Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories 9.1 Multiple-Choice and Bimodal Questions 1) !

or a molecule with the "ormula $B# the molecular shape is %%%%%%%%%%& $) linear or 'ent B) linear or trigonal planar C) linear or (shaped )) (shaped *) trigonal planar $nswer: $ Diff: 1 Page Ref: Sec. 9.1 #) $ccording to +,*-. theory, i" there are "i/e electron domains in the /alence shell o" an atom, they will 'e arranged in a(n) %%%%%%%%%% geometry& $) octahedral B) linear C) tetrahedral )) trigonal planar *) trigonal 'ipyramidal $nswer: * Diff: 1 Page Ref: Sec. 9.2 0) $ccording to +,*-. theory, i" there are "our electron domains in the /alence shell o" an atom, they will 'e arranged in a(n) %%%%%%%%%% geometry& $) octahedral B) linear C) tetrahedral )) trigonal planar *) trigonal 'ipyramidal $nswer: C Diff: 1 Page Ref: Sec. 9.2

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories 1) he electron(domain geometry and molecular geometry o" iodine trichloride are %%%%%%%%%% and %%%%%%%%%%, respecti/ely& $) trigonal 'ipyramidal, trigonal planar B) tetrahedral, trigonal pyramidal C) trigonal 'ipyramidal, (shaped )) octahedral, trigonal planar *) (shaped, trigonal planar $nswer: C Diff: 1 Page Ref: Sec. 9.2 2) he molecular geometry o" %%%%%%%%%% is s3uare planar& $) CCl 1 B) 4e!1 C) -50 )) 4e!# *) 6Cl0 $nswer: B Diff: 2 Page Ref: Sec. 9.2 7) he molecular geometry o" the C, # molecule is %%%%%%%%%%& $) linear B) 'ent C) tetrahedral )) trigonal planar *) (shaped $nswer: $ Diff: 1 Page Ref: Sec. 9.2

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories 8) he molecular geometry o" the ,i5 # Cl# molecule is %%%%%%%%%%& $) trigonal planar B) tetrahedral C) trigonal pyramidal )) octahedral *) (shaped $nswer: B Diff: 1 Page Ref: Sec. 9.2 9) he molecular geometry o" the -5Cl # molecule is %%%%%%%%%%& $) 'ent B) trigonal planar C) trigonal pyramidal )) tetrahedral *) (shaped $nswer: C Diff: 2 Page Ref: Sec. 9.2 9) he molecular geometry o" the C5Cl0 molecule is %%%%%%%%%%& $) 'ent B) trigonal planar C) trigonal pyramidal )) tetrahedral *) (shaped $nswer: ) Diff: 1 Page Ref: Sec. 9.2

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories 1:) he molecular geometry o" the ,!# molecule is %%%%%%%%%%& $) linear B) 'ent C) trigonal planar )) tetrahedral *) octahedral $nswer: B Diff: 2 Page Ref: Sec. 9.2
+ 11) he molecular geometry o" the -!1 ion is %%%%%%%%%%&

$) octahedral B) tetrahedral C) trigonal pyramidal )) trigonal planar *) trigonal 'ipyramidal $nswer: B Diff: 1 Page Ref: Sec. 9.2 1#) he ! B ! 'ond angle in the B! # on is appro;imately %%%%%%%%%%& $) 9: < B) 1:9&2 < C) 1#: < )) 19: < *) 7: < $nswer: C Diff: 1 Page Ref: Sec. 9.2

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories 10) he Cl(,i(Cl 'ond angle in the ,iCL # !# molecule is appro;imately %%%%%%%%%%& $) 9: < B) 1:9&2 < C) 1#: < )) 19: < *) 7: < $nswer: B Diff: 1 Page Ref: Sec. 9.2 11) he !(B(! 'ond angle in the B!0 molecule is %%%%%%%%%%& $) 9: < B) 1:9&2 < C) 1#: < )) 19: < *) 7: < $nswer: C Diff: 2 Page Ref: Sec. 9.2 12) he =(,(= 'ond angle in ,= # is slightly less than %%%%%%%%%%& $) 9: < B) 1:9&2 < C) 1#: < )) 19: < *) 7: < $nswer: C Diff: 1 Page Ref: Sec. 9.2

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories 17) he !(>(! 'ond angle in the >!0 molecule is slightly less than %%%%%%%%%%& $) 9: < B) 1:9&2 < C) 1#: < )) 19: < *) 7: < $nswer: B Diff: 1 Page Ref: Sec. 9.2
+ 18) he molecular geometry o" the 5 0 = ion is %%%%%%%%%%& $) linear B) tetrahedral C) 'ent )) trigonal pyramidal *) octahedral

$nswer: ) Diff: 2 Page Ref: Sec. 9.3 19) $ccording to /alence 'ond theory, which or'itals on 'romine atoms o/erlap in the "ormation o" the 'ond in Br# ? $) 0s B) 0p C) 1s )) 1p *) 0d $nswer: ) Diff: 1 Page Ref: Sec. 9.4

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories 19) he electron(domain geometry o" a sul"ur(centered compound is trigonal 'ipyramidal& he hy'ridi@ation o" the central nitrogen atom is %%%%%%%%%%& $) sp B) sp # C) sp0 )) sp0d *) sp0d #

$nswer: ) Diff: 1 Page Ref: Sec. 9.5 #:) he hy'ridi@ation o" or'itals on the central atom in a molecule is sp& he electron( domain geometry around this central atom is %%%%%%%%%%& $) octahedral B) linear C) trigonal planar )) trigonal 'ipyramidal *) tetrahedral $nswer: B Diff: 1 Page Ref: Sec. 9.5 #1) he hy'ridi@ation o" or'itals on the central atom in a molecule is sp # & he electron( domain geometry a'out this central atom is %%%%%%%%%%& $) octahedral B) linear C) trigonal planar )) trigonal 'ipyramidal *) tetrahedral $nswer: C Diff: 1 Page Ref: Sec. 9.5

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories ##) he hy'ridi@ation o" the car'on atom in car'on dio;ide is %%%%%%%%%%& $) sp B) sp # C) sp0 )) sp0d *) sp0d #

$nswer: $ Diff: 1 Page Ref: Sec. 9.5 #0) he hy'ridi@ation o" the central atom in the 4e!1 molecule is %%%%%%%%%%& $) sp B) sp # C) sp0 )) sp0d *) sp0d #

$nswer: * Diff: 2 Page Ref: Sec. 9.5

#1) he electron(domain geometry o" the $s!7 ion is octahedral& used 'y the $s atom "or 'onding are %%%%%%%%%% or'itals&

he hy'rid or'itals

$) sp # d # B) sp0 C) sp0d )) sp0d # *) sp #

$nswer: ) Diff: 2 Page Ref: Sec. 9.5

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories #2) 6n order to produce sp0 hy'rid or'itals, %%%%%%%%%% s atomic or'ital(s) and %%%%%%%%%% p atomic or'ital(s) must 'e mi;ed& $) one, two B) one, three C) one, one )) two, two *) two, three $nswer: B Diff: 1 Page Ref: Sec. 9.5 #7) he angles 'etween sp # or'itals are %%%%%%%%%%& $) 12 < B) 19: < C) 9: < )) 1:9&2 < *) 1#: < $nswer: * Diff: 1 Page Ref: Sec. 9.5 #8) here are %%%%%%%%%% A and %%%%%%%%%% B 'onds in the 5 C C 5 molecule& $) 0 and # B) 0 and 1 C) 1 and 0 )) # and 0 *) 2 and : $nswer: $ Diff: 1 Page Ref: Sec. 9.6

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories #9) here are %%%%%%%%%% A and %%%%%%%%%% B 'onds in the 5 # CCCCC5 # molecule& $) 1, # B) 7, 1 C) #, # )) #, 7 *) 7, # $nswer: * Diff: 1 Page Ref: Sec. 9.6 #9) he total num'er o" B 'onds in the 5 C C C C C > molecule is %%%%%%%%%%& $) 0 B) 1 C) 7 )) 9 *) 1# $nswer: C Diff: 1 Page Ref: Sec. 9.6

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories 0:) here is/are %%%%%%%%%% A 'ond(s) in the molecule 'elow&

$) 1 B) # C) 1# )) 10 *) 19 $nswer: C Diff: 1 Page Ref: Sec. 9.6 01) here is/are %%%%%%%%%% B 'ond(s) in the molecule 'elow&

$) : B) 1 C) # )) 1 *) 17 $nswer: C Diff: 1 Page Ref: Sec. 9.6

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories 0#) here is/are %%%%%%%%%% B 'ond(s) in the molecule 'elow&

$) 8 B) 7 C) # )) 1 *) : $nswer: ) Diff: 1 Page Ref: Sec. 9.6 00) he Lewis structure o" car'on mono;ide is gi/en 'elow& he hy'ridi@ations o" the car'on and o;ygen atoms in car'on mono;ide are %%%%%%%%%% and %%%%%%%%%%, respecti/ely& :C =: $) sp, sp0 B) sp # , sp0 C) sp0 , sp # )) sp, sp *) sp # , sp #

$nswer: ) Diff: 2 Page Ref: Sec. 9.6

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories 9.2 Multiple-Choice Questions 1) he 'asis o" the +,*-. model o" molecular 'onding is %%%%%%%%%%& $) regions o" electron density on an atom will organi@e themsel/es so as to ma;imi@e s( character B) regions o" electron density in the /alence shell o" an atom will arrange themsel/es so as to ma;imi@e o/erlap C) atomic or'itals o" the 'onding atoms must o/erlap "or a 'ond to "orm )) electron domains in the /alence shell o" an atom will arrange themsel/es so as to minimi@e repulsions *) hy'rid or'itals will "orm as necessary to, as closely as possi'le, achie/e spherical symmetry $nswer: ) Diff: 1 Page Ref: Sec. 9.2 #) $ccording to +,*-. theory, i" there are three electron domains in the /alence shell o" an atom, they will 'e arranged in a(n) %%%%%%%%%% geometry& $) octahedral B) linear C) tetrahedral )) trigonal planar *) trigonal 'ipyramidal $nswer: ) Diff: 2 Page Ref: Sec. 9.2

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories 0) Cl! 0 has D (shapedD geometry& here are %%%%%%%%%% non('onding domains in this molecule& $) : B) 1 C) # )) 0 *) 1 $nswer: C Diff: 4 Page Ref: Sec. 9.2
1) he electron domain and molecular geometry o" Br= # is %%%%%%%%%&

$) tetrahedral, trigonal planar B) trigonal planar, trigonal planar C) trigonal pyramidal, linear )) tetrahedral, 'ent *) trigonal pyramidal, seesaw $nswer: ) Diff: 4 Page Ref: Sec. 9.2 2) 6n counting the electron domains around the central atom in +,*-. theory, a %%%%%%%%%% is not included& $) non'onding pair o" electrons B) single co/alent 'ond C) core le/el electron pair )) dou'le co/alent 'ond *) triple co/alent 'ond $nswer: C Diff: 1 Page Ref: Sec. 9.2

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories 7) he electron(domain geometry o" %%%%%%%%%% is tetrahedral& $) CBr1 B) -50 C) CCl # Br# )) 4e!1 *) all o" the a'o/e e;cept 4e!1 $nswer: * Diff: 2 Page Ref: Sec. 9.2
# 8) he = C = 'ond angle in the C=0 ion is appro;imately %%%%%%%%%%&

$) 9: < B) 1:9&2 < C) 1#: < )) 19: < *) 7: < $nswer: C Diff: 2 Page Ref: Sec. 9.2 9) =" the "ollowing species, %%%%%%%%%% will ha/e 'ond angles o" 1#: <& $) -50 B) Cl!0 C) >Cl0 )) BCl0 *) $ll o" these will ha/e 'ond angles o" 1#: <& $nswer: ) Diff: 1 Page Ref: Sec. 9.2

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories

9) he molecular geometry o" the Br=0 ion is %%%%%%%%%%&

$) trigonal pyramidal B) trigonal planar C) 'ent )) tetrahedral *) (shaped $nswer: $ Diff: 2 Page Ref: Sec. 9.2 1:) he molecular geometry o" the le"t(most car'on atom in the molecule 'elow is %%%%%%%%%%&

$) trigonal planar B) trigonal 'ipyramidal C) tetrahedral )) octahedral *) (shaped $nswer: C Diff: 1 Page Ref: Sec. 9.2

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories 11) he molecular geometry o" the right(most car'on in the molecule 'elow is %%%%%%%%%%&

$) trigonal planar B) trigonal 'ipyramidal C) tetrahedral )) octahedral *) (shaped $nswer: $ Diff: 1 Page Ref: Sec. 9.2 1#) he 'ond angles marEed a, ', and c in the molecule 'elow are a'out %%%%%%%%%%, %%%%%%%%%%, and %%%%%%%%%%, respecti/ely&

$) 9: <, 9: <, 9: < B) 1#: <, 1#: <, 9: < C) 1#: <, 1#: <, 1:9&2 < )) 1:9&2 <, 1#: <, 1:9&2 < *) 1:9&2 <, 9: <, 1#: < $nswer: ) Diff: 2 Page Ref: Sec. 9.2

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories 10) he 'ond angles marEed a, ', and c in the molecule 'elow are a'out %%%%%%%%%%, %%%%%%%%%%, and %%%%%%%%%%, respecti/ely&

$) 1:9&2 <, 1:9&2 <, 1:9&2 < B) 1#: <, 1:9&2 <, 1#: < C) 1:9&2 <, 1:9&2 <, 1#: < )) 9: <, 19: <, 9: < *) 1:9&2 <, 1:9&2 <, 9: < $nswer: C Diff: 2 Page Ref: Sec. 9.2 11) he 'ond angle marEed a in the "ollowing molecule is a'out %%%%%%%%%%&

$) 9: < B) 1:9&2 < C) 1#: < )) 19: < *) 7: < $nswer: C Diff: 1 Page Ref: Sec. 9.2

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories

12) he central iodine atom in the 6Cl 1 ion has %%%%%%%%%% non'onded electron pairs and %%%%%%%%%% 'onded electron pairs in its /alence shell&

$) #, # B) 0, 1 C) 1, 0 )) 0, # *) #, 1 $nswer: * Diff: 1 Page Ref: Sec. 9.2 17) he central iodine atom in 6!2 has %%%%%%%%%% un'onded electron pairs and %%%%%%%%%% 'onded electron pairs in its /alence shell& $) 1, 2 B) :, 2 C) 2, 1 )) 1, 1 *) 1, 1 $nswer: $ Diff: 1 Page Ref: Sec. 9.2 18) he central 4e atom in the 4e!1 molecule has %%%%%%%%%% un'onded electron pairs and %%%%%%%%%% 'onded electron pairs in its /alence shell& $) 1, 1 B) #, 1 C) 1, : )) 1, 1 *) 1, # $nswer: B Diff: 1 Page Ref: Sec. 9.2

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories 19) $n electron domain consists o" %%%%%%%%%%& a) a non'onding pair o" electrons ') a single 'ond c) a multiple 'ond $) a only B) ' only C) c only )) a, ', and c *) ' and c $nswer: ) Diff: 1 Page Ref: Sec. 9.2 19) $ccording to +,*-. theory, i" there are three electron domains on a central atom, they will 'e arranged such that the angles 'etween the domains are %%%%%%%%%%& $) 9: < B) 19: < C) 1:9&2 < )) 07: < *) 1#: < $nswer: * Diff: 1 Page Ref: Sec. 9.2 #:) $ccording to +,*-. theory, i" there are "our electron domains on a central atom, they will 'e arranged such that the angles 'etween the domains are %%%%%%%%%%& $) 1#: < B) 1:9&2 < C) 19: < )) 07: < *) 9: < $nswer: B Diff: 1 Page Ref: Sec. 9.2

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories

#1) $ccording to +,*-. theory, i" there are two electron domains on a central atom, they will 'e arranged such that the angles 'etween the domains are %%%%%%%%%%& $) 07: < B) 1#: < C) 1:9&2 < )) 19: < *) 9: < $nswer: ) Diff: 1 Page Ref: Sec. 9.2 ##) he electron(domain geometry and the molecular geometry o" a molecule o" the general "ormula $Bn are %%%%%%%%%%& $) ne/er the same B) always the same C) sometimes the same )) not related *) mirror images o" one another $nswer: C Diff: 1 Page Ref: Sec. 9.2 #0) he electron(domain geometry and the molecular geometry o" a molecule o" the general "ormula $Bn will always 'e the same i" %%%%%%%%%%& $) there are no lone pairs on the central atom B) there is more than one central atom C) n is greater than "our )) n is less than "our *) the octet rule is o'eyed $nswer: $ Diff: 1 Page Ref: Sec. 9.2

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories #1) he 'ond angles in a trigonal planar molecule are %%%%%%%%%% degrees& $) 1#: B) 1:9&2 C) 9: )) 12 *) F 12 $nswer: $ Diff: 2 Page Ref: Sec. 9.2 #2) $ molecule has the "ormula $B 0 and the central atom is in a di""erent plane "rom the surrounding three atoms& 6ts molecular shape is %%%%%%%%%%& $) tetrahedral B) trigonal pyramidal C) linear )) (shaped *) 'ent $nswer: B Diff: 2 Page Ref: Sec. 9.2 #7) -Cl 2 has %%%%%%%%%% electron domains and a %%%%%%%%%% molecular arrangement& $) 7, trigonal 'ipyramidal B) 7, tetrahedral C) 2, s3uare pyramidal )) 2, trigonal 'ipyramidal *) 7, seesaw $nswer: ) Diff: 3 Page Ref: Sec. 9.2

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories #8) !or molecules o" the general "ormula $Bn n can 'e greater than "our %%%%%%%%%%& $) "or any element $ B) only when $ is an element "rom the third period or 'elow the third period C) only when $ is 'oron or 'eryllium )) only when $ is car'on *) only when $ is 4e $nswer: B Diff: 2 Page Ref: Sec. 9.2 Consider the following species when answering the following !estions: (i) -Cl0 (ii) CCl 1 (iii) eCl 1 (i/) 4e!1 (/) ,!7

#9) !or which o" the molecules is the molecular geometry (shape) the same as the +,*-. electron domain arrangement (electron domain geometry)? $) (i) and (ii) B) (i) and (iii) C) (ii) and (/) )) (i/) and (/) *) (/) only $nswer: C Diff: 2 Page Ref: Sec. 9.2

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories #9) =" the molecules 'elow, only %%%%%%%%%% is polar& $) ,'!2 B) $s5 0 C) 6 # )) ,!7 *) C5 1 $nswer: B Diff: 2 Page Ref: Sec. 9.3 0:) =" the molecules 'elow, only %%%%%%%%%% is nonpolar& $) C= # B) 5 # = C) >5 0 )) 5Cl *) eCl# $nswer: $ Diff: 1 Page Ref: Sec. 9.3 01) =" the molecules 'elow, only %%%%%%%%%% is polar& $) CCl 1 B) C5 1 C) ,e!1 )) ,iCl1 $nswer: C Diff: 1 Page Ref: Sec. 9.3

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories 0#) =" the molecules 'elow, only %%%%%%%%%% is nonpolar& $) B!0 B) >!0 C) 6!0 )) -Br0 *) BrCl0 $nswer: $ Diff: 1 Page Ref: Sec. 9.3 00) hree monosul"ur "luorides are o'ser/ed: ,!# , ,!1 , and ,!7 & =" these, %%%%%%%%%% is/are polar& $) ,!# only B) ,!# and ,!1 only C) ,!1 only )) ,!7 only *) ,!# , ,!1 and ,!7 $nswer: B Diff: 2 Page Ref: Sec. 9.3 01) he molecular geometry o" the BeCl # molecule is %%%%%%%%%%, and this molecule is %%%%%%%%%%& $) linear, nonpolar B) linear, polar C) 'ent, nonpolar )) 'ent, polar *) trigonal planar, polar $nswer: $ Diff: 1 Page Ref: Sec. 9.3

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories 02) he molecular geometry o" the -!0 molecule is %%%%%%%%%%, and this molecule is %%%%%%%%%%& $) trigonal planar, polar B) trigonal planar, nonpolar C) trigonal pyramidal, polar )) trigonal pyramidal, nonpolar *) tetrahedral, unipolar $nswer: C Diff: 2 Page Ref: Sec. 9.3 07) =" the "ollowing molecules, only %%%%%%%%%% is polar& $) BeCl # B) B!0 C) CBr1 )) ,i5 # Cl# *) Cl# $nswer: ) Diff: 1 Page Ref: Sec. 9.3 08) =" the "ollowing molecules, only %%%%%%%%%% is polar& $) CCl 1 B) BCl0 C) >Cl0 )) BeCl # *) Cl# $nswer: C Diff: 1 Page Ref: Sec. 9.3

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories 09) !or molecules with only one central atom, how many lone pairs on the central atom guarantees molecular polarity? $) 1 B) # C) 1 or # )) 0 *) 1 or 0 $nswer: $ Diff: 1 Page Ref: Sec. 9.3 09) he molecular geometry o" the C5!0 molecule is %%%%%%%%%%, and the molecule is %%%%%%%%%%& $) trigonal pyramidal, polar B) tetrahedral, nonpolar C) seesaw, nonpolar )) tetrahedral, polar *) seesaw, polar $nswer: ) Diff: 1 Page Ref: Sec. 9.3 1:) he molecular geometry o" the BCl0 molecule is %%%%%%%%%%, and this molecule is %%%%%%%%%%& $) trigonal pyramidal, polar B) trigonal pyramidal, nonpolar C) trigonal planar, polar )) trigonal planar, nonpolar *) trigonal 'ipyramidal, polar $nswer: ) Diff: 1 Page Ref: Sec. 9.3

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories 11) $ccording to /alence 'ond theory, which or'itals o/erlap in the "ormation o" the 'ond in 5Br? $) 1s on 5 and 1p on Br B) 1s on 5 and 1s on Br C) 1s on 5 and 0p on Br )) #s on 5 and 1p on Br *) #s on 5 and 0p on Br $nswer: $ Diff: 1 Page Ref: Sec. 9.4 Consider the following species when answering the following !estions: (i) -Cl0 (ii) CCl 1 (iii) eCl 1 (i/) 4e!1 (/) ,!7

1#) Ghich o" the molecules has a see(saw shape? $) (i) B) (ii) C) (iii) )) (i/) *) (/) $nswer: C Diff: 3 Page Ref: Sec. 9.3" 9.5 10) he com'ination o" two atomic or'itals results in the "ormation o" %%%%%%%%%% molecular or'itals& $) 1 B) # C) 0 )) 1 *) : $nswer: B Diff: 1 Page Ref: Sec. 9.5

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories

11) he electron(domain geometry o" a car'on(centered compound is tetrahedral& hy'ridi@ation o" the central car'on atom is %%%%%%%%%%& $) sp B) sp # C) sp0 )) sp0d *) sp0d #

he

$nswer: C Diff: 2 Page Ref: Sec. 9.5 12) =" the "ollowing, only %%%%%%%%%% has sp # hy'ridi@ation o" the central atom& $) -50 # B) C=0 C) 6Cl0
)) 60 *) -!2

$nswer: B )i"": 1 -age .e": ,ec& 9&2

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories 17) =" the "ollowing, the central atom is sp0d # hy'ridi@ed only in %%%%%%%%%%& $) -Cl2 B) 4e!1 C) -50 )) Br0 *) Be!# $nswer: B Diff: 1 Page Ref: Sec. 9.5 18) he sp0d # atomic hy'rid or'ital set accommodates %%%%%%%%%% electron domains& $) # B) 0 C) 1 )) 2 *) 7 $nswer: * Diff: 1 Page Ref: Sec. 9.5 19) he sp # atomic hy'rid or'ital set accommodates %%%%%%%%%% electron domains& $) # B) 0 C) 1 )) 2 *) 7 $nswer: B Diff: 1 Page Ref: Sec. 9.5

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories 19) he hy'ridi@ations o" nitrogen in >!0 and >5 0 are %%%%%%%%%% and %%%%%%%%%%, respecti/ely& $) sp # , sp # B) sp, sp0 C) sp0 , sp )) sp0 , sp0 *) sp # , sp0

$nswer: ) Diff: 1 Page Ref: Sec. 9.5 2:) he hy'ridi@ations o" iodine in 6!0 and 6!2 are %%%%%%%%%% and %%%%%%%%%%, respecti/ely& $) sp0 , sp0d B) sp0d , sp0d # C) sp0d , sp0 )) sp0d # , sp0d *) sp0d # , sp0d #

$nswer: B Diff: 1 Page Ref: Sec. 9.5

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories 21) he hy'ridi@ations o" 'romine in Br!2 and o" arsenic in $s!2 are %%%%%%%%%% and %%%%%%%%%%, respecti/ely& $) sp0 , sp0d B) sp0d , sp0d # C) sp0d , sp0 )) sp0d # , sp0d *) sp0d # , sp0d #

$nswer: ) Diff: 1 Page Ref: Sec. 9.5 2#) he hy'rid or'itals used "or 'onding 'y the sul"ur atom in the ,!1 molecule are %%%%%%%%%% or'itals& $) sp B) sp # C) sp0 )) sp0d *) sp0d #

$nswer: ) Diff: 1 Page Ref: Sec. 9.5

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories 20) he hy'rid or'itals used "or 'onding 'y 4e in the unsta'le 4e!# molecule are %%%%%%%%%% or'itals& $) sp # B) sp0 C) sp0d )) sp0d # *) sp $nswer: C Diff: 1 Page Ref: Sec. 9.5 21) he hy'ridi@ation scheme "or Be! # is %%%%%%%%%%& $) sp B) sp # C) sp0 )) sp0d *) sp0d #

$nswer: $ Diff: 1 Page Ref: Sec. 9.5

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories 22) he hy'ridi@ation o" the o;ygen atom la'eled y in the structure 'elow is %%%%%%%%%%& he C = 5 'ond angle is %%%%%%%%%%&

$) sp, 19: < B) sp # , 1:9&2 < C) sp0 , 1:9&2 < )) sp0d # , 9: < *) sp, 9: < $nswer: C Diff: 2 Page Ref: Sec. 9.5 27) he electron(domain geometry o" the $s!2 molecule is trigonal 'ipyramidal& hy'rid or'itals used 'y the $s atom "or 'onding are %%%%%%%%%% or'itals& $) sp # d # B) sp0 C) sp0d # )) sp0d *) sp #

he

$nswer: ) Diff: 1 Page Ref: Sec. 9.5

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories 28) %%%%%%%%%% hy'rid or'itals are used "or 'onding 'y 4e in the 4e!1 molecule& $) sp # B) sp0 C) sp0d )) sp0d # *) sp $nswer: ) Diff: 1 Page Ref: Sec. 9.5 Consider the following species when answering the following !estions: (i) -Cl0 (ii) CCl 1 (iii) eCl 1 (i/) 4e!1 (/) ,!7

29) 6n which o" the molecules does the central atom utili@e d or'itals to "orm hy'rid or'itals? $) (i) and (ii) B) (iii) only C) (i) and (/) )) (iii), (i/), and (/) *) (/) only $nswer: ) Diff: 2 Page Ref: Sec. 9.5

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories 29) 6n which o" the molecules is the central atom sp0d # hy'ridi@ed? $) (i) and (ii) B) (iii) only C) (iii) and (i/) )) (i/) and (/) *) (/) only $nswer: ) Diff: 1 Page Ref: Sec. 9.5 7:) here are %%%%%%%%%% unhy'ridi@ed p atomic or'itals in an sp(hy'ridi@ed car'on atom& $) : B) 1 C) # )) 0 *) 1 $nswer: C Diff: 1 Page Ref: Sec. 9.5 71) Ghen three atomic or'itals are mi;ed to "orm hy'rid or'itals, how many hy'rid or'itals are "ormed? $) one B) si; C) three )) "our *) "i/e $nswer: C Diff: 1 Page Ref: Sec. 9.5

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories 7#) he 'lending o" one s atomic or'ital and two p atomic or'itals produces %%%%%%%%%%& $) three sp hy'rid or'itals B) two sp # hy'rid or'itals C) three sp0 hy'rid or'itals )) two sp0 hy'rid or'itals *) three sp # hy'rid or'itals

$nswer: * Diff: 1 Page Ref: Sec. 9.5 70) $ triatomic molecule cannot 'e linear i" the hy'ridi@ation o" the central atoms is %%%%%%%%%%& $) sp B) sp # C) sp0 )) sp # or sp0 *) sp # d or sp0d #

$nswer: ) Diff: 1 Page Ref: Sec. 9.5 71) +alence 'ond theory does not address the issue o" %%%%%%%%%%& $) e;cited states o" molecules B) molecular shape C) co/alent 'onding )) hy'ridi@ation *) multiple 'onds $nswer: $ Diff: 2 Page Ref: Sec. 9.5

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories 72) $ typical dou'le 'ond %%%%%%%%%%& $) is stronger and shorter than a single 'ond B) consists o" one A 'ond and one B 'ond C) imparts rigidity to a molecule )) consists o" two shared electron pairs *) $ll o" the a'o/e answers are correct& $nswer: * Diff: 1 Page Ref: Sec. 9.6 77) $ typical triple 'ond %%%%%%%%%%& $) consists o" one A 'ond and two B 'onds B) consists o" three shared electrons C) consists o" two A 'onds and one B 'ond )) consists o" si; shared electron pairs *) is longer than a single 'ond $nswer: $ Diff: 1 Page Ref: Sec. 9.6 78) 6n a polyatomic molecule, Dlocali@edD 'onding electrons are associated with %%%%%%%%%%& $) one particular atom B) two particular atoms C) all o" the atoms in the molecule )) all o" the B 'onds in the molecule *) two or more A 'onds in the molecule $nswer: B Diff: 1 Page Ref: Sec. 9.6

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories 79) here are %%%%%%%%%% A 'onds and %%%%%%%%%% B 'onds in 5 0C C5 # C5 = C5 C5 # C C5 & $) 11, # B) 1:, 0 C) 1#, # )) 10, # *) 17, 0 $nswer: * Diff: 4 Page Ref: Sec. 9.6 79) Ghich o" the "ollowing molecules or ions will e;hi'it delocali@ed 'onding? ,= #
# $) ,=# , ,=0 , and ,=0 # B) ,=0 only C) ,= # and ,=0 # )) ,=0 and ,=0 *) >one o" the a'o/e will e;hi'it delocali@ed 'onding&

,=0

,=0#

$nswer: C Diff: 1 Page Ref: Sec. 9.6

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories 8:) Ghich o" the "ollowing molecules or ions will e;hi'it delocali@ed 'onding? >= #
+ $) >5 1 and > 0 B) >= # only + C) >= # , >5 1 , and > 0 )) > 0 only *) >= # and >0

>5 1 +

> 0

$nswer: B Diff: 1 Page Ref: Sec. 9.6 81) 6n order to e;hi'it delocali@ed B 'onding, a molecule must ha/e %%%%%%%%%%& $) at least two B 'onds B) at least two resonance structures C) at least three A 'onds )) at least "our atoms *) trigonal planar electron domain geometry $nswer: B Diff: 1 Page Ref: Sec. 9.6 8#) 6n a typical multiple 'ond, the A 'ond results "rom o/erlap o" %%%%%%%%%% or'itals and the B 'ond(s) result "rom o/erlap o" %%%%%%%%%% or'itals& $) hy'rid, atomic B) hy'rid, hy'rid C) atomic, hy'rid )) hy'rid, hy'rid or atomic *) hy'rid or atomic, hy'rid or atomic $nswer: $ Diff: 1 Page Ref: Sec. 9.6

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories 80) he car'on(car'on A 'ond in ethylene, 5 # C = C , results "rom the o/erlap o" %%%%%%%%%%& $) sp hy'rid or'itals B) sp0 hy'rid or'itals C) sp # hy'rid or'itals )) s atomic or'itals *) p atomic or'itals $nswer: C Diff: 1 Page Ref: Sec. 9.6 81) he B 'ond in ethylene, 5 # C = C5 # , results "rom the o/erlap o" %%%%%%%%%%& $) sp0 hy'rid or'itals B) s atomic or'itals C) sp hy'rid or'itals )) sp # hy'rid or'itals *) p atomic or'itals $nswer: * Diff: 1 Page Ref: Sec. 9.6 82) $ typical triple 'ond consists o" %%%%%%%%%%& $) three sigma 'onds B) three pi 'onds C) one sigma and two pi 'onds )) two sigma and one pi 'ond *) three ionic 'onds $nswer: C Diff: 1 Page Ref: Sec. 9.6

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories 87) he > > 'ond in 5>>5 consists o" %%%%%%%%%%& $) one A 'ond and one B 'ond B) one A 'ond and two B 'onds C) two A 'onds and one B 'ond )) two A 'onds and two B 'onds *) one A 'ond and no B 'onds $nswer: $ Diff: 1 Page Ref: Sec. 9.6 88) he hy'ridi@ation o" the terminal car'ons in the 5 # C = C = C5 # molecule is %%%%%%%%%%& $) sp B) sp # C) sp0 )) sp0d *) sp0d #

$nswer: B Diff: 2 Page Ref: Sec. 9.6 89) he hy'ridi@ation o" nitrogen in the 5 C >: molecule is %%%%%%%%%%& $) sp B) s # p C) s0p )) sp # *) sp0

$nswer: $ Diff: 1 Page Ref: Sec. 9.6

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories 89) he hy'ridi@ation o" the car'on atom la'eled ; in the molecule 'elow is %%%%%%%%%%&

$) sp B) sp # C) sp0 )) sp0d *) sp0d #

$nswer: B Diff: 1 Page Ref: Sec. 9.6 9:) he hy'ridi@ation o" the o;ygen atom la'eled ; in the structure 'elow is %%%%%%%%%%&

$) sp B) sp # C) sp0 )) sp0d *) sp0d #

$nswer: B Diff: 1 Page Ref: Sec. 9.6

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories 91) he Lewis structure o" car'on dio;ide is gi/en 'elow& he hy'ridi@ation o" the car'on atom in car'on dio;ide is %%%%%%%%%%&

$) sp0 B) sp # C) sp )) sp #d *) sp # d #

$nswer: C Diff: 2 Page Ref: Sec. 9.6 9#) *lectrons in %%%%%%%%%% 'onds remain locali@ed 'etween two atoms& *lectrons in %%%%%%%%%% 'onds can 'ecome delocali@ed 'etween more than two atoms& $) pi, sigma B) sigma, pi C) pi, pi )) sigma, sigma *) ionic, sigma $nswer: B Diff: 2 Page Ref: Sec. 9.6

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories 90) ,tructural changes around a dou'le 'ond in the %%%%%%%%%% portion o" the rhodopsin molecule trigger the chemical reactions that result in /ision& $) protein B) opsin C) retinal )) cones *) rods $nswer: C Diff: 3 Page Ref: Sec. 9.6 91) he 'ond order o" any molecule containing e3ual num'ers o" 'onding and anti'onding electrons is %%%%%%%%%%& $) : B) 1 C) # )) 0 *) 1/# $nswer: $ Diff: 3 Page Ref: Sec. 9.# 92) 6n comparing the same two atoms 'onded together, the %%%%%%%%%% the 'ond order, the %%%%%%%%%% the 'ond length, and the %%%%%%%%%% the 'ond energy& $) greater, shorter, greater B) greater, greater, greater C) greater, longer, greater )) greater, greater, smaller *) smaller, greater, greater $nswer: $ Diff: 4 Page Ref: Sec. 9.#

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories 97) 6n molecular or'ital theory, the A1s or'ital is %%%%%%%%%% and the A or'ital is 1s %%%%%%%%%% in the 5 # molecule& $) "illed, "illed B) "illed, empty C) "illed, hal"("illed )) hal"("illed, "illed *) empty, "illed $nswer: B Diff: 4 Page Ref: Sec. 9.#
+ 98) Based on molecular or'ital theory, the 'ond orders o" the 5 5 'onds in 5 # , 5 # , and 5 # are %%%%%%%%%%, respecti/ely

$) 1, :, and : B) 1, 1/#, and : C) 1, :, and 1/# )) 1, 1/#, and 1/# *) 1, #, and : $nswer: ) Diff: 4 Page Ref: Sec. 9.#
+ 99) Based on molecular or'ital theory, the 'ond order o" the 5 5 'ond in the 5 # ion is %%%%%%%%%%&

$) : B) 1/# C) 1 )) 0/# *) # $nswer: B Diff: 4 Page Ref: Sec. 9.#

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories 99) $n anti'onding B or'ital contains a ma;imum o" %%%%%%%%%% electrons& $) 1 B) # C) 1 )) 7 *) 9 $nswer: B Diff: 3 Page Ref: Sec. 9.# 9:) $ccording to M= theory, o/erlap o" two s atomic or'itals produces %%%%%%%%%%& $) one 'onding molecular or'ital and one hy'rid or'ital B) two 'onding molecular or'itals C) two 'onding molecular or'itals and two anti'onding molecular or'itals )) two 'onding molecular or'itals and one anti'onding molecular or'ital *) one 'onding molecular or'ital and one anti'onding molecular or'ital $nswer: * Diff: 3 Page Ref: Sec. 9.# 91) $ molecular or'ital can accommodate a ma;imum o" %%%%%%%%%% electron(s)& $) one B) two C) "our )) si; *) twel/e $nswer: B Diff: 3 Page Ref: Sec. 9.#

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories 9#) Molecular =r'ital theory correctly predicts paramagnetism o" o;ygen gas, = # & his is 'ecause %%%%%%%%%%& $) the 'ond order in = # can 'e shown to 'e e3ual to #& B) there are more electrons in the 'onding or'itals than in the anti'onding or'itals& C) the energy o" the B#p M=s is higher than that o" the A#p M= )) there are two unpaired electrons in the M= electron con"iguration o" = # *) the = = 'ond distance is relati/ely short $nswer: ) Diff: 4 Page Ref: Sec. 9.#" 9.$ 90) Molecular =r'ital theory correctly predicts diamagnetism o" "luorine gas, !# & his is 'ecause %%%%%%%%%%& $) the 'ond order in !# can 'e shown to 'e e3ual to 1& B) there are more electrons in the 'onding or'itals than in the anti'onding or'itals& C) all electrons in the M= electron con"iguration o" !# are paired& )) the energy o" the B#p M=s is higher than that o" the A#p M= *) the ! ! 'ond enthalpy is /ery low $nswer: C Diff: 4 Page Ref: Sec. 9.#" 9.$

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories 91) Based on molecular or'ital theory, the only molecule in the list 'elow that has unpaired electrons is %%%%%%%%%%& $) C # B) > # C) !# )) = # *) Li # $nswer: ) Diff: 3 Page Ref: Sec. 9.$ 92) Based on molecular or'ital theory, there are %%%%%%%%%% unpaired electrons in the =!+ ion& $) : B) 0 C) 1 )) # *) 1/# $nswer: ) Diff: 3 Page Ref: Sec. 9.$ 97) Based on molecular or'ital theory, the 'ond order o" the > > 'ond in the > # molecule is %%%%%%%%%%& $) : B) 1 C) # )) 0 *) 2 $nswer: ) Diff: 4 Page Ref: Sec. 9.$

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories

#+ 98) Based on molecular or'ital theory, the 'ond order o" the > > 'ond in the > # ion is %%%%%%%%%%&

$) : B) 0 C) 1 )) # *) 1/# $nswer: ) Diff: 4 Page Ref: Sec. 9.$ 99) Based on molecular or'ital theory, the 'ond order o" the Be Be 'ond in the Be # molecule is %%%%%%%%%%& $) : B) 1 C) # )) 0 *) 1 $nswer: $ Diff: 4 Page Ref: Sec. 9.$ 99) Based on molecular or'ital theory, the 'ond order o" the C C 'ond in the C # molecule is %%%%%%%%%%& $) : B) 1 C) # )) 0 *) 1 $nswer: C Diff: 4 Page Ref: Sec. 9.$

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories 1::) =" the "ollowing, only %%%%%%%%%% appears to gain mass in a magnetic "ield& $) C # B) > # C) !# )) = # *) Li # $nswer: ) Diff: 4 Page Ref: Sec. 9.$ 1:1) =" the "ollowing, %%%%%%%%%% appear(s) to gain mass in a magnetic "ield& B# $) = # only B) > # only C) B# and > # )) > # and = # *) B# and = # $nswer: * Diff: 4 Page Ref: Sec. 9.$ 1:#) $ccording to M= theory, o/erlap o" two p atomic or'itals produces %%%%%%%%%%& $) two 'onding molecular or'itals B) one 'onding molecular or'ital and one anti'onding molecular or'ital C) two 'onding molecular or'itals and two anti'onding molecular or'itals )) two 'onding molecular or'itals and one anti'onding molecular or'ital *) three 'onding molecular or'itals and three anti'onding molecular or'itals $nswer: B Diff: 3 Page Ref: Sec. 9.$ ># =#

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories 1:0) $ccording to M= theory, o/erlap o" two p atomic or'itals produces %%%%%%%%%%& $) one B M= and one A M= B) one B M= and one A M= C) one B M= and one B M= or one A M= and one A M= )) one B + M= and one A M= *) two B M=s, two B + M=s, one A M=, and one A M= $nswer: C Diff: 3 Page Ref: Sec. 9.$ 1:1) $n anti'onding M= %%%%%%%%%% the corresponding 'onding M=& $) is always lower in energy than B) can accommodate more electrons than C) can accommodate "ewer electrons than )) is always higher in energy than *) is always degenerate with $nswer: ) Diff: 3 Page Ref: Sec. 9.$ 1:2) he more e""ecti/ely two atomic or'itals o/erlap, %%%%%%%%%%& $) the more 'onding M=s will 'e produced 'y the com'ination B) the higher will 'e the energy o" the resulting 'onding M= and the lower will 'e the energy o" the resulting anti'onding M= C) the higher will 'e the energies o" 'oth 'onding and anti'onding M=s that result )) the "ewer anti'onding M=s will 'e produced 'y the com'ination *) the lower will 'e the energy o" the resulting 'onding M= and the higher will 'e the energy o" the resulting anti'onding M= $nswer: * Diff: 4 Page Ref: Sec. 9.$

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories 1:7) he 'ond order o" a homonuclear diatomic molecule can 'e decreased 'y %%%%%%%%%%& $) remo/ing electrons "rom a 'onding M= or adding electrons to an anti'onding M= B) adding electrons to a 'onding M= or remo/ing electrons "rom an anti'onding M= C) adding electrons to any M= )) remo/ing electrons "rom any M= *) he 'ond order o" a homonuclear diatomic molecule cannot 'e decreased 'y any means& $nswer: $ Diff: 4 Page Ref: Sec. 9.$ 1:8) he order o" M= energies in B# , C # , and > # (A#p > B#p) , is di""erent "rom the order in = # , !# , and >e # (A#p < B#p) his is due to %%%%%%%%%%& $) less e""ecti/e o/erlap o" p or'itals in = # , !#, and >e # B) the more metallic character o" 'oron, car'on and nitrogen as compared to o;ygen, "luorine, and neon C) greater #s(#p interaction in = # , !# , and >e # )) greater #s(#p interaction in B# C # , and > # *) less e""ecti/e o/erlap o" p or'itals in B# , C # , and > # $nswer: ) Diff: 5 Page Ref: Sec. 9.$ 9.3 Short Answer Questions 1) Ghat is the molecular geometry o" a molecule that has three 'onding and two non( 'onding domains? $nswer: (shaped Diff: 4 Page Ref: Sec. 9.2

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories #) 6n the /alence shell o" an atom there are si; electron domains& hey will 'e arranged in a (an) %%%%%%%%%% geometry& $nswer: octahedral Diff: 5 Page Ref: Sec. 9.2 0) Ghat are the three 'ond angles in the trigonal 'ipyramidal structure? $nswer: 9: <, 1#: <, 19: < Diff: 4 Page Ref: Sec. 9.2 1) hree molecules ha/e similar electron domains, 'ut di""erent molecular shapes& Ghy? $nswer: di""erent num'ers o" non('onding domains Diff: 4 Page Ref: Sec. 9.2 2) he 1s hydrogen or'ital o/erlaps with the %%%%%%%%%% iodine or'ital in 56& $nswer: 2p Diff: 2 Page Ref: Sec 9.5 7) $ co/alent 'ond in which o/erlap regions lie a'o/e and 'elow an internuclear a;is is called a(n) %%%%%%%%%%& $nswer: B 'ond Diff: 2 Page Ref: Sec 9.6

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories 8) he sensation o" /ision results "rom a ner/e impulse that is triggered 'y the separation o" retinal "rom %%%%%%%%%%& $nswer: opsin Diff: 2 Page Ref: Sec 9.6 9) 6n molecular or'ital theory the sta'ility o" a co/alent 'ody is related to its %%%%%%%%%%& $nswer: 'ond order Diff: 2 Page Ref: Sec 9.# 9) *ach molecular or'ital can accommodate, at most, two electrons with their spins paired& his is called the %%%%%%%%%%& $nswer: -auli principle Diff: 4 Page Ref: Sec 9.$ 1:) he more unpaired electrons in a species, the stronger is the "orce o" magnetic attraction& his is called %%%%%%%%%%& $nswer: paramagnetism Diff: 1 Page Ref: Sec 9.$ 9.4 True !alse Questions 1) -ossi'le shapes o" $B0 molecules are linear, trigonal planar, and (shaped& $nswer: !alse Diff: 2 Page Ref: Sec 9.1

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories #) Boron tri"luoride has three 'onding domains and its electron domain geometry is trigonal planar& $nswer: rue Diff: 2 Page Ref: Sec 9.2 0) *lectron domains "or single 'onds e;ert greater "orce on adHacent domains than the electron domains "or multiple 'onds& $nswer: !alse Diff: 1 Page Ref: Sec 9.2 1) he 3uantitati/e amount o" charge separation in a diatomic molecule contri'utes to the dipole moment o" that molecule& $nswer: rue Diff: 1 Page Ref: Sec 9.3 2) 4e! 1 is a polar molecule& $nswer: !alse Diff: 3 Page Ref: Sec. 9.3 7) 5y'ridi@ation is the process o" mi;ing atomic or'itals as atoms approach each other to "orm a 'ond& $nswer: rue Diff: 1 Page Ref: Sec. 9.5 8) *lectrons in core or'itals contri'ute to atom 'onding& $nswer: !alse Diff: 1 Page Ref: Sec. 9.6

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories 9) >itrogen is colorless 'ecause the minimum energy to e;cite an electron is in the ultra/iolet section o" the spectrum& $nswer: rue Diff: 3 Page Ref: Sec. 9.$ 9." Al#orithmic Questions 1) Ising the +,*-. model, the electron(domain geometry o" the central atom in B! 0 is %%%%%%%%%%& $) linear B) trigonal planar C) tetrahedral )) trigonal 'ipyramidal *) octahedral $nswer: B Diff: 1 Page Ref: Sec. 9.2 #) Ising the +,*-. model, the electron(domain geometry o" the central atom in ,! # is %%%%%%%%%%& $) linear B) trigonal planar C) tetrahedral )) trigonal 'ipyramidal *) octahedral $nswer: C Diff: 1 Page Ref: Sec. 9.2

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories 0) Ising the +,*-. model, the electron(domain geometry o" the central atom in Cl! 0 is %%%%%%%%%%& $) linear B) trigonal planar C) tetrahedral )) trigonal 'ipyramidal *) octahedral $nswer: ) Diff: 1 Page Ref: Sec. 9.2 1) Ising the +,*-. model, the electron(domain geometry o" the central atom in Br! 1 is %%%%%%%%%%& $) linear B) trigonal planar C) tetrahedral )) trigonal 'ipyramidal *) octahedral $nswer: * Diff: 1 Page Ref: Sec. 9.2 2) Ising the +,*-. model, the molecular geometry o" the central atom in 4e! # is %%%%%%%%%%& $) linear B) trigonal planar C) tetrahedral )) 'ent *) trigonal pyramidal $nswer: $ Diff: 1 Page Ref: Sec. 9.2

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories 7) Ising the +,*-. model, the molecular geometry o" the central atom in BCl 0 is %%%%%%%%%%& $) linear B) trigonal planar C) tetrahedral )) 'ent *) trigonal pyramidal $nswer: B Diff: 1 Page Ref: Sec. 9.2 8) Ising the +,*-. model, the molecular geometry o" the central atom in C! 1 is %%%%%%%%%%& $) linear B) trigonal planar C) tetrahedral )) 'ent *) trigonal pyramidal $nswer: C Diff: 1 Page Ref: Sec. 9.2 9) Ising the +,*-. model, the molecular geometry o" the central atom in ,= # is %%%%%%%%%%& $) linear B) trigonal planar C) tetrahedral )) 'ent *) trigonal pyramidal $nswer: ) Diff: 1 Page Ref: Sec. 9.2

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories 9) Ising the +,*-. model, the molecular geometry o" the central atom in >Cl 0 is %%%%%%%%%%& $) linear B) trigonal planar C) tetrahedral )) 'ent *) trigonal pyramidal $nswer: * Diff: 1 Page Ref: Sec. 9.2 1:) Ising the +,*-. model, the molecular geometry o" the central atom in -! 2 is %%%%%%%%%%& $) tetrahedral B) s3uare planar C) trigonal 'ipyramidal )) seesaw *) s3uare pyramidal $nswer: C )i"": 1 -age .e": ,ec& 9&# 11) he hy'rid or'ital set used 'y the central atom in >= 0 is %%%%%%%%%%& $) sp B) sp # C) sp0 )) sp0d *) sp0d #

$nswer: B Diff: 1 Page Ref: Sec. 9.5

Chemistry, 11e (Brown/LeMay/Bursten/Murphy) Chapter 9: Molecular Geometry and Bonding heories 1#) he hy'rid or'ital set used 'y the central atom in B! 1 is %%%%%%%%%%& $) sp B) sp # C) sp0 )) sp0d *) sp0d #

$nswer: C Diff: 1 Page Ref: Sec. 9.5 10) he hy'rid or'ital set used 'y the central atom in Jr! # is %%%%%%%%%%& $) sp B) sp # C) sp0 )) sp0d *) sp0d #

$nswer: ) Diff: 1 Page Ref: Sec. 9.5