JEE-Adv Grand Test Question Paper (P 1) - 08-05-2014

IIT Section
Subject Topic Grand Test Paper I Date

C + M + P Grand Test 06
IIT GT 06
08
th
May 2014
I20140508

Max. Marks: 252 Duration: 3 Hrs

- This paper consists of 84 questions with 3 parts of Chemistry, Mathematics and Physics
- Each Part consist of 4 sections

- Section I : 8 Multiple Choice Questions with one correct answer (with negative marks). A
correct answer carries 3 Marks. A wrong answer carries a penalty of 1 mark
- Section II : 5 Multiple Choice Questions with one or more correct answers (No negative
marks). A correct answer carries 3 Marks.
- Section III : 5 Comprehension Type questions. A correct answer carries 3 Marks. A wrong
answer carries a penalty of 1 mark
- Section IV : 10 Integer Type question with one correct answer. A correct answer carries 3
Marks. No negative mark.

2. Darken the appropriate bubble using a pen in the OMR sheet provided to you. Once entered,
the answer cannot be changed. Any corrections or modifications will automatically draw a
penalty of 1 mark.

3. Use of calculators and log tables is prohibited.

4. No clarification will be entertained during the examination. Doubts in the paper can be
reported to the coordinator after the exam.

5. All the best !!

Useful Data
At. Wt.:
N = 14; O = 16; H = 1; S = 32; Cl = 35.5; Mn = 55; Na = 23; C = 12; Ag = 108; K = 39; Fe = 56; Pb = 207
Physical constants:
34
6.626 10 J.sec h

= ,
23 -1
a
N 6.022 10 mol = ,
8 -1
C 2.998 10 ms = ,
31
e
m 9.1 10 kg
=
IIT Section

IIT GT 06
08
th
May 2014
I20140508

Ace Insignia Rough Work Page 2

Chemistry
Section I
Multiple Choice Questions with one correct answer. A correct answer carries 3 marks. A wrong
answer carries a penalty of 1 mark 8 x 3 = 24

1. Most powerful reducing agent among the following is;
(a) pyrophosphoric acid (b) hypophosphoric acid
(c) hypophosphorous acid (d) orthophosphorous acid
2. A vertical cylinder closed at both ends, is divided into two parts by a frictionless piston, each part
containing one mole of air. At temperature 300 K, the volume of upper part is 4 times than that of
the lower part. At what temperature will the volume of upper part be three times than that of lower
part?
(a) 210.937 K (b) 843.75 K (c) 354.853K (d) 421.875 K
3. Which of the following statements is correct?
(a) In Mohrs salt, ( )
4 4
2
NH SO enables hydrated
4
FeSO to be used as a better primary standard
during titration than green vitriol
(b) AgOH when added to an aqueous solution of
2 2 7
K Cr O gives precipitate of
2 2 7
Ag Cr O
(c) Oxidising action of bleaching powder is more in hot water than in cold water
(d) A warm aqueous solution of chlorine is less acidic than in cold aqueous solution
4. Two methods are generally used for preparation of carboxylic acid from alkyl halides
Method: I - Cyanide method
3
( )
H O KCN
RX A RCOOH
+

Method: II - Grignard method
2
)
CO Mg H
RX RCOOH
+

Which method is suitable for preparation of
from

(a) Method I (b) Method II (c) Both I & II (d) Neither I nor II

HO
Cl COOH
HO
IIT Section

IIT GT 06
08
th
May 2014
I20140508


5. A vessel contains H2 and H2S gases at a partial pressures of 1 and 2 atm respectively at certain
temperature then the reaction,
2 2 8
8 ( ) 8 ( ) ( ) H S g H g S s + occurs. It is found that
2 2
2 2
, 0
H H S
H H S
n n
n n
at time t at equilibrium
( (
( ( =
( (

=
(n represents no of moles)
Then identify the correct value of the given property
(a) KP = 1/256
(b) KP = 256
(c) At equilibrium the volume of the gaseous mixture is doubled when provided with
frictionless piston
(d) KP = KC = 320
6. At 35
o
C, the vapour pressure of pure liquids, A and B are 512 mm Hg and 344 mm Hg respectively.
Solution of A and B liquids (in which 0.25 is the mole fraction of A) shows a total vapour pressure of
600 mm Hg at the same temperature. Which of the following is true about the solution of A and B?
(a) A mixture of 50 ml each of A and B has a total volume of 100 ml
(b) When A is added to B to prepare a solution at 35
o
C, heat is absorbed
(c) Raoults law is obeyed by solution of A and B in which mole fraction of A is 0.25
(d) A mixture of 100 ml of A and 100 ml of B will have the volume less than 200 ml
7.
4
Z LiH
B X Y LiBH + ; If B is Boron then
(a) Z is hydrogen
(b) X is
2 6
B H
(c) Z and Y are
2
F and
2 6
B H respectively
(d) X is potassium hydroxide

8. Which of the following are isoelectronic and isostructural?
(a)
2
3 3
, NO CO

(b)
3 3
, SO NO
(c)
2
3 3
, ClO NO

(d)
2
3 3
, CO SO

IIT Section

IIT GT 06
08
th
May 2014
I20140508


Section II
Multiple Choice Questions with one or more correct answer. A correct answer carries 3 marks.
No negative mark 5 x 3 = 15
9. Pick out the correct statement(s)?
(a) Due the presence of F- centres in crystals, the crystal attains paramagnetic character
(b) Frenkel defect is a dislocation defect.
(c) In case of diamond that follows zinc blende structure the number of carbon atoms per unit
cell is four
(d) Due to Schottky defect in crystals, the electrical neutrality is not affected
10. Indicate correct statements from below;
(a) Solid PCl5 and PBr5 are ionic and exist as PX4
+
PX6
-
while PI5 does not exist as such
(b) PH5 does not exist but PF5 exists
(c) BiF5 exists
(d) BiCl3 and SbCl3 do not respond to chromyl chloride test like NaCl
11. Lucas test is used to make distinction between 1, 2 and 3 alcohols
2
.
2
ROH H O
conc
White turbidity
anhydrous ZnCl
HCl RCl + + +
(a) ROH behaves as a Lewis base
(b) Greater the value of pKa (alcohol), greater the reactivity with conc. HCl and thus faster the
formation of white turbidity.
(c) Alcohol which readily reacts with Na metal, will give turbidity readily
(d) Alcohol which gives red colour in Victor Meyer test, will give turbidity at slower rate than
those giving blue or white colour in Victor Meyer test
12. In Arrhenius equation, k = A exp
Ea
RT
| |
|
\ .
; A is equal to k when
(a) temperature is very low
(b) temperature tends to infinity
(c) activation energy is equal to zero (d) reactions carried on surface of catalyst
IIT Section

IIT GT 06
08
th
May 2014
I20140508


13. Which of the following statements are correct?
(a)
2
CaH hydrolith is used for production of
2
H
(b)
BeO is covalent due to small size but has high melting point
(c)
2
CaCl is widely used for melting ice on roads because 30% eutectic mixture of
2
CaCl / ice
freezes at 218 K
(d) Carbides of Beryllium react with water liberating methane gas

Section III
Comprehension type questions. A correct answer carries 3 marks. A wrong answer carries a
penalty of 1 mark 5 x 3 = 15
Comprehension I
Acid derivatives undergo nucleophilic displacement reaction in which, a nucleophile connects to
carbonyl carbon and displaces from acid chlorides, anhydrides, esters and amides respectively.
|| ||
O O
R C Z R C Nu

The reactivity depends on how fast, the nucleophile attacks as well as ability of the group Z to leave.
Acid chlorides undergo Rosenmunds reduction and esters undergo Claisen condenstaiton
14. Which of the following is the correct order of reactivity towards nucleophilic substitution?
(a)
2
||
2
|| || ||
O
O O O
R C NH R C Cl R C O R C OR
| |
|
> > >
|
\ .

(b)
1
2
2
|| || || ||
O O O O
R C Cl R C O R C OR R C NH
| |
|
> > >
|
\ .

(c)
( )
1
2 2
||
O
R C Cl R CONH RCOOR RCO O > > >

(d)
( )
1
2 2
||
O
R C Cl RCOOR RCO O RCONH > > >

IIT Section

IIT GT 06
08
th
May 2014
I20140508


15.
5 3 2 2
5 2
.
C H O
CH CH COOC H

A The product (A) formed in this reaction is,
(a)
3 2 2 2 5
CH CH COCH COC H (b)
3 2 2 5
CH CH COCH CHCOOC H =
(c)
|
5 3 2 2
3
||
CH CH C CH COOC H
O
CH
(d)
3
5 3 2 2 2
|
CH CH C CHCH COOC H
CH
=

16.
3 2
2
4
,
( )
. ,
H
Pd BaSO
Quinoline
Excess
CH C C CH COCl X X is

(a) (b)

(c) (d)

Comprehension II
A coordination complex with empirical formula
2 2 2
( ) ( ) Co en NO Cl is available in a number of
isomeric forms . One of them (A) reacts with both AgNO3 and ethylenediammine, while another form
(B) reacts with only AgNO3 but not with ethylene diammine. At the same time, another isomer (C) reacts
with ethylene diammine but not with AgNO3 while another isomer (D) neither reacts which AgNO3 nor
with ethylene diammine. Now answer the following questions on the basis of information given above

C C
CH
2
CHO
H
C H
3
H
C C
H
H
C H
3
CH
2
CHO
C C
CH
2
CH
2
OH
H
C H
3
H
C C
H
H
C H
3
CH
2
COCl
IIT Section

IIT GT 06
08
th
May 2014
I20140508


17. Isomer A is

(a) (b)

(c) (d)

18. Isomer B is

(a) (b)

(c) (d)

Cl
NO
2
Co en cn NO
2
NO
2
Co
en
NO
2
Cl
en
NO
2
Co
en
Cl
en
NO
2
NO
2
Co en
NO
2
en
NO
2
NO
2
Co en en Cl
NO
2
NO
2
Co
en
NO
2
Cl
en
NO
2
C
o
en
Cl
en
Co
Cl
NO
2
NO
2
en
en
IIT Section

IIT GT 06
08
th
May 2014
I20140508


Section IV
Integer answers type questions. Each carries 3 marks. No negative marks 10 x 3= 30
19. For the Mg Ag cell, how many times the difference between the EMF of the cell and its standard
EMF will change if concentration of
2
Mg
+
ions is changed from 0.1M to 0.01M and that of Ag
+
ions is changed from 0.5M to 0.25M ?
20. Starting with an initial pressure of 5 atm of azoisopropane, 40% of it decomposes into nitrogen and
hexane vapours in one hour. The pressure in atm exerted by the mixture in atm at this time will be
21. How many millilitres of 0.5M
4
KMnO are needed to react with 3.04 gms of iron (II) sulfate,
4
FeSO ?
22. When| | | |
4
K AgF
+
is reacted with
3
BF a red solid is formed. This red solid on reaction with Xe
forms a brown solid and a fluoride of Xenon. In this fluoride Xe oxidation state is
23. Aluminium chloride in acidified aqueous solution forms a coordination complex with coordination
number of

24. In the following H at C x is involved in crossed aldol reaction

x is
25. The coordination number of Al in the crystalline state of
3
AlCl is
26.
3
CH COOH by Schmidt reaction forms primary amine. 1.55 g of such amine required . g of
3
CH COOH .
27.
4 11
C H N on reaction with
2
HNO forms 3 alcohol. Thus amine is x x is .

28.

Y = how many products including stereoisomer
O
1
O
5
4
3
2 6
10
9
8
7
CH
3
CH
3
OH
H
+
-H
2
O
X
Br
2
CCl
4
Y
IIT Section

IIT GT 06
08
th
May 2014
I20140508


Mathematics
Section I

29. If e

is a complex number such that 1 e = , then the complex number
1
z e
e
= + describes a conic.
The distance between the foci of the conic, represented by z , is
(a) 2 (b) 3 (c) 4 (d) 2( 2 1)
30. If 1 m= , then the range of m

such that the two real roots of ( )
2
1 3 4 0 m x mx m + + =

are greater
then 1 is equal to
(a) | |
16
, 2,
7
(

(

(b) ( )
16
, 2,
7
| |

|
\ .

(c) | |
16
, 2,
7
(

(

(d) ( )
16
, 2,
7
| |

|
\ .

31. If
12
log 18 o = and
24
log 54 | = , then ( ) 5 o| o | + is
(a) 0 (b) 1 (c) 2 (d) 3
32. For how many values of k , the following system of equations will have infinite solutions?
2
2 1
3 4
5 10
x y z
x y z k
x y z k
+ + =
+ + =
+ + =

(a) 3 values

(b) 2 values (c) no values (d) one value
33. The line

6 x y + = is normal to the parabola
2
8 y x =

at the point
(a)

(18, 12)

(b)

(4, 2)

(c)

(2, 4)

(d)

(3, 3)

34.
The value of
3
3 2
7 2
( 7)
x
dx
x x
+ +
}
is (for some constant C )

(a) 3
7
7
x
C
x x
+
+ +

(b)
3
7
x
C
x x
+
+ +

(c)
3
4
7
x
C
x x
+
+ +

(d)
3
3
7
x
C
x x
+
+ +

IIT Section

IIT GT 06
08
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May 2014
I20140508


35. The solution of the differential equation cos
( )
dx
xy
x xdy ydx
=
+

is
(a) sin log xy x C = +

(b)

cos log xy x C = +

(c) log( ) cos xy x C = +

(d) sin log xy x C = +

36. If the equations 1 ax by + = and
2 2
1 cx dy + = have only one solution, then

(a)

2 2
1
a b
c d
+ =

(b)
a
x
c
=

(c)
b
y
d
=

(d)

1 xy =

Section II
37. If the third term in

( )
10
5
log x
x x + is

6
10
,
then

x is

(a) 10

(b)

3 2
10

(c)

5/ 2
10

(d)
7/ 2
10

38. , A B are two independent events. The probability that both occur simultaneously is

1
6

and the

probability that neither occurs is
1
3
. Then

(a)

1
( )
3
P A =

(b)
1
( )
3
P B =

(c)
1
( )
2
P A =

(d)
1
( )
2
P B =

39. Consider the expression ( ) ( )
4 5
7 2 E x x = + , where ( ) 2, 7 xe . Which of the following is true about
E ?

(a) it attains its maximum at 1 x =

(b) it attains maximum at

3 x =

(c) the maximum value of E is

4 5
6 3

(d) the minimum value of E is

5 4
4 5

40. The circles

2 2
2 8 23 0 x y x y + + + = and
2 2
4 10 19 0 x y x y + + =
(a) touch externally (b) touch internally

(c) have only one common tangent (d) have direct common tangents

IIT Section

IIT GT 06
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I20140508


41. The sides of a ABC A satisfy the equation
2 2 2
2 4 4 2 a b c ab ac + + = + . Then
(a) the triangle is isosceles (b) the triangle is obtuse
(c)
1
7
cos
8
B

= (d)
1
1
cos
4
A

=

Section III
Comprehension I
Consider the determinant
1 2 3
1 2 3
1 2 3
a a a
b b b
c c c
A =
ij
M = minor of the ( ) ,
th
i j element
ij
C = cofactor of the ( ) ,
th
i j element

42. The value of
1 31 2 32 3 33
b C b C b C + + is
(a) 0 (b) A (c) 2A (d)
2
A

43. If all the elements of the determinant are multiplied by 2 , then the value of the new determinant is
(a) 0 (b) 8A (c) 2A (d)
9
2 A

44. The value of
3 13 3 23 3 33
a M b M c M + is
(a) 0 (b) 4A (c) 2A (d) A

IIT Section

IIT GT 06
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I20140508


Comprehension II
A triangle ABC is given where (1, 1) A = and orthocentre is (2, 4) . AB and BC are members of family
of lines 0 ax by c + + = , where , , a b c are in A.P.
45. The coordinates of vertex B are
(a) (2, 1) (b) (1, 2) (c) ( 1, 2) (d) (1, 2)

46. The triangle ABC is
(a) obtuse-angled (b) right-angled
(c) acute-angled (d) equilateral

Section IV
47. Given that

, o are roots of

2
4 1 0 Ax x + = and

, | o are the roots of
2
6 1 0 Bx x + = . If , , , o | o
are in H.P., then B is equal to
48. If

( )
2 2
2 2
1
1
x y
k
k
+ =
+

is an ellipse ( k is an integer) with eccentricity

5
3
,

then k is

49. The foci of the ellipse

2 2
2
1
16
x y
b
+ = and the hyperbola
2 2
1
144 81 25
x y
= coincide . The value of
2
b is
50. The two adjacent sides of a cyclic quadrilateral are 2 and 5 and the angle between them is 60 . If
the area of the quadrilateral is 4 3 , then the product of the other two sides is
51. ABC is a triangle with ( ) ( ) ( ) 2 , 3 , 5 , 1 , 3 , 2 , , 5 , A B C = = = . If the median AD is equally

inclined to the axes, then

is
52. If the distance between the line

( )

(2 2 3 ) 4 r i j k i j k = + + +

and the plane

( 5 ) 5 r i j k + + = is k ,
then
3 3
2
k

is
IIT Section

IIT GT 06
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I20140508


53. The median AD of the triangle ABC is bisected at . E BE meets AC in F and
AF a
AC b
= . Then a b +
is
54. Let : f R R be a function satisfying the property ( ) ( ) 2 3 2 7 2, f x f x x + + + = eR.

The period of
( ) f x

is
55. Let A and B be events of an experiment and ( ) ( )
1 1
,
4 2
P A P A B = = . Then the value of ( )
c
P B A
is k . The value of
1
k
is
56. The minimum value of
2
( ) 1 2sin 3cos f x x x = + + , where
2
0,
3
x
t (
e
(

, is

IIT Section

IIT GT 06
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I20140508


Physics
Section I

57. A point A moves uniformly with a velocity v in such a way
that the direction of its velocity continually points at
another point B, which in turn, moves along a straight line
with a uniform velocity ( ) u u v < . At the initial moment u
and v are at right angles and the points are separated by a
distance l . How soon will the points meet?
(a)
2 2
lv
v u

(b)

2
2 2
l v
v u

(c)
2 2
lv
v u +
(d)
2
2 2
lv
v u

58. A small ball of mass m is connected by an inextensible massless
string of length l with an

another ball of mass M = 4m. They are
released with zero tension in the string from a height h as shown in
the figure. Find the time when the string becomes taut for the first
time after the mass M collides with the ground. Take all the
collisions be elastic.
(a)
3
l
gh
(b)
2
l
gh

(c)
3
2
l
gh
(d)
2 2
l
gh

m
M
h

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IIT GT 06
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May 2014
I20140508


59. A thin massless thread is wound on a reel of mass 3m and
moment of inertia
2
2mR . The hub radius is R and the
peripheral radius is 2R . The reel is placed on a rough table
and the friction is enough to prevent the slipping. The
acceleration of the centre of reel and of hanging mass m
respectively are :
(a)
1 1
,
15 15
g g (b)
2 2
,
15 15
g g
(c)
1 2
,
15 15
g g (d)
2 1
,
15 15
g g
60. Two small spheres having same mass and charge are located at same vertical line at heights
1
h

and
2 2 1
( ) h h h > . They both are thrown simultaneously with the same velocity V in the same direction
along the horizontal. From the initial vertical line, the first sphere hits the ground at a distance l .
Then at this instance height of the second ball, H is
(a)
2
1 2
l
h h g
V
| |
+ +
|
\ .
(b)
2
1 2
l
h h g
V
| |
+
|
\ .
(c)
2
1 2
1
2
l
h h g
V
(
| |
+
(
|
\ .
(

(d)
2
1 2
1
2
l
h h g
V
(
| |
+ +
(
|
\ .
(

61. A rectangular loop with a sliding conductor of length l
is located in a uniform magnetic field perpendicular to
the plane of the loop. The magnetic induction is B. The
connectors resistance is R. The sides AB and CD have
resistances
1
R and
2
R . Find the current flowing through
the conductor during its motion to right with a constant
velocity v
(a)
1 2
1 2 1 2
( )
( )
Blv R R
R R R R R
+
+ +
(b)
Blv
R

(c)
1 2
1 2
BlvR R
R R +
(d)
1 2
Blv
R R R + +

R
2R
3m
m

1
R
2
R
R
V
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IIT GT 06
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May 2014
I20140508


62. A concavo convex lens has an index of refraction 1.5 and the
radii of curvature of its surface are 10cm and 20 cm. The concave
surface is upward and it is filled with an oil of refractive index
1.60. The focal length of the oil-glass combination is
(a) 3/100 cm (b) 1/40 cm
(c) 18.18 cm (d) 1.818 cm

63. In the circuit shown X

is joined to Y for a long time
and then X

is jointed to Z . The total heat produced
in
2
R is
(a)
2
2
1
2
LE
R
(b)
2
2
2
2
LE
R

(c)
2
1 2
2
LE
R R
(d)
2
2
3
1
2
LE R
R

64. A proton strikes another proton at rest. Assume impact parameter to be zero, i.e., head on collision.
How close will the incident proton go to other proton?
(a)
3
2
0 0
e
m v t e

(b)
3
0 0
e
mv t e
(c)
2
2
0 0
e
mv t e
(d)
2
2
0 0
2
e
mv t e

Liquid
Glass

2
R
L
E
Z
1
R
X
Y
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IIT GT 06
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May 2014
I20140508


Section II
65. Hydrogen atoms absorb radiation of wavelength
0
and consequently emit radiations of 6 different
wavelengths are shorter than
0
. Then,
(a) The final excited state of the atoms is 4 n =
(b) The initial state of the atoms may be 2 n =
(c) The initial state of the atoms may be 3 n =
(d) There are three transitions belonging to Lyman series

66. At some instant, a disk of radius 1.0 m is performing rolling (which is not pure) on a rough
horizontal surface. The velocity of point C

in the shown direction
is 5m/sec?
(a) Instantaneous centre is at a distance 1.0 m below centre O
(b) Instantaneous centre is at a distance 0.50 m below centre O
(c) Angular velocity of disc is 5 2 ( / ) rad/sec
(d) Velocity of centre of mass is 5 2 ( / ) rad/sec

67. A process is defined by
2
= V aT where a is a constant and for which temperature of 1 mole of a gas
is increased by 100K .
(a) The work done is given by
2
1
}
V
V
PdV in which P must be a constant
(b) The work done by the gas in the process is 250R
(c) The work done by the gas in the process is 200R
(d) The work done is given by
2
1
}
V
V
PdV in which either P is constant or is a function of volume

5 / m s
C
O
45
o
IIT Section

IIT GT 06
08
th
May 2014
I20140508


68. For spherical symmetrical charge distribution, variation of electric
potential with distance from centre is given in diagram. Given that
0 0
4tc = /( ) V q R for
0
s r R and
0
4tc = /( ) V q r for
0
r R > . Find
correct options(s) :
(a) Total charge within
0
2R is q
(b) Total electrostatic energy for
0
s r R is zero
(c) At
0
= r R , electric field is discontinuous
(d) There will be no charge anywhere except at
0
= r R

69. An external magnetic field is decreased to zero, due to which a current is induced in a circular wire
loop of radius r and resistance R placed in the field. This current will not become zero at the
instant when B stops changing.
(a) At the instant when external magnetic field stops changing 0 = ( ) t , the current in the loop is
0
i . The current in the loop as a function of time for 0 > t is given by
0
2
0
t / Rt r
i e
(b) For the same as in option (a), the current in the loop as a function of time 0 > t is given by
0
2
iR
r

(c) The time in which current in loop decreases to
3
0
10
i (from 0 = t ) for 100 = O R and 5 = r cm

is given by
2
10
3 10
10
t ln
second
(d) For the same as in option (c), the time in which current in loop decreases to
3
0
10
i (from
0 = t ) for 100 = O R and 5 = r cm is given by
2
6
3
10
t
second

r

V
0

IIT Section

IIT GT 06
08
th
May 2014
I20140508


Section III
Comprehension I

1
S

and
2
S are two slits in horizontal fixed plane on which
light of wavelength 6000A
o
is incident. 1 d = mm. 1.0 D = m.
O is the origin of the coordinate system. At 0 t = , the scree
is released
2
( 10 / ) g m s = .

70. Find the velocity of central maxima at 4 t = sec:
(a) 40 (m/s) (b) 80 (m/s) (c) 40 2 (m/s) (d) 80 2 (m/s)

71. The velocity of second maxima w.r.t. central maxima at 3 t = sec is :
(a)
2i (cm/s) (b) 3 6
. i (cm/s) (c) 4 2
. i (cm/s) (d) 4 5
. i (cm/s)

72. Find the acceleration of third maxima relative to third maxima on other side of central maxima at
4 t = sec. (in
2
/ m s )
(a) 0 02
. i (b)
0.036i (c) 0 042
. i (d) 0 045
. i

Comprehension II
A Gaseous mixture enclosed in a vessel of volume V consists of one gram mole of gas A with ( 5/ 3) =
and another gas B with 7 / 5 = at a certain temperature T . The gram molecular weights of the gases
A and B are 4 and 32 respectively. The gases A and B do not react with each other and are assumed to
be ideal. The gaseous mixture follows the equation
19/13
PV =constant, in adiabatic process.
y
O
' = D
2
1/ 2 + D gt
1
S
2
S
d
6000A =
o
u
o
M
= v gt
M
x
IIT Section

IIT GT 06
08
th
May 2014
I20140508


73. If T is raised by 1K from 300K , find the percentage change in the speed of sound in the gaseous
mixture :
(a) 0.167 (b) 0.230 (c) 0.178 (d) 0.267
74. Compute the speed of sound in the gaseous mixture at 300K (in m/sec);
(a) 330 (b) 320 (c) 360 (d) 401

Section IV


75. In quick succession, a large number of ball are thrown up vertically in such a way that next ball is
thrown up when the previous ball is at the maximum height. If the maximum height is 5 m, then
find the number of balls thrown up per second
2
( 10 / sec ) g m = .

76. The springs are unstretched when system is
released from rest. The spring constant is 10 N/m
for each of the spring. The mass of each block is 3
kg. The square of the maximum speed of block A
(in
2
/ m s
2
) ( 10 / ) g m s
2
= is 2.4I , where I is the
integer. Find I .

77. Block A and B each of mass 1 kg are moving with 4m/sec
and 2m/sec respectively as shown. The coefficient of
friction of all surfaces is 0.10. Find the distance by which
centre of mass will travel before coming to rest (in m).

A
B

A
B
4 / m s 2 / m s
0.10 =
IIT Section

IIT GT 06
08
th
May 2014
I20140508


A B
C
D
3O
2O
6V
10V
2V
E
78. Two wheels, each marked with a dot on its rim, are mounted side by side, when the wheels are at
rest, the dots are aligned, One wheel is given a constant angular acceleration of
2
( / 2) / sec rad t and
the other wheel is given a constant angular acceleration of
2
( / 4) / sec rad t . Find the time after
which the two dots will become aligned again for the first time (in seconds).

79. A vessel of volume 3V contains a gas at pressure
0
4P and another vessel of volume 2V contains the
same gas at pressure
0
1.5P . Both vessels has same temperature. When both vessels are connected
by a tube of negligible volume, the equilibrium pressure is
0
IP , where I is an integer. Find the
value of I .

80. The magnification of an object placed in front of a convex lens is +2. The focal length of the lens is
2.0 metres. Find the distance (in meters) by which object has to be moved to obtain a magnification
of 2 .

81. A potential difference is applied to the plate of a capacitor filled with an insulator, with energy
stored in the capacitor as U . The capacitor is disconnected and the insulator is pulled out now. The
work done in pulling out the insulator against electric field is 4U . Find the dielectric constant of the
insulator.

82. In the circuit as shown, find the current through 3O resistor (in A):

IIT Section

IIT GT 06
08
th
May 2014
I20140508


83. In the circuit as shown, charge q varies with time t as
2
( 4) q t = , where q is in coulomb and time t is in
second. Find
AB
V at time 3 t = sec (in V ).

84.
238
92
U changes to
210
85
At by a series of o and | decays. Find number of o -decays undergone (an
integer).

+
q
A B
1O
5F
0.5H

JEE-Adv Grand Test Question Paper (P 1) - 08-05-2014

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i (from 0 = t ) for 100 = O R and 5 = r cm

0.036i (c) 0 042

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