Thermodynamics (Course number: 22006) Tutorial 3 (Properties of pure substance) Fundamental concepts 1. What do you mean by Pure substance.

. Can air be a pure substance? Justify. 2. Draw the P-T diagram for a pure substance and !e"e! its different properties. #. $%p!ain the terms !atent heat of fusion !atent heat of "aporisation and !atent heat of sub!imation with suitab!e e%amp!e. &. Write down the characteristic features of a 'uperheated steam. (. Differentiate between the terms steam and "apor? ). Write down the significance of trip!e point and critica! point of water. What are their "a!ues? *. 'how that the s!ope of fusion cur"e for most substance is positi"e e%cept for water it is negati"e. +. Differentiate between moisture and ,ua!ity and what happens to these at critica! point? -. .epresent an isobaric !ine in P-/ P-T and T-/ diagram. Problems 1. Determine the entha!py of steam at 10 bar if it is saturated 0.-( dry and superheated to 2)0 1C. 2. Determine the mass of 0.( m# of wet steam at a pressure of & bar and +02 dry. #. What is the density of water "apor at 2 bar +0 2 dryness? &. Determine the condition and ,ua!ity of steam for the fo!!owing cases. .epresent them in a T-/ diagram. 3i4 Pressure 10 5pa and temperature #12 1C 3ii4 Pressure ) 5pa and h6#&22.2 7J87g 3iii4 Pressure 10 bar and "o!ume 0.1*( m#87g (. What is the amount of heat must be supp!ied to a boi!er for generating 10 7g of steam at a pressure of 10 bar and -(2 dry if the water is supp!ied to it at #0 1C and same pressure? ). 9 "esse! of "o!ume 0.) m# contains & 7g of water and water "apor mi%ture in e,ui!ibrium at a pressure of 0.+ 5pa. Determine 3i4 /o!ume and mass of water 3ii4 /o!ume and mass of water "apor *. 9 spherica! she!! of diameter (0 cm contains steam at a pressure of 10 bar and +(2 dry. Determine the mass of both water and steam. +. 9 (00 !iter tan7 contains a saturated mi%ture of water and steam at a temperature of #00 1C. Determine the mass of each phase if their "o!umes are e,ua! and "o!ume of each phase if masses are e,ua!.

-. 9 pressure coo7er contains 2 7g of steam at ) bar and -02 dry. Determine the amount of heat must be re:ected to ma7e it (02 dry. 10. 'aturated steam at 10 bar is coo!ed unti! its dryness fraction becomes (02. Determine the change in temperature and specific "o!ume of the steam? 11. 10 7g of saturated !i,uid water at 1 bar is heated at constant pressure unti! the temperature becomes 200 1C. Determine 3i4 The initia! and fina! "o!umes 3ii4 The net wor7 done during the process 3iii4 The amount of heat transferred during the process 12. 1 7g of water at 120 1C with a ,ua!ity of 2(2 has its temperature raised by 20 1C in a constant "o!ume processs. What is the new ,ua!ity and pressure of the steam? 1#. 9 rigid "esse! of "o!ume 0.0# m# contains a mi%ture of water and steam which passes through the critica! point. ;ind out the mass of the mi%ture. 1&. 'uperheated water "apor at 1.& 5pa and 2(0 1C is a!!owed to coo! at constant "o!ume aunti! its temperature drops to 120 1C. 9t the fina! state determine the pressure ,ua!ity and entha!py of steam. 'how the process in T-/ diagram with respect to saturation !ines. 1(. Two insu!ated tan7s 9 and < are connected by a "a!"e. Tan7 9 has a "o!ume of 0.* m # and contains steam at 1.( bar 200 1C. Tan7 < has a "o!u7me of 0.#( m# and contains steam at ) bar with a ,ua!ity of -02. The "a!"e is then opened and the two tan7s comes to the state of e,ui!ibrium. Determine the fina! pressure of the tan7. 3#22.) 7Pa4