LESSON PLAN CHE594 CHEMICAL REACTION ENGINEERING

FACULTY OF CHEMICAL ENGINEERING UNIVERSITI TEKNOLOGI MARA

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1.0 COURSE INFORMATION COURSE NAME COURSE CODE PROGRAM SEMESTER CREDIT HOURS CONTACT HOURS COURSE STATUS PRE"RE#UISITE 2.0 : : : : : : : :

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CHEMICAL REACTION ENGINEERING CHE594 EH220/EH221/EH222 4 (EH220 /5 (EH221 /5 (EH222 ! 4 CORE NIL

SYNOPSIS The course deal with the engineering activities concerned with the exploitation of chemical reactions on a commercial scale. Its goal is the successful design and operation of chemical reactors which set the chemical engineering apart as a distinct branch of engineering profession. Thus, in designing and operating chemical reactors, the discussions on important topics of strong fundamentals in chemical kinetics, type of reactors and simple to more complex design approach are included. O$%ECTIVES Upon completion of this course, students should be able to: 1. !. %. &. pply principles related to chemical reactions to determine rate kinetics. "erform basic design and predict the operating performance of different types of reactors e.g. batch, continuous stirred tank and tubular flow reactors for single#multiple reactions under isothermal and non$isothermal conditions. pply the principles of catalytic reactions and design simple heterogeneous reactors. pply the knowledge of this sub'ect in carrying out chemical engineering pro'ects.

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4.0

METHODS OF INSTRUCTION (ectures and tutorials (ectures : % hours#week Tutorials : 1 hour#week

LESSON PLAN CHE594 CHEMICAL REACTION ENGINEERING

FACULTY OF CHEMICAL ENGINEERING UNIVERSITI TEKNOLOGI MARA

PAGE
&K DURATION T'()* 1 I+,-'./*,)'+ ,' C012)*34 R13*,)'+ E+5)+11-)+5 3+. R13*,)'+ K)+1,)*6 $ $ 1 1 *lassification of reactions +efinition of reaction rate ,lementary and non$elementary reactions -olecularity and order of reactions .inetic models for non$elementary reactions Temperature dependent term of a rate e/uation TOPIC/CONTENT

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ACTIVITIES 0ead C03(,1- 1 (L171+6()14 1verview of *hemical 0eaction ,ngineering 0ead C03(,1- 2 (L171+6()14 , .inetics of 2omogeneous 0eactions

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T'()* 2 D1,1-2)+3,)'+ '8 R3,1 L39 $ *onstant$volume of batch reactor $ Integral method of analysis of data $ +ifferential method of analysis of data $ -ethod of Initial 0ates $ -ethod of 2alf$(ives $ 3arying$volume batch reactor

0ead C03(,1- 5 (F'541- 4 *ollection and nalysis of 0ate +ata5 0ead C03(,1- ! (L171+6()14 Interpretation of 6atch 0eactor +ata 0ead C03(,1- ! (F'541- 4 0ate (aws and 7toichiometry 0ead C03(,1- 4 (L171+6()14 Introduction to 0eactor +esign

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T'()* ! S,')*0)'21,-)* T3:41 3+. M3,1-)34 $343+*1 $ 7toichiometric Table $ -aterial 6alance $ 0elationship between * and 8 *ase 1: *onstant density and flow systems *ase !: 6atch and flow systems of gases of changing density but with T and 9 constant.

LESSON PLAN CHE594 CHEMICAL REACTION ENGINEERING

FACULTY OF CHEMICAL ENGINEERING UNIVERSITI TEKNOLOGI MARA

PAGE
T'()* 4 D16)5+ '8 I.134 R13*,'-6 8'- S)+541 R13*,)'+6 $ Ideal batch reactor :605 $ 7pace$time and space$velocity $ 7teady state mixed flow reactor :-;05 $ 7teady state plug flow reactor :";05 $ 2olding time and space time for flow reactor $ 7i<e comparisons of single reactors T'()* 5 D16)5+ '8 M/4,)(41 R13*,'-6 3+. C'2(41; K)+1,)*6 $ ";0 in series and#or parallel $ ,/ual si<e -;0 reactors in series $ ";0 ? -;0 $ 0eversible 0eaction $ utocatalytic reactions ;ermentation *ombustion processes TEST 1 '+ T'()*6 1 ,' 5 T'()* < D16)5+ '8 M/4,)(41 R13*,)'+6 $ *oncept of selectivity and yield $ "arallel reactions Irreversible 1st order reactions in a ";0 B 60 Irreversible 1st order reactions in a -;0 "arallel reactions with other kinetics $ 7eries reactions Irreversible 1st order reactions in a ";0 Irreversible 1st order reactions in a -;0 -aximum yield of 6 in ";0 B -;0 T'()* > A+34@6)6 '8 N'+")6',01-234 R13*,'-6 $ 2eat of reaction $ ,/uilibrium constants from thermodynamics ,/uilibrium conversion ,ffect of temperature on e/uilibrium conversion at constant pressure $ ,nergy balance in an -;0 $ ,nergy balance in a ";0 $ 2eat removal or addition to maintain a reactor isothermal $ diabatic -;0 B ";0

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0ead C03(,1- 4 (F'541- 4 Isothermal 0eactor +esign 0ead C03(,1- 5 (L171+6()14 Ideal 0eactors for a 7ingle 0eaction 0ead C03(,1- < (L171+6()14 +esign for 7ingle 0eactions 0ead C03(,1- 4 (F'541- 4 Isothermal 0eactor +esign

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0ead :C03(,1- <= F'541- 4 -ultiple 0eactions5 0ead C03(,1- > (L171+6()14 +esign for "arallel 0eactions 0ead C03(,1- ? (L171+6()14 "otpourri of -ultiple 0eactions 0ead :C03(,1- ?= F'541- $ 7teady 7tate Don$isothermal 0eactor +esign5 0ead C03(,1- 9 L171+6()14 Temperature and "ressure ,ffects

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1C$11

LESSON PLAN CHE594 CHEMICAL REACTION ENGINEERING

FACULTY OF CHEMICAL ENGINEERING UNIVERSITI TEKNOLOGI MARA

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T'()* ? N'+").134 R13*,'-6 $ 0esidence time distribution $ 7tate of aggregation of the flowing stream $ ,arliness of mixing 1! 1

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0ead C03(,1- 11 (L171+6()14 6asics of Don$Ideal ;low 0ead C03(,1- 1! (F'541- +istribution of 0esidence Times for *hemical 0eactors

T'()* 9 S'4). C3,34@A1. R13*,)'+6 $ Introduction $ +esign of catalytic reactor $ 0eactors for determination of rate laws 1% 1 TEST 2 '+ T'()*6 5 ,' ?

0ead C03(,1- 1> (L171+6()14 2eterogeneous 0eactions Introduction 0ead C03(,1- 1? (L171+6()14 7olid *ataly<ed 0eactions

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1 ASSESSMENT

C03(,1- 10 S141*,1. I+./6,-)34 R13*,'- D16*-)(,)'+

*ase 7tudy and "resentation

Tests and ssignments : &CE ;inal ,xamination : =CE <.0 TEBT $OOK USED (evenspiel, 1. :1AAA5. Chemical Reaction Engineering :%rd ed.5. Dew Fork: Gohn Hiley. >.0 ADDITIONAL REFERENCES

;ogler, 2.7. :!CC=5. Elements of Chemical Reaction Engineering :%rd ed.5. Dew Gersey: "rentice 2all. Tinoco, Gr. I., 7auer, ..,Hang, G.*. B "uglisi, G.+. :!CC)5. Physical Chemistry:Principles and Applications in Biological Sciences :&th ed.5. "earson ,ducational International. 7mith, G.-. :1AA%5. Chemical Reaction Kinetics :%rd ed.5. -cIraw 2ill.
?.0 ADDITIONAL INFORMATION

LESSON PLAN CHE594 CHEMICAL REACTION ENGINEERING

FACULTY OF CHEMICAL ENGINEERING UNIVERSITI TEKNOLOGI MARA

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"lease make appointments for any consultancy. ttendance is compulsory. Do make up test will be given unless for medical excuses with legal documents presented. Do cheating in any aspect. Don$compliance will be met with the severest conse/uences.

PREPARED $Y: SIGNATURE: NAME: 15 D10 ; ,J 2 6IDTI I+0U7 !5 D102 7FI-I 6IDTI 0 2- T %5 72 0,,D ; I0UK 6+U( - D ; POSITION: (,*TU0,0 DATE: 9/9/2011 SIGNATURE:

APPROVED $Y:

NAME: *I. D10DIK 0 DU 0 POSITION: .,TU :.""5, *2,-I* ( 7*I,D*,7 DATE: 9/9/2011 "U7 T ",DI GI D D+ ,DIID,,0IDI