Concept Recapitulation Test IV/Advanced/PAPER-2/Answer/Answer

AITS-CRT(Set-IV)-Paper-2-PCM(S)-JEE(Advanced)/13
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1

ANSWERS, HINTS & SOLUTIONS
CRT(Set-IV)
(Paper-2)

Q. No. PHYSICS CHEMISTRY MATHEMATICS
1.
B B D
2.
D A A
3.
B C D
4.
D B D
5.
A C B
6.
D A B
7.
C B C
8.
A C D
9.
B A A
10.
B C A
11.
C D D
12.
A C C
1.
(A) (q, r),
(B) (p, s),
(C) (p, r),
(D) (p, s)
A (s);
B (r, t);
C (p);
D (q)
(A) (s),
(B) (r),
(C) (s),
(D) (p)
2.
(A) (q)
(B) (r)
(C) (t)
(D) (r)
(A) (s);
(B) (q);
(C) (p);
(D) (r)
(A) (p, s),
(B) (q, r),
(C) (p, r),
(D) (p, q, r, s)
1.
1 8 2
2.
2 1 1
3.
5 4 4
4.
2 4 3
5.
0 3 0

A
L
L

I
N
D
I
A

T
E
S
T

S
E
R
I
E
S

FIITJEE JEE(Advanced)-2013
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2
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4
3

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1
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7
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2


2
P Ph hy ys si ic cs s PART I

1. Rate of cooling difference in temperature

dT
dt

dT
K
dt
=
dT K .dt =
In first case:
dT 61 59 2 = =
= 60 30 = 30
dt = 4 minute

dT 2 1
K
dt 30x 4 60
= = =

For second case:
dT 2 =
50 30 20 = =

1
60
dT 2
dt 6 min.
K x 20
= = =

2.
A
(KE ) at M = mg(104) = 6 J

B
(KE ) at M = 6 J and
B
(PE ) at M =
1
10 4 4J
10
=
( )
2
B EB M
on ground
1
mv (T ) 6 4 J
2
| |
= = +
|
\ .

v 200 10 2m/ s = =

3. v
y
= v sin 30 g cos 30 t
t =
v sin30 v 1 1
sec
gcos30 g
3 3
= =

g sin30
o
g cos30
o
30
o
60
o
X
Y
v

4. In equilibrium of the charged small bodies
2
2
0 0
1 q
4
( x )
0
+
= kx
0
, where x
0
is the elongation in the
spring in equilibrium.
Let a further small elongation of x is given to the spring.
Then net restoring force on any of the charged particle is given by,
F =
2
0
2
0 0
1 q
k(x x)
4
( x x)
0
(
+
(
+ +
(

= kx. Since x < < x

0

a =
2k
m
x As F = a, where reduced mass =
m m
m m
+
=
m
2

a =
2
x, Hence =
2k
m

T = 2
m
2K


3
In absence of charge, T
0
= 2
m
2K
.
Therefore
0
T
1
T
=
5. v
2
cos + v
1
cos = v
1

v
2
= v
1

( )
2
2sin / 2
cos
(
(

6. Initially the capacitance acts as short circuited and at steady state it acts as open circuit.
Hence, at t = 0, i =
3
2
1 10
= 2 mA
At steady state i =
3
2
2 10
= 1 mA
SECTION C
1. When a charged particle of charge q, mass m enters perpendicularly to the magnetic induction B

of a magnetic field, it will experience a magnetic force F=q(v B)
= q vB sin 90 = qvB that

provide a centripetal acceleration
2
v
r

qvB =
2
mv
r
mv = qBr
The de-Broglie wavelength =
h h
mv qBr
=

particle p p
proton
q r
q r

Since
p
r
r
= 1 and
p
q
q
= 2

p
= 1/2
4. Induced emf = M
di
dt
= 0.5
3 2
50
0.01
= V
5. Since there is no interaction of disc with the magnetic field, the force acting on the disc is zero.


4
C Ch he em mi is st tr ry y PART II

SECTION-A
1. Zn + 2HCl ZnCl
2
+ H
2

3.
CH
2
OMe
OMe
H
+
CH
2
OMe
O
H
Me
C H
2
OMe
+
+
..

OH
OH
2
CH OMe
EAS
+
=
OH
NO
2
CH
2
OMe
HCl
OH
NO
2
CH
2
Cl
+ MeOH

4.
C
S
R O
R
Ni/H
2
C O
R
R
+ C
2
H
4
+ S
A
B
C
D

6.
OH
O
2
3
Br
NaHCO
O
O
Br
O
O
O
O Br
Br
Br
_
+
_ ..

7. Enantiomers are related by mirror images, I and II are mirror images and III and IV are mirror
images.
8. Diastereomers that are not related by the mirror images.
9. Erythro means the highest priority should be on the same side.
10. Both are linear.
11.
4 2 3 2 2 2
6 12 2 4 12 3 XeF H O XeO Xe H F O + + + +

6 2 3
3 6 XeF H O XeO HF + +
12.
4
XeF exists whereas
4
XeCl is not stable because the size of F is smaller than Cl


5
SECTION C
2. Xe in XeOF
4
shows sp
3
d
2
hybridization with one lone pair on Xe-atom.
3.
3 3
CH COOH CH COO H
C 0 0
C(1 ) c c

+

= 1 + (n - 1) = (1 + ) = 1.01
= 0.01
[H
+
] = c = 0.01 0.01 = 1 10
-4
m
pH = 4
4.
b
1000 0.512 288
T 1.24
m 5 18

= =

5. It has 2 chiral centres.

N
H
N
H
O
O
C H
3
CH
3

Number of stereomers =
1
1
2
2 2 3
n
n

+
+ =


6
M Ma at th he em ma at ti ic cs s PART III

SECTION A

1. Area
1/ 2
0
x 1 7
2 dx
2 4 12
= + =

2.
a 1 1
1 1 c
1 b 1 0 0
1 a 1 b 1 c
1 1 c
= + + =

1
1
1 a
=

( ) 2 1 a
1 a
1
1 a 1 a

+
= =

3.
( ) ( )
( ) ( ) ( ) ( )
P A .P B/ A
A
P
B
P A .P B/ A P A .P B/ A
| |
=
|
+
\ .

( )
( ) ( )
1
1
1 1 2

= =
+

4. For orthogonally replace p by
1
p
. Thus the equation should be similar.

5. Line BC must be parallel to one of the angle bisectors of AB and AC.
Angle bisectors are with slopes 7 and
1
7

Equation of BC is y 2 = 7(x 1)
i.e. 7x + y 9 = 0

6. Given expansion is
2n
n
1
(1 10) 1
(81)
=

79. ( ) ( ) { }
1
0
S 1 sint t 1 cost sinx f x dx = + =

Different w.r.t t we get ( ) ( ) f t t sint f x xsinx = =
Now solving ( ) f x xsinx = and y sinx = , we get x 1 or n , n I a 1 = =
Thus
1
S 1 sin1 =
Also ( ) | |
2
1
S xsinx sinx dx xcosx sinx cosx 1 sin1
= = + + =

2 1
S S 2 =
Further, ( )
2
3
S sinx xsinx dx 3 2
= =

1012. Putting x y 0 = = in the given equation ( ) ( ) ( ) ( )
n
f 0 f 0 f 0 = +
( ) f 0 0 =

7
( )
( )
( ) ( )
( )
( )
n
1/ n
n
1/ n
f 0 f h f 0
lt
f ' 0
h 0
h
+
=

( ) ( )
( )
n
1/ n
n
1/ n
f h
lt
l
h 0
h
| |
|
= =
|
|
\ .

n
l l l 0,1, 1 = =
But ( ) ( )
l 1 f ' 0 0
If l 0 = then ( )
( ) ( ) f n h f x lt
f ' x
h 0 h
+
=

( )
( ) ( )
( )
n
1/ n
n
f x f h f x
lt
l 0
h 0 h
+
= = =

( ) f ' x 0 =
But ( ) f 0 0 = f is identically zero which cant be possible
l 1 = ( ) f x x c = + but ( ) f 0 0 = ( ) C 0 f x x = = ( ) ( ) f ' 0 1and f 5 5 = =

SECTION B

1. (A) Solving two curves
x
2
+ 2 = 2|x| cos x
x
2
2|x| + 2 = cos x
(|x| 1)
2
+ 1 = cos x
Clearly solution is x = 1
Required area
1
2
1
8
(x 2 2 | x | cos x)dx
3
= + + =

(B)
1 1 1 1
1 1
1
3 7
cot 3 cot 7 tan tan
1
2
1
21

| |
+
|
| |
+ = =
|
|
\ .
|
|
\ .

1 1 1 1
1 1
1 13 21
cot 13 cot 21 tan tan
1 1
8
1
13 21

| |
+
|
\ .
+ = =

( )
1 1 1 1
cot cot 3 cot 7 cot 13 cot 21

+ + +

1
2 3
cot tan
3 2
| |
=
|
\ .

(C) t
1
t
2
= 1
Clearly ABCD is a rectangle
Co-ordinate of B(t
1
t
2
, (t
1
+ t
2
))

2
2 1 1
AB | (t t ) | 1 t = +
2
2 1 2
BC (t t ) 1 t = +
Area = AB BC = (t
2
t
1
)
2

2 2
1 2
(1 t )(1 t ) + +
3
1
1
1
t
t
| |
= +
|
\ .

Least value = 8.
O
B
A(t )
1
C(t )
2
S D
(D) For area to be maximum centre
2 2
( , )
Should lie on x + y = 1
2
+
2
= 1
As , I

2
= 0 and
2
= 1
(0, 1)

8
or
2
= 1 and
2
= 0
(1, 0)

2. When a > 0, b > 0

b
a

When a > 0, b < 0

When a < 0, b < 0

When a < 0, b > 0

SECTION C

1.
1
x 5 2 5 7
x
| |
+ + + =
|
\ .

147
y 21 0 y 21
7
= < Required prob
8
2
21
2
C .2! 2
15
C .2!
= =

2. { }
1
8
1
x x dx

{ } { }
1
8
1
2I x x x dx
( = +

,
{ } { } ( )
1
8
0
I x x x dx = +

I =
1
9
= a

3. For the point where the line intersects the curve, we have z = 0
so
x 2 y 1 0 1
x 5
3 2 1

= = =
and y 3 =
Putting these values in
2 2 2
x y a = we get
2
a 16 = i.e., a 4 =

4.
2
m 2 2m 5 0
m 1 m 7 5 0
1 1 1

= =
( )
( )
2
m 3 m m 2 0 + =
For m = 3, the lines become parallel

5. ( ) ( ) ( ) ( ) ( ) f x y f x f a y f y f a x + = + ( ) 1
Put x = y = 0 we get ( )
1
f a
2
=
Put y 0 = we get ( ) ( ) ( ) ( ) ( ) f x f x .f a f 0 f a x = + ( ) ( ) f x f a x =
Put y a x = is equation (1)
( ) ( ) ( ) ( ) ( )
2 2
f a f x f a x = + ( )
1
f x
2
= ( )
1
f x
2

`
)

Hence ( )
1
f x
2
=

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= kx. Since x < < x

= q vB sin 90 = qvB that

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