Page: 1 of 8

Dow Corning Toray Co., Ltd.

Material Safety Data Sheet

Revision Date:
MSDS No.:

2010/12/19
02223988

DOW CORNING TORAY SH 780 WHITE

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

:
:
:
:
:
:
:

Product Name
Company Name
Address
Phone Number
Fax Number
Product Code
Emergency Telephone
Number

DOW CORNING TORAY SH 780 WHITE

Dow Corning Toray Co., Ltd.
100-0004, 1-5-1 Otemachi, Chiyoda-ku, Tokyo, Japan
03-3287-8300
(Customer Service)
03-3287-8311
02223988
0436-21-3101

2. HAZARDS IDENTIFICATION
: Serious eye damage/eye irritation: Category 2A
Skin sensitization: Category 1

GHS Classification
GHS Label Elements
Pictogram or Symbol

Signal Word
Hazard Risk Statement
Precautionary Statement
Prevention

Response

Storage
Disposal
Other Hazard

: Warning
: Causes serious eye irritation.
May cause an allergic skin reaction.
: Avoid breathing dust/fume/gas/mist/vapours/spray.
Wear suitable protective clothing, gloves and eye/face protection.
Contaminated work clothing should not be allowed out of the workplace.
Wash hands thoroughly after handling.
Use only outdoors or in a well-ventilated area.
: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
IF ON SKIN: Wash with plenty of soap and water.
If eye irritation persists, get medical advice/attention.
If skin irritation or rash occurs: Get medical advice/attention.
Wash contaminated clothing before reuse.
: Not applicable.
: Dispose of in accordance with local regulations.
: None known.

3. COMPOSITION / INFORMATION ON INGREDIENTS

:
Chemical characterization
:
Generic Name
Ingredients and Contents
CAS
ENCS
Chemical
Number
Number formula

Mixture
Silicone Sealant
Wt %

Component Name

GHS Classification

22984-54-9

(2)-2039

1 - 10

Silica

CH3Si(ON=C(C
H3)(C2H5))3

1 - 10

Methyl tri(ethylmethylketoxime)
silane

Flammable liquid: Category 4

Acute toxicity (Oral): Category 5
Skin corrosion/irritation: Category 2
Serious eye damage/eye irritation: Category 2A
Skin sensitization: Category 1

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Dow Corning Toray Co., Ltd.

Material Safety Data Sheet

Revision Date:
MSDS No.:

2010/12/19
02223988

DOW CORNING TORAY SH 780 WHITE

2224-33-1

(2)-2038

C2H3Si(ON=C(
CH3)(C2H5))3

1 - 10

Vinyltri (methylethylketoxime)
silane

Flammable liquid: Category 4

Skin corrosion/irritation: Category 2
Serious eye damage/eye irritation: Category 1
Skin sensitization: Category 1

1760-24-3

(2)-2083

H2NC2H4NHC3
H6Si(OCH3)3

0.1 - 1

Aminoethylaminopropyltrimethoxys
ilane

Acute toxicity (Oral): Category 5

Acute toxicity (Inhalation - dust and mist): Category
4
Skin corrosion/irritation: Category 3
Serious eye damage/eye irritation: Category 1
Skin sensitization: Category 1
Acute aquatic hazard: Category 2
Chronic aquatic hazard: Category 2

556-67-2

(7)-475

Cycl(Si(CH3)2O)4

0.1 - 1

Octamethylcyclotetrasiloxane

Flammable liquid: Category 3

Reproductive toxicity (Inhalation - vapour): Category
2
Chronic aquatic hazard: Category 4

96-29-7

(2)-546

(CH3)(C2H5)C=
NOH

0.1 - 1

Methylethylketoxime

Flammable liquid: Category 4

Acute toxicity (Oral): Category 5
Acute toxicity (Dermal): Category 4
Serious eye damage/eye irritation: Category 1
Skin sensitization: Category 1
Carcinogenicity: Category 2

Comments

: This product contains the above chemical(s) listed by Japanese regulations and/or classified and
containing not less than cut-off value by GHS.

4. FIRST AID MEASURES

: Remove to fresh air. Get medical attention if ill effects persist.
: Remove from skin and immediately flush with water for 15 minutes. Get medical
attention if irritation or ill effects develop or persist.
: Immediately flush with water for 15 minutes. Get medical attention.
In Case of Eye Contact
: Get medical attention.
In Case of Ingestion
: Treat according to person's condition and specifics of exposure.
Comments
Possible Acute and Chronic Health Effect:
Acute
: Direct contact may cause severe irritation.
Eyes
: May cause mild irritation. Repeated skin contact may cause allergic skin reaction.
Skin
: Irritates respiratory passages very slightly. Vapours evolved during curing may cause
Inhalation
dizziness.
: Low ingestion hazard in normal use.
Ingestion
Chronic
: Repeated or prolonged exposure may cause irritation.
Skin
: Prolonged or repeated exposure by inhalation may injure internally.
Inhalation
: Repeated ingestion or swallowing large amounts may injure internally.
Ingestion
: Long-term or repeated exposure to high concentrations of oxime-silanes may cause
Other Health Hazard
narcotic type effects on the nervous system, harmful effects on the blood (anemia) and
Information
irritate nasal passages, but these effects are reversible and not considered serious.
: Causes serious eye irritation. May cause skin irritation. May cause an allergic skin
Important Symptoms and
reaction.
Hazard Effects
: Use self-contained breathing apparatus (SCBA) or other supplied-air respirator. Use full
Personal Protection for First
face respirator. Wash at mealtime and end of shift. If skin contact occurs, change
Aid or Rescue Personnel
contaminated clothing as soon as possible and thoroughly flush affected areas with cool
water. Chemical protective gloves are recommended.
: Treat symptomatically. For further information, the medical practitioner should contact
Note to physicians
Dow Corning Toray Co.,Ltd.
In Case of Inhalation
In Case of Skin Contact

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Dow Corning Toray Co., Ltd.

Material Safety Data Sheet

Revision Date:
MSDS No.:

2010/12/19
02223988

DOW CORNING TORAY SH 780 WHITE

The above listed potential effects of overexposure are based on actual data, the results of studies performed upon similar compositions, component data, and/or
expert review of the products.

5. FIRE-FIGHTING MEASURES
Extinguishing Media
Unsuitable Extinguishing
Media
Specific Hazards during Fire
Specific Fire Fighting
Protection for Fire-fighter

: On large fires use dry chemical or foam. On small fires use CO2 or dry chemical.
Water can be used to cool fire exposed containers.
: Water. Do not allow extinguishing medium to contact container contents.
: None.
: Determine the need to evacuate or isolate the area according to your local emergency
plan. Use water spray to keep fire exposed containers cool.
: Self-contained breathing apparatus and protective clothing should be worn in fighting
large fires involving chemicals.

6. ACCIDENTAL RELEASE MEASURES

Personal Precautions,
Protective Equipment and
Emergency Procedures
Environmental Precautions
Recovery and Neutralization/
Methods and Materials for
Containment and Cleaning up

: Avoid skin and eye contact. Do not breathe vapour. Do not take internally. Please refer
to section 8 Protective equipment.
: Do not allow large quantities to enter drains or surface waters.
: Observe all personal protective equipment recommendations described in this MSDS. If
diked material can be pumped, store recovered material in appropriate container. Wipe
up or scrape up and contain for salvage or disposal. Clean area as appropriate since
spilled materials, even in small quantities, may present a slip hazard. Final cleaning may
require use of steam, solvents or detergents. Dispose of saturated absorbant or cleaning
materials appropriately, since spontaneous heating may occur. Laws and regulations
may apply to releases and disposal of this material, as well as those materials and items
employed in the cleanup of releases. You will need to determine which laws and
regulations are applicable.

7. HANDLING AND STORAGE

Handling
Technical Measures

Local and General

Ventilation
Precautions
Safe Handling Advice
Avoidance of Contact
Storage
Technical Measures and
Storage Conditions
Packaging Material

: Use with adequate ventilation. Product evolves methyl ethyl ketoxime (MEKO) when
exposed to water or humid air. Provide ventilation during use to control methyl ethyl
ketoxime (MEKO) within exposure guidelines or use respiratory protection.
: Please refer to section 8 Ventilation.
: Avoid skin and eye contact. Do not breathe vapour. Do not take internally.
: Remove contaminated clothing immediately.
: Please refer to section 10 Conditions to Avoid and Materials to Avoid.
: Use reasonable care and store away from oxidizing materials. Keep container closed and
store away from water or moisture.
: None established.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Concentration Control Notification #79 from Ministry of Labor
None known.

Industrial Hygiene Standards

Component Name

Exposure Limits

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Dow Corning Toray Co., Ltd.

Material Safety Data Sheet

Revision Date:
MSDS No.:

2010/12/19
02223988

DOW CORNING TORAY SH 780 WHITE

Methyl tri(ethylmethylketoxime) silane
Vinyltri (methylethylketoxime) silane
Aminoethylaminopropyltrimethoxysilane
Octamethylcyclotetrasiloxane
Methylethylketoxime

See ethyl methyl ketoxime comments.

See ethyl methyl ketoxime comments.
See methyl alcohol comments.
Dow Corning guide: TWA 10 ppm.
Vendor guide: TWA 3 ppm, STEL 10 ppm.

Ethyl methyl ketoxime is formed upon contact with water or humid air. Provide adequate ventilation to control exposures within the following exposure
guidelines: Vendor guide TWA: 3 ppm, STEL: 10 ppm. Methyl alcohol forms on contact with water or humid air. Provide adequate ventilation to control
exposures within guidelines of OSHA PEL: TWA 200 ppm and ACGIH TLV-skin: TWA 200 ppm, STEL 250 ppm.

Engineering Measures
: Recommended.
Local Ventilation
: Recommended.
General Ventilation
Personal Protective Equipment
Personal Protective Equipment for Routine Handling
: Use respiratory protection unless adequate local exhaust ventilation is provided or
Respiratory
exposure assessment demonstrates that exposures are within recommended exposure
protection
guidelines. IH personnel can assist in judging the adequacy of existing engineering
controls.
: Organic Vapor Type.
Suitable Respirator
: Chemical protective gloves should be worn.
Hand protection
: Use proper protection - safety glasses as a minimum.
Eye protection
: Wash at mealtime and end of shift. If skin contact occurs, change contaminated clothing
Skin protection
as soon as possible and thoroughly flush affected areas with cool water. Chemical
protective gloves are recommended.
: Remove contaminated clothing immediately. Exercise good industrial hygiene practice.
Hygiene Measures
Wash after handling, especially before eating, drinking or smoking.
Personal Protective Equipment for Spills
: Use self-contained breathing apparatus (SCBA) or other supplied-air respirator.
Respiratory
protection
: Use full face respirator.
Eye protection
: Wash at mealtime and end of shift. If skin contact occurs, change contaminated clothing
Skin protection
as soon as possible and thoroughly flush affected areas with cool water. Chemical
protective gloves are recommended.
: Avoid skin and eye contact. Do not breathe vapour. Do not take internally. Use
Precautionary Measures
reasonable care.
: Product evolves methyl ethyl ketoxime (MEKO) when exposed to water or humid air.
Comments
Provide ventilation during use to control methyl ethyl ketoxime (MEKO) within
exposure guidelines or use respiratory protection.
Note

These precautions are for room temperature handling. Use at elevated temperature or aerosol/spray applications may require added
precautions.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State
Form
Color
Odour
pH
Melting point/Freezing Point
Boiling point, Initial Boiling
Point, and Boiling Range
Flash Point
Characteristics of Explosives
Vapor Pressure @ 25C

:
:
:
:
:
:

Paste
White
Some odor
Not determined.
Not determined.
Not determined.

: 84 C(Seta Closed Cup)

: Not determined.
: Not determined.

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Dow Corning Toray Co., Ltd.

Material Safety Data Sheet

Revision Date:
MSDS No.:

2010/12/19
02223988

DOW CORNING TORAY SH 780 WHITE

Vapor Density(air=1)
Specific Gravity
Solubility
Octanol/water partition
Autoignition Temperature
Decomposition Temperature
Odour Threshold
Evaporation Rate
Flammability (solid, gas)
Viscosity

:
:
:
:
:
:
:
:
:
:

Not determined.
1.02 g/cm3
Not determined.
Not determined.
Not determined.
Not determined.
Not determined.
Not determined.
Not applicable.
Not determined.

The above information is not intended for use in preparing product specifications. Contact Dow Corning before writing specifications.

10. STABILITY AND REACTIVITY

Stability
Possibility of Hazardous
Reactions
Conditions to Avoid
Materials to Avoid
Hazardous Decomposition
Products

: Stable.
: Hazardous polymerization will not occur.
: None.
: Can react with strong oxidising agents. Water, moisture or humid air can cause
hazardous vapors to form.
: Carbon oxides and traces of incompletely burned carbon compounds. Silicon dioxide.
Formaldehyde. Nitrogen oxides. Metal oxides.

11. TOXICOLOGICAL INFORMATION

Acute Toxicity
Component Name

Acute Toxicity

Methyl tri(ethylmethylketoxime) silane

LD50: > 2,520 mg/kg - Oral Rat

Aminoethylaminopropyltrimethoxysilane

LC50: < 2.44 mg/l - Inhalation Rat; 4hr dust/mist

LD50: 2,295 mg/kg - Oral Rat
LD50: > 2,000 mg/kg - Dermal Rabbit

Methylethylketoxime

LD50: 2,326 mg/kg - Oral Rat

LD50: < 1,800 mg/kg - Dermal Rabbit

Skin Corrosion/ Irritation

Serious Eye Damage/
Irritation
Respiratory Organs
Sensitization or Skin
Sensitization
Germ Cell Mutagenicity
Carcinogenicity

: Please refer to Section 3 and Section 4 Health Effect.

: Please refer to Section 3 and Section 4 Health Effect.
: Please refer to Section 3 and Section 4 Health Effect.

: Please refer to Section 3, Section 4 Health Effect and Section15 ISHL Mutagen
Substance.
:
Component Name
Description
Methylethylketoxime

Reproductive Toxicity
Specific Target Organ.
Systemic Toxicity (Single
Exposure)
Specific Target Organ.
Systemic Toxicity (Repeated
Exposure)

Annex I of EU Directive 67/548/EEC - Carc. Cat. 3 (Substances which cause

concern for man owing to possible carcinogenic effects).

: Please refer to Section 3 and Section 4 Health Effect.

: Please refer to Section 3 and Section 4 Health Effect.

: Please refer to Section 3 and Section 4 Health Effect.

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Dow Corning Toray Co., Ltd.

Material Safety Data Sheet

Revision Date:
MSDS No.:

2010/12/19
02223988

DOW CORNING TORAY SH 780 WHITE

Aspiration Hazard

: Please refer to Section 3 and Section 4 Health Effect.

12. ECOLOGICAL INFORMATION

Ecotoxicity
Environmental Effects
Acute
Chronic
Fate and Effects in
Waste Water Treatment
Plants
Persistence and Degradability
Water
Bioaccumulative Potential
Bioaccumulation
Mobility in Soil

Additional Environmental
Information

: No adverse effects on aquatic organisms are predicted.

: No adverse effects on aquatic organisms are predicted.
: No adverse effects on bacteria are predicted.

: Solid material, insoluble in water.

: No bioaccumulation potential.
: This product is a solid and does not contain significant concentrations of water soluble
constituents that may be leached from the product. It is therefore not likely to present a
danger to terrestrial organisms.
: No specific information is available.

13. DISPOSAL CONSIDERATIONS

Residual Waste
Contaminated Containers or
Packaging
Note

: This product falls under Industrial Waste based on Wastes Disposal and Public
Cleansing Law. Dispose of in accordance with local regulations.
: Dispose of in accordance with local regulations.
: None.

14. TRANSPORT INFORMATION

: Refer to Section 15.
Local Regulations
International Regulations
Sea Transport (IMDG)
Not subject to IMDG code.
Air Transport (IATA)
Not subject to IATA regulations.

15. REGULATORY INFORMATION

: This product is not applied into the code about Specified Chemical Substances,
Law Concerning Examination
Monitoring Chemical Substances and Designated Chemical Substances.
and Regulation of
Manufacture, etc. of Chemical
Substances
Industrial Safety and Health Law
: Specific
Notification Substance
Notification Component(s)
Wt %
Number
312

Indication Substance

: Not applicable.

Silica

1 - 10

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Dow Corning Toray Co., Ltd.

Material Safety Data Sheet

Revision Date:
MSDS No.:

2010/12/19
02223988

DOW CORNING TORAY SH 780 WHITE

:
Ordinance on Prevention
of Organic Solvent
Poisoning
:
Ordinance on Prevention
of Hazards due to
Specified Chemical
Substances
:
Ordinance on Prevention
of Lead Poisoning
:
Ordinance on Prevention
of Tetraalkyl Lead
Poisoning
:
Hazardous Material
:
Banned Substance
:
Mutagen Substance
:
Carcinogen Substance
:
High Pressure Gas Safe Law
:
Fire Service Law
:
Poisonous and Deleterious
Substance Control Law
Pollutant Release and Transfer :
Register
:
Marine Pollutant Prevention
Law
Chemical Inventories
TSCA
:
EINECS
AICS
IECSC
ENCS/ISHL
KECL
PICCS
DSL

:
:
:
:
:
:
:

Not applicable.

Not applicable.

Not applicable
Not applicable

Not applicable.
Not applicable
Not applicable.
Not applicable.
Not applicable.
DESIGNATED FLAMMABLE SUBSTANCES, FLAMMABLE SOLIDS (3,000kg)
Not applicable.
Not applicable.
Not Classified as a Marine Pollutant

All chemical substances in this material are included on or exempted from listing on the
TSCA Inventory of Chemical Substances.
All ingredients listed or exempt.
All ingredients listed or exempt.
All ingredients listed or exempt.
All components are listed on ENCS/ISHL or its exempt rule.
All ingredients listed, exempt or notified.
All ingredients listed or exempt.
All chemical substances in this material are included on or exempted from the DSL.

16. OTHER INFORMATION

Bibliography: Statue book of chemicals, Internal Technical Data and others
JAMP MSDSplus
Substance Information

This is based on MSDSplus(Ver.3.1) by JAMP(Joint Article Management Promotionconsortium).

This product doesnt contain object substances listed the following regulations.
The objects of investigation are the followings. Substances are applied to the regulation
for JP01, JP02, or JP03. They are contained intentionally or their concentration is more
than or equal to the cutoff value for EU01 or EU02. Their concentration is more than or
equal to 0.1% for EU03, EU04, or EU05. OT01, IA01, IA02 are not a subject of
investigation.

Relevant Standard
Code

Relevant Standard

JP01

Japanese Chemical Substances Control Law (Class I

Specified Chemical Substances)

Issued or
revised
2009-10-30

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Dow Corning Toray Co., Ltd.

Material Safety Data Sheet

Revision Date:
MSDS No.:

2010/12/19
02223988

DOW CORNING TORAY SH 780 WHITE

JP02
JP03
EU01
EU02
EU03

Industrial Safety and Health Act (Substances

Prohibited of Manufacturing etc.)
Poisonous and Deleterious Substance Control Law
(Specified Poisonous Substances)
RoHS Directive
ELV Directive
CLP Annex VI CMR-Cat1,2

2007-09-07
2007-08-15

2002/95/EC
2000/53/EC
EC No
1272/2008,
ATP1
included
EU04
REACH Annex XVII [Except EU03]
EC No
552/2009
EU05
REACH SVHC on the Candidate List
2010-01-13
Substances do not directly mean legally regulated. It depends on use and other
conditions. For more information please refer to "How to make JAMP MSDSplus".

These data are offered in good faith as typical values and not as product specifications. They are believed accurate as of the date
of this Material Safety Data Sheet based on a review of current composition and information supplied by vendors. No warranty,
either expressed or implied, is hereby made. The recommended industrial hygiene and safe handling procedures are believed to
be generally applicable. However, each user should review these recommendations in the specific context of the intended use
and determine whether they are appropriate. This Product has been developed and manufactured for general industrial use. For
medical use, or other uses where safety considerations may be required, you must in advance test and review the safety of your
intended application. Moreover, this Product is not for human implant nor human injection, nor use for applications which may
present risk of accumulating inside human bodies.

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