ANNA UNIVERSITY : CHENNAI-600 025 B.E./B.

TECH DEGREE EXAMINATIONS, JAN 14 Regulations : R-2013 First Semester (Common to All Branches) GE6163-Physics and Chemistry Laboratory-I (GS-6163 Chemistry Lab) Duration: 3 Hours Maximum Marks: 50 1 Determine the amount of dissolved oxygen present in the given water sample by 50 Winklers method. You are provided with a standard solution of Potassium Dichromate and a solution of sodium thiosulfate. 2 Compare the dissolved oxygen content in the given water samples A & B. by 50 Winklers method. You are provided with a standardised solution of sodium thiosulfate. Determine the amount of dissolved oxygen originally present in the given 50 solutions C & D which are the final iodine solutions preapared by Winklers method from 250 ml of reaction mixture. You are provided with a standard solution of Potassium Dichromate and a link solution of sodium thiosulfate. Estimate the amount of chloride ions in the given water sample by Argentometry. 50 You are provided with a standard solution of Sodium Chloride and a link solution of Silver nitrate. Compare the chloride content in the given water samples A & B. by 50 Argentometry. You are provided with a standardised solution of Silver nitrate. Compare the amounts of NaCl present in the given samples C and D by titration 50 with standardized AgNO3 solution. Estimate the amount of HNO3 present in the given sample with the help of a 50 standard base and a pH meter. Draw the following graphs. (i) Plot of volume of NaOH Vs pH of the solution (ii) 8 Plot of volume of NaOH Vs

Estimate the amount of HCl present in the given sample with the help of a 50 standard base and a pH meter. Draw the following graphs (i) Plot of volume of NaOH Vs pH of the solution (ii) Plot of volume of NaOH Vs (iii)

Estimate the amount of H2SO4 present in the given sample with the help of a 50 standard base and a pH meter. Draw the following graphs. (i) Plot of volume of NaOH Vs pH of the solution (ii) Plot of volume of NaOH Vs

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Determine the amount of HCl and CH3COOH present in the given sample using a 50 standard base and conductometer. Draw the following graph. (i) Plot of volume of NaOH Vs conductivity of the solution

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Determine the amount of HNO3 and CH3COOH present in the given sample 50 using a standard base and conductometer. Draw the following graph. (i) Plot of volume of NaOH Vs conductivity of the solution. Determine the amount of H2SO4 and CH3COOH present in the given sample 50 using a standard base and conductometer. Draw the following graph. (i) Plot of volume of NaOH Vs conductivity of the solution. Find the absorbance of different concentrations of ferrous ammonium sulphate by 50 spectrophotometer after compexing the ferric iron with thiocyanate.Determine the iron content in the given water sample from the calibration curve drawn by plotting concentration of Ferrous salt Vs Absorbance. Compare the iron content in the given water samples A & B using 50 spectrophotometer. Draw the following graph. (i) Calibration curve (plot of concentration of Ferrous solution Vs Absorbance). Estimate the amount of iron present in the given ferric ammonium sulphate 50 Spectrophotometerically using by 1,10-phenanthroline/thiocyanate method. Draw the following graph. (i) Plot of concentration of iron solution Vs Absorbance). Determine the molecular weight of the given polyvinyl alcohol using Ostwald 50 Viscometer. Draw the following graph. (i) Plot of concentrations of polymer Vs reduced viscosity. Determine the relative viscosities of different concentrations of aqueous 50 polyvinyl alcohol (0.2, 0.4, 0.5, 0.6, and 0.8 g/dl)solutions and draw the following graph and determine the viscosity average Molecular weight of polyvinyl alcohol. (i) Plot of concentration of polymer Vs Reduced viscosity. (ii) Plot of concentration of polymer Vs Inherent Viscosity.

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Estimate the amount of HCl present in the given sample using a standard 50 solution of NaOH a conductometer. Draw the following graph. (i) Plot of Volume of NaOH added to the acid solution Vs Conductivity of the solution Estimate the amount of HNO3 present in the given sample using a standard 50 solution of NaOH a conductometer. Draw the following graph. (i) Plot of Volume of NaOH added to the acid solution Vs Conductivity of the solution. Estimate the amount of H2SO4 present in the given sample using a standard 50 solution of NaOH a conductometer. Draw the following graph. (i) Plot of Volume of NaOH added Vs Conductivity of the solution

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STATEMENT OF MARK DISTRIBUTION Short Experiment Result Procedure 15 20 10

Viva 05

Total 50