1

BAHAGIAN PENGURUSAN SEKOLAH BERASRAMA PENUH

DAN SEKOLAH KECEMERLANGAN
KEMENTERIAN PELAJARAN MALAYSIA


CHEMISTRY
TRIAL-EXAM
SPM 2012
MARKING SCHEME
PAPER 1
PAPER 2
PAPER 3


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SKEMA KERTAS 1
PENTAKSIRAN DIAGNOSTIK AKADEMIK
SBP 2012
CHEMISTRY 4541/1


1 A 26 C
2 A 27 D
3 C 28 C
4 A 29 D
5 A 30 B
6 D 31 B
7 B 32 C
8 A 33 A
9 B 34 C
10 A 35 C
11 B 36 D
12 A 37 A
13 D 38 B
14 C 39 B
15 D 40 D
16 A 41 D
17 B 42 D
18 D 43 A
19 C 44 B
20 B 45 C
21 C 46 B
22 D 47 C
23 D 48 B
24 B 49 D
25 A 50 C


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MARKING SCHEME
CHEMISTRY PAPER 2 SECTION A (4541/2)
Question Mark scheme Sub
Mark
Total
Mark
1(a) A: Detergents
B: Soap
r : sodium salt
1
1

2
1(b)(i) magnesium ion // or calcium ion
r : Mg
2+
, Ca
2+
1
2
1(b)(ii) Soaps are biodegradable 1
1(c) Analgesics
Psychotherapeutic
r: wrong spelling
1
1

2
1(d)(i) Sugar
Aspartame
1
1




3
1(d)(ii) To add / restore the colour of food // To enhance its visual
appeal / appearance// more attractive

1
TOTAL 9



Question Mark scheme
Sub
Mark
Total
Mark
2(a)(i)
Magnesium
r:Mg
1
2
2(a)(ii) Has 3 shell occupied with electrons 1
2 (b)
1. Proton number of chlorine is higher than magnesium // the
number of proton of chlorine atom higher than magnesium atom
// total positive charged in nucleus higher than magnesium
2. The attractive force between the nucleus and the electrons in
chlorine atom stronger than magnesium atom // nuclei attraction
towards electrons stronger.

1

1


2
2(c) Light bulb // in welding process 1 1
2 (d) Argon 1 1
2(e)(i)

3 Cl
2 (g)
+ 2 Fe
(s)
2 FeCl
3(s)



1

1
2(e)(ii) Mass iron (III) chloride = 0.05 x 161 // 8.05 g 1 1



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4

2(e)(ii)








1







1
Total 9



Question Mark scheme
Sub
Mark
Total
Mark
3(a)(i) 6 1








4
3(a)(ii) To estimate the age of fossils and artifacts 1
3(a)(iii) C-12 // C-13




1
3(a)(iv) 7 / 6 1
3(b)(i) A: covalent
r: covalent bond
B: ionic
r: ionic bond
1

1












6
3(b)(ii) 2.8.8.1 1
3(b)(iii) High melting point and boiling point // conduct electricity in
molten or aqueous solution // soluble in water // insoluble in
organic solvent.
[Any one]
1
3(c)(iv) 2K + Cl
2
2KCl
1. Formula of reactants and products correct
2. Balance the chemical equation

1
1
TOTAL 10





13
C
6
12
C
6
Or







Hot iron wool
Wul besi panas
Heat
Panaskan
Chlorine gas
Gas klorin

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Question Mark scheme
Sub
Mark
Total
Mark
4(a)(i)
Pipette
r: wrong spelling
1






3
4(a)(ii)
Phenolphthalein // methyl orange
r: wrong spelling
1
4(a)(iii)
Phenolphthalein : pink to colourless //
methyl orange : yellow to orange

1
4(b)(i)
2KOH + H
2
SO
4
K
2
SO
4
+ 2H
2
O
Formula of reactants and products correct
Balance the chemical equation
1
1


2
4(b)(ii)
1. Mol of KOH = (1.0)(25) / 1000
= 0.025 mol

2. Molarity of H
2
SO
4
= (0.0125)(1000) / 10
= 1.25 mol dm
-3
//

Molarity of H
2
SO
4
= 0.0125 /0.01 = 1.25 mol dm
-3


Or

b
a
V M
V M
b b
a a
; Molarity of H
2
SO
4
=
10
) 25 ( 1
2
1
x
= 1.25 mol dm
-3
r: wrong unit or without unit


1
1


2
4(c)(i)
Hydrogen ion
r: H
+
(symbol ion)

1



3
4(c)(ii)
1. no water
2. contain of molecule // no hydrogen ion, H
+

1
1
TOTAL 10











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Question Mark scheme Sub
Mark
Total
Mark
5(a) Chemical formula that shows the simplest whole number ratio of
atom of each element in the compound.
1 1
5(b)(i) Mass of Mg = 2.4 g
Mass of O = 1.6 g

1







6
5(b)(ii) Mole of Mg = 2.4 / 24 = 0.1
Mol of O = 1.6 / 16 = 0.1
Mg : O = 1 : 1
1

1
5(b)(iii) MgO 1
5(b)(iv) to allow oxygen enter the crucible 1
5(b)(v) Repeat the process heating, cooling and weighing until a
constant mass is obtained.
1
5(c)







Apparatus set-up correct and functional
Labeled : magnesium ribbon, heat








1
1









2
5(d)(i) Zinc oxide // aluminium oxide
r: formula
1
2
5(d)(ii) Silver is less reactive / not reactive metal 1
TOTAL 11
















Magnesium
ribbon

Heat

crucible

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Question Mark scheme
Sub
Mark
Total
Mark
6(a) Hydrogenation 1












5
6(b) C
4
H
8 +
H
2
C
4
H
10
1
6(c)(i)
Mole of butene = 2.8 /56 = 0.05 mol

1

6(c)(ii) P1. 1 mol of butene burns in oxygen gas produce 4 mol of
carbon dioxide.
Therefore 0.05 mol of butene burns in oxygen gas produce 0.2
mol of carbon dioxide //
C
4
H
8
: CO
2
1 : 4
0.05 : 0.2
P2. volume of CO
2
= 0.2 x 24 = 4.8 dm
3




1



1
6(d) P1: 2 cm
3
of but-2-ene and 2 cm
3
of butane gas are filled in two
different test tubes.
P2 : 2 -3 drops of acidified potassium manganate (VII) solution
is added to both test tubes.
P3: But-2-ene decolourises purple acidified KMnO
4

Purple acidified KMnO
4
in butane remains unchange.
Or
P1: 2 cm
3
of but-2-ene and 2 cm
3
of butane gas are filled in two
different test tubes.
P2 : 2-3 drops of bromine water is added to both test tubes.
P3: But-2-ene decolourises brown bromine water.
Brown bromine water in butane remains unchange.

1

1

1
Or

1
1

1











3
6(e)(i) A: unvulcanised rubber
B: vulcanised rubber
1
1



3
6(e)(ii) Rubber type B/ vulcanised rubber is more elastic than rubber
type A/ unvulcanised rubber

1
TOTAL 11

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SECTION B
Question Mark scheme
Mark
Mark
7 (a)




(i) Ascending order : Cu, Y,X, W

(ii)
P1 : Positive terminal : Cu
P2 : Potential difference : 1.3V
P3: Copper is less electropositive // X is more electropositive
correct value and unit
1


1
1
1



4

7 ( b) (i)
Experiment I : Pb
2+
, Cl
-
Experiment II: H
+
. OH
-
, Cl

r: lead(II) ion, chloride ion
Hydrogen ion, hydroxide ion, chloride ion
1
1


2

7(b)(ii)

Experiment 1 Experiment II
Product at anode:
Chlorine gas

Products at cathode:
Oxygen gas

Reason:
P1: Cl
-
is discharged

P2: the only
anion presence
and discharged at anode

Reason:
P1:OH
-
is selected to be
discharged

P2:the position of OH
-
is lower
than Cl
-
in electrochemical series
.Half equation:
2Cl
-
Cl
2
+ 2e

P1:Correct formula of
reactant and product :
P2: Balance equation
. Half equation:
4OH
-
2 H
2
O + O
2
+ 4e

P1: Correct formula of reactant
and product
P2: Balance equation





1 + 1



1 + 1


1 + 1





1 + 1

1 + 1



















10


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7(c)
P1: Positive terminal: R
P2: Negative terminal:Cu
P3: Suitable metal for R : Silver
P4: Suitable solution for R : Silver nitate solution

1
1
1
1




4


Total 20

Question Mark scheme Mark Mark
8(a)
P1. Smaller size has larger total surface area.
P2. Absorb heat faster.
P3. Bigger size has smaller total surface area.
P4. Absorb heat slower
1
1
1
1



4
(b)(i)
Copper(II) sulphate
1 1
(b)(ii)
1. Experiment I
Rate of reaction = 40/2 = 20 cm
3
min
-1

2. Experiment II
Rate of reaction = 60/2 = 30 cm
3
min
-1

1

1


2
(b)(iii)
P1. Rate of reaction in Experiment II is higher than
Experiment I.
P2. Substance X used in Experiment II is a catalyst.
P3. Catalyst provided an alternative path with requires a
lower
activation energy.
P4. More particles are able to achieve lower activation
energy.
P5. Frequency of effective collisions between zinc atoms and
hydrogen ions are higher.
1

1
1

1
1




5


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(b)(iv)
1. Label of axes and unit
2. Correct curve and label










1
1








2

(v)
1. Correct formula of reactants and product
2. Balanced equation
Zn + 2H
+
Zn
2+
+ H
2
1
1

2

(vi)
1. Rate of reaction using sulphuric acid is higher.
2. Volume of hydrogen gas released is doubled.
3. Sulphuric acid is a diprotic acid.
4. Concentration of hydrogen ions in sulphuric acid is double
than that in hydrochloric acid.
1
1
1

1



4

Total 20


Volume of
gas / cm
3

Time / min
Exp II
Exp I
2
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Question Mark scheme
Mark
Mark
9(a) P1: Magnesium atom undergoes oxidation
P2: oxidation number increases from 0 to 2+
P3: Copper (II) ion undergoes reduction
P4: oxidation number decreases from +2 to 0
P5: The reaction involving oxidation and reduction
1
1
1
1
1



MAX
4
(b)
Experiment I

L can reduce copper(II) oxide// L can react with copper(II) oxide
L is more reactive than copper.
Experiment II

M can reduce copper(II) oxide//M can react with copper(II)
oxide
M is more reactive than copper.
Experiment III

M cannot reduce L oxide // M cannot react with L oxide.
M is less reactive than L//L is more reactive than M.


The arrangement in order of increasing reactivity toward oxygen is Cu,
M and L.


1
1


1
1

1
1
Max
5

1








6

(c)

Procedure :
P1. Pour 2 cm
3
of potassium bromide solution into a test tube.
P2. Add 2 cm
3
of chlorine water to the test tube and shake the mixture.
P3. Add 2 cm
3
of 1,1,1 trichloroethane to the test tube and shake the
mixture.
P4. Record the observation
P5. Repeat steps 1-4 using another halogens and halide solution.
.


1
1
1

1
1










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Result :

Chlorine water Bromine water Iodine water
Potassium
chloride

X X
Potassium
bromide
X
Potassium
iodide



Ionic equation:

1. Cl
2
+ 2Br
-
2Cl
-
+ Br
2
2. Cl
2
+ 2I
-
2Cl
-
+ I
2
3. Br
2
+ 2I
-
2Br
-
+ I
2








1

1


1
1
1


















10
20


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Question Mark scheme
Mark
Mark
10(a)
Precipitation / double decomposition reaction

Barium nitrate solution/barium chloride solution
[Any sulphate solution]
Example: sodium sulphate, potasium sulphate, sulphuric
acid
Reject : Lead(II) sulphate, calcium sulphate

Ba
2+
+ SO
4
2
BaSO
4

1

1

1

1





4
10(b)(i)
Cation : Iron(II) ion / Fe
2+


Anion: Chloride ion / Cl

1

1


2
10(b)(ii)
Test for NO
3


P1: Add 2 cm
3
of dilute sulphuric acid into the test tube follow
by 2 cm
3
of iron(II) sulphate solution.
P2: Add a few drops of concentrated sulphuric acid
P3: carefully and slowly along the side of slanting test tube
into the mixture.
P2: A brown ring is formed.


1
1
1

1






4
10(c)
Procedure:
P1. Add zinc nitrate solution to sodium carbonate solution
in a beaker.
P2. Stir the mixture.
P3. Filter the white precipitate/solid zinc carbonate formed.

P4. Add zinc carbonate to sulphuric acid in a beaker until
some zinc carbonate solid no longer dissolve.
P5. Filter the mixture.
P6. Transfer the filtrate to a evaporating dish.
P7. Heat the filtrate(zinc sulphate solution) until saturated//
Heat the filtrate to about one-third (1/3) of its initial
volume
P8. Allow the saturated solution to cool at room temperature.
P9. Filter the crystals formed.
P10. Dry the crystals by pressing it between two sheets of
filter papers.

1

1
1
1

1
1
1

1
1
1









10

Total 20

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