Safety Data Sheet

Page 1 of 9

LOCTITE 518

MSDS-No. : 153476 V001.4

Revision: 11.03.2013 printing date: 22.11.2013

Section 1. Identification of the substance/preparation and of the company/undertaking

Product name: LOCTITE 518

Identification of manufacturer, importer or distributor Manufacturer: Henkel Puerto Rico, Inc., 9 V. Quilinchini Avenue, 00637 Sabana Grande, Puerto Rico. Phone: 001 787 873 6500 Fax: 001 787 873 2619 Importer: Henkel Thailand Ltd The Offices at Centralworld, 35th Floor, 999/9 Rama 1 Rd, Kwang Patumwan, Khet Patumwan, Bangkok 10330, Thailand. Phone : + 6622098000 Fax : +6622098008 Information office (content SDS): ap-ua-psra.sea@henkel.com

Section 2. Composition / information on ingredients

Declaration of ingredients:
Hazardous components CAS-No. Acrylic acid 79-10-7 EINECS 201-177-9 content 1 - 10 % Classification N - Dangerous for the environment; R50 Xn - Harmful; R20/21/22 C - Corrosive; R35 R10 T - Toxic; R23 Xn - Harmful; R21/22, R48/20/22 O - Oxidizing; R7 C - Corrosive; R34 N - Dangerous for the environment; R51/53 Xn - Harmful; R22 Xi - Irritant; R36/38 R43 R10 Xn - Harmful; R65 Xi - Irritant; R37 N - Dangerous for the environment; R51/53

Cumene hydroperoxide 80-15-9

201-254-7

1 - 10 %

Ethane-1,2-diol 107-21-1 2-Hydroxyethyl methacrylate 868-77-9 Cumene 98-82-8

203-473-3 212-782-2 202-704-5

1 - 10 % 0,1 - 1 % 0,1 - 1 %

Section 3. Hazards identification

Hazard classification: Xi - Irritant Risk phrases: R37/38 Irritating to respiratory system and skin. R41 Risk of serious damage to eyes.

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Section 4. First aid measures

Inhalation: Move to fresh air. If symptoms persist, seek medical advice. Skin contact: Rinse with running water and soap. Seek medical advice. Eye contact: Rinse immediately with plenty of running water (for 10 minutes). Seek medical attention if necessary. Ingestion: Rinse out mouth, drink 1-2 glasses of water, do not induce vomiting. Seek medical advice.

Section 5. Fire fighting measures

Suitable extinguishing media: Carbon dioxide, foam, powder Special protection equipment for firefighters: Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. Particular danger/case of fire: Do not expose to direct heat.

Section 6. Accidental release measures

Personal precautions: Avoid skin and eye contact. Ensure adequate ventilation. See advice in chapter 8 Environmental precautions: Do not let product enter drains. Clean-up methods: For small spills wipe up with paper towel and place in container for disposal. For large spills absorb onto inert absorbent material and place in sealed container for disposal.

Section 7. Handling and storage

Handling: Use only in well-ventilated areas. Prolonged or repeated skin contact should be avoided to minimise any risk of sensitisation. Storage: Store in original containers at 8-21C (46.4-69.8F) and do not return residual materials to containers as contamination may reduce the shelf life of the bulk product.

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Section 8. Exposure controls / personal protection

ACRYLIC ACID 79-10-7 Type: ppm: mg/m3: Remarks: Type: ppm: mg/m3: Remarks: Type: ppm: mg/m3: Remarks: Type: ppm: mg/m3: Remarks: 100 ACGIH Time Weighted Average (TWA): 50 ACGIH ACGIH Can be absorbed through the skin. Ceiling Limit Value: Time Weighted Average (TWA): 2 ACGIH Skin designation:

ACRYLIC ACID 79-10-7

ETHYLENE GLYCOL, AEROSOL ONLY 107-21-1

CUMENE 98-82-8

Respiratory protection: Use only in well-ventilated areas. Hand protection: Chemical-resistant protective gloves (EN 374). Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) This information is based on literature references and on information provided by glove manufacturers, or is derived by analogy with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may be considerably shorter than the permeation time determined in accordance with EN 374 as a result of the many influencing factors (e.g. temperature). If signs of wear and tear are noticed then the gloves should be replaced.

Eye protection: Wear protective glasses. Body protection: Wear suitable protective clothing. Hygienic measures: Good industrial hygiene practices should be observed. Wash hands before work breaks and after finishing work. Do not eat, drink or smoke while working.

Section 9. Physical and chemical properties

Appearance: red gel Odor: Mild Specific gravity: 1,1 pH: not applicable Boiling point: > 150 C (> 302 F)

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(Tagliabue closed cup)> 100,00 C (> 212 F)

Flash point: Vapor pressure: (; 27 C (80.6 F)) < 10 mm hg Density: 1,1 g/cm3 Solubility: Solvent: Water, Slight VOC content (1999/13/EC) < 5 % (As defined in the Council Directive 2004/42/EC)

Section 10. Stability and reactivity

Conditions to avoid: Stable under normal conditions of storage and use. Materials to avoid: Reaction with strong oxidants. Reaction with strong acids. Reducing agents. Hazardous decomposition products: carbon oxides. Sulphur oxides nitrogen oxides Irritating organic vapours.

Section 11. Toxicological information

Oral toxicity: May cause irritation to the digestive tract.

Inhalative toxicity: Irritating to respiratory system Skin irritation: Irritating to the skin. Eye irritation: Risk of serious damage to eyes

Acute oral toxicity:

Cumene hydroperoxide 80-15-9 Value type Value Species Method Value type Value Species Method LD50 550 mg/kg rat LD50 > 2.000 mg/kg rat EU Method B.1 (Acute Toxicity (Oral))

Ethane-1,2-diol 107-21-1

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Acute inhalative toxicity:

Cumene hydroperoxide 80-15-9 Value type Value Exposure time Species Method LC50 220 ppm 4h rat

Acute dermal toxicity:

Cumene hydroperoxide 80-15-9 Value type Value Species Method LD50 500 mg/kg rat

Skin corrosion/irritation:
Cumene hydroperoxide 80-15-9 Result Exposure time Species Method corrosive

rabbit

Germ cell mutagenicity:

Acrylic acid 79-10-7 Result Type of study / Route of administration Metabolic activation / Exposure time Method Result Type of study / Route of administration Metabolic activation / Exposure time Method Result Type of study / Route of administration Metabolic activation / Exposure time Species Method Result Type of study / Route of administration Metabolic activation / Exposure time Method Result Type of study / Route of administration Metabolic activation / Exposure time Method 2-Hydroxyethyl methacrylate 868-77-9 Result Type of study / Route of administration Metabolic activation / Exposure time Method negative bacterial reverse mutation assay (e.g Ames test) with and without positive bacterial reverse mutation assay (e.g Ames test) without OECD Guideline 471 (Bacterial Reverse Mutation Assay) negative dermal mouse negative bacterial reverse mutation assay (e.g Ames test) with and without positive in vitro mammalian chromosome aberration test with and without OECD Guideline 473 (In vitro Mammalian Chromosome Aberration Test) negative bacterial reverse mutation assay (e.g Ames test) with and without OECD Guideline 471 (Bacterial Reverse Mutation Assay)

Cumene hydroperoxide 80-15-9

Cumene hydroperoxide 80-15-9

Ethane-1,2-diol 107-21-1

2-Hydroxyethyl methacrylate 868-77-9

Section 12. Ecological information

Mobility: Cured adhesives are immobile. General ecological information: Do not empty into drains / surface water / ground water.

Toxicity:

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Value type Value Acute Toxicity Study Exposure time Species Method Value type Value Acute Toxicity Study Exposure time Species Method Value type Value Acute Toxicity Study Exposure time Species Method Value type Value Acute Toxicity Study Exposure time Species Method Value type Value Acute Toxicity Study Exposure time Species Method Value type Value Acute Toxicity Study Exposure time Species Method Value type Value Acute Toxicity Study Exposure time Species Method Value type Value Acute Toxicity Study Exposure time Species Method Value type Value Acute Toxicity Study Exposure time Species Method Value type Value Acute Toxicity Study Exposure time Species Method Value type Value Acute Toxicity Study Exposure time LC50 27 mg/l Fish 96 h Salmo gairdneri (new name: Oncorhynchus mykiss) OECD Guideline 203 (Fish, Acute Toxicity Test) EC50 47 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) EC50 0,13 mg/l Algae 72 h Scenedesmus subspicatus (new name: Desmodesmus subspicatus) OECD Guideline 201 (Alga, Growth Inhibition Test) LC50 3,9 mg/l Fish 96 h Oncorhynchus mykiss OECD Guideline 203 (Fish, Acute Toxicity Test) EC50 18 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) ErC50 3,1 mg/l Algae 72 h Pseudokirchnerella subcapitata OECD Guideline 201 (Alga, Growth Inhibition Test) LC50 72.860 mg/l Fish 96 h Pimephales promelas OECD Guideline 203 (Fish, Acute Toxicity Test) NOEC 15.380 mg/l Fish 28 d Oryzias latipes OECD Guideline 204 (Fish, Prolonged Toxicity Test: 14-day Study) EC50 34.400 mg/l Daphnia 48 h Ceriodaphnia sp. OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) EC50 > 20.000 mg/l Algae Microcystis aeruginosa OECD Guideline 201 (Alga, Growth Inhibition Test) LC50 227 mg/l Fish 96 h

Acrylic acid 79-10-7

Acrylic acid 79-10-7

Acrylic acid 79-10-7

Cumene hydroperoxide 80-15-9

Cumene hydroperoxide 80-15-9

Cumene hydroperoxide 80-15-9

Ethane-1,2-diol 107-21-1

Ethane-1,2-diol 107-21-1

Ethane-1,2-diol 107-21-1

2-Hydroxyethyl methacrylate 868-77-9

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Species Method Value type Value Acute Toxicity Study Exposure time Species Method Value type Value Acute Toxicity Study Exposure time Species Method Value type Value Acute Toxicity Study Exposure time Species Method Value type Value Acute Toxicity Study Exposure time Species Method Value type Value Acute Toxicity Study Exposure time Species Method Pimephales promelas OECD Guideline 203 (Fish, Acute Toxicity Test) EC50 380 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) EC50 345 mg/l Algae 72 h Selenastrum capricornutum (new name: Pseudokirchnerella subcapitata) OECD Guideline 201 (Alga, Growth Inhibition Test) LC50 4,8 mg/l Fish 96 h Oncorhynchus mykiss OECD Guideline 203 (Fish, Acute Toxicity Test) EC50 4 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) EC50 2,6 mg/l Algae 72 h Selenastrum capricornutum (new name: Pseudokirchnerella subcapitata) OECD Guideline 201 (Alga, Growth Inhibition Test)

2-Hydroxyethyl methacrylate 868-77-9

2-Hydroxyethyl methacrylate 868-77-9

Cumene 98-82-8

Cumene 98-82-8

Cumene 98-82-8

Persistence and degradability:

Acrylic acid 79-10-7 Result Route of application Degradability Method Result Route of application Degradability Method Ethane-1,2-diol 107-21-1 Result Route of application Degradability Method Result Route of application Degradability Method Cumene 98-82-8 Result Route of application Degradability Method aerobic 86 % readily biodegradable aerobic 81 % OECD Guideline 301 D (Ready Biodegradability: Closed Bottle Test)

Cumene hydroperoxide 80-15-9

18 % OECD Guideline 301 E (Ready biodegradability: Modified OECD Screening Test) readily biodegradable aerobic 83 - 96 % OECD Guideline 301 C (Ready Biodegradability: Modified MITI Test (I)) readily biodegradable aerobic 98 % OECD Guideline 301 E (Ready biodegradability: Modified OECD Screening Test)

2-Hydroxyethyl methacrylate 868-77-9

Bioaccumulative potential / Mobility in soil:

Acrylic acid 79-10-7 LogKow Temperature 0,46 25 C

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Method OECD Guideline 107 (Partition Coefficient (n-octanol / water), Shake Flask Method) 9,1

Cumene hydroperoxide 80-15-9

Bioconcentration factor (BCF) Exposure time Species Temperature Method LogKow Temperature Method LogKow Temperature Method Bioconcentration factor (BCF) Exposure time Species Temperature Method LogKow Temperature Method

calculation OECD Guideline 305 (Bioconcentration: Flow-through Fish Test) 2,16

Cumene hydroperoxide 80-15-9

Ethane-1,2-diol 107-21-1

-1,36

Cumene 98-82-8

35,5

Carassius auratus OECD Guideline 305 (Bioconcentration: Flow-through Fish Test) 3,55 23 C OECD Guideline 107 (Partition Coefficient (n-octanol / water), Shake Flask Method)

Cumene 98-82-8

Section 13. Disposal considerations

Product Method of disposal: Dispose of in accordance with local and national regulations. Contribution of this product to waste is very insignificant in comparison to article in which it is used Packaging Disposal for uncleaned package: After use, tubes, cartons and bottles containing residual product should be disposed of as chemically contaminated waste in an authorised legal land fill site or incinerated.

Section 14. Transport information

General information: Not hazardous according to RID, ADR, ADNR, IMDG, IATA-DGR.

Section 15. Regulations - classification and identification

Indication of danger: Xi - Irritant Risk phrases: R37/38 Irritating to respiratory system and skin. R41 Risk of serious damage to eyes. Safety phrases: S23 Do not breathe vapour. S24/25 Avoid contact with skin and eyes. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28 After contact with skin, wash immediately with plenty of water and soap. S39 Wear eye/face protection. S51 Use only in well-ventilated areas.

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Global inventory status: Regulatory list TSCA AICS DSL KECI (KR) PICCS (PH) INV (CN) Notification yes yes yes yes yes yes

Section 16. Other information

Issue date: 22.11.2013 Disclaimer This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties. This safety data sheet was prepared in accordance with Council Directive 67/548/EEC and it's subsequent amendments, and Commission Directive 1999/45/EC.