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IIT Section

Subject Topic Grand Test Paper II Date


C + M + P Grand Test 09
IIT GT 09
14
th
May 2014
I20140508

1

Key Answers:
1. d 2. b 3. c 4. c 5. c 6. b 7. 2 8. 5 9. 2 10. 3
11. 3 12. a 13. a 14. b 15. b 16. b 17. a 18. 19. 20. b
21. d 22. c 23. a 24. c 25. a 26. 2 27. 1 28. 1 29. 1 30. 1
31. c 32. a 33. b 34. a 35. b 36. c 37. 38. 39. d 40. a
41. a 42. c 43. c 44. c 45. 3 46. 2 47. 4 48. 4 49. 9 50. c
51. a 52. d 53. a 54. c 55. a 56. 57.

18. A r, B s, C p, D q; 19. A q, B s, C p, D r;
37. A

p, q; B

s; C p,r, D r; 38. A r; B q, C p, D s;
56. A r, B qr, C ps, D qr; 57. A pq, B pqs, C pqr, D pqr;


Solutions:
Chemistry
1. (a) Mixture of 100 ml of / 10 M HCl and 100 ml of
10
M
NaOH is an exact neutralisation.
Hence 7 pH =
(b) After neutralisation , left 10
10
M
HCl ml =
Total volume=100 , Dilution 10times ml = | | H
+
=
2
10 2 or pH

=
(c) After neutralisation, left 10times
10
M
NaOH =
Total volume 100 = ml, 7 PH >
(d) After neutralisation, left 50
5
M
HCl ml =
total volume 100 = ml, dilution 2 = times
1
1
10 or 1
10
H pH
+
(
= = =


2. Ans: (b )
3. Selective reduction of one nitro group of a dinitro compound can often be achieved by the use of
hydrogen sulphide in aqueous or alcoholic ammonia. The reduction is favour at ortho position
with respect to OH group and para position with respect to
3
CH group. (more electrons
deficient site is more readily reducible)
4. Taking a ratio of ( )
0
/ dP NO dt (

both experiments gives
IIT Section

Subject Topic Grand Test Paper II Date
C + M + P Grand Test 09
IIT GT 09
14
th
May 2014
I20140508

2

( )
( )
( )
( )
0.2 2
1
0.1
/
/
x
dP NO dt P NO
P NO dP NO dt
( | |

= |
|
(
\ .

Taking logarithms, solving for x , and substituting the data gives
( ) ( )
( ) ( )
1 1
log 200 / 137
2.10 2
log 0.479 / 0.400
Pa s Pa s
bar bar

(
(

= = ~
(


5.
40
100
100
P
P V =
or 250 V cc = =Total volume of gas mixture
volume of bulb 250 100 150 B cc = =
6. Same magnetic moment=same number of unpaired electrons ( ) 2 n n = +
Where n = number of unpaired electrons
2 7
3 , 3 Co d
+
=

unpaired electrons
2 4
3 , 4 Cr d
+
=

unpaired electrons
2 5
3 , 5 Mn d
+
=

unpaired electrons
2 6
3 , 4 Fe d
+
=

unpaired electrons
7.







8. Balanced chemical equation is
2 2 2 2 2
2 5 2 2 5 6 ClO H O OH Cl O H O

+ + + +

2 mol of
2 2 2
5 of ClO mol H O =
9. Heat of neutralisation for strong acid with strong base 13.7 = kcal /mol
3
( )
12.5 ( 13.7) 1.2 /
CH COOH
H kcal mol A = = +
3 4
13.7 . . 10.5
CH COOH NH OH
I E I E =
4
. 13.7 1.2 10.5 2
NH OH
I E = =
10. ' " X is prepared by the action of
2
HNO on organic fertilizer
i.e.,
2 2 2 2 2 2
2 2 3 H NCONH HNO N CO H O + + +
CH
3
CH
2
C CH
CH
3
CH
3
O
(A) -ve Tol lens Test
CH
3
CH
2
CH CHCH
3
OH CH
3
(B)
C H
3
CH
2
CH C CH
3
CH
3
5
4
3
2
1
(C)
CH
3
CH
2
CHO +
CH
3
COCH
3
+ve Tol lens test
-ve Iodoform
-ve Toll ens test
+ve Iodoform
-H
2
O
IIT Section

Subject Topic Grand Test Paper II Date
C + M + P Grand Test 09
IIT GT 09
14
th
May 2014
I20140508

3

Bond order calculation of
2
N
Bond order
10 4
3
2

= =
11. Since pyrolusite
2
MnO is taken we know that ( ) A will be potassium manganate, a green coloured
compound. The purple coloured compound B will be potassium permanganate. Potassium
permanganate is a good oxidising reagent both, in alkaline and acidic medium, getting
decolourised with KOH

| |
2 2 4 2
2 MnO KOH O K MnO H O
A
+ + +
(pyrolusite) ( ) A (dark green)
with dilute
2 4
H SO
2 4
2 4 2 4 2
3 2 2 4
dil H SO
K MnO H O KMnO MnO KOH + + +
with KI (alkaline) ( ) B
4 2 3 2
2 2 2 KMnO KI H O KIO MnO KOH + + + +
( ) C
Oxidation state of Mn in compound ( ) C is 4 +
So, EC
2 2 6 2 6 3
1 2 2 3 3 3 s s p s p d
So number of unpaired electrons is 3
12. ( ) ( )
3
2
3 2 3 3 2 3
2 2
.
O
Zn H O
CH CH CH C CH CH CH CHO CH CO = +
13.
3
2
2 2 3 3 3 2 3 2 3 3
.
( ) ( ) ( )
O
Zn H O
CH C CH CH CH CH CH CH O CH CH COCH CH CH = +
14.
3
2
3 3 3
2
O
H O
CH C C CH CH COOH
15. Heat liberated ( ) 17.7 0.5 / 0.01 8.85 / kJ mol kJ mol = =
heat liberated for 1 mol of
4
8.85
16 885
0.16
CH kJ = =
or
1
combustion
885 E kJ mol

A =
16.
885
55.3
16
kJ =

17.
4( ) 2( ) 2( ) 2 ( )
2 2
g g g l
CH O CO H O + +
g
H E n RT A = A +A
IIT Section

Subject Topic Grand Test Paper II Date
C + M + P Grand Test 09
IIT GT 09
14
th
May 2014
I20140508

4

3
885 ( 2 8.31 10 300) H

A = +

1
889.986 kJ mol

=
18. Butter of tin is
4 2
5 SnCl H O
Dry Ice is solid
2
CO
Sugar Lead is ( )
3
2
Pb CH COO
White lead is ( )
3
2
2PbCO Pb OH
19. Conceptual

IIT Section

Subject Topic Grand Test Paper II Date
C + M + P Grand Test 09
IIT GT 09
14
th
May 2014
I20140508

5

Mathematics
20. ( )
( )
2
2 f x x x ax b = + +
2
0, 2 0 x x ax b = + + = has distinct real roots
0 A >
2 2
8 0 8 a b a b > >
min of 1 b =
min of 3 a =
( ) min 4 a b + =
21. Number of subsets containing
21
10
1 C =
Number of subsets containing
21
10
2 C =
Sum of elements
21 21 21
10 10 10
1 2....... 22 C C C = + +
| | ( )
21 21
10 10
1 2 ..... 3 253 C C = + + + =
22. ( ) ( ) 1, 1 f x g x s >
( ) 1, 2, 3...... g x = (


( ) ( ) ( ) ( )
1
1
1, 1 1 tan 1
2
f x g x f x g x x

(
= = = + = ( (
(


1 1 1
1 1 1
1 tan 1 tan 0 0 tan 1
2 2 2
x x x

( (
+ = = s <
( (


1
0 tan 2 0, tan2 x x

s < <
tan2 tan2 x s < and | | , 0, 2
2
x x
t
t = e
No of real sol of x in | | 10 , 2 15 t t =
23. ( ) ( )
2
1 2 1 2 z i i
e
+ = + =
( ) 2 1 2 i e e + =
2
1 2
1
i
i
e e = + =
+
( ) 2 1 2 1 0 i i e e e e = =
Locus of e is from bisector of ( ) ( ) 1, 1 , 0, 0 i.e., 1 0 x y =
24. ( ) ( ) ( ) , f x y g x h y = +
( ) ( )
2 2
4 , 6 g x x x h y y y = = +
( ) ( )
1
2 4 0 2 2 g x x x = = = ( ) ( )
1
2 6 2 3 h y y y = + = +
IIT Section

Subject Topic Grand Test Paper II Date
C + M + P Grand Test 09
IIT GT 09
14
th
May 2014
I20140508

6


( ) ( ) in 0,1 g x + ( ) ( ) in 0,1 h y +
( ) ( ) min of 1 g x g = ( ) ( ) min of h 0 y h =
( ) ( ) ( ) min , 1 0 3 0 3 f x y g h = + = + =
25.
6 6
1 1
1 1
sin cos 6 6
2
i i
i i
x y
t
t

= =
| |
+ = +
|
\ .


1 1
sin , cos , 1......6
2
i i
x y i
t
t

= = =
1, 1
i i
x y = =
( )
6
2
2
6
log 1
1
x
x
e
I x x dx C
e

| |
= + = |
|
+
\ .
}

( )
2
2
log 1 log is odd
1
x
x
e
x x
e
( | |
+ ( |
|
+ (
\ .

26.
4 4
sin cos 2 4sin cos 0 x y x y + + =
( ) ( )
2 2
2 2 2 2
sin 1 cos 1 2sin 2cos 4sin cos 0 x y x y x y + + + =
( ) ( )
2 2
2 2 2 2
sin 1 cos 1 2 sin cos 2sin cos 0 x y x y x y
(
+ + + =


( ) ( )
( )
2 2
2 2 2
sin 1 cos 1 2 sin cos 0 x y x y + + =
It is true if
2 2
sin 1, cos 1 & sin cos sin cos 1 x y x y x y = = = = =
sin cos 2 x y + =

27. cot x y = is
( )
2
2 2
2
cos sin
cot cos sin
sin
y y
y y y
y

(
+
= + = (
(

2 2
1 51
1 cot 1 1
50 50
y x = + = + = + =
50
1
51
=>
28. Let ( ) 0, 0 p =
1
386 2 386 SS ae = = =
1
2 S p Sp a = =
25 13 2a =
2 12 a =
IIT Section

Subject Topic Grand Test Paper II Date
C + M + P Grand Test 09
IIT GT 09
14
th
May 2014
I20140508

7

386
12
e = =
12
1
386
=
29. ( ) ( ) ( ) ( )
2
2
1 cos
1
sin
2 2
t b b
a a t
I x f x x dx f x dx f a b c d
+
(
( = = + (

(

} } }

( ) ( )
2 2
2 2
1 cos 1 cos
2 1
sin sin
2 2 2 2
t t
t t
f x x dx xf x x dx I I
+ +
= = ( (
} }

1
1 2
2
2 2 1
I
I I
I
= =
30.
( )
( )
500
500 2000 4
2 2 17 1 = = ( ) ( )
499 500 500 500
1 499
17 17 ....... 7 1 17 1 C C m = + + = +
Remainder = 1
31. ( )
1 3
1, 1, 0 , 0, ,
2 2
A B
| |
= =
|
\ .

A lies on
3
t 4 =
32. Projection of AB on x axis is
( )
1 3
1 0 1 0 1 0 0 1
2 2
| | | |
+ + + =
| |
\ . \ .

33. C is foot of on O AB
Equation of AB is
1 1
2 1 3
x y z +
= =


C can be taken as ( ) 2 1, 1, 3 C = +
( ) ( ) ( ) 2 2 1 1 1 3 3 0 OC AB + = ( )
3 4 11 9
, , , ,
14 7 14 14
C p q r
| |
= = =
|
\ .

7 14 14 2 p q r + + =
34. Let , x a y b = = be the asymptotes perpendicular tangents are intersecting at (2,2) 2, 2 x y = =
Equation of hyperbola is ( )( ) 2 2 0 x y k + =
( ) 0, 0 reason it 4 k =
Equation of hyperbola is ( )( ) 2 2 4 0 x y =
Equation of conjugate hyperbola is ( )( ) 2 2 4 x y =

35. Equation of tangent at (4,4) is
8 x y + =
IIT Section

Subject Topic Grand Test Paper II Date
C + M + P Grand Test 09
IIT GT 09
14
th
May 2014
I20140508

8

( ) 2 6 2, 6 x y A = = =
( ) 2 6 6, 2 y x A = = =
4 2 AB =
36. Equation of chord is
1 11
4 0 S S x y = = (1)
is tangent to conjugate hyperbola ( ) 2, 2 satisfies both (1) and conjugate hyperbola ( ) 2, 2 is
point of contact.
37. (a) Number of matrices ( ) 4! 24 N = =
a b
A
c d
(
=
(


Possible non negative value be 0,2,4,8 , , A p q s
(b) de value 8 are 4
de value 8 are 4
de value 4 are 4
de value 4 are 4
de value 2 are 4
de value 2 are 4
sum of value of all dets = 0 B s
(c) ( ) ( )
( )
3
1
2
n
ads ads adjA A A

= = =
the absolute value of is least , A C p r (


(d) Algebraically least of 8 A =
1
1 16
16 16 2
8
A
A

= = =

D r
38.
2
2 2 t x x = + +
and ( )
3 2 2
and 2 2 1 f t x at bt c t x x = + + + + + >
( ) 0 f x = has roots less than or equal to 0
( )
1
f x has two negative roots
2
3 2 0 x ax b + + = has two negative roots
2
0, 0, 0 3 a b a b > > A > >
Possible values of , , a b c be 3, 2, 0 a b c = = =
( )
1 2
3 6 12 0 f x k x x k = + + = has equal roots
0 A =
IIT Section

Subject Topic Grand Test Paper II Date
C + M + P Grand Test 09
IIT GT 09
14
th
May 2014
I20140508

9

( )( ) ( ) 36 4 3 2 0 3 2 0 k k = =
1 k =
(a) - r (b) - q (c) - p (d) - s


IIT Section

Subject Topic Grand Test Paper II Date
C + M + P Grand Test 09
IIT GT 09
14
th
May 2014
I20140508

10

Physics
39.
2
A
R
X V t i
t
= =
B
X Ri Rj = +

2
BA
X R R i Rj
t
| |
= +
|
\ .

A
V Vi =

B
V Vi =

0
BA
V i =

40. The temperature of land rises rapidly as compared to sea because of specific heat of land is 5
times less than that of sea water. Thus the air above the land becomes hot & light so rises up so
pressure drops over land. To compensate the drop of pressure, the cooler air from sea starts
blowing towards lands, setting up sea breeze. During night land as well sea radiate heat energy.
The temperature of land falls more rapidly as compared to sea water, as sea water consists of
higher specific heat capacity. The air above sea water being warm and light rises up & to take its
place the cold air from land starts blowing towards sea and set up breeze.
41. ( ) ( ) 1 sin90 .sin 90 y u =
( ) 1 .cos y u =
( )
( ) ( )
2 2
1 .
dx
y
dy dx
=
+

( ) ( )
2
1
y
m y = +
42. After two and half time periods, it is at a distance 2R0 on the negative z-axis. Y-coordinate will be
zero And the x-coordinate =2.5p0 .i.e. it is at a distance 7.5P0 from the mirror, hence its image will
be at 2(7.5P0)+2.5P0=17.5P0.
43.


( )
2 2
2 2
0
1
.
4
x
q R
dE
R x
R x
tc
=
+
+

IIT Section

Subject Topic Grand Test Paper II Date
C + M + P Grand Test 09
IIT GT 09
14
th
May 2014
I20140508

11


( )
3/2
2 2
0
1
. 2
4
qR
d x dx
R x
| t
tc
=
+


2 2 2
R x t + =
2 . 2 . x dx t dt =

3
0
0
2
.
4
x R
x
qR t dt
d
t
t
|
tc
=
=
=
} }



0
1 1
2 .2
4 2
curved
qR
R R
t
|
tc
(
=
(



0
1
1
2
curved
q
|
c
| |
=
|
\ .


0 0
1
1
2
flat
q q
|
c c
| |
=
|
\ .


0
2
flat
q
|
c
=
44. Conservation of angular momentum
( )
1 2 2 c c
I w m r h v I w mrv + = +

( )
2 2
2
2
r h v
w
r

=
Conservation of energy

( )
2 2
2
1
2
c
I mr w mgh + >
45. From the diagram the forces along the line
perpendicular to the inclined plane are
balanced.
3
cos37 sin37
4
N mg ma mg = =
-2
5
ms
6
a =

46. Let the piston be displaced by x

2
0
0
2
q
PA P A
A
= +
c

( )
2 2
2
0
2 0
0
1
2
A
PA P A
A
L x
=

+
c
c
c




a

37


cos37 mg
sin37 ma
cos37 ma
mg
sin37 mg
IIT Section

Subject Topic Grand Test Paper II Date
C + M + P Grand Test 09
IIT GT 09
14
th
May 2014
I20140508

12

( )
2 2 2
0 0 0
2 2 2 0 0 0
2
2
n
P P P P
L L L x
= =

=
c c c c c c
, 2 n =
47. Let e be the heat generated per unit volume per sec.

3 2
4
4
3
dT
r k r
dr
e t t
| |
=
|
\ .


3
dT r
dr k
e
=

2
6
wr
T C
k
= +
At
0
, 20 r R T C = =

2
0
20 40
6
C
R
T C
k
e
= + =
48. Solving for each reflection we get distance from the pole of the lens.

( ) ( )
42
4 .
2 1 2 4 1.25 1.25 1
R
cm
n
= = =
+ +

49. Wavelength of the incident sound is
10
19
2
2
i
u
u
u
f f


= =
Frequency of the incident sound is
10 18
19
10
2
i r
u u
f f f f
u

= = =


where when
r
f is the frequency of the reflected sound.
Wavelength of the reflected sound is
10 11 11 19
19
18 18
r
r
u u u u
f f f

+
= = =
19 18 9
2 11 19 11
i
r
u f
f u

= =



50.

1 2 3
2
3
e
E E E
E
+ +
= =
6
13
e
e
E
i
R r
= =
+


51. Current through 2V cell
6 13 6
3 3 39
i
A = = =
IIT Section

Subject Topic Grand Test Paper II Date
C + M + P Grand Test 09
IIT GT 09
14
th
May 2014
I20140508

13

52.
1 2 3
2
3 3
e
E E E
E
+ +
= =
2 3 2 3 2
4 1 3 13 3 13
e
e
E
i A
R r
= = = =
+ +


53.
2 2 2 2
1 2 3
, , ,
/ 4 / 16
v v v v
a a a a
r r r r
= = = =
2
1 2 3
, ,
4 16
r r
t t t
v v v
t t t
= = =
54.
2
2
c c
v
a v a r
r
= =
1 2 1
1 2 3
, ,
4 2 16 2 4
c c c
r v r v v
v a r v a v a = = = = = =
1 2
1 2 3
1
2
2, , ...........
2 2 4
c c
r r t t
t t t
v a a r
t t t
= = = = =


55. At a ( )
1
1 2 1
2
v
J m v v m along Z axis = = +
At b ( )
1 1 1
2 3 2
4 2 4
v v mv
J m v v m along Z axis
| |
= = =
|
\ .

( )
1
3 4 3
along
8
mv
J m v v Zaxis = = +
So, total impulses =
1 2 3
........ J J J + + +
56.

Draw the ray diagrams.
57. (A) X is resistor

2 2
1
dv B v
m Fm B
dt R
= = =
/
2 2
t T
mR
v ve T
B

= =
Energy is dissipated as heat is the resistor at the cost of kinetic energy. Total energy is
conserved
(B) X is an inductor
2 2
0
sin
v dv B x B
m x t
dt L mL
e e
e
= = =
Rod will oscillate simple harmonically and KE is converted into magnetic energy
(C) X is capacitor
Q CV CB V = =

2 2 0
0
2 2
ln .
F dv dv
F B C a
dt dt m B C
= =
+
constant
v at =

(D)
0
F mg =

2 2
constant
mg
a
m B C
= =
+