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Dow Corning Toray Co., Ltd. Material Safety Data Sheet

Revision Date: MSDS No.:

2011/11/29 04055856

DOW CORNING TORAY SZ-1671

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name Company Name Address Phone Number Product Code Emergency Telephone Number : : : : : : DOW CORNING TORAY SZ-1671 Dow Corning Toray Co., Ltd. 100-0004, 1-5-1 Otemachi, Chiyoda-ku, Tokyo, Japan 03-3287-8300 (Customer Service) 04055856 0436-21-3101

2. HAZARDS IDENTIFICATION
GHS Classification GHS Label Elements Pictogram or Symbol Signal Word Hazard Risk Statement Precautionary Statement Prevention Response : Not applicable for GHS classification. : None. : None. : Not hazardous. : Avoid contact with skin and eyes. : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF ON SKIN: Wash with plenty of soap and water. : Not applicable. : Not applicable. : None known.

Storage Disposal Other Hazard

3. COMPOSITION / INFORMATION ON INGREDIENTS

: Chemical characterization : Generic Name Ingredients and Contents CAS ENCS Chemical Number Number formula
556-67-2 (7)-475 Cycl(Si(CH3)2O)4

Mixture Silicone Wt %
0.1 - 1

Component Name
Octamethylcyclotetrasiloxane

GHS Classification
Flammable liquid: Category 3 Reproductive toxicity (Inhalation - vapour): Category 2 Chronic aquatic hazard: Category 4 Flammable liquid: Category 2 Skin corrosion/irritation: Category 2 Reproductive toxicity: Category 2 Specific target organ toxicity - single exposure (Inhalation - vapour): Category 3 (narcotic effects) Specific target organ toxicity - repeated exposure (Inhalation): Category 2 (central nervous system) Aspiration hazard: Category 1 Acute aquatic hazard: Category 2

108-88-3

(3)-2

C6H5CH3

<1

Toluene

Comments

: This product contains the above chemical(s) listed by Japanese regulations and/or classified and containing not less than cut-off value by GHS.

4. FIRST AID MEASURES

In Case of Inhalation In Case of Skin Contact In Case of Eye Contact : No first aid should be needed. : No first aid should be needed. : Immediately flush with water.

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Dow Corning Toray Co., Ltd. Material Safety Data Sheet

Revision Date: MSDS No.:

2011/11/29 04055856

DOW CORNING TORAY SZ-1671

: Get medical attention. In Case of Ingestion : Treat symptomatically. Comments Possible Acute and Chronic Health Effect: Acute : Direct contact may cause temporary redness and discomfort. Eyes : No significant irritation expected from a single short-term exposure. Skin : No significant effects expected from a single short-term exposure. Inhalation : Low ingestion hazard in normal use. Ingestion Chronic : No known applicable information. Skin : No known applicable information. Inhalation : Repeated ingestion or swallowing large amounts may injure internally. Ingestion : No known applicable information. Other Health Hazard Information : No significant adverse effects from normal use. Important Symptoms and Hazard Effects : No respiratory protection should be needed. Use proper protection - safety glasses as a Personal Protection for First minimum. Washing at mealtime and end of shift is adequate. Aid or Rescue Personnel : Treat symptomatically. For further information, the medical practitioner should contact Note to physicians Dow Corning Toray Co.,Ltd.
The above listed potential effects of overexposure are based on actual data, the results of studies performed upon similar compositions, component data, and/or expert review of the products.

5. FIRE-FIGHTING MEASURES
Extinguishing Media Unsuitable Extinguishing Media Specific Hazards during Fire Specific Fire Fighting Protection for Fire-fighter : On large fires use dry chemical, foam or water spray. On small fires use carbon dioxide (CO2), dry chemical or water spray. Water can be used to cool fire exposed containers. : None established. : None. : Determine the need to evacuate or isolate the area according to your local emergency plan. Use water spray to keep fire exposed containers cool. : Self-contained breathing apparatus and protective clothing should be worn in fighting large fires involving chemicals.

6. ACCIDENTAL RELEASE MEASURES

Personal Precautions, Protective Equipment and Emergency Procedures Environmental Precautions Recovery and Neutralization/ Methods and Materials for Containment and Cleaning up : Avoid eye contact. Do not take internally. Please refer to section 8 Protective equipment. : Prevent from spreading or entering into drains, ditches or rivers by using sand, earth or other appropriate barriers. : Determine whether to evacuate or isolate the area according to your local emergency plan. Observe all personal protective equipment recommendations described in this MSDS. If diked material can be pumped, store recovered material in appropriate container. Clean up remaining materials from spill with suitable absorbant. Clean area as appropriate since spilled materials, even in small quantities, may present a slip hazard. Final cleaning may require use of steam, solvents or detergents. Dispose of saturated absorbant or cleaning materials appropriately, since spontaneous heating may occur. Laws and regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which laws and regulations are applicable.

7. HANDLING AND STORAGE

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Dow Corning Toray Co., Ltd. Material Safety Data Sheet

Revision Date: MSDS No.:

2011/11/29 04055856

DOW CORNING TORAY SZ-1671

Handling Technical Measures Local and General Ventilation Precautions Safe Handling Advice Avoidance of Contact Storage Technical Measures and Storage Conditions Packaging Material : Use with adequate ventilation. : Please refer to section 8 Ventilation. : Avoid eye contact. Do not take internally. : Exercise good industrial hygiene practice. Wash after handling, especially before eating, drinking or smoking. : Please refer to section 10 Conditions to Avoid and Materials to Avoid. : Use reasonable care and store away from oxidizing materials. : None established.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Concentration Control Notification #79 from Ministry of Labor
None known.

Industrial Hygiene Standards Component Name

Octamethylcyclotetrasiloxane Toluene

Exposure Limits
Dow Corning guide: TWA 10 ppm. Japan Association on Industrial Health Guideline (2007): TWA 50 ppm (188 mg/m3). OSHA PEL (final rule): 8-Hour TWA 200 ppm, Ceiling 300 ppm, 10 minutes maximum duration 500 ppm. ACGIH TLV: TWA 20 ppm.

Engineering Measures : None should be needed. Local Ventilation : Recommended. General Ventilation Personal Protective Equipment Personal Protective Equipment for Routine Handling : No respiratory protection should be needed. Respiratory protection : None should be needed. Suitable Respirator : No special protection needed. Hand protection : Use proper protection - safety glasses as a minimum. Eye protection : Washing at mealtime and end of shift is adequate. Skin protection : Exercise good industrial hygiene practice. Wash after handling, especially before eating, Hygiene Measures drinking or smoking. Personal Protective Equipment for Spills : No respiratory protection should be needed. Respiratory protection : Use proper protection - safety glasses as a minimum. Eye protection : Washing at mealtime and end of shift is adequate. Skin protection : Avoid eye contact. Do not take internally. Use reasonable care. Precautionary Measures : If this product is heated to > 150 degrees C, trace quantities of formaldehyde may be Comments released, and adequate ventilation is required.
Note : These precautions are for room temperature handling. Use at elevated temperature or aerosol/spray applications may require added precautions. For further information regarding aerosol inhalation toxicity, please refer to the guidance document regarding the use of silicone-based materials in aerosol applications that has been developed by the silicone industry (www.SEHSC.com) or contact the Dow Corning customer service group.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State Form Color : Liquid : Light brown.

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Dow Corning Toray Co., Ltd. Material Safety Data Sheet

Revision Date: MSDS No.:

2011/11/29 04055856

DOW CORNING TORAY SZ-1671

Odour pH Melting point/Freezing Point Boiling point, Initial Boiling Point, and Boiling Range Flash Point Characteristics of Explosives Vapor Pressure @ 25C Vapor Density(air=1) Specific Gravity Solubility Octanol/water partition Autoignition Temperature Decomposition Temperature Odour Threshold Evaporation Rate Flammability (solid, gas) Viscosity : : : : : : : : : : : : : : : : : Slight odor Not determined. Not determined. > 35 C 222 C(Cleveland Open Cup) Not determined. Not determined. Not determined. 1.05 g/cm3 Not determined. Not determined. Not determined. Not determined. Not determined. Not determined. Not applicable. 765 mm2/s

The above information is not intended for use in preparing product specifications. Contact Dow Corning before writing specifications.

10. STABILITY AND REACTIVITY

Stability Possibility of Hazardous Reactions Conditions to Avoid Materials to Avoid Hazardous Decomposition Products : Stable. : Hazardous polymerization will not occur. : None. : Can react with strong oxidising agents. : Carbon oxides and traces of incompletely burned carbon compounds. Silicon dioxide. Formaldehyde.

11. TOXICOLOGICAL INFORMATION

Acute Toxicity Please refer to Section 3 and Section 4 Health Effect. Skin Corrosion/ Irritation Serious Eye Damage/ Irritation Respiratory Organs Sensitization or Skin Sensitization Germ Cell Mutagenicity Carcinogenicity Reproductive Toxicity Specific Target Organ. Systemic Toxicity (Single Exposure) Specific Target Organ. Systemic Toxicity (Repeated Exposure) Aspiration Hazard : Please refer to Section 3 and Section 4 Health Effect. : Please refer to Section 3 and Section 4 Health Effect. : Please refer to Section 3 and Section 4 Health Effect.

: Please refer to Section 3, Section 4 Health Effect and Section15 ISHL Mutagen Substance. : Please refer to Section 3, Section 4 Health Effect and Section15 ISHL Carcinogen Substance. : Please refer to Section 3 and Section 4 Health Effect. : Please refer to Section 3 and Section 4 Health Effect.

: Please refer to Section 3 and Section 4 Health Effect.

: Please refer to Section 3 and Section 4 Health Effect.

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Dow Corning Toray Co., Ltd. Material Safety Data Sheet

Revision Date: MSDS No.:

2011/11/29 04055856

DOW CORNING TORAY SZ-1671

12. ECOLOGICAL INFORMATION
Ecotoxicity Environmental Effects Acute Chronic Fate and Effects in Waste Water Treatment Plants Persistence and Degradability Degradation Bioaccumulative Potential Bioaccumulation Mobility in Soil Additional Environmental Information

: This product contains substances which may cause adverse effects in the aquatic environment. : This product contains substances which may cause adverse effects in the aquatic environment. : No specific information is available.

: In soil, siloxanes are degraded. : Low potential to bioaccumulate. : Siloxanes are removed from water by sedimentation or binding to sewage sludge. : No specific information is available.

13. DISPOSAL CONSIDERATIONS

Residual Waste Contaminated Containers or Packaging Note : This product falls under Industrial Waste (Waste Oil) based on Wastes Disposal and Public Cleansing Law. Dispose of in accordance with local regulations. : Dispose of in accordance with local regulations. : None.

14. TRANSPORT INFORMATION

: Refer to Section 15. Local Regulations International Regulations Sea Transport (IMDG) Not subject to IMDG code. Air Transport (IATA) Not subject to IATA regulations.

15. REGULATORY INFORMATION

Law Concerning Examination and Regulation of Manufacture, etc. of Chemical Substances : This product is not applied into the code about Specified Chemical Substances, Monitoring Chemical Substances and Priority Assessment Chemical Substances.

Industrial Safety and Health Law : Specific Notification Substance Number

407

Notification Component(s)
Toluene

Wt %
<1

Indication Substance Ordinance on Prevention of Organic Solvent Poisoning

: Not applicable. : Not applicable.

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Dow Corning Toray Co., Ltd. Material Safety Data Sheet

Revision Date: MSDS No.:

2011/11/29 04055856

DOW CORNING TORAY SZ-1671

: Ordinance on Prevention of Hazards due to Specified Chemical Substances : Ordinance on Prevention of Lead Poisoning : Ordinance on Prevention of Tetraalkyl Lead Poisoning : Hazardous Material : Banned Substance : Mutagen Substance : Carcinogen Substance : High Pressure Gas Safe Law : Fire Service Law : Poisonous and Deleterious Substance Control Law Pollutant Release and Transfer : Register : Marine Pollutant Prevention Law Chemical Inventories TSCA : EINECS AICS IECSC ENCS/ISHL KECL PICCS DSL HSNO : : : : : : : : Not applicable.

Not applicable Not applicable

Not applicable. Not applicable Not applicable. Not applicable. Not applicable. 4TH GROUP, 4TH CLASS PETROLEUMS (6,000L) Not applicable. Not applicable. Not Classified as a Marine Pollutant

All chemical substances in this material are included on or exempted from listing on the TSCA Inventory of Chemical Substances. All ingredients listed or exempt. All ingredients listed or exempt. All ingredients listed or exempt. All components are listed on ENCS/ISHL or its exempt rule. All ingredients listed, exempt or notified. All ingredients listed or exempt. All chemical substances in this material are included on or exempted from the DSL. All ingredients listed or exempt.

16. OTHER INFORMATION

Bibliography: Statue book of chemicals, Internal Technical Data and others JAMP MSDSplus Substance Information This is based on MSDSplus(Ver.3.1) by JAMP(Joint Article Management Promotionconsortium). This product contains the following substance(s) listed in the relevant standard and to be notified. The objects of investigation are the followings. Substances are applied to the regulation for JP01, JP02, or JP03. They are contained intentionally or their concentration is more than or equal to the cutoff value for EU01 or EU02. Their concentration is more than or equal to 0.1% for EU03, EU04, or EU05. OT01, IA01, IA02 are not a subject of investigation. Component Name CAS Number Max wt% Relevant Standard Toluene 108-88-3 <1 EU04

Relevant Standard Code Relevant Standard Issued or revised

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Dow Corning Toray Co., Ltd. Material Safety Data Sheet

Revision Date: MSDS No.:

2011/11/29 04055856

DOW CORNING TORAY SZ-1671

JP01 JP02 JP03 EU01 EU02 EU03 Japanese Chemical Substances Control Law (Class I Specified Chemical Substances) Industrial Safety and Health Act (Substances Prohibited of Manufacturing etc.) Poisonous and Deleterious Substance Control Law (Specified Poisonous Substances) RoHS Directive ELV Directive CLP Annex VI CMR-Cat1,2 2010-04-01 2007-09-07 2007-08-15

2002/95/EC 2000/53/EC EC No 1272/2008, ATP1 included EU04 REACH Annex XVII [Except EU03] EC No 552/2009 EU05 REACH SVHC on the Candidate List 2011-06-20 Substances do not directly mean legally regulated. It depends on use and other conditions. For more information please refer to "How to make JAMP MSDSplus".

These data are offered in good faith as typical values and not as product specifications. They are believed accurate as of the date of this Material Safety Data Sheet based on a review of current composition and information supplied by vendors. No warranty, either expressed or implied, is hereby made. The recommended industrial hygiene and safe handling procedures are believed to be generally applicable. However, each user should review these recommendations in the specific context of the intended use and determine whether they are appropriate. This Product has been developed and manufactured for general industrial use. For medical use, or other uses where safety considerations may be required, you must in advance test and review the safety of your intended application. Moreover, this Product is not for human implant nor human injection, nor use for applications which may present risk of accumulating inside human bodies.

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