4. Three reactions involving
2 4
H PO
acts as an acid ?
(A) II only (B) I and II (C) III only (D) I only
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For Questions 5 - 7
(A) Statement-1 is True, Statement-2 is True and Statement-2 is a correct explanation for Statement-1
(B) Statement-1 is True, Statement-2 is True and Statement-2 is NOT a correct explanation for Statement-1
(C) Statement-1 is True, Statement-2 is False
(D) Statement-1 is False, Statement-2 is True
5. Statement 1 :
The first member of s and p block elements when compared to that of subsequent
members in the same group shows different chemical behaviour.
Statement 2 : The other members of a group have vacant d-orbitals.
6. Statement 1 : N-atom in NH
3
is sp
3
-hybridised and bond angle is 107 .
Statement 2 : p- p repulsion (VSEPR) decreases bond angle to 107 .
7. Statement 1 : The value of van der Waals constant a is larger for NH
3
than PH
3
.
Statement 2 : Hydrogen bonding is present in NH
3
but not in PH
3
.
8. 10 L of hard water with temporary hardness [of Ca(HCO
3
)
2
] required 0.56 g of lime:
3 2 3 2
Ca(HCO ) CaO 2CaCO H O + +
Temporary hardness in terms of ppm of CaCO
3
is:
(A) 56 (B) 1/2 (C) 100 (D) 200
9. A person takes 3 gm of an antacid tablet comprising bicarbonate ion at 30.5 %. The volume of CO
2
evolved (at 1.0 atm and 27 C ) in the stomach (on neutralization) will be : | | R 0.08 Latm/ mol / K =
(A) 3.6L (B) 0.36L (C) 36L (D) None of these
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10. Which has greater formal charge on
*
N-atom ?
(A)
*
N N O = = (B)
*
N N O (C) Equal (D) Cant be determined
11. One mole of ferrous oxalate is oxidised by x mole of
4
MnO
+ IV.
2 3
I NaOH I IO
+ +
(A) IV (B) I, II, III (C) III, IV (D) I, II
14. In vinyl acetylene
1 2 3 4
2
CH C CH CH = , type of overlapping in ( )
2 3
C C bond is:
(A)
2
sp sp (B)
2
sp sp (C)
3 3
sp sp (D)
3 2
sp sp
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15. Sodium thiosulphate (Na
2
S
2
O
3
) is a strong reducing agent, its n-factor in acidic medium and basic
medium respectively is:
(A) 0.5, 4 (B) 1, 4 (C) 0.5, 8 (D) 1, 8
16. In terms of bond polarity, which one of the following order is correct?
(A) NH
3
< H
2
O < HF < H
2
S (B) H
2
S < NH
3
< H
2
O < HF
(C) H
2
O < NH
3
< H
2
S < HF (D) HF < H
2
O < NH
3
< H
2
S
17. An electron from one Bohr orbit can go to next higher orbit :
(A) By emission of electromagnetic radiation
(B) By absorption of any electromagnetic radiation
(C) By absorption of electromagnetic radiation of particular frequency
(D) Without emission or absorption of electromagnetic radiation
18. Which of the following statements does not form a part of Bohrs model of hydrogen atom ?
(A) Energy of the electrons in the orbit is quantised
(B) The electron in the orbit nearest to the nucleus has the lowest energy
(C) Electrons revolve in different orbits around the nucleus
(D) The position and velocity of the electrons in the orbit cannot be determined simultaneously
19. Which of the following sets of quantum numbers represents the highest energy of an atom ?
(A)
1
n 3, 1, m 1, s
2
= = = = + (B)
1
n 3, 2, m 1, s
2
= = = = +
(C)
1
n 4, 0, m 0, s
2
= = = = + (D)
1
n 3, 0, m 0, s
2
= = = = +
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20. The atomic numbers of elements A, B, C and D are Z 1, Z, Z 1 + and Z + 2, respectively. If B is a noble
gas, choose the correct answer from the following statements. ( Take Z > 2 )
I. A has higher electron affinity II. C exists in +2 oxidation state
III. D is an alkaline earth metal
(A) I and II (B) II and III (C) I and III (D) I, II and III
21. Correct order of first ionisation potential among the following elements Be, B, C, N, O is :
(A) B < Be < C < O < N (B) B < Be < C < N < O
(C) Be < B < C < N < O (D) Be < B < C < O < N
22. A certain transition in H-spectrum from an excited state to ground state in one or more steps gives rise to a
total of ten lines. How many of these belong to UV spectrum?
(A) 3 (B) 4 (C) 5 (D) 6
23. The basicity of H
3
PO
3
and H
3
PO
2
are respectively :
(A) 1, 2 (B) 2, 1 (C) 1, 1 (D) 3, 3
24. In which of the following cases, oxidation state of N atom is wrongly calculated ?
Compound Oxidation state Compound Oxidation state
(A) NH
4
Cl 3 (B) (N
2
H
5
)
2
SO
4
+2
(C) Mg
3
N
2
3 (D) NH
2
OH 1
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25. When two reactants. A and B are mixed to give products C and D, the reaction quotient Q, at the initial
stages of the reaction :
I. is zero II. increase with time
III. rate of change of Q decreases with time IV. rate of change of Q increases with time
The correct option is :
(A) I, II, III (B) I, II, IV (C) I, II (D) None of these
Paragraph for Questions 26 - 27
All such titration which involves the direct titration of Iodine with a reducing agent are grouped under Iodimetry.
If iodine is liberated as a result of chemical reaction involving oxidation of an iodide ion by a strong oxidizing
agent in neutral or acidic medium, the liberated iodine is then titrated with reducing agent. Iodometry is used to
estimate the strength of oxidizing agent. For example the estimation of Cu
2+
with thiosulphate:
2
2 2 2
Cu I Cu I I
+
+ +
2 2
2 2 3 4 6
I S O S O I
+ +
Starch is used as indicator near the end point which from blue colour complex with
3
I
j (B) 6 8
i j (C) 6 8
i j + (D) 5 2
34. Rain, driven by the wind, falls on a railway compartment with a velocity of
1
20ms
, at an angle of 30 to
the vertical. The train moves, along the direction of wind flow, at a speed of 108
1
kmh
. Determine the
apparent velocity of rain for a person sitting in the train.
(A)
1
20 7ms
(B)
1
10 7ms
(C)
1
15 7ms
(D)
1
10 7kmh
35. A man wishes to cross a river in a boat. If he crosses the river in minimum time, then he takes 10 min with
a drift of 120m. If he crosses the river taking shortest route, he takes 12.5 min, find the velocity of the boat
with respect to still water :
(A) 10 m/min (B) 20 m/min (C) 12 m/min (D) 15 m/min
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36. The angular velocity of a particle moving in a circle of radius 50 cm is increased in 5 min from
100 revolutions per minute to 400 revolutions per minute. Find the tangential acceleration of the particle.
(A)
2
60ms
(B)
2
30
ms
(C)
2
15
ms
(D)
2
60
ms
37. A body has an initial velocity of 3 m/s and has an acceleration of
2
1ms
at an angle
1
4
3
tan
| |
|
\
with the direction of initial velocity
38. A small body is dropped from a rising balloon. A person A stands on ground, while another person B is on
the balloon. Choose the correct statement : Immediately, after the body is released.
(A) Both A and B, feel that the body is coming (going) down
(B) Both A and B, feel that the body is going up
(C) A feels that the body is coming down, while B feels that the body is going up
(D) A feels that the body is going up, while B feels that the body is going down
39. In order to raise a mass of 100 kg, a man of mass 60 kg fastens a rope to it and
passes the rope over a smooth pulley. He climbs the rope with acceleration 5 g/4
relative to the rope. The tension in the rope is : (Take
2
10 g ms
= )
(A)
4875
8
N (B)
4875
2
N
(C)
4875
4
N (D)
4875
6
N
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40. An object is suspended from a spring balance in a lift. The reading is 240 N when the lift is at rest.
If the spring balance reading now changes to 220 N, then the lift is moving :
(A) Downward with constant speed (B) Downward with decreasing speed
(C) Downward with increasing speed (D) Upward with increasing speed
41. A heavy uniform chain lies on a horizontal table top. If the coefficient of friction between the chain and the
table surface is 0.25, then the maximum fraction of the length of the chain that can hang over one edge of
the table in equilibrium is :
(A) 20% (B) 25% (C) 35% (D) 15%
42. In the figure, a block of weight 60N is placed on a rough surface. The coefficient of friction between the
block and the surfaces is 0.5. What maximum can be the weight W such that the block does not slip on the
surface ?
(A) 60N (B)
60
2
N
(C) 30N (D)
30
2
N
43. A horizontal force, just sufficient to move a body of mass 4 kg lying on a rough horizontal surface,
is applied on it. The coefficient of static and kinetic friction between the body and the surface are 0.8 and
0.6, respectively. If the force continues to act even after the block has started moving, the acceleration of
the block in
2
ms
is : (
2
10 g ms
= )
(A) 1/4 (B) 1/2 (C) 2 (D) 4
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44. Which of the following statements is correct ?
(A) Kinetic energy of a system can be changed without changing its momentum
(B) Kinetic energy of a system cannot be changed without changing its momentum
(C) Momentum of a system cannot be changed without changing its kinetic energy
(D) A system cannot have energy without having momentum
45. In the figure shown, a person wants to raise a block lying on
the ground to a height h. In both the cases, if time required
is same then in which case he has to exert more force.
Assume pulleys and strings light.
(A) I (B) II
(C) Same in both (D) Cannot be determined
46. A wooden block of mass M resting on a rough horizontal floor is pulled with a force F at an angle with
the horizontal. If is coefficient of kinetic friction between the block and the surface, then the
acceleration of the block is :
(A) ( )
F
cos sin g
M
(B)
F
cos
M
(C) ( )
F
cos sin g
M
+ (D)
F
sin
M
47. A particle is moved from position
1
3 2 6
r i j k = +
to position
2
14 13 9
r i j k = + +
is s when a
retarding force F is applied. If the KE is doubled, the distance covered by it to come to rest for the same
retarding force F is :
(A) 4s (B) 6s (C) 2s (D) 8s
49.
K = 100 N/m
0 5 . =
10 m kg =
2
10 g m/ s =
A force F = 40 N is applied. Find elongation in the spring.
(A) 0.25 m (B) 0.5 m (C) 0.40 m (D) 0 m
50. A particle of mass m moves in a vertical circle. It is given 7 u g = at the lowest point. Find its speed at
the highest point.
(A) g (B) 3g
(C) 2g (D) Zero
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51. A particle moves in a straight line with the velocity as shown in figure. At 0 16 t , x m = = .
(A) The maximum value of the position coordinate of the particle is 70m
(B) The maximum value of the position coordinate of the particle is 36m
(C) The particle is at the position of 36m at t = 18s
(D) The particle is at the position of 40m at t = 30s
52. Two blocks of mass m
1
and m
2
are connected through a
massless inextensible string. Block of mass m
1
is placed at
the fixed rigid inclined surface while the block of mass m
2
hanging at the other end of the string, which is passing
through a fixed massless frictionless pulley shown in the
figure. The coefficient of static friction between the block
and the inclined plane is 0.8. The system of masses m
1
and
m
2
is released from rest. Then :
(A) The tension in the string is 20 N after releasing the system
(B) The contact force by the inclined surface on the block is not along normal to the inclined surface
(C) The magnitude of contact force by the inclined surface on the block m
1
is 20N
(D) None of these
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53. During a projectile motion if the maximum height equals the horizontal range, then the angle of projection
with the horizontal is :
(A) ( )
1
1 tan
(B) ( )
1
2 tan
(C) ( )
1
3 tan
(D) ( )
1
4 tan
54. A body is projected horizontally from the top of a tower with initial velocity
1
18ms
(B)
1
9 2 ms
(C)
1
18ms
(D)
1
18 2 ms
55. Three equal weights A, B and C of mass 2 kg each are hanging on a string
passing over a fixed frictionless pulley as shown in the figure.
The tension in the string connecting weights B and C is : (g = 9.8 m/s
2
)
(A) zero
(B) 13 N
(C) 3.3 N
(D) 19.6 N
56. Figure shows the vertical section of a frictionless surface.
A block of mass 2 kg is released from rest from position A;
its KE as it reaches position C is : (
2
10 g ms
= ) [Assume
the block does not leave contact before point C]
(A) 140 J (B) 180 J
(C) 120 J (D) 280 J
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57. Figures shows a smooth curved track terminating in a smooth horizontal part. A spring of spring constant
1
400 Nm
is attached at one end to the wedge fixed rigidly with the horizontal part. A 40g mass is
released from rest at a height of 5m on the curved track. The maximum compression of the spring is : (g =
10 m/s
2
)
(A) 10 cm (B) 5 cm
(C) 12 cm (D) 8 cm
58. Find force of friction between the wall and the block when the block is at rest :
50 W N =
300 F N =
(A) 50 N (B) 60 N
(C) 55 N (D) 49 N
59. An engine of a train moving with uniform acceleration passes an electric pole with velocity u and the last
compartment with velocity v. The middle part of the train passes past the same pole with a velocity of :
(A)
2
u v +
(B)
2 2
2
u v +
(C)
2 2
2
u v +
(D)
2 2
2
u v
60. Coefficient of friction between m
1
and m
2
= 0.5.
2
10 g m/ s =
1
10 m kg =
2
20 m kg =
If a force F is applied as shown in the figure, then acceleration of m
1
and m
2
are respectively (in m/s
2
) :
(A) 10, 10 (B) 15, 10 (C) 15, 15 (D) 10, 15
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PART - III (MATHEMATICS) 120 MARKS
STRAIGHT OBJECTIVE TYPE
This Part contains 30 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which
Only One is Correct :
61. The exhaustive range of values of a such that the angle between the pair of tangents drawn from (a, a) to
the circle
2 2
2 2 6 0 x y x y + = lies in the range
3
,
| |
|
\
is :
(A) ( ) 1, (B) ( ) ( ) 5 3 3 5 , ,
(C)
( ) ( )
2 2 2 2 , , (D) ( ) ( ) 3 1 3 5 , ,
62. If ( )
4 4
1 f sin cos = + + , then range of ( ) f is :
(A)
3
2
2
(
(
, (B)
3
1
2
(
(
, (C) [1, 2] (D) None of these
63. Let
2
be the discriminant and and ( ) 0 < < be the roots of the equation a x
2
+ b x + c = 0. Then,
2a +and 2a
can be the roots of the equation
(A) x
2
+ 2b x + b
2
= 0 (B) x
2
2b x + b
2
= 0
(C) x
2
+ 2b x 3b
2
+16ac = 0 (D) x
2
2b x 3b
2
+16ac = 0
64. Let line ( ) 1 0 1
1
x y
t
t t
+ = , ,
(B)
7
4
(C) (D) 0
68. The number of integral values of for which x
2
+ y
2
+ x + (1 ) y +
13
4
= 0 is the equation of a circle
whose radius cannot exceed 5, is:
(A) 14 (B) 12 (C) 8 (D) 10
69. Let ( )
1
cot
f
cot
=
+
and
5
4
(B)
2
4 b c
a
(C)
2
2
4 b ac
a
+
(D)
2
2
4 b c
a
+
76. If the family of lines ( ) ( ) 2 3 + = x a b y a b a b passes through the point for all values of a and b, then
the coordinates of the point are :
(A)
1 2
5 5
,
| |
|
\
(B)
2 1
5 5
,
| |
|
\
(C)
2 1
5 5
,
| |
|
\
(D)
1 2
5 5
,
| |
|
\
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77. If and are roots of
( )
2
1 2 0 a x bx + = and the quadratic equation whose roots are
1 1
2 and 2
is
2
0 px qx r + + = then p q r + + is proportional to :
(A) 2b (B) 6 8 a b (C) 6 8 b a (D) 0
78. If O is the origin and OP, OQ are distinct tangents to the circle x
2
+ y
2
+ 2gx + 2fy + c = 0, the circumcentre
of the triangle OPQ is :
(A) ( g, f ) (B) (g, f ) (C)
,
3 3
| |
|
\
g f
(D)
2 2
| |
|
\
g f
,
79. If both roots of the equation
2 2
2 1 0 x ax a + = lie between ( ) 2, 2 then a lies in the interval :
(A) ( ) ( ) 3 3 , , (B) ( ) 3,
(C) ( ) 1 1 , (D) ( ) ( ) ( ) 3 1 1 3 , , ,
80. If the intercept made on the line y mx = by lines 2 y = and y = 6 is less than 5, then the range of values of
m is:
(A)
4 4
3 3
, ,
| | | |
| |
\ \
(B)
4 4
3 3
,
| |
|
\
(C)
3 3
4 4
,
| |
|
\
(D)
3 3
4 4
, ,
| | | |
| |
\ \
81. The area of the triangle formed by the lines 0 y ax, x y a = + = and the Y-axis is equal to :
(A)
1
2 1 a +
(B)
2
1
a
a +
(C)
1
1 a +
(D)
2
2 1
a
a +
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82. If A + B + C = 0, then value of the expression
( ) ( )
2
sin A cos C cos A. cos B cos C cos B cos A.cos C cos B + + is equal to :
[Hint : Use ( ) ( ) 2cos Acos B cos A B cos A B = + + ]
(A) 1 (B) 2 (C) 0 (D) None of these
83. The number of common tangents to the circle one of which passes through the origin and cuts off
intercepts 2 on each of the positive coordinate axes, and the other circle has line segment joining the origin
and the point (1, 1) as a diameter is :
(A) 0 (B) 1 (C) 3 (D) 2
For Q.84 - 85
Let - chord of a circle be that chord of the circle which subtends an angle at the centre.
84. If 1 x y + = is chord of
2 2
1 x y + = , then is equal to :
(A)
4
(B)
2
(C)
8
= is :
(A) 1 (B) 2 (C) 2 (D)
1
2
86. The value of
3 5
sin sin sin . . . . .
n n n
+ + + to n terms is equal to :
(A) 1 (B) 0 (C)
2