Proof read done by CGS on 1-10-09 ADTW91A01 PH-1 PAPER -1 CGS ON 30-9-09 Single An !er "#e $ion 1.

Caffeine has a molecular weight of 194. If it contains 28.9% by mass of nitrogen, number of atoms of nitrogen in one molecules of caffeine is: (a 4 (b ! (c 2 (" #
2.

$he "istance between #r" an" 2n" %ohr orbits of hy"rogen atom is: (a &.'29 1&8 cm (b 2.!4' 1&8 cm (c 2.11! 1&8 cm

(" 1.&'8 1& 8 cm

#.

( )hotosensiti*e material woul" emit electrons if e+cite" by )hotons beyon" a threshol". $o o*ercome the threshol", one woul" increase: (a the *oltage a))lie" to the light source (b the intensity of light (c the wa*elength of light (" the fre,uency of light ( bo+ is "i*i"e" into two e,ual com)artments by a thin )artition an" they are fille" with gases - an" . res)ecti*ely. $he two com)artments ha*e a )ressure of 2'& torr each. $he )ressure after remo*ing the )artition will be e,ual to: (a 12' torr (b '&& torr (c 2'& torr (" /'& torr ( s)herical air bubble is rising from the "e)th of a la0e when )ressure is 1 atm an" tem)erature is $2. $he )ercentage increase in its ra"ius when it comes to the surface of a la0e will be: ((ssume tem)erature an" )ressure at the surface to be res)ecti*ely 2T 2 an" 134 (a 1&&% (b '&% (c 4&% (" 2&&%

4.

'.

One or %ore $&an one 'orre'$ o($ion )#e $ion !. 4hich of the following are co*alent com)oun"s5 (a BeCl2 (b MgCl2 (c LiH
/.

(" LiCl ("

4hich of the following gra)hs re)resent %oyle6s law5 (a (b

(c

17

17

17

8.

4hich of the following is3are incorrect for 8um)hrey lines of hy"rogen s)ectrum5 (a n2 = / n1 = 2 (b n2 = 1& n1 = ! (c n2 = ' n1 = 1 (" n2 = 11 n1 = # 4hich of the following has three significant figures5 (a !.&2 1&2# (b &.2' (c !.!& 1&#4 (" 1.'&

9.

Co%(re&en ion -1 ( formula analogous to the 9y"berg formula a))lies to the series of s)ectral lines which arise from transitions from higher energy le*el to the lower energy le*el of hy"rogen atom.

( muonic hy"rogen atom is li0e a hy"rogen atom in which the electron is re)lace" by a hea*ier )article, the :muon6. $he mass of the muon is about 2&/ times the mass of an electron, while the charge remains same as that of the electron. 9y"berg formula for hy"rogen atom is:
1 = RH 1 1 1 2 2 RH = 1&9!/8 cm n n 1 2

(nswer the following ,uestions:

1&.

9a"ius of first %ohr orbit of muonic hy"rogen atom is: (a

&.2'9 & A 2&/

(b

&.'29 & A 2&/

(c &.'29 2&/ A&

(" &.2'9 2&/ A&

11.

;nergy of first %ohr orbit of muonic hy"rogen atom is: (a

1#.! eV 2&/

(b 1#.! 2&/ eV

(c +

1#.! eV 2&/

(" +1#.! 2&/ eV

12.

Ioni<ation energy of muonic hy"rogen atom is (a +

1#.! eV 2&/

(b +1#.! 2&/ eV

(c

1#.! eV 2&/

(" 1#.! 2&/ eV

Co%(re&en ion -1* 2inetic theory of gases is a generali<ation offere" by =a+well, %olt<mann, Clausius, etc., to e+)lain the beha*iour of i"eal gas. $his theory assumes that i"eal gas molecules neither attract nor re)el each other. (*erage 0inetic energy of gas molecules is "irectly )ro)ortional to the absolute tem)erature. ( gas e,uation calle" 0inetic gas e,uation was "eri*e" on the basis of 0inetic theory.
1 PV = mnv 2 #

(nswer the following ,uestions:

1#.

Gas Density ( &.82 g L1 % &.2! g L1 C &.'1 g L1 1ic0 u) the correct statement3statements: 1. gas ( will ten" to lie at the bottom 2. the number of atoms of *arious gases (,% an" C are same #. the gases will "iffuse to form homogenous mi+ture 4. a*erage 0inetic energy of each gas is same (a 2,# (b 1,4 (c 1 >elect the incorrect statement (s about the real gases: 1. the molecules attract each other 2. they show "e*iation from %oyle6s an" Charles6 law #. *olume of gas molecules are negligible 4. the molecules ha*e negligible mass $he a*erage 0inetic energy )er molecule of an i"eal gas is e,ual to : (a &.' 0? (b &.' 9$ (c 1.' 0$ A er$ion and Rea oning

(" #,4

14.

1'.

(" 1.' 9$2

Directions: $he ,uestions (1! @ 18 gi*en below consists of >$($;=;A$ 1 an" >$($;=;A$ 2. Bse the following 0ey to choose the a))ro)riate answer. (a %oth >$($;=;A$ 1 an" >$($;=;A$ 2 are true an" >$($;=;A$ 2 is correct e+)lanation of >$($;=;A$ 1 (b %oth >$($;=;A$ 1 an" >$($;=;A$ 2 are true but >$($;=;A$ 2 is not correct e+)lanation of >$($;=;A$ 1. (c >$($;=;A$ 1 is true, >$($;=;A$ 2 is false. (" >$($;=;A$ 1 is false, >$($;=;A$ 2 is true. ( s)ecial line will be seen for 2 px 2 py transition. ;nergy is relate" in the form of wa*e of light when the electron "ro)s from 2 px to 2 py orbital Ioni<ation )otential of %e ((t. Ao. 4 is less than % ((t. Ao. ' $he first electron release" from %e is of )@orbital but that from % is of s@ orbital.

1!.

>$($;=;A$ 1: >$($;=;A$ 2: >$($;=;A$ 1: >$($;=;A$ 2: >$($;=;A$ 1: >$($;=;A$ 2:

1/.

18.

$he C@C bon" in 82C2 is shorter than D2C2 82C2 is ionic com)oun" N#%eri'al

A1. A2.

( )hoton of wa*elength 4&&& A& stri)es a metal surface, the wor0 function of the metal being 2.1# e7. Calculate the *elocity of the )hoto electron (in 1&# m3s $he com)osition of air is a))ro+imately 8&% N 2 and 2&% O2 by mass. Calculate "ensity of air at 29# 2 an" /! cm 8g )ressure.

Ei)ole moment of 2Cl is #.##! 1&29 coulomb metre which in"icates that it is highly )olar A#. molecule. $he interatomic "istance between K + and Cl in this molecule is 2.! 1&1& m. Calculate the )ercentage ionic character of 2Cl. +a$'& $&e follo!ing =1. COLUMN I ( % C E
N2

COLUMN II 1 F 9 > 4&% carbon by mass ;m)irical formula CH 2O 7a)our "ensity G 14

14 N A N A = !.&2# 1&2# electrons in a mole

CC
C! H12O! CH #COOH

=2. =atch the electronic transitions of Hist II with s)ectral )ro)erties of list II: COLUMN I COLUMN II ( % C E
n = ! n = # n = / n = #
n = ' n = 2

1 F 9 >

1& lines in the s)ectrum >)ectral lines in *isible region ! lines in the s)ectrum >)ectral lines in infrare" region

n = ! n = 2

=#. =atch the Hist II with list II: COLUMN I

COLUMN II

( % C E

9a"ius of nth orbital ;nergy of nth shell Crbital (ngular momentum electron 7elocity of electron in nth orbit

1 F 9 >

In*ersely )ro)ortional to J Integral multi)le of h32 1ro)ortional to n 2 In*ersely )ro)ortional to :n6

ANSWER KEY: 1.( !.(,C,E 11.% 1!. E A1.'8' =1. =2. =#. (@9,> (@9,> (@9,1 2.% /.%,C 12.% 1/.E #.E 8.(,C,E 1#.E 18.E A2.1.19 g H@1 A#. 8& %@9,> %@1,> %@9 C@1,F C@F,9 C@F E@1,F E@1,F E@> 4.C 9.(,C,E 14.E '.( 1&.% 1'.C