CODE: KAARTHEEKA FILE NO.

IIT 172 /17(01/11/2008)

HYD SBD ZONE / JR IIT REG (IIT-69-BITS-MODEL) / 03-11-08 /

CHEMISTRY

Section A [47- 52]

T!"# #$%&"'( %'(&)"(# 6 *+,&"-,$ %!'"%$ .+$#&"'(# (+*/$0$1 23 &' 456 E)%! .+$#&"'( !)# 2 %!'"%$# ())7(/)7(%) )(1 (1)7'+& '8 9!"%! ONLY ONE "# %'00$%&6 :'0 $)%! .+$#&"'( ;'+ 9",, /$ )9)01$1 3 *)0<# "8 ;'+ !)=$ 1)0<$($1 '(,; &!$ /+//,$ %'00$#-'(1"(> &' &!$ %'00$%& )(#9$0 )(1 ?$0' *)0< "8 (' /+//,$ "# 1)0<$($16 I( ),, '&!$0 %)#$#7 *"(+# '($ (-1) *)0< 9",, /$ )9)01$1 @ 47. Metalic sodium dissolves in liquid ammonia to form a deep blue coloured solution which is due to the formation of a) Solvated electron e ( NH 3 ) x : Na + xNH 3 Na + + e ( NH 3 ) x

b) Na : 2 Na Na + + Na

1 H2 2 1 d) Solvated atomic sodium, Na ( NH 3 ) y : ( Na ) x + y ( NH 3 ) Na ( NH 3 ) y x

+ c) NH 2 : Na + NH 3 Na + NH 2 +

48. 4'. )*. ).. )#.

When borax is heated stron l! it ives a) "#$% b) &a#"4$7 c) "a"$# d) &a"$# and "#$% "oron reacts with &a$( to form a) "oric acid b) "orates c) "oric anh!dride d) &one of these +laster of +aris hardens b! a) ,ivin off -$# b) -han in into -a-$% c) -ombinin with water d) ,ivin out water /n solva! ammonia process, sodium bicarbonate will not be precipitated a) +resence of &(% b) 0eaction with -$# c) 0eaction with brine solution d) 0eaction with &a$( 1he sealed containers of same capacit! and at the same temperature are filled with 44 of (# in one and 44 of -$# in the other. /f the pressure of -$# in the second container is . atm, that of h!dro en in the first container would be a) . atm b) .* atm c) ## atm d) 44 atm SECTION-B 43-46@ [Section II contains 4 multiple co ect ans!e t"pe #uestions$ Eac% #uestion %as 4 c%oices &'( 2'( )' an* 4'( out o+ !%ic% one o mo e ans!e s a e co ect$ ,o eac% #uestion in Section II ( "ou !ill -e a!a *e* 4 ma .s i+ "ou %a/e *a .ene* onl" t%e -u--le co espon*in0 to t%e co ect ans!e an* 1e o ma .s i+ no -u--le is *a .ene*$ In all ot%e cases( no ne0ati/e ma .in0 +o ! on0 ans!e $]

)%.

)4. )). )4.

Mar2 the correct statements in the followin . /n diborane 3"#(4) a) 5ach " atom under oes sp% h!bridisation b) 1here is tetrahedra environment around each " atom c) (b 66 "66 (b bond an le is '7* d) 1here are four h!dro en brid e bonds Ma nesium burns in the atmosphere of which of the followin ases 7 a) -$# b) &#$ c) &# d) S$# 1he pairs of compounds which cannot exist to ether in aqueous solution are a) &a(#+$4 and &a#(+$4 b) &a#-$% and &a(-$% c) &a$( and &a(#+$4 d) &a(-$% and &a$( Which of the followin will not liberate h!dro en a) 8n 9 (#S$4 3dil) b) M 9 (&$% 3dil) c) :l#$% 9 &a$( d) -u 9 (#S$4 3conc)

CODE: KAARTHEEKA FILE NO. IIT 172 /17(01/11/2008)

HYD SBD ZONE / JR IIT REG (IIT-69-BITS-MODEL) / 03-11-08 /

S$%&"'( A C 257 34'

T!"# #$%&"'( %'(&)"(# 2 .+$#&"'( (+*/$0$1 43 &' 60 E)%! .+$#&"'( %'(&)"(# STATEMENT-1 (A##$0&"'() )(1 STATEMENT-5( R$)#'() E)%! .+$#&"'( !)# 2 %!'"%$# ())7 (/)7 %) )(1 (1) '+& '8 9!"%! ONLY ONE "# %'00$%&6 :'0 $)%! .+$#&"'( ;'+ 9",, /$ )9)01$1 3 *)0<# "8 ;'+ !)=$ *)0<$1 '(,; &!$ /+//,$ %'00$#-'(1"(> &' &!$ %'00$%& )(#9$0 )(1 ?$0' *)0< "8 (' /+//,$ "# 1)0<$(16 I( ),, '&!$0 %)#$#7 *"(+# '($ (-1) *)0< 9",, /$ )9)01$16@

a) "oth : and 0 are true and 0 is the correct explanation of : b) "oth : and 0 are true but 0 is not the correct explanation of : c) : is true , 0 is false d): is false 0 is true
:SS501/$& ; 05:S$& )7. )8. )'. 4*. A##$0&"'( : Settin of cement is endothermic process R$)#'( : /t involves deh!dration of calcium aluminates and calcium silicates A##$0&"'( : 1he compound called inor anic ben<ene is bora<ine R$)#'( : "ora<ine has structural similarit! with ben<ene. A##$0&"'( : Sulphate is estimated as "aS$4 and not as M S$4 R$)#'( : /onic radius of M #9 is smaller than that of "a#9 A##$0&"'( : Ma nesium is extracted b! the electrol!sis of fused mixture of M -l#, &a-l and -a-l# R$)#'( : -alcium chloride acts as a reducin a ent.

S$%&"'( AD
5in.e* Comp e%ension T"pe T!$ #$%&"'( %'(&)"(# 3 -)0)>0)-!# P6163 7 P6366 )(1 P66 69 6 B)#$1 +-'( $)%! -)0)>0)-!7 3 *+,&"-,$-%!'"%$ .+$#&"'(# !)=$ &' /$ )(#9$0$16 E)%! .+$#&"'( !)# 2 %!'"%$# ())7 (/)7 (%) )(1 (1) '+& '8 9!"%! ONLY ONE "# %'00$%& :'0 $)%! .+$#&"'( ;'+ 9",, /$ )9)01$1 2 *)0<# "8 ;'+ 1)0<$( '(,; &!$ /+//,$ %'00$#-'(1"(> &' &!$ %'00$%& )(#9$0 )(1 ?$0' *)0< "8 (' /+//,$ "# 1)0<$($16 I( ),, '&!$0 %)#$#7 *"(+# '($ (-1) *)0< 9",, /$ )9)01$16@ 6ASSA7E-I Metallic nitrate 3:) on heatin decomposes leavin a solid residue 3") which oes into solution with dilute (-l. 1he solution of 3") ives a white precipitate with ammonium carbonate solution. 1he solution 3") with dilute (#S$4 also ives a white precipitate 3=) insoluble in dilute (-l and nitric acid. 1he precipitate 3=) is a part of a white pi ment lithopone. 4.. 4#. 4%. 1he compound 3=) is a) "aS$4 1he metal nitrate 3:) is a) -a3&$%)# 1he solid residue 3") is a) -a$ b) M S$4 b) +b3&$%)# b) +b$ c) -aS$4 c) "a3&$%)# c) 8n$ d) &a#S$4 d) >&$% d) "a$

CODE: KAARTHEEKA FILE NO. IIT 172 /17(01/11/2008)

HYD SBD ZONE / JR IIT REG (IIT-69-BITS-MODEL) / 03-11-08 /

6ASSA7E-II :l2ali and al2aline earth metals alon with (!dro en and (elium constitute s ? "loc2 elements. 1he! have low ioni<ation enthalpies and hence exhibit characteristic flame colurations. 1he! have hi hl! ne ative electrode potentials and hence are stron reducin a ents. 1heir solutions in liquid ammonia are conductin and also act as stron reducin a ents. "ein stron er reducin a ents than h!dro en, the! are usuall! prepared b! electrol!sis of their fused chlorides. 1heir oxides are basic and basic stren th increases down the roup. 1he solubilit! of carbonates and sulphates of al2ali and al2aline earth metals show opposite trends. 1he carbonates of al2aline earth metals and lithium carbonate decompose on heatin while the carbonates of other al2ali metals donot decompose on heatin . 1he bicarbonates of both al2ali and al2aline earth metals on heatin ive carbonates. 44. 1he basic character of the oxides M $, Sr$, >#$, &i$ and -s#$ increases in the order. a) M $ @ Sr$ @ >#$ @ &i$ @ -s#$ b) -s#$ A >#$ A M $ A Sr$ A &i$ c) &i$ A M $ A Sr$ A >#$ A -S#$ d) >#$ A &i$ A M $ A Sr$ A -s#$ Which of the followin are arran ed in increasin order of solubilities a) -a-$% @ >(-$% A &a(-$% b) &a(-$% A >(-$% A -a-$% c) >(-$% A &a(-$% A -a-$% d) -a-$% A &a(-$% A >(-$% /dentif! the correct order of acidic stren ths of -$#, -u$, -a$, (#$ a) -a$ A -u$ A (#$ A -$# b) (#$ A -u$ A -a$ A -$# c) -a$ A (#$ A -u$ A -$# d) (#$ A -$# A -a$ A -u$ 6ASSA7E-III : compound 3B) white cr!stalline reacts with water to produce an al2aline solution. $n heatin it produces a transparent bead which on heatin with -uS$ 4 form a blue colour bead C. -ompound B on heatin with ethanol and (#S$4 ive reen ed ed flame. -ompound B dissolves in &a$( but when conc. (#S$4 is added white cr!stals of an acid 38) separate out. 47. 1he compound B is a) &a# D"4$) 3$()4E. 8(#$ c) &a#D"4$73$()8E 1he reen ed ed flame is because of a) vapours of ethanol c) vapours of trieth!l borate 1he compound 8 is a) &a#"4$7 b) (%"$% b) &a"$# d) (%"$% b) vapours of sulphuric acid d) vapours of boron trisulphate c) &a#S$4 d) &a"3S$4)#

4).

44.

48.

4'.

6A6ER SETTER HY8 S98

MATHS: SRI CHA;8RA M<=5I: >>&2)4)5&2 6HYSICS: SRI RAMA?RISH;A: >44&>45&54 CHEMSITRY: MEE;A?SHI : >44&44)422( 27@2)7)7

8ISC=SSI<; 6ARTICI6A;T 9RA;CHES

CODE: KAARTHEEKA FILE NO. IIT 172 /17(01/11/2008)

HYD SBD ZONE / JR IIT REG (IIT-69-BITS-MODEL) / 03-11-08 /

T6T A HY8 ?6IC