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ORGANIC CHEMISTRY

Daily Practice Questions

Sample DPQ
[Straight Objective Type] Q.1 Which of the following is correct order for the rate of SN1 reaction:
CH3 CCl (I) CH3

Time : 15 min.

(II)

H | CCl | CH3

CH2Cl (III) (IV)

CH2CH2Cl

(A) I > III > II > IV Q.2

(B) I > II > III > IV

(C) IV > III > II > I

(D) III > II > I > IV

Which of the following is most reactive towards aromatic nucleophilic substitution reaction. Cl (A) O2N NO2 NO2 (B) Cl (C)
NO2 Cl

Cl NO2 (D) NO2

Q.3

Which of the following will not give iodoform test (A) CH3CCH3 || O (B) CH 3CCl || O (C) CH3CHCH3 | OH (D) CH3CHCH3 | Cl

OH
Q.4

OHOH
Find the total number of optically active isomers. (A) 16 (B) 8 (C) 12 (D) 32

[Multiple Objective Type] Q.5 Which of the following is/are correct statement : (A) Wurtz reaction undergoes via free radical as well as ionic mechanism (B) Me3 CCl gives CH2 = CHCH3 as one of the product on reaction with Na/dry ether | CH3 (C) Me3CCOONa gives Me3CCMe3 as major on Kolbes electrolysis (D) CH3COONa give CH4 on heating with soda lime
1

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Q.6

Which of the following is/are not correctly matched OH | (A) CH3 CCH3 dil. NaOH CH CCH 3 2CCH3 || | || O CH3 O
O O || || (B) Cl3CCH conc. NaOH Cl3CCONa + Cl3CCH2OH

O O OH || || | (C) C6H5CCC6H5 (i)C onc.NaOH, C H CCOOH 6 5 (ii)H 3O | C6H5


CHO

(D) Q.7

O3 (i) A conc. NaOH (ii) Zn/H 2O

OH

Which of the following can reduce Fehling solution

CH2OH | (A) C=O | (CHOH)3 | CH2OH


O || (C) CH3CCH2OH

CH2OH O H H (B) OH HH H

CHO | (D) (CHOH)4 | CH2OH

[Comprehension Objective Type] Paragraph for question nos. 8 to 10 From the scheme given below answer the following questions : A (i) O3 Conc. NaOH X+Y (ii) H2O/Zn NaOI HCOONa + Z

Yellow ppt + CH3COONa Q.8 If Y is treated with PhMgBr followed by hydrolysis gives O

OH
(A) (B)

CH3 OH
(C)

CH 2OH
(D)

CCH3

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Q.9

Compound A is : CH3 (A) CH2 = CHCH2CH3 CH3 (C) C=CH2 CH3 (D) (B) C=CHCH3 CH3 CH3 C=CHPh CH3

Q.10 Correct statement about Y is (A) it can reduce Tollens reagent (C) it can react with 2, 4 - DNP Q.11 (B) it gives isocyanide test (D) All are correct

[REASONING TYPE] Statement-1 : Optically active compound has chiral center. Statement-2 : All chiral molecules are optically active. (A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1. (B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1. (C) Statement-1 is true, statement-2 is false. (D) Statement-1 is false, statement-2 is true. Q.12 Statement-1 : Benzaldehyde gives red ppt of Cu2O with fehling solution. Statement-2 : Generally compound containing CHO group can reduce fehling solution (A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1. (B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1. (C) Statement-1 is true, statement-2 is false. (D) Statement-1 is false, statement-2 is true.

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