=
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Chemistry
Section I
Multiple Choice Questions with one correct answer. A correct answer carries 3 marks. A wrong
answer carries a penalty of 1 mark 10 x 3 = 30
1.  
2
4
( ) aq
CoCl
is blue in colour while ( )
( )
2
2
6
aq
Co H O
+
(
is pink. The colour of reaction mixture
( )
( )
( )
 
( ) ( )
2
2
2 4 2
6
4 6
aq l aq
aq
Co H O Cl CoCl H O
+
( + +
is blue at room temperature while it is pink
when cooled hence
(a) reaction is exothermic
(b) reaction is endothermic
(c) Equilibrium will shift in forward direction on adding water to reaction mixture
(d) Equilibrium will not shift in backward direction on adding water to equilibrium mixture
2. The solubility products of ( )
3
Al OH and ( )
2
Zn OH are
23
8.5 10
and
14
1.8 10
respectively.
If
4
NH OH is added to a solution containing
3 2
Al and Zn
+ +
ions, then substance precipitated first is
(a) ( )
3
Al OH (b) ( )
2
Zn OH (c) both together (d) none of these
3. An organic compound P on keeping in slightly acidic aqueous solution gives yellow precipitate
with 2,4dintirophenylhydrazine. It also decolourizes
2 4
/ Br CCl solution and gives coloured
solution/precipitate with neutral
3
FeCl solution. The structure of P can be
(a) ( )
3
2
OHC C CH CHO (b)
(c) (d)
(CH
3
)
3
C C H
O
(CH
3
)
3
C C CH
O
CHO
CH
3
O
O
C H
3
CH
3
CH
3
CH
3
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4. In which of the following reaction allyl alcohol will be formed with fastest rate, on reaction with
aqueous NaOH solution?
(a)
(b)
(c)
(d)
5. The percentage of copper in a copper (II) salt can be determined by using a thiosulphate titration.
0.305g of a copper (II) salt was dissolved in water and added to an excess of potassium iodide
solution liberating iodine according to the following equation.
( ) ( )
( )
2
2( )
2 4 2
aq s
Cu aq I aq CuI I
+
+ +
The iodine liberated required 24.5
3
cm of a 0.100 mole
3
dm
15. Which statement is/are correct about the following reaction?
2
h
R H X R X HX
u
+ +
(a) The selectivity of free radical for C H bonds of different types follows the order
Br Cl F
  
> >
(b) The reactivity of halogens towards a given C H bond follows the order
2 2 2 2
I F Br Cl > > >
(c) The reactivity of alkanes follows the order isobutene > propane > ethane > methane
(d) One mole of product is formed by absorption of one photon of light of appropriate wave
length
Section III
Integer answers type questions. Each carries 3 marks. A wrong answer carries a penalty of 1
mark 5 x 3 = 15
16. A compound (P) is formed by heating xenon and fluorine in the molecular ratio of 1:20 under
pressure in a nickel tube. (P) Undergoes stepwise hydrolysis to yield final product (Q). (Q) is also
formed when (P) is stored in glass vessels. The no. of lone pairs around central atom in (Q) is/are
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17. A sample of wustite, ,
x y
Fe O contains one Fe (III) for every three Fe (II). Calculate the value of x.
18. An optically active compound (A),
3 7 2
C H O N
forms a hydrochloride but dissolves in water to give a
neutral solution. On heating with sodalime, (A) yields ( )
2 7
C H N B . Both (A) and (B) react with
2
NaNO and HCl , the former yielding a compound (C)
3 6 3
, C H O which on heating is converted to (D),
6 8 4
C H O while the latter yields (E),
2 6
. C H O The types of carbon to which N is attached to (A) is
19. A weak field octahedral complex of
2
Ni
+
has magnetic moment value of 2.82 B.M. The number of
electrons in the
2g
t level
2
Ni
+
will be
20. The number of carbon atoms in the ring in compound C is
CH
3
CH
3
4 4
. dil KMnO HIO OH
A B C
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Mathematics
Section I
Multiple Choice Questions with one correct answer. A correct answer carries 3 marks. A wrong
answer carries a penalty of 1 mark 10 x 3 = 30
21. Suppose ABCDEFGHI J is a ten digit number, where the digits are distinct. It is given that :
A B C > > and 9 A B C + + = ,
D E F > > are consecutive even digits,
and G H I J > > > are consecutive odd digits.
The value of A is
(a) 8 (b) 7 (c) 6 (d) 5
22. If the ends of a quadrant of a circle have the coordinates ( ) 1, 3 and ( ) 3, 1 then the centre of such a
circle is
(a) ( ) 2, 2 (b) ( ) 3, 3 (c) ( ) 4, 4 (d ) ( ) 2, 6
23. Let , , a b x and y satisfy 4 ax by + = ,
2 2
2 ax by + = and
3 3
3. ax by + = Then the value of
(2 1)(2 1) x y is
(a) 4 (b) 3
(c) 5 (d) cannot be determined
24. Let ( ) f x be a realvalued function satisfying
2
( ) ( ) af x bf x px qx r + = + + , where , a b are distinct
real numbers and , p q and r are nonzero real numbers. Then ( ) 0 f x = will have a real solution, if
(a)
2 2
4
a b r
a b pq
+
 
>

\ .
(b)
2 2
4
a b r
a b pq
 
>

+
\ .
(c)
2
2
4 a b pr
a b
q
 
>

+
\ .
(d)
2
2
4 a b pr
a b
q
+  
>

\ .
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25. An event x can take place in conjunction with any one of the mutually exclusive events , , A B C . If
, , A B C are equally likely and the probability of x is
5
12
and the probability of x taking place
when A has happened is
3
8
while it is
1
4
when B has taken place then the probability of x taking
place in conjunction with C is
(a)
5
24
(b)
3
8
(c)
1
3
(d)
5
8
26. The solution of the differential equation
2 2 2 2
2 tan( ) 2
dy
x y x y xy
dx
= , given (1)
2
y
t
= , is
(a)
2 2 1
sin( )
x
x y e
= (b)
2 2
sin( ) x y x = (c)
2 2
cos( ) 0 x y x + = (d)
2 2
sin( )
x
x y e e =
27. If ( , ) h k is a point on the axis of the parabola
2 2 2
2( 1) 2( 1) ( 2) x y x y + = + + from where three
distinct normals may be drawn, then
(a) 2 h > (b) 4 h < (c) 8 h > (d) 8 h <
28.
3
4 2 1
sin
(cos 3cos 1)[tan (sec cos )]
x
dx
x x x x
=
+ + +
}
(a)
1
tan (sec cos ) x x C
+ + (b)
1
log tan (sec cos ) x x C
+ +
(c)
2
1
(sec cos )
C
x x
+
+
(d) none of these
29. Let ( ) f x be a continuous function on   0, 1 . If ( ) ( )
1 1
0 0
1, 2 f x dx x f x dx = =
} }
and
( )
1
2
0
3 x f x dx =
}
, then the number of roots of the equation ( ) 0 f x = in ( ) 0, 1 is
(a) exactly one (b) atleast one (c) atmost one (d) zero
30. The value of
1 1
2 3
n n
r s
rs
r s
o
= =
, where
0, if
1, if
rs
r s
r s
o
=
=
=
, is
(a)
6
(6 1)
5
n
(b) 6 1
n
(c)
1
(6 1)
5
n
(d) none of these
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Section II
Multiple Choice Questions with one or more correct answer. A correct answer carries 3 marks.
No negative mark 5 x 3 = 15
31. The
th
4 term in the expansion of
10
3
2
8
x
 
+

\ .
has the maximum numerical value. Then the values of
x can be in the interval
(a)
64
, 2
21
(
(
(b)
64
2,
21
(
(
(c)
64
,
21
 

\ .
(d)
64
,
21
 

\ .
32. Three vectors p
( )
0 p = , q and r are such that 3 p q p r = . Also 1 p q = = and
1
3
r = . If the
angle between q and r is 60 , then
(a) 3 q r p = + (b) 3 q r p = (c) 3 2 q r p = + (d) 3 2 q r p =
33. Let , , , a b c d be in A.P. with common difference D . If ( ) 1
t a t b t a c
f t t b t c t
t c t d t b d
+ + +
= + +
+ + +
and
4
0
( ) 32 f t dt =
}
, then D =
(a) 0 (b) 2 (c) 2 (d) 1
34. Given that the complex numbers which satisfy the equation
3 3
350 zz zz + = form a rectangle in the
Argand plane with the length of its diagonal having an integral number of units, then
(a) area of the rectangle is 48 square units
(b) If
1 2 3 4
, , , z z z z are the vertices of the rectangle, then
1 2 3 4
0 z z z z + + + =
(c) the rectangle is symmetrical about the real axis
(d) arg
1 2
( )
4
z z
t
= or
3
4
t
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35. The number of ways of choosing a triplet ( , , ) x y z such that { } max , z x y > and
{ } , , 1, 2, 3, , , 1 x y z n n e + is
(a)
1 2
3 3
n n
C C
+ +
+ (b)
( 1)(2 1)
6
n n n + +
(c)
2 2 2
1 2 n + + + (d)
2 1
3 2
2( )
n n
C C
+ +
Section III
Integer answers type questions. Each carries 3 marks. A wrong answer carries a penalty of 1
mark 5 x 3 = 15
36. Let a function ( ) f x satisfy ( ) ( ) ,
x
f x f x e '' ' = + (0) 0 f = and (0) 1. f ' = Then
5
(5) e f
' =
37. The number of positive integral solutions of the equation
1 2 3 4 5 1 2 3 4 5
x x x x x x x x x x + + + + = is . k
Then
10
k
=
38. If
2 2 2
2 1 x y z xyz + + = , then
2 2 2
3
1 1 1
dx dy dz
x y z
+ + =
39.
3 2
2 2
( 1)
x
dx
x x x x
=
+ + +
}
1
1
tan P x Q C P Q
x
 
+ + + + =

\ .
40. A light ray
1
L emerges from the point ( 5, 6) making an angle
1
tan ( 2)
with x axis. It is
reflected on x axis along the line
2
L and then reflected on y axis along the line
3
: 0. L ax by c + + = If g.c.d of , , a b c is 1, then a b c + =
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Physics
Section I
Multiple Choice Questions with one correct answer. A correct answer carries 3 marks. A wrong
answer carries a penalty of 1 mark 10 x 3 = 30
41. A man watches a steamboat starting from a point directly in front of him on the opposite bank of
river flowing at a speed of 18 km/hr. The boat has a velocity vo with respect to river at an angle
o
u
with the bank. If the steamboat blows a whistle of frequency fo , then for which of the following
combinations of vo and
o
u the frequency registered by the man will be highest?
(a)
0 0
10 / , 30 m s u u = = (b)
0 0
10 / , 30 m s u u = =
(c)
0 0
10 / , 60 m s u u = = (d) same for all the above
42. The ratio of specific heats at constant pressure & volume of a gas is 9 / 7 , then the
number of degrees of freedom of the gas molecules is:
(a) 3 (b) 5 (c) 6 (d) 7
43. A uniform bar of mass M and length L collides with a horizontal
surface. Before collision velocity of C.O.M. of bar was V0 and angular
velocity was zero. Just after Collision, velocity of centre of mass of bar
becomes V in upward direction (as shown in the figure). Angular
velocity of bar just after impact is
(a)
( )
0
6 cos V V
L
u +
(b)
( )
0
6 cos V V
L
u
(c)
( )
0
cos
6
V V
L
u +
(d)
( )
0
cos
6
V V
L
u
44. A particle of charge q and mass m starts moving from the origin under the action of an electric field
0
h h
h h
+
(d)
1 2
1 2
h h
h h +
48. A thin horizontal disc of radius R is located within a
cylindrical cavity filled with oil whose viscosity is ' ' q .
The distance between the disc and horizontal planes
of cavity is ' ' h . The power developed by the viscous
forces acting on the disc when it rotates with angular
velocity e is (The end effects are to be neglected)
(a)
2 4
4 R
h
tqe
(b)
2 4
4
R
h
tqe
(c)
2 4
2
R
h
tqe
(d)
2 4
R
h
tqe
A
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49. A cyclic process ABCA is performed on an ideal gas in which gas
expanded isobarically from A to B , then it is cooled isochorically
from B to C and finally it is compressed isothermally from C to
A . The net heat +20 joule is absorbed in this cyclic process.
Similarly in process BCDB heat absorbed is +5 joule. For a cyclic
process ADCA performed on the same ideal gas,
(a) +15 joule net heat is absorbed (b) +15 joule net heat is rejected
(c) +25 joule net heat is absorbed (d) +25 joule net heat is rejected
50. The sensitivity of a potentiometer can be increased by
(a) decreasing the length of potentiometer wire
(b) increasing the length of potentiometer wire
(c) increasing the emf of the cell in primary circuit
(d) decreasing the external resistance connected in primary circuit
Section II
Multiple Choice Questions with one or more correct answer. A correct answer carries 3 marks.
No negative mark 5 x 3 = 15
51. A balloon having a ladder connecting its top and bottom is floating fully
submerged inside water in a large container. A person of mass m standing
at the bottom most rung of the ladder climbs slowly to the top whose
height is H . Mass of the balloon is M . Neglect friction everywhere. Then,
(a) the work done by the person is mgH
(b) the centre of mass of the balloon and person system does not change
(c) the centre of mass of the ( balloon + person + water ) system does not change
(d) during climbing up the ladder the pressure at the bottom of the container becomes more
than the pressure when the man is not climbing
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52. Electric field E acts horizontally in a region of space. The gravitational field g acts vertically down.
Then
(a) the magnitude of the resultant field
2 2
E g = +
(b) the direction of the resultant field is
1
tan
g
E
u
= with horizontal
(c) the direction of the resultant field is
1
tan
E
g
u
= with horizontal
(d) the resultant field is not defined
53. Two identical capacitors
1
C and
2
C are kept connected to two identical batteries. Two identical
dielectric blocks are inserted in the gaps of the two capacitors. The
dielectric in
1
C is introduced very slowly, while that in
2
C is
introduced very fast. Heat loss in both the circuits due to dielectric
insertion are
1
H and
2
H respectively. The mechanical work done by
the capacitors in pulling the dielectric are
1
W and
2
W respectively,
Then
(a)
1 2 1 2
and W W H H = = (b)
1 2 1 2
and W W H H > <
(c)
1 2 1 2
and W W H H < > (d)
1 2 1 2
and W W H H = <
54.
40
19
K converts to
40
18
Ar by positive  decay as well as electron capture. Let Q values for the  decay
and electron capture be
1
Q and
2
Q respectively in the above reaction.
(a)
1 2
Q Q =
(b)
1 2
Q Q <
(c) Neutrino emitted in positive  decay is monoenergetic
(d) Neutrino emitted in electron capture is monoenergetic
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55. A solid uniform hemisphere is placed vertically ( ) 1 as shown and
released on a rough horizontal surface. It rolls without slipping to
a position ( ) 2 where its flat surface becomes horizontal. At this
position ( ) 2
(a) Friction force on the hemisphere is zero
(b) Normal reaction force Mg >
(c) Friction force 0 > and acts to left
(d) Normal reaction force Mg <
Section III
Integer answers type questions. Each carries 3 marks. A wrong answer carries a penalty of 1
mark 5 x 3 = 15
56. A liquid of density given by ( )
0
1 y o = + is stored in a container, where y is the distance from the
top of the liquid surface.
1
2
.
3
m o
=
0
is the density of the liquid at the top level. A very small hole
is made at the bottom of the container. Find the velocity of efflux (in m/s) when the liquid height is
1m(assume streamline flow)
57. Heat is generated uniformly per unit volume inside a spherical volume of radius 1m at rate of
3
20 / W m . The thermal conductivity of the spherical volume is
1
/
6
W mK . If the outer surface
temperature of the sphere is 20 C . If the temperature of the centre of the sphere is 10 x (in degree
centigrade), find the value of x .
58. In a nuclear reactor an element X decays to a radioactive element Y at a constant rate of
15
10 atoms
per second and releases 100MeV energy per each decay. Halflife of Y equals to X and decays to a
stable product Z . The decay of each nucleus of Y releases 50MeV . All energy released inside the
reactor is used to produce electricity at an efficiency of 25%. Calculate the electrical power in KW
generated in the reactor in steady state.


R
(1)
M
(2)
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59. The radius of curvature of each surface of an equiconvex lens is 42 R cm = . Refractive index of the
glass 1.25 = . If the final image forms after four internal reflections inside the lens (for paraxial
incident beam) calculate the distance (in cm) of the image from the lens.
60. A parallel beam of light falls normally on the first face of a prism of small angle. At the second face
it is partly refracted and partly reflected, the reflected beam striking the first face again and
emerging from it in a direction making and angle
0 1
6 30 with the reversed direction of the incident
beam. The refracted beam is found to have undergone a deviation of
0 1
1 15 from the original
direction. Find the angle of prism in degrees.