www.bannerbatteries.

com
BETTER SAFE THAN SORRY!
LEAD BATTERY KNOW-HOW
AND ACCIDENT PREVENTION.
ALL Banner STARTER BATTERIES ARE DECLARED
AS ACID-FILLED WET BATTERIES (UN 2794).



This leaflet was prepared by the Working Group on Environment and Occupational Health of the
ZVEI German Electrical and Electronic Manufacturers Association

CAS-No. Descri pti on Content R-phrases
7439-92-1 blue lead
7439-92-1 lead alloys with
traces of As,Sb
34Weight%
lead-containing
Battery paste
31Weight % R61-20/22-33-
62-52/53
7664-93-9 sulphuric acid 34Weight% R35

ZVEI information leaflet No. 1e
EditionSeptember 2012
Instructions for the safe handling of
lead-acid accumulators (lead-acid batteries)

The REACH-regulation (1907
/2006/EC) has replaced the
directive on safety data sheets
(91/155/EC). REACH
describes the setting up and
updating of safety data sheets
for substances and
preparations. For articles
like lead-acid batteries safety
data sheets are not required.

This leaflet addresses
manufacturers of batteries
and is meant to apply
voluntarily.

The notes are meant to help
to comply with legal require-
ments but do not replace
them.



1. Substances / formulation
and company name

Data on the product
Trade name

Lead-acid battery
filled with
diluted sulphuric acid

Data on the manufacturer:


Telephone:
Facsimile:

2. Hazardous substances

3. Potential hazards

No hazards in case of an intact
battery and observation of the
instructions for use.

Lead-acid batteries have
significant characteristics:

- They contain diluted
sulphuric acid, which may
cause servere acid burns.

- During the Charging process
they develop hydrogen gas
and oxygen, which unter
certain circumstances may
turn into an explosive
mixture.





- They have an internal
voltage, which depending
on their level can be
dangerous to the human
body when touched.

- Standard EN 50272-2
includes safety requirements
for batteries and battery
installations and describes
the basic precautions to
protect against dangers
deriving from electric
currents, leaking gases or
electrolytes.



2/5

Batteries are marked with the following hazard symbols:

The meaning of the hazard symbols is:



No smoking, no open flames, no sparks.

Wear safety goggles.
Sulphuric acid.

Observe operating instructions.

Explosive gas mixture.














4. First-aid measures

5. Fire-fighting measures



6. Measures to be taken in
case of unintentional
release

Cleaning / take-up procedures

Use a bonding agent, such as
sand, to absorb split acid;

Use lime / sodium carbonate for
neutralisation; dispose with due
regard to the official local
regulations, do not permit
penetration into the sewage
system, the earth or water
bodies.

















7. Handling and storage

Store frost-free under roof;
prevent short circuits.

Protect plastic housings against
exposition to direct sun
radiation.

Seek agreement with local water
authorities in case of larger
quantities.

If batteries have to be stored in
storage rooms, it is imperative
that the instructions for use are
observed.




General Information:
Sulphuric acid acts corrosive and damages
tissue
after contact with skin rinse with water, remove and wash
wetted clothing
after inhalation of acid inhale fresh air
mist*)
after contact with the rinse under running water for
eyes*) serveral minutes
after swallowing*) drink a lot of water immediately,
and swallow activated carbon
Lead-containing classified as toxic for reproduction
battery paste
after contact with skin clean with water and soap

*) seek the advice of a doctor.

Suitable extinguishing agents
When electrical devices are set in fire in general water is the suitable extinguishing
agent. For incipient fires CO
2
is the most effective agent. Fire brigades are trained
to keep a distance of 1 m when extinguishing an electrical fire (up to 1 kV) with
spray jet and a distance of 5 m with full jet. For electrical fires in electrical
installations with voltages >1 kV other distances are applicable depending on the
respective voltage. Forfires in photovoltaicinstallationsotherrulesapply.
Unsuitable extinguishing agents
Powder fire extinguishers are not suitable, amongst others because of only minor
efficiency, possible risks or collateral damages.
Special protective equipment
For larger stationary battery installations orlarger stored quantities: protective
goggles, respiratory and acid protective equipment, acid-proof clothing.

3/5


8. Exposure limits and
personal protecti ve
equipments



9. Physical and chemical
properties

Lead
Appearance:
form: solid
colour: grey
odour: odourless

Safety-related data
Solidification point: 327 C
Boiling point: 1740 C
Solubility in water (25 C):
low (0,15 mg/l)
density(20C): 11,35 g/cm
vapour pressure (20 C)

Sulphuric acid (30 38,5 %)
form: liquid
colour: colourless
odour: odourless

Solidification point:
35 bis 60C
Boiling point: ca. 108 114 C
Solubility in water (25 C):
complete
density (20 C): 1,2 1,3 g/cm
vapour pressure (20 C)







10. Stability and reacti vity of
sulphuric acid
(30 to 38,5%)

Corrosive, inflammable
liquid.
Thermal decomposition at
338 C.
Destroys organic materials
such as cardboard, wood,
textiles.
Reacts with metals
producing hydrogen.
Vigorous reactions with lyes
and alkalis.




11. Data on toxicology of the
constituents

Sulphuric acid
acts intensely corrosive on skin
and mucous membranes. The
inhalations of mists may cause
damage to the respiratory tract.

Lead and lead-containing
battery paste
may cause damage to the blood,
nerves, and kidneys when taken
in. Lead-containing battery paste
is classified as toxic for
reproduction.

12. Data on the ecology of the
constituents

Preliminary remark:
Relevant only if release is
caused by destruction of the
battery

Sulphuric acid
Water-polluting liquid within the
meaning of the German Water-
Resources Act (WHG) Water
pollution class: 1 (mildly water
polluting).
As described in section 6 use a
bonding agent, such as sand, to
absorb spilled acid or neutralise
using lime / sodium carbonate.
Dispose of under the locally
applicable provisions.
Dispose with due regard to
official local regulations,
Do not allowprogression into the
sewage system, soil or bodies of
water.

Lead and lead-containing
battery paste
arehardly soluble in water.
Lead can be dissolved in an
acidic or alkaline environment.
Chemical and physical treatment
is required for elimination from
water. Waste water containing
lead must not be disposed of in
untreated condition.

8.1No exposure caused by lead and lead-containing battery
paste.
8.2Possible exposure caused by sulphuric acid and acid mist
during filling and charging.
CAS-Nr. 7664-93-9
R-phrases R35 Causes severe burns.
S-phrases S 1/2 Keep looked up and out of
reach of children.
S 26 In case of contact with eyes
rinse immediately with plenty
water and seek medical
advice.
S 30 Never add water to this
product (applies for
concentrated acid only

S 45 In case of accident or if you
feel unwell seek medical
advice immediately (show the
label where possible)
Threshold value on workplace 0,1 mg/m
3
*)
Hazard symbol C, corrosive

Personal protective equipment: Rubber, PVC gloves, acid-
proof goggles, acid-proof clothing, safety boots.
3)
0,5 mg/m3 at the lead battery production.


13. Recyc

The points
manufactu
batteries,
dealers ta
batteries,
secondary
processing

Spent lead
subject to
German W
Ordinance
with the re
and with a
container
"Marking")

Spent lead
allowed to
batteries i
complianc

By no mea
electrolyte
acid, be e
manner. T
carried ou
companies

14. Trans

14.1 Batte
filled

Land tran
to ADR/R
Special
transpo
goods (
are not s
requirem
they me
accordin
598)
If the re
Provisio
the trans
batteries
as dang
follows:
Hazardc
UN-no.:
Naming
BATTER
WITH A
Packing
Hazard







cling informat
s of sale, the
urers and impo
respectively th
ke back dead
and render th
y lead smelter
g.
d-acid batterie
accountability
Waste Prove
e. They are ma
ecycling / retur
a crossed-out
(cf. chapter 15
).
d-acid batterie
o be mixed wit
n order not to
ce the process
ans may the
e, the diluted s
mptied in an i
This process is
ut by the proce
s.
port instructi
eries, wet,
dwithacid
nsportation ac
RID
Provision 598
ort as danger
(new +spent b
subject to othe
ments of ADR/
eet the require
ng to Special P
quirements of
on 598 are not
sport of new a
s has to be de
gerous goods

class: 8
2794
and descripti
RIES, WET, F
ACID
ggroup: none
label: 8
tion
orters of
he metal
em to the
rs for
es are not
y of the
arked
rn symbol
roller
5
es are not
h other
sing.
sulphuric
nexpert
s to be
essing
ions
ccording
8: no
rous
batteries
er
/RID if
ements
Provision
f Special
t fulfilled
and spent
eclared
s as
on:
FILLED

S
to

A
to

1
L
to

1
In
la
ADR Tunnel
E
Sea transport
o IMDG Code
Hazardclass
UN-no.: 2794
Proper shipp
BATTERIES
WITH ACID
Packaginggr
EmS: F-A, S
Packaging In
Hazard label
Air transporta
o IATA-DGR
Class: 8
UN-no.: 2794
Proper shipp
BATTERIES
WITH ACID
Hazardclass
Packaging In
4.3 Batteries
Land transpor
o ADR/RID
Hazardclass
UN-no.: 2794
Proper shipp
BATTERIES
WITH ACID
Packinggrou
Packing Inst
transport as
goods (pack
boxes)
or Special Pr
transport as
goods (in bu
Hazardlabel:
ADR Tunnel
E
Note: these r
applied by tra
Lead-acid ba
2800 aswell.
5. Marking
n accordance
aw governing
restriction cod
ation accord
e
: 8
4
ping name:
, WET, FILLE
roup: none
-B
nstruction: P 8
l: 8
ation accordin
4
ping name:
, WET, FILLE
: 8
nstruction: 870
, damaged:
rtation accord
: 8
4
ping name:
, WET, FILLE
p: none
ruction P 801
s dangerous
king in accu
rovision VV 14
s dangerous
ulk)
: 8
restriction cod
references ca
ansportation o
atteries of UN-

with the Germ
the sale, retur

de:
ing
ED
801
ng
ED
0
ding
ED
a:
4:
de:
n be
of
-no.
man
rn
and en
dispos
secon
Batter
J une 2
transp
2006/6
lead-a
marke
wheel
symbo
below


In add
recycl


The m
the im
be res
attach
additio
inform
of the
attach
the Ge
quoted
volunt
batter
with th
Minist
Septe

The m
the ba
identif
(packa
instruc
respon


16. Ot

The d
based
and do
assura
Existin
have t
recipie
respon

nvironmentally
sal of batteries
ndary cells (Ba
riegesetz, Batt
2009 (nationa
position of dire
66/EC (battery
acid batteries h
ed with a cross
ie bin with the
ol for lead Pb
w.

dition, the ISO
ing symbol is

manufacturer, r
mporter of the b
sponsible for t
hment of the sy
on, a consume
mation on the s
symbols has
hed, which is r
erman Battery
d above as we
tary agreemen
ry manufacture
he German Fe
ter of the Envi
ember 1988.
manufactures a
atteries subjec
fication require
aging, technic
ctions, leaflets
nsible for this
ther informat
ata rendered
d on today's kn
o not constitut
ance op prope
ng laws and re
to be observe
ent pf the prod
nsibility.
4/5

y sound
s and
atteries Act
tG) from 25
l
ective
y directive)
have to be
sed-out
e chemical
shown
-return /
rendered.
respectively
batteries shall
he
ymbols. In
er / user
significance
to be
required by
y Ordinance
ell as by the
nt of the
es concluded
ederal
ronment in
and sellers of
ct to
ements
cal
s) shall be
information.
ion
above are
nowledge,
te an
erties.
egulations
d by the
duct in own
5


5/5





Editor:
ZVEI Zentralverband Elektrotechnik- und Elektronikindustrie e. V.
Fachverband Batterien
Lyoner Strae 9
60528 Frankfurt

Fon.: +49 69 6302-283
Fax: +49 69 6302-362
Mail: batterien@zvei.org

ZVEI 2012
In spite of all due care, however, we cannot accept any liability
that the information is complete or correct or up to date.

Banner GmbH
Banner Strae 1, A-4021 Linz
Tel. ++43/(0)732/3888-0, Fax ++43/(0)732/3888-21399
E-Mail: oce@bannerbatterien.com
BULGARIEN
Banner Baterii Bulgaria EOOD /
-
Ul. Ljublana 46, J&L Center, 1. Stock / . 46, J&L
Center, . 1., BG-1618 Soa /
Telefon: / . +359/2/889 01 20
Fax: / : +359/2/889 01 21
E-Mail: oce.bbg@bannerbatteries.com
DNEMARK
Banner Batterier Danmark ApS
Silovej 14, Solrd, DK-2690 Karlslunde
Telefon: +45/70 20 60 61
Fax: +45/70 20 60 69
E-Mail: oce.bdk@bannerbatteries.com
DEUTSCHLAND
Banner Batterien Deutschland GmbH
Kesselbodenstrae 3, D-85391 Allershausen (Mnchen)
Telefon: +49/(0)6441/30 73-23000
Fax: +49/(0)6441/30 73-23099
E-Mail: oce.bda@bannerbatterien.com
Banner Batterien Deutschland GmbH -
Verkaufsniederlassung
Lise-Meitner-Str. 5, D-41515 Grevenbroich (Dsseldorf )
Telefon: +49/(0)6441/30 73-23500
Fax: +49/(0)6441/30 73-23599
E-Mail: oce.bdg@bannerbatterien.com
Banner Batterien Deutschland GmbH -
Verkaufsniederlassung
Am Schwingbach 14-16
D-35625 Httenberg/Rechtenbach (Frankfurt)
Telefon: +49/(0)6441/30 73-23100
Fax: +49/(0)6441/30 73-23199
E-Mail: oce.bdh@bannerbatterien.com
Banner Batterien Deutschland GmbH -
Verkaufsniederlassung Mutzschen
Zum Storchennest 3, D-04668 Grimma (Leipzig)
Telefon: +49/(0)6441/30 73-23200
Fax: +49/(0)6441/30 73-23299
E-Mail: oce.bdm@bannerbatterien.com
Banner Batterien Deutschland GmbH -
Verkaufsniederlassung Pforzheim
Sdweg 6, D-75245 Neulingen-Gbrichen (Pforzheim) -
Telefon: +49/(0)6441/30 73-23300
Fax: +49/(0)6441/30 73-23399
E-Mail: oce.bdp@bannerbatterien.com
Banner Batterien Deutschland GmbH -
Verkaufsniederlassung
Friedrich-Bckling-Str. 21, D-16816 Neuruppin (Berlin)
Telefon: +49/(0)6441/30 73-23400
Fax: +49/(0)6441/30 73-23499
E-Mail: oce.bdne@bannerbatterien.com
FRANKREICH
Banner France SAS
Zone Industrielle No. 2, 5, Rue Vauban, F-68170 Rixheim
Telefon: +33/(0)389/44 28 38
Fax: +33/(0)389/54 13 28
E-Mail: oce.bf@bannerbatteries.com
Banner Toulouse - Succursale
80 Rue de Fenouillet, F-31200 TOULOUSE
Telefon: 05/61 32 72 11
Fax: 05/61 32 88 94
Banner Ile de France - Succursale
Parc GVIO - Hall 1 - Batiment D , 86/114,
avenue Louis Roche, F-92230 Gennevilliers
Telefon: 01/47 94 32 75
Fax: 01/47 98 05 19
E-Mail: oce.bfp@bannerbatteries.com
GROSSBRITANNIEN
Banner Batteries (GB) Ltd.
Units 5-8 Canal View Business Park,
Wheelhouse Road, Rugeley, UK-WS15 1UY Staordshire
Telefon: +44/(0)1889/57 11 00
Fax: +44/(0)1889/57 73 42
E-Mail: oce.bgb@bannerbatteries.com
STERREICH
Banner GmbH
Banner Strae 1, A-4021 Linz
Telefon: +43/(0)732/38 88-0
Fax: +43/(0)732/38 88-21399
E-Mail: oce@bannerbatterien.com
Banner Batterien sterreich GmbH
Banner Strae 1, A-4021 Linz
Telefon: +43/(0)732/38 88-0
Fax: +43/(0)732/38 88-21399
E-Mail: oce@bannerbatterien.com
Banner/EAST PENN Battery Services GmbH
Banner Strae 1, A-4021 Linz
Telefon: +43/(0)732/38 88-0
Fax: +43/(0)732/38 88-21399
E-Mail: oce@bannerbatterien.com
Banner Kunststowerk GmbH
Traunauweg 22, A-4030 Linz
Telefon: +43/(0)732/38 88-21800
Fax: +43/(0)732/38 88-21850
E-Mail: oce@bannerkunststo.com
Banner Batterien sterreich GmbH -
Verkaufsniederlassung
Krntner Str. 168, A-8053 Graz
Telefon: 0316/27 21 52-22100
Fax: 0316/27 21 52-22199
E-Mail: oce.bag@bannerbatterien.com
Banner Batterien sterreich GmbH -
Verkaufsniederlassung
Bundesstr. 4, A-6063 Innsbruck/Rum
Telefon: +43/(0)512/26 20 70-22200
Fax: +43/(0)512/26 20 70-22299
E-Mail: oce.bai@bannerbatterien.com
Banner Batterien sterreich GmbH -
Verkaufsniederlassung
Banner Str. 1, A-4021 Linz
Telefon: +43/(0)732/38 88-21601, 21602
Fax: +43/(0)732/38 88-21699
E-Mail: oce.bal@bannerbatterien.com
Banner Batterien sterreich GmbH -
Verkaufsniederlassung
Lehenweg 6, A-6830 Rankweil
Telefon: +43/(0)5522/44 2 58-22300
Fax: +43/(0)5522/45 3 57
E-Mail: oce.bar@bannerbatterien.com
Banner Batterien sterreich GmbH -
Verkaufsniederlassung
Lamezanstr. 5, A-1232 Wien
Telefon: 01/616 51 81-22000
Fax: 01/616 21 90
E-Mail: oce.baw@bannerbatterien.com
Banner Batterien sterreich GmbH -
Verkaufsniederlassung
Steingasse 207, A-9020 Klagenfurt
Telefon: 0463/33 7 22-22400
Fax: 0463/33 6 19-22499
E-Mail: oce.bak@bannerbatterien.com
POLEN
Banner Polska Sp. z o.o.
ul. Gliwicka 234, PL-40861 Katowice
Telefon: +48/(0)32/203 72 45
Fax: +48/(0)32/203 72 46
E-Mail: oce.bpl@bannerbatteries.com
Banner Polska Sp. z o.o. - Filia
ul. Krta 2, PL-05850 Ozarw Mazowiecki (Warszawa)
Telefon: +48/(0)22/721 14 47
Fax: +48/(0)22/721 14 48
E-Mail: oce.bplw@bannerbatteries.com
RUMNIEN
Banner Baterii Romania s.r.l.
B-dul Biruinei nr. 67, RO-077145 Pantelimon, jud. llfov
Telefon: +4/021/3000 627, +4/021/310 11 49
Fax: +4/021/3000 637
E-Mail: oce.bro@bannerbatteries.com
RUSSLAND
OOO Banner Batterien/
Krasnogorskij rajon, Promzona-37, pos.Archangelskoe /
-37, .,
RUS-143420 Moskovskaja Oblast /
Telefon: / : +7/(499)504 98 69
Fax: / : +7/(499)504 98 69
E-Mail: oce.bru@bannerbatteries.com
SCHWEIZ
Banner Batterien Schweiz AG / Batteries Banner Suisse SA
Banner Strae 1, CH-5746 Walterswil
Telefon: +41/(0)840 Banner (226637)
Gratisfax: +41/(0)800 Banner (226637)
E-Mail: oce.bchw@bannerbatterien.com
Banner Batterien Schweiz AG - Verkaufsniederlassung
Banner Strae 1, CH-5746 Walterswil
Telefon: 0840 Banner (226637)
Fax: 0800 Banner (226637)
E-Mail: oce.bchw@bannerbatterien.com
SLOWAKEI
Banner Baterie SR, s.r.o.
Za Stanicou 1, Nr. 1537, SK-83104 Bratislava 3
Telefon: +421/(0)2/43 63 43 44
Fax: +421/(0)2/43 42 18 74
E-Mail: oce.bskb@bannerbatteries.com
TSCHECHIEN
Banner Baterie R, s.r.o.
Uhnves, Ptelstv 1011, CZ-10400 Praha 10
Telefon: +420/267 090-510
Fax: +420/267 090-522
E-Mail: oce.bczp@bannerbatteries.com
TRKEI
Banner Ak San. ve Tic. Ltd. ti.
Beylikdz Mermerciler Sanayi Sit., 7. Cad. No:4
(Hellmann Logistik binas), TR-34520 Beylikdz - stanbul
Telefon: +90/212/877 85 10
Fax: +90/212/879 29 72
E-Mail: oce.btri@bannerbatteries.com
UNGARN
Banner Batterien Hungria Kft
Ipari park, Jedlik nyos u. 6, H-2330 Dunaharaszti
Telefon: +36/24/49 18 91
Fax: +36/24/49 18 92
E-Mail: oce.bhb@bannerbatteries.com
www.bannerbatteries.com