CHEMISTRY

Class : II IIT-JEE Achiever /Medical Excel 2012-2014 Practice Paper - 01 Max. Marks Duration Date 70 marks 3 hrs 15 min 24-01-2014

Instructions 1. The questions paper has four parts: A, B, C and D. All parts are compulsory. 2. Write balanced chemical equations and draw labeled diagrams wherever required. 3. Use log tables and the simple calculator if necessary. (Use of scientific calculators is not allowed). PART - A

I. Answer ALL of the following (each question carries 1 mark) 1. What type of semiconductor is obtained if germanium is doped with indium? 2. What is a colligative property? 3. Define boiling point of a liquid.

[10 1 = 10]

4. How many faradays of current is required to produce 40 g of calcium from molten CaCl2? (Atomic mass of Ca = 40). 5. How does adsorption of a gas on a solid vary with temperature? 6. Name the carbon reduction process of extraction of a metal. 7. How is xenon hexafluoride prepared? 8. Arrange the following in the order of increasing boiling points of the following: Bromoethane, chloroethane, iodoethane. 9. Name the product formed when acetaldehyde reacts with excess of ethanol in the presence of dry hydrogen chloride. 10. How do you show the presence of carbonyl group in glucose is an aldehyde group?
PART - B

II. Answer any FIVE of the following (each question carries 2 marks) 11. Calculate the packing efficiency in a simple cubic close packed structure.

[5 2 = 10]

12. The equivalence conductances of NaCl, HCl and CH3COONa at infinite dilutions are 126.5, 426.0 and 91.0 S cm2 eq 1 respectively at 25 C. Calculate the equivalent conductance of acetic acid at infinite dilution. 13. In a chemical reaction in gas phase 2A 4B + C, the concentration of B is found to increase by 3 1 5 10 mol L in 10 seconds. Calculate (i) the rate of appearance of B and (ii) rate of disappearance of A.
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14. Transition metals form complex compounds. Explain. 15. Illustrate hydroboration - oxidation with an example. 16. Explain Rosenmunds reduction with an example. 17. What are tranquilisers? Give an example. 18. What are anionic and cationic detergents? Give one example for each.
PART - C

III. Answer any FIVE of the following (each question carries 3 marks) 19. Give the principles of refining of metals by the following methods (i) Liquation (ii) Zone refining (iii) Vapour phase refining.

[5 3 = 15]

20. Discuss the trends in chemical reactivity of group 15 elements with oxygen. 21. (a) Complete the following sequence of reactions (i) PbS + O3 (ii) SO 2 MnO 4 H 2 O (b) Write the structure of peroxodisulphuric acid. [2] [1]

22. (a) Arrange the oxyacids of chlorine in the order of increasing acid strength and write the structure of the strongest acid. (b) How is bromine pentafluoride prepared? 23. Account for the following (a) Transition metals exhibit variable oxidation states. (b) Transition metals and most of their compounds are paramagnetic. (c) Zn, Cd and Hg are called non-transition metals. 24. What is lanthanide contraction? Explain the causes and consequences of lanthanide contraction. 25. Explain bonding in CoCl3.5NH3 on the basis of Werners theory. 26. Give the IUPAC name of [CoBr2(en)2]+ and write the structures of cis and trans isomers.
PART - D

[2] [1]

[3] [3] [3] [3]

IV. Answer any THREE of the following (each question carries 5 marks)

[3 5 = 15] [3] [2]

27. (a) What is close packing arrangement: Discuss briefly hexagonal close packing arrangement. (b) Explain ferromagnetism with an example.

28. (a) What are non-ideal solutions? With graphical representation explain non-ideal solutions showing negative deviation with an example. (b) State Henrys law. What is the effect of pressure on the solubility of gas in a liquid? 29. (a) Explain the electrochemical phenomenon of corrosion taking rusting of iron as an example. [3] [2] [3]

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(b) Give the cell reactions for a lead storage battery when the battery is in use.

[2]

30. (a) Explain the effect of temperature on the rate of a reaction based on the concept of activation energy. [3] (b) Give any two differences between molecularity and order of a reaction. 31. (a) Explain the mechanism of Micelle formation and Cleansing action of soap. (b) Give the reaction of chlorobenzene with acetyl chloride in the presence of anhydrous AlCl3. V. Answer any FOUR of the following (each question carries 5 marks) 32. (a) Explain SN1 mechanism with a suitable example. (b) Give the reaction of chlorobenzene with acetyl chloride in the presence of anhydrous AlCl3. 33. (a) Give equations for the following reactions (i) oxidation of 1-propanol with alkaline KMnO4 solution. (ii) nitration of phenol with nitrating mixture. (iii) acetaldehyde with CH3MgI followed by acidification. (b) Explain why o-nitrophenol is more acidic than o-cresol. [3] [2] [2] [3] [2]

[4 5 = 20] [3] [2]

34. (a) An organic compound A of molecular formula C7H6O gives a yellow solid with 2,4-DNP and reduces Tollens reagent to a bright silver mirror. The compound A on treatment with conc. NaOH solution gives B (C7 H 6 O 2 [3] Na ) and C(C7H8O). Identify A, B and C. (b) Explain the relative reactivity of ethanal and propanone towards nucleophilic addition reactions. [2] 35. (a) How are the following conversions effected? (i) ethyl amine to ethyl alcohol. [3] [2] [3] [2] [3] [2] (ii) aniline to phenyl isocyanide (iii) benzene diazonium chloride to chlorobenzene. (b) Explain Hoffmans bromamide reaction with an example. 36. (a) Describe briefly about (i) primary, (ii) secondary and (iii) tertiary structure of proteins. (b) What is a nucleotide? Give an example. 37. (a) What are condensation polymers? Give the synthesis of nylon-6,6? (b) What is difference between thermoplastics and thermosetting plastics?

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