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Supplier
Signs and Symptoms of Acute Exposure May cause irritation and redness. May be absorbed through the skin. May cause swelling. May cause Skin frostbite (liquid form). May cause irritation to the respiratory system. May cause headache, nausea and vomiting. May cause Inhalation unconsciousness. Lack of oxygen may cause unconsciousness, in extreme cases can cause death. May cause fatigue. Gas iz mild irritant, may cause irritation, tearing, redness. . May cause blurred vision. Liquid form may Eyes cause frostbite, irritation, tearing, redness An unlikely route of exposure. May cause frostbite to mouth and throat tissues Ingestion Chronic Health Effects The substance may effect on the bone marrow, resulting in leukaemia. This substance is probably carcinogenic to humans. May cause heritable genetic damage in humans. Animal tests show that this substance possibly causes toxic effect upon human reproduction.
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Repeated exposures may cause injury to lungs, liver and kidneys. Prolonged or repeated exposure may cause a general deterioration of health.
CLP
GHS
Clasification (Hazard Class and Category Code GHS) Risk Phrases (Hazard statement GHS)
T; Toxic
R45 May cause cancer R46 May cause heritable genetic damage
H220 Extremely flammable gas H350 May cause cancer H340 May cause genetic defects
Inhalation Skin
Eyes
Ingestion
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Note to Physician
No specific antidote, treat symptomatically Treat unconsciousness, frostbite, nausea, hypotension, seizures and cardiac arrhythmia in the conventional manner. Sympathomimetics and catecholamines should be avoid or used with caution (lowest effective dose) because of possible cardiac sensitization. Administer oxygen by mask if there is respiratory distress. Treatment of overexposure should be direct at controlling the symptoms and clinical condition of a patient. After adequate first aid, no further treatment is necessary unless symptoms reappear.
Extinguishing Media Extinguishing Media (which shall not be used for safety reasons) Hazardous Combustion Products
Coplete combustion may proceede: carbon dioxide, water vapour Incomplete combustion may proceed: carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons aldehides and ketones. Danger of polymerisation after heating and after action of air oxygen explosive character of polymerisation Self-contained breathing apparatus and complete protective clothing Keep unnecessary personnel away. Combat fire from a maximum distance and sheltered position. Avoid inhaling any smoke and combustion materials. Immediately whit draws in case of fire and container venting or heat discoloration of a container.
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Storage
Specific use(s)
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Mutagenic effects Teratogenic effects Sensibilization Special Remarks on Other Toxic Effects on Humans The substance may effect on the bone marrow, resulting in leukemia. This substance is probably carcinogenic to humans. May cause heritable genetic damage in humans. Animal tests show that this substance possibly causes toxic effect upon human reproduction. Repeated exposures may cause injury to lungs, liver and kidneys. The substance is toxic to lungs, the nervous system, liver, mucous membranes Symptoms of chronic intoxication are indefinite. Big possibility of the affecting the marrow, liver, and vasoneuroses.
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It is not PBT/vPvB substance The product has not classified as dangerous for the environment. The product evaporates readily exposure to aquatic life is expected to be minimal.
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239 1010
Required label(s)
Road (ADR) / Rail (RID)/ Water (ADNR) BUTADIENES, STABILIZED Proper Shipping Name 1010 UN Number 2 (2.1 flammable gas) Hazard class 2F Transport category / Packaging group
Marine (IMO) Proper Shipping Name UN Number IMDG class EmS category Packaging group
Required label(s)
Air Transport (IATA/ICAO) Proper Shipping Name UN Number ICAO/IATA class Packaging group
Required label(s)
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Clasification (Hazard Class and Category Code GHS) Risk Phrases (Hazard statement GHS)
T; Toxic
R45 May cause cancer R46 May cause heritable genetic damage S45 In case of accident or if you feel unwell, seek medical advice immediately (show the lable where possible) S53 Avoid exposure - obtain special instructions before use
H220 Extremely flammable gas H350 May cause cancer H340 May cause genetic defects
P210 - Keep away from heat /sparks /open flames/hot surfaces- No smoking. P243 - Prevent from accumulation of static charges P281 - Use personal protective equipment as required. P377 - Leaking gas fire: Do not extinguish, unless leak can be stopped safely. P381 - Eliminate all ignition sources if safe to do so. P308+P313 - If exposed or concerned: Get medical advice/attention P403 - Store in a well-ventilated place.
P501 - Dispose of contents / container in accordance with local /regional / national regulations
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Key/Legend American Conference of Governmental Industrial Hygienists ACGIH European Agreement concerning the International Carriage of Dangerous Goods by inland Waterways ADNR European Agreement concerning the International Carriage of Dangerous Goods by Road ADR Chemical Abstract Service CAS European Union EU International Agency for Research on Cancer IARC International Air Transport Association IATA International Civil Aviation Organization ICAO International Maritime Dangerous Goods IMDG International Maritime Organization IMO Lethal Concentration, concentration of a chemical which kills 50% of a sample population LC50 Lethal Dose, dose of a chemical which kills 50% of a sample population LD50 National Fire Protection Association NFPA National Toxicology Programme NTP Occupational Safety and Health Administration OSHA International Rule for Transport of Dangerous Substances by Railway RID Threshold Limit Value TLV Time Weighted Averages TWA This information applies to the PRODUCT AS SUCH and conforming to specifications of HIP- Petrohemija Pancevo. In case of formulations or mixtures, it is necessary to ascertain that a new danger will not appear. The information contained is based on our knowledge of the product, at the date of publishing and it is given quite sincerely. However the revision of some data is in progress. Users are advised of possible additional hazards when the product is used in applications for which it was not intended. This sheet shall only be used and reproduced for prevention and security purposes. The references to legislative, regulatory and codes of practice documents cannot be considered as exhaustive. It is the responsibility of the person receiving the product to refer to the totality of the official documents concerning the use, the possession and the handling of the product. It is also the responsibility of the handlers of the product to pass on to any subsequent persons who will come into contact with the product. (usage, storage, cleaning of containers, other processes) the totality of the information contained within this safety data sheet and necessary for safety at work, the protection of health and the protection of environment.