substance At the start I have studied.. I have revised 10-11 I understand the terms atom, element, ion, molecule, compound, empirical & molecular formula (1.3a) 1 2 3 1 2 3 1 2 3 12-13 I can write balanced equations (full & ionic) for simple reactions, including the use of state smbols 1.3b) 1 2 3 1 2 3 1 2 3 1!-1" 1#-1$ I understand the terms relati%e atomic mass, amount of substance, molar mass & parts per million (ppm) 1.3c) 1 2 3 1 2 3 1 2 3 2!-2" I can calculate the amount of substance in a solution of &nown concentration 1.3d) 1 2 3 1 2 3 1 2 3 1'-1( I can use chemical equations to calculate reacting masses & %ice %ersa using the concepts of amount of substance and molar mass1.3e) 1 2 3 1 2 3 1 2 3 20-21 I can use chemical equations to calculate %olumes of gases & %ice %ersa using the concepts of amount of substance and molar %olume of gases 1.3f) 1 2 3 1 2 3 1 2 3 30-31 I can use chemical equations & e)perimental results to deduce percentage ields & atom economies in laborator and industrial processes and understand wh the are important1.3g) 1 2 3 1 2 3 1 2 3 1#-1$ I understand, and can carr out, calculations using the *%ogadro constant 1.3h) 1 2 3 1 2 3 1 2 3 22-23 2'-2( I can analse & e%aluate results obtained from finding a formula or confirming an equation b e)periment, e+g+ the reaction of lithium with water and deducing the equation from the amounts in moles of lithium and hdrogen 1.3i) 1 2 3 1 2 3 1 2 3 30-31 I can ma&e a salt & calculate the percentage ield of product, e+g+ preparation of a double salt (ammonium iron (II) sulphate from iron, ammonia and sulphuric acid) 1.3!) 1 2 3 1 2 3 1 2 3 2'-2( I can carr out & interpret results of simple test tube reactions, such as replacements, reactions of acids, precipitations, to relate the obser%ations to the state smbols used in equations and to practise writing full and ionic equations 1.3") 1 2 3 1 2 3 1 2 3 pages Chapter 1.# $nergetics At the start I have studied.. I have revised 32-33 3!-3" I understand the term enthalp change, ,- 1.%a) 1 2 3 1 2 3 1 2 3
.de)cel */ 0hemistr 1arget sheet 2nit 1 3!-3" I can construct simple enthalp le%el diagrams showing the enthalp change 1.%b) 1 2 3 1 2 3 1 2 3 3!-3" I can recall the signs for ,- e)othermic and endothermic reactions, eg illustrated b the use of e)o- and endothermic reactions in hot and cold pac&s 1.%c) 1 2 3 1 2 3 1 2 3 3#-3( I &now the definitions of standard enthalp changes of reaction, formation, combustion, neutrali3ation & atomi3ation and can use e)perimental data to calculate energ transferred in a reaction and hence the enthalp change of the reaction 1.%d) 1 2 3 1 2 3 1 2 3 !2-!" I &now -ess4s 5aw & can appl this to calculating enthalp changes of reaction from data pro%ided, selected from a table of data or obtained from e)periments+ I understand wh standard data is necessar to carr out calculations of this tpe 1.%e) 1 2 3 1 2 3 1 2 3 3#-3( !#-!$ I can e%aluate the results obtained from e)periments using the e)pression6 energ transferred in 7oules 8 mass ) specific heat capacit ) temp change+ I can comment on sources of error and assumptions made in the e)periments 1.%f) 1 2 3 1 2 3 1 2 3 !'-!( I understand the terms bond enthalp and mean bond enthalp, and can use bond enthalpies in -ess ccle calculations and recognise their limitations 1.%g) 1 2 3 1 2 3 1 2 3 !'-!( I understand that bond enthalp data gi%es some indication about which bond will brea& first in a reaction, how eas or difficult it is and therefore how rapidl a reaction will ta&e place at room temperature 1.%g) 1 2 3 1 2 3 1 2 3 pages Chapter 1.3 Atomic structure and the periodic table At the start I have studied.. I have revised "2-"3 I &now the definitions of relati%e atomic mass, relati%e isotopic mass & relati%e molecular mass and understand that the are measured relati%e to 1912 mass 12 0 atom (1.&a) 1 2 3 1 2 3 1 2 3 "2-"3 I understand the basic principles of a mass spectrometer & can interpret data to i) determine isotopic comp of a sample of an element, e+g+ polonium ii) deduce relati%e atomic mass of an element iii) measure relati%e molecular mass of a compound1.&b) 1 2 3 1 2 3 1 2 3 "#-"( I can describe some uses of mass spectrometers, e+g+ in radioacti%e dating, in space research, in sport to detect the use of anabolic steroids, in the pharmaceutical industr to pro%ide and identifier for compounds snthesised for possible identification as drugs1.&c) 1 2 3 1 2 3 1 2 3 #2-#3 I understand the definition of ioni3ation energies of gaseous atoms :and that the are endothermic processes1.&d) 1 2 3 1 2 3 1 2 3 #2-#3 I can recall ideas about electronic structure de%eloped from i) an understanding that successi%e ioni3ation energies pro%ide e%idence for the e)istence of quantum shells and the group to which the elements belong, ii) an understanding that the first ioni3ation energ of successi%e elements pro%ides e%idence for electron sub shells1.&e) 1 2 3 1 2 3 1 2 3 ##-#$ I can describe the shapes of electron densit plots (or maps) for s and p orbitals1.&f) 1 2 3 1 2 3 1 2 3 #!-#" I can predict electronic structure and configuration of atoms of the elements from hdrogen to &rpton inclusi%e using 1s;notation and electron in-bo)es notation (recall electrons populate orbits singl before pairing up) 1.&g) 1 2 3 1 2 3 1 2 3 #'-$3 I understand that electronic structure determines the chemical properties of an element1.&h) 1 2 3 1 2 3 1 2 3 #'-$3 I &now that the periodic table is di%ided into bloc&s such as s, p and d1.&i) 1 2 3 1 2 3 1 2 3 $!-$$ I can represent data for the elements in graphical form for elements 1 to 3# and use this to e)plain the meaning of the term <periodic propert=1.&!) 1 2 3 1 2 3 1 2 3 $!-$$ I can e)plain trends from periods 2 & 3 i) melting temp of elements based on gi%en data using the structure and the bonding between the atoms or molecules of the element ii) ioni3ation energ based on gi%en data or recall of the shapes of the plots of ionisation energ %ersus atomic number using ideas of electronic structure and the wa that electron energ le%els %ar across the period1.&") 1 2 3 1 2 3 1 2 3 pages Chapter 1.% 'onding At the start I have studied.. I have revised 1 ionic bonding $'-$( '2-'3 I can recall & interpret e%idence for the e)istence of ions b reference to the phsical properties of ionic compounds, electron densit maps & migration of ions, e+g+ electrolsis of aqueous copper chromate (>I) 1.(.1a) 1 2 3 1 2 3 1 2 3 $'-$( I can describe the formation of ions in terms of electron loss or gain 1.(.1b) 1 2 3 1 2 3 1 2 3 $'-$( I can draw electron configuration diagrams of cations and anions using dots or crosses to represent electrons 1.(.1c) 1 2 3 1 2 3 1 2 3 '0-'1 I can describe ionic crstals as giant lattices of ions 1.(.1d) 1 2 3 1 2 3 1 2 3 $'-$( I can describe ionic bonding as the result of strong net electronic attraction between ions 1.(.1e) 1 2 3 1 2 3 1 2 3 '0-'1 I can recall trends in ionic radii down the group and for a set of isoelectronic ions , e+g+ ? 3- to *l 3@ 1.(.1f) 1 2 3 1 2 3 1 2 3 A I can recall the stages in the formation of a solid ionic crstal from its elements & &now that this leads to a measure %alue for the lattice energ 1.(.1g) 1 2 3 1 2 3 1 2 3 '!-'" I can test the ionic model for ionic bonding of a particular compound b a comparison of lattice energies obtained from the e)perimental %alues in Born--aber ccles, with pro%ided %alues calculated from electrostatic theor 1.(.1h) 1 2 3 1 2 3 1 2 3 '#-'$ I can e)plain the meaning of the term polari3ation as applied to ions 1.(.1i) 1 2 3 1 2 3 1 2 3 '#-'$ I understand that the polari3ing power of a cation depends on its radius and charge, and polari3aribilit of an anion depends on its si3e 1.(.1!) 1 2 3 1 2 3 1 2 3 '#-'$ I understand that the polari3ation of anions b cations leads to some co%alenc in an ionic bond, based on e%idence from Born--aber ccles 1.(.1") 1 2 3 1 2 3 1 2 3 '!-'" I can use %alues calculated for standard heats of formation based on Born--aber ccles to e)plain wh particular ionic compounds e)ist, eg the relati%e stabilit of Cg0l2 o%er Cg0l or Cg0l3 and ?a0l o%er ?a0l2 1.(.1l) 1 2 3 1 2 3 1 2 3 # covalent bonding (0-(1 I can demonstrate an understanding that co%alent bonding is strong & arises from the electrostatic attraction between the nucleus & electrons which are between nuclei, based on the e%idence6 i ) the phsical properties of giant atomic structures ii) electron densit maps for simple molecules 1.(.#a) 1 2 3 1 2 3 1 2 3 ''-(1 I can draw electron configuration diagrams for simple co%alentl bonded molecules including those with multiple bonds and dati%e co%alent bonds, using dots or crosses to represent electrons 1.(.#b) 1 2 3 1 2 3 1 2 3 3 metallic bonding (2-(3 I understand that metals consist of giant lattices of metal ions in a sea of delocalised electrons 1.(.3a) 1 2 3 1 2 3 1 2 3 (2-(3 I can describe metallic bonding as the strong attraction between metal ions and the sea of delocalised electrons 1.(.3b) 1 2 3 1 2 3 1 2 3 (2-(3 I can use the models in 1+#+3a and 1+#+3b to interpret simple properties of metals e+g+ conducti%it & melting temperatures 1.(.3c) 1 2 3 1 2 3 1 2 3 pages Chapter 1.& Introductor) organic chemistr) At the start I have studied.. I have revised 100-103 I understand that a series of organic compounds is characterised b a general formula with one or more functional groups 1.*.1a) 1 2 3 1 2 3 1 2 3 100-103 I can appl the rules of I2D*0 nomenclature to organic compounds and draw these compounds, as I encounter them, using structural, displaed & s&eletal formulae 1.*.1b) 1 2 3 1 2 3 1 2 3 (!-(( I appreciate the difference between ha3ard and ris& 1.*.1c) 1 2 3 1 2 3 1 2 3 (!-(( I understand the ha3ards associated with organic compounds and wh it is necessar to carr out ris& assessments when dealing with potentiall ha3ardous materials 1.*.1d) 1 2 3 1 2 3 1 2 3 (!-(( I can suggest was that ris& can be reduced and reactions can be carried out safel b6 i) wor&ing on a smaller scale ii) ta&ing specific precautions or using alternati%e techniques depending on properties of substances in%ol%ed carring out reaction using alternati%e method that in%ol%es less ha3ardous substances 1.*.1d) 1 2 3 1 2 3 1 2 3 pages Chapter 1.( +he Al"anes At the start I have studied.. I have revised 10!-10" I can state the general formula of al&anes and understand that the are saturated hdrocarbons which contain single bonds onl 1.*.#a) 1 2 3 1 2 3 1 2 3 10#-10$ I can e)plain the e)istence of structural isomers using al&anes (up to 0") as e)amples 1.*.#b) 1 2 3 1 2 3 1 2 3 10'-113 I &now that al&anes are used as fuels and obtained from the fractional distillation, crac&ing and reformation of crude oil 1.*.#c) 1 2 3 1 2 3 1 2 3 120-123 I can discuss the reasons for de%eloping alternati%e fuels in terms of sustainabilit & reducing emission of 0E2 & its relationship to climate change 1.*.#d) 1 2 3 1 2 3 1 2 3 11!-11$ 11'-11( I can describe the reactions of al&anes in terms of combustion, substitution b chlorine showing the mechanism of free radical substitution in terms of initiation, propagation and termination, and using curl half-arrows in the mechanism to show the formation of free radicals in the initiation step using a single dot to represent the unpaired electron 1.*.#e) 1 2 3 1 2 3 1 2 3 ,ages Chapter 1.* +he al"enes At the start I have studied.. I have revised 12!-12' I can state the general formula of al&enes and understand that the are unsaturated hdrocarbons with a carbon-carbon double bond which consists of a F and a G bond 1.*.3a) 1 2 3 1 2 3 1 2 3 12!-12' I can e)plain .-H isomerism (geometric 9cis9trans isomerism) in terms of restricted rotation around a 080 double bond and the nature of substituents on the carbon atoms 1.*.3b) 1 2 3 1 2 3 1 2 3 12!-12' I can show an understanding of the .- H- naming sstem and wh it is necessar to use this when the cis- trans- naming sstem brea&s down 1.*.3c) 1 2 3 1 2 3 1 2 3 12(-131 I can describe the addition reactions of al&enes, limited to6 i) addition of hdrogen with nic&el catalst to form al&ane ii) addition of halogens to produce di- substituted halogenoal&anes iii) addition of hdrogen halides to produce mono-substituted halogenoal&anes i%) o)idation of the double bond b potassium manganate (>II) to produce a diol 1.*.3d) 1 2 3 1 2 3 1 2 3 132-133 I can describe the mechanism (including diagrams), gi%ing e%idence where possible of6 i) electrophillic addition of bromine and hdrogen bromide to ethane ii) the electrophillic addition of hdrogen bromide to propene 1.*.3e) 1 2 3 1 2 3 1 2 3 12(-131 I can describe the test for presence of 080 using bromine water and understand that the product is the addition of E- and Br 1.*.3f) 1 2 3 1 2 3 1 2 3 13!-13" I can describe addition polmeri3ation of al&enes and II the repeat unit gi%en the monomer and %ice %ersa 1.*.3g) 1 2 3 1 2 3 1 2 3 13#-1!1 I can interpret gi%en information about the uses of energ and resources o%er the life-ccle of polmer products to show how the use of renewable resources, reccling and energ reco%er can contribute to more sustainable use of materials 1.*.3h) 1 2 3 1 2 3 1 2 3