San Pedro College

Davao City
COURSE SYLLABUS
1
st
Semester
S.Y. 201!201"
Ca#alla$ %anna& 'ay
Castillo$ (ona Lisa
C)arenta$ Carl 'ris
Dia*$ Benilda
+ernande*$ Liane (aristel
,a-ia*on$ .ivien
(olina$ 'arl A)g)st)s
/e-rada$ (ary Lo)ise
0nstr)1tor
0. COURSE 202LE3 Organi1 C&emistry
/ame o4 S)-5e1t3 C&em 200
2ime o4 Dis1)ssion3 Semestral
00. COURSE DESCR0P20O/3
An introd)1tion to t&e 4ield o4 #&ysi1al organi1 1&emistry. 2o#i1s in1l)de -onding and str)1t)re$ 1on4ormational analysis$
stereo1&emistry$ a1ids and -ases rea1tivity and rea1tion. Develo#s #ro-lem!solving s6ills related to t&e nat)re o4 matter$ 1&emi1al rea1tions$
stoi1&iometry$ energy trans4ormations$ atomi1 and mole1)lar str)1t)re$ 7)ant)m t&eory$ 1&emi1al -onding$ and #eriodi1 #ro#erties.
Em#&asi*es 7)alitative and 7)antitative e8#eriments$ data analysis and error #ro#agation. Le1t)re and la-oratory 1o)rse develo#s s6ill and
)nderstanding o4 analyti1al 1&emistry and instr)mental analysis. 2&e 1&emistry o4 aromati1$ 1ar-onyl$ and nitrogen 1om#o)nds. 2&e 4irst
se1tion is designed to alert yo) and yo)r instr)1tor to #ossi-le &a*ards asso1iated 9it& e8#erimental o#erations -eing #er4ormed -e1a)se o4
t&e 4lamma-le t&e )se o4 4lameless &eating so)r1es is em#&asi*ed. 2&e g)idelines and met&ods in t&e 4inis&ing to)1&es se1tion are #rovided
to assist yo) in t&e #ro#er dis#osal o4 t&e s#ent 1&emi1als and ot&er -y#rod)1ts o4 t&e e8#erimental #ro1ed)res. Pre!la- e8er1ises are
intended to -e 9or6ed as #art o4 #re#aring 4or t&e la-oratory and are 1ontained in a se#arate -oo6. 2&ey are designed to test t&e
)nderstanding o4 t&e -asi1 1on1e#ts )nderlying t&e e8#eriments -eing #er4ormed and t&e te1&ni7)es re7)ired to 1ond)1t t&e #ro1ed)res in a
sa4e and s)11ess4)l manner.
000. CRED02S3 : )nits ;Le1t)re3 &o)rs<9ee6= La-oratory3 > &o)rs<9ee6?
0.. SPC .ision3
A Domini1an learning 1omm)nity$ 1ommitting to e81ellen1e in t&e 4ormation o4 #ersons$ living and s#reading t&e love o4 t&e
1om#assionate @es)s A %ealer and 2ea1&er.
SPC (ission3
Be$ t&e st)dents$ sta44$ 4a1)lty$ and administrators$ 1ommit o)rselves to 1ontin)ally3
B)ild a n)rt)ring C&ristian 1omm)nity 9it& #assion 4or tr)t&$ servi1e$ and e81ellen1e=
Provide t&e P&ili##ines and t&e 9orld 9it& t&e #ersons 9&o are #ro4essionally and te1&ni1ally s6ill4)l im-)ed 9it& strong et&i1al$
moral$ and s#irit)al val)es t&ro)g& innovative #rograms o4 instr)1tion and 4ormation$ resear1&$ and 1omm)nity e8tension servi1es=
S)stain 7)ality 9or6 li4e 4or t&e em#loyees -y #roviding 1om#etitive -ene4its$ good 9or6ing 1onditions and o##ort)nities 4or
gro9t& and develo#ment=
Ens)re a s)staina-le e1onomi1 via-ility o4 t&e organi*ation t&ro)g& e44i1ient )se o4 reso)r1es
SPC Core .al)es3
!2r)t& and 9isdom
!C)ality and e81ellen1e
!Res#e1t t&e )ni7)eness o4 #ersons
!So1ial res#onsi-ility
!+amily s#irit and sense o4 1aring
.. COURSE ,OALS3
At t&e end o4 t&e 1o)rse$ t&e st)dents are e8#e1ted to3
1. 2o -e a-le to analy*e t&e str)1t)re o4 organi1 1om#o)nds -y re1ogni*ing main 4)n1tional gro)#s.
2. 2o -e 4amiliar 9it& t&e nomen1lat)re$ #re#aration and rea1tions o4 t&e 4)n1tional gro)#s and its derivatives.
. 2o -e a-le to name organi1 1om#o)nds )sing 0UPAC system.
". 2o 6no9 several organi1 1om#o)nds rea1tions and -e a-le to )se t&em to -)ild organi1 1om#o)nds.
:. 2o -e a-le to 9rite systemati1 names and dra9 a11)rate str)1t)res.
>. 2o re1ogni*e t&e str)1t)re and 4)n1tions o4 t&e di44erent organi1 1om#o)nds.

;2PO?
At t&e end o4 t&e 1o)rse$ 9it& t&e #ro#er motivation and dire1tion o4 t&e tea1&er and 9it& t&e st)dentsD 1ommitment to develo# a god
st)dy &a-it and -e a-le to a##ly it 9it& ot&er t&ings= 9it& t&e &el# o4 relevant materials and re4eren1es$ t&e st)dents are a-le to3
1. Com#are t&e 1&emi1als o4 di44erent 4)n1tional gro)#s.
2. Des1ri-e t&e str)1t)res$ 1&ara1teristi1s and #ro#erties o4 1&emi1als in ea1& 4)n1tional gro)#.
. Dis1)ss t&e im#ortan1e o4 sa4ety meas)res 9&ile #er4orming inside t&e la-oratory.
". E8#lain t&e -asi1 1on1e#ts )nderlying t&e e8#eriments -eing #er4ormed and t&e te1&ni7)es re7)ired to 1ond)1t t&e #ro1ed)res in a
sa4e and s)11ess4)l manner.
2&ese goals are 1onsidered a1&ieved i4 E0F o4 t&e 1lass is a-le to satis4a1torily e8#lain all 1on1e#ts and -e a-le to a##ly t&ese in all
t&e le1t)re and la-oratory a1tivities and #ass all oral and 9ritten o)t#)ts s)11ess4)lly.
.0. 2EAC%0/, PLA/
S#e1i4i1 O-5e1tives Contents 2ea1&ing<Learning
A1tivities
.al)es
0n4)sed
2ime
Allotment
Re4eren1es Eval)ation
At t&e end o4 t&is
1&a#ter$ t&e st)dents
are e8#e1ted to3
1. Dis1)ss t&e
&istory o4
Organi1
C&emistry
2. Dis1)ss t&e
so)r1es o4
Organi1
C&emistry
. Di44erentiate
t&e 4)n1tional
,ro)#s
". Dis1)ss t&e
str)1t)res o4
Organi1
Com#o)nds
and t&e Le9is
Ele1tron Dot
+orm)la
:. Di44erentiate
t&e ty#es o4
%y-ridi*ation
and t&e ty#es
o4 -onding
Orientation ,iving o4 S)-5e1t
Sylla-)s
A9areness
o4
res#onsi-iliti
es
1.: &o)rs Carrey +.
;?.Organi1
C&emistry >t&
Edition
Smit& @. ,.
;?.Organi1
C&emistry
0nternational
Edition
(1()rry. @.
;?.+)ndamentals o4
Organi1 C&emistry
:t& Edition
,il-ert$ @. G
(artin$ S.
;?.E8#erimental
Organi1 C&emistry
2nd Edition
Solomons$ 2.B.
;?.+)ndamentals o4
Organi1 C&emistry
"t& Edition
Pasto et al.$
;?.E8#eriments and
2e1&ni7)es in
Organi1
2e1&ni7)es
C%AP2ER 1
0ntrod)1tion
1.1 %istory o4 Organi1 C&emistry
a. (i1&el C&evre)l
-. +riedr1& Bo&ler
1.2 So)r1es o4 Organi1 Com#o)nd
a. 0solation 4rom /at)re
-. Synt&esis in t&e La-oratory
1. Ot&er 0m#ortant So)r1es
1. +)n1tional ,ro)#s
a. Al1o&ols
-. Alde&ydes
1. Amines
d. Car-o8yli1 A1id
e. Esters
4. Et&ers
g. Al6yl %alides
&. 'etones
i. /itriles
5. S)l4oni1 A1ids
6. 2&iols
Logi1al
Presentation
Listening
S6ills
Patien1e
A9areness
1.: &o)rs
1." Str)1t)res o4 Organi1 Com#o)nds and
Le9is Ele1tron Dot +orm)la
1.: %y-ridi*ation
a. 2y#es o4 %y-rid Or-ital
A. s# &y-rid or-ital
B. s#2 &y-rid or-ital
C. s# &y-rid or-ital
1.: &o)rs Britten
C)i* a-o)t
t&e
Di44erent
+)n1tional
,ro)#s

-. 2y#es o4 Bonding
A. Sigma -ond
B. Pi Bond
C%AP2ER 2
%ydro1ar-ons ;Al6anes and Cy1loal6anes?
2.1 0ntrod)1tion and Str)1t)re o4
%ydro1ar-ons
a. Categories o4 Organi1 Com#o)nds
A.Ali#&ati1 Com#o)nds
B. Aromati1 Com#o)nds
C Cy1li1 Com#o)nds
D. %etero1y1li1 Com#o)nds
-. 2y#es o4 %ydro1ar-ons
A. Sat)rated
B. Unsat)rated
1. +amilies o4 %ydro1ar-ons
A. Al6anes
B. Al6enes
C. Al6ynes
D. Aromati1 %ydro1ar-ons
d. 2y#es o4 Car-on Atoms
A. C)aternary Car-ons
B. 2ertiary Car-ons
C. Se1ondary Car-ons
D. Primary Car-ons
e. Str)1t)ral +orm)las
A. Straig&t 1&ain al6anes
B. Bran1&ed 1&ain al6anes
2.2 De4inition o4 0somerism
a. 2y#es o4 0somers
A. Constit)tional 0somers
B. ,eometri1 0somers
1.: &o)rs Britten
C)i* on
identi4ying
t&e ty#es
o4 &y-rid
or-ital in a
given
str)1t)re
2. C&ara1teristi1s o4 al6anes and
1y1loal6anes
2." /omen1lat)re o4 al6anes and
1y1loal6anes
2.: Cis!2rans 0somerism in Cy1loal6anes
2.> Al6anes
A. P&ysi1al Pro#erties o4 Al6anes
B. Boiling Point and (elting Point
2.H Rea1tions
A. Com-)stion
B. %alogenation
2.I %ydro1ar-on Reso)r1es
A. /at)ral ,as and Petrole)m
B. Coal
C%AP2ER
%ydo1ar-ons ;Al6enes and Al6ynes?
.1 C&ara1teristi1s o4 Al6enes and Al6ynes
.2 Str)1t)re and /omen1lat)re o4 Al6enes
and Al6ynes
. Stereoisomerism o4 Al6enes
A. Cis isomer
B. 2rans isomer
." Pro#erties o4 Al6enes and Al6ynes
.: 2y#es o4 Rea1tions 1ommon to
Al6enes
A. Addition Rea1tion
B. Elimination
C. S)-stit)tion
D. Rearrangement
.> De4inition o4 %alogenation$ %ydration$
%ydrogenation$ O8idation
.H (eaning o4 Polymeri*ation
1.: &o)rs Britten
C)i* on
/aming
and
Dra9ing
t&e
str)1t)re o4
Al6anes
and
Cy1loal6an
es
Britten
C)i* on
/aming
and
Dra9ing
t&e
str)1t)re o4
.I 2y#es o4 Synt&eti1 Polymers
A. Addition Polymers
B. Condensation Polymers
.E Classi4i1ation o4 Polymers
A. Elastomers
B. +i-ers
C. Plasti1s
.10 0m#ortant Al6enes and Al6ynes
Al6enes
and
Al6ynes
Prelims
E8am
C%AP2ER "
Ben*ene and its Derivatives
".1 Dis1overy o4 Ben*ene
".2 C&ara1teristi1s$ Str)1t)re and
Pro#erties o4 Ben*ene
". /omen1lat)re o4 Ben*ene
A. 0UPAC
B. Common /ame
"." Rea1tions o4 Ben*ene and its
Derivatives
A. /itration
B. S)l4onation
C. %alogenation
D. +riedel!Cra4ts al6ylation
".: Rea1tions o4 (ono!s)-stit)ted
Aromati1 Com#o)nds
A. Ort&o and Para s)-stit)ents
B. (eta dire1ting s)-stit)ents
".> C&ara1teristi1s o4 Aromati1 Com#o)nds
".H Resonan1e o4 Aromati1 Com#o)nds
1.: &o)rs
C%AP2ER :
Al1o&ols$ Et&ers and 2&iols
1.: &o)rs Britten
C)i* on
At t&e end o4 t&is
1&a#ter$ t&e st)dents
are e8#e1ted to3
1. Revie9 t&e
4)n1tional
gro)#s o4
Al1o&ols$
Et&ers$ and
2&iols
2. /ame and
dra9 t&e
str)1t)res o4
al1o&ols$
et&ers$ and
t&iols )sing
0UPAC and
1ommon
name
. Predi1t t&e
#&ysi1al
#ro#erties o4
al1o&ols$
et&ers$ and
t&iols
". Predi1t t&e
#rod)1ts o4
O8idation
Rea1tions
:. Dis1)ss t&e
me1&anism o4
al1o&ol
o8idation and
Antia-)se
:.1 De4inition o4 Al1o&ols$ P&enols$ Et&ers
and 2&iols
:.2. /omen1lat)re o4 Al1o&ols$ Et&ers$
P&enols and 2&iols
A. 0UPAC
B. Common /ame
:. Classi4i1ation o4 Al1o&ol
A. Primary ;1J? al1o&ol
B. Se1ondary ;2J? al1o&ol
C. 2ertiary ;J? al1o&ol
:." Str)1t)re and Pro#erties o4 Al1o&ol
:.: Com#arison o4 t&e -oiling #oints
:.> Sol)-ility o4 Al1&ols
t&e
Rea1tions
o4 Ben*ene
Britten
C)i* on
/aming
and
Dra9ing
t&e
Str)1t)re
o4 Ben*ene
:.H Rea1tion o4 Al1o&ols$ P&enols and
Et&ers
A. A1id!-ase rea1tion o4 al1o&ols and
#&enol
:.I O8idation o4 Al1o&ols
:.E /)1leo#&ili1 S)-stit)tion o4 Al1o&ols
:.10 Elimination o4 Bater 4rom Al1o&ols
:.11 Pro#erties o4 Al1o&ols and P&enols
:.12 C&ara1teristi1s o4 P&enols
:.1 Some Common Al1o&ols
A. (et&anol
B. Et&anol
C. 2!Pro#anol
D. 1$2!Et&anediol
E. 1$2$!Pro#anetriol
:.1" C&ara1teristi1s o4 Et&ers
:.1: C&ara1teristi1s o4 2&iols
1.: &o)rs Britten
C)i* on
1lassi4i1ati
on o4
Al1o&ols
Britten
C)i* on
/aming
and
Dra9ing
t&e
Str)1t)re
o4 Et&ers
and 2&iols
At t&e end o4 t&is
1&a#ter$ t&e st)dents
are e8#e1ted to3
1. E8#lain and
di44erentiate
isomers
2. /ame and
dra9
stereoisomers
. E8#lain
1&irality o4
mole1)les
". Dis1)ss t&e
signi4i1an1e
o4 1&irality in
nat)re
C%AP2ER >
C&irality
>.1 De4inition o4 0somers
>.2 2y#es o4 0somers
A. Stereo 0somers
a. ,eometri1 0somers
0. A1&iral
i. Cis!2rans 0somers
-. O#ti1al 0somers
0. C&iral
i. Enantiomers
1. De8trorotatory
mole1)les
2. Levorotatory mole1)les
. Ra1emi1 (i8t)re
1.: &o)rs Britten
C)i* on
/aming
and
Dra9ing
t&e
Str)1t)re
o4 Et&ers
and 2&iols
es#e1ially in
-iologi1al
#ro1ess
:. E8#lain &o9
1&irality is
dete1ted
ii. Diastereomers
1. E#imers
>. 0denti4ying C&iral or A1&iral
A. Stereogeni1 Center
B. Plane o4 Symmetry
C. Center o4 Symmetry
D. C&an!0ngold!Prelog
>." /aming t&e Stereo1enters
A. R system
B. S System
>.: De4inition o4 O#ti1al A1tivity
>.> P&ysi1al Pro#erties o4 Enantomiers
(idterm
E8am
At t&e end o4 t&is
1&a#ter$ t&e st)dents
are e8#e1ted to3
1. /ame and
dra9 t&e
str)1t)res o4
amines )sing
0UPAC and
1ommon
name
2. Classi4y
amines
. Predi1t t&e
#&ysi1al
#ro#erties o4
amines
". Brite t&e
rea1tions o4
amines
C%AP2ER H
Amines
H.1 Uses o4 Amines
H.2 2y#es o4 Amines
A. Al6yl Amines
B. Aryl Amines
C. %etero1y1li1 Amines
H. Classi4i1ation o4 Amines
A. Primary Amines
B. Se1ondary Amines
C. 2ertiary Amines
H." /omen1lat)re o4 Amines
A. 0UPAC
B. Common /ame
H.: P&ysi1al Pro#erties o4 Amines
A. Sol)-ility
B. Boiling Point
C. Ot&er P&ysi1al Pro#erties
1.: &o)rs Britten
C)i* on
t&e
Classi4i1ati
on and
2y#es o4
Amines
Britten
C)i* on
/aming
and
Dra9ing
Str)1t)re
o4 Amines
:. En)merate
a##li1ations
o4 amines
H.> Basi1ity o4 Amines
H.H C&emi1al Rea1tions o4 Amines
A. Rea1tion 9it& A1ids
At t&e end o4 t&is
1&a#ter$ t&e st)dents
are e8#e1ted to3
1. /ame and
dra9 t&e
str)1t)res o4
alde&ydes
and 6etones
)sing 0UPAC
and 1ommon
name
2. Predi1t t&e
#&ysi1al
#ro#erties o4
alde&ydes
and 6etones
. Provide t&e
#rod)1ts in
t&e
#re#aration o4
alde&ydes
and 6etones
". identi4y t&e
1om#o)nds
9&i1&
)ndergo 6eto!
enol
ta)tomerism
:. 0denti4y
o8idation!
C%AP2ER I
Alde&ydes and 'etones
I.1 Str)1t)re and Bonding o4 Alde&ydes
and 'etones
I.2 /omen1lat)re o4 Alde&ydes
A. 0UPAC
B. Common /ame
I. /omen1lat)re o4 'etones
A. 0UPAC
B. Common /ame
I." Pro#erties o4 Alde&ydes and 'etones
1.: &o)rs Britten
C)i* on
/aming
and
Dra9ing
Str)1t)re
o4
Alde&ydes
red)1tion
rea1tions in
nat)re
I.: Uses o4 Alde&ydes and 'etones
I.> Rea1tions o4 Alde&ydes and 'etones
A. Com-)stion
B. O8idation
I.H O8idation$ Red)1tion and %ydration o4
Alde&ydes
I.I Addition o4 Al1o&ols
1.: &o)rs
At t&e end o4 t&is
1&a#ter$ t&e st)dents
are e8#e1ted to3
1. /ame and
dra9 t&e
str)1t)res o4
Car-o8yli1
A1ids$
An&ydrides$
Esters$
Amides )sing
0UPAC and
1ommon
name
2. Predi1t t&e
#&ysi1al
#ro#erties o4
Car-o8yli1
A1ids$
An&ydrides$
Esters$
Amides
. Brite t&e
C%AP2ER E
Car-o8yli1 A1ids and its Derivatives
E.1 Str)1t)res o4 Car-o8yli1 a1ids$
An&ydrides$ Esters and Amides
E.2 /omen1lat)re o4 Car-o8yli1 A1ids
A. 0UPAC
B. Common /ame
E. /omen1lat)re o4 Di1ar-o8yli1 A1ids
E." Pro#erties o4 Car-o8yli1 A1ids
E.: ,eneral str)1t)res o4 Car-o8yli1 a1ids
and its derivatives.
E.> /omen1lat)re o4 A1id An&ydrides
1.: &o)rs
rea1tions o4
Car-o8yli1
A1ids$
A-&ydrides$
Esters$
Amides
". Understand
t&e
im#ortan1e o4
Car-o8yli1
A1id$
An&ydrides$
Esters$
Amides in
medi1ine
E.H Brie4 des1ri#tion on Amides
E.I /omen1lat)re o4 Amides
E.E Pro#erties o4 Amides
E.10 /omen1lat)re o4 Esters
E.11 ,eneral Rea1tion Patterns o4 Esters
E.12 Rea1tion o4 Car-o8yli1 A1ids
A. Car-o8yli1 A1ids to A1id C&lorides
B. Car-o8yli1 A1ids to A1id An&ydrides
E.1 %ydrolysis o4 An&ydrides$ Esters and
Amide
A. %ydrolysis o4 A1id %alides into A1ids
B. %ydrolysis o4 A1id An&ydride to A1ids
C. %ydrolysis o4 Amides to Car-o8ylate
0on
D. %ydrolysis o4 Esters into Car-o8yli1
A1ids
E.1" De4inition o4 Sa#oni4i1ation
A. Sa#oni4i1ation Rea1tion
1.: &o)rs
B. Cleansing A1tion o4 Soa#
E.1: /e)trali*ation o4 Car-o8yli1 A1ids
+inals
E8am
La-oratory 2ea1&ing Plan3
S#e1i4i1 O-5e1tives Contents
2ea1&ing<Learning
A1tivities
.al)es 0n4)sed
2ime
Allotment
Re4eren1es Eval)ation
At t&e end o4 t&is
semester$ t&e
st)dents are
e8#e1ted to3
1. 2o determine
t&e melting
#oints o4
1itri1 a1id$
)rea$
-en*oi1 a1id$
o8ali1 a1id
and sali1yli1
a1id
2. 2o 1om#are
t&e e44e1ts o4
str)1t)res
and
4)n1tional
gro)#s on
t&e melting
#oints o4
E8#eriment no. 13
(EL20/, PO0/2
DE2ER(0/A20O/
1.1. 0ntrod)1tion to
&eat and
tem#erat)re
1.2. (elting Points
o4 t&e 4ollo9ing3
a. Ben*io1 a1id
-. Citri1 a1id
1. O8ali1 a1id
d. Sali1yli1 a1id
e. Urea
1.. E44e1ts o4
str)1t)res and
4)n1tional gro)#s
on t&e melting
#oints o4 organi1
1om#o)nds.
Demonstration o4 t&e
e8#eriment
E8#erimentation
&o)rs
E8#eriment no. 23 Demonstration o4 t&e &o)rs
organi1
1om#o)nds
K
. 2o identi4y
t&e )n6no9n
organi1
1om#o)nd
sam#le
)sing
melting #oint
Determinatio
n
K
". 2o determine
t&e -oiling
#oints o4
a1etone$
9ater$ 2!
#ro#anol$
et&anol$
a1eti1
a1id$2!
met&yl!2!
#ro#anol
:. 2o 1om#are
t&e e44e1ts o4
str)1t)res
and
4)n1tional
gro)#s on
t&e -oiling
#oints o4
organi1
BO0L0/, PO0/2
DE2ER(0/A20O/
2.1. 0ntrod)1tion o4
Boiling Point
2.2. Boiling Point o4
t&e 4ollo9ing3
a. A1eti1 a1id
-. A1etone
1. Et&anol
d. 2!met&yl!2!
#ro#anol
e. 2!#ro#anol
4. 9ater
2.. +a1tors
a44e1ting Boiling
Point
e8#eriment
E8#erimentation
E8#eriment no. 3
#%
DE2ER(0/A20O/
.1. (eaning o4
a1id and -ase
.2. #% o4 t&e
4ollo9ing3
a. A1eti1 a1id
-. A1etone
1. Et&anol
d. 2!#ro#anol
e. Bater
4. +ormi1 a1id
g. 2!met&yl!2!
#ro#anol
&. Sali1yli1 a1id
i. Cy1lo&e8anol
Demonstration o4 t&e
e8#eriment
E8#erimentation
&o)rs
1om#o)nd
K
>. 2o determine
t&e #% o4 :F
a1etone$
sodi)m
-en*oate$
9ater$ 2!
#ro#anol$
et&anol$ 2!
met&yl!2!
#ro#anol$
a1eti1 a1id$
4ormi1 a1id$
sali1yli1 a1id
and #)re
1y1lo&e8anol
H. 2o 1om#are
t&e e44e1ts o4
str)1t)re and
4)n1tional
gro)#s on
t&e #% o4
organi1
1om#o)nds.
K
I. 2o determine
t&e sol)-ility
o4 sodi)m
-en*oate$
)rea$
-en*oi1 a1id$
#&t&ali1 a1id$
E8#eriment no. "3
SOLUB0L02Y
".1. (eaning
</at)re o4 Sol)-ility
".2. Sol)-ility o4 t&e
4ollo9ing3
a. A1etanilide
-. Ben*oi1 a1id
1. P&t&ali1 a1id
an&ydride
d. Sali1yli1 a1id
e. Sodi)m
-en*oate
4. Urea
g. A1eti1 a1id
&. A1etone
i. Cy1lo&e8ane
5. Et&yl al1o&ol
Demonstration o4 t&e
e8#eriment
E8#erimentation
&o)rs
E8#eriment no. :A
PUR0+0CA20O/
(E2%OD3
EL2RAC20O/
:a.1.
(eaning</at)re o4
E8tra1tion
Demonstration o4 t&e
e8#eriment
E8#erimentation
&o)rs
E8#eriment no. :B3
PUR0+0CA20O/
(E2%OD3
SUBL0(A20O/
:-.1.
(eaning</at)re o4
S)-limation
Demonstration o4 t&e
e8#eriment
E8#erimentation
&o)rs
E8#eriment no. :C3 Demonstration o4 t&e &o)rs
sali1yli1 a1id
and
a1etanilide$
et&yl al1o&ol$
a1etone$
a1eti1 a1id in
9ater
E. 2o 1om#are
t&e e44e1ts o4
str)1t)re and
4)n1tional
gro)#s on
t&e sol)-ility
o4 organi1
1om#i)nds.
K
10. 2o se#arate
-en*oi1 a1d
4rom t&e
mi8t)re.
11. 2o e8#lain
&o9
ele1trolytes
a44e1t
e8tra1tion
12. 2o e8#lain
&o9 m)lti#le
e8tra1tion
a44e1ts t&e
e44i1ien1y o4
e8tra1tion
K
1. 2o se#arate
PUR0+0CA20O/
(E2%OD3
CRYS2ALL0MA20O
/ A/D
DECOLOR0MA20O/
:1.1.
/at)re<(eaning o4
Crystalli*ation
e8#eriment
E8#erimentation
E8#eriment no. :D3
PUR0+0CA20O/
(E2%OD3 S0(PLE
D0S20LLA20O/
:d.1.
/at)re<(eaning o4
Distillation
Demonstration o4 t&e
e8#eriment
E8#erimentation
&o)rs
E8#eriment no. >A3
%YDROCARBO/S3
AL'A/ES
>a.1.
/at)re<(eaning o4
al6anes
Demonstration o4 t&e
e8#eriment
E8#erimentation
&o)rs
E8#eriment no. >B3
%YDROCARBO/S3
AL'E/ES A/D
ARO(A20C
%YDROCARBO/S
>-.1.
/at)re<(eaning o4
Al6enes and
Aromati1
%ydro1ar-ons
Demonstration o4 t&e
e8#eriment
E8#erimentation
&o)rs
E8#eriment no. >C3
%YDROCARBO/S3
Demonstration o4 t&e
e8#eriment
&o)rs
#&t&ali1
an&ydride
4rom t&e
mi8t)re
1". 2o e8#lain
&o9
di44eren1e in
#&ysi1al
#ro#erties
&el# in t&e
1&oi1es o4
#)ri4i1ation
met&od. K
1:. 2o o-tain
#)re -en*oi1
a1id 4rom t&e
mi8t)re
1>. 2o e8#lain
t&e 4a1tors
a44e1ting
1rystalli*atio
n and
de1oloni*atio
n
1H. to e8#lain
&o9
di44eren1e in
rate o4
1rystalli*atio
n a44e1t t&e
#)rity o4 t&e
1rystals. K
1I. to se#aret
AL'Y/ES
>1.1.
/at)re<(eaning o4
Al6ynes
>1.2. Rea1tion o4
al6anes to ignition
and BaeyerDs tests
E8#erimentation
E8#eriment no. H3
ALCO%OLS
H.1.
/at)re<(eaning o4
Al1o&ols
H.2 2&e rea1tions o4
al1o&ols to t&e
4ollo9ing3
a. Sol)-ility in
9ater and in
P&os#&ori1 a1id
-. Sodi)m
1. L)1as
Reagent
d. O8idation o4
Al1o&ols
e. 0odo4orm
Rea1tion
H.. 2&e di44erent
1lassi4i1ation o4
al1o&ols3
a. Primary
-. Se1ondary
1. 2ertiary
Demonstration o4 t&e
e8#eriment
E8#erimentation
&o)rs
E8#eriment no. I3
ALDE%YDES A/D
Demonstration o4 t&e
e8#eriment
&o)rs
'E2O/ES
I.1.
/at)re<(eaning o4
Alde&ydes and
6etones
I.2. 2&e di44eren1e
-et9een alde&ydes
and 6etones )sing
t&e di44erent tests3
a. S1&i44Ds test
-. 2ollenDs test
1. +e&lingDs test
I.. 2&e rea1tion o4
a1etone and
et&anol to 0odo4orm
test.
I.". 2&e rea1tion
4or t&e
a)too8idation o4
-en*alde&yde.
E8#erimentation
E8#eriment no. E3
CARBOLYL0S
AC0DS A/D 02S
DER0.A20.ES
E.1.
/at)re<(eaning o4
Car-o8yli1 a1ids
E.2. 2&e
me1&anism o4 t&e
4ollo9ing3
a. Esteri4i1ation o4
et&anol and a1eti1
-. Rea1tion o4
Demonstration o4 t&e
e8#eriment
E8#erimentation
&o)rs
a1eti1 a1id 9it&
+eCl
1. Rea1tion o4
a1eti1 a1id
an&ydride 9it& %2O
d. Rea1tion o4
Ben*amide 9it&
/aO%
e. Rea1tion o4
Potassi)m O8alate
9it& +e
E8#eriment no. E3
PREPARA20O/
A/D A/ALYS0S O+
SOAP
E.1.
/at)re<(eaning o4
Soa#
E.2. 2&e 4ollo9ing
#ro#erties o4 t&e
soa# #rod)1edNN
Demonstration o4 t&e
e8#eriment
E8#erimentation
&o)rs
E8#eriment no. 113
PREPARA20O/
A/D A/ALYS0S O+
E2%A/OL
11.1.
/at)re<(eaning o4
Et&anol
Demonstration o4 t&e
e8#eriment
E8#erimentation
&o)rs
E8#eriment no. 123
A/ALYS0S O+
ACE20C AC0D
12.1.
/at)re<(eaning o4
A1eti1 a1id
Demonstration o4 t&e
e8#eriment
E8#erimentation
&o)rs
.00. COURSE RECU0RE(E/2S3
Le1t)re3
Attendan1e
Assignments
C)i**es
Le1t)re notes
La-oratory3
Com#ilation o4 La-oratory A1tivities #er gro)#
Post!la-oratory re#orts
D Str)1t)ral model o4 4)n1tional gro)#s ;Prelim?
Soa# ma6ing #rod)1t ;+inals?
.000. RE+ERRE/CES3
Carrey$ +. ;?. Organic Chemistry 6
th
Edition.
Smit&$ @. ,. ;?. Organi1 C&emistry 0nternational Edition.
(1()rry$ @. ;?. +)ndamentals o4 Organi1 C&emistry :
t&
Edition.
,il-ert$ @.$ G (artin$ S. ;?. E8#erimental Organi1 C&emistry 2
nd
Edition.
Solomons$ 2. B. ;?. +)ndamentals o4 Organi1 C&emistry "
t&
Edition.
Pasto et al.$ ;?. E8#eriments and 2e1&ni7)es in Organi1 2e1&ni7)es.