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Name : ………………………………………………… NRIC : …………………………

JABATAN PELAJARANTERENGGANUJABATANPELAJARAN TERENGGANUJABATANPELAJAR


JABATAN PELAJARANTERENGGANUJABATANPELAJARAN TERENGGANUJABATANPELAJAR
JABATAN PELAJARANTERENGGANUJABATANPELAJARAN TERENGGANUJABATANPELAJAR
962/1 TRIAL
JABATAN PELAJARANTERENGGANUJABATANPELAJARAN TERENGGANUJABATANPELAJAR
STPM 2009
JABATAN PELAJARANTERENGGANUJABATANPELAJARAN TERENGGANUJABATANPELAJAR
JABATAN PELAJARANTERENGGANUJABATANPELAJARAN TERENGGANUJABATANPELAJAR
JABATAN PELAJARANTERENGGANUJABATANPELAJARAN TERENGGANUJABATANPELAJAR
JABATAN PELAJARANTERENGGANUJABATANPELAJARAN TERENGGANUJABATANPELAJAR
JABATAN PELAJARANTERENGGANUJABATANPELAJARAN TERENGGANUJABATANPELAJAR
JABATAN PELAJARANTERENGGANUJABATANPELAJARAN
JABATAN PELAJARAN TERENGGANUJABATANPELAJAR
JABATAN PELAJARANTERENGGANUJABATANPELAJARAN
NEGERI TERENGGANU TERENGGANUJABATANPELAJAR
JABATAN PELAJARANTERENGGANUJABATANPELAJARAN TERENGGANUJABATANPELAJAR
JABATAN PELAJARANTERENGGANUJABATANPELAJARAN TERENGGANUJABATANPELAJAR
JABATAN PELAJARANTERENGGANUJABATANPELAJARAN TERENGGANUJABATANPELAJAR
JABATAN PELAJARANTERENGGANUJABATANPELAJARAN TERENGGANUJABATANPELAJAR
CHEMISTRY
JABATAN PELAJARANTERENGGANUJABATANPELAJARAN TERENGGANUJABATANPELAJAR
PAPER 1
JABATAN PELAJARANTERENGGANUJABATANPELAJARAN TERENGGANUJABATANPELAJAR
JABATAN PELAJARANTERENGGANUJABATANPELAJARAN TERENGGANUJABATANPELAJAR
JABATAN PELAJARANTERENGGANUJABATANPELAJARAN TERENGGANUJABATANPELAJAR
JABATAN PELAJARANTERENGGANUJABATANPELAJARAN TERENGGANUJABATANPELAJAR
JABATAN PELAJARANTERENGGANUJABATANPELAJARAN TERENGGANUJABATANPELAJAR
One hour and forty-five minutes
JABATAN PELAJARANTERENGGANUJABATANPELAJARAN TERENGGANUJABATANPELAJAR
JABATAN PELAJARANTERENGGANUJABATANPELAJARAN TERENGGANUJABATANPELAJAR
JABATAN PELAJARANTERENGGANUJABATANPELAJARAN TERENGGANUJABATANPELAJAR
JABATAN PELAJARANTERENGGANUJABATANPELAJARAN TERENGGANUJABATANPELAJAR

Instructions to candidates :

DO NOT OPEN THIS BOOKLET UNTIL YOU ARE TOLD TO DO SO.

There are fifty questions in this paper. For each question, four suggested answers are given.
Choose one correct answer and indicate it on the multiple-choice answer sheet provided.

Read the instructions on the multiple-choice answer sheet very carefully.

Answer all questions.Marks will not be deducted for wrong answers.The total score for this
paper is the number of correctly answered questions.

This question paper consists of 14 printed pages.


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Section A

Four suggested answers labelled A, B, C and D are given for each question.
Choose one correct answer.

1 The mass spectrum of iron shows peaks at mass number of 54, 56, 57, and 58.
This shows that

A The atoms of iron have different numbers of neutron


B The sample of iron is radioactive
C The sample of iron is not pure
D The atoms of iron have different numbers of proton

2 Which of the following gases is most likely to exhibit ideal behavior?

A NH3 C CO2
B C4H10 D H2

P/atm

217

5.1

-57 374 T/OC

3 The phase diagram for carbon dioxide is shown above. Which of the following statements is
not true?

A The melting point of carbon dioxide increases with an increase in pressure.


B Solid carbon dioxide is denser than liquid carbon dioxide.
C Solid, liquid and gaseous carbon dioxide cannot exist in equilibrium at 1.0 atm.
D Carbon dioxide can be solidified at 1.0 atm by greatly reducing the temperature.

4 The electronic configuration of the outermost shell of an element is 3s2 3p1. What is the
proton number for this element?

A 3 B 11 C 13 D 15

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5 Which of the following has the biggest radius?

A F– B Cl– C Na+ D Al3+

6 The information below describes an element, T.

• Melting point is 44OC


• Produces acidic oxides
• Monatomic in solid

Element T could be

A Fluorine C Magnesium
B Sodium D Phosphorus

7 The graph shows a property when going across period three. What could the property be?

Property

Proton number

A Atomic size
B Ionization energy
C Electric conductivity
D Boiling point

8 Which of the following molecules will not form a hydrogen bond with another similar
molecule?

A C6H5OH
B CH3NH2
C CH3CHO
D NH3

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Valence
band

Conductor
band

The diagram shows the conductor and the valence bands. Which of the following elements
can be represented by the diagram shown?

A Carbon C Neon
B Magnesium D Oxygen

10 The shape of a molecule depends on the following factors, except

A The number of lone-pair electrons


B The number of bond-pair electrons
C The number of attractions between the electron orbitals
D The number of atoms bonded to the central atom

11 A chemist sketched a graph as shown below.


Rate of reaction

Reactant

Products

Time
Which of the following reactions can be represented byb the graph above?

A Esterification C Sulphonation
B Nitration D Neutralization

12 Which of the following is true about the half life of a first order reaction?

A The half life is longer for a catalyzed reaction.


B The half life is shorter when pressure increase.
C After the fourth half life, the percentage of the remaining element
is 6.25% of the original quantity.
D The half life is influenced by the concentration of the reactant.

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13 The dissociation of dinitrogen tetroxide into nitrogen dioxide is represented by the equation
below.

N2O4 (g) 2NO2 (g) Ho = + 57.2 kJmol-1

If the temperature of an equilibrium mixture of the gases is increased at constant pressure ,


the volume of the mixture will

A Increase, but only because of a shift of equilibrium towards the right


B Increase, both because of a shift of equilibrium towards the right and also because of
thermal expansion.
C Stay the same, because any thermal expansion could be exactly counteract any
thermal expansion
D Decrease, because a shift of equilibrium towards the left would more than counteract
any thermal expansion.

14 Public swimming pools are often chlorinated to kill bacteria. As an alternative to chlorination
silver ions can be used in a concentration of not more than 10-6 moldm-3 and not less than
10-7 moldm-3 of silver ions.

Which of the following compounds would, in saturated solution, provided the necessary
concentration of silver ion?

compound solubility product

A AgBr 5 x 10-13 mol2dm-6


B AgCl 2 x 10-10 mol2dm-6
C AgIO3 2 x 10-8 mol2dm-6
D Ag2SO4 2 x 10-5 mol3dm-9

15 Distillation of a mixture of bromobenzene (C6H5Br) and steam at a pressure of 101kPa and


a temperature of 95oC gave a distillate containing 100g water. The vapour pressure of water
at 95oC is 85 kPa. What is the percentage by mass of bromobenzene in the distillate?
(RMM C6H5Br = 156.5 ; H2O = 18.0)

A 50%
B 62%
C 76%
D 100%

16 Some data relating to magnesium and its compounds are as follows?

standard electrode potential of magnesium = -2.38V


melting point of magnesium oxide = 2850o C
melting point of magnesium chloride = 714o C

What is the most suitable method for extracting magnesium metal from its ores?

A Electrolysis of aqueous magnesium chloride


B Electrolysis of molten magnesium chloride
C Electrolysis of molten magnesium oxide
D Reduction of magnesium oxide with carbon

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17 A current of 8A is passed through molten aluminium oxide using inert electrodes.


What will be the approximate volume of gas liberated, measured at s.t.p ?

A 2.8 dm3
B 5.6 dm3
C 8.4 dm3
D 11.2 dm3

18 Which one of the following equation correctly defines the enthalpy change of formation
of carbon monoxide?

A C(s) + ½ O2(g) CO(g)


B C(s) + O (g) CO(g)
C C(g) + ½ O2(g) CO(g)
D C(s) + CO2(g) 2CO(g)

19 The enthalpy changes of formation of gaseous ethane and gaseous ethane are 52 kJmol-1
and 85 kJmol-1 respectively at 298K.

What is the enthalpy change of reaction at 298K for the following process?

C2H4(g) + H2(g) C2H6(g)

A -137 kJmol-1
B -33 kJmol-1
C +33 kJmol-1
D 137 kJmol-1

20 Four isomers of C6H12 are shown below.

CH CH CH3 C2H5

C C C

H C2H5 H CH3

C2H5 CH3
C2H5 H

C C C C

CH3
CH3 H CH3

Which of the following pairs consists of a pair of cis-trans isomers?

A 1 and 2 C 1 and 4
B 1 and 3 D 2 and 4

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21 Which one of the following is a correct statement about the two alkenes
CH3CH2CH=CH2 and CH3CH=CHCH3?

A Neither exhibits cis-trans (geometrical) isomerism.


B Neither may be polymerized
C Neither reacts with bromine to give 1,4-dibromobutane
D Neither reacts with hydrogen to form butane.

22 Which one of the following reagents could best be used to distinguish between hex-1-ene and
methylbenzene?

A Ag(NH3)2+ in H2O
B Br2 in CCl4
C I2 in NaOH
D 2,4-dinitrophenylhydrazine in CH3OH

23 Compound G has the molecular formula C8H9C1. When compound G is heated with acidified
potassium manganate(VII), a compound with the molecular formula C8H6O4 is formed.
Compound G is most probably

A C

B D

24 Complete the following reaction equation.

`Ethanoyl 2-hydroxybenzoic
chloride acid

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25 Aldehyde and ketone are produced through catalytic oxidation of alkenes. One example of the
reaction scheme is shown below where ethanal is produced from the oxidation of ethene.

Based on the scheme above, the product


formed from catalytic oxidation of but-2-ene is

A CH3CH2CHO
B CH3CH2CH2CHO
C CH3COCH2CH3
D CH2COCH3

26. A reaction between compound P, CH3COCH2CO2CH2CH3 and phenyihydrazine is the first


step in synthesizing Antipyrine, a type of medicine used to control fever. The reaction scheme
is as follows.

What could Q be?

27. Why is ethanoic acid a stronger acid in liquid ammonia than in water?

A Ammonia is a stronger base than water.


B The molecules of ethanoic acid form a hydrogen bond with water.
C Ethanoic acid dissolves better in liquid ammonia than water.
D Ethanoic acid has a higher enthalpy of hydration.

28 Ethanol is more soluble in water when compared to ethyl ethanoate. Why is this?

A Ethanol is a polar molecule whereas ethyl ethanoate is not polar.


B Ethanol is not polar whereas ethyl ethanoate is polar.
C Hydrogen bonds are formed between the ethanol and water molecules.
D Hydrogen bonds are formed between ethyl ethanoate molecules.

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29 Which of the following compounds produces a white precipitate with ammonia?

A C

B D

30.

Reagent R is most probably

A Ammonia nitrate
B Ethanamide
C Alcoholic ammonia
D Methylamine

31 In an experiment, diluted hydrochloric acid was added to 2-aminopropanoic acid until the pH
of the solution is 2. What is the shape of 2-aminopropanoic acid molecule that exists at this
pH?

A C

B D

32 The scheme shows

A cationic polymerisation
B anionic polymerisation
C coordination polymerisation
D condensation polymerization

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33 Which of the following forms an ionic hydride?

A Sodium
B Silicon
C Sulphur
D Chlorine

34 Aqueous aluminium chlorine has a pH less than 7 because

A the charge density of the aluminium ion is high.


B the aluminium ion undergoes hydrolysis
C aluminium chloride undergoes partial dissociation in water.
D aluminium chloride is a covalent compound.

35 A tetrachloride of Group 14, XCl4 has the following properties.

(i) It is easily hydrolysed.


(ii) Unstable to heat.
(iii) Decomposes at room temperature according to the equation
XCl4 → XCl2 + Cl2
X could be

A germanium
B carbon
C silicon
D lead

36 Which of the following best explain the decreasing thermal stability of the chlorides and
oxides in the oxidation state of +4 of the Group 14 elements (carbon to lead ) in the Periodic
Table when descending the group?

A The bond energy increases.


B The first and second ionization energy decreases.
C The standard electrode potential decreases.
D Presence of the inert pair effect of the s orbital electrons.

37 Which of the following is correct regarding dinitrogen tetroxide, N2O4?

A It is polar.
B It has a ‘V’ shape
C It is produced from NO2.
D It contains one unpaired electron.

38 Which of the following is true with regards to the ammonia molecule?

A It is non-polar molecule.
B It has a trigonal planar shape
C The H− N− H bond angle is 107o.
D It contains two lone pairs of electrons.

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39 The scheme below shows the reactions between potassium iodide with hot concentrated
sulphuric acid, and with aqueous siver nitrate, as well as the solubility of the precipitate Y in
concentrated aqueous ammonia.

Conc. H2SO4
Vapour X
heat

KI(s)

AgNO3 (aq) Conc. NH3


Precipitate Y Product

Which of the following is correct with regards to the colour of vapour X, colour of the
precipitate Y, and the solubility of Y, in concentrated ammonia?

Colour of X Colour of Y Solubility of Y, in conc. NH3

A Brown White Soluble


B Purple Yellow Soluble
C Purple White Insoluble
D Purple Yellow Insoluble

40 Which of the following statements helps to explain why nickel can act as a catalyst in the
hydrogenation of ethene at 200 oC according to the equation :

H2C = CH2 (g) + H2 (g) → CH3CH3 (g)

A Nickel can exhibits variable oxidation states.


B Nickel has d orbitals that can form temporary bonds.
C Nickel can form stable intermediate with the reactants.
D Nickel is neutral in the hydrogenation process of H2C = CH2 .

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Section B

For questions 41 through 50, one or more of the three numbered statements 1 to 3 may be correct.
Decide whether each of the statements is or is not correct. The responses A to D should be selected
on the basis of the following.

A B C D
1 only is correct. 1 and 2 only are 2 and 3 only are 1, 2 and 3 only
correct. correct. are correct.

41 Which of the following depends on the number of solute particles in a given mass of solvent?

1 Elevation of boiling point of solvent


2 Depression of freezing point of solvent
3 Vapor pressure of solute

42 Hydroxyapatite, Ca5(PO4)3OH is the main constituent of tooth enamel . In the presence of


saliva, the following equilibria exist.

Ca5(PO4)3OH (s) 5Ca2+ (aq) + 3PO43- (aq) + OH- aq)

HPO42- (aq) H+ (aq) + PO43- (aq)

Which of the following statements help to explain why tooth enamel is dissolved more
readily when saliva is acidic?

1 The hydroxide ions are neutralised by the acid


2 The phosphate ion PO42- (aq) accepts H+ (aq)
3 Calcium ions react with acids

43 The dissociation constants, Ka, for three acids are given below:

Acid Ka (moldm-3)
phenylethanoic acid 4.90 x 10-5
3-hydroxybenzoic acid 8.32 x 10-5
2-chlorobutanoic acid 1.15 x 10-3

Which of the following statement is/are correct about the acid?

1 Ka for 2,2-dichlorobutanoic acid is greater than Ka for 2-chlorobutanoic acid


2 [H+] in 1.00 moldm-3 phenylethanoic acid solution is 4.90 x 10-5
3 3-hydroxybenzoic acid is the strongest acid

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44 Under which of the following conditions would the Partition Law not hold?

1 When the solutions are concentrated


2 When the solute dissociate or associate in the solvents
3 When the temperature changes

45 Which pairs of compounds can react to produce a compound with the following
structural formula?

46 Which of the following compounds can be used to prepare diazonium salt when reacted with
nitric acid(III)?

47 Which of the following statements explain the increasing thermal stability of the carbonates
of the Group 2 elements (beryllium to barium) when descending the group?

1 When the solutions are concentrated


2 When the solute dissociate or associate in the solvents
3 When the temperature changes

48 Which of the following aqueous cations would give a precipitate when excess ammonia is
added to it?

1 Al3+ 2 Zn2+ 3 Cu2+

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49 In the diaphragm cell for the manufacture of chlorine by elavtrolysis of brine. The function of
the diaphragm

1 is to separate the anode compartment from the cathode compartment.


2 is to prevent the reaction between chlorine and sodium hydroxide produced.
3 Is to act as catalyst to speed up the electrolysis process.

50 A complex salt with the formula of [Ni(NH3)x(H2O)y]Cl2 has the composition by mass of
nickel, 13.98%; and hydrogen, 3.79%. Which of the following statements are true with
regards to the complex salt?

1 The ratio of x to y in the formula of the salt is 2:1.


2 The name of the complex salt is diaquatetraamminenickel(II) chloride.
3 The cis isimer of the complex is optically active.

END OF QUESTION PAPER

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CONFIDENTIAL*

Name : ………………………………………………… NRIC : …………………………

JABATAN PELAJARAN ERENGGANUJABATANPELAJARAN TERENGGANU JABATANPELAJAR


JABATAN PELAJARAN ERENGGANUJABATANPELAJARAN TERENGGANU JABATANPELAJAR
JABATAN962
PELAJARAN
/ 2 ERENGGANUJABATANPELAJARAN TERENGGANU JABATANPELAJAR
OTI 2
JABATAN PELAJARAN ERENGGANUJABATANPELAJARAN TERENGGANU JABATANPELAJAR
STPM
JABATAN PELAJARAN ERENGGANUJABATANPELAJARAN TERENGGANU 2009
JABATANPELAJAR
JABATAN PELAJARAN ERENGGANUJABATANPELAJARAN TERENGGANU JABATANPELAJAR
JABATAN PELAJARAN ERENGGANUJABATANPELAJARAN TERENGGANU JABATANPELAJAR
JABATAN PELAJARAN ERENGGANUJABATANPELAJARAN TERENGGANU JABATANPELAJAR
JABATAN PELAJARAN ERENGGANUJABATANPELAJARAN TERENGGANU JABATANPELAJAR
JABATAN PELAJARAN TERENGGANU JABATANPELAJAR
JABATAN PELAJARAN ERENGGANUJABATANPELAJARAN
NEGERI TERENGGANU TERENGGANU JABATANPELAJAR
JABATAN PELAJARAN ERENGGANUJABATANPELAJARAN
JABATAN PELAJARAN ERENGGANUJABATANPELAJARAN TERENGGANU JABATANPELAJAR
JABATAN PELAJARAN ERENGGANUJABATANPELAJARAN TERENGGANU JABATANPELAJAR
JABATAN PELAJARAN ERENGGANUJABATANPELAJARAN TERENGGANU JABATANPELAJAR
JABATAN PELAJARAN ERENGGANUJABATANPELAJARAN
CHEMISTRY TERENGGANU JABATANPELAJAR
JABATAN PELAJARAN ERENGGANUJABATANPELAJARAN TERENGGANU JABATANPELAJAR
PAPER 2
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JABATAN PELAJARAN ERENGGANUJABATANPELAJARAN TERENGGANU JABATANPELAJAR
JABATAN PELAJARAN ERENGGANUJABATANPELAJARAN
STRUCTURE AND ESSAY TERENGGANU JABATANPELAJAR
JABATAN PELAJARAN ERENGGANUJABATANPELAJARAN TERENGGANU JABATANPELAJAR
JABATAN PELAJARAN ERENGGANUJABATANPELAJARAN TERENGGANU JABATANPELAJAR
JABATAN PELAJARAN ERENGGANUJABATANPELAJARAN TERENGGANU JABATANPELAJAR
JABATAN PELAJARAN ERENGGANUJABATANPELAJARAN TERENGGANU JABATANPELAJAR
Two and a half hours
JABATAN PELAJARAN ERENGGANUJABATANPELAJARAN TERENGGANU JABATANPELAJAR
JABATAN PENLAJARAN ERENGGANUJABATANPELAJARAN TERENGGANU JABATANPELAJA

Instructions to candidates :
For examiner’s use
Answer all the questions in Section A in the Section Marks Marks
spaces provided. Obtained
Answer any four questions from section B. 1 10
For this section, write your answers on the
2 10
answer sheets provided. Begin each
answer on a fresh sheet of paper. Answers A 3 10
should be illustrated by large, clearly 4 10
labeled diagrams wherever suitable. 40
Answers may be written in either Malay or 5 15
English.
Arrange your answer in numerical order
6 15
and tie the answer sheets to this booklet. B 7 15
8 15
9 15
10 15
60
TOTAL 100

This question paper consists of 11 printed pages

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Section A (40 Marks)


Answer all questions in this section.

1 (a) The relative atomic mass of X is 79.99.

(i) Why is the relative atomic mass of X not a whole number?

……………………………………………………………………………………..
[1 mark]

(ii) In nature, X contains two isotopes with mass numbers 79 and 81.
Calculate the percentage abundance of the isotopes 79X and 81X.

[2 marks]
(iii) If X exist as a monoatomic element,sketch the mass spectrum of X.

[2 marks]
(b) Graph against p for 1.0 mol H2 and CO2 at 273K is shown below:

H2
CO2

Ideal gas

(i) Explain why carbon dioxide behaves like an ideal gas at low pressure.

…………………………………………………………………………………

…………………………………………………………………………………
[1 mark]
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(ii) What type of deviation from ideal gas behaviour for hydrogen.

…………………………………………………………………………….
[1 mark]

(iii) Why hydrogen shows only deviation in (ii).

……………………………………………………………………………….
[2 marks]

2 (a) The following diagram shows an arrangement of an electrochemical cell created from

two half- cells, A and B.

(i) Write the overall equation for the above cell

[1 mark]

(ii) With reference to the Data Booklet, calculate the electromotive force(e.m.f)
of the under standard condition.

[3 marks]
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(iii) Using the result obtained in(ii),write the Nernst equation of the above cell
reaction.

[1 mark]

(b) (i) On the incomplete outline below sketch the Born-Haber cycle which includes
the standard enthalpy change of formation, /\H, and the lattice energy of
calcium sulphide. Label all the enthalpy changes involved and the chemical
species at each stage. [Abbreviations can be used, as in part (b).]

Ca2+(g) + S2-(g)

Energy

Ca(s) + S(s)

CaS(s)

[5 marks]

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(ii) The standard enthalpy changes of atomisation,

∆H0a of calcium = 178 kJ mol-1

∆H0a of sulphur = 279 kJ mol-1

The sum of the first two electron affinities of sulphur = 337 kJ mol-1
The standard enthalpy change of formation,

∆H0a of calcium sulphide = - 487 kJ mol-1.

First ionisation of Calcium = +590 kJmol-1

Second ionisation of Calcium = +1150 kJmol-1

Calculate the lattice energy of calcium sulphide.

[2 marks]

3 (a) Write the equations for the reaction of ethanoyl chloride, CH3COCl, with 1-propanol,
CH3CH2CH2OH, and aniline, C6H5NH2. Name the organic products formed.

(i) 1-propanol

(ii) Aniline

[4 marks]
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(b) Write an equation to show how aniline can be obtained from the product formed in
(a)(ii) above.

[1 mark]

(c) Give the formulae of the products obtained when the following ester
O O
║ ║
OCH2CHOCCH2CH2C

CH2

is heated with aqueous sodium hydroxide.

[2 marks]

(d) (i) Give the structural formulae of the reagents that are required to produce
COOH

Compound X, O-C-CH3 , by a one step reaction.



O

(ii) State a use for compound X.

[3 marks]

4 (a) When ammonium nitrate is heated,it liberates a colourless gas. The gas can be used as
an anaesthetic.

(i) Give the name of the gas

………………………………………………………………….……………
[1 mark]
(ii) Write the equation for the above reaction.

…………………………………………………………………………….…
[1 mark]
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On the axes below,sketch the general trend for each property of the elements or their
compound the third period of the Periodic Table. No scale is given for the vertical
axis.Your sketch is expected to be clear but only qualitative.
Expalain the changes shown.

Melting point of oxides (oC)

Na Mg Al Si PS
[1 mark]

Explanation

……………………………………………………………………………………….

.....................................................................................................................................

………………………………………………………………………………………..

[3 marks]

(b) Chromium (proton number = 24) is a d-block element. A lot of chromium compound
are used in the laboratory.

(i) Write the electronic configuration for the Cr3+ ion.

………………………………………………………………………..………..
[1 mark]

(ii) Briefly explain why the Cr3+ (aq) ion is coloured.

……………………………………………………………………………….

……………………………………………………………………………….

………………………………………………………………………………
[3 marks]
.

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5 (a) State the difference between the hydrogen emission spectrum and a spectrum
produced by a tungsten filament bulb.
[2 marks]

(b) States all the orbitals for the carbon atom and state the differences between them.
[2 marks]

(c) Hund`s rule, Pauli exclusion principle and Aufbau principle are used to determine the
ground states electronic configuration of an atom.

(i) State the rule and principles.


[3 marks]

(ii) Describe how the two principles are applied to oxide ion O2-, as an example.
[3 marks]

(d) (i) What is meant by the atomic radius of an element?


[ 1 mark]

(ii) State and explain the changes in the radius of the atom of elements in Period
2, that is, from lithium to neon.
[4 marks]

6 (a) Predict the shape of the NH3 molecules and NH4+ ions , explain the differences in
their bond angel.
[4 marks]
(b) Draw a labeled diagram showing the overlapping of orbitals in
(i) H2O
[2 marks]
(ii) C2H4
[2 marks]
(c) The boiling point of H2O is higher than HF.Explain.
[2 marks]

(d) The rate of decomposition of acidic hydrogen peroxide can be analysed through
titration. Hydrogen peroxide samples with a fixed volume are taken at specific times
and were titrated with potassium manganate(IV) solution. The titration results are as
follows:

Time/min 0 10 20 30

Volume of KMnO4(aq)/cm3 45.5 27.4 16.4 9.9

(i) Determine the half-life of this reaction by plotting the graph, using the data
from the table above.
[4 marks]
(ii) What is the order of this reaction?
[1 mark]

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7 (a) State Le Chatelier’s principle.


[2 marks]

Referring to the equilibrium


4NH3(g) + 5O2(g) 4NO(g) + 6H2O(g) ∆H = –908 kJ mol–1

(b) Explain
(i) the effect on the yield of NO when pressure on equilibrium mixture is
increased
(ii) the effect on equilibrium constant, Kc when temperature on the equilibrium
mixture is decreased.
[4 marks]

(c) If 0.40 mol of NH3 and 0.50 mol of O2 in a 1 dm3 container is allowed to react in the
presence of catalyst Platinum/Rhodium until an equilibrium is established, the yield
of NO is 30% by mole. Calculate the number of mol of NO produced.
[2 marks]

Given that the reaction A B is second order.

(d) Sketch the graphs of (i) concentration of A versus time and (ii) rate versus
concentration of A.
[2 marks]

1
(e) If the graph of versus time is as given below.
[A]

Calculate 1
(i) the rate constant / mol–1 dm–3
[A]
(ii) the initial concentration of
A 12.

2.0

0 20 t / min
[3 marks]

(f) Suggest the mechanism for the reaction A B


[2 marks]

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8 (a) Describe and explain the variation in boiling point of the tetrachlorides of Group 14
from Carbon to lead
[4 marks]

(b) How and why do CCl4 and SiCl4 differ in their reaction with water? Include,in your
answer any reaction that occurs.
[4 marks]

(c) Suggest a use of each element or compound below, and explain how each of the uses
is related to physical or chemical properties and structure.

(i) Silicon
(ii) Silicon (IV) oxide
(iii) Carbon dioxide
[3 marks]

(d) Aluminium is extracted from a mixture of molten aluminium oxide and cryolite,
Na3AlF6 by electrolysis. Suggest factors that have to be taken into consideration when
choosing a site for an aluminium factory.
State one adverse effect on the environment as a result of the extraction process of
aluminium.
[4 marks]

9 (a) An alkene, C4H8 reacts with hydrogen chloride to produce a compound, C4H9Cl, draw
the structure of the alkene and the chloro-compound.
[2 marks]

(b) With reference to the reaction scheme below.:

Cl2/ light
A C2H6

NaOH
reflux

Step 1 B

Conc.
180oC H2SO4

Br2/CCl4 NaOH
C D E
Reflux
(i) Identify compounds A to E.
(ii) Name the reagent used in step I.
(iii) Give an important use for compound E.
[7 marks]

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(c) Suggest how you would differentiate the following pairs of compounds by chemical
means.
(i) 1-iodohexane and 1-chlorohexane
(ii) chlorocyclohexane and chlorohexane
(iii) 1-chloro-1- butane and 1- chlorobutane
[6 marks]

10 (a) The structural formulae of two amines are shown below.

Tetrahyroquinoline

Tetrahydroisoquinoline

Which is the stronger base? Explain


[2 marks]
(b) Suggest ,with reasons.how the basicity of 3,4-difluorophenylamine might campare
with that of phenylamine.

3,4-Difluorophenylamine

[2 marks]
(c) Ziegler-Natta catalyst is a mixture of titanium(IV) chloride, TiCl4 and
triethylaluminium, Al(CH3CH2)3, Explain the addition polymerisation mechanism
with the ziegler-Natta catalyst to produce poly(ethene).
[6 marks]

(d) Give two advantages of addition polymerisation with the Ziegler-Natta catalyst
campared to addition with free radical polymerisation in the production of
poly(ethene)
[3 marks]

(e) Nylon has similar characteristics with a few natural compounds.What are these
compound? Explain.
[2 marks]
END OF QUESTION PAPER
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Name : ………………………………………………… NRIC : …………………………

JABATAN PELAJARAN TERENGGANUJABATANPELAJARAN TERENGGANU JABATANPELAJA


JABATAN PELAJARAN TERENGGANUJABATANPELAJARAN TERENGGANU JABATANPELAJA
JABATAN PELAJARAN TERENGGANUJABATANPELAJARAN TERENGGANU JABATANPELAJA
TRIAL
962/1
JABATAN PELAJARAN TERENGGANUJABATANPELAJARAN TERENGGANU
STPMJABATANPELAJA
2009
JABATAN PELAJARAN TERENGGANUJABATANPELAJARAN TERENGGANU JABATANPELAJA
JABATAN PELAJARAN TERENGGANUJABATANPELAJARAN TERENGGANU JABATANPELAJA
JABATAN PELAJARAN TERENGGANUJABATANPELAJARAN TERENGGANU JABATANPELAJA
JABATAN PELAJARAN TERENGGANUJABATANPELAJARAN TERENGGANU JABATANPELAJA
JABATAN PELAJARAN TERENGGANUJABATANPELAJARAN TERENGGANU JABATANPELAJA
JABATAN PELAJARAN TERENGGANUJABATANPELAJARAN
JABATAN PELAJARAN TERENGGANU JABATANPELAJA
JABATAN PELAJARAN TERENGGANUJABATANPELAJARAN
NEGERI TERENGGANU TERENGGANU JABATANPELAJA
JABATAN PELAJARAN TERENGGANUJABATANPELAJARAN TERENGGANU JABATANPELAJA
JABATAN PELAJARAN TERENGGANUJABATANPELAJARAN TERENGGANU JABATANPELAJA
JABATAN PELAJARAN TERENGGANUJABATANPELAJARAN TERENGGANU JABATANPELAJA
JABATAN PELAJARAN TERENGGANUJABATANPELAJARAN TERENGGANU JABATANPELAJA
TRIAL EXAMINATION 2009
JABATAN PELAJARAN TERENGGANUJABATANPELAJARAN TERENGGANU JABATANPELAJA
JABATAN PELAJARAN TERENGGANUJABATANPELAJARAN TERENGGANU JABATANPELAJA
JABATAN PELAJARAN TERENGGANUJABATANPELAJARAN TERENGGANU JABATANPELAJA
JABATAN PELAJARAN TERENGGANUJABATANPELAJARAN
CHEMISTRY TERENGGANU JABATANPELAJA
JABATAN PELAJARAN TERENGGANUJABATANPELAJARAN TERENGGANU JABATANPELAJA
PAPER 1 & 2
JABATAN PELAJARAN TERENGGANUJABATANPELAJARAN TERENGGANU JABATANPELAJA
JABATAN PELAJARAN TERENGGANUJABATANPELAJARAN TERENGGANU JABATANPELAJA
JABATAN PELAJARAN TERENGGANUJABATANPELAJARAN TERENGGANU JABATANPELAJA
JABATAN PELAJARAN TERENGGANUJABATANPELAJARAN TERENGGANU JABATANPELAJA

MARKING SCHEME

This answer paper consists of 17 printed pages


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OTI 2 2009 2 STPM

STPM CHEMISTRY 962/1


OTI 2 2009

MARKING SCHEME PAPER 1

Question Answer Explanation


No.
1 A These are the isotopes of iron. Different isotopes have different numbers of
neutron
2 D Of the 4 gasses given hydrogen gas is most likely to exhibit ideal behavior.
Refer to any graph of (pV/nRT) against p.
3 D Carbon dioxide cannot be solidified at 1.0 atm if the temperature is greatly
reduced. At 1.0 atm CO2 exists in both solid and gaseous forms.
4 C Actual electronic arrangement is 1s2 2s2 2p6 3s2 3p1. Total number of
electron is 13. Thus the proton number is 13
5 C Na+ is the biggest as it has the smallest number of nuclear charge. The
smaller the nuclear charge, the bigger the ionic size.
6 D Only phosphorus can exist as monatomic solid with acidic properties in its
oxides.
7 C Across period 3 from left to right, conductivity increases for the first 3
elements, then starts to decrease as the elements become metalloid, and
decreases further as elements are non-metals.
8 C In the CH3CHO molecule, hydrogen atom is bonded to carbon not oxygen.
So no intermolecular hydrogen bonds.
9 B No energy gap between the two bands, so it belongs to a metal, which is
magnesium.
10 C There are only repulsive forces exist between electron orbitals. So the lone
pair electrons push each other so that the angle between them is maximized.
11 A The graph is reversible reaction. The rate of the forward reaction is equal to
the rate of the backward reaction over time. The formation of ester is a
reversible reaction.
12 C e.g.: if the original sample = 100g
100g → 50g → 25g → 12.5g → 6.25g
t1/2 t1/2 t1/2 t1/2
Percentage remaining after the 4th half life = 6.25 x 100 = 6.25%
100
13
Since the forward reaction is endothermic, an increase in temperature shifts
B
the equilibrium to the right according to Le Chatelier’s principle, by
absorbing the excess heat. In the case, more gas particles are produced and
there is an increase in volume. Furthermore, heating will also cause the gases
to expand.

14
AgBr (s) Ag + (aq) + Br-(aq)
A
Ksp = [ Ag+ ] [Br- ]
= 5 x 10 -13 mol2dm-3

But [ Ag+ ] = [Br -]


[ Ag+ ] = ( 5 x 10 -13 )1/2
= 7.1 x 10-7 moldm-3

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OTI 2 2009 3 STPM

Question Answer Explanation


No.
15
mB = MB x PoB
B
mW MW x PoW

mB = 156.6 x (101 x 85)


100 18 x 85

= 163.66

% bromobenzene = 163.66 x 100


(1663.66 + 100)

= 62%

16
The very negative Eo value of Mg shows that Mg2+ is very difficult to be
B
reduced to Mg. Therefore, normal chemical reduction is not suitable. A
feasible way would be the electrolysis of molten Mg2+ , in this case, MgCl2
(MgCl2 has a lower m.p. than MgO).
17
A 2O2-(l) O2(g) + 4e
Quantity of electricity used = I x t
= 8 x (100 x 60)
= 48000 C

Amount of electrons passed = 48000C


96000 Cmol-1
= 0.5 mol

Amount of O2 evolved = 0.5


4
= 0.125 mol

Volume of O2 evolved = 0.125 x 22.4


= 2.8 dm3

18
The enthalpy change of formation of CO is the enthalpy change when 1
A
mol of gaseous CO is formed from its constituent elements, that is C and O2,
at their standard states.

19
H = -52 + (-85) = - 137 kJmol-1
A
20
For cis-trans isomers, 2 different groups must be bonded to the same C at the
A
double bond.

B : 1 and 3 are identical


C : 1 and 4 are structural isomers
D : 2 and 4 are structural isomers

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Question Answer Explanation


No.
21
C Upon reacting with Br2 , but-1- ene gives 1,2- dibromobutane and
but -2-ene gives 2,3- dibromobutane.
22
Being an alkene, hex-1-ene undergoes electrophilic addition readily with Br2
B
in CCl4 and decolourised it. Methylbenzene is unable to do so.

CH3(CH2)3CH=CH2 + Br2 CH3(CH3)3CHBr—CH2Br

23 A

24 A Remember: Ethanoyl chloride (acyl chloride) will react with alcohols but
not with carboxylic acids.

25 B CH3CH2COOH All carbonyl compounds, which are aldehyde and ketone


react with 2,4-dinitrophenyihy- drazine to form orange precipitate that has a
high melting point.

26 A Ethanoic acid is a weak acid and it partially ionises in water to produce


hydroxonium ion, H+.
CH3COOH + H20 CH3COO- + H
If ethanoic acid is dissolved in a base like ammonia that is able to extract the
proton (H+) from ethanoic acid more effectively, more ethanoic acid
molecules will ionise. Thus H+ ions are produced are the strength of ethanoic
acid will increase. Thus ethanoic is a stronger acid in liquid ammonia than in
water.
27 D The reaction equation is as follows.

Remember: This molecule contains phenyihydrazine carbonyl group.

28 C Hydrogen bonds are formed between ethanol and water molecules.


Thus ethanol is soluble in water.

Whereas ethyl ethanoate (ester) that has a long carbon chain does not form
hydrogen bonds with water, thus it is less soluble in water

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Question Answer Explanation


No.
29 C

30 D chloride
An aromatic amine with an amino group at its side chain will have similar
chemical properties as an aliphatic amine.

31
At pH 2, an acidic solution and 2-amino- propanoic acid (alanine)will exist
D
as positive ions.

32 B
The reaction results in a nucleophilic addition to the double bond and the
anionic polymerisation process takes place.

33 A
NaH – ion, SiH4 - covalent, H2S – covalent, HCl – covalent.
The sodium atom wiyh the biggest size among the four elements has
the lowest ionization energy and can lose electron readily to form
ionic compound.

34 A
Aluminium is a amphoteric. It si soluble in aqueous sodium
hydroxide.
Al2O3 (p) + 2OH- (aq) + 3H2O(l) → 2[(OH)4]- (aq)
35 D
XCl4 decomposes at room temperature showing that the X-Cl bond is
very weak. Hence, X must have the biggest size in Group 14.

PbCl4(l)→ PbCl2 (s) + Cl2 (g)

36 D
The inert pair effect increases going down the Group 14. Hence, the
+2 state becomes progressively more stable while the + 4 state
becomes less stable.

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OTI 2 2009 6 STPM

Question Answer Explanation


No.
37 C The Lewis structure of N2O4 is as follows :

It is a symmetrical molecule. Hence is non-polar.


There are 3 bond pairs with no lone pairs surrounding the nitrogen
atom. Hence, its shape is triginal planar and not ‘V’ shape.
As can be seen from the Lewis diagram all the electrons in N2O4 are
paired. N2O4 is formed from the dimerisation of NO2.
2NO2 N2O4

38 C The lone pair electrons in NH3 pushes the three bonding pairs closer to
one another. Hence, its bond angle is slightly less than that of a perfect
tetrahedron, 109.5o .
39 D KI reacts with H2SO4 to produce iodine, which is a purple fume.
KI + H 2SO4 → KHSO4 + HI(g)
2HI(g) + H2SO4 → I2(g) + SO2(g) + 2H2O

KI reacts with silver nitrate to produce silver iodide, which is yellow.


KI(aq) + AgNO3 (aq) → KNO3 (aq) + AgI(s)

AgI is insoluble in either dilute or concentrated ammonia.


40 B Heterogeneous catalyst uses their empty d orbitals to form temporary bonds
with the reacting molecules. This process is known as adsorption.
41 B 1 Elevation of boiling point of solvent
2 Depression of freezing point of solvent
42
According to Le Chatliers Principle,
B(1,2)
When OH- ions are neutralized by the acid, position of eq will shift to the
right, making the solid Ca5(PO4)3OH dissolved.
When the PO43- ions accepts H+ , the eq will shift to the right, making the
solid Ca5(PO4)3OH dissolved.

43
Halogen is an donating group which decreases the acid strength.( Ka is
A( 1 )
greater)
44
Partition law can only be used under the following condition
D(1,2,3)
- the solutions must be dilute
- the solute cannot undergo dissociation or association in one solvent and
not the other
- the temperature must be fixed

45 D The Grignard reagent has the general formula, RMgX. With ketones, a

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Question Answer Explanation


No.
tertiary alcohol is produced.
Remember: The C—Mg and C—Li bonds are very polar. When either the
C—Mg or the C—Cl bonds undergoes fission, the carbon acts
as a nucleophile

46 A To form a diazonium salt, nitric(III) acid must react with a primary aromatic
amine solution at a temperature of 0 — 5°C. 2-methylphenylamine, is a
primary aromatic amine.

47 A Going down group 2, the size of the cation increases causing the polarizing
power to decrease. Statement 2 only indicates that the oxides are more stable
than the carbonates. It does not explain about the stability trend of the
carbonates.
48 C Zn(OH)2 and Cu(OH)2 are soluble in excess ammonia.

49 B
50 B Mol ratio of Ni : N : H = 13.98/59 : 13.27/14 : 2.79/1
= 0.236 : 0.947 : 3.79
= 1 : 4 : 16
:. Ratio of H2 : N = 8 : 4 = 2 : 1
The complex does not contain polydentate ligands. Hence, it cannot exhibits
optical isomerism.

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8

STPM CHEMISTRY

OTI 2 2009/TRIAL EXAM

MARKING SCHEME

PAPER 2
SECTION A ( Structured Question )

QUESTION SUGGESTED ANSWERS SUGGESTED


NO MARKS
1(a)(i) The element X contains isotopes. 1

79
1(a)(ii) Lets the percentage abundance of X = x% 1
or
81
Percentage abundance of X = (100-x)% 1

79.99 = 1

X = 50.5
1
Percentage abundance of isotopes 79X = 50.5%
Percentage abundance of isotopes 81X = 49.5%
Any 2
1(a)(iii)
Abundance(%)
Axis labeled
50.5 and unit
1
49.5

Draw a correct
peak
1
79 80 81 m/e

1(b)(i)
At low pressure, the molecules are far apart , so 1
repulsive forces among the molecules of CO2 1

1(b)(ii) Positive deviation 1

1(b)(iii)
Forces of repulsion between the H2 gas molecules 1
which causes the speed of H2 molecule collision with the vessel wall to 1
increase.
So the pressure of H2 is higher, causing > 1 (positive deviation)

Total 10
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9

QUESTION SUGGESTED ANSWERS SUGGESTED


NO MARKS
2 (a) (i) Zn(s) + 2Ag + (aq) → Zn 2+(aq) + 2Ag(s) 1

2 (a) (ii) Half cell reaction E0/V


Zn2+(aq) + 2e→ Zn(s) -0.76 1
2Ag+ (aq) + 2e → 2Ag(s) +0.8 1
Zn(s) + 2Ag+ (aq) → Zn2+(aq) + 2Ag(s)
E.m.f. of cell = 0.80 + 0.76 = 1.56 V 1

2 (a) (iii) Ecell — Eceii° - 0.059 log [Zn2+] 1


2 [Ag]2

2 (b) (i) 5
For every
single level
energy
shown,one
mark will be
given

Latice energy
CaS(s)

2 (b) (ii) -487 = 178 + 279 + (590 + 1150) + 337 + Lattice energy

Lattice energy = -3021 kJ mol-1 1+1


Total 10

3 (a) (i) CH3COCl + CH3CH2CH2OH → CH3COO CH2CH2CH3 + HCl 1


Propyl ethanoate 1
3 (a) (ii) CH3COCl + C6H5NH2 → CH3CONH C6H5 + HCl 1
N-phenyl ethanamide 1
3 (b) Heat with dilute sulphuric acid. 1
CH3CONH C6H5 + H2O → CH3COOH + C6H5NH2
3 (c) Structural formulae of the products :
HOCH2CHOH and NaOOCCH2COONa 1+1

CH3
3 (d) (i) Heat 2-hydroxybenzoic acid with ethanoyl chloride. 1
1
3 (d) (ii) X is aspirin. It is an analgesic. 1
Total 10
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10

QUESTION SUGGESTED ANSWERS SUGGESTED


NO MARKS
4 (a) (i) Dinitrogen oxide, N2O 1

4 (a) (ii) NH4NO3(s) → N2O(g) + 2H2O(l) 1

4 (b) Melting point of oxides

Na Mg Al Si P S

Explanation:
Na2O and MgO, ionic with strong electrostatic forces;Al2O3, ionic 1
with
Covalent character; SiO2 macromolecular with high melting 1
point;
Oxides of P and S,simples molecules 1

4 (c) (i) 1

4 (c) (ii) 3d electrons absorb energy in the visible wavelengths except the 1+1
green wavelength which it reflects and jump to the higher set of vacant
3d orbitals. Therefore, Cr3+ ions appear green.

Total 10
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11

QUESTION SUGGESTED ANSWERS SUGGESTED


NO MARKS
5(a) The hydrogen emission spectrum consist of discrete lines 1
whereas the spectrum produced by the tungsten filament bulb is a 1
continuos spectrum.
5(b) 1s,2s,2px,2py 1
The difference between 1s and 2s is that
the size of 2s is bigger than 1s. 1
or or
The difference between 2s and 2p is that 1
2s is spherical but that 2p is dumb-bell shape. …………
Max 2
………...
5(c) (i) Hund`s rule: 1
When electrons are placed in a set of orbital with equal energies, the
electrons must occupy them singly with parallel spin before they can
occupy the orbital in pairs.

Pauli exclusion principle:


Each orbital can only be filled with two electrons with opposite spins. 1
Aubau principle:
Electrons occupy orbitals in order of the energy levels of the orbitals.
1
Orbitals with the lowest energy are always occupied first.

5(c) (ii) Number of electrons in O2- ion = 8+2=10


Step 1: Apply Pauli exclusion principle and Aufbau principle.Fill 1s
orbital with two electrons.

1s 2s 2p
Step 2:Fill 2s orbital with two electrons
1

1s 2s 2p
Step 3: Apply Hund`s rule.
Fill 2px,and 2py orbitals wih three electrons. The electrons must
be in parallel spins. 1

1s 2s 2p
Step 4: Fill the remaining three electrons in 2px,2py and 2pz orbitals . 1
Each pair of electrons must be in parallel spins. Describe or
show the filling
using a
diagram
1s 2s 2p Any 3
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12

QUESTION SUGGESTED ANSWERS SUGGESTED


NO MARKS
5(d) (i) Atomic radius is defined as half the distance between the nuclei of two 1
closest and identical atoms.

5(d) (ii) When across a period(from lithium to neon),


atomic radius decreases. 1
Because the nuclear charge increases(number of protons) 1
But the screening effect remains almost constant as the number of 1
shells remain the same.
The attraction of the valence electrons by the nucleus increases. 1

Total 15
6 (a) NH3
Valence electron, N : 5e
3H : 3e
-------------
8e 3 bond pair, 1 lone pair 1
-------------

..
N
Draw or state
Or trigonal pyramidal
107 0 the shape
1
H H H
NH4+
Valence electron, N : 5e
4H : 4e
Positive charge : -1e
(less 1 electron)
-------------
8e 4 bond pair, no lone pair 1
--------------

+
H

N Or tetrahedral

109.5)
H H H Draw or state
the shape
1

The bond angle of NH3 is 1070 wheares the bond angle of NH4+
Any 4
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13

QUESTION SUGGESTED ANSWERS SUGGESTED


NO MARKS
6 (b) (i) H2O H(1 s)

Overlapping
1
sp3 orbitals

O label
H(1 s) 1
..

6 (b) (ii)
C2H4 H(1s) π
H(1s)

δ
Overlapping
1

H(1s) H(1s) label


1
C C
6 (c) Boiling point of H2O is higher than HF because
each HF molecule forms 2 intermolecular hydrogen bonds 1
compared to 4 intermolecular hydrogen bonds formed by each H2O 1
molecule.
6 (d) (i)
Volume of KMnO4
Label the axis
and unit
1

40

Plot the graph


1+1
30

Indicate on the
20 graph
t1/2

1
10

t1/2= 13.5 t1/2= 13.5

10 20 30 t/min

From the graph, the half- life of the reaction is 13.5 minutes.
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14

QUESTION SUGGESTED ANSWERS SUGGESTED


NO MARKS
6 (d) (ii) From the graph, half life doesnot depend on the concentration of 1
hydrogen peroxide. Thus, the reaction is first order.
Total 15
7(a) When an equilibrium is disturbed then equilibrium will shift in the 2m
direction that will reduce the effect of the disturbance.
7(b)(i) Yield of NO decreases. 1m
When pressure is increased, equilibrium will shift to the left because 1m
the backward reaction will reduce the number of gaseous molecules.

7(b)(ii) Value of Kc increases. 1m


The forward reaction is exothermic, the Kc value decreases with 1m
increase in temperature.

7(c) Let x be the number of mol of NO produced


Total number of moles at equilibrium = 0.40 – x + 0.50 – 1.25x + x + 1m
1.5x or
x
= 30 %
0.4 x + 0.5 1.25x + x + 1.5x
1m
x =0.29 mol

7(d) (ii) (ii)


[A] Rat ]

0 t 0 [A
7(e)(i) 1 1
= kt +
[A] [A]0 1m

12.0 − 2.0
k= = 0.40 mol–1 dm3 min–1 1m
25

7(e)(ii) 1
= 2.0
[A]0
1m
[A]0 = 0.50 mol dm–3

7(f) A + A → M slow step 1m


M → 2B fast step 1m

Total 15
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15

QUESTION SUGGESTED ANSWERS SUGGESTED


NO MARKS
8 (a) Boiling point of tetrachlorides increases down the group 1

All the tetrachlorides are non-polar and are simple molecules. 1

Molecular size increases from top to bottom. 1

Strength of van der Waals forces increases down the group. 1

8 (b) SiC14 undergoes hydrolysis whereas CCI4 does not. 1


This is because the Si atom has empty d orbitals which can be attacked 1
by lone pair electrons from water molecules. The product of
hydrolysis is silicon(IV) oxide and hydrochloric acid.

1
1
, C atom in tetrachioromethane does not contain empty
d orbitals, hence does not undergo hydrolysis.

8 (c) (i) Semiconductor 1

Semimetal, electrical conductivity increases when temperature is


raised. 1
Ceramic
The Si—O covalent bond in the giant covalent network is strong. 1
In fire extinguishers. Does not support combustion

8 (d) An aluminium factory has to be located near a port so that the raw 1
material, bauxite ore, can be easily transported to it. This will reduce
cost.
1
As the electrolysis of molten aluminium oxide involves the use of a
large amount of electricity, the aluminium factory must be located
close to a hydroelectric dam for a supply of cheap electricity. 1
These two factors can help to reduce the cost of producing aluminium.
One bad effect on the environment caused by the extraction of 1
aluminium is the release of poisonous hydrogen fluoride and fluorine
gas into the air, which are formed during electrolysis of a mixture of
aluminium oxide and cryolite.

Total 15
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16

QUESTION SUGGESTED ANSWERS SUGGESTED


NO MARKS

9(a) CH3-CH=CH-CH3

CH3- CH- CH2-CH3


2m
Cl

9(b) A: CH3CH2Cl D : CH2Br- CH2Br


B : CH3CH2OH E : CH2OH – CH2OH
C : CH2=CH2 5m

9(c) Ethanolic KOH 1m

9(d) monomer for polyester 1m

9 (e) - heat with ethanolic silver nitrate


1-iodohexane : yellow precipitate of AgI
1- chlorohexane : white precipitate of AgCl 1+1
- heat with ethanolic silver nitrate
Chlorocyclohexane : white precipitate
Chlorobenzene : no precipitate 1+ 1
- add acidified KMnO4
1- chloro-1- butane : decolourisation of KMnO4
1- chlorobutane : KMnO4 solution is not decolourised. 1+ 1

Total 15
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17

QUESTION SUGGESTED ANSWERS SUGGESTED


NO MARKS
10 (a) Tetrahydroisoquinoline is the stronger base. In tetrahydroquinoline, the 1
unshared electron pair is delocalised into the aromatic ring, making it 1
less available to accept a proton, whereas tetrahydroisoquinoline
resembles an alkylamine.

10 (b) 3,4-Difluorophenylamine is a weaker base than phenylamine because 1


the two F atoms are electron-withdrawing and they reduce the 1
availability of the lone pair of electrons on the N atom to accept a
proton.

10 (c) An ethyl group, CH3CH2 is transferred from triethylaluminium to 1


titanium(IV) chloride to produce a complex,

Ethene molecules act as Lewis bases and are bonded to titanium which
1
has vacant d orbitals. These ethene monomers are inserted between the
1
titanium and the ethyl group to form a polymer.

1
The process is terminated when a hydrogen atom is added to a titanium
atom, and the poly(ethene) chain is separated from titanium.

10 (d) The poly(ethene) polymer formed by the addition polymerisation 1


process using the Ziegler-Natta catalyst is a linear polymer and of high 1+1
density and high melting point.

10 (e) Proteins and polypeptides. 1


Nylon has peptide linkages, CONH, which are also found in 1
proteins and polypeptides.
Total 15

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