(B)
21
6.17 10 J
(C)
20
6.17 10 J
(D)
20
6.17 10 kJ
Vidyamandir Classes
VMC/Gas Laws 24 HWT/Chemistry
DATE : IITJEE :
MARKS :
| |
|
\ .
10
TIME : 25 MINUTES
NAME : TEST CODE : G Laws [3]
ROLL NO. START TIME : END TIME : TIME TAKEN:
STUDENTS SIGNATURE : PARENTS SIGNATURE :
This test contains a total of 10 Objective Type Questions.
Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. KE per unit volume is :
(A)
3
P
2
(B)
3
RT
2
(C)
0
3 RN
2 N
(D)
3 RT
2 n
2. Select correct statement(s) :
(A) The velocity at which distribution of molecules is maximum is called most probable velocity
(B) Most probable velocity of a gas is larger than root mean square velocity
(C) Both statements are correct (D) None is correct
3. Select correct statement(s)
(A) Kinetic energy is zero at 0 C (B) RMS velocity of
2
O at 27 C is =
1
3 8.314 300
ms
32
(C) Distribution of molecules is very small when u 0 or u (D) All the statements are correct
4. One molecule is moving at a speed of 1ms
1
and two molecules are moving at 2ms
1
. Hence, root mean square velocity is :
(A)
1
1 ms
(B)
1
1.67 ms
(C)
1
3ms
(D)
1
1.73 ms
(B)
1
L atmmol
(C)
1
L mol
(D)
2
atm L mol
|
\ .
(C)
a
1
RTV
| |
+
|
\ .
(D)
a
1
RTV
| |
|
\ .
10. In the above Questions, near the point B, compressibility factor Z is about :
(A)
Pb
1
RT
| |
|
\ .
(B) 1 (C)
Pb
1
RT
| |
+
|
\ .
(D)
a
1
RTV
| |
|
\ .
A
B
CO
Ideal
PV
P
Vidyamandir Classes
VMC/Gas Laws 25 HWT/Chemistry
DATE : IITJEE :
MARKS :
| |
|
\ .
10
TIME : 25 MINUTES
NAME : TEST CODE : G Laws [4]
ROLL NO. START TIME : END TIME : TIME TAKEN:
STUDENTS SIGNATURE : PARENTS SIGNATURE :
This test contains a total of 10 Objective Type Questions.
Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. Match Column I with Column II and select the correct answers :
Column I Column II
1. Critical temperature (p)
a
Rb
2. Boyle temperature (q)
2a
Rb
3. Inversion temperature (r)
c
T
T
4. Reduced temperature (s)
8a
27Rb
1 2 3 4 1 2 3 4 1 2 3 4 1 2 3 4
(A) q p s r (B) q r s p (C) q r s p (D) s p q r
2. A gas in an open container is heated from 27 C to 127 . The fraction of the original amount of the gas remaining in the container
will be :
(A) 3/4 (B) 1/2 (C) 1/4 (D) 1/8
3. Mole fraction of water vapour in the water saturated air is 0.02. If total pressure is 1.2 atm, partial pressure of dry air is :
(A) 1.18 atm (B) 1.22 atm (C) 1.176 atm (D) 1.224 atm
4. At constant volume, for a fixed amount of a gas the pressure of the gas increases with rise of temperature due to :
(A) increase in average molecular speed (B) increased rate of collision amongst molecules
(C) increase in molecular attraction (D) decrease in mean free path
5. The expression of root mean square speed of molecules of a gas is given as :
(A)
rms
3RT
u
M
= (B)
rms
3RT
u
m
= (C)
rms
3kT
u
M
= (D)
rms
8RT
u
M
=
t
6. The expression of average speed of molecules of a gas is given as :
(A)
av
8RT
u
m
=
t
(B)
av
8RT
u
M
=
t
(C)
av
8kT
u
M
=
t
(D)
av
8RT
u
M
=
7. The expression of most probable speed of molecules of a gas is given as
(A)
mp
2RT
u
M
= (B)
mp
3RT
u
M
= (C)
mp
8RT
u
M
=
t
(D)
mp
8RT
u
M
=
8. For a given gas, which of the following relationships is correct at a given temperature ?
(A)
rms av mp
u u u > > (B)
rms av mp
u u u < < (C)
rms av mp
u u u > < (D)
rms av mp
u u u < >
Vidyamandir Classes
VMC/Gas Laws 26 HWT/Chemistry
9. A molecule of SO
2
is two times heavier than O
2
molecule. At 298 K, the average kinetic energy of SO
2
molecules is
(A) two time that of O
2
molecules (B) half that of O
2
molecules
(C) four times that of O
2
molecules (D) same as that of O
2
molecules
10. Which of the following is expected to possess the largest root mean square speed at the same temperature?
(A) H
2
S (B) NH
3
(C) SO
2
(D) CO
2
Vidyamandir Classes
VMC/Gas Laws 27 HWT/Chemistry
DATE : IITJEE :
MARKS :
| |
|
\ .
10
TIME : 25 MINUTES
NAME : TEST CODE : G Laws [5]
ROLL NO. START TIME : END TIME : TIME TAKEN:
STUDENTS SIGNATURE : PARENTS SIGNATURE :
This test contains a total of 10 Objective Type Questions.
Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. The rms speed of hydrogen is 7 times the rms speed to nitrogen. If T is the temperature of the gas, then :
(A)
2 2
T(H ) T(N ) = (B)
2 2
T(H ) T(N ) > (C)
2 2
T(H ) T(N ) < (D)
2 2
T(H ) 7T(N ) =
2. If the volume of 2 moles of an ideal gas at 540 K is 44.8L, its pressure will be :
(A) 1 atm (B) 2 atm (C) 3 atm (D) 4 atm
3. The compressibility factor of an ideal gas is :
(A) 0 (B) 1 (C) 2 (D) 4
4. The dimensions of pressure are the same as that of
(A) energy (B) force
(C) energy per unit volume (D) force per unit volume
5. Ice, water and steam can exist simultaneously at
(A) All temperatures (B) All pressures
(C) All temperatures and pressure (D) triple point
6. The behaviour of a gas deviates the least from that of an ideal gas at
(A) 550 K and 1 atm (B) 350 K and 3 atm (C) 350 K and 4 atm (D) 450 K and 2 atm
7. The density of a gas will be the highest at :
(A) stp (B) 0 C and 2atm (C) 273 C and 1 atm (D) 273 C and 2 atm
8. The density of a gas at 27 C and 1 atm is d. At what temperature would its density be 0.75d, if the pressure is kept constant?
(A) 20 C (B) 30 C (C) 400 K (D) 300 K
9. For one mole of an ideal gas,
pV
R
T
= . The value of R varies with
(A) p (B) V (C) T (D) None of these
10 The temperature above which a gas remains ideal over a wide range of pressures is called
(A) boiling point (B) Boyles temperature
(C) critical temperature (D) ideal temperature
Vidyamandir Classes
VMC/Gas Laws 28 HWT/Chemistry
DATE : IITJEE :
MARKS :
| |
|
\ .
10
TIME : 25 MINUTES
NAME : TEST CODE : G Laws [6]
ROLL NO. START TIME : END TIME : TIME TAKEN:
STUDENTS SIGNATURE : PARENTS SIGNATURE :
This test contains a total of 10 Objective Type Questions.
Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. The density of methane at 27 C and 2.0 atmospheric pressure is :
(A)
1
0.13gL
(B)
1
0.26gL
(C)
1
1.30 gL
(D)
1
26.0 gL
2. A certain gas effuses through a small opening of a vessel at a rate which is exactly one-fifth the rate at which helium does the same.
Thus, the molecular weight of the gas is :
(A) 100 (B) 75 (C) 50 (D) 25
3. If the pressure of a gas is reduced to half and the absolute temperature is doubled, the volume of the gas will
(A) remain unchanged (B) be reduced to 1/4
th
(C) be doubled (D) increase fourfold
4. The weight of CH
4
in a 9-L cylinder at 27 C temperature and 16 atm pressure is (R = 0.08 L atm
1 1
K mol
)
(A) 9.6g (B) 96.0 g (C) 4.8 g (D) 48.0 g
5. What would be the number of moles of
2
H in 0.224 L of H
2
(g) at stp (273 K, 1 atm) ? Assume the gas to behave identically :
(A) 1.0 (B) 0.1 (C) 0.01 (D) 0.001
6. At a high pressure, the compressibility factor (Z) of a real gas is usually greater than one. This can be explained from van der Waals
equation by neglecting the value of :
(A) b (B) a (C) both a and b (D) V
7. Which of the following statements is correct for pV = nRT ?
(A) n is the number of molecules of the gas
(B) V denotes the volume of one mole of the gas
(C) n moles of the gas has volume V
(D) p is the pressure of the gas when only one mole of the gas is present.
8. The correct value of the universal gas constant, R, is close to :
(A) 0.082 L atm
1 1
K mol
(B) 0.082 L
1 1 1
atm K mol
(C) 0.082 L atm K
1
mol
(D)
1 1
0.082 Latm K mol
9. The values of the van der Waals constant a for the gases
2 2 3
O , N , NH and
4
CH are 1.360L
2
atm
2
mol
, 1.390L
2
atm
2
mol
,
4.170L
2
atm
2
mol
and
2
2.253L atm
2
mol
(C)
2
rms
A
1
pV mnN
3
= v (D) All of these
4. 0.28 g of a gas occupies 224 mL at stp. The gas could be :
(A) CO (B) C
2
H
4
(C) N
2
(D) All of these
5. How many O
2
molecules are present in 2.0 L of oxygen gas at 27 C temperature and 3.0 atm pressure ?
(A)
3
1.0 10 (B)
23
1.5 10 (C)
24
1.5 10 (D)
24
2.5 10
6. Which of the following gases has the highest value of the van der Waals constant a ?
(A)
4
CCl ( ) (B)
3
NH (g) (C)
2
CO (g) (D)
2
H O(g)
7. Consider the reaction
2 3
2Al(s) 3Cl (g) 2AlCl (s) + . The approximate volume of chlorine that would react with 324 g of
aluminium at stp is :
(A) 121 L (B) 134 L (C) 260 L (D) 403 L
8. In a classroom, there are 13 rows of students. A teacher releases laughing gas (
2
N O) from the front and tear gas (molar mass 176) from
the rear of the classroom simultaneously. Students of which row from the front will have a tendency to weep and smile simultaneously?
(A) 9
th
row (B) 12
th
row (C) 7
th
row (D) 10
th
row
9. The vapour density of a mixture containing
2 2
N (g) and O (g) is 14.4. The percentage of N
2
in the mixture is
(A) 20% (B) 80% (C) 60% (D) 50%
10 The rate of effusion of an ideal gas through a hole depends upon
(A) The pressure of the gas (B) The molar mass of the gap
(C) area of the hole (D) All of these
Vidyamandir Classes
VMC/Gas Laws 31 HWT/Chemistry
DATE : IITJEE :
MARKS :
| |
|
\ .
10
TIME : 25 MINUTES
NAME : TEST CODE : G Laws [9]
ROLL NO. START TIME : END TIME : TIME TAKEN:
STUDENTS SIGNATURE : PARENTS SIGNATURE :
This test contains a total of 10 Objective Type Questions.
Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. The vapour density of a gas depends upon the :
(A) total number of molecules (B) total number of neutrons in the molecules
(C) total number of electrons in the molecules (D) molecular mass of the gas
2. Which of the following statements is incorrect ?
(A) Gases do not have a definite volume of shape.
(B) The volume of an Ideal gas is equal to the volume of the container in which it is kept.
(C) A gas exerts pressure on the walls of the container in which it is kept.
(D) The mass of a gas cannot be determined by weighing the container in which it is kept.
3. A sample of a gas at 100 C and 0.80 atm pressure has a density of 1.15 g
1
L
\ .
(C)
1
M RT
p
| |
=
|
\ .
(D) M (p)RT =
5. If a gas expands at a constant temperature,
(A) the pressure decreases (B) the kinetic energy of the molecules increases
(C) the kinetic energy of the molecules decreases (D) the number of molecules of the gas increases
6. A bottle of dry ammonia and a bottle of dry hydrogen chloride connected through a long tube are opened simultaneously at both ends.
The white ammonium chloride ring will from first
(A) at the centre of the tube (B) near the hydrogen chloride bottle
(C) near the ammonia bottle (D) throughout the length of the tube
7. The root-mean-square speed of O
2
gas molecules at 27 C is :
(A)
1
498 ms
(B)
1
384 ms
(C)
1
484 ms
(D)
1
584 ms