Theinformation contained herein is theexclusiveproperty of TTRI and shall not bedistributed, reproduced, or disclosed in wholeor in part without prior
written permission of TTRI.
1 The Development of Protimo Anti-Microbial Textile (Always effective type) ByDr. Lin, Chun Hung chLin.0697@ttri.org.tw s y n d e c k
Theinformation contained herein is theexclusiveproperty of TTRI and shall not bedistributed, reproduced, or disclosed in wholeor in part without prior written permission of TTRI. Introduction In our real life, all kinds of bacteria, germ and fungus are around ourselves. These microbial will grow rapidly if the suitable environment were given to them, which would cause a lot of diseases happened when contact them. And will spread or transmit to other people easily. That is how a lot of people have the illness happened and get killed. That is the reason why Antimicrobial textiles were invented and had been paid a highly attention to its development by most of the people in the world. It can be foreseen obviously that antimicrobial textile will have a lot of demand in the market and create a lot of profits and commercial opportunity under the increasing of the attention of personal health, daily hygiene and expect of the quality of living life style by the consumer. By ITIS reports, J apan has the largest antimicrobial textile market in the world, which is larger than US and European markets . In Canada it has about 350 millions Canadian Dollars of antimicrobial textile market. It is recognized that will have 10% growth rate of the world antimicrobial textile market within 8 years period. It is the trend of the future textile market. Introduction s y n d e c k
Theinformation contained herein is theexclusiveproperty of TTRI and shall not bedistributed, reproduced, or disclosed in wholeor in part without prior written permission of TTRI. 3 Market report of consumer requirement of antimicrobial products Product % Socks 28.0 Underwear 13.3 Panties 6.0 Handkerchief 5.6 Towel 5.3 Shoe 4.9 Slipper 3.4 Telephone 2.5 OthersBathrooms products, cooking ware, cutting board, wallet, water piping, wet towels/paper towel of restaurant, remote controller etc. People surveyedTotal 1600 of adult men, women from age 20yrs to 50 yrs. Fromwww.antibacteria.com.tw s y n d e c k
Theinformation contained herein is theexclusiveproperty of TTRI and shall not bedistributed, reproduced, or disclosed in wholeor in part without prior written permission of TTRI. 4 Domestic and foreign market of Antimicrobial Textiles The antimicrobial products/technologies of domestic and international market Company Product Anti-microbial agent Remarks
Domestic Far Eastern Anti-microbial/anti odor yarn Silver, anti-microbial agent (PET) More than 95 bacteriostasis tested by TTRI Shin Kung Tree in one Silver, anti-microbial agent (PET) 99.9 of bacteriostasis tested by national certify test Chung Shin Anti-microbial/odor yarn Silver ion, anti-microbial agent (PET) Tested by TTRI
Japan Teijin Chemitac (silver anti- microbial agent (PET) Chemitac, Silver anti microbial agent (PET) Certified by SEK, it inhibits the growth of MRSA Kanebo Gohesen Livefresh Silver ion anti-microbial agent (Nylon) After 50 washes, still has its anti- microbial function -- SEK certified Toray Seberis-M Zeolite/quatemary ammonium salt (Nylon) Control the growing of MRSA
US & EURO Trevira Bioactive Silver ion, anti-microbial agent (PET) Oeko-Tex certified Du Pont Tyvek Anti-microbial agent (PE) Multi-liquid VS Anti-bacterial function tested by DuPont Inc. Sterling Biofresh Triclosan (Acrylic) Micro fiber, soft, registered in US Environmental Protection Agency
s y n d e c k
Theinformation contained herein is theexclusiveproperty of TTRI and shall not bedistributed, reproduced, or disclosed in wholeor in part without prior written permission of TTRI. Silver Antimicrobial Agent faces the challenge s y n d e c k
Theinformation contained herein is theexclusiveproperty of TTRI and shall not bedistributed, reproduced, or disclosed in wholeor in part without prior written permission of TTRI. The Restriction of the Silver Antimicrobial Textile The complain of silver ion textiles from the consumer: Easy pilling and color fading s y n d e c k
Theinformation contained herein is theexclusiveproperty of TTRI and shall not bedistributed, reproduced, or disclosed in wholeor in part without prior written permission of TTRI.
When washing this products by using cl ean wat er wi t h t he t emper at ur e under 30 degree C D r y c l e a n i n g , bl eachi ng, col or e n h a n c i n g , softener and anti - m i c r o b i a l det ergent are not a l l o w e d
The Restriction of the Silver Antimicrobial Textile s y n d e c k
Theinformation contained herein is theexclusiveproperty of TTRI and shall not bedistributed, reproduced, or disclosed in wholeor in part without prior written permission of TTRI. 8 Processing of development Processing of the R &D of Anti-microbial fiber Evaluation of the anti-microbial agent Technology of the anti-microbial master batch Long term effect of anti-microbial fiber spinning technology Long term effect of anti-microbial fiber testing technology s y n d e c k
Theinformation contained herein is theexclusiveproperty of TTRI and shall not bedistributed, reproduced, or disclosed in wholeor in part without prior written permission of TTRI. The Characteristics of Antimicrobial Agents Organic Anti-microbial material Inorganic Anti- microbial material
Natural material Photo- catalyst material Anti-microbial agent Protimo TBZ Silver, copper, lead Wasabi, Chinese cypress extracted oil TiO2 Distribution of pathogens Fungi 223 Bacterial 147 Algae 27 Fungi 32 Bacterial 0 Algae 0
Fungi 3 Bacterial 6 Algae 0 Yeast 1
Unknown Unknown MIC value 1~25 ppm 1~50 ppm 2000~3000 ppm Anti-microbial mechanism Non-outflow (Forever Type) Outflow Sterilizing Unknown Sterilizing Problems Poor heat resistance, Intend to turn to yellow color Color changed Unknown Light required s y n d e c k
Theinformation contained herein is theexclusiveproperty of TTRI and shall not bedistributed, reproduced, or disclosed in wholeor in part without prior written permission of TTRI. 10 Pallium Cell nucleus Lipid double membrane Protimo anti-microbial agent Destroys only the pallium Bacteria nucleus in Suspended animation How does the Protimo Antimicrobial Agent Work? After sending danger signals to the others (Evasion signal Transmission), they are eventually destroyed by losing the nutrients. s y n d e c k
Theinformation contained herein is theexclusiveproperty of TTRI and shall not bedistributed, reproduced, or disclosed in wholeor in part without prior written permission of TTRI. It destroys only the pallium of bacteria or fungus, which will be interrupted the proteinase, DNA, thiol group synthetized and stop their reproduction mechanism. The interrupted synthetized bacteria will release its proteinase from the destroyed pallium, which means sending the chemical signal (in dangerous) to other bacteria. That will prevent other bacterial to approach those material which has Protimo contain. Then, the bacterial will not be able to survive without required reproduction nutrition. Protimo Antimicrobial Mechanism s y n d e c k
Theinformation contained herein is theexclusiveproperty of TTRI and shall not bedistributed, reproduced, or disclosed in wholeor in part without prior written permission of TTRI. The Safety of Protimo Antimicrobial Agent s y n d e c k
Theinformation contained herein is theexclusiveproperty of TTRI and shall not bedistributed, reproduced, or disclosed in wholeor in part without prior written permission of TTRI. 13 Anti-microbial value >2.0It means the sample has antimicrobial effect (JIS L1902:2008) Sterilizing activity value >0.0means the sample has sterilizing activity effect (JIS L1902:2008) Trichophyton mentagrophytes tested grade0No growthGrade 1lightly growth (<10%)Grade 2Minor growth (<10~30%)Grade 3medium growth (30~60%)Grade 4Growth heavily (>60%)(ASTM G21-2009) Anti- microbial Nylon Master batch antimicrobial agent concentration (%) Anti microbial agent concentr ation in the fiber (%) Staphylococcus Aureus (MRSA) Trichophyton mentagrophytes Before dyeing After dyeing Anti- microbial value Sterilizing activity value Anti- microbial value Sterilizing value Grade 5 0.2 5.6 3.2 5.4 3.2 0 Antimicrobial Nylon fiber SDY Homo, Round shape fiber Denier/ filament Tenacity (gf/d) Elongation % 80/48 4.8 39.8 s y n d e c k
Theinformation contained herein is theexclusiveproperty of TTRI and shall not bedistributed, reproduced, or disclosed in wholeor in part without prior written permission of TTRI. 14 154 2011 Problems caused by MRSA s y n d e c k
Theinformation contained herein is theexclusiveproperty of TTRI and shall not bedistributed, reproduced, or disclosed in wholeor in part without prior written permission of TTRI. Test method JIS Z2801:2010 Result Bacterial count (24hrs.) Antimicrobia l activity value
Staphylococcus Aureus (MRSA) Initial count 1.6 E6 -- Untreated sample 2.1 E6 -- 0.2% Protimo antimicrobial added Nylon fiber sample1 2.4 E2 3.95 0.2% Protimo antimicrobial added Nylon fiber sample2 2.6 E2 3.78 Required standard: Antimicrobial activity value should larger than2.0 MRSA Test of Protimo Antimicrobial contained Nylon fiber s y n d e c k
Theinformation contained herein is theexclusiveproperty of TTRI and shall not bedistributed, reproduced, or disclosed in wholeor in part without prior written permission of TTRI.
Test method JIS L1902:2008 Bacterial fluid absorption method Result JIS white cotton fabric Contain Protimo antimicrobial Nylon knitting fabric Contain Protimo antimicrobial Nylon knitting fabric after washing and bleaching (20g/l) Staphyloco ccus Aureus (MRSA) ATCC 6538P Concentratio n of bacteria 1.3 E5 1.5 E5 1.3 E5 Ma 2.6 E4 -- -- Mb 7.0 E6 -- -- Mo -- 2.7 E4 2.4 E4 Mc -- 1.2 E3 1.8 E2 Growth rate 2.4 -- -- Bacteriostasi s activity value -- 3.8 5.0 Sterilizing activity value -- 1.4 2.6 When Bacteriostasis activity value >2.2 means it has bacteriostasis effect, Sterilizing value >0means it has sterilizing effect. The Antimicrobial Test of Washed & Bleached Nylon fabric s y n d e c k
Theinformation contained herein is theexclusiveproperty of TTRI and shall not bedistributed, reproduced, or disclosed in wholeor in part without prior written permission of TTRI.
Test method JIS L1902:2008 Bacterial fluid absorption method Test result J IS White cotton fabric 0.2% Protimo antimicrobial agent added Nylon fiber (refining) 0.2% Protimo antimicrobial agent added Nylon fiber (refining and dyeing)
Staphylococcus Aureus (MRSA) ATCC 6538P Concentration 1.5 E5 1.5 E5 1.5 E5 Ma 3.0 E4 -- -- Mb 9.4 E6 -- -- Mo -- 2.4 E4 1.8 E4 Mc -- <20 <20 Growth rate 2.5 -- -- Bacteriostasis activity value -- 5.6 5.4 Sterilizing activity value -- 3.2 3.2 When Bacteriostasis activity value >2.2 means it has bacteriostasis effect, Sterilizing value >0 means it has sterilizing effect The MRSA Test of the Protimo Antimicrobial Nylon fiber s y n d e c k
Theinformation contained herein is theexclusiveproperty of TTRI and shall not bedistributed, reproduced, or disclosed in wholeor in part without prior written permission of TTRI.
Item tested Test Result Test Method Contain 0.5% Protimo antimicrobial PET fiber Contain 0.2% Protimo antimicrobial agent Nylon fiber ASTM G21- 2009
Grade 0 PS: The definition of the Anti-fungus degree evaluation: Observation of the growth of fungus on the tested sample Grade Non-growth 0 minor growth (<10%) 1 lightly growth (10~30%) 2 medium growth (30~60%) 3 Heavily growth (>60%) 4
Note: This is the result observed after 28 days culture period.
The result of the polyester and nylon fibers Trichophyton mentagrophytes test s y n d e c k
Theinformation contained herein is theexclusiveproperty of TTRI and shall not bedistributed, reproduced, or disclosed in wholeor in part without prior written permission of TTRI. Test method JIS L1902:2008 Bacterial fluid absorption method Test Result JIS White cotton fabric Regular Nylon fiber 25% Antimicrobia l Nylon fiber 50% Antimicrobial Nylon fiber
75% Antimicrobi al Nylon fiber 100% Antimicrobial Nylon fiber
Bacteriostasis value >2.0 shows the tested sample has antimicrobial and anti odor effect Sterilizing activity value >0 shows the tested sample has sterilizing effect. The Antimicrobial Test of Mixed Antimicrobial/Regular Nylon Fibers s y n d e c k
Theinformation contained herein is theexclusiveproperty of TTRI and shall not bedistributed, reproduced, or disclosed in wholeor in part without prior written permission of TTRI. 20 Anti- microbial PET fibers POY Homo round shape POY Sheath/core structure DTY Sheath /core structure Denier/ filament Tenacity (gf/d) Elongation % Denier/ filament Tenacity (gf/d) Elongation % Denier/ filament Tenacity (gf/d) Elongation % 120/48 2.4 110 120/48 2.4 115 75/48 4.1 26.1 Anti- microbial PET
Master batch antimicrobial agent concentration (%) Anti microbial agent concentration in the fiber (%) Staphylococcus Aureus (MRSA) Trichophyton mentagrophytes Before dyeing After dyeing The sterilization rate % The sterilization rate % Grade 5 0.3~0.5 98.4 <0 0 When sterilization rate %>0It means it has antimicrobial function (AATCC 100-2004) s y n d e c k
Theinformation contained herein is theexclusiveproperty of TTRI and shall not bedistributed, reproduced, or disclosed in wholeor in part without prior written permission of TTRI.
Test method JIS L1902:2008 Bacterial fluid absorption method Test Result JIS white cotton fabric PET fabric PET fabric after bleaching (20% X 2hr)
Staphylococcus Aureus (MRSA) ATCC 6538P Concentration of Bacteriopexia 1.7 E5 1.7 E5 1.18 E5 Ma 3.2 E4 -- -- Mb 6.9 E6 -- -- Mo -- 3.5 E+4 3.5 E+4 Mc -- 1.9 E+4 2.0 E+4 Growth rate 2.3 -- -- Bacteriostasis activity value -- 2.6 2.6 Sterilizing value -- 0.2 0.2
Klebsiella pneumoniae ATCC 4352 Concentration of Bacteriopexia 1.4 E5 1.4 E5 1.4 E5 Ma 3.0 E4 -- -- Mb 2.5 E7 -- -- Mo -- 2.7 E+4 2.8 E+4 Mc -- 1.7 E+3 1.7 E+3 Growth rate 2.9 -- -- Bacteriostasis activity value -- 4.2 4.1 Sterilizing value -- 1.3 1.2 When Bacteriostasis activity value >2.2 means it has bacteriostasis effect, Sterilizing value >0means it has sterilizing effect. The Antimicrobial Test of Washed & Bleached PET fabric s y n d e c k
Theinformation contained herein is theexclusiveproperty of TTRI and shall not bedistributed, reproduced, or disclosed in wholeor in part without prior written permission of TTRI. Before washing No inhibition ring shown. And, no bacterial grown on the sample. After 20 washing cycles: No inhibition ring shown. And, no bacterial grown on the sample.
Free anti-microbial agent sample test: Yellow bacteria track will be appeared when no agent applied. Polyester Binder 6% + Protimo - B 0.5% 160x2MIN The Antimicrobial activity Test of the Antimicrobial Finishing Textile s y n d e c k
Theinformation contained herein is theexclusiveproperty of TTRI and shall not bedistributed, reproduced, or disclosed in wholeor in part without prior written permission of TTRI. Test method JIS L1902:2008 Bacterial fluid absorption method Result JIS white cotton fabric PET fabric (Before washing) PET fabric (After 20 washing)
Staphylococcus Aureus (MRSA) ATCC 6538P Concentration of bacteria 2.1 E5 2.1 E5 2.1E5 Ma 4.0 E4 -- -- Mb 9.1 E6 -- -- Mo -- 3.9 E4 3.4 E4 Mc -- 3.6 E4 8.4 E4 Growth rate 2.5 -- -- Bacteriostasis activity value -- 2.4 3.0 Sterilizing activity value -- 0.0 0.7 Bacteriostasis activity value >2.2 means the tested sample has bacteriostasis effect. Sterilizing value >0 means the tested sample has sterilizing effect. Tested sample: 6% Binder + 0.5% APDS (Antimicrobial agent) The Antimicrobial Activity and Efficacy Test of the Finishing PET Fabric s y n d e c k
Theinformation contained herein is theexclusiveproperty of TTRI and shall not bedistributed, reproduced, or disclosed in wholeor in part without prior written permission of TTRI.
Grade A Note : Grading of fungus resistance Grade A : The growth area of fungus on tested sample <1/10 of sample area Grade B : The growth area of fungus on tested sample between1 /10~1/3 of sample area Grade C : The growth area of fungus on tested sample >1 /3 of sample area Trichophyton mentagrophytes test after finishing treatment s y n d e c k
Theinformation contained herein is theexclusiveproperty of TTRI and shall not bedistributed, reproduced, or disclosed in wholeor in part without prior written permission of TTRI.
Item tested Result Method 0.2% Protimo antimicrobial Finished PET fabric(After 50 washes) 0.3% Protimo antimicrobial Finished PET fabric(After 50 washes CNS 2690 L3063-2008 Dry environment
Fungus resistance
Trichophyton mentagrophytes AATCC 9533
Grade A
Grade A Note : Grading of fungus resistance Grade A : The growth area of fungus on tested sample <1/10 of sample area Grade B : The growth area of fungus on tested sample between1 /10~1/3 of sample area Grade C : The growth area of fungus on tested sample >1 /3 of sample area
Trichophyton mentagrophytes test after finishing treatment s y n d e c k
Theinformation contained herein is theexclusiveproperty of TTRI and shall not bedistributed, reproduced, or disclosed in wholeor in part without prior written permission of TTRI. Test method JIS L1902:2008 Bacterial fluid absorption method Result JIS White cotton fabric PET fabric (After 50 washes)
Staphylococcus Aureus (MRSA) ATCC 6538P Concentration 1.4E5 1.4E5 Ma 2.7 E4 -- Mb 9.7E6 -- Mo -- 2.1 E4 Mc -- 3.9 E3 Growth rate 2.6 -- Bacteriostasis activity value -- 3.5 Sterilizing activity value -- 1.0 Bacteriostasis activity value >2.2 means the tested sample has bacteriostasis effect. Sterilizing value >0 means the tested sample has sterilizing effect. Tested sample: 6% Binder + 0.2% APDS (Antimicrobial agent) The MRSA Antimicrobial Test of the Finishing fabric s y n d e c k
Theinformation contained herein is theexclusiveproperty of TTRI and shall not bedistributed, reproduced, or disclosed in wholeor in part without prior written permission of TTRI. 27 Advantage and its Application Advantage Intimate wears (Underwear, pantyhose etc.) Home textile Sport wears Medical, hygiene garment 1. With 0.2~0.5 wt% concentration in the fiber will have the antimicrobial effect. 2. By adding the agent during the Solution dye will have the same effect. 3. After 50 washes still keep the antimicrobial function. It has a long term effect. Application s y n d e c k