454u1
Percubaan
SPM
Chemistry
2OO9 PEPERIKSAAN PERCUBAAN
Paper1 SIJIL PELAJARAN MALAYSIA
1%hours NEGERI PERAK
2009
CHEMISTRY
PAPER 1
1. Kertassoalanini adalahdalamdwibatnsa
2. SoalandalambahasakrggerismendahuluisoalanyangsepadandalamBahasaMelayu.
3. Calondikehendakimembacamaklumatdi halamanbelakangkertassoalanini.
A Treafuentof cancer
Rawatancancer
B Desftoybacteriain food
Memusnahkanbaheria dalam malmnan
C Estimatethe ageof fossils
Menganggarlmnumurfosil
D Studythe metabolismof fertilisersin plant
Menglmji metabolismabaja dalam tumbuhan
Diagram1
Rajah I
Whichof the following is true aboutfluorineatom?
Antara berilafi,yang manakahbenar tentangatomfluorin?
Numberof electons Nucleonnunrber
Bilangan elektron Nombor nukleon
A9 10
B9 19
c l0 t9
D19 28
What is an electolyte?
Apalrah elehrolit?
A Substancesthat conductelecticity in moltenstateand aqueoussolution.
Bahanyang mengalirlmnelehrik dalam keadaanleburan dan larutan ahtes
B Ionic compoundthat conductelecticity in all physicalstates.
Sebatianionik mengalirkanelektrik dalam semuakeadaanfizik
C Substancesttrat cannotconductelecticity.
Bahan yang tidak boleh mengalirkanelektrilc
D Non metalthat canconductelecticity.
Bulran logam yang boleh mengalirkanelektrik.
represent
Whichof the following chemicalequations nzutalization?
Antara persamaankimia berihtt yang manakahmewakilipeneutralan?
A Zn + 4SOo -+ ZnSO4+ H2
B AgNO, + HCI -+ AgCl + HNO3
C 2NaOH + HrSOo+ NqSOo + 2HrO
D CaCO,+ H2SO4 + CaSOo+ H2O+ CO,
10 Substance
X + Sulphuricacid -) Salt Y + Water + Carbondioxide
What is substance
X?
BahanX + asid sulfurik + GaramY + air + karbondioksida
Apalrah bahan X?
A Copper(Il)oxide
Kuprurn (II) oksida
B lvlagnesiummetal
Logarnmagnesium
C Zinc carbonate
Zink karbonat
D Sodiumhydroxide
Natrium hidroksida
15
Coconutoil + Sodiumhydroxide ----+ A + Soap
Minyak kelapa + Natrium hidroksida + A + Sabun
Whatis A?
ApakahA?
A Ethane
Etana
B Ethanol
Etanol
C Glycaol
Gliserol
D Sodiumethanoate
Natrium etanoat
A EnergylTanga
N, + 3H,
Energr/Tenaga
AH: - 45 kJ
Enerry/Ternga
AH = -45 kJ
Nr* 14
EnerrylTenaga
AH = -45 kJ
Tl
Time /min
Masa /min
D@nrn2
Rajah 2
Which of the following statements canbe deducedfiom Diagram2?
Antara pernyataan berihtt, yang manalmhboleh disimpullcandaripada Rajah 2?
A Themeltingpoint of X is I
Takatlebur X ialah T,
B Substance X is a liquid at t, to !
BahanX adalah cecair pada t, hingga t,
C Heat energyis absorbedfrom 0 to t
Tenagahaba diserap daripada 0 ie t,
D Kinetic enerry of particlesdecreases from ! to t,
Tenagakinetik zarah berhtrang daripada trke t,
Carbon
Karbon
0.1 mol dm-3Copper(Il)sulphatesolution
Larutanfuprum(Il) sulfat 0.1mol dm-3
Dagram3
Rajah 3
Which ion that will be dischargedat the anode?
Ion manalrahyang akan dinyahcaskandi anod?
A Copper(tr) ion.
Ion htprum (II).
B Sulphateion.
Ion sulfat
C Hydroxideion
Ion hidroksida.
D Hydrogenion.
Ion hidrogen.
Dagram 4
Rajah 4
Identifythe solutionY
Kenal pasti larutan Y
A hon@ sulphate
Ferum(II) sulfat
B Lead@ sulphate
Plumbum(Il)sulfat
C kon(Itr) nitate
Ferum(Ill nitrat
D Zinc nitate
Zink nitrat
31 Diagmm5 strows curveT obtainedfrom the decomposition of 50 cm3of 1.0mol dmi hydrogen
oxide powderas a catalyst at 300C.
peroxidesolutionby using 5 g of manganese(IV)
Rajah 5 menunjuLfantengtang T yang diperolehi daripada penguraian 50 cm3 larutan
hidrogenperopsida I.o mit dmi menggunakan5 g serbuk mangan (IV) oksida sebagai
mangkinPada suhu 3UC
Volumeof gas/ cnf
Time/ s
Masa / s
DiagrafiI 5
Rajah 5
Which of the following changesof reactingconditionsmustbe doneto obtaincurveS?
Antara perubahan keadaan tindak balas berikut yang manakah mesti dilalatkan untuk
menghasilkanlenghtng S ?
A Increasethe temperatureup to 600C
Tinglmtkansuhu kePada6UC
B Use 3 g manganeso(It/)oxide powder
Gunakan3 g serbukmangan(IV)oksida
c use 100cm3of 1.0mol dm-3hydrogen peroxidesolution.
Gunakan 100cm3larutan hidrogenperoksida1.0 mol dm3
D Add 50 cm3of distilledwaterinto the solution
Tambahlcan 50 cm3air suling ke dalam larutan
33 A studentfound that an iron nail left in a beakerof geldin" rustsafter a few days.How the rate
ofrusting can be reduced?
Seorangpelajar mendapatipaht besi berkarat, selepasdibiarkan di dalam bikar yang
mengandungigelatin selama beberapa hari. Bagoimanakah kadar pengaratan dapat
dihtrangkan?
A A few dropsof phenolphthaleinis added
Beberapatitisfenolphtaleindimasukkon
B The beakeris kept awayfrom the sunlight
Bilrar diletaklwnjauh daripada cahayamatahari
C The beakerof gelatinis coveredwith a pehi dish
Bilrnr yang tnengandungigelatin ditutup denganpiring petri.
D Zinc powderis addedto the gelatinbelorethe experiment.
Serbukferum dimasukkankepadagelatin sebelumelaperimen..
36 Thefollowinginformationis aboutatomW
Maklumat berikut adalah tentang atom W
Diagram6
Rajah 6
Whichof the followingdiagnmsshowsthe electonanangement
for tlre compoundformedbenveen
atomsR and S?
Antara raiah berikut yang manakah menunjukkansusunanelektron bagi sebatianyong
terbentukantara atom R dan S?
O O Q
B
CI o
')-
c
l-
tl
O tt
ilt t
tt ol O
D
oo Q
454u1 [Lihat sebelah
ST]LIT
16 454lll
SI]LIT
electoplate an iron
4l which of the following diagramsshowsthe correctset-upof apparatusto
key with silver?
yang betul untuk
Yang manakah antara raiah berikut menunjukkansusunon radas
menyadurkan palat besi denganargentum?
A
Silver
Argentum
Silvernitate solution
Iron key
Larutan argentumnitrat
Kunci besi
Silver
Argentum
Silver
Argentum
Silver
Argentum
454Lll SI]LIT
SULIT t7 4l4ttl
45 What is the massof zinc sulphatethat canbe preparedby addingexcesszinc with 50 cm3of 1.0
mol dma sulphuricacid
Apalrahjisim zink sulfat yang boleh disediaknnapabila zink berlebihanditambahkankepada
50 cm3asid sulfurih L0 mol dm-3
[Relativeatomicmass: O, 16 ;5,32 ; Zn, 65]
[Jisim atom relattf : O, 16 ; S, 32 ; Zn, 65J
A 6.50g
B 8.05g
C 11.45g
D 1 6 . 1 0g
Time/ min 0 I 2 a
J 4 5
Masa/ min
Volume of hydrogen gas / cmj 0.0 15.0 25.0 30.0 3 3 . 0 3 3 . 0
hipadu gas hidrogen/ cm3
Table3
Jadual 3
What is the averagerateof reactionin the third minute?
Berapakahkadar tindak balaspurata dalam minit ketiga?
A 0.067cm3s -r
B 0.083cm3s -l
C 0.110cm3s -1
D 0.167cm3s -r
48
Propanolreactswith ethanoicacid in the presenceof concentated
sulphtnicacidto form compowd Z.
Propanol bertindak balas denganasid etanoik dalam kehadiran asid
sulfurik pelmt bagi menghasilknnsebatianZ.
2. Answerall questions.
Jawab semua soalan,
454u1
ST]LIT
SI.ILIT 4s4tn
NAMA:
454u2
Percubaan NO. ANGKA GILIRAN:
SPM
Chemistry
2009 PEPERIKSAAN PERCUBAAN
Paper2
ZYzhouts
SIJIL PELAJARAN MALAYSIA
NEGERI PERAK
2009
CIIEMISTRY
Paper 2
[60 marks]
[60 markah]
ao*.. all questionsin ttris section.
Jautabsemaa soalan dalam balwgian ini.
Diagram1.1 showsthe soapanionwhich consistof trvo parts,part A and part B.
Rajah I.I menunjuklan anion bagi sabunyang mempunyaidua bahagian, bahagianA dan
balngian B
o
tl
A:
B:
12marksl
[2 marlwhJ
ll markl
ll marlwhl
I marlcl
fl marlwhl
CREAn||Y
NilAltGiAR,T}rF,
IhI(3REDIEhITS : Palrn
OiI , Palrrr l(ernel Oil,
Lechitin
hoductby, Lb€st Cmpng
ExpiryDatel0l0?010
Diagram1.2
Rajah1.2
I marlfl
ll markahl
G) Statethetunctionof foodadditivein (bxt.
Nyatakanfungsi bahantambahmalwnandalam(b)(r.
ll markl
[l marlwhl
ll markl
ll marlwhl
ll markl
I markahl
ll markl
I marlmhl
ll markl
ll marlwhl
CDStateone usageof P.
Nyatalrnnsatu kegunaanP
ll markl
ll markahl
(b) What is the nameof the positively chargedsubatomicparticle found in the nucleusof an
afiom?
Apakah nama zarah subatomyang bercaspositif yang terdapat dalam nukleussuatu
atom?
fi markl
ft markahl
(c) Statettre numberof valenceelectonsof atomP.
Nyatalrnnbilangan elektron valens bagi atom P
fi markl
ll marknhl
@ Writethe standard
representation
of oneof theisotopes
abovein the form of i X .
ll markl
ll markahl
(e) Magnesiumreactswith oxygento form a compourd.
Magnesiumbertindakbalasdenganoksigenuntuk membentuksuatu sebatian.
0) Write a balancedchemicalequationfor the reaction.
Tuliskanpersamaankimia yang seimbangbagi tindakbalastersebut
[2 marks]
12 markahl
[2 marlcs]
12 morkahl
4541n [Lihat sebelah
SIJLIT
SLILIT 6 4|.4tn
3 Table3 slrowsthe pH valueof four solutionsW, & Y and Z wrthconcentationof 0.1 mol
dmr
Jadual 3 menuniukknnnilai pH bagi empatlarutan W, X, Y clanZ yang berkepepatan
0.1 mol dm;.
Solution pH valtre
Larutan Nilai oH
w I
X 5
Y 7
Z t4
Table3
Jadual 3
(a) Basedon the informationin Table3,
Berdasarlwnmaklumatdalamjadual 3,
G) Which solutiontums a blue litnus paperto red?
Larutan manalcahdapat menukarkankertas litmus biru kepadamerah?
ll mark)
ll markahl
(i) Wthout uslngan indicator,describea chemicaltestto verify the answerin (aXr).
Tanpamenggunakansuatupenunjulc,huraikan satu ujian kimia untuk mengesahkan
jawapan dalam (a)(t).
12marlal
12markahl
(if Which solutionis a stong acid?
Larutan manakahmerupakansuatu asid kuat?
ll markl
ll markahl
(b) z reactswith sulphuricacidto form sodiumsulphateand water.
Z bertindakbalas denganasid sulfurik untuk menghasilknnnatrium sulfat dan ain
() Statettre ttane of Z.
Nyatalmn nama bagi Z.
ll marlQ
ll markahl
[3 marks]
[3 marlmh]
(c) By referringto Table3, which solutionpossiblycanbe sodiumsulphate?
Dengan meruiuk Jadual 3, larutan manakahberkemungkinannatrium sulfat?
ll markl
fi marknhl
Diagram4 showsa simplecell usingzinc and copperas the electodesand blue solutionof X as
the elecftolyte.The readingof the voltneter is 1.8V.
Raiah 4 menuniukkansatu sel ringkas menggunakanzink dan kuprum sebagai eleknod dan
larutan biru X sebagaielektrolit.Bacaanvoltmeterialah I.8V
Voltrneter
Diagrarn4
Rajah 4
(a) h Diagmm4, showthe directionof the flow of electons.
Dalam Rajah 4, tandalranarah aliran eleloron.
ll markl
ll narkahl
(b) Which metalreactsas the negativeternrinal?
Logam yang manalmhbertindak sebagaiterminal negatiJ?
ll markl
} marlmhJ
(c) Whatis the enerry changein the cell above?
Apalrahperubahan tenagadi dalam sel di atas?
ll markl
ll markahl
454rn [Lihat sebelah
SULIT
ST]LIT 8 4s4tn
(d) Namethe ion that givesthe blue colourof solutionX.
Namakanion yang memberikanwarna biru larutan X.
ll markl
ll markahl
(e) G) After a few minutes,the copperrod becomesthicker.Give a reason.
Selepasbeberapaminit, rod laryrum menjadi tebal. Berikan satu sebab.
ll nark)
fl marlcahl
c)Write a half equationfor yotr answerin (exl).
Tulislransetengahpersamaanbagijowapan anda di (e)(i).
ll markl
$ narkahl
(/) G) Statethe changein the readingof the volfineterif zinc rod is reptacedby magnesium
rod.
Nyatalcan perubahanyang berlaht kepadabacaan voltmeterjilca rod zink diganti
denganrod magnesium?
ll markl
I markahl
(i) Explainyouranswerin (r(t.
jawapanandadi (fl(i).
Jelaslran
12marksl
12markahl
@) Write the over:allionic equationfor the cell.
Tttlislran persarnaanion lceseluruhanbagi sel
II markl
ll marlwhl
4541n, [Lihat sebelah
ST]LIT
sulrr g 4541n
5' Two setsof experimentare carried out to study the effect of catalyston the
rate of reaction
betweenzinc and sulphuricacid.
Dua set eksperimendijalankan untuk mengkaii lcesanmangkin terhadap pndar
tindak balas
antara zink dan qsid sulfurik
Table5
Jadual 5
fl markl
ll markahl
4541n
[Lihat sebelah
STJLIT
SULIT 10 414ln
12marksl
12marlmhl
(c) Writea chemicalequationfor thereactionbetween
zincandsulphuricacid.
Tttlislranpersamaankimia bagi tindakbalasantarazink denganasid sulfurik
12marksl
12markahl
12marks]
12markahl
ff Experiment
II
Eksperimen
II
12 marlcsl
p. narkahl
(i| Comparethe averagerate of reactionfor the first three minutesof ExperimentI and
ExperimentII.
Explainhow catalystaffece the rateof reactionby usingthe collisiontheory.
BandingltanImdar tindak balas purata bagi tiga minit pertama untuk Epsperimen
I dan EksperimenII.
Tbranglmnbagaimana mangkin mempengaruhikadar tindbk balas menggunapan
teori perlanggaron.
13marlal
13markahl
4541n
[Lihat sebelah
ST]LIT
ST'LIT t2 4541n
Ethyl propanoate
Etil propanoat
+
Water
Air
Diagram6
Rajah 6
Basedon diagram6,
BerdasarlranRajah 6,
(a) Statettre nameof reaction1.
Nyataknn nama bagi tindak balas L
II marlcl
ll markahl
(6) Statethe nameof catalystP.
Nyatalrannama bagi mangkinP.
ll markl
ll narkahl
(c) Statethe nameof the compourdX whenCrHureactswith chlorine.
Nyatakannama sebatianX apabila Cflo bertindak balas denganklorin.
, ll markf
fl marlwhl
4541n [Lihat sebelah
SI'LIT
SULIT 13 45412
@ compoundz is an
{cohol and canbe producedfrom fermentationprocess.
SebatianZ merupalmnsuatu alkohol dan boleh dihasilkan melalui prosespenapaian.
write the chemicalequationfor a completecombustionof compoundZ.
rblislran persamaanki.miabagi pembakaranlenglap sebatian Z,
12marksl
12markahl
(e) G) haw the sfirch'al formtrlaeof two isomersof compoundy
Statethe nameof the isomers.
Lukislwnformula struktur bagi dua isomer sebatian y
Nyatakan nama bagi isomer-isomeritu.
14 marksl
[4 markah]
(i) CompoundY undergoes oxidationreactionby usingacidifiedpotassiummanganate(Vtr),
Klvftrq solution.
Statettre observationfor the reaction.
Sebatian Y menialani tindak balas pengoksidaandengan menggunalcan
larutan
lulium manganat(VII), KMnOoberasid.
Nyatalcanpemerhatian bagi tindak balas itu.
ll markl
ll narlwhl
U) Statethe homologousseriesfor ethyl propanoate.
Nyatalrnn siri homolog bagi etil propanoat.
ll marlcl
ll marlwhl
4s4rn
[Lihat sebelah
ST]LIT
ST]LIT 14 4541D
SectionB
Bahagian B
120marksl
120marlcahl
Answerany one questionfrom this section.
Jowab mana-manasatu soalandaripadabahagianini.
(a) Describethe mechanismof rusting.
Your descriptionshould include the followings:
Huraikan melmnismaPengaratan'
Hur aian anda hendaklah mengandungip erlrara-perkara berikut
o a labelled diagram
rajah berlabel
o half equationsthat take place at the positive terminal
(the edge of water droplet) and the negativeterminal
setengahpersamaan yang berlaku pada terminal positif
(pada hujung titisan air) dan terminal negatif'
l7 marksl
[7 marknh]
Metal
Metal P Metal Q
Logam
Logam P Logam Q
Diagram 7
Rajah 7
Testtube A B C
Tabunguji
ST]LIT L6 4541n
0 9 l9
R 6 L2
Tiable8
Jadual 8
of atomsQ and R.
(a) G) Write the electronarrangement
Tuliskansusunanelectron bagi atom Q dan R.
f2 marlal
12markahl
(c) Statetlre changeof the reactivityof Group 1 and Group 17 elementsin the PeriodicTi$le
wtrengoingdown the grouP.
Explainyorrranswer.
Nyatakanperubahan kereahifan unsur-unsurkumpulan I dan lrumpulan17 dalam
Jadual Berkala (Jnsurapabila menurunikumpulan.
Teranglcan j awapan anda.
l8 marlnl
[8 marlwhl
SectionC
Bahagian C
120marksl
120markahl
Answerany one questionfrom this section.
Jawab mana-manasatu soalan daripada bahagian ini.
sodiumcarbonatesolution necessaryapparatus
Iarutan natrium karbonat radasyang sesuai
Energg
Tenaga
AH=+xkJmol' r
Diagram10
Rajah I0
Er\D OF QUESTIONPAPER
KERTASSOAI./IN TAMAT
454u2 [Lihat sebelah
SI]LIT
SULIT 19 4541n
3. fuiswer one questionfrom SectionB and one questionfrom SectionC. Write your answersfor
SectionB and SectioinC on the lined pagesat the end of the question paper.Ansner questions
in SectionB and SectionC in detail.You may usequestions,diagrams,tables,gfaphsand other
suitablemethodsto explainyour answer.
Jawab satu soalan daripada Bahagian B dan satu soalan dari Bahagian C. Tulisjnvapan
bagi Bahagian B dan Bahagian C pada helaian tambahanyang dibekalkanoleh pengcMas
peperiksaan.Javtab soalan dalam Bahagian B dan Bahagian C dengan terperinci. Anda
boleh menggunaknnpersamaan, rajah, jadual, graf dan cara lain yang sesuai untuk
menjelaskanjawapan anda.
4541n
STJLIT
ST]LIT 4s4u3
NAMA:
454u3
Chemisfi
Kertas 3 NO. ANGKA GILIRAN:
Peperiksaan
Percubaan
2009 PEPERIKSAAN PERCUBAAN
1%hours SIJIL PELAJARAN MALAYSIA
NEGERI PERAK
2009
CHEMISTRY
KIMIA
PAPER3
KERTAS3
Onehour andthiny minutes
Satujam tiga puluh minit
J. Calon dikehendakimembacamaklumatdi
halamanbelalwngkertassoalan ini.
Step 3 The weight was droppedso that it hit the ball bearing.
Langkah 3 Pemberatitu dijatuhlcansupayamenghentambebolakeluli tersebut.
Step4 The diameterof dent madeon the copperblock was measuredand the reading
was recorded.
Langkah 4 Diameter lekukyang terbentukpada bongknhkuprum diukur dan bacaanrrya
direlndkan.
Step 5 Step I to step4 was repeatedtwice on the other parts of the samecopperblock
in orderto obtainthe averagediameter.
Langkah 5 Langkah I hingga 4 diulang sebanyakdua kali lagi atas bahagian lain
bonglmh htprum yang sama untuk mendapatkan purata diameten
Step6 Step I to step 5 was repeatedby replacingthe copper block with the bronze
block.
Langkah 6 Langlmh t hingga 5 diulang denganmenggantikanbongkah htprum dengan
bonglrahgangsa.
Thread
Benang
Weight
Pemberat
Copperblock
Blok kuprum
Diagram1.1
Rajah1.1
Steelball bearing
Bebola keluli
Crosssectionview
Pandangansisi
Copperblock
Bonglrah htprum
Top view
Pandangan daripada atas
Diagnm 1.2
Rajah 1.2
D i a m e t e: r.............cm : .............cm
D iameter Diam eter
: ........... ..c m
Diagram1.2(a)
RajahL2 (a)
n
D i a m e t e: r.............cm D iameter
: .............cm Diam eter
: ........... ..c m
Diagram1.2(b)
RajahL2 (b)
(a) By using a rulel measurethe diameterof dentsand recordin the spacesprovided.
Dengan menggunakanpembaris, uhtr diameter lelwk dan catatkanpada ruang yang
disediakan.
13marksl
13narkahl
454u3 [Lihat sebelah
ST]LIT
SI]LIT 4S4tB
[3 marlcsl
[3 markahl
(c) Calculatethe averagediameterof dentsor\
Hitungknn nilai purata diameter lefuk pada,
G) Copperblock
Bonglcahhtprum
(i) Bronzeblock
Bongkahgangsct
[3 marksl
13markahl
(d) G) Stateoneobsenration fromthis experiment
thatcanbe obtained .
Nyatakansatupemerhatianyang ini
dapatdiperolehdaripadaeksperimen
13marksl
13marlcahl
13 narksl
[3 marlwh]
4S4rR pihat sebelah
$ruT
$ruT 4541/6
13marksl
[3 markahl
13marlcsl
13markahj
13marksl
13narkahl
13marksl
13narlahl
[3 marksl
13 marlwhl
[3 marlal
13 marlwhl
Plana laboratoryexperiment
to investigate
ttreeffwt of concentationof chlorideion on the selective
dischargeat the anode.
Rancang satu eksperimenmakrnal untuk mengkaji kesan kepekatanion klorida dalam
pemilihan nyahcaspada anod.
Yourplamingshouldincludettrefollowingaspects:
Perancangananda hendaklahnengandungi aspek-aspek'
berilafi:'
(a) Statementof the problem
Pernyataanmasalah
(6) All the variables
Semuapembolehubah
(c) Statementof the hlpothesis
Pernyataanhipotesis
(ra)List of substances
and apparatus
Senarai bahan dan radas
(e) Procedureof the experiment
Prosedureksperimen
(fl Tabulationof data
Penjadualandata
ll7 marksl
ll7 narlwhl
7. If you wish to changeyour answer,crossout the answerthat you have done.Then wite down
the new answer.
Jila anda hendak menular javtapan, batallan jawapan yang telah dibuat. Kernudiantulis
jawapan yang baru.
scientificcalculator.
You mayusea non-programmable
Anda dibenarknnmenggunalwnkalhtlator saintifik yang tidak boleh diprogram.
454U3
STJLIT
SULIT 4s4It3
PEPERIKSAANPERCUBAANNEGERIPERAK
SIJILPELAJARANMALAYSIA
2009
SKEMAPEMARKAHAN
CHEMISTRY
4541t1
4541t2
4541t3
4541/3 SULIT
JAWABAN KERTAS1 : PERCUBAANSPM2OO9
)
MARKING SCHEME PAPER2
TRIAL EXAM 2OO9
No Answer Mark
I (a) (i) A hydrophobic// hydrocarbon I
B an anionic // hydrophilic I
(ii) B // hydrophilic I
(b) (D Lechitin I
Total 9
t2 14
cll c
66
2Mg + Oz 2MgO
-
andproducts- I
-correctformulaeof reactants
t-,,
1
1+1
-coffectnumberof shellsandnumberof electronsfor Me and
O-1 ma rk
-correctchargesfor Me andO - I mark
Total 9
a
J (a) (i) wllx I
(ii) - W is addedinto sodiumcarbonate/any metalcarbonatestated l+ l
in a testtube,
- Gasreleased turnslime watercloudy
// - magnesiumlzincis addedinto W in a testtube,
- gasreleased givesa'pop' soundwith a liehtedsplinter
(iii) w I
(b) (i) Sodiumhydroxide I
(ii) 2NaOH + HzSO+ --+ Na2SO4 + 2H2O l+l+ 1
- Correct formulae of reactants
- correct formulae of products
- Balancedequation
(iii Y 1
Total 9
Total l0
(b) 1. Functionaldi I
2.Label I
Sulphuric
It
t-P
(c) 7-n + HzSO+ ZnSO++ rh l+ 1
- Correct formulaeof reactants
- correctformulaeof products
(d)
1.Correctnumberof molof sulphuric
acid I
2. Conectthema:rimumvolume 1
0.0025x24 ll 0.06dm3ll
0.0025x24000 ll 60 cm3
(e) (D Experiment
I.
40.0 ll 0.2222cm's-r
180 I
- Conectanswerwith unit
(ii) ExperimentII
52.0 ll 0.2889cm3s-r
180 I
- Correctanswerwith unit
(iii) The averagerate of reactionfor experimentII is higher 1
than experimentI.
Catalystreducethe activation energy. I
More colliding particlesare able to achievethe lower I
activation energyto increasethe frequencyof effective
collision.
Total t2
-l
6 (a) Addition reaction/ hydrationi'eaction I
(b) Phosphoric
acid I
HH H
ttl
Fl-c-c-c-oH
tll
HH H
I
Propan-2..ol''
TI T
H-C-C-C-H
I
'l J',l I
(0 Ester I
Total 11
(
MARKING SCFIEMEPAPER2 SECTIONB AND C
7 (a)
Negativeterminal/lanode: Fe ) Fe2*+ 2e I
PositiveterminaVlcathode: 02 *2HzO +4e ) 4OH- I
iron(I[) ionsproducedcombinedwith thehydroxideions I
to form Fe(OH)z/ iron(Il) hydroxide I
Fe(OH)zis oxidizedby oxygento form rust/ Fe2O3 I
x.H2O
7
(b) (D usingprotective coating: oil/ paintlplasticsI galvanizingl I
tin plating
(iD Alloying : stainless steel- carbon* chromium+ nickel I
(iii) Sacrificialprotection.- iron is attached
to the sacrificialmetal 1
which is moreelectropositive thaniron
-Correctmethodwith example a
J
1
8 (a) (i) l.Theelectronarrangement of atomQ:2.7112,7 1+l
2.The electronarrangement of atomR:2.4112.4 2
(ii) l.The numberof neutronsin atomR is 6 1+1
2.Thenumberof electrons in atomO is 9 2
o) 1.QandR form covalentbond. I
2.AtomQ hasanelectronarrangement of 2.7112,7 I
3.AtomR hasan electronarrangement of 2.4112,4 I
4.Toachievethe stableelectronarrangement, [atom]R I
shareselectronswith [atom]Q.
5.One[atom]R contributes 4 electrons. I
6. Each[atom]R contributes oneelectron. I
7. [Atom] R sharesfour of its valenceelectronseachwith 4 I
atomsof Q
8. moleculewith the formulaRQa.
I
'@l
@
6 [c)
:E
Notes: points4,7 and8 canbeobtainedfrom the diagram
8
(c) For group I elements.
1. Going down the group ,atomic size increases//the
valenceelectronbecomesfurther away from the
nucleus I
2. Forcesof attractionbetweenthe protons/ nucleusand I
the valenceelectronbecomesweaker.
3. It is easierfor the atom to donate/ releasethe valence I
electrons.
4. The reactivity increasesdown the group // 1
reactive
Reactivity increaseslN4ore
Lithium,Sodium,Potassium,Rubidium,Caesium,Francium// I
L i ,N a , K, Rb, Cs, Fr
For Group17elements.
l.Atomic sizeincreases whendescendingthe group//the I
valenceelectronsbecomefurtherawayfrom nucleus.
2. Forcesof attractionbetweentheprotons/ nucleusandthe I
valenceelectronsbecomeweaker
3.It is moredifficult for theatomto acceptlgainheceive I
electrons.
4.Thereactivitydecreases downtheGroup// I
\
0
Reactivityincreases/\4ore
reactive
Fluorine,Chlorine,Bromine,Iodine,Astatine
max 8
Total 20
Total 20
Ll
I
No. Markine Scheme Mark
Result:
oC
10. Initial temperatureof water = tr
oC
Highesttemperatureof water: t2
Increasein temperature : ( tr -tz) oC: T oC
Calculation:
12.Numberof molesof [alcohol]= (mr-JItt = n
molar massof [alcohol]
13.Heatchange=250x4.2x T = Q J
14.Heatofcombustion=Q
- J mo l-r ll -Q k J mo l-l
n nx 1000 t2
Total 20
1t
OUESTION ANSWER SCORE
I (a) 1 .4 ,1 .5 ,1 .3
0 .9 ,0 .8 ,0 .9 a
J
l(b)
Diameterof dent/ cm
I ll lll J
differentsizesdisturbthe orderlyarrangement
of atomsin
the metalandits reducethe layerof atomsfrom sliding.
bronze
l(e)
Puremetal Alloy
a
J
lr
OUESTION SAMPLE AI\SWER SCORE
2 (a) How doesthe concentrationof chloride ion/solution. affect the
product at the anode/ electrode? a
J
durationof electrolysis
Apparatus: Batteries,carbonelectrodes,connectingwireswith
crocodileclips,electrolyticcell,testtubes,
litmuspaperandwoodensplinter.
2(e) Procedures
:
2(f)
Observation
1.0mol dm'' of
chloridesolution
0.001mol dm-'of
chloridesolution
\L