Boron Carbon
Be
5 27 28 6 7 31
N
Nitrogen
O
Oxygen
F
Fluorine
Ne
Neon
Lithium
Beryllium
8 32
9 35.5
10 40
23
24
Na
Aluminium
Mg
13 51 52 55 56 59 59 64 65 70 14 73
Al Si
P
Phosphorus
S
Sulphur
Cl
Silicon Chlorine
Ar
Argon
Sodium
Magnesium
11
12
15 75
16 79
17 80
18 84
39
40
45
48
K
Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc
Ca
24 93 96 101 103 106 108 112 25 26 27 28 29 30 31
Sc
Ti
Cr
Mn
Fe
Co
Ni
Cu
Zn
Ga
Gallium
Ge
Germanium
As
Arsenic
Se
Selenium
Br
Bromine
Kr
Krypton
Potassium
Calcium
Scandium
Titanium
19
20
21
22
23
32 115 119
33 122
34 128
35 127
36 131
16
85
88
89
91
University of Cambridge International Examinations is part of the University of Cambridge Local Examinations Syndicate (UCLES) which is itself a department of the University of Cambridge.
0620/01/M/J/04
Rb
Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver
Sr
42 181 184 186 190 192 195 197 43 44 45 46 47 48
Zr
Nb
Mo
Tc
Ru
Rh
Pd
Ag
Cd
Cadmium
In
Indium
Sn
Tin
Sb
Antimony
Te
Tellurium
I
Iodine
Xe
Xenon
Rubidium
Strontium
Yttrium
Zirconium
37
38
39
40
41
49 201 204
50 207
51 209
52
53
54
133
137
139
178
Cs
Tantalum Iridium Tungsten Rhenium Osmium Platinum
Ba
74 77 75 76 78 79
La Ta W Re Os Pt
Hf
Ir
Au
Gold
Hg
Mercury
Tl
Thallium
Pb
Lead
Bi
Bismuth
Po
Polonium
At
Astatine
Rn
Radon
Caesium
Barium
Lanthanum
Hafnium
55
56
57
72
73
80
81
82
83
84
85
86
226
227
Fr
140 141 144 150
Ra
Ac
152 157 159 162 165 167 169 173 175
Francium
Radium
Actinium
87
88
89
Pr
59 60 238 61
Nd
Pm
62
Sm
Samarium
Eu
Europium
Gd
Gadolinium
Tb
Terbium
Dy
Dysprosium
Ho
Holmium
Er
Erbium
Tm
Thulium
Yb
Ytterbium
Lu
Lutetium
58 232
63
64
65
66
67
68
69
70
71
Key Th
Thorium Protactinium Uranium
X Pa
91 92
X = atomic symbol
90
U
93
Np
Neptunium
Pu
Plutonium
Am
Americium
Cm
Curium
Bk
Berkelium
Cf
Californium
Es
Einsteinium
Fm
Fermium
Md
Mendelevium
No
Nobelium
Lr
Lawrencium
94
95
96
97
98
99
100
101
102
103
The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.).