Match the following.

M1.
COLUMN I COLUMN II
A
2
dil solution
F NaOH



+
P Sodium halide is one of the product
B
2
Conc.solution
F NaOH



+
Q isproportionation reaction
C
2
Cold!dilute
Cl NaOH



+
"
2
O is one of the product

2
Hot!Conc
Cl NaOH



+
S
f actor
n of halo#en is 2
$
f actor
n
of halo#en is 1
M2.
COLUMN I COLUMN II
A Solu%le in a concentrated
&
NH solution P
2
Ag S
B Solu%le in e'cess (CN solution Q ( )
2
Cu OH
C Solu%le in e'cess h)po solution " A#Br
Solu%le in cone.HCl S A#Cl
M1. A*P!S B*P!"!S C*P!Q!$ *P!Q
M2. A*Q!"!S B*P!Q!"!S C*Q!"!S *Q!S
Match the following
Match the following
M1.
COLUMN I COLUMN II
A
$he sum of first! and third nearest
nei#h%ourin# atom in SCC
P 2+
B
$he sum of fourth! fifth nearest
nei#h%ourin# atoms in FCC
Q 1,
C
$he sum of first! second! third
nearest nei#ht%ourin# ions in NaCl
structure
" 2-

$he sum of second and third nearest

nei#h%ourin# atoms BCC
S 1.
M2.
COLUMN I COLUMN II
A & &
H PO
P isproportionates
B 2 2 .
H S O
Q Forms t/o t)pes of salt 0i%asic1
C HO ClO " Plane of s)mmetr)
& 2
H PO
S
At least one
&
sp h)%ridi2ed atom is
present
M1. A* Q B*" C*P *S
M2. A* P! Q! "! S B* P!Q! S C*P!"!S *P!"!S
N2.
( )
( )
2 1
-
1
& 2.3 1- min
M
A C zeroorder K M

=
( )
( )
2 1
1
1
2 +.4& 1- min
M
B D First order K

=
At the end of 2- minutes Find the 5alue of
[ ]
[ ]
[ ]
[ ]
C D
B A
+
Match the following
M1.
COLUMN I COLUMN II
A
& 2
6 66 6 Au Au Mg Mg
+ +
P Spontaneous cell construction
B
2
6 66 6 Li Li Cu Cu
+ +
Q Non*spontaneous cell construction
C
( )
( )
( ) ( )
( )
( )
2 2
1 1
2 1
6 6 66 6 6
M M
atm atm
Pt H g H H H g Pt
+ +
"
-
Cell cell
E E =

( ) ( ) ( ) ( ) 6 66 6 Zn s ZnO s HgO s Hg l
S 78uili%rium constant
1
e
K =

Comprehension -1
A feather)! #reenish solid precipitate can %e o%ser5ed if chlorine #as is %u%%led into /ater
close to its free2in# point. Similar precipitates form /ith other #ases such as methane and no%le #ases.
$hese materials are interestin# %ecause 5ast 8uantities of so called methane h)drates are supposed to e'ist
in nature. 0compara%le in 8uantit) /ith other natural #as deposits1
$hese precipitates all ha5e related structures. $he molecules of /ater 9ust a%o5e its free2in#
point form a h)dro#en %ond strucute. $he #as moelcules sta%ili2e this frame /or: %) fillin# in the rather
lar#e ca5ities in the /ater structure formin# clatharates.
$he cr)stals of chlorine and methane clatharates ha5e the same structure. $heir main
characteristics are dodecahedra formed from 2- /ater moelcules. $he unit cell of the cr)stal can %e thou#ht
as a %od)*centred cu%ic arran#ement %uilt from these dodecahedra /hich are almost spherical o%9ects. $he
dodecahedra are connected 5ia additional /ater molecules located on the faces of unit cell. $/o /ater
molecules can %e found on each face of the unit cell.
$here are t/o t)pes of ca5ities in this strucuture. One is internal space in the dodecahedra
0A1. $hese are some /hat smaller than the other t)pes of 5oids 0B1! of /hich there are + for each unit cell.
NOTE:
;n #eometr)! a dodecahedron is a pol)hedron /ith t/el5e flat faces. ;t is composed
of 12 re#ular penta#onal faces! /ith three meetin# at each 5erte'. ;t has 2- 5ertices and &-
ed#es.
1. Ho/ man) t)pe A ca5ities can %e found in a unit cell<
0a11 0%1 2 0c1 & 0d1 ,
2. Ho/ man) /ater molecules are there in a unitcell<
0a1 ,- 0%1 2, 0c1 ,+ 0d1 &-
&. ;f all ca5ities contain a #uest molecule! /hat is the ratio of the num%er of /ater to the num%er of #uest
molecules<
0a1 3 0%1 & 0c1 &.=3 0d1 3.=3
Comprehension -1
A dilute solution contains >'? moles of solute A in 1 :# of sol5ent /ith molal ele5ation constant
!
K $he
solute dimerises in the solution accordin# to the follo/in# e8uation.
2
2A A .$he de#ree of association
is ( )
1. $he 5an?t Hoff factor /ill %e@
0a1 1 2 i = 0%1 1
2
i

= 0c1 1
2
i

= + 0d1
1 i = +
2. $he molecular /ei#ht o%ser5ed /ill %e @
0a1 #reater than actual molecular /ei#ht 0%1 Aesser than actual molecular
/ei#ht
0c1 e8ual to the actual molecular /ei#ht 0d1 cannot %e predicted %) the data
#i5en

&. $he de#ree of association is e8ual to@
0a1
( )
.2
! !
!
K " #
#

0%1
( ) 2
! !
!
K " #
K "

= 0c1
2
2
!
!
#
K "

= +
0d1
2
!
!
#
K "

=
1-.B
11.A 12.B
Comprehension -1I
;n the 8ualitati5e anal)sis of inor#anic salts! the different cations are classified
into fi5e #roups. $his clasification is %ased on the solu%ilit) products of the chlorides!
sulphides! h)dro'ides and car%onates of selecti5e ions. Broup ; consists of cations /ith
least (sp for their chlorides. Broup ;; consists of cations /ith least (sp for their
sulphides. Broup ;;; consists of cations /ith least :sp for their h)dro'ides! Broup ;C
consists of cations /ith sli#htl) hi#her 5alue of (sp for their sulphides. Broup C consists
of cations /ith least (sp for their car%onates.
1. An a8 solution of a salt #i5es a /hite ppt. /hen treated /ith dil HCl. $he ppt is
solu%le in hot /ater and a %lac: ppt is formed /hen ( )
2
H S g
is passed throu#h the hot
solution. $he cation in the salt is
0a1
Ag
+
0%1
2
P!
+
0c1
2
2
Hg
+
0d1
2
Hg
+
2. Dhich amon# the follo/in# pairs of ions cannot %e separated %) ( )
2
H S g
in dilute
HCl<
0a1
& &
! Bi S!
+ +
0%1
2 2
! Fe Hg
+ +
0c1
2 2
! Zn Cu
+ +
0d1
2 2
E Ni Cd
+ +
&. Dhich of the follo/in# pairs are solu%le in a8 &
NH
solution<
0a1 2
E CaF AgCl
0%1
( ) ( )
2 &
E Cu OH Al OH
0c1
( )
2
E AgCl Cu OH
0d1
( )
2
&
E CaF Al OH
1&.B 1,.A 13.C