Vidyamandir Classes

VMC/Atomic Structure 23 HWT-Solutions/Chemistry

Solutions to Home Work Test/Chemistry
1.(C) In lightest nuclei there is only one proton and zero neutrons and
e
mp (1876)m
4.(A) Is and 25 are considered degenerate orbitals.
5.(A) Number of photoelectrons is proportional to intensity if incident beam only if frequency of light is greater than threshold
frequency.
7.(B)
max 0
K . E h h = v v
19
15 max
0
34
2
K.E 6.63 10 J
10 Hz
h
6.63 10 J H 1

v v = = =


15 15
0
(2 1) 10 Hz 10 Hz v = =
8. For Bohrs theory, only one proton should be resent.
1.(C)
2 2
1 2
1 1
E 13.6 ev
(n ) (n )
(
A =
(
(

Put
2
n
And
1
n 1 =
2. Fact
3. K.E. eV = [V : Change in potential]
2
1
m eV
2
v = (e : charge]

2eV
V
m
=
4.
h h h
p mV 2m(K.E)
= = =
1
K.E

5. In n = 4 we have
16 orbitals
8. Calcium has z = 20

2 2 6 2 6 2
1s 2s 2p 3s 3p 4s
10. z = 28 for nickel

2 2 6 2 6 2 8
Ni 1s 2s 2p 3s 3p 4s 3d
2 2 2 6 2 6 0 8
Ni 1s 2s 2p 3s 3p 4s 3d
+

2 unpaired e s

Atomic Structure HWT - 1

Atomic Structure HWT - 2
8
3d
Vidyamandir Classes
VMC/Atomic Structure 24 HWT-Solutions/Chemistry
1. Use
h
mV
=
2. Shortest wavelength is given when largest energy change is there.
for H it is n = 1 to n
And for longest wavelength, look for smallest energy charge

2
He
+
n = 3 to n = 2. Let wavelength by y.
2
2 2
1 1 1
R (1) R
x
(1) ( )
(
= =
(

2
2 2
1 1 1 (5)
R (2) R 4
y 4 9
(2) (3)
(
= =
(

x 5 9x
y
y 9 5
= =
8. Radial nodes are given by : n 1
1. Hydrogen atom has 1 proton and 1 electron.
ionized hydrogen atom has only 1 proton.
5.
2
n
r
z
6. Angular Momentum =
nh h
n :
2 2
(
=
(
t t


8. In module 9. In module
1. k(z = 19) we have
2 2 2 2 6 1
1s 2s 2p 3s 3p 4s
Outermost e

is
1
4s
4, 0, 0, +
1
2
or 4, 0, 0,
1
2

.
2. Use
h
[p mv]
p
= = 5.
1
T
n
=
6. Splitting of spectral lines in electric field is Stark effect. Splitting of spectral lines in magnetic field is leeman effect.
7. Fact
9. Isobars have equal atomic mass [protons + neutrons]
Istotoes have equal atomic no. [protons]
Isotones have equal neutrons.
1. for d orbital 2 = 4. Angular momentum
nh
2
=
t
5. Fact 6. Fact
7. When n + e values lashes we look for value of n and smaller the nature of n larger is the stability.
8. Isotones have equal neutrons. 10. Use
2 2
1 2
1 1
E
(n ) (n )
(
A
(
(

Atomic Structure HWT - 3
Atomic Structure HWT - 4
Atomic Structure HWT - 5
Atomic Structure HWT - 6
Vidyamandir Classes
VMC/Atomic Structure 25 HWT-Solutions/Chemistry
1. Hunds rule is niolated in 1
st
case. 6. Use
max 0
K. E hv w =
7. Spherical nodes = n 1 9. Use Aufbavs principle to know the configuration
1. These transmissions belong to lyman series
Uv rays
4.
6. Energy of photon
1 hc
as E
(
=
(


2. Add all e s

to get atomic number here

3. z = 21
2 2 6 2 6 2 1
1s 2s 2p 3s 3p 4s 3d
4. 12 p electrons 5
1
3d 1 d electon.
8. Fact 10. Use
h h
p mv
= =
1. Cl (z = 17)
2 2 6 2 5
1s 2s 2p 3s 3p
n = 3
e = 1
m could be l or.
4. Fact.
5. 3s, 3p, 3d
1 + 3 + 5 = 9 orbitals
9. Definition of Hunds rule.
Atomic Structure HWT 7
Atomic Structure HWT - 8
Atomic Structure HWT - 9
Atomic Structure HWT - 10
2 8
Ni has3d
+

2 unpaired e s