85)

The correct order of increasing solubility of AgCl in (A) water, (B) 0.1

FILE NO. 89/175/17/12 BaCl " and (#) 0.1 !aCl, (C) 0.1

8')

!% $ is a) A & B & C & # b) B & C & A & # c) C & B & # & A d) C & B & A & # A solution of !% ( Cl and !% $ has )% = 8 . *hich of the following hydro+ides ,ay be )reci)itated when this
solution is ,i+ed with e-ual .olu,e of 0." a)

g ( 0% ) " ( 1 s) = $.5 10

( c) Ba ( 0% ) " 1 s) = 1.1 10

) b)

Ca ( 0% ) " ( 1 s) = ".1105 )

of ,etal ion /

1' d) 2e ( 0% ) " 1 s) = 8.110

83)

*hat can be the ,a+i,u, )ossible ,olarity of Co "+ ions in 0.1

"1 %Cl saturated with % "4 1 a = ( 10 ,

88)

gi.en that 1 s) for Co4 is " 10"1 and concentration of saturated % "4 = 0.1 . a) 1.00 b) 0.50 c) (.(8 10 11 d) 0.10 2or the titration of a wea5 base with strong acid, the )% at the e-ui.alence )oint is on the acidic side. 6t is because of

a) slight e+cess of the acid b) slight e+cess of the base c) cationic hydrolysis of the salt for,ed d) anionic hydrolysis of the salt for,ed 87) 6n the titration of a ,onoacid wea5 base with a strong acid, the )% at half of the e-ui.alence )oint is a) ) 1 b b) 1( ) 1 b c) 3 ) 1 b d) 3 + ) 1 b 70) 2or the titration of a dibasic wea5 acid % " A ) base gra)h is as shown in the figure. ) )oints.
1 a( 1)

1 a( ")

)
1 a( ")

1 a( 1)

" with a strong base, )% .ersus .olu,e of the

and )

are e-ual to the )% .alues corres)onding to the

#
C

B
)%

8olu,e of !a0% added

a) B and # res)ecti.ely b) A and B res)ecti.ely c) C and # res)ecti.ely d) A and C res)ecti.ely 71) The cur.e in the figure shows the .ariation of )% during the course of titration of a wea5 acid, %A with a strong base ( !a0% ). At which )oint in the titration cur.e is the concentration of the acid e-ual to that of its con9ugate base /

#
)%

a) ;oint #

b) ;oint :

,l of !a0% added c) ;oint C

d) ;oint B

7")

"5,l of a wea5 acid, %A re-uired 15 ,l of 0.1 !a0% for the end )oint. #uring titration, the )% of the acid solution is found to be 5.30 u)on the addition of 10 ,l of the abo.e al5ali. The ) 1a of the wea5 acid is
a) 5.(0 b) '.$0 c) 5.'0 d) 5.30

7$)

FILE NO. 89/175/17/12 The )% of blood is 3.(. 6f the buffer in blood is C0 " and %C0 , calculate the ratio of con9ugate base to
3 acid ( % " C0$ ) to ,aintain the )% of the blood. <i.en 11 of % " C0$ = (.5 10 $

7()

a) 8.5 b) 10.0 !% $ with 0.1 6n the titration of 100 ,l of 0.01

c) 11."5 d) none of these %Cl, at the stages of addition of 5, 10 and 11 ,l of acid

+ +

75)

solution, the )% .alues are 7."', 5.'" and $ res)ecti.ely. The reaction !% ( + % " 0 !% $ + % $0 is e+)ected to occur at a) %alf neutrali=ation )oint b) :-ui.alence )oint c) Beyond the e-ui.alence )oint d) 6soelectric )oint *hat concentration of !% $ ,ust be )resent which 9ust )re.ents )reci)itation of AgCl in 0.00( Ag + and 0.001
+ 10 8 Cl / <i.en 1 s) of AgCl = 1.0 10 , 1 d for Ag ( !% $ ) " = 1.0 10

a) 0.01 7') 73)

b) 0.00"

c) 0.0"
1"

d) 0.1

The solubility of Ag4C! in 0.00"

+ !% $ is ( 1 s) for Ag4C! > 1.0 10 ? 1 d for Ag ( !% $ ) " = 1.0 108

a) $ 105 b) ( 10( c) ( 105 d) " 105 Calculate Ag + ion concentration in a solution containing 0.0" ,ol of Ag!0$ and 0.1( ,ol of !% $ in 1 @ ( 1 d for Ag ( !% $ ) " = 1.0 10 8
+

78) 77)

a) " 10 b) 1.0 10 c) " 10 6n An acidAbase indicator %6n in a buffer of )% = ) 1 is ioni=ed to the e+tent of a) 70.7B b) 71 B c) 10 B 1a An acidAbase indicator of ) = ( will be suitable for the titration
8 8

7 d) " 10

d) 70 B

a) %Cl with !% $

b) C% $C00% with !% $

c) C% $C00% will !a0% d) %Cl with 10%

100)