1) Find the value of Keq for the following equation

2 NO (g)

N2 (g)

O2 (g)

Given:
RXN
Initial
Change
Equilibrium

[ NO(g) ]
1.6 M

[ N2 (g) ]
0.6 M

[ O2 (g) ]
0.6 M

1.4 M

Answer: Keq = 0.25

2) Find the value of Keq for the following equation at 1000C if
CO (g)

H2O (g)

CO2 (g)

H2 (g)

if the starting concs. are [ CO ] = 0.8 M, [ H2O ] = 2.40 M, [ CO2 ] = 0.62 M, [ H2 ] = 0.5 M
and the equilibrium concentration of CO2 is [ CO2 ] = 0.92 M
Answer: Keq = 0.70
3) Find the value of Keq for the following equation
2 CO2 (g)

2 CO (g)

O2 (g)

if the starting concentration are [ CO2 ] = 2.4 M, [ CO ] = 0.11 M, [ O2 ] = 1.6 M

and the equilibrium concentration of O2 (g) is [ O2 ] = 1.8 M
Answer: Keq = 0.16
4) Find the value of Keq for the following equation
2 SO2 (g)

O2 (g)

2 SO3 (g)

if the starting concentrations are: [ SO2 ] = 0.4 M, [ O2 ] = 1.6 M, [ SO3 ] = 29.7 M

and the equilibrium concentration of SO2 is [ SO2 ] = 1.2 M
Answer: Keq = 290
5) Calculate the concentration of CO2 (g) in the following equilibrium
CO (g)

H2O (g)

CO2 (g)

H2 (g)

if at equilibrium the [CO (g)] = 1.5 M, [ H2O (g)] = 1.2 M, [ H2 (g) ] = 0.8 M
and the Keq of the equilibrium is 0.7
Answer: [CO2 (g)] = 1.58 M
6) Calculate the concentration of N2 (g) in the following equilibrium
N2 (g)

3 H2 (g)

2 NH3 (g)

if at equilibrium the [H2 (g)] = 0.7 M, [NH3 (g)] = 1.5 M, and the Keq of the equilibrium is 15
Answer: [H2 (g)] = 0.44 M
7) Calculate the concentration of NO (g) in the following equilibrium
N2 (g)

O2 (g)

2 NO (g)

if at equilibrium the [N2 (g)] = 1.3 M, [O2 (g)] = 0.9 M,

and the Keq of the equilibrium is 4.5
Answer: [NO (g)] = 2.3 M
8) Calculate the concentration of NO (g) in the following equilibrium
2 NO (g)

O2 (g)

2 NO2 (g)

if at equilibrium the [NO2 (g)] = 0.0043 M, [O2 (g) ] = 0.9 M,

and the Keq of the equilibrium is 2.0 x 10 -6
Answer : [NO (g)] = 3.2 M
Using mole ratios and algebra to solve for Keq .
9) Calculate the [Pb2+] , and [I-] at equilibrium for the following reaction , if the Kc = 1.4*10-4.
PbI2 (s) <----> Pb2+ (aq) + 2I- (aq)
10) Calculate the [Ba2+] and [SO4 2-] at equilibrium for the following rxn if the Kc = 1.1*10-10
BaSO4 (s) <------> Ba2+ (aq) + SO4 2- (aq)
11) Calculate the [H+] ion at equilibrium for oxalic acid in the following equilibrium if the
equilibrium [C2O4H2] = 0.0010 mol/l and the Kc= 5.9*10-2

C2O4H2 (aq) <-----> C2O4H - (aq) + H+ (aq)

12) Calculate the equilibrium concentration of [HClO] if the equilibrium concentration of [ClO-]
= 0.0045 mol/l and the Kc = 3.0*10 -8.
HClO (aq) <-----> CLO- (aq) + H+ (aq)
13) The value of Kc for the following reaction is 4 at a certain temperature. Calculate the
equilibrium concentrations of [CO] and [Cl2] is the equilibrium concentration of [COCl2] = 0.054
mol/l and the equation is
COCl2 (g) <-----> CO (g) + Cl2 (g)
14. 4.00 moles of HI are placed in an evacuated 5.00 L flask and then heated to 800 K. The
system is allowed to reach equilibrium. What will be the equilibrium concentration of each
species?
2 HI(g)

H2(g) + I2(g)

Kc = 0.016 @ 800 K

15. 0.600 moles of NO and 0.750 moles of O2 are placed in an empty 2.00 L flask. The system
is allowed to establish equilibrium. What will be the equilibrium concentration of each species
in the flask?
2 NO2(g)

2 NO(g) + O2(g)

Kc = 0.50

16. The concentrations of an equilibrium mixture of O2 , CO, and CO2 were 0.18 M, 0.35 M,
and 0.029 M respectively. Enough CO was added to the flask containing the equilibrium
mixture to momentarily raise its concentration to 0.60 M. What will be the concentration of each
species in the flask once equilibrium has been re-established after the additional carbon
monoxide was added?
2 CO2(g)

2 CO(g) + O2(g)

17. Cl2 gas undergoes homolytic cleavage into chlorine atoms at 1100oC. Kp at 1100oC for this
process is 1.13 x 10-4. If a sample with an initial Cl2 gas pressure of 0.500 atm was allowed to
reach equilibrium, what is the total pressure in the flask?
Cl2(g)

2 Cl(g)

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