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AITS-CRT-IV-PCM (Sol)-JEE (Mai n)/14

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1





ANSWERS, HINTS & SOLUTIONS
CRTIV
(Main)




Q. No. PHYSICS CHEMISTRY MATHEMATICS
1.
A D D
2.
B B B
3.
D C C
4.
D A D
5.
C B B
6.
C B A
7.
A D C
8.
A A C
9.
B B C
10.
C D B
11.
A A A
12.
C C D
13.
D C A
14.
B A C
15.
A A A
16.
A A B
17.
D C C
18.
C B B
19.
D B D
20.
A B C
21.
B A A
22.
B D C
23.
D B A
24.
C C A
25.
C A D
26.
A D C
27.
D A B
28.
C D C
29.
C A D
30.
B B B
A
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AITS-CRT-IV-PCM (Sol)-JEE (Mai n)/14
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2
P P h hy ys si i c cs s PART I


SECTION A

1.


2. 2.4 km downstream from the point directly opposite to 0

3. rate of change of speed
=tangential component of acceleration
(component of acceleration in the direction of velocity)

2

3i 3j 6 4

a. v (2i j) . 2m/ s
5 5

| |
+ +
= = + = =
|
|
\ .






4. Force is always perpendicular to velocity

5. elementary mass =x dy
x =R cosu, y =R sinu
dy =R cosu du
elementary mass =o (Rcosu) (Rcosu du)
=oR
2
cos
2
u du

/2
2 2
0
an
/2
2 2
0
Rcos R cos d ydm
y
.dm
R cos d
t
t
u o u
= =
o u u
} }
}
}


4
R
3
=
t



6. Let the block is in translational equilibrium and ready to
topple.
] =F
N =mg
Taking torque about C.O.M. =0

a a a
F N
2 2 2
| | | | | |
+ =
| | |
\ . \ . \ .
f
2F =N

F
N
mg
]=F
u
R
x
y
y
x

n
a

t
a

v

For maximum
1N 3N 9N 10N 23N
A triangle is possible with sides 4 unit, 9 unit and 10 unit. Hence minimum
resultant is zero.
3N 1N
9N
10N

AITS-CRT-IV-PCM (Sol)-JEE (Mai n)/14
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3

N
F
2
=

N
2
= f
but N s f

N
N
2
s

1
2
>
7.
o
o
s
V V
V V
| |
=
|

\ .
f f .
Here, V
o
=u +at
V
s
=0
] varies linearly with t.

8. As long as cylinder is completely inside, B is constant in magnitude, then its value decreases
linearly with displacement and finally becomes zero.

9.


( )
2
2
n
5
V
R 5 5m
1
a
5
= = =

10. Applying work-energy theorem w.r.t wedge

19.
( )
0 0 0 0
P
kq kq kq 3kq
V
2a a a / 2 2a
= + = .
20. Pitch =
1.5
0.3
5
= mm
Least count =
0.3
0.006
50
= mn

21.
1 1 2 2
mv mv =

2 1 1 2
v mv / m = (1)

2 2
2 1 1 2
2
2
a 1 1
mg mv mv
2 2
kx
2 2
1
= + (2) From work energy theorem
Substituting (1) in (2) and solving

2
2 2
1
1 1 2
m(ka 4 mga)
v
4m(m m )

=
+
=10 cm/s

22. Mechanical energy loss happens due to viscous/frictional forces without which the liquid will
oscillate. This is released as heat
1/ms
at t =0
at t =1sec
5

1/ms
2/ms
1m/s
2

1m/s
2


AITS-CRT-IV-PCM (Sol)-JEE (Mai n)/14
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4
23.
2
3
GMm
mr
r
e =

3 2
GM r = e (GM =gr
2
)

3 2
2
r .
g
R
e
=

3 2
2 2
(4nR) .
g
n .R
e
=

2
g 64nR = e .

24. Frequencies are in odd ratio hence it is a closed organ pipe.

v
freq (2n 1)
4L
= +

2v
(frequency) 100Hz
4L
A = =
L =1.7 m.

25. For maximum elongation charges on the blocks must be equal to
Q
2
on each block.

2
2
0 0
Q
1 2
kx
4 ( x)
| |
|
\ .
=
tc +


0 0
Q 2( x) 4 kx = + tc .

26. Number of emitted electrons
12 4
5
10 2 10 25
10


= =5 10
4
electrons
q =+ne =8 10
15
C.

27.
3 6
R 2
3 6

= O = O
+


1 2
1 1 1
R R R
= +
1 2
2 2 2
1 2
dR dR dR
R R R
= +
% error =
R
100%
R
A

=
1 2
1 1 2 2
R R 1 1
R 100 100 %
R R R R
| | A A
+
|
\ .

=
1 1
2 1 2 %
3 6
| |
+
|
\ .

=
4
%
3


28. As V increases, E increases,
min
decreases,
Ko
remains constant so (
Ko

min
) increases

29. Increasing the filament current increases the intensity because more electron
now strike the target. Decreasing the potential difference increases the minimum wavelength.

30.
( )
5
9
1.6 1 1.8 10
900 10

=12

AITS-CRT-IV-PCM (Sol)-JEE (Mai n)/14
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5
C Ch he em mi i s st tr r y y PART II


SECTION A

1.

C H
3
HC
OEt
OEt
(p) (Acetal)
3
H O
3
CH CHO
+



: differentiated by Na, Fehling and Tollens test

( )
3
H O
3 2 2 3
CH CH O CH CH EtOH; differentiatedby Na,Fehling andTollen's test
q
+



2.

Ag / AgX / X
E =

Ag / Ag
E + + Ksp ln
F
RT


3. Compounds with more covalent nature, was unable to respond to chromyl chloride test SnCl
4
,
due to mole polarizing power of Sn
+4
the compound is more covalent.

5.
| |
| | | |
2
3
c 2
2 2
SO
K
SO O
=

| |
c
2
1
K 100
O
= =
[O
2
] =10
2


2
n
10
10

=
n =0.1

6.
2
2
1
2
1
1
2 1
T
V P
T
V P
T
V 2 P
n n n + = = + =

8. x
A
=0.3 , x
B
=0.7

T
B
B
T
A
A
P
P
y ,
P
P
y = =

2
7
x P
x P
2
3
4 . 0
6 . 0
y
y
B B
A A
B
A
= = = =



9. RbCl and KCl have rock salt structure
5 . 0 a a
KCl RbCl
=
( ) ( ) 5 . 0 r r 2 r r 2
Cl K Cl Rb
=
+ +

Hence

A 33 . 1 r
K
=
+


11. Intramolecular aldol condensation.

12. Perkinss reaction

AITS-CRT-IV-PCM (Sol)-JEE (Mai n)/14
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13. Bromination of benzylic carbon followed by hydrolysis

14. Hoffmann elimination, least stable alkene will be the major product.

16. |-Hydroxy compound is easily dehydrated.

17.
2 2
2AB (g) 2AB(g)+B (g)
1 0 0
1- x x x/ 2


Total moles =1 x +x +x/2 =1 +x/2.

( ) ( )
( )
2
p 2
x 2 x
p
k =
1+x/ 2
1- x
| |
|
\ .
[ x is small, 1-x =1 and 1 +x/2 =1].

( )
1 3
3
p p p
x p
k = x = 2k P = 2k P
2


19. At constant pressure, the addition of inert gas shifts the equilibrium towards larger no. of moles.

20. The hybridisation of B in
3
BBr is
2
sp that C in
2
CS is sp, that of S in
2
SO is
2
sp while that of
S in
4
SF is
3
sp d. Hence
2
CS has the maximum bond angle of 180.

27.
3 2 3 2
NaHCO NaOH Na CO H O + +

28. For a bcc lattice

o
X 0.4
0.732 Y 0.546A
Y 0.732
+

= = =
Now, for fcc lattice,

Z
0.414 Z Y 0.414
Y
+
+

= =
=0.546 0.414
=0.226
o
A
29.
C
O
H
C
O
Ph
O
H
C
O
Ph
(I)
O
C
H
Cl
C H Cl
Cl HO
(II)
C
C
O
O
C
H
O
O
H
(III)
H C
O
O
H
H
H
(V)


30. Hint: It is Acyl Cleavage








AITS-CRT-IV-PCM (Sol)-JEE (Mai n)/14
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7
M Ma at th he em ma at ti i c cs s PART III


SECTION A

1. f(x) =f(x)
x
n
=(x)
n


2.
a
a
x
log x
lim
x

0 and
x
x
a
a
lim
log x


3. g(x) =cos (x) ||x| 1|, x e R

4.
dv rdh 2hdr
r
dt dt dt
| |
= t +
|
\ .


5. f(x) =
4 3 2
ax bx cx
dx
4 3 2
+ + +
f(0) =0, f(1) =
a b c
d 0
4 3 2
+ =

6. h(x) =f
2
(x) +(f'(x))
2

h'(x) =2x(f'(x))
2
g(x)

7. Let F be the fuel charges. Then,
2
3v
F
16
=
Let train covers kms. Then, total cost for running the train,
3v
C 300
16 v

= +
For
dc
0
dv
= and
2
2
d c
0
dv
>
v =40 km/hr

8. For maximum or minimum, f'(x) =0
x
2
+8x (12 +t) =0
t <4

9. AD divides BC in ratio AB : AC
So, P.V. of D =
( ) ( )

AB 2i 5j 7k AC 2i 3j 4k
AB AC
+ + + + +
+



10. Required vector
1 2
r x b x c = +


and ( )
2
r a a
3
=


( ) ( )
1 1

r 2i j x 2 k 4 x = +

, where x
1
e R

12.
| |
2
r a x a b c =


,
| |
3
r b x b c a =


,
| |
1
r c x c a b =




13. Equation of line x +2y +z 1 +(x +y 2z 2) =0

AITS-CRT-IV-PCM (Sol)-JEE (Mai n)/14
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8
x +y 2 +(x +z 2) =0
(0, 0, 1) lies on it
=0, =2
For point of intersection, z =0

14. Equation of lines, (y mx) +, (z c) =0
(y +mx) +
2
(z +c) =0
It meets at xaxis, hence
1
=
2

cy =mzx

15. Slope of reflected ray =
3
4

Equation of incident ray is (y +4) =
( )
3
x 2
4
+ i.e., 4y +3x +22 =0

16. Required area =4(Area of AS
2
OS
4
) =
1
1
4 ae 8be
2


17.
( ) ( )
1 1 1 1
r r 1 r r 1
sin tan tan r tan r 1
r r 1 1 r r 1

| | | |

= = | |
| |
+ +
\ . \ .


18.
2 2 2
1 1
AG 2b 2c a a
3 3
= + = ;
2 2
1
BG b 4c
3
= +

( ) ( )( )
1
GAB
AG BG AB 5 13
R
4 12
= =
A


19. z
n
1 =(z 1)(z z
1
)(z z
2
) .. (z z
n 1
)
Differentiating w.r.t. x

n 1
n
n 1
nz 1 1 1
.....
z 1 z 2 z z z 1

= + + +



20.
( ) ( )
r
1 1 1
T
2 1 3 5 ..... 2r 1 1 3 5 ..... 2r 1
| |
=
|
+ \ .


22.
( )
1 cosx cosx
sinx 2cosx 0 sinx cosx 0 0
0 0 sinx cosx
A = + =


tan x =2 or tan x =1

23. Required area =
( ) ( )
2
x 2
0
2 2x x dx
}


(0, 1)
y
(2, 4)
x' x
y'
O (2, 0)


26. Combined mean =16; d
1
=9; d
2
=6

AITS-CRT-IV-PCM (Sol)-JEE (Mai n)/14
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( ) ( )
2 2 2 2
1 1 1 2 2 2 2
1 2
n d n d
67.2
n n
o + + o +
o = =
+


27. 1 s 1 +sin
3
x s 2
I
2 2 2
t t
s s

28.
dy
xy
dx
x e =

lnx
ydy dx
x
=
} }


( )
2
y lnx c = +

29. Let A(o, 0) and B(|, 0) be the two points
OT
2
=OAOB =o| =
c
a


30.
( )
18
1 x
f x
1 x

=
+


( )
( )
18
1 x 1
f x 1
x

=