Rufer
Supercapacitors: Summary
Generalities on Supercapacitors
Principle Model of a supercapacitor Series connection of supercapacitors
Conclusion
Generalities on Supercapacitors
Principle
Supercapacitors: electrochemical double layer capacitor High energy density, together with a high power density
Separator
+ + + + + + + + + + + + + + + + + + + + + + + + + + + + + -
Electrolyte
+ + + + + + + + + + + + + + + + + + + + + + + + + + + + + -
+
Energy stored by charge transfer at the boundary between electrodes and electrolyte Amount of stored energy is a function of : Electrode surface, size of ions, level of electrolyte decomposition voltage
Electrodes
Current collector
Generalities on Supercapacitors
Principle : technology
Electrodes: activated carbon High surface area part Define the energy density Current collectors High conducting part Membrane Avoids electronic contacts between the electrodes Allows the mobility of the charged ions Electrolyte Supplies and conducts ions Dissociation voltage of organic electrolytes less than 3V Organic electrolytes have a lower ionic conductivity (reduced power capability)
Separator
+ + + + + + + + + + + + + + + + + + + + + + + + + + + + + -
Electrolyte
+ + + + + + + + + + + + + + + + + + + + + + + + + + + + + -
Electrodes
Current collector
Generalities on Supercapacitors
Model of supercapacitors
ic Rs
r1 r2 c2 rn cn
uc
Rl
u Co
Cu
c1
Voltage dependant capacitance Series resistor Leakage resistor rc sub-circuits (relaxation phenomena)
Generalities on Supercapacitors
Series connection of supercapacitors
Voltage sharing solution, using power electronics solutions to offer a high efficiency.
i1
D1 Ns1
C1
i1
C1
i'2 i2
T1
D1 il1 D2
i2
D2 Ns2
L1
T2
C2
i1
Np1 T1 D1
T' 2
D'2 il2
C2 L2 C3
i3
C1
T i3 D3 Ns3
T' 3
D'3
C3
i2
Np2 T2 D2
Nf Df
C2
i3
Np3 T3 D3
C3
1 2 WM = CU M 2
Voltage discharge ratio: the minimum voltage during the discharge has to be limited for efficiency reasons
d=
Um 100 UM
The usable energy is then only part of the maximum stored energy
d 2 Wu = WM 1 100
Number of supercapacitors for a given usable energy
Ns =
2Wu
2 d 2 CU M 1 100
Wu=0.55MJ (5.7kW.h) C=1800F, UM=2.5V, IM=200A d (%) Volume (m3) Weight (kg) 50 1.46 1948 60 1.71 2283 70 2.15 2865
ic
L Ue ic
Rs C uc
P=Cte
Rs u I uc C
Time for loading energy has to be kept up to 10s for a 90% energy efficiency (Ic<320A or P<700W) Time for unloading energy has to be kept up to 10s for a 90% energy efficiency (Ic<320A or P<400W) Taking into account the necessity of 90% of energy efficiency, the current or the power for charging/discharging have to be limited: the power density is only 806W/kg (instead of 4300W/kg)
End of line Supercapacitive Tank DC DC Val-Vert Station 3 km Supply Station 675Vdc Bellefontaine Station
TL
R_Vscaps Iline_r
G2
ymax
Vscaps_max + -
Vendline_ref
+ R_Vinter
Itransfer
-1 +
+ R_Iscaps
Vendline
Iinject
PWM
Vinter
PWM
Iscaps
Vscaps
L1 RL1 Cinter
L2 RL2 Cscaps
RECTIFIER SUBSTATION
LINE (CATENARY)
SUPERCAPACITORS-BASED SUBSTATION
U end-of-line (V)
600
U Scaps (V)
400
200
-200
I Scaps (A)
-400
-600
-800
200
400
600
800
1000
1200
1400
1600
1800
t (s)
Convertisseur AC - DC unidirectionnel
Convertisseur DC - AC bidirectionnel
MG
Diesel
Principle of operation
RECUPERATION Scap
Elmerts stockeurs dnergie Convertisseur DC - DC bidirectionnel
The track
Altitude (m)
Altitude
2000 4000 6000 8000 10000 12000 14000 16000 18000
P nette P moy
temps (s)
x 10
6
Puissance (W)
0.5 0 -0.5 -1 -1.5 -2 0 2000 4000 6000 8000 10000 12000 14000 16000 18000
600
500
400
300
200
100
0 0
100
200
300
400
500
600
I D1
Is
Us
I D2
Id
Ud
Uc
load : 1400kg
Conclusion
Supercapacitors are new components for energy storage
High energy density (even if lower than batteries) High power density
Energy efficiency
Power availability of supercapacitors is affected by their energy efficiency
Applications
Main applications use supercapacitors as energy buffers In applications where supercapacitors are used as main energy source (UPS), the reduced energy density is compensate by their high power density, combined with an increased lifetime compared to batteries.