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Document number Revision Date of revision

HSE-PLN-028 2 01/07/2014



Laurel Formation Tight Gas Pilot Exploration
Program (TGS14)
Environment Plan Summary Document


TGS14 EP Summary Document_Rev_2 Buru Energy Limited 1
1. INTRODUCTION
Buru Energy Exploration wells approved by the Western Australian Department of Mines and
Petroleum (DMP) and drilled in the Laurel Formation in 2011 to 2013 have shown commercial
indications of both conventional and tight gas. These wells have been suspended under approval from
the DMP. Further exploration operations are required to determine the commercial prospectivity of this
petroleum resource during the tenure of the Companys exploration permits. These exploration
Activities involve the stimulation of the reservoir using a process called hydraulic fracturing (HF) or
fraccing. A number of notable international reviews have concluded that the potential risks to human
and environmental health associated with tight gas are low if the operations are properly run and
regulated.
Buru Energy (the Company) has developed the Laurel Formation Tight Gas Pilot Exploration Program
(TGS14) Environment Plan (HSE-PLN-017) to identify the potential environmental impacts associated
with the Activity and set out the mitigation and management measures to ensure that environmental
impacts and environmental risks associated with the Activity will be of an acceptable level and
reduced to as low as reasonably practicable (ALARP). This summary document provides an
overview of the Activities that will occur and summarises the mitigation and management measures in
the TGS14 Environment Plan (EP). A separate Operations Pan and Safety Plan have also been
prepared and approved by the DMP for this Activity.
1.1. Contact Details
Contact details for the Company are:
Chief Scientist
Buru Energy Limited
Phone: +61 8 9215 1800
Fax: +61 8 9215 1899
Email: info@buruenergy.com


2. OVERVIEW OF ACTIVITY
TGS14 Activities will be undertaken at four existing well sites in the Canning Basin, namely Valhalla
North 1, Asgard 1, Yulleroo 3 and Yulleroo 4.
2.1. Location
The four well sites where TGS14 Operations will occur are shown in Figure 1 below. The location of
these well sites and associated exploration permit are included in Table 1.
Table 1: Details of existing wells and well sites where TGS14 Operations will occur.
Well Site Exploration
Permit Area
Easting Northing Existing Well
Total Depth (m)
Valhalla/Asgard Region
Valhalla North 1 EP371 R1 683112 8006105 3,344
Asgard 1 EP 371 714726 7981294 3,524
Yulleroo Region
Yulleroo 3 EP 391 R2 488510 8026425 3,712
Yulleroo 4 EP 436 R1 487081 8028803 3,846



TGS14 EP Summary Document_Rev_2 Buru Energy Limited 2

Figure 1: Location of existing well sites where TGS14 Activities will occur.

The proximity of each of the well sites from the nearest town and protected areas (e.g. ESA) is shown
in Table 2.
Table 2: Proximity of each well site from the nearest town and protected area.
Well Site Nearest Town Nearest ESA
Yulleroo 3 Yulleroo 3 is located 72 km
east of Broome
Yulleroo 3 is located 6.5 km S of Taylors
Lagoon
Yulleroo 4 Yulleroo 4 is located 72 km
east of Broome
Yulleroo 4 is located 4 km S of Taylors
Lagoon
Valhalla North 1 Valhalla North 1 is located
90 km WNW of
Fitzroy Crossing
Valhalla North 1 is located 24 km E of
Camballin Floodplains
Valhalla North 1 is located 25 km ENE
of West Kimberley National Heritage
Place
Asgard 1 Asgard 1 is located 56 km
WSW of Fitzroy Crossing
Asgard 1 is located 57 km ESE of
Camballin Floodplains
Asgard 1 is located 19 km N of the West
Kimberley National Heritage Place
Yulleroo 3 is located 2.8 km as the crow flies from the Yulleroo 4 well site and 5 km by track. Valhalla
North 1 is located 40 km as the crow flies from the Asgard 1 well site and 55 km by track.



TGS14 EP Summary Document_Rev_2 Buru Energy Limited 3
2.1. Stages of Works and Timing
The stages of works and timing that will be undertaken during the TGS14 Program include the
following:
Stages of
Work
Job Steps Indicative
Timing/
Duration
Site setup filling of the water retention ponds, Mobilisation and
site
establishment
to occur
indicatively from
May-August
2014.
establishing bunded storage areas for storage of hazardous
substances, fuel storage areas and refuelling,
establishment of a bulk materials handling area for sand proppant
storage,
establish a site office and camp site with amenities,
mobilise equipment, personnel and supplies.
HF
Operations
rig up and pressure test the well, Between 10 and
26 days at each
site depending
on number of
stages.
conduct wireline and slickline operations and perforate the steel
casing at selected intervals in the well,
set up, connect and test well stimulation equipment,
conduct HF operations at each of the well sites, monitor and
report,
rig down and demobilise equipment and HF personnel.
Well cleanup mill out plugs using coil tubing equipment, Dependent
upon rates at
which sand,
debris and
treatment water
return from
formation
recover sand, debris and HF fluid,
clean up of the well allowing flowback.
Flowback
testing
well flowback for a 30-90 day period of subsequent to HF and well
cleanup,
Flowback to
occur for
between 30 and
90 days
conduct hydrocarbon flow testing and characterisation including
intermittent and continuous periods of flaring with intensity-
duration-frequency to be monitored and reported,
conduct produced water testing, including chemistry analysis and
chatacterisation including treatment optimisation for reuse and
disposal.
Monitoring,
care and
maintenance
reinject the flowback to formation, haul residual flowback to a
licenced facility for disposal (as required),
Will occur at the
end of flowback
testing

Reinjection
expected to
take less than a
week at each
well site.
Conduct environmental monitoring of groundwater bores
upstream and downstream of the well site prior to, during and post
HF treatment at each well site,
Conduct air quality monitoring prior to and during HF operations at
one well site,
Conduct microseismic monitoring at each of the well site areas
prior to, during and post HF treatments,
Care and maintenance of the well sites following the completion of
operations.
2.2. Personnel
Approximately 50 personnel are expected to be located at each well site during the HF Operations
stage. These will principally be the Contractors personnel with a small number of Company
operational and supervisory personnel. Halliburton has been appointed as the contractor (Contractor)
to undertake the HF Activities. Halliburton is one of the largest global oilfield services companies and
completed over ~160,000 HF treatments worldwide during 2013. Halliburton has a proven track record
of successfully completing HF operations to a high standard and has the appropriate and necessary
health and environment safety management systems and policies in place. The Contractor will be
contractually required to comply with the approved Environment Plan for the Activities and the


TGS14 EP Summary Document_Rev_2 Buru Energy Limited 4
Companys Environmental Policy as well as all applicable legislation and regulatory requirements
including the APPEA Code. A Company representative will oversee the Activities including completion
of operational checklists in accordance with the Company Operations Management Procedure (OP-
PR-025).
2.3. Well Site Operations
2.3.1. Mobilisation
The machinery and equipment, personnel and supplies will be mobilised on semi-trailers to the well
site and camp site over a period of approximately 48 hours. Access to each well site will utilise existing
roads and access tracks. All transport on public roads will be in accordance with State road legislation.
Vehicles travelling along station roads and well access tracks will be limited to 80 km/h and 60 km/h
restrictions respectively. All vehicles will be required to adhere to the Companys Travel Management
to or within Buru Operations Policy (HSE-PR-002) which includes restrictions on night time driving
except under approved circumstances that have been risk assessed and shown to be ALARP in the
approved Environment Plan or in the event of an emergency. All traffic and parking will be confined to
designated tracks and parking areas. Operational personnel will not be permitted outside the Activity
area under normal circumstances.
2.3.2. Water Use
Water for the Activities will be sourced from bores licenced by DoW under the Rights in Water and
Irrigation Act 1914 (WA) located near each well site. The maximum amount of water permitted to be
extracted for the 2014 program is 50 ML per year at each well site under the DoW licences. This limit
includes sufficient contingencies for road maintenance, fire protection, camp operations as well as HF
operations. Permitted maximum water use as a percentage of catchment recharge was estimated for
the Yulleroo region to be less than 1.6% of the conservative annual groundwater recharge estimate for
the Yulleroo sub-catchment.
Conservative water use estimates for the entire TGS14 Activities represent less than 0.020% of the
annual sustainable yield of the Canning Basin. Opportunities will be sought to re-use water during
subsequent HF treatments at each site in TGS14 which will further reduce total water use.
2.3.3. Water Storage
A risk-benefit analysis was undertaken by the Company considering amenity, biodiversity, fugitive
emissions and logistical impacts to determine the most suitable approach for managing water on site.
This analysis identified impervious earthen water retention ponds of turkey nest design for retention
of bore water and HF flowback water during the Activities as the most suitable approach for managing
water. Turkey Nests are so-named because they resemble the nests made by turkeys in the
landscape and are highly effective as water retention ponds. Each water retention pond will be triple
lined during construction with two High Density Polyethylene (HDPE) impervious liners interleaved
with Geotextile fabric (A34). Based on the expected water quality in flowback, this approach to storage
of water and management exceeds those outlined by Department of Water in Water Quality Protection
Note 39 (DoW, 2009) for waste water stabilisation ponds and is consistent with the conservative
approach adopted by the Company. Flowback in retention ponds will be managed to stay 1.5 m below
the top of the levee to provide sufficient freeboard to exceed a 1:100 year rainfall event. Also, by
design, the ponds cannot be inundated by flood waters from a 1:100 year rainfall event.
Upon flowback, water will be fully characterised using laboratory analysis. This characterisation of HF
flowback water will provide the information required by the Company for the reuse of water during
subsequent programs.
2.3.4. Well Preparation


TGS14 EP Summary Document_Rev_2 Buru Energy Limited 5
Prior to mobilising the HF spread to site, the following will be undertaken to prepare each well for the
HF treatment:
Each well will cleaned out using a wireline/coil tubing unit in preparation for the HF treatment.
This will be done by flushing the wellbore with fresh water pumped from the retention pond for
source water down the wellbore and returned to the Water Retention Pond.
Following cleanout of the well, a brine solution (2% KCL) will be pumped down the wellbore so
the well is partially full.
A specialist wellhead will be installed and pressure tested.
The wellbore has been pressure tested for integrity and determined to be free of any
obstructions to allow access to the perforations.
Stage 1 perforations will be completed
2.4. HF Operations
HF Operations are undertaken stimulate the formation and release gas and other hydrocarbons into
the well. During all operations relating to well stimulation, a dual barrier philosophy will be employed.
HF treatments will be performed in each of the wells at selected target zone(s) at defined depths
below ground level in the Laurel formation. The number and depths of HF treatments at each well are
shown in Table 3 below.
Table 3: Number and depths of HF treatments at each well.
Well Site # HF Treatments Highest HF Zone (m) Deepest HF Zone (m)
Yulleroo 3 5 2720 3625
Yulleroo 4 13 2435 3450
Valhalla North 1 7 2355 3305
Asgard 1 11 2400 3450

Zones will be accessed by perforating the production casing and surrounding cement of the well with
small holes approximately 3 mm in diameter, using a specially designed well perforating gun.
Perforations are typically made along four sides facing the target formation, through the casing,
cementing, and any other barrier between the formation and the well. Hydraulic stimulation will
commence at the deepest zone in each of the wells. A Design of Service (DoS) has been prepared by
the Company and the contractor for the implementation of HF Activities at each of the well sites. Each
of these well DoSs has been independently reviewed with an environmental risk assessment focus by
an international industry specialist reviewer, and signed off.
Prior to the first HF treatment, a DFIT (Diagnostic Fracture Injection Test) will be performed at the
lowest HF zone in each well. This is a short duration, small volume diagnostic fracturing operation to
validate the modelled HF design performance in the formation. The DFIT uses a small amount
(<20,000 L) of brine water which is pumped into the formation until fracture initiation. At that point the
frac valve is closed and the wells pressure decline is monitored over time and the results used to
confirm the calibration of the modelled HF design.
Pumping of each HF treatment will occur over a period of 2 to 5 hours. The HF treatment is expected
to have pumping rates down the well bore of up to 10 m/minute. Water from the tanks will be pumped
into the blenders where sand and chemical additives are mixed prior to being fed into the high
pressure positive displacement pumps for pumping down the well hole. The downhole mixture is
varied in a series of sequential pumping steps to stimulate the reservoir.
Following the completion of each pumping treatment, a temporary plug is installed above the
completed stage and the next stage up the well is perforated and pumped. In this manner, HF
treatments are undertaken from the deepest zone to the shallowest zone in the well with
approximately one HF treatment completed each day.


TGS14 EP Summary Document_Rev_2 Buru Energy Limited 6
2.4.1. Vertical Separation from Potable Aquifers
The Betty Formation of the Grant Group is the deepest (potentially usable) groundwater aquifer that
occurs across the Canning Basin. The Grant Group extends over most of the Canning Basin, including
the Fitzroy Trough, and in the northern Canning Basin comprises three formations the Carolyn,
Winifred and Betty Formations. The Betty Formation in the Grant Aquifer is the closest potential
potable (based only on salinity values) aquifer, to the top of the Laurel Formation. However it is
extremely deep and not commercially viable. In addition, based on petroleum well logs it is likely to
also contain hydrocarbons that have migrated over geological time from the deeper Laurel formation.
The vertical separation between the top of the gas zones and the base of the Betty Formation is a
possible consideration. Table 4 shows the distance separations from the top of the HF zone. All
distances exceed the so called respect zone which is the recommended minimum 600 m depth
separation between the HF zone and the drinking water aquifer (Royal Society, 2012). This respect
zone is based on detailed analysis of data acquired from several thousand shale gas HF operations
in the USA which reported a maximum vertical fracture length of 588 m (Davies et al, 2012). These
data showed that less than 1% of vertical fracture lengths exceeded 350 m and that none exceeded
588 m.
Table 4: Top and base elevations and separation distance from Laurel formation at TGS14 wells.
Well Ground Level
(m AHD)
Elevation of Grant Group
(m AHD)
Thickness
(m)
Separation to top
of HF Zone (m)
Top Bottom
Yulleroo 4 >1,100
Yulleroo 3 57 -376 -677 301 >1,100
Valhalla North 1 -715 -1499 784 740
Asgard 1 123 -695 -1246 551 670
2.4.2. Chemicals Used Down hole
Water makes up the majority (~94%) of the HF fluid system, followed by proppants (sand) as the
second largest component (~5%), and the remaining constituents (<1.0%) being made up of chemical
additives. Total chemicals not including salt used in each HF treatment is approximately 3,529 L. The
products to be used in the HF fluid system have been fully disclosed in accordance with Regulation
15(9) of the Petroleum and Geothermal Energy Resources (Environment) Regulations 2012 and
Chemical Disclosure Guideline (2013) published by the DMP, and are provided as Appendix A to this
Summary. This includes ecotoxological risk assessment data for each product and each chemical.
An environmental chemical risk assessment has been conducted for the downhole HF fluid system by
an independent specialist in accordance with the DMP Guidelines. This detailed Environmental
Chemical Risk Assessment has determined that none of the chemicals to be used are classified in
their downhole form as carcinogens or teratogens; are not persistent in the environment and do not
bioaccumulate. The risk assessment concluded that the chemical constituents were readily
biodegradable or consumed downhole (acids and bases). An ecotoxicity assessment of the HF fluid
and its breakdown products show they are non-toxic under national guidelines. The biocide has low
mammalian and avian toxicity and the high salinity of flowback water would prevent wildlife from using
flowback as a source of drinking water.
2.4.3. Proppant Supply
Sand will be used as the proppant during the Activities and will be sourced from a quarry located
approximately 25 km north of Perth. Proppant will be transported to site using bulk grain tippers. The
Valhalla 2 well site will be used as a proppant storage area during HF Activities at the Valhalla North 1
and Asgard 1 well sites while the Yulleroo 2 well site will be used as a proppant storage area during
HF Activities at the Yulleroo 3 and Yulleroo 4 well sites. At the laydown areas, the sand will be
unloaded and stored on an elevated mesh lining pad and covered by a waterproof tarp. The mesh


TGS14 EP Summary Document_Rev_2 Buru Energy Limited 7
lining will provide a 2 inch (5 cm) interface between the ground and the sand prohibiting water and
surface sand (pindan sand) contact with the proppant.
2.5. Well Cleanup and Flowback
Following the completion of HF treatments, the plugs will be milled out and well cleanup will
commence. Well cleanup occurs prior to HF flowback and is the phase where sand, debris, and HF
fluid are returned from the well. The trash catcher catches pieces of rubber and composite from the
plugs that were used to isolate the zones. Following well cleanup, flowback will commence. During
flowback, the fluid will be diverted to pass through a separator. The separator is based on differences
in the density of substances. As the gas is lighter, it is diverted through the top outlet of the separator
via a pipeline to the flare. Liquid hydrocarbons are lighter than water in the separator and will be
diverted through a separate outlet to storage tanks onsite. Water, as the denser liquid, will build up in
the bottom of the separator and then will flow into the Water Retention Pond through a third outlet.
2.5.1. Flowback Water Management
Following HF Operations and during the well flowback phase, between 40 and 70% of water injected
to the Laurel Formation is expected to return to the surface. Most (~80%) of this flowback water
returns to the surface in the first two weeks of well flowback. Although TGS14 is an early stage of the
investigation of the Laurel formation, the Company has already collected significant environmental
data to inform the characterization of the quality of the flowback to be stored in impermeable retention
ponds following TGS14 hydraulic fracture treatments at each of the TGS14 wells. This includes data
from the results of Yulleroo 2 hydraulic fracture flowback analysis, chemical analysis of drill cuttings
from the well, bore logs and geological core samples from the Petroleum wells. Based on these
analyses, the Company has determined that the flowback water is very high in salt at 3-5 times the
salt concentration of seawater and is not toxic to fauna or humans. The Company has also determined
that the flowback fluid from the Laurel formation is not radioactive and that heavy metals are at very
low levels or not detectable. Any produced hydrocarbons will be removed from the flowback water
through the use of a three phase separator, as described above.
As stated in Section 2.3.3 above, water retention ponds have been designed with sufficient freeboard
to handle a 1:100 year rainfall event. The rate of flowback is managed at the choke at the well head
with the well able to be shut-in at any point during flowback, if required.
2.5.2. Flaring
Gas flow rates are not expected to exceed 5,000 m (2 MMSCF)/day for each well. The alternative to
flaring is cold venting of gas to the atmosphere. Flaring converts methane (CH4) to carbon dioxide
(CO
2
) and water (H
2
O). Emission of CH
4
during cold venting (no flaring) to the atmosphere is 21 times
worse in terms of greenhouse gases emission compared to emission of CO
2
following flaring. The gas
will be flared in a concrete lined flare pit during TGS14. The flare pit will be located within the cleared,
gravel sheeted and fenced well site area which has a minimum of 5 m wide firebreak maintained
around the well site fence.
The Company has considered alternative approaches to managing the liquid hydrocarbons
(condensate) including use of a vertical flare. The Company considers the use of a separator and
concrete lined flare pit as the approach that reduces HSE risk (particularly fire) associated with the
Activities to ALARP. The flare pit has been engineered to be impermeable to liquids. Concrete will be
150 mm thick on the bottom and sides of the flare pit and 200 mm thick at the end of the flare pit
where the flare is situated. In addition to ensuring all gas is flared and that air emissions are reduced,
the use of horizontal flare pits will contain any surges in the flare associated with the combustion of
liquid hydrocarbons should they not be captured by the separator.
2.5.3. Reinjection of Flowback Fluid


TGS14 EP Summary Document_Rev_2 Buru Energy Limited 8
Fluid will be reinjected to the Laurel Formation at the end of the flowback period. Based on
Halliburtons international experience, the Company has >99% confidence that the liquid component of
the flowback will be able to be returned to formation. The capacity of the formation to receive the
flowback water is validated during the stimulation process when a greater volume of liquid is injected
into the formation.
Flowback will be re-injected at an estimated rate of 20 bbl/minute. Based on these rates, reinjection of
flowback is expected to be completed in approximately 5 days at each of the well sites. Once
reinjection of flowback water to the formation has been completed, a residual sediment slurry
comprising an estimated 1-2% of total flowback water volume will remain in water retention pond. The
slurry will consist of proppant and dust that will blow in during the flowback period. This residual
sediment will remain in situ while it is analysed in the laboratory to inform suitable disposal options.
2.5.4. Waste Storage and Disposal
During the Activities, general and industrial waste will be stored onsite in segregated areas including,
but not limited to:
Putrescible waste
General waste
Industrial waste
Waste management will be included in on-site inductions and recycling will be encouraged during the
operations.
Putrescible waste will be stored at the camp site and well site in securely covered skips/bins to
prevent fauna access, including feral fauna, and litter generation. All putrescible waste will be regularly
removed from the Activity area for disposal at a licensed waste disposal facility.
General and industrial waste will be suitably stored onsite in segregated areas including, but not
limited to:
Excess proppant sand stored within dry materials storage area;
Produced liquid hydrocarbons stored in a fit for purpose storage tank within a bunded area;
Residual flowback within the Water Retention Pond; and
Empty chemical containers returned to Service provider facilities offsite.
Where possible, industrial waste will be reused or recycled. If the industrial waste cannot be reused or
recycled, it will be removed from the Activity area for disposal at a licensed waste disposal facility in
accordance with landfill operator requirements and the Environmental Protection (Controlled Waste)
Regulations 2004, where applicable. Chemical drums used during HF Operations will be capped and
transported off site by the contractor for approved disposal.
At the well site and camp site, sewage (black water) will be separated from grey water. Sewage will be
stored on site and then transported off site by a licenced contractor.
2.5.5. Power
Portable diesel generators onsite will provide power at the well site and camp site. All electrical
equipment, instrumentation, lighting and cabling will be installed in accordance with statutory
requirements.
2.6. Dangerous Goods
The Company defines dangerous goods according to the Dangerous Goods Safety Information Sheet
(DMP, 2009) and the Work Health and Safety Regulations. Examples of dangerous goods that will be
on site are petrol and diesel. Dangerous goods will be stored, including segregation if applicable, in


TGS14 EP Summary Document_Rev_2 Buru Energy Limited 9
accordance with Dangerous Goods Safety (Storage and Handling of Non-Explosives) Regulations
2004 (WA) and relevant material safety data sheets (MSDS). A bunded or double skinned bulk diesel
fuel storage tank will be established within the well site. Each dangerous good stored and handled will
have a MSDS available onsite.
2.6.1. Refuelling
Vehicle and mobile equipment refuelling will be undertaken at designated refuelling areas at the well
site and camp site in accordance with the Company Refuelling Procedure (HSE-PR-011). At the well
site, the refuelling area will be located within an impermeable lined and bunded area. At the camp site,
the refuelling area will be located within a bunded area such as a drip tray or bunded pallet. Refuelling
of stationary equipment such as generators will typically be undertaken using a small tank
(approximately 1,200 L) on the back of a service vehicle or dedicated refuelling trailer. A drip tray will
be located under refuelling points during mobile refuelling.
2.7. Hazardous Substances
Under the Work Health and Safety Regulations, hazardous substances are those that, following
worker exposure, can have an adverse effect on health or the environment. Examples of hazardous
substances include poisons, substances that cause burns or skin and eye irritation etc. Many
hazardous substances are also classified as dangerous goods. Examples of hazardous substances
that will be on site are biocide and acid. Hazardous substances will be stored, including segregation if
applicable, in accordance with relevant MSDS.
There will be two chemical storage areas located on site. These are:
A curtain-sided truck (tautliner) will be used for the storage of dry chemicals and chemicals
contained in Industrial Bulk Containers (IBCs).
An impermeable bunded area on site will be available for the storage of wet chemicals.
Sodium chloride will also be stored within these impermeable bunded areas.
All hazardous substances will be stored within impermeable bunds such as bunded pallets, inside
bunded containers etc. All hazardous substances stored and handled onsite will have a MSDS
available onsite. Spill kits will be available onsite for immediate containment and clean-up of spills of
hazardous substances. Large spills (>80 L) will be contained, cleaned-up immediately and remediated
in accordance with the Canning Basin Operations Spill Response Plan (HSE-ICM-003).
2.8. Post-HF Operations
2.8.1. Demobilisation
Upon completion of HF activities, all equipment, personnel and supplies will be demobilised from the
Activity area in accordance with the Company Demobilisation Procedure (HSE-PR-021). This
Procedure outlines the process and timing of demobilisation to be implemented by the Company at the
conclusion of an Activity to ensure the area is left in a condition that minimises risk to the environment
and people. This includes, but is not limited to, the requirement for the fence surrounding the well site,
including the water retention ponds and flare pits to be left in place and the gate closed, fauna egress
paths to be in place on all open excavations and all waste to be removed from the location.
2.8.2. Well Suspension
Following the completion of the Activity, the well sites will be suspended and placed in a care and
maintenance phase pending the potential implementation of a second stage of testing of the Laurel
Formation exploration program.
The groundwater monitoring program implemented by the Company will continue monthly for 6
months following the completion of Operations to demonstrate no impacts on groundwater as a result


TGS14 EP Summary Document_Rev_2 Buru Energy Limited 10
of the Activities. The groundwater monitoring program will then continue quarterly until plugging and
abandonment of the Petroleum well.
2.8.3. Rehabilitation
Depending on the results of the exploration Activities, the respective exploration wells may be plugged
and abandoned. Should the well be plugged and abandoned, these works will be undertaken in
accordance with clause 529 of the Onshore Petroleum Schedule, the PGER Act and recognised
international standards including the United Kingdom Onshore Oil and Gas Guidelines UKOOG and
DNV standards. Cement plugs will then be set in the open hole and at surface before covering the site
with soil. The collar will be removed from the wellhead cellar and the cellar backfilled to a grade
consistent with the adjacent area. An abandonment plaque will be posted. Once wells have been
plugged and abandoned, rehabilitation will commence within three months, depending on weather
conditions and contractor/equipment availability. Rehabilitation will be undertaken in accordance with
the Companys Rehabilitation Procedure (OP-PR-022). This includes the ripping of compacted areas,
the re-contouring of the site to match the surrounding environment and the re-spreading of topsoil and
vegetation over the site. Post-rehabilitation monitoring and inspections will be carried out to determine
if there is any need for active rehabilitation. Active rehabilitation includes spreading native local seeds,
planting seedlings and additional erosion control measures, as required.

3. ENVIRONMENTAL IMPACTS AND MANAGEMENT MEASURES
A summary of the existing environmental characteristics of the Activity, potential impacts that could
result from the Activity and the risk of these potential impacts occurring is provided in Table 5.
Included in this table are also the management and mitigation measures that form part of the
implementation strategy to minimise environmental risk.



TGS14 EP Summary Document_Rev_2 Buru Energy Limited 11
Table 5: Summary of the existing environment and potential impacts associated with the Activity
Environmental
characteristic
Description Potential Impact Management Measures Risk Implementation Strategy
Shallow
Groundwater
Aquifers
(<200 m)
The groundwater systems in the Activity areas
have been characterised through the
development of a conceptual groundwater model.
This model has been peer-reviewed by an
Independent Specialist from The University of
Western Australia (UWA).

Yulleroo Region:
The surficial aquifer in the Yulleroo region is the
Broome Sandstone. Recharge of the Broome
sandstone is mainly by direct percolation of
rainfall or indirectly through overlying sediments.
Groundwater discharge is to the Indian Ocean in
the vicinity of Roebuck Bay and by
evapotranspiration in wetland areas such as Lake
Eda that occurs approximately 30 km west of
Yulleroo towards Roebuck Bay.

There is more than 2,000 m of impermeable hard
rock between the Broome sandstone aquifer
which is the source of drinking water in the
Yulleroo area and the highest proposed HF zone
meaning it is implausible for HF to reach the
aquifer.

Within the Yulleroo region, the top of the water
table is between 10 and 20 m deep depending on
ground level. Water has been estimated to take
10 to 20 days to infiltrate from the ground surface
to the water table. The estimated groundwater
travel times from Yulleroo 3 or Yulleroo 4 to Lake
Eda and Roebuck Bay are approximately 640
years and 1,800 years respectively. Baseline
water quality sampling in the Yulleroo region
indicates groundwater is fresh to brackish with
salinity ranging from 350 to 1,400 mg/L TDS.
Most parameters were below Australian drinking
water guideline values with the exceptions of
boron in Bohemia bore and gross alpha and
gross beta radiation in Yulleroo 2 and Yulleroo 3
water bores.

Valhalla/ Asgard Region:
The Liveringa Aquifer is the main surficial aquifer
in the Valhalla/ Asgard Region and extends to
~290 m depth. There are generally few
sandstone beds which are typically thin.
Reported salinities generally range from 250 to
1,000 mg/L in the region though may be up to
3,500 mg/L TDS, particularly in deeper areas.
Recharge of the Liveringa occurs mainly from
rainfall on areas of outcrop. There is more than
2,000 m of impermeable hard rock between the
Liveringa sandstone aquifer which is the source
of drinking water in the Asgard and Valhalla area
and the highest proposed HF zone meaning it is
implausible for HF to reach the aquifer.

The top of the water table ranges from ~30 m
depth at Valhalla North to approx 60 m at Asgard.
Infiltration to the water table is slow with water
likely taking between 70 to 300 days to travel
from the ground surface to the water table.
Potential Impacting Mechanisms
Sub-surface migration of HF fluid
or produced formation water/liquid
hydrocarbons into shallow potable
aquifer due to:
o Well integrity failure.
o Well control event.
o Well casing rupture due to over
pressure.
o Annulus (backside) leakage
from cementing.
Surface migration of HF fluid or
produced water into shallow
potable aquifers.
Surface migration of hazardous
substances or dangerous goods
into shallow potable aquifers.
Groundwater drawdown.
Inadequate management of waste.
Vehicle rollover leading to spill of
hazardous substances.

Source-Pathway-Receptor Analysis
Source - Chemical Risk Assessment
An ecotoxicity assessment of HF
fluid to be used for the Activity has
been undertaken at an accredited
Ecotox laboratory using local
rainbow fish species
(Melanotaeniidae). The results
show the HF Fluid is classified as
non-toxic under national guidelines
Independent Chemical risk
assessment indicates the
constituent chemicals source have
low persistence and readily
biodegrade
The biocide has low mammalian
and avian toxicity and the high
salinity of flowback water would
prevent wildlife from using
flowback as a source of drinking
water
There are no chemicals in the HF
fluid that will plausibly cause
exceedances of Inert classification
for landfill guidelines.
Flowback water in water retention
ponds will be fully contained in
triple lined water retention ponds
and fully characterised to inform
subsequent reuse options.
Proppant sand will be captured in
water retention ponds. Returned
proppant will be analysed during
cleanup of the water retention
ponds. Should the material meet
Class 1 landfill guidelines and the
DMP concurs with the findings, the
material will be used for blending
with roadbase to resurface the site/
track during track maintenance.
Operational Management
Dangerous goods will be stored in accordance with Dangerous Goods
Safety (Storage and Handling of Non-Explosives) Regulations 2004
(WA), including segregation if applicable, in self bunded (double
skinned) tanks.
Dangerous goods will be transported in accordance with Dangerous
Goods Safety (Road and Rail Transport of Non-Explosives)
Regulations 2007.
All vehicle movements to be undertaken in accordance with Travel
Management Procedure (HSE-PR-002):
o Vehicles driving on station roads limited to 80 km/h
o Vehicles driving on the well access tracks limited to 60 km/h
o No driving at night except under approved circumstances
defined in the approved EP or in an emergency.
Vehicles and personnel access restricted to existing access track, well
site and camp site.
Repair of localised soil erosion or sedimentation on access track, well
site and camp site, where required.
The Contractor will be required to provide full HSE documentation for
site specific operations that will bridge to the approved Environment
Plan, and Company supporting procedures, for the Activity.
Transportation will be undertaken in accordance with the Contractors
procedures or JHA.
Refuelling and fuel transfer will be undertaken in accordance with the
Refuelling Procedure (HSE-PR-011) including:
o Vehicles and mobile equipment refuelling will be undertaken
within impermeable lined and bunded designated refuelling
areas at the well sites.
o Refuelling of stationary machinery and equipment will be
undertaken using a mobile tanker with a drip tray under
refuelling points.
o Refuelling operations to be manned at all times and spill kits
available for immediate containment and clean-up of spills of
dangerous goods.
Hazardous substances will be stored, including segregation if
applicable, in accordance with relevant MSDS. All hazardous
substances will be stored within impermeable bunds such as bunded
pallets, inside PVC lined bunded area etc.
The Contractor will be required to provide full HSE documentation for
site specific operations that will bridge to the approved Environment
Plan and associated Operations Plan and Safety Plan, and Company
supporting procedures, for the Activity. Handling of hazardous
substances to be undertaken by suitably trained personnel in
accordance with Contractors procedures or JHA.
All site personnel to have appropriate PPE equipment including
respiratory protection where appropriate.
Independent verification of well-maintained and operating machinery,
vehicles and equipment will be required from the Contractor.
In accordance with the Operations Management Procedure (OP-PR-
025) completion of a weekly operational checklist:
o Storage of dangerous goods and hazardous substances.
o Integrity of bunded areas.

Contractor Design of Service Document
A Design of Service document for each well has been prepared and
approved under the Operations Plan for this Activity and includes the
following:
Independent review of each well HF design and sensitivity analysis
around predicted heights for the HF in each zone by Dr Chris Green.
HF designed to conform with well design specifications (e.g. casing
design limits).
Pressure testing of well head and tree conducted prior to HF at each
Based on the Buru
Energy risk matrix,
risks may be ranked
from Risk Class 1
(LOW risks) to Risk
Class 4 (HIGH) risks.

Risks to shallow
groundwater aquifers
are typically in the
Class 1 (LOW) risk
Class.

The following potential
impacts were ranked as
Class 2 risks. These lie
on the acceptance
threshold but require
active monitoring by
management:
Vehicular accidents
en route to and from
site resulting in
potential spill of
hazardous or
dangerous goods:
Serious but rare
event (once every 5
years or less).
A well control event
that may result in
surface spills.
Serious but rare
event (once every 5
years or less).
A well control event
that may result in
well integrity failure
and sub-surface
leaks. Serious but
rare (once every 5
years or less).
Inappropriate
storage or handling
of dangerous goods
or hazardous
substances including
hydraulic fracturing
fluid constituents:
Serious but rare
(once every 5 years
or less).

To ensure risks to
shallow groundwater
aquifers are managed
to ALARP, the
Company will
implement the suite of
management measures
outlined in the previous
column.
Planning and Preparation for HF Operations
Induction of all personnel prior to going on
site.
Geohazard and geomechanical assessment
completed and independently reviewed for
each well.
Modelling of predicted HF containment
envelope undertaken and operational
procedures reviewed independently for each
well site.
Well integrity assessment reviewed
independently for each well site.
Verification of equipment integrity required to
be provided by contractor prior to activities
commencing.
Contractor to pressure test all equipment prior
to the commencement of HF Activities.
Licencing of ground water bores for level of
anticipated water use at each well site

Dangerous Goods and Hazardous
Substances Storage and Handling
All hazardous chemicals to be stored in
dedicated bunded areas in accordance with
the regulations and MSDSs.
Maintain the hazardous substances area in a
clean and environmentally acceptable
manner.
MSDS available for all hazardous substances
stored onsite.
Handling of hazardous substances to be
undertaken by suitably trained personnel only
and in accordance with Contractors
procedures or JHA.
All refuelling to be undertaken in accordance
with Company Refuelling Procedure (HSE-
PR-011).
A designated refuelling area to be established
at the camp site.
Well calibrated and maintained machinery,
vehicles and equipment.

HF Operations
Double isolation barriers on fracture
stimulation equipment.
Certified flowback equipment and contractor
flowback procedures followed.
Pressure testing on all equipment at rig-up.
Approved rig up to facilitate controlled bleed
off from the fracture stimulation equipment.
Routine HF well control procedures including
pressure control (chokes, redundant flowback
line, contingency measures).

Reinjection of flowback fluid to formation
Certified flowback equipment and contractor
flowback procedures followed.
Pressure testing on all equipment prior to
commencing reinjection.
Redundancy in pumps used for reinjection.
3/16 (~950 micron) in-line filter to be installed


TGS14 EP Summary Document_Rev_2 Buru Energy Limited 12
Environmental
characteristic
Description Potential Impact Management Measures Risk Implementation Strategy

Groundwater in the Liveringa Formation generally
flows westwards towards the Fitzroy River. The
estimated groundwater travel time from the
Valhalla region to the Fitzroy River is 16,000
years. Most station bores in the Valhalla-Asgard
region yield small supplies of fresh to slightly
saline water from the surficial Liveringa Formation
which are generally considered to be aquicludes,
aquitards or minor aquifers.
Pathway
The largest feasible spill that may
occur on-site will be readily
contained and absorbed on the
gravel hardstand area within the
perimeter fence of the well site and
can be readily and rapidly scraped
up and placed on a HDPE lined
storage are for removal from site.
All flowback water will be stored in
lined water retention ponds and
regularly checked for presence of
radiation during the flowback
period.
Flowback of condensate will be
into double skinned tanks on site.
Largest feasible spill from a vehicle
collision or rollover will be readily
contained within 100 m of crash
site, cleaned-up by placing on
HDPE lined storage area and
removed to a licensed waste
disposal facility.
Receptor
Nearest aquifer is Broome
Sandstone Aquifer (~50 m deep) in
Yulleroo region nearest bore is a
pastoral bore which is 5 km away.
There are no drinking water bores
that could plausibly be affected
Nearest aquifer is Liveringa Aquifer
(~80 m deep) in Asgard/Valhalla
region nearest bore is a pastoral
bore which is 5 km away. There
are no drinking water bores that
could plausibly be affected.





















well.
Independent review of relevant operational elements of HF Activity
prior to Activity by Dr Chris Green.
Monitor pH levels of flowback water so as to ensure that acid
concentrations are neutralised to the required threshold value.
Well specific operational details to be provided by a suitably qualified
Contractor with HF treatment experience including:
o Pressure kickouts and pop-off valves to prevent exceedances in
design pressures.
o Double isolation barriers on fracture stimulation equipment.
o Immediate shutdown monitoring system installed (high and low
pressure systems).
o Exclusion zone around high pressure pumping area during
operations.
o Rig up to facilitate controlled bleed off from the HF treatment
equipment.
o Equipment pressure tested after rig-up and prior to conducting
the Activity.
o Clean water will be circulated through reticulation system to
clean system prior to demobilisation of equipment.
o Certified flowback flowback equipment and flowback best
available techniques followed.
o All fluid will be contained in the designated retention ponds and
tanks.
All chemicals and other substances to be used down hole during the
Activity will be fully disclosed in accordance with regulation 15(9) of the
Petroleum and Geothermal Energy Resources (Environment)
Regulations 2012 (WA) and Chemical Disclosure Guideline.
Hardstand area will be gravel surfaced and contain small (< 20 L)
volumes of fluid that may spill from the dilute HF fluid and flowback.
All concentrated chemicals directly transferred from Industrial Bulk
Containers (IBC) containers to blender via metred closed loop
flowlines during HF operation there is no double handling.
Maximum of 15,800 L of dilute HF fluid contained at the well site prior
to and during pumping.
Contractor equipment will be purpose designed and required to
provide evidence that it is well calibrated and in good working order as
part of the selection and mobilisation process.
Regular maintenance to ensure integrity of equipment including
pressure testing, maintenance assessment and fail-safe automation
systems.
Contractor will be required to provide full HSE documentation for site
specific operations that will bridge to the approved Environment Plan
and Operations Plan and Safety Plans, and Company supporting
procedures, for the Activity.
Confirmation that no anomalous pressure readings in annulus between
intermediate and production casing prior to and during HF treatment.
Routine HF well control procedures including pressure control (chokes,
redundant flowback line, contingency measures).
Presence of corrosive materials in fluid adaptively managed to mitigate
casing rupture.
Velocities managed below 30 m/sec to mitigate erosion of
casing/tubing.
Monitoring the annulus (backside) pressure between intermediate and
production casing
Regular maintenance to ensure integrity of equipment including
pressure testing, maintenance assessment and fail-safe automation
systems.
No chemicals used during drilling of down holes for microseismic
monitoring program.
Real time monitoring of anomalous pressure changes during HF
activity and rapid shutdown of pumping in accordance with Micro
Seismic Monitoring Procedure (HSE-PR0-020) including thresholds for
ceasing operations.
to remove solids prior to reinjection to
formation.

Waste Management
Lidded bins to be made available on site for
disposal of waste.
All grey water to be treated through an
Aerated Wastewater Treatment System
(AWTS).
Treated grey water will then be released into
a leach drain that is filled with ballast rock and
covered with soil.
All sewage to be stored on site then taken off
site by a licenced contractor for disposal at a
licenced facility.
All putrescible wastes (e.g. food scraps) to be
segregated and stored in securely covered
bins for disposal at a licensed waste disposal
facility.
All inert and industrial wastes (e.g. cardboard
boxes) to be segregated and stored in bins
for recycling or disposal at a licensed waste
disposal facility.
All controlled wastes (e.g. empty fuel drums,
waste oil) to be segregated and stored in a
bunded area for transport and disposal at a
licensed waste disposal facility
All waste, equipment and dangerous goods
and hazardous substances removed from
well sites following the completion of TGS14
operations in accordance with the
Demobilisation Procedure (HSE-PR-021).

Flowback Water Management at Well Site
Flowback monitored for presence of liquid
hydrocarbons and separator installed if
required to separate liquids. Separated liquids
stored in a HDPE lined and bunded tank
system prior to trucking offsite for disposal.
Immediate testing of flowback water to
identify COPC (including NORMs) in flowback
water according to Company's Produced
Water Monitoring Procedure (OP-PR-024).

Disposal of Flowback Water
Final disposal option for flowback water
agreed with regulator based on results of
characterisation prior to disposal.
If disposal occurs at Sundown, brine to be
evaporated and then capped with native clay
as part of ongoing rehabilitation of the
Sundown site in accordance with Blina
Oilfield Care and Maintenance Environment
Plan.
All required DER licences will be secured
prior to disposal of brine at Sundown site.

Monitoring
Planning and Preparation
Baseline monitoring of groundwater quality
and depth to water undertaken at each well
site for at least 12 months prior to
commencement of the Activity.
Baseline monitoring of groundwater quality at


TGS14 EP Summary Document_Rev_2 Buru Energy Limited 13
Environmental
characteristic
Description Potential Impact Management Measures Risk Implementation Strategy
Water extraction for operational requirements will be minimised by
recycling of flowback fluids, where practicable.
Taking of water under approval of the DoW licence.
All production water bores metered.

Environmental Monitoring
Nested environmental monitoring bores in alluvium and groundwater
up-gradient and down-gradient on well pads to detect leaks in
accordance with Groundwater Characterisation and Assessment
Program (Appendix D-2)
In accordance with the Company Environmental Monitoring Procedure
(HSE-PR-013), baseline, operational and post operational
groundwater monitoring (quality and level) from water bores and site
environmental monitoring bores.
Baseline groundwater monitoring (quality) has been implemented for
more than one year.
Monitoring of Sundown site in accordance with any DER licence
conditions.
Continuous Gasclam loggers installed on environmental monitoring
bores downstream of well will continuously measure methane, VOCs
and groundwater depth during surveillance phase.
Near field and far field measures of water bores to determine regional
baseline of groundwater depth and contour.
Depth to groundwater included in Company groundwater monitoring
program.
Results of water level monitoring and other parameters during
operations will be used to assist in calibrating hydrogeological model
for future activities.

Flowback Monitoring and Management
Characterisation of HF flowback in numerous international studies
indicates the constituents are not highly toxic or persistent.
Analysis of Yulleroo 2 flowback water indicates constituents of
potential concern (COPC) and NORM in flowback water are likely to
be low.
All recovered fracturing fluids will be isolated in impervious storage
areas designed to prevent leakage, as required by APPEA Code of
Practice for Hydraulic Fracturing (2011) Guideline 5.
Characterisation of flowback water to confirm low toxicity in
accordance with Produced Water Monitoring Procedure (OP-PR-024).
In accordance with Produced Water Monitoring Procedure (OP-PR-
024) analysis of flowback water conducted during and immediately
after flowback ceases with radiation meter to detect anomalous
readings above background bore water values/guideline levels.
A radiation meter will be used on site to confirm NORM is below
guideline and background values. If elevated radiation levels detected
then treatment of flowback water to remove solids (which contain the
NORMs) will be undertaken and the solids containing the NORMs
taken to licenced facility for disposal.
Maximise reuse of flowback water in subsequent HF treatment
between well sites; final reinjection of flowback into the target
formation at each well site.
Monitor pH levels of flowback water so as to ensure that acid
concentrations are neutralised to the required threshold value
In accordance with the Environmental Monitoring Procedure (HSE-PR-
013), baseline, operational and post operational groundwater
monitoring (quality and level) will be implemented through the water
bores and site environmental monitoring bores.
Construction of Water Retention Ponds with adequate storage
capacity and two layers of 1500 micron HDPE liners interleaved with
Geotextile fabric (A34) in accordance with WQPN39 (DoW,2009).
Flowback will be monitored for the presence of liquid hydrocarbons
and mobile separator installed to separate liquids, if required.
Sundown.
Installation of environmental monitoring bores
at each well site.

Operations
Manned operation for the duration of the
Activity, therefore visual monitoring for
anomalous conditions, including spills, will be
undertaken at all times.
Weekly checks of bunded storage area to
ensure no chemical spills in accordance with
the Operations Management Procedure (OP-
PR-025).
Monitoring of groundwater quality and depth
during operations in accordance with the
Environmental Monitoring Procedure (HSE-
PR-013).
Characterisation of flowback water in
accordance with Produced Water Monitoring
Procedure (OP-PR-024) to inform disposal
options.
All spills of dangerous goods and hazardous
substances are reported in accordance with
the Incident Reporting Procedure (HSE-PR-
009).
Monitor pH levels of flowback water so as to
ensure that acid concentrations are
neutralised to the required threshold value
Minimum of one internal environmental audit
during operations.
Monitoring of Sundown site in accordance
with any DER licence conditions.

Following Demobilisation
Checks of well site and associated
infrastructure completed every three months
following the completion of TGS14 Activities.
Post operations monitoring of groundwater,
including Sundown if used, for at least 6
months in accordance with the Environmental
Monitoring Procedure (HSE-PR-013).
No signs of spills within the Activity area
following demobilisation.
Flowback in retention ponds to monitored for
free board.
Water bores capped and locked following
demobilisation.





TGS14 EP Summary Document_Rev_2 Buru Energy Limited 14
Environmental
characteristic
Description Potential Impact Management Measures Risk Implementation Strategy
Separated liquids will be transferred by a flowline and stored in an
impervious lined and bunded tank for trucking offsite to refinery.

Waste Management
Waste will be managed and monitored in accordance with Waste
Monitoring and Management Procedure (HSE-PR-005) including:
o Waste oil, lubricants or other oil contaminated materials will be
stored in dedicated, labelled containers within a bunded area at
the well sites.
o Chemical drums will be stored within bunded area at well sites.
o Disposal for all industrial waste at a licensed waste disposal
facility in accordance with Environmental Protection (Controlled
Waste) Regulations 2004, where applicable.
Records will be kept of waste type and volume.

Waste Water
The Activity will be for a short duration.
All sewage to be stored on site then taken off site for disposal by a
licenced contractor for disposal at a licenced facility.
All grey water to be treated through an aerated wastewater treatment
system designed to comply with AS/NZS 1546.3: On-site domestic
wastewater treatment units - Aerated wastewater treatment systems.
Treated grey water will be released into a leach drain that is filled with
ballast rock and covered with soil.

Groundwater Drawdown
Minor volumes of water will be pumped from groundwater sites and
minor drawdown is expected to be localised to footprint of well pad.
Peer review of Companys hydrological environmental risk assessment
by Professor Neil Coles (UWA).
Total water use for all Activities, not including reuse options which will
reduce the total water use, will be a maximum of 50 ML at each well
site in accordance with DoW licence conditions which includes
contingencies for fire control, road maintenance and camp use as well
as HF operations.
During the Companys operation, there have been no reported adverse
impacts of groundwater drawdown from drilling operations which
require up to 5 ML of water extracted from local water bores.

Spill Response
The Activity will be a manned operation and therefore visual
monitoring for anomalous conditions, including spills or leaks, will be
undertaken at all times.
Containment, clean-up and remediation of a spill will be undertaken
immediately in accordance with Canning Basin Operations Spill
Response Plan (HSE-ICM-003) (OSRP) and Canning Basin
Operations Incident Management Plan (HSE-ICM-002) (IMP).
Personnel will be trained in the implementation of the OSRP and ERP.
This includes emergency response drills and/or emergency muster
drills conducted regularly.
In the unlikely event of an unplanned spill outside of the well site, a
monitoring program to be designed and implemented in consultation
with the DMP.
Reporting, investigating and implementing corrective actions for all
spills of dangerous goods in accordance with Incident Reporting
Procedure (HSE-PR-009).
Deep potable
groundwater
aquifers
(>200 m)
Yulleroo Region:
The Wallal formation is a recognised aquifer. In
the Yulleroo region, the water has a TDS of 3,700
mg/L (not potable) and flows westwards to
ocean. In the Yulleroo region, the minimum
distance between the highest HF zone (2291m
depth) and the Wallal (base depth 461 m) is at
Y3. The distance separation is 1830 m.
Potential Impacting Mechanisms
Uncontained hydraulic fracture
impacting deep potable aquifers.
Well integrity failure impacting
deep potable aquifers.
Reinjection of flowback water
into target formation at the end
of the TGS14 testing program.
All chemicals and other substances to be used down hole during the
Activity will be fully disclosed in accordance with regulation 15(9) of the
Petroleum and Geothermal Energy Resources (Environment)
Regulations 2012 (WA) and Chemical Disclosure Guideline.

Pre-Activity Monitoring and Management
Multiple sets of casing and cement forming barriers between
stimulation fluid and aquifers demonstrated by cement bond logs (CBL)
Risks to deep
groundwater aquifers
are typically in the
Class 1 (LOW) risk
Class.

The following potential
impact was ranked as a
Planning and Preparation for HF Operations
Geohazard and geomechanical assessment
completed and independently reviewed for
each well site.
Modelling of predicted HF containment
envelope undertaken and operational
procedures reviewed independently for each
well site.


TGS14 EP Summary Document_Rev_2 Buru Energy Limited 15
Environmental
characteristic
Description Potential Impact Management Measures Risk Implementation Strategy

Valhalla-Asgard Region:
The surficial Liveringa aquifer in the Valhalla-
Asgard region overlies the Noonkanbah
Formation which continues to about 720 m depth
to the top of the Poole Sandstone. The latter
formations comprise mainly fine-grained
sediments (shale and siltstone) that are low-
yielding. Groundwater is ~800 mg/L TDS in the
Noonkanbah Formation. The Betty unit of the
Grant aquifer is likely to be the deepest
recognised aquifer in the Valhalla- Asgard area
but well logs do reveal hydrocarbon shows in this
formation suggesting the water is not potable.
However for conservative evaluation the
Minimum distance between the highest HF zone
(2355 m depth at VN1) and the Betty Unit (base
depth 1385 m) is at VN1. The distance
separation is 970 m.

Source-Pathway-Receptor Analysis
Source
Chemical Risk Assessment Refer to
Shallow Groundwater Aquifers Section
above. In addition:
Pumping pressure (energy) and
water volume to enable a
fracture to extend more than a
few hundred metres is beyond
the capacity and scale of the
designed HF treatments making
it implausible

Pathway: Geological and Hydrological
Environment Risk Assessment
Likelihood of this pathway is not
physically plausible
Review of geological features in the
Activity area from seismic survey
maps have determined the
following natural features that will
prevent surface aquifer
contamination:
o More than 1,800 m of rock
separating the stimulation
zone and base of nearest
surface aquifer which is three
times recommended respect
zone.
o The tight Anderson Formation,
with permeabilitys ranging
from 10 to 500 mD (0.008 to
0.4 m/d), overlies the Laurel
Formation, sealing any
migration of gas upwards
towards the aquifers for
hundreds of millions of years.
o Natural stress barriers will
highly constrain (<300 m) the
vertical propagation of
hydraulic fractures based on
geomechanic principles of
deep rock.
o Isolation of surface aquifers
from deeper zone by
impermeable rock layers
(aquicludes).
Independent groundwater study
has determined that the
groundwater transmission within the
aquifer zones occurs over many
hundreds of years to nearest
sensitive receptors/biological
interfaces.
Hydrogeological characterisation of
groundwater systems at Activity
areas demonstrates separation
distance between top of HF zone
and nearest potable groundwater
system exceeds international
recommendations.
Peer review of Companys
hydrological environmental risk
and pressure tests.
Pre-fracture subsurface modeling and design engineering of HF
treatment to manage fracture height/length growth within the planned
stimulated rock volume (SRV).
Very low toxicity HF fluid sourced from food industry with rapid
biodegradation (<30 days) of approved constituents of potential
concern at extremely low concentrations. Massive dilution of any
constituents of potential concern would occur even if a pathway to a
receptor existed.
DFIT conducted prior to HF at each well to validate model.

Operational Management
Real time monitoring of anomalous pressure changes during HF activity
and rapid shutdown of pumping in accordance with Micro Seismic
Monitoring Procedure (HSE-PR0-020) including thresholds for ceasing
operations.

HF Design and Operational Review
Pre-fracture subsurface modelling and design engineering of HF
treatment to manage fracture height/length growth within the planned
stimulated rock volume (SRV).
DFIT conducted prior to HF at each well.

Environmental Monitoring
Nested environmental monitoring bores in alluvium and groundwater
up-gradient and down-gradient on well pads to detect leaks in
accordance with Groundwater Characterisation and Assessment
Program (Appendix D-2)
In accordance with the Company Environmental Monitoring Procedure
(HSE-PR-013), baseline, operational and post operational
groundwater monitoring (quality and level) from water bores and site
environmental monitoring bores.
Baseline groundwater monitoring (quality) has been implemented for
more than one year.
Continuous Gasclam loggers installed on environmental monitoring
bores downstream of well will continuously measure methane, VOCs
and groundwater depth during surveillance phase.

Class 2 risk. This risk
lies on the acceptance
threshold and require
active monitoring by
management.
A well control event
that may result in
well integrity failure
and sub-surface
leaks. Serious but
rare (once every 5
years or less).

To ensure risks to deep
potable groundwater
aquifers are managed
to ALARP, the
Company will
implement the suite of
management measures
outlined in the previous
column.

Induction of all personnel prior to going on
site.
Pressure testing and calibration of HF
equipment to occur prior to stimulation.
Independent review of TGS14 HF Operations
Environment Risk review by Dr Christopher
Green.
Independent review of well integrity prior to
HF Operations commencing.
Peer review of Companys Hydrological
environmental risk assessment by Professor
Neil Coles (UWA).

HF and Reinjection Operations
Real time surface monitoring of anomalous
pressure changes during HF activity and
rapid shutdown of pumping procedure
according to the Company's Micro Seismic
Monitoring Procedure (HSE-PRO-020):
Green: All events PPV<3.5mm/s.
Response: Continue pumping as per schedule.

Orange: Recorded event >3.5 mm/s and <16
mm/s.
Response: Continue pumping at current rate.
Adjust ML 3.5 and ML 4.5 categories.

Red: Recorded event >16 mm/s.
Response: Shut down. Do not bleed off.
Observe microseismic for 3 hours.

Certified flowback equipment and contractor
flowback procedures followed.
Pressure testing on all equipment prior to
commencing reinjection.
Redundancy in pumps used for reinjection.
3/16 (~950 micron) in-line filter to be installed
to remove solids prior to reinjection to
formation.

Monitoring
Baseline monitoring of naturally occurring
microseismic events in the region prior to
commencing activities. Collection of baseline
information will determine if the Activity area
is prone to natural micro-seismic events and
the relative magnitude of these, should they
occur.

Micro-seismic monitoring of fracture
propagation will occur in real time during
stimulation activities. Real time monitoring
for seismic events to be undertaken during
operations as outlined in the Micro Seismic
Monitoring Procedure (HSE-PRO-020).



TGS14 EP Summary Document_Rev_2 Buru Energy Limited 16
Environmental
characteristic
Description Potential Impact Management Measures Risk Implementation Strategy
assessment by Professor Neil
Coles (UWA)

Receptor
The only deep potentially potable
(based on TDS information only)
aquifer is the Betty formation in the
Grant system in the Asgard and
Valhalla area and this is too deep to
be accessible for use evidence of
natural migration of hydrocarbons
to this formation from the Laurel
and other naturally occurring
constituents suggest the Betty is
unlikely to be potable.
The Betty formation flows west from
this area and becomes increasingly
saline and is extremely slow moving
(m/year).
Soils and
Surface water
Soils:
The Canning Basin topography is dominated by
sandplains, however, in the lower parts of the
west and south, stony plains on weathered or
fresh rock occur. There are also some rocky
plateaux and ridges. The Fitzroy sandplains are
comprised of longitudinal sand ridges, without
surface drainage. The plain is covered by
longitudinal sandy dunes that trend mainly in a
west northwest to east southeast direction.
Individual dunes can reach 250 km in length with
an average spacing of 250 to 500 m and ~6-
11 metres in height.
There will be minimal disturbance of the
landforms of the surrounding area from the
Activity as the Activities will be confined to
existing well sites and access tracks.
The geology and geomorphology of the Activity
area indicates that there is an extremely
low/implausible probability of the occurrence of
acid sulphate soils. Given the lack of ground
disturbing works associated with the Activities, it
is highly unlikely that the Activity will impact soils.

Surface Water:
The primary catchment in the Activity area is the
Fitzroy River catchment. The Fitzroy River flows
for 733 km from the King Leopold and Mueller
Ranges into King Sound south of Derby. The
Fitzroy River has large but short duration floods
(i.e. less than two months in the wet season);
flood inundation is most frequently confined to
the areas adjacent to the main channel. The local
area in both Yulleroo and Valhalla is
characterised by limited surface drainage and
surface flow will be mainly sheet-flow in tracts
downslope from uplands and extending for short
distances into dune field.
Valhalla North 1
The nearest water courses to Valhalla North 1
well site are the Mount Wynne Creek,
approximately 5 km north, and Mount Hardman
Creek, approximately 11 km south. Both creeks
are intermittent and flow into the Fitzroy River.
Asgard 1
Potential Impacting Mechanisms
Contamination of surface water.
Soil erosion, sedimentation or
compaction.
Contamination of soil or surface
water due to spills or leaks of
dangerous goods.
Inappropriate rehabilitation at the
conclusion of the Activity.

Source-Pathway-Receptor Analysis
Source Chemical Risk Assessment
refer to Shallow Groundwater
Aquifers Section above.

Pathway
Given the large distance to the
closest surface water body to the
well sites and operations will be
conducted during the dry season it
is implausible that minor spills will
impact on surface water systems.
Minor spills can be readily scraped
up and removed to an approved
waste disposal facility under the
OSCP.
The largest feasible spill that may
occur will be readily contained and
absorbed on the gravel hardstand
area within the perimeter fence of
the well site and can be readily and
rapidly scraped up and placed on a
HDPE lined storage are for
removal from site.
Largest feasible spill from a vehicle
collision or rollover will be readily
contained within 100 m of crash
site, cleaned-up by placing on
HDPE lined storage area and
removed to a licensed waste
disposal facility.
Receptor
Nearest permanent surface water
body to Yulleroo well sites is
Taylors Lagoon located ~ 4 km
Operational Management
Dangerous goods will be stored in accordance with Dangerous
Goods Safety (Storage and Handling of Non-Explosives)
Regulations 2004 (WA), including segregation if applicable, in self
bunded (double skinned) tanks.
Dangerous goods will be transported in accordance with Dangerous
Goods Safety (Road and Rail Transport of Non-Explosives)
Regulations 2007.
Dangerous goods will be stored within impermeable bunding such
as bunded pallets or double skinned tanks.
All vehicle movements to be undertaken in accordance with Travel
Management Procedure (HSE-PR-002):
o Vehicles driving on station roads limited to 80 km/h
o Vehicles driving on the well access tracks limited to 60 km/h
o No driving at night except under approved circumstances
defined in the approved EP or in an emergency.
Vehicles and personnel access restricted to existing access track,
well site and camp site.
Repair of localised soil erosion or sedimentation on access track,
well site and camp site, where required.
The Contractor will be required to provide full HSE documentation
for site specific operations that will bridge to the approved
Environment Plan, and Company supporting procedures, for the
Activity. Transportation will be undertaken in accordance with the
Contractors procedures or JHA.
Independent verification of well-maintained and operating
machinery, vehicles and equipment will be required from the
contractor.
Returned proppant will be required to meet Class 1 landfill
guidelines prior to beneficial use.
Refuelling and fuel transfer will be undertaken in accordance with
the Refuelling Procedure (HSE-PR-011) including:
o Vehicles and mobile equipment refuelling will be undertaken
within impermeable lined and bunded designated refuelling
areas at the well sites.
o Refuelling of stationary machinery and equipment will be
undertaken using a mobile tanker with a drip tray under
refuelling points.
o Refuelling operations to be manned at all times and spill kits
available for immediate containment and clean-up of spills
of dangerous goods.
Hazardous substances will be stored, including segregation if
applicable, in accordance with relevant MSDS. All hazardous
substances will be stored within impermeable bunds such as
bunded pallets, inside PVC lined bunded area etc.
Given the distance of
the Activities from the
nearest surface water
bodies and the
management and
mitigation measures
that will be
implemented, risks to
soils and surface water
are typically in the
Class 1 (LOW) risk
Class.

The following potential
impacts were ranked as
Class 2 risks. These lie
on the acceptance
threshold but require
active monitoring by
management:
Vehicular accidents
en route to and from
site resulting in
potential spill of
hazardous or
dangerous goods:
Serious but rare
event (once every 5
years or less).
A well control event
that may result in
surface spills.
Serious but rare
event (once every 5
years or less).
Inappropriate
storage or handling
of dangerous goods
or hazardous
substances including
hydraulic fracturing
fluid constituents:
Serious but rare
(once every 5 years
or less).
Planning and Preparation for HF Operations
Induction of all personnel prior to going on
site.
The Activity will occur during the dry season
when there is no surface water in the area.
Verification of equipment integrity required to
be provided by contractor prior to activities
commencing.
Contractor to pressure test all equipment prior
to the commencement of HF Activities.
Storage and Handling Facilities
All hazardous chemicals to be stored in
dedicated bunded areas in accordance with
the relevant regulations and MSDSs.
Maintain the hazardous substances area in a
clean and environmentally acceptable
manner.
MSDS's to be stored on site for all hazardous
substances.
Handling of hazardous substances to be
undertaken by suitably trained personnel only
and in accordance with contractors
procedures or JHA.
Waste Management
Lidded bins to be made available on site for
disposal of waste.
All grey water to be treated through an
Aerated Wastewater Treatment System
(AWTS).
Treated grey water will then be released into
a leach drain that is filled with ballast rock and
covered with soil.
All sewage to be stored on site then taken off
site by a licenced contractor for disposal at a
licenced facility.
All putrescible wastes (e.g. food scraps) to be
segregated and stored in securely covered
bins for disposal at a licensed waste disposal
facility.
All inert and industrial wastes (e.g. cardboard
boxes) to be segregated and stored in bins
for recycling or disposal at a licensed waste


TGS14 EP Summary Document_Rev_2 Buru Energy Limited 17
Environmental
characteristic
Description Potential Impact Management Measures Risk Implementation Strategy
The closest major water courses to Asgard 1 well
site are the Fitzroy River, approximately 30 km
south and the ephemeral Mt Hardman Creek,
approximately 25 km northwest.
Yulleroo 3 and Yulleroo 4
The closest drainage area to the Yulleroo well
sites 4 is a small intermittent drainage line,
located approximately 5 km and 8 km south of
Yulleroo 3 and Yulleroo 4 respectively. Taylors
Lagoon and the associated clay pans are
situated approximately 7 km and 4 km northeast
of the well sites.
northeast of Yulleroo 4.
Nearest surface water bodies to
Valhalla & Asgard are Mt Wynne
and Mt Hardman creeks. Mt
Wynne Creek is located ~4 km
northwest of Valhalla North and Mt
Hardman Creek is located ~2 km
southeast of Valhalla North 1.
Nearest surface water body to the
Yulleroo access track is Taylors
Lagoon is located ~5 km northeast
The access track (Calwynyardah
Noonkanbah Road) to Asgard 1
crosses Mt Wynne Creek and Mt
Hardman Creek, ephemeral
tributaries that flow into Fitzroy
River. Given that the Activity will be
undertaken during the dry season,
it is highly unlikely these creeks will
contain surface water.
Given the large distance to the
closest surface water body to the
well sites and operations will be
conducted during the dry season it
is implausible that minor spills will
impact on surface water.

Designated parking area within the cleared well site for machinery
and vehicles.
The Contractor will be required to provide full HSE documentation
for site specific operations that will bridge to the approved
Environment Plan, and Company supporting procedures, for the
Activity. Handling of hazardous substances to be undertaken by
suitably trained personnel in accordance with Contractors
procedures or JHA.
All site personnel to have appropriate PPE equipment including
respiratory protection where appropriate.
In accordance with the Operations Management Procedure (OP-
PR-025) completion of a weekly operational checklist:
o Storage of dangerous goods and hazardous substances.
o Integrity of bunded areas.
Maximise reuse of flowback water in subsequent HF treatment
between well sites if practicable; final reinjection of flowback into the
target formation at each well site.
Following completion of the Activity, evaporated brine will be
capped and sealed with native clay as part of ongoing rehabilitation
of the Sundown interceptor pond.
The Activity will be for a short duration.

Contractor Design of Service Document
Well specific operational details to be provided by a suitably
qualified Contractor with HF treatment experience including:
o Pressure kickouts and pop-off valves to prevent
exceedances in design pressures.
o Double isolation barriers on fracture stimulation equipment.
o Immediate shutdown monitoring system installed (high and
low pressure systems).
o Exclusion zone around high pressure pumping area during
operations.
o Rig up to facilitate controlled bleed off from the HF
treatment equipment.
o Equipment pressure tested after rig-up and prior to
conducting the Activity.
o Clean water will be circulated through reticulation system to
clean system prior to demobilisation of equipment.
o Certified flowback flowback equipment and flowback best
available techniques followed.
o All fluid will be contained in the designated retention ponds
and tanks.
All chemicals and other substances to be used down hole during
the Activity will be fully disclosed in accordance with regulation
15(9) of the Petroleum and Geothermal Energy Resources
(Environment) Regulations 2012 (WA) and Chemical Disclosure
Guideline (see Appendix to this Summary EP).
Hardstand area will be gravel surfaced and contain small (< 20 L)
volumes of fluid that may spill from the dilute HF fluid and flowback.
All concentrated chemicals directly transferred from Industrial Bulk
Containers (IBC) containers to blender via metred closed loop
flowlines during HF operation there is no double handling.
Maximum of 15,800 L of dilute HF fluid stored at the well site prior
to pumping.
Contractor equipment will be purpose designed and required to
provide evidence that it is well calibrated and in good working order
as part of the selection and mobilisation process.
Regular maintenance to ensure integrity of equipment including
pressure testing, maintenance assessment and fail-safe automation
systems.

Waste Management
Waste will be managed and monitored in accordance with Waste

To ensure risks to soils
and surface water are
managed to ALARP,
the Company will
implement the suite of
management measures
outlined in the previous
column.

disposal facility.
All controlled wastes (e.g. empty fuel drums,
waste oil) to be segregated and stored in a
bunded area for transport and disposal at a
licensed waste disposal facility
All waste, equipment and dangerous goods
and hazardous substances removed from
well sites following the completion of TGS14
operations in accordance with the
Demobilisation Procedure (HSE-PR-021).
HF Operations
Double isolation barriers on fracture
stimulation equipment.
Certified flowback equipment and contractor
flowback procedures followed.
Pressure testing on all equipment at rig-up.
Approved rig up to facilitate controlled bleed
off from the fracture stimulation equipment.
Routine HF well control procedures including
pressure control (chokes, redundant flowback
line, contingency measures).
All spills of dangerous goods and hazardous
substances are reported in accordance with
the Incident Reporting Procedure (HSE-PR-
009).
Refuelling
All refuelling to be undertaken in accordance
with Company's Refuelling Procedure (HSE-
PR-011).
A designated refuelling area to be established
at the camp site.
Well calibrated and maintained machinery,
vehicles and equipment.
Flowback Management at Site
Flowback monitored for presence of liquid
hydrocarbons and separator installed if
required to separate and separated liquids
stored in a HDPE lined and bunded tank
system prior to trucking offsite for disposal.
Characterisation of flowback water to confirm
low toxicology prior to disposal.
Flowback Water
Flowback water contained and isolated to
prevent release of COPC to groundwater,
surface water and soil.
Immediate testing of flowback water to
identify COPC (including NORMs) in flowback
water according to Company's Produced
Water Monitoring Procedure (OP-PR-024).
Certified flowback equipment and contractor
flowback procedures followed.
Pressure testing on all equipment prior to
commencing reinjection.
Redundancy in pumps used for reinjection.
3/16 (~950 micron) in-line filter to be installed
to remove solids prior to reinjection to
formation.
Monitoring
During Operations
Site is manned and so operations will be


TGS14 EP Summary Document_Rev_2 Buru Energy Limited 18
Environmental
characteristic
Description Potential Impact Management Measures Risk Implementation Strategy
Monitoring and Management Procedure (HSE-PR-005) including:
o Waste oil, lubricants or other oil contaminated materials will be
stored in dedicated, labelled containers within a bunded area at
the well sites.
o Chemical drums will be stored within bunded area at well sites.
o Disposal for all industrial waste at a licensed waste disposal
facility in accordance with Environmental Protection (Controlled
Waste) Regulations 2004, where applicable.
Records will be kept of waste type and volume.

Waste Water
The Activity will be for a short duration.
All sewage to be stored on site then taken off site for disposal by a
licenced contractor for disposal at a licenced facility.
All grey water to be treated through an aerated wastewater treatment
system designed to comply with AS/NZS 1546.3: On-site domestic
wastewater treatment units - Aerated wastewater treatment systems.
Treated grey water will be released into a leach drain that is filled with
ballast rock and covered with soil.

Flowback Monitoring and Management
All recovered fracturing fluids will be isolated in imperviousstorage
areas designed to prevent leakage, as required by APPEA Code of
Practice for Hydraulic Fracturing (2011) Guideline 5.
Characterisation of flowback water to confirm low toxicity in
accordance with Produced Water Monitoring Procedure (OP-PR-
024).
Monitor pH levels of flowback water so as to ensure that acid
concentrations are neutralised to the required threshold value
In accordance with the Environmental Monitoring Procedure
(HSEPR- 013), baseline, operational and post operational
groundwater monitoring (quality and level) will be implemented
through the water bores and site environmental monitoring bores.
Construction of Water Retention Ponds with adequate storage
capacity and two layers of 1500 micron HDPE liners interleaved
with Geotextile fabric (A34) in accordance with WQPN39
(DoW,2009).
Flowback water will be contained within lined Water Retention Pond
to prevent release of radioactive material.
In accordance with Produced Water Monitoring Procedure (OP-PR-
024) analysis of flowback water conducted during and immediately
after flowback ceases with radiation meter to detect anomalous
readings above background bore water values/guideline levels.
A radiation meter will be used on site to confirm NORM is below
guideline and background values. If elevated radiation levels
detected then treatment of flowback water to remove solids (which
contain the NORMs) will be undertaken and the solids containing
the NORMs taken to licenced facility for disposal.
Flowback will be monitored for the presence of liquid hydrocarbons
and mobile separator installed to separate liquids, if required.
Separated liquids will be transferred by a flowline and stored in an
impervious lined and bunded tank for trucking offsite to refinery.

Spill Response
Containment, clean up and remediation of minor spills immediately.
Minor spills can be readily scraped up and removed to an approved
waste disposal facility under the Companys OSCP.
The Activity will be a manned operation and therefore visual
monitoring for anomalous conditions, including spills or leaks, will
be undertaken at all times.
Containment, clean-up and remediation of a spill will be undertaken
immediately in accordance with Canning Basin Operations Spill
Response Plan (HSE-ICM-003) (OSCP) and Canning Basin
visually monitored at all times.
Weekly checks of hazardous substance
storage area to ensure no spills in
accordance with the Operations Management
Procedure (OP-PR-025).
Characterisation of Flowback Water in
accordance with Produced Water Monitoring
Procedure (OP-PR-024) to inform disposal
options.
Monitor pH levels of flowback water so as to
ensure that acid concentrations are
neutralised to the required threshold value.
Monitoring of Sundown site in accordance
with any DER licence conditions.
Following Demobilisation:
Checks of well site and associated
infrastructure completed every three months
following the completion of TGS14 Activities.
Following demobilisation, sites are checked
for erosion every 3 months (weather
permitting).
No signs of spills within the Activity area
following demobilisation.
Ongoing monitoring of Sundown site in
accordance with the Company's Blina Oilfield
Care and Maintenance Environment Plan.
Flowback in retention ponds to monitored for
free board.


TGS14 EP Summary Document_Rev_2 Buru Energy Limited 19
Environmental
characteristic
Description Potential Impact Management Measures Risk Implementation Strategy
Operations Incident Management Plan (HSE-ICM-002) (IMP).
Personnel will be trained in the implementation of the OSCP and
ERP. This includes emergency response drills and/or emergency
muster drills conducted regularly.
In the unlikely event of a spill outside of the well site, a monitoring
program to be designed and implemented in consultation with the
DMP.
Reporting, investigating and implementing corrective actions for all
spills of dangerous goods in accordance with Incident Reporting
Procedure (HSE-PR-009).
If anomalous conditions arise, such as a leak, then equipment will
be taken off line and shut-in. This will include shutting down all
pumping or flowback and closing in at the master valve of the well if
necessary.

Monitoring
On-going monitoring of groundwater quality at the environmental
monitoring bore located downstream of the Sundown evaporation
pond as part of groundwater monitoring program.
Monitoring of Sundown site in accordance with any DER licence
conditions.
Biodiversity The Activities will be confined to existing well
sites with no cleaning or ground disturbing works
occurring due to the Activities. The lack of
vegetation clearing associated with the Activities
mitigates many impacts on biodiversity.

Valhalla-Asgard Region
The Valhalla-Asgard region is located in the sub-
region of Fitzroy Trough and is the semi-arid
northern periphery of Canning Basin containing
the middle and lower catchments of the Fitzroy
River. It includes the alluvial plains associated
with the river and also areas of sandplain and
eroded dune surfaces derived from the Canning
Basin. The Valhalla & Asgard areas are located
within the dune areas outside the floodplain.

Yulleroo Region
The Yulleroo area is located in the more coastal
sub-region of Pindanland and is a fine-textured
sand-sheet with subdued dunes and includes the
paleodelta (delta formed in past geological time)
of the Fitzroy River which today exits at King
Sound near Derby. This is the coastal, semi-arid,
north-western margin of the Canning Basin.

The biodiversity occurring in the areas
surrounding the well sites has been well
characterised and documented. This includes
level 1 flora and fauna surveys that were
conducted prior to the drilling of the Petroleum
wells as required under the PGER Act.

Both the Yulleroo and Valhalla regions occur in
the Dampierland bioregion according to the
Interim Biogeographic Regionalisation of
Australia (IBRA). Within the Dampierland, the
vegetation is characterised by pindan
assemblage that occurs on the sand plains.
Pindan is described as a grassland wooded by a
sparse upper layer of trees and a dense, thicket-
forming middle layer of unarmed, phyllodal
Acacia (Beard, 1979). It consists of shrublands
Potential Impacting Mechanisms
Introduction/ spread of weed
species.
Disturbance of native flora species,
including conservation significant
flora species, and native fauna
habitat
Disturbance of native fauna
species including conservation
significant species.
Fauna trapped in open
excavations.
Disturbance of ESAs.
Operational Noise from the well
site and camp site.
Light spill from the well site and
camp site.
Light from flaring.
Inadequate demobilisation.
Attraction of feral fauna to the
Activity area.





Weed Management
Proppant will be sand that is specifically quarried, screened to
specific grade (measured in microns) and quality controlled checked
by the supplier to ensure suitability for HF treatment including no
foreign materials.
All proppant will be certified as weed and pathogen free.
Proppant will be stored in dedicated proppant storage area.
Proppant will be transported to the Activity areas as required and will
be blended into the HF treatment system from the sand handling unit.
As the Activity will not require any vegetation clearing, and vehicle
and personnel access will be limited to the Activity areas, it is unlikely
there will be any direct impacts on native flora, including conservation
significant flora species.
The Company has undertaken various operations in the Activity areas
which include the well site and camp site operations and have not
had any recorded incidents of bush fires being caused by the
Companys operations.
In accordance with the Quarantine Procedure (HSE-PR-024), the
following management measures will be implemented:
o All personnel and equipment will be restricted to existing access
tracks, well sites and camp sites.
o There will be no ground disturbing work during the Activities.
o Personnel will check clothing and shoes for weeks or weed
material when entering from a high risk source area prior to
going onsite in accordance with the Quarantine Logbook (HSE-
FM-011).
Environment and Heritage Induction for operational personnel
including weed species in the Valhalla area.

Operations Management
Boundaries of all well sites, including water retention ponds and flare
pit, fenced and gated to prevent feral fauna, including cattle,
accessing the water source.
Water Retention Ponds will be fenced with ringlock fence with
birdwire at the base. Egress paths constructed from conveyor belt
matting with 50 mm mesh will be installed on open excavations to
allow small fauna to climb out.
Fencing of Water Retention Ponds with ringlock fence and birdwire to
include the flare pit.
Sensor locations for microseismic monitoring program selected based
on access to ensure no disturbance of vegetation.
In accordance with the Operations Management Procedure (OP-PR-
Given no clearing is
required to undertake
the Activities and the
management and
mitigation measures
that will be
implemented, risks to
biodiversity (flora and
fauna) are typically in
the Class 1 (LOW) risk
Class.

The following potential
impact was ranked as a
Class 2 risk. This risk
lies on the acceptance
threshold and require
active monitoring by
management.
Bushfires that may
result from ignition
sources from
operations during
the Activity: Serious
but Rare (once every
5 years or less).

To ensure risks to
biodiversity are
managed to ALARP,
the Company will
implement the suite of
management measures
outlined in the previous
column.



Planning and Preparation
Induction of all personnel prior to going on
site.
The Company has consulted with DFES in
Kimberley regarding appropriate fire breaks
around Operational sites.
Travel
All travel to occur in accordance with the
Company's Travel Management Procedure
(HSE-PR-002). This includes:
o Vehicles driving on station roads limited
to 80 km/hr during daylight hours,
o Vehicles driving on well access tracks
limited to 60 km/hr during daylight hours,
o Vehicle speeds during crew transfers
outside of daylight hours to be limited to
60 km/h on main Noonkanbah road and
40 km/hr in Yulleroo region and on
Asgard access road,
o Should proppant transfer be undertaken
outside of daylight hours, vehicle speeds
to be limited to 60 km/h on main
Noonkanbah road and 40 km/hr in
Yulleroo region and on Asgard access
road.
General Operations
All vehicle movements to be restricted to
access tracks and specified activity areas.
No clearing to be undertaken as part of
works.
Biosecurity Checklist (HSE-FM-007) to be
completed for frac spread prior to arriving in
Yulleroo region and prior to arriving in
Valhalla-Asgard region.
Egress paths constructed from conveyor belt
matting with 50 mm mesh will be installed on
water retention ponds during Activities.
Fire-fighting equipment located at well site
and camp site with personnel trained in its
use.


TGS14 EP Summary Document_Rev_2 Buru Energy Limited 20
Environmental
characteristic
Description Potential Impact Management Measures Risk Implementation Strategy
and grasslands characterised by the low tree
savannah mapped as ribbon grass with baobabs,
bauhinia and beefwood.

No priority or listed plant species will be affected
by the Activities. No weed species were identified
at the well sites while three weed species have
been identified along the access route to the
Valhalla North 1 well site. These were Calotropis
procera (Rubber Bush), Sida cordifolia (Flannel
Weed) and Cenchrus ciliaris (Buffel Grass). The
key anthropogenic dispersal mechanisms for
these species are ground disturbing works and
driving off road, neither of which will be permitted
during the current Activities.

The fauna assemblage of the Dampierland and
Great Sandy Desert bioregions is unique as it
represents a blending of Western Australias
desert and tropical coastal zones. The region is
characterised by fauna species including the red
kangaroo (Macropus rufus), nailtail wallaby
(Onychogalea sp.), the dingo (Canis lupus
dingo), various goanna species, snakes, lizards,
and various birds including the friar bird
(Philemon sp.), peaceful dove (Geopelia placida),
brown quail (Coturnix ypsilophora), crested
pigeon (Ocyphaps lophotes), white cockatoo
(Cacatua sp.), honeyeater (Fam. Meliphagidae)
and bush turkeys (Ardeotis australis). Domestic
cows and cats are also common.

During on-ground surveys, the Rainbow Bee-
eater (Merops lagotis) was identified in both the
Yulleroo and Valhalla & Asgard areas. The
Company has considered the presence of the
Rainbow Bee-eater in the Activity areas, and
given that this species is highly mobile and can
easily fly away, it is unlikely this species will be
impacted by the Activity. Bilbies (Macrotis lagotis)
were not observed during the on-ground surveys
of the Activity areas however there have been
positive identifications of Bilbies in the wider
Yulleroo area. The Company is monitoring this
population in partnership with the Yawuru
Traditional Owners of the Yulleroo region. During
previous operations in the Yulleroo region
including drilling of the wells, the Company has
had no impact on Bilby populations.

The nearest Environmentally Sensitive Area
(ESAs) to the Yulleroo region is Taylors Lagoon,
located approximately 4 km northeast of Yulleroo
4. The nearest ESA to the Valhalla region is
Camballin Floodplain, a Schedule 1 area located
24 km east of Valhalla North 1. No known
Threatened Ecological Communities or Priority
Ecological Communities (PEC) occur at the well
sites or in the near vicinity. As the Activity will not
require any vegetation clearing, and vehicle and
personnel access will be limited to the Activity
areas, it is unlikely there will be any direct
impacts on ESAs as a result of the Activities.
025), completion of a weekly operational checklist.
Mobilisation of HF treatment equipment to and from each Activity
area will be undertaken once only over a short period (2-3 days).
Loud (90 dB close to source) HF treatment operations (i.e. pumping)
will be confined to daytime operations and will be short duration (~
one day).
Flow-back operations (i.e. separator and gas flare) will have low
noise levels which will be barely audible beyond well site.
Well maintained and muffled trucks.
Security and safety lighting will be situated at the centre of the well
site and light levels at the perimeter of the well site are expected to
be very low (ambient levels). No lighting is required around the
perimeter of the well site.
Lighting intensity from flare will attenuate over a short distance at
ground level and will only be visible in the sky vision.
Only low light sources are used at the camp site (i.e. no floodlights).
Camp site is arranged with internally lit walkways so that no artificial
light sources illuminate the vegetation near the camp site.
Demobilisation to be undertaken during the day.
The fence surrounding the well site, including the water retention
ponds and flare pit, will be left in place and gate kept closed.

Bush Fire Prevention
Maintenance of fire breaks at well sites undertaken prior to Activity
Flaring of gas will be keep to a minimum in accordance with APPEA
Code of Practice for Hydraulic Fracturing (2011) Guideline 6.
Flaring to be undertaken in a closed loop flare system with design of
flare (sizing) and location appropriate for expected volumes.
Flaring can be controlled readily by shutting in the well if anomalous
conditions occur during flaring.
Horizontal flare pit will be used to contain any surges in the flare
associated with the combustion of hydrocarbons.
Vehicles and personnel access to be limited to delineated access
track, camp site and drill pad to eliminate the chance of fire ignition
sources.
The following fire prevention measures will be implemented:
o Maintenance of a firebreak on the outside of the well site and
camp site fence line.
o Firefighting equipment located at the well site and camp site and
personnel trained in its use.
o Designated smoking areas.

Waste Management
All sewage will be stored and then taken off site by a licenced
contractor for disposal at a licenced facility.
Treated grey water will be discharged into a leach drain that is filled
with ballast rock and covered with soil.
Putrescible waste stored in lidded bins/skips which are kept closed.
All waste will be removed from the Activity areas upon demobilisation.

Travel Management
In accordance with the Travel Management Procedure (HSE-PR-002):
o Vehicles driving on station roads limited to 80 km/h during daylight
hours.
o Vehicles driving on the well access tracks limited to 60 km/h
during daylight hours.
o Crew changes to occur at 0600 hrs and 1800 hrs.
o Vehicle speeds during crew transfers outside of daylight hours to
be limited to 60 km/h on main Noonkanbah road and 40 km/hr in
Yulleroo region and on Asgard access road.
o Should proppant transfer be undertaken outside of daylight hours,
vehicle speeds to be limited to 60 km/h on main Noonkanbah road
and 40 km/hr in Yulleroo region and on Asgard access road.
Camp site to be arranged with internally lit
walkways and common areas so that light
and noise spill is directed inwards.
No personnel permitted outside of the activity
area (well site, camp site or access tracks) at
any time.
Low light sources used at camp site (no
floodlights or similar).
Maintenance of firebreak outside of fence
line.
Only diesel vehicles used in operations.
Boundary of well sites and Sundown
evaporation pond area fenced and gated to
prevent macro-fauna (including cattle)
entering open excavations.
Waste Management
Lidded bins to be made available on site for
disposal of waste.
All grey water to be treated through an
Aerated Wastewater Treatment System
(AWTS).
Treated grey water will then be released into
a leach drain that is filled with ballast rock and
covered with soil.
All sewage to be stored on site then taken off
site by a licenced contractor for disposal at a
licenced facility.
All putrescible wastes (e.g. food scraps) to be
segregated and stored in securely covered
bins for disposal at a licensed waste disposal
facility.
All inert and industrial wastes (e.g. cardboard
boxes) to be segregated and stored in bins
for recycling or disposal at a licensed waste
disposal facility.
All controlled wastes (e.g. empty fuel drums,
waste oil) to be segregated and stored in a
bunded area for transport and disposal at a
licensed waste disposal facility
All waste, equipment and dangerous goods
and hazardous substances removed from
well sites following the completion of TGS14
operations in accordance with the
Demobilisation Procedure (HSE-PR-021).
Monitoring
Bilby Monitoring
A site walkover of the area surrounding
(within 100 m) of the Yulleroo 1, Yulleroo 3
and Yulleroo 4 well sites to be undertaken by
Company Environmental Scientists to identify
any active bilby burrows.
Should active Bilby burrows be identified, a
fine-scale monitoring program will be
implemented consistent with the program
implemented during the drilling of the
Yulleroo 4 well and described in the
Companys Greater Bilby Monitoring
Procedure (HSE-PR-019).
During HF Operations
Weekly inspection of activity area for impacts
outside of activity area in accordance with the


TGS14 EP Summary Document_Rev_2 Buru Energy Limited 21
Environmental
characteristic
Description Potential Impact Management Measures Risk Implementation Strategy
o Bilby road signs to be maintained along the main Yulleroo access
track near areas where habitat suitable for Bilby populations is
present.
Vehicle and personnel access limited to the well site, camp site and
access track to prevent disturbance outside of Activity area.
In accordance with the Operations Management Procedure (OP-PR-
025) completion of a weekly operational checklist including:
o No disturbance outside of the Activity areas.
o Inspection of fencing and egress paths.
Broome Veterinary Hospital (9192 1319 - 24 hour emergency service)
or DPAW Wildcare Helpline (9474 9055 - 24 hour telephone service)
will be contacted for advice if any fauna become injured.
Environment and Heritage Inductions for operational personnel
including conservation significant species.
A site walkover of the area surrounding (within 100 m) of the Yulleroo 3
and Yulleroo 4 well sites will be undertaken by Company Environmental
Scientists to identify any active Bilby burrows. In the unlikely event that
bilby burrows are identified, a fine-scale monitoring program will be
implemented consistent with the program implemented during the
drilling of the Yulleroo 4 well and described in the Companys Greater
Bilby Monitoring Procedure (HSE-PR-019).

Camp Site
A site walkover of the area surrounding (within 100 m) of the
Yulleroo 1, Yulleroo 2, Yulleroo 3 and Yulleroo 4 well sites will be
undertaken by Company Environmental Scientists to identify any active
Bilby burrows. This will be undertaken prior to mobilisation and
following 3 months of activities. Should active Bilby burrows be
identified, a fine-scale monitoring program will be implemented
consistent with the program implemented during the drilling of the
Yulleroo 4 well and described in the Companys Greater Bilby
Monitoring Procedure (HSE-PR-019).
No personnel are permitted outside the boundaries of the Camp Site at
any time.
The camp site will be arranged with internally lit walkways, thereby
minimising light spill outside the boundaries of the camp site.
Company's Operations Management
Procedure (OP-PR-025).
Weekly inspection of egress paths on open
excavations and fencing around operational
sites.
Weed survey around sites to be undertaken
following operations.
Post Operations
Weed survey around sites to be undertaken
following operations.
Fence surrounding the well site will be left in
place and gate closed to prevent macro-fauna
entering the well site.
Egress paths to be present in all open
excavations and flare pit upon demobilisation.



Atmosphere
(Air Emissions)
Recent detailed international reviews of fugitive
emissions from shale gas wells have shown
emissions and human health risks are low
provided operations are properly run and
regulated. Management of flowback using
Reduced Emissions Completion (REC), where
methane and other VOC emissions are
minimised, has been adopted for the HF activities
in TGS14. However, undertaking the TGS14
activities presents an opportunity to collect robust
data regarding the fugitive emissions associated
with HF activities.

This opportunity will be taken by the Company
who will implement a quantitative air monitoring
study as part of TGS14 Activities. This will
confirm that the Activities are low risk to the
environment and human health.

Air emissions may also be produced through
vehicle and equipment use, the same as
emissions associated with driving a vehicle for
everyday activities. Finally as Company access
tracks are gravel sheeted, vehicle traffic will
generate dust.
Potential Impacting Mechanisms
Production of atmospheric pollutants
due to:
Inadequate flaring.
Gas leaks from couplings or flow
lines.
Volatiles organic carbons from
Retention Ponds.
Radon radiation from degassing of
flowback fluid
Emissions from vehicle and
equipment use.
Generation of dust on access
tracks.
Reduced Emissions Completions (REC), where methane and other
VOC emissions are minimised, adopted as standard operating
practice.
Couplings and flow lines for flow-back reticulation system pressure
tested for leaks.
Gas reticulation system from flow-back monitored for gas leaks.
Regular monitoring of Water Retention Ponds for build-up of
hydrocarbons.
Radiation monitoring of flowback water on regular basis.
Air quality monitoring will be conducted during Activity at one selected
well site for Measurement and Monitoring of Emission Flux.
Data collected during air quality monitoring will be provided to the
DMP following analysis at the conclusion of the TGS14 program.
All site personnel to have appropriate PPE equipment including
respiratory protection where appropriate.
Vehicle and equipment use will be minimised.
Independent verification of well-maintained and operating machinery,
vehicles and equipment will be required from the Contractor.
Recording and reporting greenhouse gas emissions in accordance
with the Company HSE Reporting Procedure (HSE-PR-014).
Regular assessment and maintenance of Company access tracks,
including the implementation of dust control measures as required.
Due to the detailed
international reviews
regarding fugitive
emissions from shale
gas well completions
and the management
and mitigation
measures that have
been adopted to
minimise air emissions,
risks to the atmosphere
through air emissions
are in the Class 1
(LOW) risk class.


Planning and Preparation for HF Operations
Operational air quality monitoring undertaken
at one selected well pad
Equipment in place and calibrated to measure
emissions.
Induction of all personnel prior to going on
site.
Induction of PIC's to include reporting
requirements for emissions and discharges.

During HF Operations
Operational air quality monitoring undertaken
at one selected well pad
Reporting of all spills and incidents in
accordance with the Company's Incident
Reporting Procedure (HSE-PR-009).
Well calibrated and maintained machinery,
vehicles, flowlines, valves and equipment.
Installation of 3 phase separator to separate
and store liquid hydrocarbons in approved
storage tank for removal to refinery, in the
event of significant liquids (e.g. condensate or
oil) flowback.
Flaring of all vented hydrocarbons in a
horizontal flare pit.
Vehicle fleet records maintained including
type of vehicle, fuel usage, age of vehicle and


TGS14 EP Summary Document_Rev_2 Buru Energy Limited 22
Environmental
characteristic
Description Potential Impact Management Measures Risk Implementation Strategy
mileage.
Any incidence of fire extinguisher usage
reported in accordance with Company's
Incident Reporting Procedure (HSE-PR-009)
Regular checks and monthly reporting of
venting, flaring, fuel usage.
Integrity of flowlines and storage tanks
checked in accordance with the Company's
Asset Integrity Management Procedure (OP-
PR-026) to minimise fugitive emissions.
Quantitative records of volume of flowback
water maintained.
All site personnel to have appropriate PPE
equipment including respiratory protection
where required.

Refuelling
All refuelling to be undertaken in accordance
with Company's Refuelling Procedure (HSE-
PR-011).
A designated refuelling area to be established
at the camp site.

Disposal of Flowback Water
Characterisation of flowback water to identify
COPC against NPI criteria.
Records of volume of flowback water
disposed of at Sundown site maintained.

Monitoring and Auditing
Planning and Preparation:
Installation and calibration of air emissions
monitoring equipment included in the
mobilisation checklist in accordance with the
Company's Operations Management
Procedure (OP-PR-025).
Operations
Site is manned and so operations will be
visually monitored at all times.
Weekly checks of facility to ensure no fuel
spills in accordance with the Company's
Operations Management Procedure (OP-PR-
025).
Monthly completion of the Company's Safety
and Environment Reporting Form (e.g. HSE-
FM-006).
Records of volumes of flowback water
disposed of at Sundown maintained.
All complaints relating to loss of amenity due
to air emissions will be recorded as an
incident according to the Company's Incident
Reporting Procedure (HSE-PR-009).
Amenity The wells at which the Activity will be undertaken
are located within sparsely populated areas with
limited settlement, transport or communications
infrastructure. Land use is generally open range
pasture grazing. The well sites where the
Activities will be undertaken are situated at least
20 km from the nearest homestead, 30 km from
the nearest community and 70 km from the
nearest town. While the remoteness of the areas
presents logistical and operational challenges, it
does mean that impacts to amenity are mitigated
Potential Impacting Mechanisms
Increased traffic
Increased noise, light or vibrations.
Impacts on visual amenity.
Microseismic event
Communication prior to mobilisation and weekly updates and notices
to Councils, Traditional Owner, Groups, pastoralists during the
Activity.

Operations Management
Vehicles and personnel access to be limited to the camp site and
access track to prevent disturbance outside of Activity area.
Vehicles will comply with the Travel Management Procedure (HSE-
PR-002), which includes speed limits.
Vehicles and personnel access to be limited to the camp site and
Due to the remote
location of the well
sites, the short duration
of the activities and the
communication that will
occur with key
stakeholders, risks to
the amenity of the area
are in the Class 1
(LOW) risk class.

Planning, Communication and Consultation
Induction of all personnel prior to going on
site.
The Company has commenced discussions
with local government including the Kimberley
Police and the Department of Fire and
Emergency Services (DFES) regarding the
Activity.
The Company has on-going consultation with
local landholders and other stakeholders


TGS14 EP Summary Document_Rev_2 Buru Energy Limited 23
Environmental
characteristic
Description Potential Impact Management Measures Risk Implementation Strategy
through the absence of nearby receptors.

Disruption to traffic in the area presents a
possible impact on amenity. However, all
equipment will be mobilised to site over a short
period and so the impact on amenity is expected
to be low. Traditional Owners will be fully
engaged in updates and invited to site to view the
program activities when operational under
Company specified safety arrangements. Access
to their lands will be unrestricted by the Activity
except at the well site, except by prior
permission, because of safety requirements.

Any elevated noise and light during Activities will
typically occur during daylight hours and will be of
short duration (~2 hours).

Hydraulic fracturing does cause microseismic
events, thought these are 10,000 to 1,000,000
times weaker than seismic events that can be felt
at the surface. There are 300,000 fracs per year
in the US and no reports of significant
microseismic events.

A detailed review of geological features and
geohazards in the Activity area has been
undertaken from seismic survey maps and well
logs to determine proximity to natural fault lines
and potential risk prior to commencing the
Activity.
access track to prevent disturbance outside of Activity area.
In accordance with the Company Operations Management Procedure
(OP-PR-025), completion of the weekly operational checklist.
All equipment, personnel and supplies will be demobilised from the
well site and camp site at the completion of Activities.
Mobilisation of HF treatment equipment to and from each Activity
area will be undertaken once only over a short period (2-3 days).
The fence surrounding the well site, including the water retention
ponds and the flare pit, will be left in place and gate kept closed to
prevent stock entering the well site.
Loud (90 dB close to source) HF treatment operations (i.e. pumping)
will be short duration (~ one day).
Flow-back operations (i.e. separator and gas flare) will have low
noise levels which will be barely audible beyond well site.
Well maintained and muffled trucks, equipment and machinery.
The camp site will be oriented with internally lit walkways to mitigate
light spill into the surrounding areas.
Lighting intensity from flare will attenuate over a short distance at
ground level and will only be visible in the sky vision.
Only low light sources are used at the camp site (i.e. no floodlights).
Camp site is arranged with internally lit walkways so that no artificial
light sources illuminate the vegetation near the camp site.
Security and safety lighting will be situated at the centre of the well
site and light levels at the perimeter of the well site are expected to
be very low (ambient levels). No lighting is required around the
perimeter of the well site.
Microseismic
Real time monitoring of anomalous pressure changes during
reinjection activity and rapid shutdown of pumping in accordance with
Micro Seismic Monitoring Procedure (HSE-PR0-020) including
thresholds for ceasing operations.
The Company will
continue to engage and
communicate with key
stakeholders prior to,
during and after the HF
program.

regarding the Activity including regular
notice/updates until completion of the Activity.
Communication with Main Roads will occur
prior to activities commencing and a Traffic
Management Plan developed for the activities
if required.
Review of geological features in the Activity
area from Seismic survey maps to determine
potential risk and proximity of fault lines prior
to commencing activities.

HF Operations
Microseismic
Micro-seismic monitoring of fracture
propagation will occur in real time during
stimulation activities. Real time monitoring for
seismic events to be undertaken during
operations as outlined in Company's Micro
Seismic Monitoring Procedure (HSE-PRO-
020).

Noise and Light
The contractor must ensure that all
equipment is maintained and muffling
equipment applied where required.
Camp site to be arranged with internally lit
walkways and common areas so that light
and noise spill is directed inwards.
Contractor representative to use lowest light
levels while still complying with Australian
Safety Standards.
Any noise or light complains during
operations to be investigated in accordance
with the Company's Incident Reporting
Procedure (HSE-PR-009). Where a complaint
has been received, the Company will
investigate the complaint and implement
further mitigation measures where required.

Traffic & Dust Management
All travel to comply with the Company's
Travel Management Procedure (HSE-PR-
002).
Vehicle activity will be limited to designated
access routes and operational areas.
Dust management measures implemented
where required.
Heavy vehicle movements on station tracks
limited to periods when track surface is stable
and unlikely to be rutted/damaged (i.e. during
wet weather movements of rig).

Monitoring
Planning and Preparation
Communication with affected landholders in
accordance with the Company's Land Access
Consultation Procedure (LAE-PR-002).
Baseline monitoring of naturally occurring
microseismic events in the region prior to
commencing activities. Collection of baseline
information will assist determining if the
Activity area is prone to natural micro-seismic
events and the relative magnitude of these, if


TGS14 EP Summary Document_Rev_2 Buru Energy Limited 24
Environmental
characteristic
Description Potential Impact Management Measures Risk Implementation Strategy
they occur. Geoscience Australia database
also interrogated for Canning Basin seismicity
monitoring to provide long time series of
magnitude and location of significant seismic
events throughout the Canning Basin
Operations
Real time monitoring of anomalous pressure
changes during HF activities and rapid
shutdown of pumping as outlined in
Company's Micro Seismic Monitoring
Procedure (HSE-PRO-020)
All complaints relating to loss of amenity will
be recorded as an incident according to the
Company's Incident Reporting Procedure
(HSE-PR-009).
Monitoring of access track and maintenance
grading/ dust suppression implemented as
required.

Post Operations
All waste, equipment and dangerous goods
and hazardous substances removed from
well sites following the completion of TGS14
operations in accordance with the
Demobilisation Procedure (HSE-PR-021)
Checks of well site and associated
infrastructure completed every three months
following the completion of TGS14 Activities.
Fence surrounding the well site will be left in
place and gate closed to prevent third party
access.
Well cellar to be fenced or covered following
demobilisation.

Cultural
Heritage and
Community
The Company recognises the Traditional
Owners, and all aboriginal peoples and groups,
of the Activity area and their affinity with the land.
The Company has a strong and valued working
relationship with Aboriginal Peoples and groups,
demonstrated through:
Heritage Protection Agreements in place for
exploration activities to ensure Aboriginal
heritage is protected.
Conducting heritage surveys before
commencing work on Traditional Owners
land.
Keeping the relevant communities and
groups informed of Company exploration
activities.
Engaging appropriate Traditional Owners as
cultural monitors during ground disturbing
exploration activities in the field.

The Company has also undertaken a
comprehensive engagement program with
Traditional Owners by virtue of a strategic gas
roadmap process. This establishes a
participatory process that encompasses
Traditional Owner values and heritage and
ongoing community engagement in Company
planning and development of this potential
resource. This includes the support of
independent specialist reviewers to provide
Potential Impacting Mechanisms
Disturbance of cultural heritage
site/s or object/s outside of Activity
area.
Disruption of local landholders.
Damage to property or disturbance
of stock.
Impact on Traditional Owners
Sense of Place for region.








Operations Management
Communication prior to mobilisation and weekly updates and notices to
Councils, Traditional Owner, Groups, pastoralists during the Activity.
On-going communication with Traditional Owners through the Buru
Community Liaison team based in Broome.
Traditional Owner representatives will be invited to well sites to observe
operations under Company specified safety arrangements.
Vehicles and personnel access to be limited to the camp site and
access track to prevent disturbance outside of Activity area.
Vehicles will comply with the Travel Management Procedure (HSE-PR-
002), which includes speed limits.
In accordance with the Company Operations Management Procedure
(OP-PR-025), completion of the weekly operational checklist.
Environment and Heritage/Cultural Awareness Inductions with local
Traditional Owner representatives for operational personnel, including
the requirement to stay within Activity area.
The fence surrounding the well site, including the water retention ponds
and the flare pit, will be left in place and gate kept closed to prevent
stock entering the well site.
All equipment, personnel and supplies will be demobilised from the well
site and camp site.
Demobilisation to be undertaken during the day.
Due to strong and
valued working
relationship that the
Company has with
Traditional Owners in
the region, the
comprehensive
engagement process
the Company is
undertaking with the
Traditional Owners and
as Activities are
occurring on previously
cleared well sites, risks
to the cultural heritage
and community as a
result of the Activities
are in the Class 1
(LOW) risk class.

The Company will
continue to engage and
consult with key
stakeholders prior to,
during and after the HF
program.




Planning, Communication and Consultation
Community open days at major towns;
specific agency, local government, business,
pastoralist, other stakeholder and community
group presentations; information sharing
through printed media advertisements;
conducting regional school lesson programs
on petroleum science;
Cultural Induction of all personnel prior to
going on site.
On-going communication with Traditional
Owners through the Buru Community Liaison
team based in Broome.
Independent peer review of key risk areas by
recognised leading specialists and made
available to stakeholders.
Provide support for Traditional Owners to
engage independent specialist advice through
Specialist Panel Review process.
Consultation with Traditional Owner groups to
understand community concerns and address
concerns through the Specialist Review
process.
Development of a joint Yulleroo Gas roadmap
and Asgard/Valhalla Gas roadmap including
joint risk assessment review workshops with
TO groups and government agencies.
During Operations


TGS14 EP Summary Document_Rev_2 Buru Energy Limited 25
Environmental
characteristic
Description Potential Impact Management Measures Risk Implementation Strategy
expert advice to Traditional owners regarding the
environmental risks associated with the proposed
Activities. It also includes the establishment of an
accredited training and employment program for
Environmental Science Cadets with candidates
from Traditional owner groups to undertake the
ongoing environmental monitoring program for
the gas development; the active identification of
training and employment in the Company and
through its specialist service providers and active
identification of business opportunities for local
Aboriginal companies and enterprises.
All vehicle movements to be restricted to
access tracks and specified activity areas.
No additional clearing will be required as part
of these works, mitigating impacts on heritage
sites.

Monitoring
Site is manned and so operations will be
visually monitored at all times.
Weekly checks to be completed in
accordance with the Operations Management
Procedure (OP-PR-025).
Cultural heritage monitors invited to well sites
to observe operations under Company
specified safety arrangements.
Company website will be regularly updated
with relevant information, monitoring results
and project results as they come to hand.




TGS14 EP Summary Document_Rev_2 Buru Energy Limited 26
4. CONSULTATION
4.1. Identification of Key Stakeholder Groups
The Company commenced a stakeholder consultation register database for the Tight Gas
Development Project in November 2011. The Company maintains and updates the stakeholder
database on a regular basis. Key stakeholders relevant to the proposed TGS14 activities are included
below.
4.1.1. Government Departments
Commonwealth Department of Environment (formerly Sustainability, Environment, Water,
Population and Communities DSEWPaC)
WA Department of Mines and Petroleum (DMP)
WA Environmental Protection Authority (EPA)
WA Department of State Development (DSD)
WA Department of Water (DOW)
Water Corporation
Department of Health (DoH)
Department of Environment Regulation (DER) Formerly Department of Environment and
Conservation (DEC)
Department of Parks and Wildlife (DPAW) Formerly Department of Environment and
Conservation (DEC)
WA Department of Agriculture and Food (DAF)
4.1.2. Traditional Owner Groups
Yawuru PBC (Yulleroo Region)
Valhalla Region (unclaimed area)
Noonkanbah (Asgard)
Warrawa Claim Group (Sundown Oilfield Area)
4.1.3. Local Community and Industry Associations
Pastoralists and Graziers Association (PGA)
Kimberley Rangelands Biosecurity Association (KBRA)
Kimberley Development Commission (KDC)
Broome Shire Council
Derby Shire Council
4.2. Ongoing Consultation and Engagement
The Company has embarked on an extensive community engagement program, with the overarching
aim of developing long term and sustainable relationships with all stakeholders, particularly the
Kimberley community, current and future.
The community engagement program involves proactively engaging with the regional Kimberley
community and the overall State through a two-way communication process that ensures Buru Energy
openly shares information about its activities and is proactive and genuinely responsive to community
interest and feedback.
This engagement is being undertaken through direct community engagement as well as engagement
with the community through media.
4.2.1. General community engagement


TGS14 EP Summary Document_Rev_2 Buru Energy Limited 27
In the past year, Buru Energy has been engaging with the broader Kimberley community about its
program of activities through portions of the community, including the Shire of Broome, regional
Government agency representatives and sections of the business community such as the local
Chambers of Commerce in Broome, Wyndham and Derby. This has included providing dozens of
individually tailored briefings for community groups, businesses and government bodies.
Since early November last year, Buru Energy has launched a more intense engagement with the
broader Kimberley community. This is being carried out through various initiatives and activities.
These include a dedicated 1800 phone line and Community@buruenergy.com email address to
encourage a two-way dialogue between Buru Energy and the community, a community register to log
and respond to inquiries made through the dedicated phone line and email, provision of information
kits and details on the schedule of presentations and information sessions, through a registration
process via the internet, and dedicated phone line and email and providing presentations to
community and business organisations between November and mid-2014.
The Company has also undertaken community information sessions in the main regional centres of
the community being Broome (22 January), Derby (12 March) and Fitzroy Crossing (13 March).
Eighty six participants attended the Broome community open day and raised a range of issues
including the scale of any proposed future development, clarification around the biocide (BE-9) chosen
for the activities and employment opportunities with the Company. Overall, it was estimated that
approximately 15 of the attendees were members of issue motivated/ environmentalist groups and the
rest were neutral or in favour of the proposal.
Approximately 30 people attended the Derby event while a further 12 people attended the Fitzroy
Crossing event. Buru fielded a range of questions from people, with many interested in knowing about
future employment and business opportunities and what the benefits of an expanded gas industry
would be. People were also interested in how we will protect water resources and how well integrity
will be maintained.
Community feedback through the community awareness campaign, information sessions and
presentations is thoroughly reviewed by Buru Energy to ensure matters of interest are properly
targeted and taken into consideration as part of the process of moving forward with any activities.
Buru Energy engages with the Kimberley community through supporting various community events
throughout the region including the Kimberley Art Prize, Derby Boab Festival and Broomes Shinju
Matsuri Festival of the Pearl. Buru Energy also supports community organisations and sporting
groups in various ways such as funding sporting teams to attend regional and State Carnivals. These
are just some examples of the many organisations and activities Buru Energy has supported in recent
years.
In regards to engagement with the broader Western Australian community, Buru Energy has been
actively engaged with WA Government representatives, as well as industry and community peak
organisations based in Perth such as PGA, Australian Petroleum Production & Exploration Association
(APPEA) and Chamber of Minerals and Energy (CME). Buru Energy also sponsors and attends a wide
range of technical workshops, seminars and conferences in WA and inter-state and presents papers
on various disciplines including geology, environment, economics and Traditional Owner engagement.
Buru Energy will continue engaging with Perth based organisations to ensure ongoing engagement.
Throughout its current and future activities in the Kimberley, Buru Energy will maintain an active
engagement program with the Kimberley community and the broader Western Australian community
through an open and transparent dialogue.
4.2.2. Engagement with pastoralists
Buru Energy is engaging with pastoralists through the Pastoralists and Graziers Association (PGA),
attending various PGA zone meetings to ensure an open and ongoing dialogue. Buru Energy is also


TGS14 EP Summary Document_Rev_2 Buru Energy Limited 28
engaging with pastoralists on a one-on-one basis, visiting individual stations to discuss intended
activities and respond to matters relating to the proposed process.
4.2.3. Government Departments
An inter-agency working group has been set up under the Department for State Development for the
Canning Basin Project. This group is facilitated by the Department for State Development and
attended by DMP, OEPA, DER, DoW, DAA, DPC, DRD, and MRWA representatives. The working
group met on the 4
th
of December 2013 and presented the proposed works program for small scale
proof of concept program scheduled to be undertaken during 2014.
The Company has also met individually with the Office of the EPA, Department of Environmental
Regulation, Department of Water, Department of Health, Water Corporation and Main Roads Western
Australian to discuss the proposed TGS14 activities
During consultation with the Department of Health and the Department of Water, the Company
specifically asked for feedback on the proposed works and in particular the proposed monitoring
programs. Three lots of written advice from the DoW have been made available to the Company
during April and May 2014. Advice from the DoW covered petroleum well construction and integrity,
the design of monitoring program including the location of groundwater monitoring bores, the
frequency of monitoring and the use of Chloride as a Key Sentinel Indicator, the design of surface
water facilities including available freeboard, hydraulic fracturing occurring from deepest to shallowest
zones, reporting to regulatory agencies during the HF program, protection of deep groundwater
aquifers, the Companys lack of interaction with PDWSAs and water licencing.
The Company has reviewed all written advice provided by the DoW against the technical information
provided in the Environment Plan and associated technical appendices. Further detailed information
was included in a subsequent iteration of the Environment Plan regarding the monitoring program
particularly in relation to the frequency of monitoring. Advice regarding the frequency and design of the
monitoring program has also been received from Prof. Neil Coles from UWA. All matters raised in the
DoW advice have been addressed in the revised Environment Plan.
Feedback received from the Department of Health in March 2014 is that the proposal posed minimal
impacts on potable water sources and health of the community.
During the EPA referral process, the OEPA requested clarification regarding maintaining adequate
freeboard in water retention ponds during the flowback activities. The Company provided a response
to the OEPA on this matter and incorporated further detail in the Environment Plan. The EPA made a
decision not to assess the proposal and released Public Advice on the 13 January 2014. The decision
was then open to appeal until the 28 January 2014. A total of 81 appeals were received during the
appeals process, of these 81 appeals, 33 were deemed invalid due to the non-payment of appeal
fees. The Company provided a response to appeals to the Office of the Appeals Convenor on the
4 March 2014. The Minister for the Environment made a determination regarding the 48 remaining
appeals on the 16 June 2014 that the decision of the EPA not to assess the proposal was justified. All
appeals were dismissed.
The Company met with the DER office in Broome on 5 February 2014 to discuss the Companys
proposed TGS14 program and specifically the requirement for any works approvals. The Company
completed a scoping form for the proposed TGS14 activities. Advice received from the DER is that
based on the design capacity and scale of the proposed activities a Works Approval under Part V of
the Environment Protection Act 1986 is not required. The Company will continue to engage with the
DER to ensure that we are compliant with our obligations under the EP Act.
Buru Energy prepared a memo outlining the proposed approach for air quality monitoring associated
with the TGS14 program. This was provided to the DER Air Quality branch for their review and
comment. The DER indicated that the proposed approach for air quality monitoring is appropriate to
assess the fugitive emissions (e.g. methane, CO
2
, VOCs and other contaminants) for the TGS14
program. Following the completion of the TGS14 program and the analysis of data, Buru will provide


TGS14 EP Summary Document_Rev_2 Buru Energy Limited 29
collected data to the DMP. The data will be reviewed internally and used to design an appropriate
monitoring program for subsequent stages of exploration, appraisal and development.
No further feedback has been received from State Government departments that have been consulted
and communication with these parties will be continued.
Buru Energy has extensively engaged with Department of Parks and Wildlife (DPAW) formerly DEC
staff regarding our proposed management measures for Bilbies in the Canning Basin. This included a
meeting on the 25th of January 2013 to specifically discuss our Bilby management measures across
the Canning Basin. The Company also sponsored and participated in a Bilby workshop with DPAW in
October 2013.
4.2.4. Dedicated engagement with Traditional Owners and the indigenous
community
Buru Energy is very active with its direct engagement with indigenous communities in the Canning
Basin and has good working relations with Traditional Owners. By partnering with Traditional Owners
throughout its operations, Buru Energy is forming strong relationships and mutual respect of traditions,
culture and heritage. Buru Energy is creating jobs and helping to build skills among communities. Buru
Energy is also motivated to building capacity of local indigenous businesses as a way of investing in
the future sustainability and viability of local communities.
Since early 2014, Buru Energy has stepped up its direct engagement with Traditional Owners and
their community groups to establish new employment and training programs and initiatives. Increased
levels of engagement have also been focused on ensuring an open and transparent two-way dialogue
about Buru Energys current and intended activities in the Canning Basin.
Buru Energy has also established a program for extensive engagement with 36 remote communities.
This level of engagement will provide the opportunity for an open and transparent two-way dialogue
about Buru Energys current and intended activities, the opportunities these activities create for remote
communities, and how to assist communities to identify real opportunities.
Specific initiatives undertaken by Buru Energy in recent months include establishing a dedicated
Traditional Owner liaison team to ensure continuous and ongoing engagement, development of
cultural awareness training for all Buru staff and contracts (covering multiple Traditional Owner
language groups), commencement of recruitment for environment and heritage monitoring personnel,
offering Environmental Science Cadetships, in partnership with Broome TAFE, establishing a strategic
formal joint Traditional Owner engagement gas development plan process for Yawuru and other
West Kimberley language groups and facilitating independent specialist advisor support on the gas
project to Traditional Owner groups. Further information on the independent specialist review process
is included below.
Specialist Review Process
To ensure Traditional Owner groups are well informed regarding the environmental impacts
associated with the proposed activities, the Company is supporting three different specialist review
panels for the three different TO groups. These three different TO groups include the Yawuru, the
Noonkanbah, and KRED. This specialist review panel, chosen independently by the relevant TO
groups, has been taken up by each of the Traditional Owner groups. Each panel is independent of the
regulatory review process and will involve review by independent international experts with expertise
relating to environmental impacts associated with shale gas developments. The specialist review
panel process was running concurrently with the regulatory approvals process from October 2013.
The specialist reviewers appointed by each of the groups to advise them include:
Nyamba Buru Yawuru (NBY): Dr Tina Hunter, University of QLD; Prof Brian Evans et al.,
Curtin University; Environ specialists, CSIRO Professor Damian Barrett and Dr Bruce Doran,
ANU;


TGS14 EP Summary Document_Rev_2 Buru Energy Limited 30
Yungngora peoples: Prof. Manouchehr Haghighi, Adelaide University; Dr Lynn Reid, CDM
Smith; Dr Daniel Tormey, Environ;
KRED Enterprises: Ceri Morgan, Morgan Consulting; Prof. Manouchehr Haghighi, Adelaide
University; Dr Daniel Tormey, Environ; Dr Lynn Reid, CDM Smith; Dr Jenny Stauber, CSIRO.
The specialist review process undertaken by the Yawuru and Yungngora peoples includes a series of
risk review workshops and community meetings undertaken in collaboration with the independent
specialists, Traditional Owner reference group members and the community. These meetings have
ensured that key areas of concern are collected and communicated back to Buru. During the Yawuru
process, this included a meeting at the Yulleroo well sites on the 30 May 2014.
Queries, questions and comments included in technical responses from specialist reviewers covered
the breadth of petroleum activities including relevant legislation and codes of practice, well design and
well integrity, hydrogeology, surface water management, modelling of fracture propagation, validation
of models, management of surface facilities, management of air emissions, groundwater monitoring
and spill response.
Subsequent revisions of the Environment Plan have been updated to address matters raised by
specialist reviewers. This has included updating the risk assessment table, where required.
This consultative and transparent approach for activities in the Yulleroo and Asgard/Valhalla regions
ensures the concerns of the Yawuru, the Yungngora and their constituents are addressed during the
planning and assessment process.
At the Yungngora community meeting on the 24 June, the Community announced their support in
principle for the Laurel Formation Tight Gas Pilot Exploration Program.
As stated above, a similar specialist review process is underway with KRED Enterprises, even though
none of Buru Energys current gas activities are on the land of KRED constituents. This is to ensure all
Traditional Owners in the Kimberley have access to the same information.
4.3. Communication
During the conduct of the Activity, a weekly operations report is provided to relevant stakeholders in
electronic format. This will include a progress report, summary of operations undertaken during the
previous week and a summary of any operations proposed during the following week. All
stakeholders will be advised of unforeseen changes, such as delays to the intended commencement
or completion of the Activity.
Communications will be available onsite at all times by way of satellite phones, two-way radios and
internet connections. All personnel in Perth hold mobile phones to facilitate after hours communication
if required.
This summary of the Environment Plan will be available on the DMP and Company website along with
full chemical disclosure details including ecotoxological chemical risk assessment data.
Any third parties with concerns, queries or feedback in relation to the Activity, including stakeholders
and members of the community, can contact the Companys head office in Perth between 08.30 and
18.00 Monday to Friday by phone, fax or email as set out below:
Telephone: 08 9215 1800
Facsimile: 08 9215 1899
Email: info@buruenergy.com
















Appendix A
Chemical Disclosure

A. HF System Details
Operator Buru Energy
Project/Well TGS14
System Stimulation Chemicals
Total Volume of System 1,698,416 L
B. Product List
Product Name Supplier Purpose
Product in
system fluid (%)
Toxicity and Ecotoxicity Information
MSDS
attached
Water 93.98564% No Hazard
Water in
products
1.67%
No Hazard

Acetic Acid - 60% Halliburton Buffer 0.00802%
CONSTITUENT 1 (100%):
Acute Fish Toxicity 96h LC50: 75 mg/L (Lepomis macrochirus)
Acute Crustacean Toxicity 24h LC50: 47 mg/L (Daphnia magna)
Acute Algae Toxicity 24h EC50: 156 mg/L (Chlorococcales)
Biodegradation: Readily Biodegradable (99% degradation in 7d)
Bioaccumulation: Not Bioaccumulative (based on Log Kow: -0.17)
CONSTITUENT 2 (60%): No Hazard - Water makes up the
remainder of this product
Yes
BE-9 Halliburton Biocide 0.00842%
CONSTITUENT 1 (10%):
Acute Fish Toxicity of degradation product 96h LC50:
<700 mg/L (goldfish, zebrafish)Test: Closed Bottle (OECD 301D)
Biodegradability/Bioaccumulation: Duration: 28 day Procedure:
Ready biodegradability. Ref. LOLI Desktop Component is classified
by Korea MOE using GHS Criteria "Hazardous to the Aquatic
Environment - Acute: Category 1" and "Hazardous to the Aquatic
Environment - Chronic: Category 1".
CONSTITUENT 2 (100%): No Hazard-Water makes up the
remainder of this product
Yes
CLBXTAU121 Halliburton High Temp Breaker 0.00935%
Acute Toxicity:
Acute Fish Toxicity 48h LC50: 450 mg/L (Leuciscus idus)
Yes


Fish: Leuciscus idus: EC50=2300-2700 mg/L;
LD 50 ORAL (RAT): 5900 mg/kg
LD 50 INTRAPERITONEAL (RAT): 4000 mg/kg
LD 50 SUBCUTANEOUS (RAT): 6600 mg/kg
LD 50 INTRAPERITONEAL (MOUSE): 1750 mg/kg
Listed as a permitted food additive in multiple jurisdictions
(including Australia). Component is defined by Germany's Federal
Environment Agency as "Hazard Class 1 - Low Hazards to Waters"
(Water Classification Annex 3).
Readily Biodegradable
CLLAU301 Halliburton Crosslinker 0.09354%
CONSTITUENT 1 (10%):
Acute Fish Toxicity 96h LC50: 3.6 mg/L (Salvelinus fontinalis);
Acute Crustacean Toxicity 48h EC50: 3.2 mg/L (Daphnia magna);
Acute Algae Toxicity 22h EC50: >25 mg/L (Aphanizomenon flos-
aquae);
Biodegradation: Not Applicable (Inorganic);
CONSTITUENT 2 (10%):
Acute Fish Toxicity 96h LC50: 42 mg/L (Gambusia affinis);
Acute Crustacean Toxicity 24h EC50: 29 mg/L (Daphnia magna);
Acute Algae Toxicity: No Data Available;
Biodegradation: Not Applicable (Inorganic);
Bioaccumulation: Not Applicable (Inorganic)
CONSTITUENT 3 (100%):
No Hazard- Water makes up the remainder of this product
Yes
CLWGAU421 Halliburton Gelling Agent 0.02804%
Acute Toxicity:
Acute Fish Toxicity 96h LC50: 20,000 mg/L (Oncorhynchus mykiss);
Acute Crustacean Toxicity 48h EC50: 87.26 mg/L (Ceriodaphnia
dubia)
Yes
DCA 30001
(FDP-S1085-13)

Halliburton Scale Inhibitor 0.04677%
CONSTITUENT 1 (30%):
Acute Toxicity:
48h LC50: >200 mg/L (Daphnia Magna)
96 h LC50: >1000 mg/L (Brachydanio)
28d LC50: > 450 mg/L (Brachydanio rerio)
21d EC50: = 450 mg/L (Daphnia Magna)
Yes


96h EC50: =180 mg/L (Selenastrum capricornutum)
Component is defined by Germany's Federal Environment Agency
as "Hazard Class 1, Low Hazards to Water" (Water Classification
Annex 1).; Component is classified by Cosmetic Ingredient Review
as a "Safe Ingredient With Qualifications"; Component is classified
by the US EPA - FIFRA as a "Inert Ingredient Permitted for Use in
Nonfood Use Pesticide Products"; Component is classified by the
US EPA - Design for the Environment (DfE) as part of the "Safer
Chemical Ingredients List - Polymer"; Component is classified by
the US FDA as a "Direct Food Additive" and an "Indirect Food
Additive". Component was classified (out of 229 notifiers) by one
notifier as an Aquatic Chronic Cat. 3
CONSTITUENT 2 (10%):
Acute Toxicity:
48h LC50: 1.94 mg/L (Ceriodaphnia dubia)
96h LC50: 26.2 mg/L (Pimephales promelas)
CONSTITUENT 3 (1%):
Acute Toxicity:
96h LC50: 45.4 mg/L (Oncorhynchus mykiss)
48h EC50: 40.38 mg/L (Ceriodaphnia dubia)
Biodegradation: Not Applicable (Inorganic)
Bioaccumulation: Not Applicable (Inorganic)
CONSTITUENT 4 (100%):
No Hazard- Water makes up the remainder of this product
FE-2 Halliburton Buffer 0.00118%
Acute Toxicity:
96h LC50: 440 mg/L (Leuciscus idus)
24h EC50: 85 mg/L (Daphnia magna)
Biodegradation: Readily Biodegradable (98% degradation in 48
(OECD 302B))
Bioaccumulation: Not Bioaccumulative (based on Log Pow: -1.72)
Yes
DCA-23001
(FR-50D)
Halliburton Friction Reducer 0.01371%
CONSTITUENT 1 (30%):
Acute Toxicity:
48h LC50: =218.1 mg/L (Ceriodaphnia dubia)
48h LC50: < 1 mg/L (Daphnia Magna)
Yes


72h EC50: = 4310 mg/L (Skeletonema Costatum)
48h LC50: = 2202 mg/L (Acartia Tonsa)
96h LC50: =9051 mg/L (Scophthalmus Maximus)
Component is classified by the US FDA as a "Direct Food Additive"
and an "Indirect Food Additive".
CONSTITUENT 2 (1%):
Acute Toxicity:
96h LC50: 4.96 mg/L (Ctenopharyngodon idella)
48h LC50: 7.4 mg/L (Daphnia magna)
Biodegradation: Persistent (<10% degradation in 28d (OECD
301D))
Bioaccumulation: Not Bioaccumulative (based on BCF = 48)
CONSTITUENT 3 (100%):
Acute Toxicity:
96h LC50: 1000 mg/L (Morone saxatilis)
48h EC50: 402.6 mg/L (Daphnia magna)
96h EC50: 2430 mg/L (Navicula seminulum)
Biodegradation: Not Applicable (Inorganic)
Bioaccumulation: Not Applicable (Inorganic)
DCA-17004
(HAI-150E)
Halliburton Corrosion Inhibitor 0.000537%
No Hazard - natural product
REACH ANNEX V: Exempt for OSPAR
OCNS Group E
CEFAS Registration Number 25119
Component is naturally-occurring and is generally not classified by
notifiers.
Yes
Hydrochloric Acid
- 32%
Halliburton Acid 0.10200%
CONSTITUENT 1 (60%):
Acute Toxicity:
96h LC50: 4.92 mg/L (Cyprinus carpio)
48h EC50: 0.492 mg/L (Daphnia magna)
72h EC50: 0.097 mg/L (Selenastrum capricornutum);
Biodegradation: Not Applicable (Inorganic);
Bioaccumulation: Not Applicable (Inorganic);
CONSTITUENT 2 (100%):
No Hazard-Water makes up the remainder of this product.
Yes


Sodium Chloride Halliburton Clay Stabilizer 0.86515%
Acute Toxicity:
96h LC50: 1000 mg/L (Morone saxatilis)
48h EC50: 402.6 mg/L (Daphnia magna)
96h EC50: 2430 mg/L (Navicula seminulum)
Biodegradation: Not Applicable (Inorganic)
Bioaccumulation: Not Applicable (Inorganic)
Yes
100 Mesh Sand Halliburton Proppant 0.28216% No Hazard Natural Product Yes
40/70 Sand Halliburton Proppant 2.88206% No Hazard Natural Product Yes
Water Tracerco Dissolution medium
+ flush fluid
0.000008357% No Hazard Natural Product Yes
T-140a Tracerco Chemical Water
Tracer
0.0000000348% CONSTITUENT 1 (10-30%):
sodium 2-fluorobenzoate
Acute Toxicity:
96h LC50 440mg/L Marine Fish Scophthalmus maximus
Oral, Mouse: LD50 = 300 mg/kg; Oral, rabbit: LD50 = 3200 mg/kg;
Oral, rat: LD50 = 980 mg/kg.
Carcinogenicity: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
CONSTITUENT 2 (>60%):
No Hazard-Water makes up the remainder of this product.
Yes
T-140b Tracerco Chemical Water
Tracer
0.0000000348% CONSTITUENT 1 (1-10%):
sodium 3-fluorobenzoate
Acute Toxicity:
48 h LC50: > 298 mg/L (Marine Copepod Acartia tonsa)
EC50: 934 mg/L (Fish toxicity marine fish Cryrinodon variegatus)
EC50: > 10000 mg/L (Algal toxicity marine unicellular algae
Skeletonema costatum)
EC50: 9344 mg/L (Marine Acartia tonsa)
EC50 > 14185 mg/L (Marine crustacean Corophium volutator)
CONSTITUENT 2 (>60%):
No Hazard-Water makes up the remainder of this product.
Yes
T-140c Tracerco Chemical Water
Tracer
0.0000000348% CONSTITUENT 1 (1-10%):
sodium 4-fluorobenzoate
Acute Toxicity:
Yes


48 h LC50: > 430 mg/L (Marine Copepod Acartia tonsa)
Oral, mouse: LD50 = 300 mg/kg; Oral, rabbit: LD50 = 3200 mg/kg;
Oral, rat: LD50 = 980 mg/kg.
Carcinogenicity: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.)
CONSTITUENT 2 (>60%):
No Hazard-Water makes up the remainder of this product.
T-158a Tracerco Chemical Water
Tracer
0.0000000348% CONSTITUENT 1 (1-10%):
sodium 2,4-fluorobenzoate
Acute Toxicity:
48 h LC50: > 460 mg/L (Marine Copepod Acartia tonsa)
Oral, mouse: LD50 = 830 mg/kg; . Other: oral rat LD50 > 5000
Carcinogenicity: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
CONSTITUENT 2 (>60%):
No Hazard-Water makes up the remainder of this product.
Yes
T-158b Tracerco Chemical Water
Tracer
0.0000000348% CONSTITUENT 1 (10-30%):
sodium 2,5-fluorobenzoate
Acute Toxicity:
48 h LC50: > 460 mg/L (Marine Copepod Acartia tonsa)
Oral, mouse: LD50 = 830 mg/kg; . Other: oral rat LD50 > 5000
Carcinogenicity: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
CONSTITUENT 2 (>60%):
No Hazard-Water makes up the remainder of this product.
Yes
T-158c Tracerco Chemical Water
Tracer
0.0000000348% CONSTITUENT 1 (10-30%):
sodium 2,6-fluorobenzoate
Acute Toxicity:
48 h LC50: > 1521 mg/L (Marine Copepod Acartia tonsa
Oral, mouse: LD50 >1000 mg/kg; . Other: oral rat LD50 > 5000
Carcinogenicity: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
CONSTITUENT 2 (>60%):
No Hazard-Water makes up the remainder of this product.
Yes
T-158d Tracerco Chemical Water
Tracer
0.0000000348% CONSTITUENT 1 (10-30%):
sodium 3,4-fluorobenzoate
Acute Toxicity:
48 h LC50: > 1521 mg/L (Marine Copepod Acartia tonsa
Yes


Oral, mouse: LD50 >1000 mg/kg; . Other: oral rat LD50 > 5000
Carcinogenicity: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
CONSTITUENT 2 (>60%):
No Hazard-Water makes up the remainder of this product.
T-176c Tracerco Chemical Water
Tracer
0.0000000348% CONSTITUENT 1 (10-30%):
sodium 3,4-fluorobenzoate
Acute Toxicity:
48 h LC50: > 254 mg/L (Marine Copepod Acartia tonsa
Oral, mouse: LD50 >1000 mg/kg; . Other: oral rat LD50 > 5000
Carcinogenicity: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
CONSTITUENT 2 (>60%):
No Hazard-Water makes up the remainder of this product.
Yes
T-190a Tracerco Chemical Water
Tracer
0.0000000348% CONSTITUENT 1 (10-30%):
sodium 2 (trifluoromethyl) benzoate
Acute Toxicity:
48 h LC50: > 443 mg/L (Marine Copepod Acartia tonsa)
LD 50 > 3000 mg/kg (oral rat)
Carcinogenicity: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
CONSTITUENT 2 (>60%):
No Hazard-Water makes up the remainder of this product.
Yes
T-190b Tracerco Chemical Water
Tracer
0.0000000348% CONSTITUENT 1 (10-30%):
sodium 3 (trifluoromethyl) benzoate
Acute Toxicity:
48 h LC50: > 167 mg/L (Marine Copepod Acartia tonsa)
LD 50 > 3000 mg/kg (oral rat)
Carcinogenicity: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
CONSTITUENT 2 (>60%):
No Hazard-Water makes up the remainder of this product.
Yes
T-190c Tracerco Chemical Water
Tracer
0.0000000348% CONSTITUENT 1 (10-30%):
sodium 4 (trifluoromethyl) benzoate
Acute Toxicity:
48 h LC50: > 134 mg/L (Marine Copepod Acartia tonsa)
10d LC 50: 283 mg/L (Marine crustacean Corophium volutator)
72h EC50 >695 mg/L (Algal toxicity marine unicellularn algae
Yes


Skeletonema costatum)
96h LC50 >3200 mg/L (Marine Fish Scophthalmus Maximus
Carcinogenicity: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
CONSTITUENT 2 (>60%):
No Hazard-Water makes up the remainder of this product.
T-194a Tracerco Chemical Water
Tracer
0.0000000348% CONSTITUENT 1 (10-30%):
sodium 2,3,4,5 tetrafluoro benzoic acid
Acute Toxicity:
48h LC50: >305 mg/L (Marine Copepod Acartia tonsa)
10d LC50: 407 mg/L (Marine crustacean Corophium volutator)
72h EC50 >2075 mg/L (Algal toxicity marine unicellular algae
Skeletonema costatum)
96h LC50 440 mg/L (Marine Fish Scophthalmus Maximus)
Carcinogenicity: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
CONSTITUENT 2 (>60%):
No Hazard-Water makes up the remainder of this product.
Yes
T-300 Tracerco Chemical
Gas Tracer
0.000001175% Acute Toxicity:
48h LC50: >10,000 mg/L (Marine Copepod Acartia tonsa)
96h LC50 >5600 mg/L (Fish Scophthalmus maximus unicellular)
72h LC50 >10000 mg/L ( Algae Skeletonema costatum)
10d LC50 >12710 mg/L (Marine crustacean Corophium volutator)
Yes
T-300a Tracerco Chemical
Gas Tracer
0.000001175% Acute Toxicity:
48h LC50: >10,000 mg/L (Marine Copepod Acartia tonsa)
96h LC50 >5600 mg/L (Fish Scophthalmus maximus unicellular)
72h LC50 >10000 mg/L ( Algae Skeletonema costatum)
10d LC50 >12710 mg/L (Marine crustacean Corophium volutator)
Yes
T-350 Tracerco Chemical
Gas Tracer
0.000001175% Acute Toxicity:
48h LC50: >10,000 mg/L (Marine Copepod Acartia tonsa)
96h LC50 >5600 mg/L (Fish Scophthalmus maximus unicellular)
72h LC50 >10000 mg/L ( Algae Skeletonema costatum)
10d LC50 >12710 mg/L (Marine crustacean Corophium volutator)
Yes
T-400b Tracerco Chemical
Gas Tracer
0.000001175% Acute Toxicity:
48h LC50: >10,000 mg/L (Marine Copepod Acartia tonsa)
Yes


96h LC50 >5600 mg/L (Fish Scophthalmus maximus unicellular)
72h LC50 >10000 mg/L ( Algae Skeletonema costatum)
10d LC50 >12710 mg/L (Marine crustacean Corophium volutator)
T-400c Tracerco Chemical
Gas Tracer
0.000001175% Acute Toxicity:
48h LC50: >10,000 mg/L (Marine Copepod Acartia tonsa)
96h LC50 >5600 mg/L (Fish Scophthalmus maximus unicellular)
72h LC50 >10000 mg/L ( Algae Skeletonema costatum)
10d LC50 >12710 mg/L (Marine crustacean Corophium volutator)
Yes
T-400d Tracerco Chemical
Gas Tracer
0.000001175% Acute Toxicity:
48h LC50: >10,000 mg/L (Marine Copepod Acartia tonsa)
96h LC50 >5600 mg/L (Fish Scophthalmus maximus unicellular)
72h LC50 >10000 mg/L ( Algae Skeletonema costatum)
10d LC50 >12710 mg/L (Marine crustacean Corophium volutator)
Yes
T-412 Tracerco Chemical
Gas Tracer
0.000001175% Acute Toxicity:
48h LC50: >10,000 mg/L (Marine Copepod Acartia tonsa)
96h LC50 >5600 mg/L (Fish Scophthalmus maximus unicellular)
72h LC50 >10000 mg/L ( Algae Skeletonema costatum)
10d LC50 >12710 mg/L (Marine crustacean Corophium volutator)
Yes
T-438 Tracerco Chemical
Gas Tracer
0.000001175% Acute Toxicity:
48h LC50: >10,000 mg/L (Marine Copepod Acartia tonsa)
96h LC50 >5600 mg/L (Fish Scophthalmus maximus unicellular)
72h LC50 >10000 mg/L ( Algae Skeletonema costatum)
10d LC50 >12710 mg/L (Marine crustacean Corophium volutator)
Yes
T-450a Tracerco Chemical
Gas Tracer
0.000001175% Acute Toxicity:
48h LC50: >10,000 mg/L (Marine Copepod Acartia tonsa)
96h LC50 >5600 mg/L (Fish Scophthalmus maximus unicellular)
72h LC50 >10000 mg/L ( Algae Skeletonema costatum)
10d LC50 >12710 mg/L (Marine crustacean Corophium volutator)
Yes
T-450b Tracerco Chemical
Gas Tracer
0.000001175% Acute Toxicity:
48h LC50: >10,000 mg/L (Marine Copepod Acartia tonsa)
96h LC50 >5600 mg/L (Fish Scophthalmus maximus unicellular)
72h LC50 >10000 mg/L ( Algae Skeletonema costatum)
10d LC50 >12710 mg/L (Marine crustacean Corophium volutator)
Yes


T-450c Tracerco Chemical
Gas Tracer
0.000001175% Acute Toxicity:
48h LC50: >10,000 mg/L (Marine Copepod Acartia tonsa)
96h LC50 >5600 mg/L (Fish Scophthalmus maximus unicellular)
72h LC50 >10000 mg/L ( Algae Skeletonema costatum)
10d LC50 >12710 mg/L (Marine crustacean Corophium volutator)
Yes
T-462a Tracerco Chemical
Gas Tracer
0.000001175% Acute Toxicity:
48h LC50: >10,000 mg/L (Marine Copepod Acartia tonsa)
96h LC50 >5600 mg/L (Fish Scophthalmus maximus unicellular)
72h LC50 >10000 mg/L ( Algae Skeletonema costatum)
10d LC50 >12710 mg/L (Marine crustacean Corophium volutator)
Yes
Iridium Zero
Wash Bead
Tracer
SpectraStim Proppant Tracer 0.0000000139% CONSTITUENT 1 > 5% : Silicon Dioxide & Aluminium Oxide;
Acute Toxicity:
Oral, mouse: LD50 >8000 mg/kg; Oral, rabbit: LD50 > 5000 mg/kg;
Oral, rat: LD50 > 10000 mg/kg.
CONSTITUENT 2 <5% : Iridium 192 Oxide; Titanium Oxide;
Potassium Oxide; Iron Oxide; Calcium Oxide; Sodium Oxide
Acute Toxicity:
Oral LD50 Rat: >10000 mg/kg.
CONSTITUENT 3 <5% : Methanol; Dipropylene glycol methyl ether;
Xanthanum gum
Acute Toxicity:
Oral, rat: LD50 >5000 mg/kg
Biodegradation: Not Applicable (Inorganic);
CONSTITUENT 4>90 %: No Hazard-Water makes up the remainder
of this product.
Yes

Antimony Zero
Wash Bead
Tracer
SpectraStim Proppant Tracer 0.0000000139% CONSTITUENT 1 > 5% : Silicon Dioxide & Aluminium Oxide;
Acute Toxicity:
Oral, mouse: LD50 >8000 mg/kg; Oral, rabbit: LD50 > 5000 mg/kg;
Oral, rat: LD50 > 10000 mg/kg.
CONSTITUENT 2 <5% : Antimony124 Oxide ; Titanium Oxide;
Potassium Oxide; Iron Oxide; Calcium Oxide; Sodium Oxide
Biodegradation: Not Applicable (Inorganic);
Acute Toxicity:
Yes


Oral LD50 Rat: >10000 mg/kg.
CONSTITUENT 3 <5% : Methanol; Dipropylene glycol methyl ether;
Xanthanum gum
Acute Toxicity:
Oral, rat: LD50 >5000 mg/kg
CONSTITUENT 4>90 %: No Hazard-Water makes up the remainder
of this product.
Scandium Zero
Wash Bead
Tracer
SpectraStim Proppant Tracer 0.0000000139% CONSTITUENT 1 > 5% : Silicon Dioxide & Aluminium Oxide;
Acute Toxicity:
Oral, mouse: LD50 >8000 mg/kg; Oral, rabbit: LD50 > 5000 mg/kg;
Oral, rat: LD50 > 10000 mg/kg.
CONSTITUENT 2 <5% : Scandium46 Oxide ; Titanium Oxide;
Potassium Oxide; Iron Oxide; Calcium Oxide; Sodium Oxide
Biodegradation: Not Applicable (Inorganic);
Acute Toxicity:
Oral LD50 Rat: >10000 mg/kg.
CONSTITUENT 3 <5% : Methanol; Dipropylene glycol methyl ether;
Xanthanum gum
Acute Toxicity:
Oral, rat: LD50 >5000 mg/kg
CONSTITUENT 4>90 %: No Hazard-Water makes up the remainder
of this product.
Yes
TOTAL 100%








C. Chemical List
Chemicals within HF Fluid CAS number
Mass
fraction (%)
Toxicity and Ecotoxicity Information
Buru Supplied Water 7732-18-5 86.40%
Crystalline silica, quartz 14808-60-7 11.7%
Acute Toxicity:
No ecotoxicity data is available for this component. Similar silica-
based components have low acute hazards. Available
information suggests that ecotoxicity is not a concern for this
component.
Sodium chloride 7647-14-5 1.72%
Acute Toxicity:
Acute Fish Toxicity 96h LC50: 1000 mg/L (Morone saxatilis)
Acute Crustacean Toxicity 48h EC50: 402.6 mg/L (Daphnia
magna)
Acute Algae Toxicity 96h EC50: 2430 mg/L (Navicula seminulum)

Bioaccumulation/biodegradation:
Biodegradation: Not Applicable (Inorganic)
Bioaccumulation: Not Applicable (Inorganic)
Hydrochloric acid 7647-01-0 0.0662%
Acute Toxicity:
Acute Fish Toxicity 96h LC50: 4.92 mg/L (Cyprinus carpio);
Acute Crustacean Toxicity 48h EC50: 0.492 mg/L (Daphnia
magna);
Acute Algae Toxicity 72h EC50: 0.097 mg/L (Selenastrum
capricornutum);
Bioaccumulation/biodegradation:
Biodegradation: Not Applicable (Inorganic);
Bioaccumulation: Not Applicable (Inorganic)
Sodium carboxymethyl cellulose 9004-32-4 0.0411%
Acute Toxicity:
Acute Fish Toxicity 96h LC50: 20000 mg/L (Oncorhynchus mykiss);
Acute Crustacean Toxicity 48h EC50: 87.26 mg/L (Ceriodaphnia
dubia)
Sodium chloride 7647-14-5 0.0203%
Acute Toxicity:
Acute Fish Toxicity 96h LC50: 1000 mg/L (Morone saxatilis)


Acute Crustacean Toxicity 48h EC50: 402.6 mg/L (Daphnia
magna)
Algae Algae Toxicity 96h EC50: 2430 mg/L (Navicula seminulum)

Bioaccumulation/biodegradation:
Biodegradation: Not Applicable (Inorganic)
Bioaccumulation: Not Applicable (Inorganic)
Sodium polyacrylate 9003-04-7 0.0150%
Acute Toxicity:
Component is defined by Germany's Federal Environment
Agency as "Hazard Class 1, Low Hazards to Water" (Water
Classification Annex 1).; Component is classified by Cosmetic
Ingredient Review as a "Safe Ingredient With Qualifications";
Component is classified by the US EPA - FIFRA as a "Inert
Ingredient Permitted for Use in Nonfood Use Pesticide Products";
Component is classified by the US EPA - Design for the
Environment (DfE) as part of the "Safer Chemical Ingredients List
- Polymer"; Component is classified by the US FDA as a "Direct
Food Additive" and an "Indirect Food Additive".Component was
classified (out of 229 notifiers) by one notifier as an Aquatic
Chronic Cat. 3
Citric acid, triethyl ester 77-93-0 0.00977%
Acute Toxicity:
Acute Fish Toxicity 48h LC50: 450 mg/L (Leuciscus idus)
LD 50 ORAL (RAT): 5900 mg/kg
LD 50 INTRAPERITONEAL (RAT): 4000 mg/kg
LD 50 SUBCUTANEOUS (RAT): 6600 mg/kg
LD 50 INTRAPERITONEAL (MOUSE): 1750 mg/kg
LD 50 ORAL (CAT): 35,000 mg/kg
Listed as a permitted food additive in multiple jurisdictions
(including Australia). Component is defined by Germany's
Federal Environment Agency as "Hazard Class 1 - Low Hazards to
Waters" (Water Classification Annex 3).
Readily Biodegradable
Aluminum sulfate 10043-01-3 0.00865% Acute Toxicity:


Acute Fish Toxicity 96h LC50: 3.6 mg/L (Salvelinus fontinalis);
Acute Crustacean Toxicity 48h EC50: 3.2 mg/L (Daphnia magna);
Acute Algae Toxicity 22h EC50: >25 mg/L (Aphanizomenon flos-
aquae);

Bioaccumulation/biodegradation:
Biodegradation: Not Applicable (Inorganic);
Biodegradation: Not Applicable (Inorganic)
Acetic acid 64-19-7 0.00771%
Acute Toxicity:
Acute Fish Toxicity 96h LC50: 75 mg/L (Lepomis macrochirus)
Acute Crustacean Toxicity 24h LC50: 47 mg/L (Daphnia magna)
Acute Algae Toxicity 24h EC50: 156 mg/L (Chlorococcales)

Bioaccumulation/biodegradation:
Biodegradation: Readily Biodegradable (99% degradation in 7d)
Bioaccumulation: Not Bioaccumulative (based on Log Kow: -0.17)
Acrylamide acrylate copolymer 9003-06-9 0.00610%
Acute Toxicity:
Component is classified by the US FDA as a "Direct Food
Additive" and an "Indirect Food Additive".
Sulfuric acid 7664-93-9 0.00433%
Acute Toxicity:
Acute Fish Toxicity 96h LC50: 42 mg/L (Gambusia affinis);
Acute Crustacean Toxicity 24h EC50: 29 mg/L (Daphnia magna);
Acute Algae Toxicity: No Data Available;

Bioaccumulation/biodegradation:
Biodegradation: Not Applicable (Inorganic);
Bioaccumulation: Not Applicable (Inorganic)
Sodium bisulfite 7631-90-5 0.00250%
Acute Toxicity:
Acute Crustacean Toxicity 48h LC50: 1.94 mg/L (Ceriodaphnia
dubia)Acute Fish Toxicity 96h LC50: 26.2 mg/L (Pimephales
promelas)
Citric acid 77-92-9 0.00245%
Acute Toxicity:
Acute Fish Toxicity 96h LC50: 440 mg/L (Leuciscus idus)


Acute Crustacean Toxicity 24h EC50: 85 mg/L (Daphnia magna)

Bioaccumulation/biodegradation:
Biodegradation: Readily Biodegradable (98% degradation in 48
(OECD 302B))Bioaccumulation: Not Bioaccumulative (based on
Log Pow: -1.72)
Sodium hydroxide 1310-73-2 0.000499%
Acute Toxicity:
Acute Fish Toxicity 96h LC50: 45.4 mg/L (Oncorhynchus mykiss)

Bioaccumulation/biodegradation:
Biodegradation: Not Applicable (Inorganic)Bioaccumulation: Not
Applicable (Inorganic)
Acute Crustacean Toxicity 48h EC50: 40.38 mg/L (Ceriodaphnia
dubia)
Tributyl tetradecyl phosphonium chloride 81741-28-8 0.000386%
Acute Toxicity:
Component is classified by Korea MOE using GHS Criteria
"Hazardous to the Aquatic Environment - Acute: Category 1" and
"Hazardous to the Aquatic Environment - Chronic: Category 1".
Coffee Extract 68916-18-7 0.000147%
Acute Toxicity:
No ecotoxicity data is available for this component. Additional
information was not present using LOLI Desktop. Component is
naturally-occurring and is generally not classified by notifiers.
2- Fluorobenzoic Acid Sodium Salt 490-97-1
2.90824E-13
(~0.03 ppb)
Acute Toxicity:
96h LC50 440mg/L Marine Fish Scophthalmus maximus
Oral, Mouse: LD50 = 300 mg/kg; Oral, rabbit: LD50 = 3200 mg/kg;
Oral, rat: LD50 = 980 mg/kg.
Carcinogenicity: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
3- Fluorobenzoic Acid Sodium Salt 499-57-0
2.90824E-13
(~0.03 ppb)
Acute Toxicity:
48 h LC50: > 298 mg/L (Marine Copepod Acartia tonsa)
EC50: 934 mg/L (Fish toxicity marine fish Cryrinodon variegatus)
EC50: > 10000 mg/L (Algal toxicity marine unicellular algae
Skeletonema costatum)
EC50: 9344 mg/L (Marine Acartia tonsa)


EC50 > 14185 mg/L (Marine crustacean Corophium volutator)
4- Fluorobenzoic Acid Sodium Salt 499-90-1
2.90824E-13
(~0.03 ppb)
Acute Toxicity:
48 h LC50: > 430 mg/L (Marine Copepod Acartia tonsa)
Oral, mouse: LD50 = 300 mg/kg; Oral, rabbit: LD50 = 3200 mg/kg;
Oral, rat: LD50 = 980 mg/kg.
Carcinogenicity: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
2,4 Difluorobenzoic Acid, Sodium Salt
1765-08-8
2.90824E-13
(~0.03 ppb)
Acute Toxicity:
48 h LC50: > 460 mg/L (Marine Copepod Acartia tonsa)
10d LC50 6718 mg/L - Marine crustacean Corophium volutator
72h EC50 > 660 mg/L - Algal toxicity marine unicellular algae
Skeletonema costatum
96h LC50 >3200 mg/L - Marine Fish Scophthalmus Maximus
Oral, mouse: LD50 = 830 mg/kg; . Other: oral rat LD50 > 5000
Carcinogenicity: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
2,5 Difluorobenzoic Acid, Sodium Salt 522651-42-9
2.90824E-13
(~0.03 ppb)
Acute Toxicity:
48 h LC50: > 272 mg/L (Marine Copepod Acartia tonsa)
CAS#:Draize test, rabbit, eye: 100 mg/24H Moderate; Oral,
mouse: LD50 = 300 mg/kg; Oral, rabbit: LD50 = 3200 mg/kg; Oral,
rat: LD50 = 980 mg/kg.
Carcinogenicity: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
2,6 Difluorobenzoic Acid, Sodium Salt 6185-28-0
2.90824E-13
(~0.03 ppb)
Acute Toxicity:
48 h LC50: > 1521 mg/L (Marine Copepod Acartia tonsa)
3,4 Difluorobenzoic Acid, Sodium Salt 522651-44-1
2.90824E-13
(~0.03 ppb)
Acute Toxicity:
48 h LC50: > 254 mg/L (Marine Copepod Acartia tonsa)
Carcinogenicity: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
2,4,5 Trifluorobenzoic Acid, Sodium Salt 522651-48-5
2.90824E-13
(~0.03 ppb)
Acute Toxicity:
48 h LC50: > 429 mg/L (Marine Copepod Acartia tonsa)
10d LC50 > 331 mg/L (Marine crustacean Corophium volutator)
72 h EC50: > 10000 mg/L (Algal toxicity marine unicellular algae
Skeletonema costatum)
96h LC50 660 mg/L ( Marine Fish Scophthalmus Maximus)
2 - Trifluoromethylbenzoic Acid, Sodium Salt 2966-44-1
2.90824E-13
(~0.03 ppb)
Acute Toxicity:
48 h LC50: > 443 mg/L (Marine Copepod Acartia tonsa)


LD 50 > 3000 mg/kg (oral rat
3- Trifluoromethylbenzoic Acid, Sodium Salt 69226-41-1
2.90824E-13
(~0.03 ppb)
Acute Toxicity:
48 h LC50: > 167 mg/L (Marine Copepod Acartia tonsa)
4- Trifluoromethylbenzoic Acid, Sodium Salt 25832-58-0
2.90824E-13
(~0.03 ppb)
Acute Toxicity:
48 h LC50: > 134 mg/L (Marine Copepod Acartia tonsa)
10d LC 50: 283 mg/L (Marine crustacean Corophium volutator)
72h EC50 >695 mg/L (Algal toxicity marine unicellularn algae
Skeletonema costatum)
96h LC50 >3200 mg/L (Marine Fish Scophthalmus Maximus)
2,3,4,5-Tetrafluorobenzoic Acid, Sodium Salt 67852-79-3
2.90824E-13
(~0.03 ppb)
Acute Toxicity:
48h LC50: >305 mg/L (Marine Copepod Acartia tonsa)
10d LC50: 407 mg/L (Marine crustacean Corophium volutator)
72h EC50 >2075 mg/L (Algal toxicity marine unicellular algae
Skeletonema costatum)
96h LC50 440 mg/L (Marine Fish Scophthalmus Maximus)
Perfluorodimethylcyclobutane 2994-71-0
2.90824E-13
(~0.03 ppb)
Acute Toxicity:
Oral, mouse: LD50 = 300 mg/kg; Oral, rabbit: LD50 = 3200 mg/kg;
Oral, rat: LD50 = 980 mg/kg:
Carcinogenicity: Not listed by ACGIH, IARC, NIOSH, NTP, or
OSHA.
Perfluoromethylcyclopentane 1805-22-7
2.90824E-13
(~0.03 ppb)
Acute Toxicity:
Rabbit, eye: 100 mg/24H Moderate; Oral, Mouse: LD50 = 300
mg/kg; Oral, rabbit: LD50 = 3200 mg/kg; Oral, rat: LD50 = 980
mg/kg. Carcinogenicity: Not listed by ACGIH, IARC, NTP, or CA
Prop 65.
Perfluormethylcyclohexane 355-02-2
2.90824E-13
(~0.03 ppb)
Acute Toxicity:
96h LC50: >10,000 mg/L (Marine Copepod Acartia tonsa)
Biodegradation: 1% in 28 days
Perfluoroethylcyclohexane 335-21-7
2.90824E-13
(~0.03 ppb)
Acute Toxicity:
8800 ug/L 96 week(s) LC50 Striped bass (Morone saxatilis)
3100 ug/L 96 week(s) LC50 Bay shrimp (Crangon franciscorum)
i-Perfluoropropylcyclohexane 423-02-9
2.90824E-13
(~0.03 ppb)
Acute Toxicity:
48h LC50: >10,000 mg/L (Marine Copepod Acartia tonsa)


96h LC50 >5600 mg/L (Fish Scophthalmus maximus unicellular)
72h LC50 >10000 mg/L (Algae Skeletonema Costatum)
10d LC50 >12616 mg/L (Marine crustacean Corophium volutator)
Perfluorodecalin 306-94-5
2.90824E-13
(~0.03 ppb)
Acute Toxicity:
48h LC50: >10,000 mg/L (Marine Copepod Acartia tonsa)
96h LC50 >5600 mg/L (Fish Scophthalmus maximus unicellular)
72h LC50 >10000 mg/L ( Algae Skeletonema costatum)
10d LC50 >12710 mg/L (Marine crustacean Corophium volutator)
Silicon Dioxide 7631-86-9
<1E-10
(~<1ppb)
Acute Toxicity:
Oral, mouse: LD50 >8000 mg/kg; Oral, rabbit: LD50 > 5000
mg/kg; Oral, rat: LD50 > 10000 mg/kg.
Aluminium Oxide 1344-28-1
<1E-10
(~<1ppb
Acute Toxicity:
Oral LD50 Rat >5000 mg/kg
Iridium 192 Oxide 14694-69-0
<1E-10
(~<1ppb
Acute Toxicity:
Oral LD50 Rat: >10000 mg/kg.
Titanium Oxide 51745-87-0
<1E-10
(~<1ppb
Acute Toxicity:
Rat LD50: 5500 mg/kg I
Mouse LD50: 5400 mg/kg;
Potassium Oxide 12136-45-7
<1E-10
(~<1ppb
Acute Toxicity:
Oral LD50 Rat: 500 mg/kg
Iron Oxide 1332-37-2
<1E-10
(~<1ppb
Acute Toxicity:
LD50 in mice: 755 mg/kg
Calcium Oxide 1305-78-8
<1E-10
(~<1ppb
Acute Toxicity:
LD50 in mice: >20,000 mg/kg
Scadium46 Oxide 51745-87-0
2.90824E-13
(~0.03 ppb)
Acute Toxicity:
Inhalation, rat: LC50 = 64000 mg/L/4H
Antimony124 Oxide 14683-10-4
2.90824E-13
(~0.03 ppb)
Acute Toxicity:
Inhalation, rat: LC50 = 83.2 mg/L/4H
Methanol 67-56-1
2.90824E-13
(~0.03 ppb)
Acute Toxicity:
Oral, rat: LD50 = 5628 mg/kg
Dipropylene glycol methyl ether 34590-94-8
2.90824E-13
(~0.03 ppb)
Acute Toxicity:
Skin, rabbit: LD50 = 15800 mg/kg.
Xanthanum Gum 1113866-2 2.90824E-13 Acute Toxicity:


(~0.03 ppb) Component is classified by the US FDA as a "Direct Food
Additive" and an "Indirect Food Additive".
TOTAL 100%


















Appendix B
Chemical MSDSs

MATERIAL SAFETY DATA SHEET
Product Trade Name:
ACETIC ACID
Revision Date: 27-Aug-2013
Manufacturer/Supplier
Hazchem Code: 2P
Product Trade Name: ACETIC ACID
Poisons Schedule: S6
Halliburton Australia Pty. Ltd.
15 Marriott Road
Jandakot
WA 6164
Australia
ACN Number: 009 000 775
Telephone Number: 61 (08) 9455 8300
Fax Number: 61 (08) 9455 5300
Product Emergency Telephone
Australia: 08-64244950
Papua New Guinea: 05 1 281 575 5000
NewZealand: 06-7559274
Fire, Police & Ambulance - Emergency Telephone
Australia: 000
Papua New Guinea: 000
New Zealand: 111
Statement of Hazardous Nature
Application: Acid
Synonyms: None
Hazardous according to the criteria of NOHSC, Dangerous Goods according to
the criteria of ADG.
Prepared By Chemical Compliance
Telephone: 1-580-251-4335
e-mail: fdunexchem@halliburton.com
Chemical Family: Organic acid
2. COMPOSITION/INFORMATION ON INGREDIENTS
UN Number: , UN2790
Identification of Substances or Preparation
Substances CAS Number PERCENT (w/w) Australia NOHSCNew Zealand
WES
ACGIH TLV-TWA
Dangerous Goods Class: 8
ACETIC ACID
Subsidiary Risk:
Page 1 of 6
None
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Acetic acid 64-19-7 30 - 60% TWA: 10 ppm TWA:
25 mg/m
3
STEL: 15 ppm
STEL: 37 mg/m
3
STEL: 15 ppm
STEL: 37 mg/m
3
TWA: 10 ppm TWA:
25 mg/m
3
TWA: 10 ppm
STEL: 15 ppm
Non-Hazardous Substance to Total of 100%
3. HAZARDS IDENTIFICATION
Hazard Overview May cause eye, skin, and respiratory burns. May be harmful if swallowed.
Combustible.
Risk Phrases R10 Flammable.
R34 Causes burns.
HSNO Classification Not Determined
4. FIRST AID MEASURES
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory
irritation develops or if breathing becomes difficult.
Skin In case of contact, immediately flush skin with plenty of soap and water for at least
15 minutes. Get medical attention. Remove contaminated clothing and launder
before reuse.
Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of
water for at least 15 minutes and get medical attention immediately after flushing.
Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek
medical attention. Never give anything by mouth to an unconscious person.
Notes to Physician Not Applicable
5. FIRE FIGHTING MEASURES
Suitable Extinguishing Media
Water fog, carbon dioxide, foam, dry chemical.
Extinguishing media which must not be used for safety reasons
None known.
Special Exposure Hazards Use water spray to cool fire exposed surfaces. Decomposition in fire may produce
toxic gases. Do not allow runoff to enter waterways.
Special Protective Equipment
for Fire-Fighters
Full protective clothing and approved self-contained breathing apparatus required
for fire fighting personnel.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautionary
Measures
Use appropriate protective equipment.
Environmental Precautionary
Measures
Prevent from entering sewers, waterways, or low areas.
ACETIC ACID
Page 2 of 6
Procedure for Cleaning /
Absorption
Isolate spill and stop leak where safe. Neutralize with lime slurry, limestone, or
soda ash. Contain spill with sand or other inert materials. Scoop up and remove.
7. HANDLING AND STORAGE
Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands
after use. Launder contaminated clothing before reuse.
Storage Information Store away from alkalis. Store away from oxidizers. Store in a cool well ventilated
area. Keep container closed when not in use.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas
without good cross ventilation.
Respiratory Protection Organic vapor/acid gas respirator.
Hand Protection Impervious rubber gloves. Neoprene gloves. Nitrile gloves. Butyl rubber gloves.
Skin Protection Full protective chemical resistant clothing.
Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.
Other Precautions Eyewash fountains and safety showers must be easily accessible.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Color: Clear
Odor: Acrid
pH: 2.9
Specific Gravity @ 20 C (Water=1): 1.05
Density @ 20 C (kg/l): 1.048
Bulk Density @ 20 C (kg/M3): Not Determined
Boiling Point/Range (C): 117
Freezing Point/Range (C): 16
Pour Point/Range (C): Not Determined
Flash Point/Range (C): 42
Flash Point Method: Not Determined
Autoignition Temperature (C): Not Determined
Flammability Limits in Air - Lower (g/m
3
): Not Determined
Flammability Limits in Air - Lower (%): 5.4
Flammability Limits in Air - Upper (g/m
3
): Not Determined
Flammability Limits in Air - Upper (%): 16
Vapor Pressure @ 20 C (mmHg): 11.7
Vapor Density (Air=1): Not Determined
Percent Volatiles: 100
Evaporation Rate (Butyl Acetate=1): Not Determined
Solubility in Water (g/100ml): Soluble
Solubility in Solvents (g/100ml): Not Determined
VOCs (g/l): Not Determined
Viscosity, Dynamic @ 20 C (centipoise): Not Determined
Viscosity, Kinematic @ 20 C (centistokes): Not Determined
Partition Coefficient/n-Octanol/Water: Not Determined
Molecular Weight (g/mole): 60.6
Decomposition Temperature (C): Not Determined
ACETIC ACID
Page 3 of 6
10. STABILITY AND REACTIVITY
Stability Data: Stable
Hazardous Polymerization: Will Not Occur
Conditions to Avoid Keep away from heat, sparks and flame.
Incompatibility (Materials to
Avoid)
Strong alkalis.
Hazardous Decomposition
Products
Toxic fumes. Carbon monoxide and carbon dioxide.
Additional Guidelines Not Applicable
11. TOXICOLOGICAL INFORMATION
Principle Route of Exposure Eye or skin contact, inhalation.
Sympotoms related to exposure
Acute Toxicity
Inhalation Causes severe respiratory irritation.
Eye Contact May cause eye burns.
Skin Contact Causes severe burns.
Ingestion Causes burns of the mouth, throat and stomach.
Chronic Effects/Carcinogenicity Prolonged, excessive exposure may cause erosion of the teeth.
Toxicology data for the components
Substances
CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Acetic acid 64-19-7 3310 mg/kg ( Rat )
600 mg/kg (Rabbit)
1060 mg/kg ( Rabbit ) 11.4 mg/L ( Rat ) 4 h
12. ECOLOGICAL INFORMATION
Ecotoxicological Information
Ecotoxicity Product
Acute Fish Toxicity: Not determined
Acute Crustaceans Toxicity: Not determined
Acute Algae Toxicity: Not determined
Ecotoxicity Substance
Substances
CAS Number Toxicity to Algae Toxicity to Fish Toxicity to
Microorganisms
Daphnia Magna (Water
Flea)
Acetic acid 64-19-7 EC50: 90 mg/L
(Microcystis aeruginosa)
LC50: 79 mg/l
(Pimephales promelas)
LC50: 75 mg/l
(Pimephales promelas)
No information available EC50: 47 mg/l (Daphnia
magna)
LC50: 32 mg/L (Artemia
salina)
Persistence and degradability
Readily biodegradable
Bioaccumulative potential
Does not bioaccumulate
ACETIC ACID
Page 4 of 6
Mobility in soil
No information available
Results of PBT and vPvB assessment
No information available.
Other adverse effects
13. DISPOSAL CONSIDERATIONS
Disposal Method Disposal should be made in accordance with federal, state, and local regulations.
Contaminated Packaging Follow all applicable national or local regulations.
14. TRANSPORT INFORMATION
Land Transportation
ADR
UN2790, Acetic Acid Solution , 8 , III
Air Transportation
ICAO/IATA
UN2790, Acetic Acid Solution , 8 , III
RQ (Acetic Acid - 5683 kg.)
Sea Transportation
IMDG
UN2790, Acetic Acid Solution , 8 , III
RQ (Acetic Acid - 5683 kg.)
EmS F-A, S-B
Other Transportation Information
Labels: Corrosive
15. REGULATORY INFORMATION
Chemical Inventories
Australian AICS Inventory All components listed on inventory or are exempt.
New Zealand Inventory of
Chemicals
All components listed on inventory or are exempt.
US TSCA Inventory All components listed on inventory or are exempt.
EINECS Inventory This product, and all its components, complies with EINECS
Classification C - Corrosive.
ACETIC ACID
Page 5 of 6
Risk Phrases R10 Flammable.
R34 Causes burns.
Safety Phrases S23 Do not breathe gas, fumes, vapour or spray.
S26 In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.
S45 In case of accident or if you feel unwell, seek medical advice immediately.
S1/2 Keep locked up and out of reach of children.
16. OTHER INFORMATION
The following sections have been revised since the last issue of this SDS
Not applicable
Contact
Australian Poisons Information Centre
24 Hour Service: - 13 11 26
Police or Fire Brigade: - 000 (exchange): - 1100
New Zealand National Poisons Centre
0800 764 766
Additional Information For additional information on the use of this product, contact your local Halliburton
representative.
For questions about the Safety Data Sheet for this or other Halliburton products,
contact Chemical Compliance at 1-580-251-4335.
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to
accuracy or completeness. The information is obtained from various sources
including the manufacturer and other third party sources. The information may not
be valid under all conditions nor if this material is used in combination with other
materials or in any process. Final determination of suitability of any material is the
sole responsibility of the user.
***END OF MSDS***
ACETIC ACID
Page 6 of 6


MATERIAL SAFETY DATA SHEET
Product Trade Name:
BE-9
Revision Date: 21-Dec-2012
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Statement of Hazardous Nature Hazardous according to the criteria of NOHSC, Dangerous Goods according to the
criteria of ADG.
Manufacturer/Supplier Halliburton Australia Pty. Ltd.
15 Marriott Road
Jandakot
WA 6164
Australia
ACN Number: 009 000 775
Telephone Number: 61 (08) 9455 8300
Fax Number: 61 (08) 9455 5300
Product Emergency Telephone
Australia: 08-64244950
Papua New Guinea: 05 1 281 575 5000
NewZealand: 06-7559274
Fire, Police & Ambulance - Emergency Telephone
Australia: 000
Papua New Guinea: 000
New Zealand: 111
Identification of Substances or Preparation
Product Trade Name: BE-9
Synonyms: None
Chemical Family: Solution
UN Number: , UN2922
Dangerous Goods Class: 6.1
Subsidiary Risk: 8
Hazchem Code: 2X
Poisons Schedule: None
Application: Biocide
Prepared By Chemical Compliance
Telephone: 1-580-251-4335
e-mail: fdunexchem@halliburton.com
2. COMPOSITION/INFORMATION ON INGREDIENTS
Substances CAS Number PERCENT Australia
NOHSC
New Zealand
OEL
ACGIH TLV-TWA
Tributyl tetradecyl phosphonium
chloride
81741-28-8 5 - 10% Not applicable Not applicable Not applicable
BE-9
Page 1 of 6
Non-Hazardous Substance to Total of 100%
3. HAZARDS IDENTIFICATION
Hazard Overview May cause eye and skin burns. May cause respiratory irritation. May be harmful if
swallowed. May be harmful if inhaled.
Risk Phrases R22 Harmful if swallowed.
R36/38 Irritating to eyes and skin.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
HSNO Classification Not Determined
4. FIRST AID MEASURES
Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably
mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.
Skin Wash with soap and water. Get medical attention if irritation persists. Remove
contaminated clothing and launder before reuse. Remove contaminated shoes and
discard.
Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water
for at least 15 minutes and get medical attention immediately after flushing.
Ingestion If swallowed, do NOT induce vomiting. Give victim two glasses of water, Call a
physician immediately. Never give anything by mouth to an unconscious person.
Notes to Physician Not Applicable
5. FIRE FIGHTING MEASURES
Suitable Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.
Extinguishing media which must
not be used for safety reasons
None known.
Special Exposure Hazards Decomposition in fire may produce toxic gases. Do not allow runoff to enter
waterways. Use water spray to cool fire exposed surfaces.
Special Protective Equipment for
Fire-Fighters
Full protective clothing and approved self-contained breathing apparatus required for
fire fighting personnel.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautionary MeasuresUse appropriate protective equipment.
Environmental Precautionary
Measures
Prevent from entering sewers, waterways, or low areas.
Procedure for Cleaning /
Absorption
Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.
Scoop up and remove.
BE-9
Page 2 of 6
7. HANDLING AND STORAGE
Handling Precautions Avoid contact with eyes, skin, or clothing. Wash hands after use. Launder
contaminated clothing before reuse. Do NOT consume food, drink, or tobacco in
contaminated areas.
Storage Information Store in a cool well ventilated area. Keep container closed when not in use. Store
away from direct sunlight. Store in a dry location. Store in a manner to prevent
commingling with incompatible materials. Store away from alkalis. Store away from
reducing agents.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas
without good cross ventilation.
Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational
exposure limits or if exposure is unknown, wear a NIOSH certified, European
Standard EN 149, or equivalent respirator when using this product. Selection of and
instruction on using all personal protective equipment, including respirators, should
be performed by an Industrial Hygienist or other qualified professional.
Dust/mist respirator. (N95, P2/P3)
Hand Protection Impervious rubber gloves. Neoprene gloves. Polyvinylchloride gloves.
Skin Protection Wear impervious protective clothing, including boots, gloves, lab coat, apron, rain
jacket, pants or coverall, as appropriate, to prevent skin contact.
Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.
Other Precautions Eyewash fountains and safety showers must be easily accessible.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Color: Clear colorless
Odor: Slight
pH: 6-8
Specific Gravity @ 20 C (Water=1): 0.95-1.00
Density @ 20 C (kg/l): 0.95-1.00
Bulk Density @ 20 C (kg/m
3
): Not Determined
Boiling Point/Range (C): 100
Freezing Point/Range (C): Not Determined
Pour Point/Range (C): Not Determined
Flash Point/Range (C): Not Determined
Flash Point Method: Not Determined
Autoignition Temperature (C): Not Determined
Flammability Limits in Air - Lower (g/m
3
): Not Determined
Flammability Limits in Air - Lower (%): Not Determined
Flammability Limits in Air - Upper (g/m
3
): Not Determined
Flammability Limits in Air - Upper (%): Not Determined
Vapor Pressure @ 20 C (mmHg): Not Determined
Vapor Density (Air=1): Not Determined
Percent Volatiles: Not Determined
Evaporation Rate (Butyl Acetate=1): Not Determined
Solubility in Water (g/100ml): Miscible
Solubility in Solvents (g/100ml): Not Determined
VOCs (g/l): Not Determined
Viscosity, Dynamic @ 20 C (centipoise): Not Determined
BE-9
Page 3 of 6
9. PHYSICAL AND CHEMICAL PROPERTIES
Viscosity, Kinematic @ 20 C (centistokes): 55-65
Partition Coefficient/n-Octanol/Water: < 3
Molecular Weight (g/mole): Not Determined
Decomposition Temperature (C): Not Determined
10. STABILITY AND REACTIVITY
Stability Data: Stable
Hazardous Polymerization: Will Not Occur
Conditions to Avoid None anticipated
Incompatibility (Materials to
Avoid)
Reducing agents. Strong alkalis.
Hazardous Decomposition
Products
Chlorine. Phosphorus acids. Carbon monoxide and carbon dioxide.
Additional Guidelines Not Applicable
11. TOXICOLOGICAL INFORMATION
Principle Route of Exposure Eye or skin contact, inhalation.
Inhalation May cause respiratory irritation. May be harmful if inhaled.
Skin Contact May cause skin burns. Harmful if absorbed through the skin.
Eye Contact May cause eye burns.
Ingestion May be harmful if swallowed.
Aggravated Medical Conditions Lung disorders. Skin disorders.
Chronic Effects/Carcinogenicity Not determined
Other Information None known.
Toxicity Tests
Oral Toxicity: LD50: > 2000 mg/kg (Rat)
Dermal Toxicity: Not determined
Inhalation Toxicity: LC50: 0.9 mg/l 4-hour (rat) (TTPC)
Primary Irritation Effect: Not determined
Carcinogenicity Not determined
Genotoxicity: Ames test: negative
Reproductive /
Developmental Toxicity:
Not determined
12. ECOLOGICAL INFORMATION
Mobility (Water/Soil/Air) Not determined
Persistence/Degradability Readily biodegradable
BE-9
Page 4 of 6
Bio-accumulation Not determined
Ecotoxicological Information
Acute Fish Toxicity: LC50: (96 hour) 0.46 mg/L (Oncorhynchus mykiss)
LC50: (96 hour) 0.06 mg/l (Lepomis macrochirus)
LC50: (96 hour) 0.58 mg/l (fish)
Acute Crustaceans Toxicity:TLM96: 1.6 mg/l (Crangon crangon) TLM48: 0.025 mg/l (Daphnia magna)
Acute Algae Toxicity: Not determined
Chemical Fate Information Not determined
Other Information Not applicable
13. DISPOSAL CONSIDERATIONS
Disposal Method Disposal should be made in accordance with federal, state, and local regulations.
Incineration recommended in approved incinerator according to federal, state, and
local regulations.
Contaminated Packaging Follow all applicable national or local regulations.
14. TRANSPORT INFORMATION
Land Transportation
ADR
UN2922, Corrosive Liquid, Toxic, N.O.S.(contains Tributyl Tetradecyl Phosphonium Chloride), 8, (6.1), II
Air Transportation
ICAO/IATA
UN2922, Corrosive Liquid, Toxic, N.O.S., 8, (6.1), II
(contains Tributyl Tetradecyl Phosphonium Chloride)
Sea Transportation
IMDG
UN2922, Corrosive Liquid, Toxic, N.O.S.(contains Tributyl Tetradecyl Phosphonium Chloride), 8, (6.1), II
EmS F-A, S-B
Other Transportation Information
Labels: Corrosive
Toxic
15. REGULATORY INFORMATION
Chemical Inventories
Australian AICS Inventory All components listed on inventory or are exempt.
New Zealand Inventory of
Chemicals
This product does not comply with NZIOC
US TSCA Inventory All components listed on inventory or are exempt.
EINECS Inventory This product, and all its components, complies with EINECS
BE-9
Page 5 of 6
Classification Xi - Irritant.
N - Dangerous For The Environment.
Risk Phrases R22 Harmful if swallowed.
R36/38 Irritating to eyes and skin.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
Safety Phrases S26 In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.
S45 In case of accident or if you feel unwell, seek medical advice immediately.
S60 This material and/or its container must be disposed of as hazardous waste.
S61 Avoid release to the environment. Refer to special instructions/Safety data
sheets.
S1/2 Keep locked up and out of reach of children.
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
16. OTHER INFORMATION
The following sections have been revised since the last issue of this MSDS
Section 15. Regulatory Information
Contact
Australian Poisons Information Centre
24 Hour Service: - 13 11 26
Police or Fire Brigade: - 000 (exchange): - 1100
New Zealand National Poisons Centre
0800 764 766
Additional Information For additional information on the use of this product, contact your local Halliburton
representative.
For questions about the Material Safety Data Sheet for this or other Halliburton
products, contact Chemical Compliance at 1-580-251-4335.
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy
or completeness. The information is obtained from various sources including the
manufacturer and other third party sources. The information may not be valid under
all conditions nor if this material is used in combination with other materials or in any
process. Final determination of suitability of any material is the sole responsibility of
the user.
***END OF MSDS***
BE-9
Page 6 of 6

MATERIAL SAFETY DATA SHEET
Product Trade Name:
CLBXTAU121
Revision Date: 07-Nov-2012
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Statement of Hazardous Nature Non-Hazardous according to the criteria of NOHSC, Non-Dangerous Goods
according to the criteria of ADG.
Manufacturer/Supplier Halliburton Australia Pty. Ltd.
15 Marriott Road
Jandakot
WA 6164
Australia
ACN Number: 009 000 775
Telephone Number: 61 (08) 9455 8300
Fax Number: 61 (08) 9455 5300
Product Emergency Telephone
Australia: 08-64244950
Papua New Guinea: 05 1 281 575 5000
NewZealand: 06-7559274
Fire, Police & Ambulance - Emergency Telephone
Australia: 000
Papua New Guinea: 000
New Zealand: 111
Identification of Substance or Preparation
Product Trade Name: CLBXTAU121
Synonyms: None
Chemical Family: Organic hydrocarbon
UN Number: None
Dangerous Goods Class: None
Subsidiary Risk: None
Hazchem Code: None
Poisons Schedule: None
Application: Breaker
Prepared By Chemical Compliance
Telephone: 1-580-251-4335
e-mail: fdunexchem@halliburton.com
2. COMPOSITION/INFORMATION ON INGREDIENTS
Substance CAS Number Percent Australia
NOHSC
New Zealand
OEL
ACGIH TLV-TWA
Citric acid, triethyl ester 77-93-0 60 - 100% Not determined Not determined Not applicable
CLBXTAU121
Page 1 of 6
Non-hazardous Substance to Total of 100%
3. HAZARDS IDENTIFICATION
Hazard Overview No significant hazards expected.
Risk Phrases None
HSNO Classification Non-hazardous
4. FIRST AID MEASURES
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation
develops or if breathing becomes difficult.
Skin Get medical attention if irritation persists. Wash with soap and water.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 25 minutes
and get medical attention if irritation persists.
Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek
medical attention. Never give anything by mouth to an unconscious person.
Notes to Physician Not Applicable
5. FIRE FIGHTING MEASURES
Suitable Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.
Unsuitable Extinguishing Media None known
Special Exposure Hazards Not applicable.
Special Protective Equipment for
Fire-Fighters
Full protective clothing and approved self-contained breathing apparatus required for
fire fighting personnel.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautionary MeasuresUse Appropriate protective equipment. Slippery when wet.
Environmental Precautionary
Measures
Prevent from entering sewers, waterways or low areas.
Procedure for
Cleaning/Absorption
Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.
Scoop up and remove.
7. HANDLING AND STORAGE
Handling Precautions Wash hands after use. Avoid contact with eyes, skin, or clothing. Avoid breathing
mist. Avoid breathing vapours.
Storage Information Keep from freezing. Store away from oxidisers. Keep container closed when not in
use. Store in a well ventilated area. Product has a shelf life of 24 months
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls Use in a well ventilated area.
CLBXTAU121
Page 2 of 6
Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational
exposure limits or if exposure is unknown, wear a NIOSH certified, European
Standard EN 149, or equivalent respirator when using this product. Selection of and
instruction on using all personal protective equipment, including respirators, should
be performed by an Industrial Hygienist or other qualified professional.
Not normally needed. But if significant exposures are possible then the following
respirator is recommended. Dust/mist respirator. (N95,P2/P3)
Hand Protection Normal work gloves.
Skin Protection Normal work coveralls.
Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.
Other Precautions None known.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Colour: Light green
Odour: Odourless
pH: Not Determined
Specific Gravity @ 20 C (Water=1): 1.14
Density @ 20 C (kg/l): 0.988
Bulk Density @ 20 C (kg/l): Not Determined
Boiling Point/Range (C): 294
Freezing Point/Range (C): -45
Pour Point/Range (C): Not Determined
Flash Point/Range (C): 155
Flash Point Method: CC
Autoignition Temperature (C): Not Determined
Flammability Limits in Air - Lower (g/m
3
): Not Determined
Flammability Limits in Air - Lower (%): Not Determined
Flammability Limits in Air - Upper (g/m
3
): Not Determined
Flammability Limits in Air - Upper (%): Not Determined
Vapour Pressure @ 20 C (mmHg): < 1
Vapour Density (Air=1): 9.54
Percent Volatiles: Not Determined
Evaporation Rate (Butyl Acetate = 1): Not determined.
Solubility in Water (g/100ml): Soluble
Solubility in Solvents (g/100ml): Not Determined
VOCs (g/l): Not Determined
Viscosity, Dynamic @ 20 C
(centipoise):
Not Determined
Viscosity, Kinematic @ 20 C
(centistokes):
Not Determined
Partition Coefficient/n-Octanol/Water: Not Determined
Molecular Weight (g/mole): 276.28
Decomposition Temperature (C): Not Determined
10. STABILITY AND REACTIVITY
Stability Data: Stable
Hazardous Polymerisation: Will Not Occur
Conditions to Avoid None anticipated
CLBXTAU121
Page 3 of 6
Incompatibility (Materials to
Avoid)
None known.
Hazardous Decomposition
Products
Carbon monoxide and carbon dioxide.
Additional Guidelines Not Applicable
11. TOXICOLOGICAL INFORMATION
Principle Route of Exposure Eye or skin contact, inhalation.
Inhalation May cause mild respiratory irritation.
Skin Contact May cause mild skin irritation.
Eye Contact May cause mild eye irritation.
Ingestion May cause abdominal pain, vomiting, nausea, and diarrhoea.
Aggravated Medical Conditions None known.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are
chronic health hazards.
Other Information None known.
Toxicity Tests
Oral Toxicity: LD50: > 5000 mg/kg (Rat)
Dermal Toxicity: LD50: > 5000 mg/kg (Rabbit)
Inhalation Toxicity: LC50: 1300 ppm/6 hr. (Rat)
Primary Irritation Effect: Not determined
Carcinogenicity: Not determined
Genotoxicity: Not determined
Reproductive/Development
al
Toxicity:
Not determined
12. ECOLOGICAL INFORMATION
Mobility (Water/Soil/Air) Not determined
Persistence/Degradability Not determined
Bio-accumulation Not Determined
Ecotoxicological Information
Acute Fish Toxicity: Not determined
Acute Crustaceans Toxicity:Not determined
Acute Algae Toxicity: Not determined
Chemical Fate Information Not determined
Other Information Not applicable
CLBXTAU121
Page 4 of 6
13. DISPOSAL CONSIDERATIONS
Disposal Method Disposal should be made in accordance with federal, state and local regulations.
Contaminated Packaging Empty container completely. Transport with all closures in place. Return for reuse or
dispose in a sanitary landfill according to national or local regulations.
14. TRANSPORT INFORMATION
Land Transportation
ADR Not restricted
Air Transportation
ICAO/IATA Not restricted
Sea Transportation
IMDG Not restricted
Other Shipping Information
Labels: None
15. REGULATORY INFORMATION
Chemical Inventories
Australian AICS Inventory All components listed.
New Zealand Inventory of
Chemicals
All components listed on inventory or are exempt.
US TSCA Inventory All components listed.
EINECS Inventory All components are listed on the inventory.
Classification Not Determined
Risk Phrases None
Safety Phrases None
16. OTHER INFORMATION
The following sections have been revised since the last issue of this MSDS:
Not applicable
Contact
Australian Poisons Information Centre
24 Hour Service: - 13 11 26
Police or Fire Brigade: - 000 (exchange): - 1100
New Zealand National Poisons Centre
0800 764 766
CLBXTAU121
Page 5 of 6
Additional Information For additional information on the use of this product, contact your local Halliburton
representative.
For questions about the Material Safety Data Sheet for this or other Halliburton
products, contact Product Stewardship at 1-580-251-4335.
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy
or completeness. The information is obtained from various sources including the
manufacturer and other third party sources. The information may not be valid under
all conditions nor if this material is used in combination with other materials or in any
process. Final determination of suitability of any material is the sole responsibility of
the user.
***END OF MSDS***
CLBXTAU121
Page 6 of 6

MATERIAL SAFETY DATA SHEET
Product Trade Name:
CLLAU301
Revision Date: 20-Aug-2012
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Statement of Hazardous Nature Hazardous according to the criteria of NOHSC, Non-Dangerous Goods according to
the criteria of ADG.
Manufacturer/Supplier Halliburton Australia Pty. Ltd.
15 Marriott Road
Jandakot
WA 6164
Australia
ACN Number: 009 000 775
Telephone Number: 61 (08) 9455 8300
Fax Number: 61 (08) 9455 5300
Product Emergency Telephone
Australia: 08-64244950
Papua New Guinea: 05 1 281 575 5000
NewZealand: 06-7559274
Fire, Police & Ambulance - Emergency Telephone
Australia: 000
Papua New Guinea: 000
New Zealand: 111
Identification of Substance or Preparation
Product Trade Name: CLLAU301
Synonyms: None
Chemical Family: Inorganic Blend
UN Number: None
Dangerous Goods Class: None
Subsidiary Risk: None
Hazchem Code: None
Poisons Schedule: S6
Application: Crosslinker
Prepared By Chemical Compliance
Telephone: 1-580-251-4335
e-mail: fdunexchem@halliburton.com
2. COMPOSITION/INFORMATION ON INGREDIENTS
Substance CAS Number Percent Australia
NOHSC
New Zealand
WES
ACGIH TLV-TWA
Inorganic salt Proprietary 5 - 10% TWA: 2 mg/m
3
TWA: 2 mg/m
3
2 mg/m
3
CLLAU301
Page 1 of 6
2. COMPOSITION/INFORMATION ON INGREDIENTS
Sulfuric acid 7664-93-9 1 - 5% TWA: 1 mg/m
3
STEL: 3 mg/m
3
TWA: 1 mg/m
3
TWA: 0.2 mg/m
3
Non-hazardous Substance to Total of 100%
3. HAZARDS IDENTIFICATION
Hazard Overview May cause eye, skin and respiratory irritation.
Risk Phrases
R36/38 Irritating to eyes and skin.
HSNO Classification 6.1E Acutely Toxic Substances 6.3A Irritating to the skin 6.4A Irritating to the eye
8.1A Corrosive to metals 9.1D Slightly harmful in the aquatic environment
4. FIRST AID MEASURES
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation
develops or if breathing becomes difficult.
Skin Wash with soap and water. Get medical attention if irritation persists.
Eyes Immediately flush eyes with large amounts of water for at least 15 minutes. Get
immediate medical attention.
Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek
medical attention. Never give anything by mouth to an unconscious person.
Notes to Physician Not Applicable
5. FIRE FIGHTING MEASURES
Suitable Extinguishing Media All standard fire fighting media
Unsuitable Extinguishing Media None known
Special Exposure Hazards Not applicable.
Special Protective Equipment for
Fire-Fighters
Not applicable.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautionary MeasuresUse Appropriate protective equipment.
Environmental Precautionary
Measures
Prevent from entering sewers, waterways or low areas.
Procedure for
Cleaning/Absorption
Isolate spill and stop leak where safe. Neutralise with lime slurry, limestone, or soda
ash. Contain spill with sand or other inert materials. Scoop up and remove.
7. HANDLING AND STORAGE
Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing mist.
Storage Information Store in a cool, dry location. Product has a shelf life of 24 months
CLLAU301
Page 2 of 6
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls Use in a well ventilated area.
Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational
exposure limits or if exposure is unknown, wear a NIOSH certified, European
Standard EN 149, or equivalent respirator when using this product. Selection of and
instruction on using all personal protective equipment, including respirators, should
be performed by an Industrial Hygienist or other qualified professional.
Not normally needed. But if significant exposures are possible then the following
respirator is recommended. Dust/mist respirator. (N95,P2/P3)
Hand Protection Impervious rubber gloves.
Skin Protection Normal work coveralls.
Eye Protection Wear safety glasses or goggles to protect against exposure.
Other Precautions None known.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Colour: White
Odour: Odourless
pH: 0.80
Specific Gravity @ 20 C (Water=1): 1.01
Density @ 20 C (kg/l): Not Determined
Bulk Density @ 20 C (kg/l): Not Determined
Boiling Point/Range (C): Not Determined
Freezing Point/Range (C): Not Determined
Pour Point/Range (C): Not Determined
Flash Point/Range (C): Not Determined
Flash Point Method: Not Determined
Autoignition Temperature (C): Not Determined
Flammability Limits in Air - Lower (g/m
3
): Not Determined
Flammability Limits in Air - Lower (%): Not Determined
Flammability Limits in Air - Upper (g/m
3
): Not Determined
Flammability Limits in Air - Upper (%): Not Determined
Vapour Pressure @ 20 C (mmHg): Not Determined
Vapour Density (Air=1): Not Determined
Percent Volatiles: Not Determined
Evaporation Rate (Butyl Acetate = 1): Not determined.
Solubility in Water (g/100ml): Soluble
Solubility in Solvents (g/100ml): Not Determined
VOCs (g/l): Not Determined
Viscosity, Dynamic @ 20 C
(centipoise):
Not Determined
Viscosity, Kinematic @ 20 C
(centistokes):
Not Determined
Partition Coefficient/n-Octanol/Water: Not Determined
Molecular Weight (g/mole): Not Determined
Decomposition Temperature (C): Not Determined
10. STABILITY AND REACTIVITY
Stability Data: Stable
Hazardous Polymerisation: Will Not Occur
CLLAU301
Page 3 of 6
Conditions to Avoid None anticipated
Incompatibility (Materials to
Avoid)
Strong alkalis
Hazardous Decomposition
Products
Oxides of sulphur.
Additional Guidelines Not Applicable
11. TOXICOLOGICAL INFORMATION
Principle Route of Exposure Eye or skin contact, inhalation.
Sympotoms related to exposure
Inhalation May cause respiratory irritation.
Skin Contact May cause skin irritation.
Eye Contact May cause severe eye irritation.
Ingestion In large amounts: May cause abdominal pain, vomiting, nausea, and diarrhoea.
Aggravated Medical Conditions None known.
Chronic Effects/Carcinogenicity Contains sulphuric acid, a potential carcinogen.
Other Information None known.
Toxicity Tests
Oral Toxicity: Not determined
Dermal Toxicity: Not determined.
Inhalation Toxicity: Not determined
Primary Irritation Effect: Not determined
Carcinogenicity: Not determined
Genotoxicity: Not determined
Reproductive/Development
al
Toxicity:
Not determined
12. ECOLOGICAL INFORMATION
Mobility (Water/Soil/Air) Not determined
Persistence/Degradability Not applicable
Bio-accumulation Not Determined
Ecotoxicological Information
Acute Fish Toxicity: Not determined
Acute Crustaceans Toxicity:Not determined
Acute Algae Toxicity: Not determined
Chemical Fate Information Not determined
CLLAU301
Page 4 of 6
Other Information Not applicable
13. DISPOSAL CONSIDERATIONS
Disposal Method Disposal should be made in accordance with federal, state and local regulations.
Contaminated Packaging Follow all applicable national or local regulations.
14. TRANSPORT INFORMATION
Land Transportation
ADR Not restricted
Air Transportation
ICAO/IATA Not restricted
Sea Transportation
IMDG Not restricted
Other Shipping Information
Labels: None
15. REGULATORY INFORMATION
Chemical Inventories
Australian AICS Inventory All components listed.
New Zealand Inventory of
Chemicals
All components listed on inventory or are exempt.
US TSCA Inventory All components listed.
EINECS Inventory All components are listed on the inventory.
Classification Xi - Irritant.
Risk Phrases
R36/38 Irritating to eyes and skin.
Safety Phrases S23 Do not breathe gas, fumes, vapour or spray.
S24/25 Avoid contact with skin and eyes.
16. OTHER INFORMATION
The following sections have been revised since the last issue of this MSDS:
Not applicable
CLLAU301
Page 5 of 6
Contact
Australian Poisons Information Centre
24 Hour Service: - 13 11 26
Police or Fire Brigade: - 000 (exchange): - 1100
New Zealand National Poisons Centre
0800 764 766
Additional Information For additional information on the use of this product, contact your local Halliburton
representative.
For questions about the Material Safety Data Sheet for this or other Halliburton
products, contact Product Stewardship at 1-580-251-4335.
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy
or completeness. The information is obtained from various sources including the
manufacturer and other third party sources. The information may not be valid under
all conditions nor if this material is used in combination with other materials or in any
process. Final determination of suitability of any material is the sole responsibility of
the user.
***END OF MSDS***
CLLAU301
Page 6 of 6


MATERIAL SAFETY DATA SHEET
Product Trade Name:
FDP-S1085-13
Revision Date: 21-Feb-2013
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Trade Name: FDP-S1085-13
Synonyms: None
Chemical Family: Polymer Blend
Application: Scale Inhibitor
Manufacturer/Supplier Halliburton Energy Services, Inc.
P.O. Box 1431
Duncan, Oklahoma 73536-0431
Emergency Telephone: (281) 575-5000
Prepared By Chemical Compliance
Telephone: 1-580-251-4335
e-mail: fdunexchem@halliburton.com
2. COMPOSITION/INFORMATION ON INGREDIENTS
Substances CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA
Polyacrylate 10 - 30% Not applicable Not applicable
3. HAZARDS IDENTIFICATION
Hazard Overview May cause eye and skin irritation.
4. FIRST AID MEASURES
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation
develops or if breathing becomes difficult.
Skin Wash with soap and water. Get medical attention if irritation persists.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes
and get medical attention if irritation persists.
Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek
medical attention. Never give anything by mouth to an unconscious person.
Notes to Physician Treat symptomatically.
FDP-S1085-13
Page 1 of 5
5. FIRE FIGHTING MEASURES
Flash Point/Range (F): > 200Min: > 200
Flash Point/Range (C): > 93.3Min: > 95
Flash Point Method: ASTM D3278-78
Autoignition Temperature (F): Not Determined
Autoignition Temperature (C): Not Determined
Flammability Limits in Air - Lower (%): Not Determined
Flammability Limits in Air - Upper (%): Not Determined
Fire Extinguishing Media All standard firefighting media. Do NOT spray pool fires directly with water. A solid
stream of water directed into hot burning liquid can cause splattering.
Special Exposure Hazards Decomposition in fire may produce toxic gases.
Special Protective Equipment for
Fire-Fighters
Full protective clothing and approved self-contained breathing apparatus required for
fire fighting personnel.
NFPA Ratings: Health 1, Flammability 1, Reactivity 0
HMIS Ratings: Health 1, Flammability 1, Physical Hazard 0 , PPE: B
6. ACCIDENTAL RELEASE MEASURES
Personal Precautionary MeasuresUse appropriate protective equipment.
Environmental Precautionary
Measures
Prevent from entering sewers, waterways, or low areas.
Procedure for Cleaning /
Absorption
Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.
Scoop up and remove.
7. HANDLING AND STORAGE
Handling Precautions Avoid contact with eyes, skin, or clothing.
Storage Information Store away from oxidizers. Product has a shelf life of 12 months.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls Use in a well ventilated area.
Respiratory Protection Not normally necessary.
Hand Protection Butyl rubber gloves.
Skin Protection Normal work coveralls.
Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.
Other Precautions Eyewash fountains and safety showers must be easily accessible.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Color: Clear
Odor: Mild
pH: 5.7 - 5.9
Specific Gravity @ 20 C (Water=1): 1.137
FDP-S1085-13
Page 2 of 5
9. PHYSICAL AND CHEMICAL PROPERTIES
Density @ 20 C (lbs./gallon): 9.47
Bulk Density @ 20 C (lbs/ft3): Not Determined
Boiling Point/Range (F): Not Determined
Boiling Point/Range (C): Not Determined
Freezing Point/Range (F): Not Determined
Freezing Point/Range (C): Not Determined
Vapor Pressure @ 20 C (mmHg): Not Determined
Vapor Density (Air=1): Not Determined
Percent Volatiles: ~ 80
Evaporation Rate (Butyl Acetate=1): Not Determined
Solubility in Water (g/100ml): Soluble
Solubility in Solvents (g/100ml): Not Determined
VOCs (lbs./gallon): Not Determined
Viscosity, Dynamic @ 20 C (centipoise): Not Determined
Viscosity, Kinematic @ 20 C (centistokes): Not Determined
Partition Coefficient/n-Octanol/Water: Not Determined
Molecular Weight (g/mole): Not Determined
10. STABILITY AND REACTIVITY
Stability Data: Stable
Hazardous Polymerization: Will Not Occur
Conditions to Avoid None known.
Incompatibility (Materials to
Avoid)
Strong oxidizers.
Hazardous Decomposition
Products
Carbon monoxide and carbon dioxide. Toxic monomer fumes.
Additional Guidelines Not Applicable
11. TOXICOLOGICAL INFORMATION
Principle Route of Exposure Eye and skin contact.
Inhalation May cause respiratory irritation.
Skin Contact May cause skin irritation.
Eye Contact May cause eye irritation.
Ingestion Irritation of the mouth, throat, and stomach.
Aggravated Medical Conditions None known.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are
chronic health hazards.
Other Information None known.
Toxicity Tests
Oral Toxicity: Not determined
Dermal Toxicity: Not determined
Inhalation Toxicity: Not determined
FDP-S1085-13
Page 3 of 5
Primary Irritation Effect: Not determined
Carcinogenicity Not determined
Genotoxicity: Not determined
Reproductive /
Developmental Toxicity:
Not determined
12. ECOLOGICAL INFORMATION
Mobility (Water/Soil/Air) Not determined
Persistence/Degradability Not determined
Bio-accumulation Not determined
Ecotoxicological Information
Acute Fish Toxicity: Not determined
Acute Crustaceans Toxicity:Not determined
Acute Algae Toxicity: Not determined
Chemical Fate Information Not determined
Other Information Not applicable
13. DISPOSAL CONSIDERATIONS
Disposal Method Disposal should be made in accordance with federal, state, and local regulations.
Contaminated Packaging Follow all applicable national or local regulations.
14. TRANSPORT INFORMATION
Land Transportation
DOT
Not restricted
Canadian TDG
Not restricted
ADR
Not restricted
Air Transportation
ICAO/IATA
Not restricted
Sea Transportation
IMDG
Not restricted
FDP-S1085-13
Page 4 of 5
Other Transportation Information
Labels: None
15. REGULATORY INFORMATION
US Regulations
US TSCA Inventory All components listed on inventory or are exempt.
EPA SARA Title III Extremely
Hazardous Substances
Not applicable
EPA SARA (311,312) Hazard
Class
Acute Health Hazard
EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical
Release Reporting" under Section 313 (40 CFR 372).
EPA CERCLA/Superfund
Reportable Spill Quantity
Not applicable.
EPA RCRA Hazardous Waste
Classification
If product becomes a waste, it does NOT meet the criteria of a hazardous waste as
defined by the US EPA.
California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.
MA Right-to-Know Law One or more components listed.
NJ Right-to-Know Law One or more components listed.
PA Right-to-Know Law One or more components listed.
Canadian Regulations
Canadian DSL Inventory All components listed on inventory or are exempt.
WHMIS Hazard Class Un-Controlled
16. OTHER INFORMATION
The following sections have been revised since the last issue of this MSDS
Not applicable
Additional Information For additional information on the use of this product, contact your local Halliburton
representative.
For questions about the Safety Data Sheet for this or other Halliburton products,
contact Chemical Compliance at 1-580-251-4335.
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy
or completeness. The information is obtained from various sources including the
manufacturer and other third party sources. The information may not be valid under
all conditions nor if this material is used in combination with other materials or in any
process. Final determination of suitability of any material is the sole responsibility of
the user.
***END OF MSDS***
FDP-S1085-13
Page 5 of 5


MATERIAL SAFETY DATA SHEET
Product Trade Name:
FE-2
Revision Date: 04-Jan-2011
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Statement of Hazardous Nature Hazardous according to the criteria of NOHSC, Non-Dangerous Goods according to
the criteria of ADG.
Manufacturer/Supplier Halliburton Australia Pty. Ltd.
53-55 Bannister Road
Canning Vale
WA 6155
Australia
ACN Number: 009 000 775
Telephone Number: 61 (08) 9455 8300
Fax Number: 61 (08) 9455 5300
Product Emergency Telephone
Australia: 08-64244950
Papua New Guinea: 05 1 281 575 5000
NewZealand: 06-7559274
Fire, Police & Ambulance - Emergency Telephone
Australia: 000
Papua New Guinea: 000
New Zealand: 111
Identification of Substances or Preparation
Product Trade Name: FE-2
Synonyms: None
Chemical Family: Organic acid
UN Number: None
Dangerous Goods Class: None
Subsidiary Risk: None
Hazchem Code: None
Poisons Schedule: None
Application: Iron Control Agent
Prepared By Chemical Compliance
Telephone: 1-580-251-4335
e-mail: fdunexchem@halliburton.com
2. COMPOSITION/INFORMATION ON INGREDIENTS
Substances CAS Number PERCENT Australia NOHSC ACGIH TLV-TWA
Citric acid 77-92-9 60 - 100% Not applicable Not applicable
Total to 100%
FE-2
Page 1 of 6
3. HAZARDS IDENTIFICATION
Hazard Overview May cause eye, skin, and respiratory irritation. Airborne dust may be explosive.
Hazard Ratings
Flammability: 0
Toxicty: 0
Body Contact: 1
Reactivity: 0
Chronic: 0
Scale: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4
4. FIRST AID MEASURES
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation
develops or if breathing becomes difficult.
Skin Wash with soap and water. Get medical attention if irritation persists.
Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water
for at least 15 minutes and get medical attention immediately after flushing.
Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek
medical attention. Never give anything by mouth to an unconscious person.
Notes to Physician Not Applicable
5. FIRE FIGHTING MEASURES
Suitable Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.
Extinguishing media which must
not be used for safety reasons
None known.
Special Exposure Hazards Decomposition in fire may produce toxic gases. Organic dust in the presence of an
ignition source can be explosive in high concentrations. Good housekeeping
practices are required to minimize this potential.
Special Protective Equipment for
Fire-Fighters
Full protective clothing and approved self-contained breathing apparatus required for
fire fighting personnel.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.
Environmental Precautionary
Measures
Prevent from entering sewers, waterways, or low areas.
Procedure for Cleaning /
Absorption
Scoop up and remove.
7. HANDLING AND STORAGE
Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust.
Storage Information Store away from alkalis. Store away from oxidizers. Store in a cool, dry location.
Product has a shelf life of 60 months.
FE-2
Page 2 of 6
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls Use in a well ventilated area.
Respiratory Protection Dust/mist respirator. (95%)
Hand Protection Impervious rubber gloves.
Skin Protection Normal work coveralls.
Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.
Other Precautions Eyewash fountains and safety showers must be easily accessible.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Solid
Color: White
Odor: Odorless
pH: 1.8
Specific Gravity @ 20 C (Water=1): 1.665
Density @ 20 C (kg/l): Not Determined
Bulk Density @ 20 C (kg/m
3
): Not Determined
Boiling Point/Range (C): Not Determined
Freezing Point/Range (C): Not Determined
Pour Point/Range (C): Not Determined
Flash Point/Range (C): Not Determined
Flash Point Method: Not Determined
Autoignition Temperature (C): 1000
Flammability Limits in Air - Lower (g/m
3
): Not Determined
Flammability Limits in Air - Lower (%): 8
Flammability Limits in Air - Upper (g/m
3
): Not Determined
Flammability Limits in Air - Upper (%): 65
Vapor Pressure @ 20 C (mmHg): Not Determined
Vapor Density (Air=1): Not Determined
Percent Volatiles: 0
Evaporation Rate (Butyl Acetate=1): Not Determined
Solubility in Water (g/100ml): Soluble
Solubility in Solvents (g/100ml): Not Determined
VOCs (g/l): Not Determined
Viscosity, Dynamic @ 20 C (centipoise): Not Determined
Viscosity, Kinematic @ 20 C (centistrokes): Not Determined
Partition Coefficient/n-Octanol/Water: Not Determined
Molecular Weight (g/mole): 192.13
Decomposition Temperature (C): Not Determined
10. STABILITY AND REACTIVITY
Stability Data: Stable
Hazardous Polymerization: Will Not Occur
Conditions to Avoid None anticipated
Incompatibility (Materials to
Avoid)
Strong alkalis. Strong oxidizers.
Hazardous Decomposition
Products
Carbon monoxide and carbon dioxide.
FE-2
Page 3 of 6
Additional Guidelines Not Applicable
11. TOXICOLOGICAL INFORMATION
Principle Route of Exposure Eye or skin contact, inhalation.
Inhalation May cause respiratory irritation.
Skin Contact May cause skin irritation.
Eye Contact May cause severe eye irritation.
Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,
nausea, and diarrhea.
Aggravated Medical Conditions None known.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are
chronic health hazards.
Other Information None known.
Toxicity Tests
Oral Toxicity: LD50: 11700 mg/kg (Rat)
Dermal Toxicity: Not determined
Inhalation Toxicity: Not determined
Primary Irritation Effect: Not determined
Carcinogenicity Not determined
Genotoxicity: Not determined
Reproductive /
Developmental Toxicity:
Not determined
12. ECOLOGICAL INFORMATION
Mobility (Water/Soil/Air) Not determined
Persistence/Degradability Biodegradable
Bio-accumulation Not determined
Ecotoxicological Information
Acute Fish Toxicity: Not determined
Acute Crustaceans Toxicity:TLM96: 100-330 ppm (Crangon crangon)
Acute Algae Toxicity: Not determined
Chemical Fate Information Not determined
Other Information Not applicable
FE-2
Page 4 of 6
13. DISPOSAL CONSIDERATIONS
Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.
Contaminated Packaging Follow all applicable national or local regulations.
14. TRANSPORT INFORMATION
Land Transportation
ADR
Not restricted
Air Transportation
ICAO/IATA
Not restricted
Sea Transportation
IMDG
Not restricted
Other Shipping Information
Labels: None
15. REGULATORY INFORMATION
Chemical Inventories
Australian AICS Inventory All components listed.
US TSCA Inventory All components listed on inventory or are exempt.
EINECS Inventory This product, and all its components, complies with EINECS
Classification Xi - Irritant.
Risk Phrases R36 Irritating to eyes.
Safety Phrases
S24/25 Avoid contact with skin and eyes.
16. OTHER INFORMATION
The following sections have been revised since the last issue of this MSDS
Not applicable
Contact
Australian Poisons Information Centre
24 Hour Service: - 13 11 26
Police or Fire Brigade: - 000 (exchange): - 1100
New Zealand National Poisons Centre
0800 764 766
FE-2
Page 5 of 6
Additional Information For additional information on the use of this product, contact your local Halliburton
representative.
For questions about the Material Safety Data Sheet for this or other Halliburton
products, contact Chemical Compliance at 1-580-251-4335.
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy
or completeness. The information is obtained from various sources including the
manufacturer and other third party sources. The information may not be valid under
all conditions nor if this material is used in combination with other materials or in any
process. Final determination of suitability of any material is the sole responsibility of
the user.
***END OF MSDS***
FE-2
Page 6 of 6
MATERIAL SAFETY DATA SHEET
Product Trade Name:
FR-50D
Revision Date: 05-Nov-2013

None Allocated
Halliburton Australia Pty. Ltd.
15 Marriott Road
Jandakot
WA 6164
Australia
ACN Number: 009 000 775
Telephone Number: 61 (08) 9455 8300
Fax Number: 61 (08) 9455 5300
Product Emergency Telephone
Australia: 08-64244950
Papua New Guinea: 05 1 281 575 5000
NewZealand: 06-7559274
Fire, Police & Ambulance - Emergency Telephone
Australia: 000
Papua New Guinea: 000
New Zealand: 111
Statement of Hazardous Nature
Application: Friction Reducer
Synonyms: None
Non-Hazardous according to the criteria of NOHSC, Non-Dangerous Goods
according to the criteria of ADG.
Prepared By Chemical Compliance
Telephone: 1-580-251-4335
e-mail: fdunexchem@halliburton.com
Chemical Family: Salt Polymer Blend
2. COMPOSITION/INFORMATION ON INGREDIENTS
UN Number: None
Identification of Substances or Preparation
Substances CAS Number PERCENT (w/w) Australia NOHSCNew Zealand
WES
ACGIH TLV-TWA
Dangerous Goods Class: None
Salt Proprietary 60 - 100% Not applicable Not applicable Not applicable
Non-Hazardous Substance to Total of 100%
Subsidiary Risk: None
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Manufacturer/Supplier
Hazchem Code:
FR-50D
None Allocated
Product Trade Name:
Page 1 of 6
FR-50D
Poisons Schedule:
3. HAZARDS IDENTIFICATION
Hazard Overview May cause eye, skin, and respiratory irritation.
Risk Phrases None
HSNO Classification 6.1E Acutely Toxic Substances
6.4A Irritating to the eye
4. FIRST AID MEASURES
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory
irritation develops or if breathing becomes difficult.
Skin Wash with soap and water. Get medical attention if irritation persists.
Eyes Immediately flush eyes with large amounts of water for at least 15 minutes. Get
immediate medical attention.
Ingestion Under normal conditions, first aid procedures are not required.
Notes to Physician Not Applicable
5. FIRE FIGHTING MEASURES
Suitable Extinguishing Media
All standard fire fighting media
Extinguishing media which must not be used for safety reasons
None known.
Special Exposure Hazards Organic dust in the presence of an ignition source can be explosive in high
concentrations. Good housekeeping practices are required to minimize this
potential.
Special Protective Equipment
for Fire-Fighters
Not applicable.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautionary
Measures
Use appropriate protective equipment. Avoid creating and breathing dust.
Environmental Precautionary
Measures
Prevent from entering sewers, waterways, or low areas.
Procedure for Cleaning /
Absorption
Scoop up and remove.
7. HANDLING AND STORAGE
Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust. Ground
and bond containers when transferring from one container to another. Slippery
when wet.
FR-50D
Page 2 of 6
Storage Information Store in a cool, dry location. Use good housekeeping in storage and work areas to
prevent accumulation of dust. Close container when not in use. Keep from heat,
sparks, and open flames. Product has a shelf life of 24 months.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls Use in a well ventilated area.
Respiratory Protection If engineering controls and work practices cannot keep exposure below
occupational exposure limits or if exposure is unknown, wear a NIOSH certified,
European Standard EN 149, or equivalent respirator when using this product.
Selection of and instruction on using all personal protective equipment, including
respirators, should be performed by an Industrial Hygienist or other qualified
professional.
HEPA Respirator.
Hand Protection Normal work gloves.
Skin Protection Normal work coveralls.
Eye Protection Wear safety glasses or goggles to protect against exposure.
Other Precautions None known.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Powder
Color: White
Odor: Slight
pH: 9 (.5%)
Specific Gravity @ 20 C (Water=1): 2.0
Density @ 20 C (kg/l): Not Determined
Bulk Density @ 20 C (kg/M3): Not Determined
Boiling Point/Range (C): Not Determined
Freezing Point/Range (C): Not Determined
Pour Point/Range (C): Not Determined
Flash Point/Range (C): Not Determined
Flash Point Method: Not Determined
Autoignition Temperature (C): Not Determined
Flammability Limits in Air - Lower (g/m
3
): Not Determined
Flammability Limits in Air - Lower (%): Not Determined
Flammability Limits in Air - Upper (g/m
3
): Not Determined
Flammability Limits in Air - Upper (%): Not Determined
Vapor Pressure @ 20 C (mmHg): Not Determined
Vapor Density (Air=1): Not Determined
Percent Volatiles: Not Determined
Evaporation Rate (Butyl Acetate=1): Not Determined
Solubility in Water (g/100ml): Soluble
Solubility in Solvents (g/100ml): Not Determined
VOCs (g/l): Not Determined
Viscosity, Dynamic @ 20 C (centipoise): Not Determined
Viscosity, Kinematic @ 20 C (centistokes): Not Determined
Partition Coefficient/n-Octanol/Water: Not Determined
Molecular Weight (g/mole): Not Determined
Decomposition Temperature (C): Not Determined
FR-50D
Page 3 of 6
10. STABILITY AND REACTIVITY
Stability Data: Stable
Hazardous Polymerization: Will Not Occur
Conditions to Avoid None anticipated
Incompatibility (Materials to
Avoid)
Strong oxidizers.
Hazardous Decomposition
Products
Carbon monoxide and carbon dioxide. Ammonia.
Additional Guidelines Not Applicable
11. TOXICOLOGICAL INFORMATION
Principle Route of Exposure Eye or skin contact, inhalation.
Sympotoms related to exposure
Acute Toxicity
Inhalation May cause respiratory irritation.
Eye Contact Causes eye irritation.
Skin Contact May cause skin irritation.
Ingestion Large doses may cause nausea, vomiting and diarrhea.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are chronic
health hazards.
Toxicology data for the components
Substances
CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Salt Proprietary 3 g/kg ( Rat ) 10 g/kg ( Rabbit ) 42 g/m
3
( Rat ) 1 h
12. ECOLOGICAL INFORMATION
Ecotoxicological Information
Ecotoxicity Product
Acute Fish Toxicity: LC50 (96): > 100 mg/l
Acute Crustaceans Toxicity: Not determined
Acute Algae Toxicity: Not determined
Ecotoxicity Substance
Substances
CAS Number Toxicity to Algae Toxicity to Fish Toxicity to
Microorganisms
Daphnia Magna (Water
Flea)
Salt Proprietary No information available TLM96: > 1000 mg/l
(Oncorhynchus mykiss)
No information available TLM96: > 1,000,000 ppm
(Mysidopsis bahia)
12.2 Persistence and degradability
No information available
12.3 Bioaccumulative potential
No information available
12.4 Mobility in soil
No information available
FR-50D
Page 4 of 6
12.5 Results of PBT and vPvB assessment
No information available.
12.6 Other adverse effects
13. DISPOSAL CONSIDERATIONS
Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.
Contaminated Packaging Follow all applicable national or local regulations.
14. TRANSPORT INFORMATION
Land Transportation
ADR
Not restricted
Air Transportation
ICAO/IATA
Not restricted
Sea Transportation
IMDG
Not restricted
Other Transportation Information
Labels: None
15. REGULATORY INFORMATION
Chemical Inventories
Australian AICS Inventory All components listed on inventory or are exempt.
New Zealand Inventory of
Chemicals
This product does not comply with NZIOC
US TSCA Inventory All components listed on inventory or are exempt.
EINECS Inventory This product, and all its components, complies with EINECS
Classification Not Classified
Risk Phrases None
Safety Phrases None
16. OTHER INFORMATION
The following sections have been revised since the last issue of this SDS
Not applicable
FR-50D
Page 5 of 6
Contact
Australian Poisons Information Centre
24 Hour Service: - 13 11 26
Police or Fire Brigade: - 000 (exchange): - 1100
New Zealand National Poisons Centre
0800 764 766
Additional Information For additional information on the use of this product, contact your local Halliburton
representative.
For questions about the Safety Data Sheet for this or other Halliburton products,
contact Chemical Compliance at 1-580-251-4335.
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to
accuracy or completeness. The information is obtained from various sources
including the manufacturer and other third party sources. The information may not
be valid under all conditions nor if this material is used in combination with other
materials or in any process. Final determination of suitability of any material is the
sole responsibility of the user.
***END OF MSDS***
FR-50D
Page 6 of 6
MATERIAL SAFETY DATA SHEET
Product Trade Name:
HAI-150E
Revision Date: 27-Aug-2013
None Allocated
Product Trade Name: HAI-150E
Poisons Schedule: None Allocated
Halliburton Australia Pty. Ltd.
15 Marriott Road
Jandakot
WA 6164
Australia
ACN Number: 009 000 775
Telephone Number: 61 (08) 9455 8300
Fax Number: 61 (08) 9455 5300
Product Emergency Telephone
Australia: 08-64244950
Papua New Guinea: 05 1 281 575 5000
NewZealand: 06-7559274
Fire, Police & Ambulance - Emergency Telephone
Australia: 000
Papua New Guinea: 000
New Zealand: 111
Statement of Hazardous Nature
Application: Corrosion Inhibitor
Synonyms: None
Non-Hazardous according to the criteria of NOHSC, Non-Dangerous Goods
according to the criteria of ADG.
Prepared By Chemical Compliance
Telephone: 1-580-251-4335
e-mail: fdunexchem@halliburton.com
Chemical Family: Blend
2. COMPOSITION/INFORMATION ON INGREDIENTS
UN Number: None
Identification of Substances or Preparation
Substances CAS Number PERCENT (w/w) Australia NOHSCNew Zealand
WES
ACGIH TLV-TWA
Dangerous Goods Class: None
Contains no hazardous
substances
Mixture 60 - 100% Not applicable Not applicable Not applicable
Subsidiary Risk:
HAI-150E
None
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Page 1 of 6
Manufacturer/Supplier
Hazchem Code:
Non-Hazardous Substance to Total of 100%
3. HAZARDS IDENTIFICATION
Hazard Overview May cause eye, skin, and respiratory irritation.
Risk Phrases None
HSNO Classification Non-hazardous
4. FIRST AID MEASURES
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory
irritation develops or if breathing becomes difficult.
Skin Get medical attention if irritation persists. Wash with soap and water.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 15
minutes and get medical attention if irritation persists.
Ingestion Under normal conditions, first aid procedures are not required.
Notes to Physician Not Applicable
5. FIRE FIGHTING MEASURES
Suitable Extinguishing Media
All standard fire fighting media
Extinguishing media which must not be used for safety reasons
None known.
Special Exposure Hazards Organic dust in the presence of an ignition source can be explosive in high
concentrations. Good housekeeping practices are required to minimize this
potential.
Special Protective Equipment
for Fire-Fighters
Full protective clothing and approved self-contained breathing apparatus required
for fire fighting personnel.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautionary
Measures
Use appropriate protective equipment.
Environmental Precautionary
Measures
None known.
Procedure for Cleaning /
Absorption
Scoop up and remove.
7. HANDLING AND STORAGE
Handling Precautions Avoid creating or inhaling dust.
Storage Information Store away from oxidizers. Store in a dry location.
HAI-150E
Page 2 of 6
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls A well ventilated area to control dust levels.
Respiratory Protection Not normally needed. But if significant exposures are possible then the following
respirator is recommended:
Dust/mist respirator. (N95, P2/P3)
Hand Protection Normal work gloves.
Skin Protection Normal work coveralls.
Eye Protection Wear safety glasses or goggles to protect against exposure.
Other Precautions None known.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Solid
Color: Brown
Odor: Coffee bean
pH: Not Determined
Specific Gravity @ 20 C (Water=1): Not Determined
Density @ 20 C (kg/l): Not Determined
Bulk Density @ 20 C (kg/M3): Not Determined
Boiling Point/Range (C): Not Determined
Freezing Point/Range (C): Not Determined
Pour Point/Range (C): Not Determined
Flash Point/Range (C): Not Determined
Flash Point Method: Not Determined
Autoignition Temperature (C): Not Determined
Flammability Limits in Air - Lower (g/m
3
): Not Determined
Flammability Limits in Air - Lower (%): Not Determined
Flammability Limits in Air - Upper (g/m
3
): Not Determined
Flammability Limits in Air - Upper (%): Not Determined
Vapor Pressure @ 20 C (mmHg): Not Determined
Vapor Density (Air=1): Not Determined
Percent Volatiles: Not Determined
Evaporation Rate (Butyl Acetate=1): Not Determined
Solubility in Water (g/100ml): Soluble
Solubility in Solvents (g/100ml): Not Determined
VOCs (g/l): Not Determined
Viscosity, Dynamic @ 20 C (centipoise): Not Determined
Viscosity, Kinematic @ 20 C (centistokes): Not Determined
Partition Coefficient/n-Octanol/Water: Not Determined
Molecular Weight (g/mole): Not Determined
Decomposition Temperature (C): Not Determined
10. STABILITY AND REACTIVITY
Stability Data: Stable
Hazardous Polymerization: Will Not Occur
Conditions to Avoid None known.
Incompatibility (Materials to
Avoid)
Strong oxidizers.
HAI-150E
Page 3 of 6
Hazardous Decomposition
Products
Carbon monoxide and carbon dioxide.
Additional Guidelines Not Applicable
11. TOXICOLOGICAL INFORMATION
Principle Route of Exposure Eye or skin contact, inhalation.
Sympotoms related to exposure
Acute Toxicity
Inhalation May cause mild respiratory irritation.
Eye Contact May cause mild eye irritation.
Skin Contact May cause mild skin irritation.
Ingestion None known
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are chronic
health hazards. Generally Recognized As Safe (GRAS)
Toxicology data for the components
Substances
CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Contains no hazardous
substances
Mixture No data available No data available No data available
12. ECOLOGICAL INFORMATION
Ecotoxicological Information
Ecotoxicity Product
Acute Fish Toxicity: Not determined
Acute Crustaceans Toxicity: Not determined
Acute Algae Toxicity: Not determined
Ecotoxicity Substance
Substances
CAS Number Toxicity to Algae Toxicity to Fish Toxicity to
Microorganisms
Daphnia Magna (Water
Flea)
Contains no
hazardous substances
Mixture No information available No information available No information available No information available
Persistence and degradability
Product is biodegradable
Bioaccumulative potential
Does not bioaccumulate
Mobility in soil
No information available
Results of PBT and vPvB assessment
No information available.
Other adverse effects
13. DISPOSAL CONSIDERATIONS
Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.
HAI-150E
Page 4 of 6
Contaminated Packaging Follow all applicable national or local regulations.
14. TRANSPORT INFORMATION
Land Transportation
ADR
Not restricted
Air Transportation
ICAO/IATA
Not restricted
Sea Transportation
IMDG
Not restricted
Other Transportation Information
Labels: None
15. REGULATORY INFORMATION
Chemical Inventories
Australian AICS Inventory All components listed on inventory or are exempt.
New Zealand Inventory of
Chemicals
All components listed on inventory or are exempt.
US TSCA Inventory All components listed on inventory or are exempt.
EINECS Inventory This product, and all its components, complies with EINECS
Classification Not Classified
Risk Phrases None
Safety Phrases None
16. OTHER INFORMATION
The following sections have been revised since the last issue of this SDS
Not applicable
Contact
Australian Poisons Information Centre
24 Hour Service: - 13 11 26
Police or Fire Brigade: - 000 (exchange): - 1100
New Zealand National Poisons Centre
0800 764 766
HAI-150E
Page 5 of 6
Additional Information For additional information on the use of this product, contact your local Halliburton
representative.
For questions about the Safety Data Sheet for this or other Halliburton products,
contact Chemical Compliance at 1-580-251-4335.
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to
accuracy or completeness. The information is obtained from various sources
including the manufacturer and other third party sources. The information may not
be valid under all conditions nor if this material is used in combination with other
materials or in any process. Final determination of suitability of any material is the
sole responsibility of the user.
***END OF MSDS***
HAI-150E
Page 6 of 6

MATERIAL SAFETY DATA SHEET
Product Trade Name:
HYDROCHLORIC ACID
Revision Date: 04-Jan-2010
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Statement of Hazardous Nature Hazardous according to the criteria of NOHSC, Dangerous Goods according to the
criteria of ADG.
Manufacturer/Supplier Halliburton Australia Pty. Ltd.
53-55 Bannister Road
Canning Vale
WA 6155
Australia
ACN Number: 009 000 775
Telephone Number: 61 (08) 9455 8300
Fax Number: 61 (08) 9455 5300
Product Emergency Telephone
Australia: 08-64244950
Papua New Guinea: 05 1 281 575 5000
NewZealand: 06-7559274
Fire, Police & Ambulance - Emergency Telephone
Australia: 000
Papua New Guinea: 000
New Zealand: 111
Identification of Substances or Preparation
Product Trade Name: HYDROCHLORIC ACID
Synonyms: None
Chemical Family: Inorganic acid
UN Number: , UN1789
Dangerous Goods Class: 8
Subsidiary Risk: None
Hazchem Code: 2R
Poisons Schedule: S6
Application: Solvent
Prepared By Chemical Compliance
Telephone: 1-580-251-4335
e-mail: fdunexchem@halliburton.com
2. COMPOSITION/INFORMATION ON INGREDIENTS
Substances CAS Number PERCENT Australia NOHSC ACGIH TLV-TWA
Hydrochloric acid 7647-01-0 30 - 60% 5 ppm 2 ppm
Total to 100%
HYDROCHLORIC ACID
Page 1 of 6
3. HAZARDS IDENTIFICATION
Hazard Overview May cause eye, skin, and respiratory burns. May be harmful if swallowed.
Hazard Ratings
Flammability: 0
Toxicty: 2
Body Contact: 3
Reactivity: 0
Chronic: 0
Scale: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4
4. FIRST AID MEASURES
Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably
mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.
Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15
minutes. Get medical attention. Remove contaminated clothing and launder before
reuse.
Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water
for at least 15 minutes and get medical attention immediately after flushing.
Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek
medical attention. Never give anything by mouth to an unconscious person.
Notes to Physician Not Applicable
5. FIRE FIGHTING MEASURES
Suitable Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.
Extinguishing media which must
not be used for safety reasons
None known.
Special Exposure Hazards May form explosive mixtures with strong alkalis. Decomposition in fire may produce
toxic gases. Reaction with steel and certain other metals generates flammable
hydrogen gas. Do not allow runoff to enter waterways.
Special Protective Equipment for
Fire-Fighters
Full protective clothing and approved self-contained breathing apparatus required for
fire fighting personnel.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautionary MeasuresUse appropriate protective equipment.
Environmental Precautionary
Measures
Prevent from entering sewers, waterways, or low areas.
Procedure for Cleaning /
Absorption
Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.
Neutralize to pH of 6-8. Scoop up and remove.
7. HANDLING AND STORAGE
Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after
use. Launder contaminated clothing before reuse.
HYDROCHLORIC ACID
Page 2 of 6
Storage Information Store away from alkalis. Store in a cool well ventilated area. Keep container closed
when not in use. Product has a shelf life of 24 months.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas
without good cross ventilation.
Respiratory Protection Acid gas respirator.
Hand Protection Impervious rubber gloves.
Skin Protection Full protective chemical resistant clothing. Rubber boots.
Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.
Other Precautions Eyewash fountains and safety showers must be easily accessible.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Color: Clear colorless
Odor: Pungent acrid
pH: 0.8
Specific Gravity @ 20 C (Water=1): 1.18
Density @ 20 C (kg/l): 1.16
Bulk Density @ 20 C (kg/m
3
): Not Determined
Boiling Point/Range (C): 110
Freezing Point/Range (C): -46
Pour Point/Range (C): Not Determined
Flash Point/Range (C): Not Determined
Flash Point Method: Not Determined
Autoignition Temperature (C): Not Determined
Flammability Limits in Air - Lower (g/m
3
): Not Determined
Flammability Limits in Air - Lower (%): Not Determined
Flammability Limits in Air - Upper (g/m
3
): Not Determined
Flammability Limits in Air - Upper (%): Not Determined
Vapor Pressure @ 20 C (mmHg): 26
Vapor Density (Air=1): Not Determined
Percent Volatiles: 35
Evaporation Rate (Butyl Acetate=1): Not Determined
Solubility in Water (g/100ml): Soluble
Solubility in Solvents (g/100ml): Not Determined
VOCs (g/l): Not Determined
Viscosity, Dynamic @ 20 C (centipoise): Not Determined
Viscosity, Kinematic @ 20 C (centistrokes): Not Determined
Partition Coefficient/n-Octanol/Water: Not Determined
Molecular Weight (g/mole): 36.5
Decomposition Temperature (C): Not Determined
10. STABILITY AND REACTIVITY
Stability Data: Stable
Hazardous Polymerization: Will Not Occur
Conditions to Avoid None anticipated
HYDROCHLORIC ACID
Page 3 of 6
Incompatibility (Materials to
Avoid)
Strong alkalis.
Hazardous Decomposition
Products
Flammable hydrogen gas. Chlorine. Hydrogen sulfide.
Additional Guidelines Not Applicable
11. TOXICOLOGICAL INFORMATION
Principle Route of Exposure Eye or skin contact, inhalation.
Inhalation Causes severe respiratory irritation.
Skin Contact May cause skin burns.
Eye Contact May cause eye burns.
Ingestion Causes burns of the mouth, throat and stomach.
Aggravated Medical Conditions Skin disorders.
Chronic Effects/Carcinogenicity Prolonged, excessive exposure may cause erosion of the teeth.
Other Information None known.
Toxicity Tests
Oral Toxicity: Not determined
Dermal Toxicity: Not determined
Inhalation Toxicity: LC50: 3124 ppm/1 hr. (Rat)
Primary Irritation Effect: Not determined
Carcinogenicity Not determined
Genotoxicity: Not determined
Reproductive /
Developmental Toxicity:
Not determined
12. ECOLOGICAL INFORMATION
Mobility (Water/Soil/Air) Not determined
Persistence/Degradability Not determined
Bio-accumulation Not determined
Ecotoxicological Information
Acute Fish Toxicity: Not determined
Acute Crustaceans Toxicity:Not determined
Acute Algae Toxicity: Not determined
Chemical Fate Information Not determined
Other Information Not applicable
HYDROCHLORIC ACID
Page 4 of 6
13. DISPOSAL CONSIDERATIONS
Disposal Method Disposal should be made in accordance with federal, state, and local regulations.
Contaminated Packaging Follow all applicable national or local regulations.
14. TRANSPORT INFORMATION
Land Transportation
ADR
UN1789,Hydrochloric Acid Solution, 8, II
Air Transportation
ICAO/IATA
UN1789,Hydrochloric Acid Solution, 8, IIRQ (Hydrochloric Acid - 2273 kg.)
Sea Transportation
IMDG
UN1789,Hydrochloric Acid Solution, 8, IIRQ (Hydrochloric Acid - 2273 kg.)
EmS F-A, S-B
Other Shipping Information
Labels: Corrosive
15. REGULATORY INFORMATION
Chemical Inventories
Australian AICS Inventory All components listed.
US TSCA Inventory All components listed on inventory or are exempt.
EINECS Inventory This product, and all its components, complies with EINECS
Classification C - Corrosive.
Risk Phrases R34 Causes burns.
R37 Irritating to respiratory system.
Safety Phrases S9 Keep container in a well ventilated place.
S26 In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.
S45 In case of accident or if you feel unwell, seek medical advice immediately.
S1/2 Keep locked up and out of reach of children.
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
HYDROCHLORIC ACID
Page 5 of 6
16. OTHER INFORMATION
The following sections have been revised since the last issue of this MSDS
Not applicable
Contact
Australian Poisons Information Centre
24 Hour Service: - 13 11 26
Police or Fire Brigade: - 000 (exchange): - 1100
New Zealand National Poisons Centre
0800 764 766
Additional Information For additional information on the use of this product, contact your local Halliburton
representative.
For questions about the Material Safety Data Sheet for this or other Halliburton
products, contact Chemical Compliance at 1-580-251-4335.
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy
or completeness. The information is obtained from various sources including the
manufacturer and other third party sources. The information may not be valid under
all conditions nor if this material is used in combination with other materials or in any
process. Final determination of suitability of any material is the sole responsibility of
the user.
***END OF MSDS***
HYDROCHLORIC ACID
Page 6 of 6

MATERIAL SAFETY DATA SHEET
Product Trade Name:
TLC-W3 - ROCK SALT
Revision Date: 04-Jan-2011
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Statement of Hazardous Nature Non-Hazardous according to the criteria of NOHSC, Non-Dangerous Goods
according to the criteria of ADG.
Manufacturer/Supplier Halliburton Australia Pty. Ltd.
53-55 Bannister Road
Canning Vale
WA 6155
Australia
ACN Number: 009 000 775
Telephone Number: 61 (08) 9455 8300
Fax Number: 61 (08) 9455 5300
Product Emergency Telephone
Australia: 08-64244950
Papua New Guinea: 05 1 281 575 5000
NewZealand: 06-7559274
Fire, Police & Ambulance - Emergency Telephone
Australia: 000
Papua New Guinea: 000
New Zealand: 111
Identification of Substances or Preparation
Product Trade Name: TLC-W3 - ROCK SALT
Synonyms: None
Chemical Family: Inorganic Salt
UN Number: None
Dangerous Goods Class: None
Subsidiary Risk: None
Hazchem Code: None
Poisons Schedule: None
Application: Additive
Prepared By Chemical Compliance
Telephone: 1-580-251-4335
e-mail: fdunexchem@halliburton.com
2. COMPOSITION/INFORMATION ON INGREDIENTS
Substances CAS Number PERCENT Australia NOHSC ACGIH TLV-TWA
Sodium chloride 7647-14-5 60 - 100% Not applicable Not applicable
Total to 100%
TLC-W3 - ROCK SALT
Page 1 of 6
3. HAZARDS IDENTIFICATION
Hazard Overview May cause eye, skin, and respiratory irritation.
Hazard Ratings
Flammability: 0
Toxicty: 0
Body Contact: 0
Reactivity: 0
Chronic: 0
Scale: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4
4. FIRST AID MEASURES
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation
develops or if breathing becomes difficult.
Skin Wash with soap and water. Get medical attention if irritation persists.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes
and get medical attention if irritation persists.
Ingestion Under normal conditions, first aid procedures are not required.
Notes to Physician Not Applicable
5. FIRE FIGHTING MEASURES
Suitable Extinguishing Media All standard fire fighting media
Extinguishing media which must
not be used for safety reasons
None known.
Special Exposure Hazards Not applicable.
Special Protective Equipment for
Fire-Fighters
Not applicable.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.
Environmental Precautionary
Measures
Prevent from entering sewers, waterways, or low areas.
Procedure for Cleaning /
Absorption
Scoop up and remove.
7. HANDLING AND STORAGE
Handling Precautions Avoid creating or inhaling dust.
Storage Information Store in a cool, dry location. Product has a shelf life of 24 months.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls Use in a well ventilated area.
TLC-W3 - ROCK SALT
Page 2 of 6
Respiratory Protection Not normally needed. But if significant exposures are possible then the following
respirator is recommended:
Dust/mist respirator. (95%)
Hand Protection Normal work gloves.
Skin Protection Normal work coveralls.
Eye Protection Wear safety glasses or goggles to protect against exposure.
Other Precautions None known.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Solid
Color: White
Odor: Odorless
pH: Not Determined
Specific Gravity @ 20 C (Water=1): 2.16
Density @ 20 C (kg/l): Not Determined
Bulk Density @ 20 C (kg/m
3
): Not Determined
Boiling Point/Range (C): Not Determined
Freezing Point/Range (C): Not Determined
Pour Point/Range (C): Not Determined
Flash Point/Range (C): Not Determined
Flash Point Method: Not Determined
Autoignition Temperature (C): Not Determined
Flammability Limits in Air - Lower (g/m
3
): Not Determined
Flammability Limits in Air - Lower (%): Not Determined
Flammability Limits in Air - Upper (g/m
3
): Not Determined
Flammability Limits in Air - Upper (%): Not Determined
Vapor Pressure @ 20 C (mmHg): Not Determined
Vapor Density (Air=1): Not Determined
Percent Volatiles: Not Determined
Evaporation Rate (Butyl Acetate=1): Not Determined
Solubility in Water (g/100ml): Soluble
Solubility in Solvents (g/100ml): Not Determined
VOCs (g/l): Not Determined
Viscosity, Dynamic @ 20 C (centipoise): Not Determined
Viscosity, Kinematic @ 20 C (centistrokes): Not Determined
Partition Coefficient/n-Octanol/Water: Not Determined
Molecular Weight (g/mole): 58.44
Decomposition Temperature (C): Not Determined
10. STABILITY AND REACTIVITY
Stability Data: Stable
Hazardous Polymerization: Will Not Occur
Conditions to Avoid None anticipated
Incompatibility (Materials to
Avoid)
None known.
Hazardous Decomposition
Products
None known.
Additional Guidelines Not Applicable
TLC-W3 - ROCK SALT
Page 3 of 6
11. TOXICOLOGICAL INFORMATION
Principle Route of Exposure Eye or skin contact, inhalation.
Inhalation May cause respiratory irritation.
Skin Contact Prolonged or repeated contact may cause skin irritation.
Eye Contact May cause eye irritation.
Ingestion None known
Aggravated Medical Conditions None known.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are
chronic health hazards.
Other Information None known.
Toxicity Tests
Oral Toxicity: LD50: 3000 mg/kg (Rat)
Dermal Toxicity: Not determined
Inhalation Toxicity: Not determined
Primary Irritation Effect: Not determined
Carcinogenicity Not determined
Genotoxicity: Not determined
Reproductive /
Developmental Toxicity:
Not determined
12. ECOLOGICAL INFORMATION
Mobility (Water/Soil/Air) Not determined
Persistence/Degradability Not applicable
Bio-accumulation Not determined
Ecotoxicological Information
Acute Fish Toxicity: Not determined
Acute Crustaceans Toxicity:Not determined
Acute Algae Toxicity: Not determined
Chemical Fate Information Not determined
Other Information Not applicable
13. DISPOSAL CONSIDERATIONS
Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.
Contaminated Packaging Follow all applicable national or local regulations.
TLC-W3 - ROCK SALT
Page 4 of 6
14. TRANSPORT INFORMATION
Land Transportation
ADR
Not restricted
Air Transportation
ICAO/IATA
Not restricted
Sea Transportation
IMDG
Not restricted
Other Shipping Information
Labels: None
15. REGULATORY INFORMATION
Chemical Inventories
Australian AICS Inventory All components listed.
US TSCA Inventory All components listed on inventory or are exempt.
EINECS Inventory This product, and all its components, complies with EINECS
Classification Not Classified
Risk Phrases None
Safety Phrases None
16. OTHER INFORMATION
The following sections have been revised since the last issue of this MSDS
Not applicable
Contact
Australian Poisons Information Centre
24 Hour Service: - 13 11 26
Police or Fire Brigade: - 000 (exchange): - 1100
New Zealand National Poisons Centre
0800 764 766
Additional Information For additional information on the use of this product, contact your local Halliburton
representative.
For questions about the Material Safety Data Sheet for this or other Halliburton
products, contact Chemical Compliance at 1-580-251-4335.
TLC-W3 - ROCK SALT
Page 5 of 6
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy
or completeness. The information is obtained from various sources including the
manufacturer and other third party sources. The information may not be valid under
all conditions nor if this material is used in combination with other materials or in any
process. Final determination of suitability of any material is the sole responsibility of
the user.
***END OF MSDS***
TLC-W3 - ROCK SALT
Page 6 of 6

MATERIAL SAFETY DATA SHEET
Product Trade Name:
CLWGAU421
Revision Date: 05-Sep-2012
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Statement of Hazardous Nature Non-Hazardous according to the criteria of NOHSC, Non-Dangerous Goods
according to the criteria of ADG.
Manufacturer/Supplier Halliburton/Baroid Australia Pty. Ltd.
53-55 Bannister Road
Canning Vale
WA 6155
Australia
ACN Number: 009 000 775
Telephone Number: 61 (08) 9455 8300
Fax Number: 61 (08) 9455 5300
Product Emergency Telephone
Australia: 08-64244950
Papua New Guinea: 05 1 281 575 5000
New Zealand: 06-7559274
Fire, Police & Ambulance - Emergency Telephone
Australia: 000
Papua New Guinea: 000
New Zealand: 111
Identification of Substances or Preparation
Product Trade Name: CLWGAU421
Synonyms: None
Chemical Family: Carbohydrate
UN Number: None
Dangerous Goods Class: None
Subsidiary Risk: None
Hazchem Code: None
Poisons Schedule: None
Application: Gelling Agent
Prepared By Chemical Compliance
Telephone: 1-580-251-4335
e-mail: fdunexchem@halliburton.com
2. COMPOSITION/INFORMATION ON INGREDIENTS
Substances CAS Number PERCENT Australia
NOHSC
New Zealand
OEL
ACGIH TLV-TWA
Polysaccharide 60 - 100% Not applicable Not applicable Not applicable
CLWGAU421
Page 1 of 6
Non-Hazardous Substance to Total of 100%
3. HAZARDS IDENTIFICATION
Hazard Overview May cause eye, skin, and respiratory irritation. Airborne dust may be explosive.
Risk Phrases None
HSNO Classification 9.1C Substances that are harmful in the aquatic environment.
4. FIRST AID MEASURES
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation
develops or if breathing becomes difficult.
Skin Wash with soap and water. Get medical attention if irritation persists.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes
and get medical attention if irritation persists.
Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medical
attention.
Notes to Physician Not Applicable
5. FIRE FIGHTING MEASURES
Suitable Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.
Extinguishing media which must
not be used for safety reasons
None known.
Special Exposure Hazards Organic dust in the presence of an ignition source can be explosive in high
concentrations. Good housekeeping practices are required to minimize this
potential.
Special Protective Equipment for
Fire-Fighters
Full protective clothing and approved self-contained breathing apparatus required for
fire fighting personnel.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautionary MeasuresAvoid creating and breathing dust. Slippery when wet.
Environmental Precautionary
Measures
None known.
Procedure for Cleaning /
Absorption
Scoop up and remove.
7. HANDLING AND STORAGE
Handling Precautions Wash hands after use. Launder contaminated clothing before reuse. Avoid contact
with eyes, skin, or clothing. Avoid creating or inhaling dust. Avoid dust
accumulations. Slippery when wet. Ground and bond containers when transferring
from one container to another.
CLWGAU421
Page 2 of 6
Storage Information Store in a well ventilated area. Store away from oxidizers. Keep container closed
when not in use. Store in a cool, dry location. Keep from heat, sparks, and open
flames. Product has a shelf life of 24 months.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls A well ventilated area to control dust levels. Local exhaust ventilation should be used
in areas without good cross ventilation.
Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational
exposure limits or if exposure is unknown, wear a NIOSH certified, European
Standard EN 149, or equivalent respirator when using this product. Selection of and
instruction on using all personal protective equipment, including respirators, should
be performed by an Industrial Hygienist or other qualified professional.
Not normally needed. But if significant exposures are possible then the following
respirator is recommended:
Dust/mist respirator. (95%)
Hand Protection Normal work gloves.
Skin Protection Normal work coveralls.
Eye Protection Wear safety glasses or goggles to protect against exposure.
Other Precautions Eyewash fountains and safety showers must be easily accessible.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Powder
Color: White to off white
Odor: Odorless
pH: 6.5-8 (1%)
Specific Gravity @ 20 C (Water=1): 1.6
Density @ 20 C (kg/l): Not Determined
Bulk Density @ 20 C (kg/m
3
): 750
Boiling Point/Range (C): Not Determined
Freezing Point/Range (C): Not Determined
Pour Point/Range (C): Not Determined
Flash Point/Range (C): Not Determined
Flash Point Method: Not Determined
Autoignition Temperature (C): > 370
Flammability Limits in Air - Lower (g/m
3
): Not Determined
Flammability Limits in Air - Lower (%): Not Determined
Flammability Limits in Air - Upper (g/m
3
): Not Determined
Flammability Limits in Air - Upper (%): Not Determined
Vapor Pressure @ 20 C (mmHg): Not Determined
Vapor Density (Air=1): Not Determined
Percent Volatiles: Not Determined
Evaporation Rate (Butyl Acetate=1): Not Determined
Solubility in Water (g/100ml): Forms gel
Solubility in Solvents (g/100ml): Not Determined
VOCs (g/l): Not Determined
Viscosity, Dynamic @ 20 C (centipoise): Not Determined
Viscosity, Kinematic @ 20 C (centistokes): Not Determined
Partition Coefficient/n-Octanol/Water: Not Determined
Molecular Weight (g/mole): Not Determined
Decomposition Temperature (C): Not Determined
CLWGAU421
Page 3 of 6
10. STABILITY AND REACTIVITY
Stability Data: Stable
Hazardous Polymerization: Will Not Occur
Conditions to Avoid None known.
Incompatibility (Materials to
Avoid)
Strong oxidizers.
Hazardous Decomposition
Products
Carbon monoxide and carbon dioxide.
Additional Guidelines Not Applicable
11. TOXICOLOGICAL INFORMATION
Principle Route of Exposure Eye or skin contact, inhalation.
Inhalation May cause mild respiratory irritation. In high air concentrations: May impede
respiration.
Skin Contact May cause an allergic skin reaction. Prolonged or repeated contact may cause skin
irritation.
Eye Contact May cause mild eye irritation.
Ingestion May cause allergic reaction.
Aggravated Medical Conditions None known.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are
chronic health hazards.
Other Information None known.
Toxicity Tests
Oral Toxicity: Not determined
Dermal Toxicity: Not determined
Inhalation Toxicity: Not determined
Primary Irritation Effect: Not determined
Carcinogenicity Not determined
Genotoxicity: Not determined
Reproductive /
Developmental Toxicity:
Not determined
12. ECOLOGICAL INFORMATION
Mobility (Water/Soil/Air) Not determined
Persistence/Degradability Readily biodegradable
Bio-accumulation Not determined
CLWGAU421
Page 4 of 6
Ecotoxicological Information
Acute Fish Toxicity: Not determined
Acute Crustaceans Toxicity:Not determined
Acute Algae Toxicity: Not determined
Chemical Fate Information Not determined
Other Information Not applicable
13. DISPOSAL CONSIDERATIONS
Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.
Contaminated Packaging Follow all applicable national or local regulations.
14. TRANSPORT INFORMATION
Land Transportation
ADR
Not restricted
Air Transportation
ICAO/IATA
Not restricted
Sea Transportation
IMDG
Not restricted
Other Transportation Information
Labels: None
15. REGULATORY INFORMATION
Chemical Inventories
Australian AICS Inventory All components listed on inventory or are exempt.
New Zealand Inventory of
Chemicals
All components listed on inventory or are exempt.
US TSCA Inventory All components listed on inventory or are exempt.
EINECS Inventory This product, and all its components, complies with EINECS
Classification Not Classified
Risk Phrases None
Safety Phrases None
16. OTHER INFORMATION
The following sections have been revised since the last issue of this MSDS
Not applicable
CLWGAU421
Page 5 of 6
Contact
Australian Poisons Information Centre
24 Hour Service: - 13 11 26
Police or Fire Brigade: - 000 (exchange): - 1100
New Zealand National Poisons Centre
0800 764 766
Additional Information For additional information on the use of this product, contact your local Halliburton
representative.
For questions about the Material Safety Data Sheet for this or other Halliburton
products, contact Chemical Compliance at 1-580-251-4335.
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy
or completeness. The information is obtained from various sources including the
manufacturer and other third party sources. The information may not be valid under
all conditions nor if this material is used in combination with other materials or in any
process. Final determination of suitability of any material is the sole responsibility of
the user.
***END OF MSDS***
CLWGAU421
Page 6 of 6


MATERIAL SAFETY DATA SHEET
Product Trade Name:
SAND - COMMON BROWN
Revision Date: 05-Jan-2010
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Statement of Hazardous Nature Hazardous according to criteria of WorkSafe
Manufacturer/Supplier Halliburton Australia Pty. Ltd.
53-55 Bannister Road
Canning Vale
WA 6155
Australia
ACN Number: 009 000 775
Telephone Number: 61 (08) 9455 8300
Fax Number: 61 (08) 9455 5300
Product Emergency Telephone
Australia: 08-64244950
Papua New Guinea: 05 1 281 575 5000
NewZealand: 06-7559274
Fire, Police & Ambulance - Emergency Telephone
Australia: 000
Papua New Guinea: 000
New Zealand: 111
Identification of Substances or Preparation
Product Trade Name: SAND - COMMON BROWN
Synonyms: None
Chemical Family: Sand
UN Number: None
Dangerous Goods Class: None
Subsidiary Risk: None
Hazchem Code: None
Poisons Schedule: None
Application: Proppant
Prepared By Chemical Compliance
Telephone: 1-580-251-4335
e-mail: fdunexchem@halliburton.com
2. COMPOSITION/INFORMATION ON INGREDIENTS
SUBSTANCE CAS Number PERCENT Australia NOHSC ACGIH TLV-TWA
Crystalline silica, quartz 14808-60-7 60 - 100% 0.1 mg/m
3
0.025 mg/m
3
SAND - COMMON BROWN
Page 1 of 7
Total to 100%
3. HAZARDS IDENTIFICATION
Hazard Overview CAUTION! - ACUTE HEALTH HAZARD
May cause eye and respiratory irritation.
DANGER! - CHRONIC HEALTH HAZARD
Breathing crystalline silica can cause lung disease, including silicosis and lung
cancer. Crystalline silica has also been associated with scleroderma and kidney
disease.
This product contains quartz, cristobalite, and/or tridymite which may become
airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty
conditions. Use only with adequate ventilation to keep exposures below
recommended exposure limits. Wear a NIOSH certified, European Standard EN
149, or equivalent respirator when using this product. Review the Material Safety
Data Sheet (MSDS) for this product, which has been provided to your employer.
Hazard Ratings
Flammability: 0
Unknown Aquatic Toxicty 0
Body Contact: 0
Reactivity: 0
Chronic: 4
Scale: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4
4. FIRST AID MEASURES
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation
develops or if breathing becomes difficult.
Skin Wash with soap and water.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes
and get medical attention if irritation persists.
Ingestion Under normal conditions, first aid procedures are not required.
Notes to Physician Not Applicable
5. FIRE FIGHTING MEASURES
Suitable Extinguishing Media None - does not burn.
Unsuitable Extinguishing Media None known.
Special Exposure Hazards Not applicable.
Special Protective Equipment for
Fire-Fighters
Not applicable.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.
SAND - COMMON BROWN
Page 2 of 7
Environmental Precautionary
Measures
None known.
Procedure for Cleaning /
Absorption
Collect using dustless method and hold for appropriate disposal. Consider possible
toxic or fire hazards associated with contaminating substances and use appropriate
methods for collection, storage and disposal.
7. HANDLING AND STORAGE
Handling Precautions This product contains quartz, cristobalite, and/or tridymite which may become
airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty
conditions. Use only with adequate ventilation to keep exposure below
recommended exposure limits. Wear a NIOSH certified, European Standard En 149,
or equivalent respirator when using this product. Material is slippery when wet.
Storage Information Use good housekeeping in storage and work areas to prevent accumulation of dust.
Close container when not in use. Product has a shelf life of 36 months.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain
exposures below applicable exposure limits listed in Section 2.
Respiratory Protection Wear a NIOSH certified, European Standard EN 149, or equivalent respirator when
using this product.
Hand Protection Normal work gloves.
Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be
laundered before reuse. Use precautionary measures to avoid creating dust when
removing or laundering clothing.
Eye Protection Wear safety glasses or goggles to protect against exposure.
Other Precautions None known.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Solid
Color: Brown
Odor: Odorless
pH: Not Determined
Specific Gravity @ 20 C (Water=1): 2.63 - 2.67
Density @ 20 C (kg/l): Not Determined
Bulk Density @ 20 C (kg/m
3
): Not Determined
Boiling Point/Range (C): Not Determined
Freezing Point/Range (C): Not Determined
Pour Point/Range (C): Not Determined
Flash Point/Range (C): Not Determined
Flash Point Method: Not Determined
Autoignition Temperature (C): Not Determined
Flammability Limits in Air - Lower (g/m
3
): Not Determined
Flammability Limits in Air - Lower (%): Not Determined
Flammability Limits in Air - Upper (g/m
3
): Not Determined
Flammability Limits in Air - Upper (%): Not Determined
Vapor Pressure @ 20 C (mmHg): Not Determined
Vapor Density (Air=1): Not Determined
Percent Volatiles: 0
SAND - COMMON BROWN
Page 3 of 7
9. PHYSICAL AND CHEMICAL PROPERTIES
Evaporation Rate (Butyl Acetate=1): Not Determined
Solubility in Water (g/100ml): Insoluble
Solubility in Solvents (g/100ml): Not Determined
VOCs (g/l): Not Determined
Viscosity, Dynamic @ 20 C (centipoise): Not Determined
Viscosity, Kinematic @ 20 C (centistrokes): Not Determined
Partition Coefficient/n-Octanol/Water: Not Determined
Molecular Weight (g/mole): 65
Decomposition Temperature (C): Not Determined
10. STABILITY AND REACTIVITY
Stability Data: Stable
Hazardous Polymerization: Will Not Occur
Conditions to Avoid None known.
Incompatibility (Materials to
Avoid)
Hydrofluoric acid.
Hazardous Decomposition
Products
Amorphous silica may transform at elevated temperatures to tridymite (870 C) or
cristobalite (1470 C).
Additional Guidelines Not Applicable
11. TOXICOLOGICAL INFORMATION
Principle Route of Exposure Eye or skin contact, inhalation.
Inhalation Inhaled crystalline silica in the form of quartz or cristobalite from occupational
sources is carcinogenic to humans (IARC, Group 1). There is sufficient evidence in
experimental animals for the carcinogenicity of tridymite (IARC, Group 2A).
Breathing silica dust may cause irritation of the nose, throat, and respiratory
passages. Breathing silica dust may not cause noticeable injury or illness even
though permanent lung damage may be occurring. Inhalation of dust may also have
serious chronic health effects (See "Chronic Effects/Carcinogenicity" subsection
below).
Skin Contact None known.
Eye Contact May cause mechanical irritation to eye.
Ingestion None known
Aggravated Medical Conditions Individuals with respiratory disease, including but not limited to asthma and
bronchitis, or subject to eye irritation, should not be exposed to quartz dust.
SAND - COMMON BROWN
Page 4 of 7
Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a
progressive, disabling, and sometimes-fatal lung disease called silicosis. Symptoms
include cough, shortness of breath, wheezing, non-specific chest illness, and
reduced pulmonary function. This disease is exacerbated by smoking. Individuals
with silicosis are predisposed to develop tuberculosis.
Cancer Status: The International Agency for Research on Cancer (IARC) has
determined that crystalline silica inhaled in the form of quartz or cristobalite from
occupational sources can cause lung cancer in humans (Group 1 - carcinogenic to
humans) and has determined that there is sufficient evidence in experimental
animals for the carcinogenicity of tridymite (Group 2A - possible carcinogen to
humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres
(June 1997) in conjunction with the use of these minerals. The National Toxicology
Program classifies respirable crystalline silica as "Known to be a human carcinogen".
Refer to the 9th Report on Carcinogens (2000). The American Conference of
Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a
suspected human carcinogen (A2).
There is some evidence that breathing respirable crystalline silica or the disease
silicosis is associated with an increased incidence of significant disease endpoints
such as scleroderma (an immune system disorder manifested by scarring of the
lungs, skin, and other internal organs) and kidney disease.
Other Information For further information consult "Adverse Effects of Crystalline Silica Exposure"
published by the American Thoracic Society Medical Section of the American Lung
Association, American Journal of Respiratory and Critical Care Medicine, Volume
155, pages 761-768 (1997).
Toxicity Tests
Oral Toxicity: Not determined
Dermal Toxicity: Not determined
Inhalation Toxicity: Not determined
Primary Irritation Effect: Not determined
Carcinogenicity Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (June
1997).
Genotoxicity: Not determined
Reproductive /
Developmental Toxicity:
Not determined
12. ECOLOGICAL INFORMATION
Mobility (Water/Soil/Air) Not determined
Persistence/Degradability Not applicable
Bio-accumulation Not Determined
Ecotoxicological Information
Acute Fish Toxicity: Not determined
Acute Crustaceans Toxicity:Not determined
SAND - COMMON BROWN
Page 5 of 7
Acute Algae Toxicity: Not determined
Chemical Fate Information Not determined
Other Information Not applicable
13. DISPOSAL CONSIDERATIONS
Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.
Contaminated Packaging Follow all applicable national or local regulations.
14. TRANSPORT INFORMATION
Land Transportation
ADR
Not restricted
Air Transportation
ICAO/IATA
Not restricted
Sea Transportation
IMDG
Not restricted
Other Shipping Information
Labels: None
15. REGULATORY INFORMATION
Chemical Inventories
Australian AICS Inventory Not Determined
US TSCA Inventory All components listed on inventory or are exempt.
EINECS Inventory This product, and all its components, complies with EINECS
Classification Not Classified
Risk Phrases None
Safety Phrases None
16. OTHER INFORMATION
The following sections have been revised since the last issue of this MSDS
Not applicable
SAND - COMMON BROWN
Page 6 of 7
Contact
Australian Poisons Information Centre
24 Hour Service: - 13 11 26
Police or Fire Brigade: - 000 (exchange): - 1100
New Zealand Poisons Information System
Deunedin: -(03) 479 1200 (Normal Hours)
-(03) 474 0999 (Emergency)
Additional Information For additional information on the use of this product, contact your local Halliburton
representative.
For questions about the Material Safety Data Sheet for this or other Halliburton
products, contact Chemical Compliance at 1-580-251-4335.
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy
or completeness. The information is obtained from various sources including the
manufacturer and other third party sources. The information may not be valid under
all conditions nor if this material is used in combination with other materials or in any
process. Final determination of suitability of any material is the sole responsibility of
the user.
***END OF MSDS***
SAND - COMMON BROWN
Page 7 of 7
Tracerco Chemwatch Hazard Alert Code: 2
Tracerco T-140a
Chemwatch: 4886-72
Version No: 3.1.1.1
Safety Data Sheet according to WHS and ADG requirements
Issue Date: 25/02/2014
Print Date: 16/05/2014
Initial Date: Not Available
S.GHS.AUS.EN
SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING
Product Identifier
Product name Tracerco T-140a
Chemical Name Not Applicable
Synonyms Not Available
Proper shipping name Not Applicable
Chemical formula Not Applicable
Other means of identification Not Available
CAS number Not Applicable
Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses Use according to manufacturer's directions.
Details of the supplier of the safety data sheet
Registered company name Tracerco
Address
2 Harris Road Malaga 6090 WA
Australia
Telephone +61 8 9209 3905
Fax +61 8 9209 3725
Website www.tracerco.com
Email admin.aus@tracerco.com
Emergency telephone number
Association / Organisation Not Available
Emergency telephone numbers +61 8 9209 3905 (9am-5pm)
Other emergency telephone
numbers
+61 8 9209 3905 (9am-5pm)
SECTION 2 HAZARDS IDENTIFICATION
Classification of the substance or mixture
HAZARDOUS CHEMICAL. NON-DANGEROUS GOODS. According to the Model WHS Regulations and the ADG Code.
CHEMWATCH HAZARD RATINGS
Max Min
Flammability 0
Toxicity 2

Body Contact 2

Reactivity 0
Chronic 0
0 = Minimum
1 = Low
2 = Moderate
3 = High
4 = Extreme
Poisons Schedule Not Applicable
GHS Classification
[1]
Acute Toxicity (Oral) Category 4, Acute Toxicity (Inhalation) Category 4, Skin Corrosion/Irritation Category 2, Eye
Irrit. 2, STOT - SE (Resp. Irr.) Category 3
Continued...
Legend:
1. Classified by Chemwatch; 2. Classification drawn from HSIS ; 3. Classification drawn from EC Directive
1272/2008 - Annex VI
Label elements
GHS label elements
SIGNAL WORD WARNING
Hazard statement(s)
H302 Harmful if swallowed
H332 Harmful if inhaled
H315 Causes skin irritation
H319 Causes serious eye irritation
H335 May cause respiratory irritation
Precautionary statement(s): Prevention
P271 Use only outdoors or in a well-ventilated area.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Precautionary statement(s): Response
P321 Specific treatment (see advice on this label).
P305+P351+P338
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/attention.
P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor/physician/first aider/if you feel unwell.
Precautionary statement(s): Storage
P405 Store locked up.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
Precautionary statement(s): Disposal
P501 Dispose of contents/container to authorised chemical landfill or if organic to high temperature incineration
SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
Substances
See section below for composition of Mixtures
Mixtures
CAS No %[weight] Name
490-97-1 10-30 sodium 2-fluorobenzoate
7732-18-5 >60 water
SECTION 4 FIRST AID MEASURES
Description of first aid measures
Eye Contact
If this product comes in contact with the eyes:
Wash out immediately with fresh running water.
Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids
by occasionally lifting the upper and lower lids.
Seek medical attention without delay; if pain persists or recurs seek medical attention.
Chemwatch: 4886-72
Version No: 3.1.1.1
Page 2 of 8
Tracerco T-140a
Issue Date: 25/02/2014
Print Date: 16/05/2014
Continued...
Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
Skin Contact
If skin contact occurs:
Immediately remove all contaminated clothing, including footwear.
Flush skin and hair with running water (and soap if available).
Seek medical attention in event of irritation.
Inhalation
If fumes, aerosols or combustion products are inhaled remove from contaminated area.
Other measures are usually unnecessary.
Ingestion
If swallowed do NOT induce vomiting.
If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain
open airway and prevent aspiration.
Observe the patient carefully.
Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming
unconscious.
Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink.
Seek medical advice.
Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5 FIREFIGHTING MEASURES
Extinguishing media
There is no restriction on the type of extinguisher which may be used.
Use extinguishing media suitable for surrounding area.
Special hazards arising from the substrate or mixture
Fire Incompatibility None known.
Advice for firefighters
Fire Fighting
Alert Fire Brigade and tell them location and nature of hazard.
Wear breathing apparatus plus protective gloves in the event of a fire.
Prevent, by any means available, spillage from entering drains or water courses.
Use fire fighting procedures suitable for surrounding area.
Fire/Explosion Hazard
Non combustible.
Not considered to be a significant fire risk.
Expansion or decomposition on heating may lead to violent rupture of containers.
Decomposes on heating and may produce toxic fumes of carbon monoxide (CO).
SECTION 6 ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Minor Spills
Clean up all spills immediately.
Avoid breathing vapours and contact with skin and eyes.
Control personal contact with the substance, by using protective equipment.
Contain and absorb spill with sand, earth, inert material or vermiculite.
Major Spills
Minor hazard.
Clear area of personnel.
Alert Fire Brigade and tell them location and nature of hazard.
Control personal contact with the substance, by using protective equipment as required.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
SECTION 7 HANDLING AND STORAGE
Precautions for safe handling
Safe handling
Limit all unnecessary personal contact.
Wear protective clothing when risk of exposure occurs.
Use in a well-ventilated area.
When handling DO NOT eat, drink or smoke.
Chemwatch: 4886-72
Version No: 3.1.1.1
Page 3 of 8
Tracerco T-140a
Issue Date: 25/02/2014
Print Date: 16/05/2014
Continued...
Other information
Store in original containers.
Keep containers securely sealed.
Store in a cool, dry, well-ventilated area.
Store away from incompatible materials and foodstuff containers.
Conditions for safe storage, including any incompatibilities
Suitable container
Polyethylene or polypropylene container.
Packing as recommended by manufacturer.
Check all containers are clearly labelled and free from leaks.
Storage incompatibility None known
PACKAGE MATERIAL INCOMPATIBILITIES
Not Available
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Control parameters
OCCUPATIONAL EXPOSURE LIMITS (OEL)
INGREDIENT DATA
Not Available
EMERGENCY LIMITS
Ingredient TEEL-0 TEEL-1 TEEL-2 TEEL-3
water 500(ppm) 500(ppm) 500(ppm) 500(ppm)
Ingredient Original IDLH Revised IDLH
Tracerco T-140a Not Available Not Available
Exposure controls
Appropriate engineering
controls
Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard.
Well-designed engineering controls can be highly effective in protecting workers and will typically be independent
of worker interactions to provide this high level of protection.
The basic types of engineering controls are:
Process controls which involve changing the way a job activity or process is done to reduce the risk.
Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker
and ventilation that strategically "adds" and "removes" air in the work environment.
Personal protection
Eye and face protection
Safety glasses with side shields.
Chemical goggles.
Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written
policy document, describing the wearing of lenses or restrictions on use, should be created for each workplace or
task.
Skin protection See Hand protection below
Hand protection
The selection of suitable gloves does not only depend on the material, but also on further marks of quality which
vary from manufacturer to manufacturer. Where the chemical is a preparation of several substances, the
resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the
application.
The exact break through time for substances has to be obtained from the manufacturer of the protective gloves
and.has to be observed when making a final choice.
Suitability and durability of glove type is dependent on usage.
Body protection See Other protection below
Other protection
Overalls.
Eyewash unit.
Thermal hazards Not Available
Recommended material(s) Respiratory protection
Chemwatch: 4886-72
Version No: 3.1.1.1
Page 4 of 8
Tracerco T-140a
Issue Date: 25/02/2014
Print Date: 16/05/2014
Continued...
GLOVE SELECTION INDEX
Glove selection is based on a modified presentation of the:
"Forsberg Clothing Performance Index".
The effect(s) of the following substance(s) are taken into account in the
computer-generated selection:
Tracerco T-140a
Material CPI
BUTYL A
NEOPRENE A
VITON A
* CPI - Chemwatch Performance Index
A: Best Selection
B: Satisfactory; may degrade after 4 hours continuous immersion
C: Poor to Dangerous Choice for other than short term immersion
NOTE: As a series of factors will influence the actual performance of the
glove, a final selection must be based on detailed observation. -
* Where the glove is to be used on a short term, casual or infrequent
basis, factors such as "feel" or convenience (e.g. disposability), may
dictate a choice of gloves which might otherwise be unsuitable following
long-term or frequent use. A qualified practitioner should be consulted.
Particulate. (AS/NZS 1716 & 1715, EN 143:000 & 149:001, ANSI Z88 or
national equivalent)
Where the concentration of gas/particulates in the breathing zone,
approaches or exceeds the "Exposure Standard" (or ES), respiratory
protection is required.
Degree of protection varies with both face-piece and Class of filter;
the nature of protection varies with Type of filter.
Required
Minimum
Protection Factor
Half-Face
Respirator
Full-Face
Respirator
Powered Air
Respirator
up to 10 x ES -AUS P2 -
-PAPR-AUS /
Class 1 P2
up to 50 x ES -
-AUS / Class
1 P2
-
up to 100 x ES - -2 P2 -PAPR-2 P2 ^
^ - Full-face
A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 =
Acid gas or hydrogen cyanide(HCN), B3 = Acid gas or hydrogen
cyanide(HCN), E = Sulfur dioxide(SO2), G = Agricultural chemicals,
K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB =
Methyl bromide, AX = Low boiling point organic compounds(below
65 degC)
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Appearance Liquid; mixes with water.
Physical state Liquid Relative density (Water = 1) Not Available
Odour Not Available
Partition coefficient n-octanol /
water
Not Available
Odour threshold Not Available Auto-ignition temperature (C) Not Applicable
pH (as supplied) Not Available Decomposition temperature Not Available
Melting point / freezing point
(C)
Not Available Viscosity (cSt) Not Available
Initial boiling point and boiling
range (C)
Not Available Molecular weight (g/mol) Not Applicable
Flash point (C) Not Applicable Taste Not Available
Evaporation rate Not Available Explosive properties Not Available
Flammability Not Applicable Oxidising properties Not Available
Upper Explosive Limit (%) Not Applicable
Surface Tension (dyn/cm or
mN/m)
Not Available
Lower Explosive Limit (%) Not Applicable Volatile Component (%vol) 80
Vapour pressure (kPa) Not Available Gas group Not Available
Solubility in water (g/L) Miscible pH as a solution(1%) Not Available
Vapour density (Air = 1) Not Available VOC g/L Not Available
SECTION 10 STABILITY AND REACTIVITY
Reactivity See section 7
Chemical stability Product is considered stable and hazardous polymerisation will not occur.
Possibility of hazardous
reactions
See section 7
Conditions to avoid See section 7
Incompatible materials See section 7
Chemwatch: 4886-72
Version No: 3.1.1.1
Page 5 of 8
Tracerco T-140a
Issue Date: 25/02/2014
Print Date: 16/05/2014
Continued...
Hazardous decomposition
products
See section 5
SECTION 11 TOXICOLOGICAL INFORMATION
Information on toxicological effects
Inhaled
Evidence shows, or practical experience predicts, that the material produces irritation of the respiratory system, in
a substantial number of individuals, following inhalation. In contrast to most organs, the lung is able to respond to
a chemical insult by first removing or neutralising the irritant and then repairing the damage. The repair process,
which initially evolved to protect mammalian lungs from foreign matter and antigens, may however, produce
further lung damage resulting in the impairment of gas exchange, the primary function of the lungs. Respiratory
tract irritation often results in an inflammatory response involving the recruitment and activation of many cell
types, mainly derived from the vascular system.
Ingestion
Accidental ingestion of the material may be damaging to the health of the individual.
Ingestion may result in nausea, abdominal irritation, pain and vomiting
Skin Contact
Evidence exists, or practical experience predicts, that the material either produces inflammation of the skin in a
substantial number of individuals following direct contact, and/or produces significant inflammation when applied to
the healthy intact skin of animals, for up to four hours, such inflammation being present twenty-four hours or
more after the end of the exposure period. Skin irritation may also be present after prolonged or repeated
exposure; this may result in a form of contact dermatitis (nonallergic). The dermatitis is often characterised by
skin redness (erythema) and swelling (oedema) which may progress to blistering (vesiculation), scaling and
thickening of the epidermis. At the microscopic level there may be intercellular oedema of the spongy layer of the
skin (spongiosis) and intracellular oedema of the epidermis.
Eye
Evidence exists, or practical experience predicts, that the material may cause eye irritation in a substantial
number of individuals and/or may produce significant ocular lesions which are present twenty-four hours or more
after instillation into the eye(s) of experimental animals.
Repeated or prolonged eye contact may cause inflammation characterised by temporary redness (similar to
windburn) of the conjunctiva (conjunctivitis); temporary impairment of vision and/or other transient eye
damage/ulceration may occur.
Chronic
Long-term exposure to respiratory irritants may result in disease of the airways involving difficult breathing and
related systemic problems.
Tracerco T-140a
TOXICITY IRRITATION
Not Available Not Available
sodium 2-fluorobenzoate
TOXICITY IRRITATION
Not Available Not Available
water
TOXICITY IRRITATION
Not Available Not Available
* Value obtained from manufacturer's msds
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances
Tracerco T-140a Not available.
SODIUM 2-FLUOROBENZOATE
Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This
may be due to a non-allergenic condition known as reactive airways dysfunction syndrome (RADS) which can
occur following exposure to high levels of highly irritating compound. Key criteria for the diagnosis of RADS
include the absence of preceding respiratory disease, in a non-atopic individual, with abrupt onset of persistent
asthma-like symptoms within minutes to hours of a documented exposure to the irritant. A reversible airflow
pattern, on spirometry, with the presence of moderate to severe bronchial hyperreactivity on methacholine
challenge testing and the lack of minimal lymphocytic inflammation, without eosinophilia, have also been
included in the criteria for diagnosis of RADS.
WATER No significant acute toxicological data identified in literature search.
Acute Toxicity Carcinogenicity
Chemwatch: 4886-72
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Tracerco T-140a
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Continued...
Skin Irritation/Corrosion Reproductivity
Serious Eye Damage/Irritation STOT - Single Exposure
Respiratory or Skin
sensitisation
STOT - Repeated Exposure
Mutagenicity Aspiration Hazard
CMR STATUS
Not Applicable
SECTION 12 ECOLOGICAL INFORMATION
Toxicity
DO NOT discharge into sewer or waterways.
Persistence and degradability
Ingredient Persistence: Water/Soil Persistence: Air
Not Available Not Available Not Available
Bioaccumulative potential
Ingredient Bioaccumulation
Not Available Not Available
Mobility in soil
Ingredient Mobility
Not Available Not Available
SECTION 13 DISPOSAL CONSIDERATIONS
Waste treatment methods
Product / Packaging disposal
Recycle wherever possible.
Consult manufacturer for recycling options or consult local or regional waste management authority for
disposal if no suitable treatment or disposal facility can be identified.
Dispose of by: burial in a land-fill specifically licenced to accept chemical and / or pharmaceutical wastes or
incineration in a licenced apparatus (after admixture with suitable combustible material).
Decontaminate empty containers.
SECTION 14 TRANSPORT INFORMATION
Labels Required
Marine Pollutant NO
HAZCHEM Not Applicable
Land transport (): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
SECTION 15 REGULATORY INFORMATION
Safety, health and environmental regulations / legislation specific for the substance or mixture
sodium
2-fluorobenzoate(490-97-1) is
found on the following
regulatory lists
water(7732-18-5) is found on the
following regulatory lists
"WHO Model List of Essential Medicines - Adults","Australia Inventory of Chemical Substances (AICS)","OECD
List of High Production Volume (HPV) Chemicals","OSPAR National List of Candidates for Substitution
Norway","IMO IBC Code Chapter 18: List of products to which the Code does not apply","Sigma-AldrichTransport
Chemwatch: 4886-72
Version No: 3.1.1.1
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Tracerco T-140a
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Print Date: 16/05/2014
Continued...
Information","Australia High Volume Industrial Chemical List (HVICL)","International Fragrance Association (IFRA)
Survey: Transparency List"
SECTION 16 OTHER INFORMATION
Other information
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the
Chemwatch Classification committee using available literature references.
A list of reference resources used to assist the committee may be found at:
www.chemwatch.net/references
The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards
are Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current
or available engineering controls must be considered.
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from CHEMWATCH. TEL (+61 3) 9572 4700.
Chemwatch: 4886-72
Version No: 3.1.1.1
Page 8 of 8
Tracerco T-140a
Issue Date: 25/02/2014
Print Date: 16/05/2014
end of SDS
Tracerco Chemwatch Hazard Alert Code: 1
Tracerco T-140b
Chemwatch: 4886-94
Version No: 2.1.1.1
Safety Data Sheet according to WHS and ADG requirements
Issue Date: 25/02/2014
Print Date: 16/05/2014
Initial Date: Not Available
S.GHS.AUS.EN
SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING
Product Identifier
Product name Tracerco T-140b
Chemical Name Not Applicable
Synonyms Not Available
Proper shipping name Not Applicable
Chemical formula Not Applicable
Other means of identification Not Available
CAS number Not Applicable
Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses Use according to manufacturer's directions.
Details of the supplier of the safety data sheet
Registered company name Tracerco
Address
2 Harris Road Malaga 6090 WA
Australia
Telephone +61 8 9209 3905
Fax +61 8 9209 3725
Website www.tracerco.com
Email admin.aus@tracerco.com
Emergency telephone number
Association / Organisation Not Available
Emergency telephone numbers +61 8 9209 3905 (9am-5pm)
Other emergency telephone
numbers
+61 8 9209 3905 (9am-5pm)
SECTION 2 HAZARDS IDENTIFICATION
Classification of the substance or mixture
NON-HAZARDOUS CHEMICAL. NON-DANGEROUS GOODS. According to the Model WHS Regulations and the ADG Code.
CHEMWATCH HAZARD RATINGS
Max Min
Flammability 0
Toxicity 1

Body Contact 1

Reactivity 0
Chronic 0
0 = Minimum
1 = Low
2 = Moderate
3 = High
4 = Extreme
Poisons Schedule Not Applicable
GHS Classification Not Applicable
Continued...
Label elements
GHS label elements
Not Applicable
SIGNAL WORD NOT APPLICABLE
Hazard statement(s)
Not Applicable
Precautionary statement(s): Prevention
Not Applicable
Precautionary statement(s): Response
Not Applicable
Precautionary statement(s): Storage
Not Applicable
Precautionary statement(s): Disposal
Not Applicable
SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
Substances
See section below for composition of Mixtures
Mixtures
CAS No %[weight] Name
499-57-0 1-10 sodium 3-fluorobenzoate
7732-18-5 >60 water
SECTION 4 FIRST AID MEASURES
Description of first aid measures
Eye Contact
If this product comes in contact with the eyes:
Wash out immediately with fresh running water.
Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids
by occasionally lifting the upper and lower lids.
Seek medical attention without delay; if pain persists or recurs seek medical attention.
Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
Skin Contact
If skin contact occurs:
Immediately remove all contaminated clothing, including footwear.
Flush skin and hair with running water (and soap if available).
Seek medical attention in event of irritation.
Inhalation
If fumes, aerosols or combustion products are inhaled remove from contaminated area.
Other measures are usually unnecessary.
Ingestion
If swallowed do NOT induce vomiting.
If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain
open airway and prevent aspiration.
Observe the patient carefully.
Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming
unconscious.
Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink.
Seek medical advice.
Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5 FIREFIGHTING MEASURES
Extinguishing media
There is no restriction on the type of extinguisher which may be used.
Use extinguishing media suitable for surrounding area.
Chemwatch: 4886-94
Version No: 2.1.1.1
Page 2 of 7
Tracerco T-140b
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Print Date: 16/05/2014
Continued...
Special hazards arising from the substrate or mixture
Fire Incompatibility None known.
Advice for firefighters
Fire Fighting
Alert Fire Brigade and tell them location and nature of hazard.
Wear breathing apparatus plus protective gloves in the event of a fire.
Prevent, by any means available, spillage from entering drains or water courses.
Use fire fighting procedures suitable for surrounding area.
Fire/Explosion Hazard
Non combustible.
Not considered to be a significant fire risk.
Expansion or decomposition on heating may lead to violent rupture of containers.
Decomposes on heating and may produce toxic fumes of carbon monoxide (CO).
SECTION 6 ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Minor Spills
Clean up all spills immediately.
Avoid breathing vapours and contact with skin and eyes.
Control personal contact with the substance, by using protective equipment.
Contain and absorb spill with sand, earth, inert material or vermiculite.
Major Spills
Minor hazard.
Clear area of personnel.
Alert Fire Brigade and tell them location and nature of hazard.
Control personal contact with the substance, by using protective equipment as required.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
SECTION 7 HANDLING AND STORAGE
Precautions for safe handling
Safe handling
Limit all unnecessary personal contact.
Wear protective clothing when risk of exposure occurs.
Use in a well-ventilated area.
When handling DO NOT eat, drink or smoke.
Other information
Store in original containers.
Keep containers securely sealed.
Store in a cool, dry, well-ventilated area.
Store away from incompatible materials and foodstuff containers.
Conditions for safe storage, including any incompatibilities
Suitable container
Polyethylene or polypropylene container.
Packing as recommended by manufacturer.
Check all containers are clearly labelled and free from leaks.
Storage incompatibility None known
PACKAGE MATERIAL INCOMPATIBILITIES
Not Available
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Control parameters
OCCUPATIONAL EXPOSURE LIMITS (OEL)
INGREDIENT DATA
Not Available
EMERGENCY LIMITS
Ingredient TEEL-0 TEEL-1 TEEL-2 TEEL-3
water 500(ppm) 500(ppm) 500(ppm) 500(ppm)
Chemwatch: 4886-94
Version No: 2.1.1.1
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Tracerco T-140b
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Print Date: 16/05/2014
Continued...
Ingredient Original IDLH Revised IDLH
Tracerco T-140b Not Available Not Available
Exposure controls
Appropriate engineering
controls
General exhaust is adequate under normal operating conditions.
Personal protection
Eye and face protection
Safety glasses with side shields.
Chemical goggles.
Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written
policy document, describing the wearing of lenses or restrictions on use, should be created for each workplace or
task.
Skin protection See Hand protection below
Hand protection
The selection of suitable gloves does not only depend on the material, but also on further marks of quality which
vary from manufacturer to manufacturer. Where the chemical is a preparation of several substances, the
resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the
application.
The exact break through time for substances has to be obtained from the manufacturer of the protective gloves
and.has to be observed when making a final choice.
Suitability and durability of glove type is dependent on usage.
Body protection See Other protection below
Other protection
Overalls.
Eyewash unit.
Thermal hazards Not Available
Recommended material(s)
GLOVE SELECTION INDEX
Glove selection is based on a modified presentation of the:
"Forsberg Clothing Performance Index".
The effect(s) of the following substance(s) are taken into account in the
computer-generated selection:
Tracerco T-140b
Material CPI
BUTYL A
NEOPRENE A
VITON A
* CPI - Chemwatch Performance Index
A: Best Selection
B: Satisfactory; may degrade after 4 hours continuous immersion
C: Poor to Dangerous Choice for other than short term immersion
NOTE: As a series of factors will influence the actual performance of the
glove, a final selection must be based on detailed observation. -
* Where the glove is to be used on a short term, casual or infrequent
basis, factors such as "feel" or convenience (e.g. disposability), may
dictate a choice of gloves which might otherwise be unsuitable following
long-term or frequent use. A qualified practitioner should be consulted.
Respiratory protection
Particulate. (AS/NZS 1716 & 1715, EN 143:000 & 149:001, ANSI Z88 or
national equivalent)
Where the concentration of gas/particulates in the breathing zone,
approaches or exceeds the "Exposure Standard" (or ES), respiratory
protection is required.
Degree of protection varies with both face-piece and Class of filter;
the nature of protection varies with Type of filter.
Required
Minimum
Protection Factor
Half-Face
Respirator
Full-Face
Respirator
Powered Air
Respirator
up to 10 x ES -AUS P2 -
-PAPR-AUS /
Class 1 P2
up to 50 x ES -
-AUS / Class
1 P2
-
up to 100 x ES - -2 P2 -PAPR-2 P2 ^
^ - Full-face
A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 =
Acid gas or hydrogen cyanide(HCN), B3 = Acid gas or hydrogen
cyanide(HCN), E = Sulfur dioxide(SO2), G = Agricultural chemicals,
K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB =
Methyl bromide, AX = Low boiling point organic compounds(below
65 degC)
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Appearance Liquid; mixes with water.
Physical state Liquid Relative density (Water = 1) Not Available
Chemwatch: 4886-94
Version No: 2.1.1.1
Page 4 of 7
Tracerco T-140b
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Print Date: 16/05/2014
Continued...
Odour Not Available
Partition coefficient n-octanol /
water
Not Available
Odour threshold Not Available Auto-ignition temperature (C) Not Applicable
pH (as supplied) Not Available Decomposition temperature Not Available
Melting point / freezing point
(C)
Not Available Viscosity (cSt) Not Available
Initial boiling point and boiling
range (C)
Not Available Molecular weight (g/mol) Not Applicable
Flash point (C) Not Applicable Taste Not Available
Evaporation rate Not Available Explosive properties Not Available
Flammability Not Applicable Oxidising properties Not Available
Upper Explosive Limit (%) Not Applicable
Surface Tension (dyn/cm or
mN/m)
Not Available
Lower Explosive Limit (%) Not Applicable Volatile Component (%vol) 90
Vapour pressure (kPa) Not Available Gas group Not Available
Solubility in water (g/L) Miscible pH as a solution(1%) Not Available
Vapour density (Air = 1) Not Available VOC g/L Not Available
SECTION 10 STABILITY AND REACTIVITY
Reactivity See section 7
Chemical stability Product is considered stable and hazardous polymerisation will not occur.
Possibility of hazardous
reactions
See section 7
Conditions to avoid See section 7
Incompatible materials See section 7
Hazardous decomposition
products
See section 5
SECTION 11 TOXICOLOGICAL INFORMATION
Information on toxicological effects
Inhaled
Not normally a hazard due to non-volatile nature of product
The material is not thought to produce adverse health effects or irritation of the respiratory tract (as classified by
EC Directives using animal models). Nevertheless, good hygiene practice requires that exposure be kept to a
minimum and that suitable control measures be used in an occupational setting.
Ingestion
Accidental ingestion of the material may be damaging to the health of the individual.
Ingestion may result in nausea, abdominal irritation, pain and vomiting
Skin Contact
Limited evidence exists, or practical experience predicts, that the material either produces inflammation of the
skin in a substantial number of individuals following direct contact, and/or produces significant inflammation when
applied to the healthy intact skin of animals, for up to four hours, such inflammation being present twenty-four
hours or more after the end of the exposure period. Skin irritation may also be present after prolonged or repeated
exposure; this may result in a form of contact dermatitis (nonallergic). The dermatitis is often characterised by
skin redness (erythema) and swelling (oedema) which may progress to blistering (vesiculation), scaling and
thickening of the epidermis. At the microscopic level there may be intercellular oedema of the spongy layer of the
skin (spongiosis) and intracellular oedema of the epidermis.
Eye
Limited evidence exists, or practical experience suggests, that the material may cause eye irritation in a
substantial number of individuals and/or is expected to produce significant ocular lesions which are present
twenty-four hours or more after instillation into the eye(s) of experimental animals. Repeated or prolonged eye
contact may cause inflammation characterised by temporary redness (similar to windburn) of the conjunctiva
(conjunctivitis); temporary impairment of vision and/or other transient eye damage/ulceration may occur.
Chronic
Long-term exposure to the product is not thought to produce chronic effects adverse to health (as classified by
EC Directives using animal models); nevertheless exposure by all routes should be minimised as a matter of
course.
Tracerco T-140b
TOXICITY IRRITATION
Not Available Not Available
Chemwatch: 4886-94
Version No: 2.1.1.1
Page 5 of 7
Tracerco T-140b
Issue Date: 25/02/2014
Print Date: 16/05/2014
Continued...
* Value obtained from manufacturer's msds
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances
Tracerco T-140b Not available.
SODIUM 3-FLUOROBENZOATE
Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This
may be due to a non-allergenic condition known as reactive airways dysfunction syndrome (RADS) which can
occur following exposure to high levels of highly irritating compound. Key criteria for the diagnosis of RADS
include the absence of preceding respiratory disease, in a non-atopic individual, with abrupt onset of persistent
asthma-like symptoms within minutes to hours of a documented exposure to the irritant. A reversible airflow
pattern, on spirometry, with the presence of moderate to severe bronchial hyperreactivity on methacholine
challenge testing and the lack of minimal lymphocytic inflammation, without eosinophilia, have also been
included in the criteria for diagnosis of RADS.
WATER No significant acute toxicological data identified in literature search.
Acute Toxicity Carcinogenicity
Skin Irritation/Corrosion Reproductivity
Serious Eye Damage/Irritation STOT - Single Exposure
Respiratory or Skin
sensitisation
STOT - Repeated Exposure
Mutagenicity Aspiration Hazard
CMR STATUS
Not Applicable
SECTION 12 ECOLOGICAL INFORMATION
Toxicity
DO NOT discharge into sewer or waterways.
Persistence and degradability
Ingredient Persistence: Water/Soil Persistence: Air
Not Available Not Available Not Available
Bioaccumulative potential
Ingredient Bioaccumulation
Not Available Not Available
Mobility in soil
Ingredient Mobility
Not Available Not Available
SECTION 13 DISPOSAL CONSIDERATIONS
Waste treatment methods
Product / Packaging disposal
Recycle wherever possible.
Consult manufacturer for recycling options or consult local or regional waste management authority for
disposal if no suitable treatment or disposal facility can be identified.
Dispose of by: burial in a land-fill specifically licenced to accept chemical and / or pharmaceutical wastes or
incineration in a licenced apparatus (after admixture with suitable combustible material).
Decontaminate empty containers.
SECTION 14 TRANSPORT INFORMATION
Labels Required
Marine Pollutant NO
Chemwatch: 4886-94
Version No: 2.1.1.1
Page 6 of 7
Tracerco T-140b
Issue Date: 25/02/2014
Print Date: 16/05/2014
Continued...
HAZCHEM Not Applicable
Land transport (): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
SECTION 15 REGULATORY INFORMATION
Safety, health and environmental regulations / legislation specific for the substance or mixture
sodium
3-fluorobenzoate(499-57-0) is
found on the following
regulatory lists
water(7732-18-5) is found on the
following regulatory lists
"WHO Model List of Essential Medicines - Adults","Australia Inventory of Chemical Substances (AICS)","OECD
List of High Production Volume (HPV) Chemicals","OSPAR National List of Candidates for Substitution
Norway","IMO IBC Code Chapter 18: List of products to which the Code does not apply","Sigma-AldrichTransport
Information","Australia High Volume Industrial Chemical List (HVICL)","International Fragrance Association (IFRA)
Survey: Transparency List"
SECTION 16 OTHER INFORMATION
Other information
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the
Chemwatch Classification committee using available literature references.
A list of reference resources used to assist the committee may be found at:
www.chemwatch.net/references
The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards
are Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current
or available engineering controls must be considered.
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from CHEMWATCH. TEL (+61 3) 9572 4700.
Chemwatch: 4886-94
Version No: 2.1.1.1
Page 7 of 7
Tracerco T-140b
Issue Date: 25/02/2014
Print Date: 16/05/2014
end of SDS
Tracerco Chemwatch Hazard Alert Code: 1
Tracerco T-140c
Chemwatch: 4886-95
Version No: 2.1.1.1
Safety Data Sheet according to WHS and ADG requirements
Issue Date: 25/02/2014
Print Date: 16/05/2014
Initial Date: Not Available
S.GHS.AUS.EN
SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING
Product Identifier
Product name Tracerco T-140c
Chemical Name Not Applicable
Synonyms Not Available
Proper shipping name Not Applicable
Chemical formula Not Applicable
Other means of identification Not Available
CAS number Not Applicable
Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses Use according to manufacturer's directions.
Details of the supplier of the safety data sheet
Registered company name Tracerco
Address
2 Harris Road Malaga 6090 WA
Australia
Telephone +61 8 9209 3905
Fax +61 8 9209 3725
Website www.tracerco.com
Email admin.aus@tracerco.com
Emergency telephone number
Association / Organisation Not Available
Emergency telephone numbers +61 8 9209 3905 (9am-5pm)
Other emergency telephone
numbers
+61 8 9209 3905 (9am-5pm)
SECTION 2 HAZARDS IDENTIFICATION
Classification of the substance or mixture
NON-HAZARDOUS CHEMICAL. NON-DANGEROUS GOODS. According to the Model WHS Regulations and the ADG Code.
CHEMWATCH HAZARD RATINGS
Max Min
Flammability 0
Toxicity 1

Body Contact 1

Reactivity 0
Chronic 0
0 = Minimum
1 = Low
2 = Moderate
3 = High
4 = Extreme
Poisons Schedule Not Applicable
GHS Classification Not Applicable
Continued...
Label elements
GHS label elements
Not Applicable
SIGNAL WORD NOT APPLICABLE
Hazard statement(s)
Not Applicable
Precautionary statement(s): Prevention
Not Applicable
Precautionary statement(s): Response
Not Applicable
Precautionary statement(s): Storage
Not Applicable
Precautionary statement(s): Disposal
Not Applicable
SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
Substances
See section below for composition of Mixtures
Mixtures
CAS No %[weight] Name
499-90-1 1-10 sodium 4-fluorobenzoate
7732-18-5 >60 water
SECTION 4 FIRST AID MEASURES
Description of first aid measures
Eye Contact
If this product comes in contact with the eyes:
Wash out immediately with fresh running water.
Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids
by occasionally lifting the upper and lower lids.
Seek medical attention without delay; if pain persists or recurs seek medical attention.
Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
Skin Contact
If skin contact occurs:
Immediately remove all contaminated clothing, including footwear.
Flush skin and hair with running water (and soap if available).
Seek medical attention in event of irritation.
Inhalation
If fumes, aerosols or combustion products are inhaled remove from contaminated area.
Other measures are usually unnecessary.
Ingestion
If swallowed do NOT induce vomiting.
If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain
open airway and prevent aspiration.
Observe the patient carefully.
Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming
unconscious.
Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink.
Seek medical advice.
Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5 FIREFIGHTING MEASURES
Extinguishing media
There is no restriction on the type of extinguisher which may be used.
Use extinguishing media suitable for surrounding area.
Chemwatch: 4886-95
Version No: 2.1.1.1
Page 2 of 7
Tracerco T-140c
Issue Date: 25/02/2014
Print Date: 16/05/2014
Continued...
Special hazards arising from the substrate or mixture
Fire Incompatibility None known.
Advice for firefighters
Fire Fighting
Alert Fire Brigade and tell them location and nature of hazard.
Wear breathing apparatus plus protective gloves in the event of a fire.
Prevent, by any means available, spillage from entering drains or water courses.
Use fire fighting procedures suitable for surrounding area.
Fire/Explosion Hazard
Non combustible.
Not considered to be a significant fire risk.
Expansion or decomposition on heating may lead to violent rupture of containers.
Decomposes on heating and may produce toxic fumes of carbon monoxide (CO).
SECTION 6 ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Minor Spills
Clean up all spills immediately.
Avoid breathing vapours and contact with skin and eyes.
Control personal contact with the substance, by using protective equipment.
Contain and absorb spill with sand, earth, inert material or vermiculite.
Major Spills
Minor hazard.
Clear area of personnel.
Alert Fire Brigade and tell them location and nature of hazard.
Control personal contact with the substance, by using protective equipment as required.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
SECTION 7 HANDLING AND STORAGE
Precautions for safe handling
Safe handling
Limit all unnecessary personal contact.
Wear protective clothing when risk of exposure occurs.
Use in a well-ventilated area.
When handling DO NOT eat, drink or smoke.
Other information
Store in original containers.
Keep containers securely sealed.
Store in a cool, dry, well-ventilated area.
Store away from incompatible materials and foodstuff containers.
Conditions for safe storage, including any incompatibilities
Suitable container
Polyethylene or polypropylene container.
Packing as recommended by manufacturer.
Check all containers are clearly labelled and free from leaks.
Storage incompatibility None known
PACKAGE MATERIAL INCOMPATIBILITIES
Not Available
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Control parameters
OCCUPATIONAL EXPOSURE LIMITS (OEL)
INGREDIENT DATA
Not Available
EMERGENCY LIMITS
Ingredient TEEL-0 TEEL-1 TEEL-2 TEEL-3
water 500(ppm) 500(ppm) 500(ppm) 500(ppm)
Chemwatch: 4886-95
Version No: 2.1.1.1
Page 3 of 7
Tracerco T-140c
Issue Date: 25/02/2014
Print Date: 16/05/2014
Continued...
Ingredient Original IDLH Revised IDLH
Tracerco T-140c Not Available Not Available
Exposure controls
Appropriate engineering
controls
General exhaust is adequate under normal operating conditions.
Personal protection
Eye and face protection
Safety glasses with side shields.
Chemical goggles.
Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written
policy document, describing the wearing of lenses or restrictions on use, should be created for each workplace or
task.
Skin protection See Hand protection below
Hand protection
The selection of suitable gloves does not only depend on the material, but also on further marks of quality which
vary from manufacturer to manufacturer. Where the chemical is a preparation of several substances, the
resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the
application.
The exact break through time for substances has to be obtained from the manufacturer of the protective gloves
and.has to be observed when making a final choice.
Suitability and durability of glove type is dependent on usage.
Body protection See Other protection below
Other protection
Overalls.
Eyewash unit.
Thermal hazards Not Available
Recommended material(s)
GLOVE SELECTION INDEX
Glove selection is based on a modified presentation of the:
"Forsberg Clothing Performance Index".
The effect(s) of the following substance(s) are taken into account in the
computer-generated selection:
Tracerco T-140c
Material CPI
BUTYL A
NEOPRENE A
VITON A
* CPI - Chemwatch Performance Index
A: Best Selection
B: Satisfactory; may degrade after 4 hours continuous immersion
C: Poor to Dangerous Choice for other than short term immersion
NOTE: As a series of factors will influence the actual performance of the
glove, a final selection must be based on detailed observation. -
* Where the glove is to be used on a short term, casual or infrequent
basis, factors such as "feel" or convenience (e.g. disposability), may
dictate a choice of gloves which might otherwise be unsuitable following
long-term or frequent use. A qualified practitioner should be consulted.
Respiratory protection
Particulate. (AS/NZS 1716 & 1715, EN 143:000 & 149:001, ANSI Z88 or
national equivalent)
Where the concentration of gas/particulates in the breathing zone,
approaches or exceeds the "Exposure Standard" (or ES), respiratory
protection is required.
Degree of protection varies with both face-piece and Class of filter;
the nature of protection varies with Type of filter.
Required
Minimum
Protection Factor
Half-Face
Respirator
Full-Face
Respirator
Powered Air
Respirator
up to 10 x ES -AUS P2 -
-PAPR-AUS /
Class 1 P2
up to 50 x ES -
-AUS / Class
1 P2
-
up to 100 x ES - -2 P2 -PAPR-2 P2 ^
^ - Full-face
A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 =
Acid gas or hydrogen cyanide(HCN), B3 = Acid gas or hydrogen
cyanide(HCN), E = Sulfur dioxide(SO2), G = Agricultural chemicals,
K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB =
Methyl bromide, AX = Low boiling point organic compounds(below
65 degC)
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Appearance Liquid; mixes with water.
Physical state Liquid Relative density (Water = 1) Not Available
Chemwatch: 4886-95
Version No: 2.1.1.1
Page 4 of 7
Tracerco T-140c
Issue Date: 25/02/2014
Print Date: 16/05/2014
Continued...
Odour Not Available
Partition coefficient n-octanol /
water
Not Available
Odour threshold Not Available Auto-ignition temperature (C) Not Applicable
pH (as supplied) Not Available Decomposition temperature Not Available
Melting point / freezing point
(C)
Not Available Viscosity (cSt) Not Available
Initial boiling point and boiling
range (C)
Not Available Molecular weight (g/mol) Not Applicable
Flash point (C) Not Applicable Taste Not Available
Evaporation rate Not Available Explosive properties Not Available
Flammability Not Applicable Oxidising properties Not Available
Upper Explosive Limit (%) Not Applicable
Surface Tension (dyn/cm or
mN/m)
Not Available
Lower Explosive Limit (%) Not Applicable Volatile Component (%vol) 90
Vapour pressure (kPa) Not Available Gas group Not Available
Solubility in water (g/L) Miscible pH as a solution(1%) Not Available
Vapour density (Air = 1) Not Available VOC g/L Not Available
SECTION 10 STABILITY AND REACTIVITY
Reactivity See section 7
Chemical stability Product is considered stable and hazardous polymerisation will not occur.
Possibility of hazardous
reactions
See section 7
Conditions to avoid See section 7
Incompatible materials See section 7
Hazardous decomposition
products
See section 5
SECTION 11 TOXICOLOGICAL INFORMATION
Information on toxicological effects
Inhaled
Not normally a hazard due to non-volatile nature of product
The material is not thought to produce adverse health effects or irritation of the respiratory tract (as classified by
EC Directives using animal models). Nevertheless, good hygiene practice requires that exposure be kept to a
minimum and that suitable control measures be used in an occupational setting.
Ingestion
Accidental ingestion of the material may be damaging to the health of the individual.
Ingestion may result in nausea, abdominal irritation, pain and vomiting
Skin Contact
Limited evidence exists, or practical experience predicts, that the material either produces inflammation of the
skin in a substantial number of individuals following direct contact, and/or produces significant inflammation when
applied to the healthy intact skin of animals, for up to four hours, such inflammation being present twenty-four
hours or more after the end of the exposure period. Skin irritation may also be present after prolonged or repeated
exposure; this may result in a form of contact dermatitis (nonallergic). The dermatitis is often characterised by
skin redness (erythema) and swelling (oedema) which may progress to blistering (vesiculation), scaling and
thickening of the epidermis. At the microscopic level there may be intercellular oedema of the spongy layer of the
skin (spongiosis) and intracellular oedema of the epidermis.
Eye
Limited evidence exists, or practical experience suggests, that the material may cause eye irritation in a
substantial number of individuals and/or is expected to produce significant ocular lesions which are present
twenty-four hours or more after instillation into the eye(s) of experimental animals. Repeated or prolonged eye
contact may cause inflammation characterised by temporary redness (similar to windburn) of the conjunctiva
(conjunctivitis); temporary impairment of vision and/or other transient eye damage/ulceration may occur.
Chronic
Long-term exposure to the product is not thought to produce chronic effects adverse to health (as classified by
EC Directives using animal models); nevertheless exposure by all routes should be minimised as a matter of
course.
Tracerco T-140c
TOXICITY IRRITATION
Not Available Not Available
Chemwatch: 4886-95
Version No: 2.1.1.1
Page 5 of 7
Tracerco T-140c
Issue Date: 25/02/2014
Print Date: 16/05/2014
Continued...
* Value obtained from manufacturer's msds
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances
Tracerco T-140c Not available.
SODIUM 4-FLUOROBENZOATE
Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This
may be due to a non-allergenic condition known as reactive airways dysfunction syndrome (RADS) which can
occur following exposure to high levels of highly irritating compound. Key criteria for the diagnosis of RADS
include the absence of preceding respiratory disease, in a non-atopic individual, with abrupt onset of persistent
asthma-like symptoms within minutes to hours of a documented exposure to the irritant. A reversible airflow
pattern, on spirometry, with the presence of moderate to severe bronchial hyperreactivity on methacholine
challenge testing and the lack of minimal lymphocytic inflammation, without eosinophilia, have also been
included in the criteria for diagnosis of RADS.
WATER No significant acute toxicological data identified in literature search.
Acute Toxicity Carcinogenicity
Skin Irritation/Corrosion Reproductivity
Serious Eye Damage/Irritation STOT - Single Exposure
Respiratory or Skin
sensitisation
STOT - Repeated Exposure
Mutagenicity Aspiration Hazard
CMR STATUS
Not Applicable
SECTION 12 ECOLOGICAL INFORMATION
Toxicity
DO NOT discharge into sewer or waterways.
Persistence and degradability
Ingredient Persistence: Water/Soil Persistence: Air
Not Available Not Available Not Available
Bioaccumulative potential
Ingredient Bioaccumulation
Not Available Not Available
Mobility in soil
Ingredient Mobility
Not Available Not Available
SECTION 13 DISPOSAL CONSIDERATIONS
Waste treatment methods
Product / Packaging disposal
Recycle wherever possible.
Consult manufacturer for recycling options or consult local or regional waste management authority for
disposal if no suitable treatment or disposal facility can be identified.
Dispose of by: burial in a land-fill specifically licenced to accept chemical and / or pharmaceutical wastes or
incineration in a licenced apparatus (after admixture with suitable combustible material).
Decontaminate empty containers.
SECTION 14 TRANSPORT INFORMATION
Labels Required
Marine Pollutant NO
Chemwatch: 4886-95
Version No: 2.1.1.1
Page 6 of 7
Tracerco T-140c
Issue Date: 25/02/2014
Print Date: 16/05/2014
Continued...
HAZCHEM Not Applicable
Land transport (): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
SECTION 15 REGULATORY INFORMATION
Safety, health and environmental regulations / legislation specific for the substance or mixture
sodium
4-fluorobenzoate(499-90-1) is
found on the following
regulatory lists
water(7732-18-5) is found on the
following regulatory lists
"WHO Model List of Essential Medicines - Adults","Australia Inventory of Chemical Substances (AICS)","OECD
List of High Production Volume (HPV) Chemicals","OSPAR National List of Candidates for Substitution
Norway","IMO IBC Code Chapter 18: List of products to which the Code does not apply","Sigma-AldrichTransport
Information","Australia High Volume Industrial Chemical List (HVICL)","International Fragrance Association (IFRA)
Survey: Transparency List"
SECTION 16 OTHER INFORMATION
Other information
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the
Chemwatch Classification committee using available literature references.
A list of reference resources used to assist the committee may be found at:
www.chemwatch.net/references
The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards
are Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current
or available engineering controls must be considered.
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from CHEMWATCH. TEL (+61 3) 9572 4700.
Chemwatch: 4886-95
Version No: 2.1.1.1
Page 7 of 7
Tracerco T-140c
Issue Date: 25/02/2014
Print Date: 16/05/2014
end of SDS
Tracerco Chemwatch Hazard Alert Code: 1
Tracerco T-158a
Chemwatch: 4886-96
Version No: 2.1.1.1
Safety Data Sheet according to WHS and ADG requirements
Issue Date: 25/02/2014
Print Date: 16/05/2014
Initial Date: Not Available
S.GHS.AUS.EN
SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING
Product Identifier
Product name Tracerco T-158a
Chemical Name Not Applicable
Synonyms Not Available
Proper shipping name Not Applicable
Chemical formula Not Applicable
Other means of identification Not Available
CAS number Not Applicable
Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses Use according to manufacturer's directions.
Details of the supplier of the safety data sheet
Registered company name Tracerco
Address
2 Harris Road Malaga 6090 WA
Australia
Telephone +61 8 9209 3905
Fax +61 8 9209 3725
Website www.tracerco.com
Email admin.aus@tracerco.com
Emergency telephone number
Association / Organisation Not Available
Emergency telephone numbers +61 8 9209 3905 (9am-5pm)
Other emergency telephone
numbers
+61 8 9209 3905 (9am-5pm)
SECTION 2 HAZARDS IDENTIFICATION
Classification of the substance or mixture
NON-HAZARDOUS CHEMICAL. NON-DANGEROUS GOODS. According to the Model WHS Regulations and the ADG Code.
CHEMWATCH HAZARD RATINGS
Max Min
Flammability 0
Toxicity 1

Body Contact 1

Reactivity 0
Chronic 0
0 = Minimum
1 = Low
2 = Moderate
3 = High
4 = Extreme
Poisons Schedule Not Applicable
GHS Classification Not Applicable
Continued...
Label elements
GHS label elements
Not Applicable
SIGNAL WORD NOT APPLICABLE
Hazard statement(s)
Not Applicable
Precautionary statement(s): Prevention
Not Applicable
Precautionary statement(s): Response
Not Applicable
Precautionary statement(s): Storage
Not Applicable
Precautionary statement(s): Disposal
Not Applicable
SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
Substances
See section below for composition of Mixtures
Mixtures
CAS No %[weight] Name
1765-08-8 1-10 sodium 2,4-difluorobenzoate
7732-18-5 >60 water
SECTION 4 FIRST AID MEASURES
Description of first aid measures
Eye Contact
If this product comes in contact with the eyes:
Wash out immediately with fresh running water.
Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids
by occasionally lifting the upper and lower lids.
Seek medical attention without delay; if pain persists or recurs seek medical attention.
Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
Skin Contact
If skin contact occurs:
Immediately remove all contaminated clothing, including footwear.
Flush skin and hair with running water (and soap if available).
Seek medical attention in event of irritation.
Inhalation
If fumes, aerosols or combustion products are inhaled remove from contaminated area.
Other measures are usually unnecessary.
Ingestion
If swallowed do NOT induce vomiting.
If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain
open airway and prevent aspiration.
Observe the patient carefully.
Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming
unconscious.
Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink.
Seek medical advice.
Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5 FIREFIGHTING MEASURES
Extinguishing media
There is no restriction on the type of extinguisher which may be used.
Use extinguishing media suitable for surrounding area.
Chemwatch: 4886-96
Version No: 2.1.1.1
Page 2 of 7
Tracerco T-158a
Issue Date: 25/02/2014
Print Date: 16/05/2014
Continued...
Special hazards arising from the substrate or mixture
Fire Incompatibility None known.
Advice for firefighters
Fire Fighting
Alert Fire Brigade and tell them location and nature of hazard.
Wear breathing apparatus plus protective gloves in the event of a fire.
Prevent, by any means available, spillage from entering drains or water courses.
Use fire fighting procedures suitable for surrounding area.
Fire/Explosion Hazard
Non combustible.
Not considered to be a significant fire risk.
Expansion or decomposition on heating may lead to violent rupture of containers.
Decomposes on heating and may produce toxic fumes of carbon monoxide (CO).
SECTION 6 ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Minor Spills
Clean up all spills immediately.
Avoid breathing vapours and contact with skin and eyes.
Control personal contact with the substance, by using protective equipment.
Contain and absorb spill with sand, earth, inert material or vermiculite.
Major Spills
Minor hazard.
Clear area of personnel.
Alert Fire Brigade and tell them location and nature of hazard.
Control personal contact with the substance, by using protective equipment as required.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
SECTION 7 HANDLING AND STORAGE
Precautions for safe handling
Safe handling
Limit all unnecessary personal contact.
Wear protective clothing when risk of exposure occurs.
Use in a well-ventilated area.
When handling DO NOT eat, drink or smoke.
Other information
Store in original containers.
Keep containers securely sealed.
Store in a cool, dry, well-ventilated area.
Store away from incompatible materials and foodstuff containers.
Conditions for safe storage, including any incompatibilities
Suitable container
Polyethylene or polypropylene container.
Packing as recommended by manufacturer.
Check all containers are clearly labelled and free from leaks.
Storage incompatibility None known
PACKAGE MATERIAL INCOMPATIBILITIES
Not Available
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Control parameters
OCCUPATIONAL EXPOSURE LIMITS (OEL)
INGREDIENT DATA
Not Available
EMERGENCY LIMITS
Ingredient TEEL-0 TEEL-1 TEEL-2 TEEL-3
water 500(ppm) 500(ppm) 500(ppm) 500(ppm)
Chemwatch: 4886-96
Version No: 2.1.1.1
Page 3 of 7
Tracerco T-158a
Issue Date: 25/02/2014
Print Date: 16/05/2014
Continued...
Ingredient Original IDLH Revised IDLH
Tracerco T-158a Not Available Not Available
Exposure controls
Appropriate engineering
controls
General exhaust is adequate under normal operating conditions.
Personal protection
Eye and face protection
Safety glasses with side shields.
Chemical goggles.
Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written
policy document, describing the wearing of lenses or restrictions on use, should be created for each workplace or
task.
Skin protection See Hand protection below
Hand protection
The selection of suitable gloves does not only depend on the material, but also on further marks of quality which
vary from manufacturer to manufacturer. Where the chemical is a preparation of several substances, the
resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the
application.
The exact break through time for substances has to be obtained from the manufacturer of the protective gloves
and.has to be observed when making a final choice.
Suitability and durability of glove type is dependent on usage.
Body protection See Other protection below
Other protection
Overalls.
Eyewash unit.
Thermal hazards Not Available
Recommended material(s)
GLOVE SELECTION INDEX
Glove selection is based on a modified presentation of the:
"Forsberg Clothing Performance Index".
The effect(s) of the following substance(s) are taken into account in the
computer-generated selection:
Tracerco T-158a
Material CPI
BUTYL A
NEOPRENE A
VITON A
* CPI - Chemwatch Performance Index
A: Best Selection
B: Satisfactory; may degrade after 4 hours continuous immersion
C: Poor to Dangerous Choice for other than short term immersion
NOTE: As a series of factors will influence the actual performance of the
glove, a final selection must be based on detailed observation. -
* Where the glove is to be used on a short term, casual or infrequent
basis, factors such as "feel" or convenience (e.g. disposability), may
dictate a choice of gloves which might otherwise be unsuitable following
long-term or frequent use. A qualified practitioner should be consulted.
Respiratory protection
Particulate. (AS/NZS 1716 & 1715, EN 143:000 & 149:001, ANSI Z88 or
national equivalent)
Where the concentration of gas/particulates in the breathing zone,
approaches or exceeds the "Exposure Standard" (or ES), respiratory
protection is required.
Degree of protection varies with both face-piece and Class of filter;
the nature of protection varies with Type of filter.
Required
Minimum
Protection Factor
Half-Face
Respirator
Full-Face
Respirator
Powered Air
Respirator
up to 10 x ES -AUS P2 -
-PAPR-AUS /
Class 1 P2
up to 50 x ES -
-AUS / Class
1 P2
-
up to 100 x ES - -2 P2 -PAPR-2 P2 ^
^ - Full-face
A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 =
Acid gas or hydrogen cyanide(HCN), B3 = Acid gas or hydrogen
cyanide(HCN), E = Sulfur dioxide(SO2), G = Agricultural chemicals,
K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB =
Methyl bromide, AX = Low boiling point organic compounds(below
65 degC)
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Appearance Liquid; mixes with water.
Physical state Liquid Relative density (Water = 1) Not Available
Chemwatch: 4886-96
Version No: 2.1.1.1
Page 4 of 7
Tracerco T-158a
Issue Date: 25/02/2014
Print Date: 16/05/2014
Continued...
Odour Not Available
Partition coefficient n-octanol /
water
Not Available
Odour threshold Not Available Auto-ignition temperature (C) Not Applicable
pH (as supplied) Not Available Decomposition temperature Not Available
Melting point / freezing point
(C)
Not Available Viscosity (cSt) Not Available
Initial boiling point and boiling
range (C)
Not Available Molecular weight (g/mol) Not Applicable
Flash point (C) Not Applicable Taste Not Available
Evaporation rate Not Available Explosive properties Not Available
Flammability Not Applicable Oxidising properties Not Available
Upper Explosive Limit (%) Not Applicable
Surface Tension (dyn/cm or
mN/m)
Not Available
Lower Explosive Limit (%) Not Applicable Volatile Component (%vol) 90
Vapour pressure (kPa) Not Available Gas group Not Available
Solubility in water (g/L) Miscible pH as a solution(1%) Not Available
Vapour density (Air = 1) Not Available VOC g/L Not Available
SECTION 10 STABILITY AND REACTIVITY
Reactivity See section 7
Chemical stability Product is considered stable and hazardous polymerisation will not occur.
Possibility of hazardous
reactions
See section 7
Conditions to avoid See section 7
Incompatible materials See section 7
Hazardous decomposition
products
See section 5
SECTION 11 TOXICOLOGICAL INFORMATION
Information on toxicological effects
Inhaled
Not normally a hazard due to non-volatile nature of product
The material is not thought to produce adverse health effects or irritation of the respiratory tract (as classified by
EC Directives using animal models). Nevertheless, good hygiene practice requires that exposure be kept to a
minimum and that suitable control measures be used in an occupational setting.
Ingestion
Accidental ingestion of the material may be damaging to the health of the individual.
Ingestion may result in nausea, abdominal irritation, pain and vomiting
Skin Contact
Limited evidence exists, or practical experience predicts, that the material either produces inflammation of the
skin in a substantial number of individuals following direct contact, and/or produces significant inflammation when
applied to the healthy intact skin of animals, for up to four hours, such inflammation being present twenty-four
hours or more after the end of the exposure period. Skin irritation may also be present after prolonged or repeated
exposure; this may result in a form of contact dermatitis (nonallergic). The dermatitis is often characterised by
skin redness (erythema) and swelling (oedema) which may progress to blistering (vesiculation), scaling and
thickening of the epidermis. At the microscopic level there may be intercellular oedema of the spongy layer of the
skin (spongiosis) and intracellular oedema of the epidermis.
Eye
Limited evidence exists, or practical experience suggests, that the material may cause eye irritation in a
substantial number of individuals and/or is expected to produce significant ocular lesions which are present
twenty-four hours or more after instillation into the eye(s) of experimental animals. Repeated or prolonged eye
contact may cause inflammation characterised by temporary redness (similar to windburn) of the conjunctiva
(conjunctivitis); temporary impairment of vision and/or other transient eye damage/ulceration may occur.
Chronic
Long-term exposure to the product is not thought to produce chronic effects adverse to health (as classified by
EC Directives using animal models); nevertheless exposure by all routes should be minimised as a matter of
course.
Tracerco T-158a
TOXICITY IRRITATION
Not Available Not Available
Chemwatch: 4886-96
Version No: 2.1.1.1
Page 5 of 7
Tracerco T-158a
Issue Date: 25/02/2014
Print Date: 16/05/2014
Continued...
* Value obtained from manufacturer's msds
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances
Tracerco T-158a Not available.
SODIUM
2,4-DIFLUOROBENZOATE
Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This
may be due to a non-allergenic condition known as reactive airways dysfunction syndrome (RADS) which can
occur following exposure to high levels of highly irritating compound. Key criteria for the diagnosis of RADS
include the absence of preceding respiratory disease, in a non-atopic individual, with abrupt onset of persistent
asthma-like symptoms within minutes to hours of a documented exposure to the irritant. A reversible airflow
pattern, on spirometry, with the presence of moderate to severe bronchial hyperreactivity on methacholine
challenge testing and the lack of minimal lymphocytic inflammation, without eosinophilia, have also been
included in the criteria for diagnosis of RADS.
WATER No significant acute toxicological data identified in literature search.
Acute Toxicity Carcinogenicity
Skin Irritation/Corrosion Reproductivity
Serious Eye Damage/Irritation STOT - Single Exposure
Respiratory or Skin
sensitisation
STOT - Repeated Exposure
Mutagenicity Aspiration Hazard
CMR STATUS
Not Applicable
SECTION 12 ECOLOGICAL INFORMATION
Toxicity
DO NOT discharge into sewer or waterways.
Persistence and degradability
Ingredient Persistence: Water/Soil Persistence: Air
Not Available Not Available Not Available
Bioaccumulative potential
Ingredient Bioaccumulation
Not Available Not Available
Mobility in soil
Ingredient Mobility
Not Available Not Available
SECTION 13 DISPOSAL CONSIDERATIONS
Waste treatment methods
Product / Packaging disposal
Recycle wherever possible.
Consult manufacturer for recycling options or consult local or regional waste management authority for
disposal if no suitable treatment or disposal facility can be identified.
Dispose of by: burial in a land-fill specifically licenced to accept chemical and / or pharmaceutical wastes or
incineration in a licenced apparatus (after admixture with suitable combustible material).
Decontaminate empty containers.
SECTION 14 TRANSPORT INFORMATION
Labels Required
Marine Pollutant NO
Chemwatch: 4886-96
Version No: 2.1.1.1
Page 6 of 7
Tracerco T-158a
Issue Date: 25/02/2014
Print Date: 16/05/2014
Continued...
HAZCHEM Not Applicable
Land transport (): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
SECTION 15 REGULATORY INFORMATION
Safety, health and environmental regulations / legislation specific for the substance or mixture
sodium
2,4-difluorobenzoate(1765-08-8)
is found on the following
regulatory lists
water(7732-18-5) is found on the
following regulatory lists
"WHO Model List of Essential Medicines - Adults","Australia Inventory of Chemical Substances (AICS)","OECD
List of High Production Volume (HPV) Chemicals","OSPAR National List of Candidates for Substitution
Norway","IMO IBC Code Chapter 18: List of products to which the Code does not apply","Sigma-AldrichTransport
Information","Australia High Volume Industrial Chemical List (HVICL)","International Fragrance Association (IFRA)
Survey: Transparency List"
SECTION 16 OTHER INFORMATION
Other information
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the
Chemwatch Classification committee using available literature references.
A list of reference resources used to assist the committee may be found at:
www.chemwatch.net/references
The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards
are Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current
or available engineering controls must be considered.
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from CHEMWATCH. TEL (+61 3) 9572 4700.
Chemwatch: 4886-96
Version No: 2.1.1.1
Page 7 of 7
Tracerco T-158a
Issue Date: 25/02/2014
Print Date: 16/05/2014
end of SDS
Tracerco Chemwatch Hazard Alert Code: 2
Tracerco T-158b
Chemwatch: 4886-97
Version No: 2.1.1.1
Safety Data Sheet according to WHS and ADG requirements
Issue Date: 25/02/2014
Print Date: 16/05/2014
Initial Date: Not Available
S.GHS.AUS.EN
SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING
Product Identifier
Product name Tracerco T-158b
Chemical Name Not Applicable
Synonyms Not Available
Proper shipping name Not Applicable
Chemical formula Not Applicable
Other means of identification Not Available
CAS number Not Applicable
Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses Use according to manufacturer's directions.
Details of the supplier of the safety data sheet
Registered company name Tracerco
Address
2 Harris Road Malaga 6090 WA
Australia
Telephone +61 8 9209 3905
Fax +61 8 9209 3725
Website www.tracerco.com
Email admin.aus@tracerco.com
Emergency telephone number
Association / Organisation Not Available
Emergency telephone numbers +61 8 9209 3905 (9am-5pm)
Other emergency telephone
numbers
+61 8 9209 3905 (9am-5pm)
SECTION 2 HAZARDS IDENTIFICATION
Classification of the substance or mixture
HAZARDOUS CHEMICAL. NON-DANGEROUS GOODS. According to the Model WHS Regulations and the ADG Code.
CHEMWATCH HAZARD RATINGS
Max Min
Flammability 0
Toxicity 2

Body Contact 2

Reactivity 0
Chronic 0
0 = Minimum
1 = Low
2 = Moderate
3 = High
4 = Extreme
Poisons Schedule Not Applicable
GHS Classification
[1]
Acute Toxicity (Oral) Category 4, Acute Toxicity (Inhalation) Category 4, Skin Corrosion/Irritation Category 2, Eye
Irrit. 2, STOT - SE (Resp. Irr.) Category 3
Continued...
Legend:
1. Classified by Chemwatch; 2. Classification drawn from HSIS ; 3. Classification drawn from EC Directive
1272/2008 - Annex VI
Label elements
GHS label elements
SIGNAL WORD WARNING
Hazard statement(s)
H302 Harmful if swallowed
H332 Harmful if inhaled
H315 Causes skin irritation
H319 Causes serious eye irritation
H335 May cause respiratory irritation
Precautionary statement(s): Prevention
P271 Use only outdoors or in a well-ventilated area.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Precautionary statement(s): Response
P321 Specific treatment (see advice on this label).
P305+P351+P338
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/attention.
P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor/physician/first aider/if you feel unwell.
Precautionary statement(s): Storage
P405 Store locked up.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
Precautionary statement(s): Disposal
P501 Dispose of contents/container to authorised chemical landfill or if organic to high temperature incineration
SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
Substances
See section below for composition of Mixtures
Mixtures
CAS No %[weight] Name
522651-42-9 10-30 sodium 2,5-difluorobenzoate
7732-18-5 >60 water
SECTION 4 FIRST AID MEASURES
Description of first aid measures
Eye Contact
If this product comes in contact with the eyes:
Wash out immediately with fresh running water.
Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids
by occasionally lifting the upper and lower lids.
Seek medical attention without delay; if pain persists or recurs seek medical attention.
Chemwatch: 4886-97
Version No: 2.1.1.1
Page 2 of 8
Tracerco T-158b
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Continued...
Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
Skin Contact
If skin contact occurs:
Immediately remove all contaminated clothing, including footwear.
Flush skin and hair with running water (and soap if available).
Seek medical attention in event of irritation.
Inhalation
If fumes, aerosols or combustion products are inhaled remove from contaminated area.
Other measures are usually unnecessary.
Ingestion
If swallowed do NOT induce vomiting.
If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain
open airway and prevent aspiration.
Observe the patient carefully.
Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming
unconscious.
Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink.
Seek medical advice.
Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5 FIREFIGHTING MEASURES
Extinguishing media
There is no restriction on the type of extinguisher which may be used.
Use extinguishing media suitable for surrounding area.
Special hazards arising from the substrate or mixture
Fire Incompatibility None known.
Advice for firefighters
Fire Fighting
Alert Fire Brigade and tell them location and nature of hazard.
Wear breathing apparatus plus protective gloves in the event of a fire.
Prevent, by any means available, spillage from entering drains or water courses.
Use fire fighting procedures suitable for surrounding area.
Fire/Explosion Hazard
Non combustible.
Not considered to be a significant fire risk.
Expansion or decomposition on heating may lead to violent rupture of containers.
Decomposes on heating and may produce toxic fumes of carbon monoxide (CO).
SECTION 6 ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Minor Spills
Clean up all spills immediately.
Avoid breathing vapours and contact with skin and eyes.
Control personal contact with the substance, by using protective equipment.
Contain and absorb spill with sand, earth, inert material or vermiculite.
Major Spills
Minor hazard.
Clear area of personnel.
Alert Fire Brigade and tell them location and nature of hazard.
Control personal contact with the substance, by using protective equipment as required.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
SECTION 7 HANDLING AND STORAGE
Precautions for safe handling
Safe handling
Limit all unnecessary personal contact.
Wear protective clothing when risk of exposure occurs.
Use in a well-ventilated area.
When handling DO NOT eat, drink or smoke.
Chemwatch: 4886-97
Version No: 2.1.1.1
Page 3 of 8
Tracerco T-158b
Issue Date: 25/02/2014
Print Date: 16/05/2014
Continued...
Other information
Store in original containers.
Keep containers securely sealed.
Store in a cool, dry, well-ventilated area.
Store away from incompatible materials and foodstuff containers.
Conditions for safe storage, including any incompatibilities
Suitable container
Polyethylene or polypropylene container.
Packing as recommended by manufacturer.
Check all containers are clearly labelled and free from leaks.
Storage incompatibility None known
PACKAGE MATERIAL INCOMPATIBILITIES
Not Available
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Control parameters
OCCUPATIONAL EXPOSURE LIMITS (OEL)
INGREDIENT DATA
Not Available
EMERGENCY LIMITS
Ingredient TEEL-0 TEEL-1 TEEL-2 TEEL-3
water 500(ppm) 500(ppm) 500(ppm) 500(ppm)
Ingredient Original IDLH Revised IDLH
Tracerco T-158b Not Available Not Available
Exposure controls
Appropriate engineering
controls
General exhaust is adequate under normal operating conditions.
Personal protection
Eye and face protection
Safety glasses with side shields.
Chemical goggles.
Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written
policy document, describing the wearing of lenses or restrictions on use, should be created for each workplace or
task.
Skin protection See Hand protection below
Hand protection
The selection of suitable gloves does not only depend on the material, but also on further marks of quality which
vary from manufacturer to manufacturer. Where the chemical is a preparation of several substances, the
resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the
application.
The exact break through time for substances has to be obtained from the manufacturer of the protective gloves
and.has to be observed when making a final choice.
Suitability and durability of glove type is dependent on usage.
Body protection See Other protection below
Other protection
Overalls.
Eyewash unit.
Thermal hazards Not Available
Recommended material(s)
GLOVE SELECTION INDEX
Glove selection is based on a modified presentation of the:
"Forsberg Clothing Performance Index".
The effect(s) of the following substance(s) are taken into account in the
computer-generated selection:
Respiratory protection
Particulate. (AS/NZS 1716 & 1715, EN 143:000 & 149:001, ANSI Z88 or
national equivalent)
Where the concentration of gas/particulates in the breathing zone,
approaches or exceeds the "Exposure Standard" (or ES), respiratory
Chemwatch: 4886-97
Version No: 2.1.1.1
Page 4 of 8
Tracerco T-158b
Issue Date: 25/02/2014
Print Date: 16/05/2014
Continued...
Tracerco T-158b
Material CPI
BUTYL A
NEOPRENE A
VITON A
* CPI - Chemwatch Performance Index
A: Best Selection
B: Satisfactory; may degrade after 4 hours continuous immersion
C: Poor to Dangerous Choice for other than short term immersion
NOTE: As a series of factors will influence the actual performance of the
glove, a final selection must be based on detailed observation. -
* Where the glove is to be used on a short term, casual or infrequent
basis, factors such as "feel" or convenience (e.g. disposability), may
dictate a choice of gloves which might otherwise be unsuitable following
long-term or frequent use. A qualified practitioner should be consulted.
protection is required.
Degree of protection varies with both face-piece and Class of filter;
the nature of protection varies with Type of filter.
Required
Minimum
Protection Factor
Half-Face
Respirator
Full-Face
Respirator
Powered Air
Respirator
up to 10 x ES -AUS P2 -
-PAPR-AUS /
Class 1 P2
up to 50 x ES -
-AUS / Class
1 P2
-
up to 100 x ES - -2 P2 -PAPR-2 P2 ^
^ - Full-face
A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 =
Acid gas or hydrogen cyanide(HCN), B3 = Acid gas or hydrogen
cyanide(HCN), E = Sulfur dioxide(SO2), G = Agricultural chemicals,
K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB =
Methyl bromide, AX = Low boiling point organic compounds(below
65 degC)
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Appearance Liquid; mixes with water.
Physical state Liquid Relative density (Water = 1) Not Available
Odour Not Available
Partition coefficient n-octanol /
water
Not Available
Odour threshold Not Available Auto-ignition temperature (C) Not Applicable
pH (as supplied) Not Available Decomposition temperature Not Available
Melting point / freezing point
(C)
Not Available Viscosity (cSt) Not Available
Initial boiling point and boiling
range (C)
Not Available Molecular weight (g/mol) Not Applicable
Flash point (C) Not Applicable Taste Not Available
Evaporation rate Not Available Explosive properties Not Available
Flammability Not Applicable Oxidising properties Not Available
Upper Explosive Limit (%) Not Applicable
Surface Tension (dyn/cm or
mN/m)
Not Available
Lower Explosive Limit (%) Not Applicable Volatile Component (%vol) 80
Vapour pressure (kPa) Not Available Gas group Not Available
Solubility in water (g/L) Miscible pH as a solution(1%) Not Available
Vapour density (Air = 1) Not Available VOC g/L Not Available
SECTION 10 STABILITY AND REACTIVITY
Reactivity See section 7
Chemical stability Product is considered stable and hazardous polymerisation will not occur.
Possibility of hazardous
reactions
See section 7
Conditions to avoid See section 7
Incompatible materials See section 7
Hazardous decomposition
products
See section 5
SECTION 11 TOXICOLOGICAL INFORMATION
Chemwatch: 4886-97
Version No: 2.1.1.1
Page 5 of 8
Tracerco T-158b
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Print Date: 16/05/2014
Continued...
Information on toxicological effects
Inhaled
Evidence shows, or practical experience predicts, that the material produces irritation of the respiratory system, in
a substantial number of individuals, following inhalation. In contrast to most organs, the lung is able to respond to
a chemical insult by first removing or neutralising the irritant and then repairing the damage. The repair process,
which initially evolved to protect mammalian lungs from foreign matter and antigens, may however, produce
further lung damage resulting in the impairment of gas exchange, the primary function of the lungs. Respiratory
tract irritation often results in an inflammatory response involving the recruitment and activation of many cell
types, mainly derived from the vascular system.
Ingestion
Accidental ingestion of the material may be damaging to the health of the individual.
Ingestion may result in nausea, abdominal irritation, pain and vomiting
Skin Contact
Evidence exists, or practical experience predicts, that the material either produces inflammation of the skin in a
substantial number of individuals following direct contact, and/or produces significant inflammation when applied to
the healthy intact skin of animals, for up to four hours, such inflammation being present twenty-four hours or
more after the end of the exposure period. Skin irritation may also be present after prolonged or repeated
exposure; this may result in a form of contact dermatitis (nonallergic). The dermatitis is often characterised by
skin redness (erythema) and swelling (oedema) which may progress to blistering (vesiculation), scaling and
thickening of the epidermis. At the microscopic level there may be intercellular oedema of the spongy layer of the
skin (spongiosis) and intracellular oedema of the epidermis.
Eye
Evidence exists, or practical experience predicts, that the material may cause eye irritation in a substantial
number of individuals and/or may produce significant ocular lesions which are present twenty-four hours or more
after instillation into the eye(s) of experimental animals.
Repeated or prolonged eye contact may cause inflammation characterised by temporary redness (similar to
windburn) of the conjunctiva (conjunctivitis); temporary impairment of vision and/or other transient eye
damage/ulceration may occur.
Chronic
Long-term exposure to respiratory irritants may result in disease of the airways involving difficult breathing and
related systemic problems.
Tracerco T-158b
TOXICITY IRRITATION
Not Available Not Available
sodium 2,5-difluorobenzoate
TOXICITY IRRITATION
Not Available Not Available
water
TOXICITY IRRITATION
Not Available Not Available
* Value obtained from manufacturer's msds
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances
Tracerco T-158b Not available.
SODIUM
2,5-DIFLUOROBENZOATE
Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This
may be due to a non-allergenic condition known as reactive airways dysfunction syndrome (RADS) which can
occur following exposure to high levels of highly irritating compound. Key criteria for the diagnosis of RADS
include the absence of preceding respiratory disease, in a non-atopic individual, with abrupt onset of persistent
asthma-like symptoms within minutes to hours of a documented exposure to the irritant. A reversible airflow
pattern, on spirometry, with the presence of moderate to severe bronchial hyperreactivity on methacholine
challenge testing and the lack of minimal lymphocytic inflammation, without eosinophilia, have also been
included in the criteria for diagnosis of RADS.
WATER No significant acute toxicological data identified in literature search.
Acute Toxicity Carcinogenicity
Skin Irritation/Corrosion Reproductivity
Serious Eye Damage/Irritation STOT - Single Exposure
Respiratory or Skin
sensitisation
STOT - Repeated Exposure
Mutagenicity Aspiration Hazard
Chemwatch: 4886-97
Version No: 2.1.1.1
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Tracerco T-158b
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Print Date: 16/05/2014
Continued...
CMR STATUS
Not Applicable
SECTION 12 ECOLOGICAL INFORMATION
Toxicity
DO NOT discharge into sewer or waterways.
Persistence and degradability
Ingredient Persistence: Water/Soil Persistence: Air
Not Available Not Available Not Available
Bioaccumulative potential
Ingredient Bioaccumulation
Not Available Not Available
Mobility in soil
Ingredient Mobility
Not Available Not Available
SECTION 13 DISPOSAL CONSIDERATIONS
Waste treatment methods
Product / Packaging disposal
Recycle wherever possible.
Consult manufacturer for recycling options or consult local or regional waste management authority for
disposal if no suitable treatment or disposal facility can be identified.
Dispose of by: burial in a land-fill specifically licenced to accept chemical and / or pharmaceutical wastes or
incineration in a licenced apparatus (after admixture with suitable combustible material).
Decontaminate empty containers.
SECTION 14 TRANSPORT INFORMATION
Labels Required
Marine Pollutant NO
HAZCHEM Not Applicable
Land transport (): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
SECTION 15 REGULATORY INFORMATION
Safety, health and environmental regulations / legislation specific for the substance or mixture
sodium
2,5-difluorobenzoate(522651-42-9)
is found on the following
regulatory lists
water(7732-18-5) is found on the
following regulatory lists
"WHO Model List of Essential Medicines - Adults","Australia Inventory of Chemical Substances (AICS)","OECD
List of High Production Volume (HPV) Chemicals","OSPAR National List of Candidates for Substitution
Norway","IMO IBC Code Chapter 18: List of products to which the Code does not apply","Sigma-AldrichTransport
Information","Australia High Volume Industrial Chemical List (HVICL)","International Fragrance Association (IFRA)
Survey: Transparency List"
SECTION 16 OTHER INFORMATION
Other information
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the
Chemwatch: 4886-97
Version No: 2.1.1.1
Page 7 of 8
Tracerco T-158b
Issue Date: 25/02/2014
Print Date: 16/05/2014
Continued...
Chemwatch Classification committee using available literature references.
A list of reference resources used to assist the committee may be found at:
www.chemwatch.net/references
The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards
are Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current
or available engineering controls must be considered.
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from CHEMWATCH. TEL (+61 3) 9572 4700.
Chemwatch: 4886-97
Version No: 2.1.1.1
Page 8 of 8
Tracerco T-158b
Issue Date: 25/02/2014
Print Date: 16/05/2014
end of SDS
Tracerco Chemwatch Hazard Alert Code: 2
Tracerco T-158c
Chemwatch: 4886-98
Version No: 2.1.1.1
Safety Data Sheet according to WHS and ADG requirements
Issue Date: 25/02/2014
Print Date: 16/05/2014
Initial Date: Not Available
S.GHS.AUS.EN
SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING
Product Identifier
Product name Tracerco T-158c
Chemical Name Not Applicable
Synonyms Not Available
Proper shipping name Not Applicable
Chemical formula Not Applicable
Other means of identification Not Available
CAS number Not Applicable
Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses Use according to manufacturer's directions.
Details of the supplier of the safety data sheet
Registered company name Tracerco
Address
2 Harris Road Malaga 6090 WA
Australia
Telephone +61 8 9209 3905
Fax +61 8 9209 3725
Website www.tracerco.com
Email admin.aus@tracerco.com
Emergency telephone number
Association / Organisation Not Available
Emergency telephone numbers +61 8 9209 3905 (9am-5pm)
Other emergency telephone
numbers
+61 8 9209 3905 (9am-5pm)
SECTION 2 HAZARDS IDENTIFICATION
Classification of the substance or mixture
HAZARDOUS CHEMICAL. NON-DANGEROUS GOODS. According to the Model WHS Regulations and the ADG Code.
CHEMWATCH HAZARD RATINGS
Max Min
Flammability 0
Toxicity 2

Body Contact 2

Reactivity 0
Chronic 0
0 = Minimum
1 = Low
2 = Moderate
3 = High
4 = Extreme
Poisons Schedule Not Applicable
GHS Classification
[1]
Acute Toxicity (Oral) Category 4, Acute Toxicity (Inhalation) Category 4, Skin Corrosion/Irritation Category 2, Eye
Irrit. 2, STOT - SE (Resp. Irr.) Category 3
Continued...
Legend:
1. Classified by Chemwatch; 2. Classification drawn from HSIS ; 3. Classification drawn from EC Directive
1272/2008 - Annex VI
Label elements
GHS label elements
SIGNAL WORD WARNING
Hazard statement(s)
H302 Harmful if swallowed
H332 Harmful if inhaled
H315 Causes skin irritation
H319 Causes serious eye irritation
H335 May cause respiratory irritation
Precautionary statement(s): Prevention
P271 Use only outdoors or in a well-ventilated area.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Precautionary statement(s): Response
P321 Specific treatment (see advice on this label).
P305+P351+P338
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/attention.
P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor/physician/first aider/if you feel unwell.
Precautionary statement(s): Storage
P405 Store locked up.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
Precautionary statement(s): Disposal
P501 Dispose of contents/container to authorised chemical landfill or if organic to high temperature incineration
SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
Substances
See section below for composition of Mixtures
Mixtures
CAS No %[weight] Name
6185-28-0 10-30 sodium 2,6-difluorobenzoate
7732-18-5 >60 water
SECTION 4 FIRST AID MEASURES
Description of first aid measures
Eye Contact
If this product comes in contact with the eyes:
Wash out immediately with fresh running water.
Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids
by occasionally lifting the upper and lower lids.
Seek medical attention without delay; if pain persists or recurs seek medical attention.
Chemwatch: 4886-98
Version No: 2.1.1.1
Page 2 of 8
Tracerco T-158c
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Print Date: 16/05/2014
Continued...
Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
Skin Contact
If skin contact occurs:
Immediately remove all contaminated clothing, including footwear.
Flush skin and hair with running water (and soap if available).
Seek medical attention in event of irritation.
Inhalation
If fumes, aerosols or combustion products are inhaled remove from contaminated area.
Other measures are usually unnecessary.
Ingestion
If swallowed do NOT induce vomiting.
If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain
open airway and prevent aspiration.
Observe the patient carefully.
Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming
unconscious.
Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink.
Seek medical advice.
Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5 FIREFIGHTING MEASURES
Extinguishing media
There is no restriction on the type of extinguisher which may be used.
Use extinguishing media suitable for surrounding area.
Special hazards arising from the substrate or mixture
Fire Incompatibility None known.
Advice for firefighters
Fire Fighting
Alert Fire Brigade and tell them location and nature of hazard.
Wear breathing apparatus plus protective gloves in the event of a fire.
Prevent, by any means available, spillage from entering drains or water courses.
Use fire fighting procedures suitable for surrounding area.
Fire/Explosion Hazard
Non combustible.
Not considered to be a significant fire risk.
Expansion or decomposition on heating may lead to violent rupture of containers.
Decomposes on heating and may produce toxic fumes of carbon monoxide (CO).
SECTION 6 ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Minor Spills
Clean up all spills immediately.
Avoid breathing vapours and contact with skin and eyes.
Control personal contact with the substance, by using protective equipment.
Contain and absorb spill with sand, earth, inert material or vermiculite.
Major Spills
Minor hazard.
Clear area of personnel.
Alert Fire Brigade and tell them location and nature of hazard.
Control personal contact with the substance, by using protective equipment as required.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
SECTION 7 HANDLING AND STORAGE
Precautions for safe handling
Safe handling
Limit all unnecessary personal contact.
Wear protective clothing when risk of exposure occurs.
Use in a well-ventilated area.
When handling DO NOT eat, drink or smoke.
Chemwatch: 4886-98
Version No: 2.1.1.1
Page 3 of 8
Tracerco T-158c
Issue Date: 25/02/2014
Print Date: 16/05/2014
Continued...
Other information
Store in original containers.
Keep containers securely sealed.
Store in a cool, dry, well-ventilated area.
Store away from incompatible materials and foodstuff containers.
Conditions for safe storage, including any incompatibilities
Suitable container
Polyethylene or polypropylene container.
Packing as recommended by manufacturer.
Check all containers are clearly labelled and free from leaks.
Storage incompatibility None known
PACKAGE MATERIAL INCOMPATIBILITIES
Not Available
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Control parameters
OCCUPATIONAL EXPOSURE LIMITS (OEL)
INGREDIENT DATA
Not Available
EMERGENCY LIMITS
Ingredient TEEL-0 TEEL-1 TEEL-2 TEEL-3
water 500(ppm) 500(ppm) 500(ppm) 500(ppm)
Ingredient Original IDLH Revised IDLH
Tracerco T-158c Not Available Not Available
Exposure controls
Appropriate engineering
controls
General exhaust is adequate under normal operating conditions.
Personal protection
Eye and face protection
Safety glasses with side shields.
Chemical goggles.
Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written
policy document, describing the wearing of lenses or restrictions on use, should be created for each workplace or
task.
Skin protection See Hand protection below
Hand protection
The selection of suitable gloves does not only depend on the material, but also on further marks of quality which
vary from manufacturer to manufacturer. Where the chemical is a preparation of several substances, the
resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the
application.
The exact break through time for substances has to be obtained from the manufacturer of the protective gloves
and.has to be observed when making a final choice.
Suitability and durability of glove type is dependent on usage.
Body protection See Other protection below
Other protection
Overalls.
Eyewash unit.
Thermal hazards Not Available
Recommended material(s)
GLOVE SELECTION INDEX
Glove selection is based on a modified presentation of the:
"Forsberg Clothing Performance Index".
The effect(s) of the following substance(s) are taken into account in the
computer-generated selection:
Respiratory protection
Particulate. (AS/NZS 1716 & 1715, EN 143:000 & 149:001, ANSI Z88 or
national equivalent)
Where the concentration of gas/particulates in the breathing zone,
approaches or exceeds the "Exposure Standard" (or ES), respiratory
Chemwatch: 4886-98
Version No: 2.1.1.1
Page 4 of 8
Tracerco T-158c
Issue Date: 25/02/2014
Print Date: 16/05/2014
Continued...
Tracerco T-158c
Material CPI
BUTYL A
NEOPRENE A
VITON A
* CPI - Chemwatch Performance Index
A: Best Selection
B: Satisfactory; may degrade after 4 hours continuous immersion
C: Poor to Dangerous Choice for other than short term immersion
NOTE: As a series of factors will influence the actual performance of the
glove, a final selection must be based on detailed observation. -
* Where the glove is to be used on a short term, casual or infrequent
basis, factors such as "feel" or convenience (e.g. disposability), may
dictate a choice of gloves which might otherwise be unsuitable following
long-term or frequent use. A qualified practitioner should be consulted.
protection is required.
Degree of protection varies with both face-piece and Class of filter;
the nature of protection varies with Type of filter.
Required
Minimum
Protection Factor
Half-Face
Respirator
Full-Face
Respirator
Powered Air
Respirator
up to 10 x ES -AUS P2 -
-PAPR-AUS /
Class 1 P2
up to 50 x ES -
-AUS / Class
1 P2
-
up to 100 x ES - -2 P2 -PAPR-2 P2 ^
^ - Full-face
A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 =
Acid gas or hydrogen cyanide(HCN), B3 = Acid gas or hydrogen
cyanide(HCN), E = Sulfur dioxide(SO2), G = Agricultural chemicals,
K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB =
Methyl bromide, AX = Low boiling point organic compounds(below
65 degC)
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Appearance Liquid; mixes with water.
Physical state Liquid Relative density (Water = 1) Not Available
Odour Not Available
Partition coefficient n-octanol /
water
Not Available
Odour threshold Not Available Auto-ignition temperature (C) Not Applicable
pH (as supplied) Not Available Decomposition temperature Not Available
Melting point / freezing point
(C)
Not Available Viscosity (cSt) Not Available
Initial boiling point and boiling
range (C)
Not Available Molecular weight (g/mol) Not Applicable
Flash point (C) Not Applicable Taste Not Available
Evaporation rate Not Available Explosive properties Not Available
Flammability Not Applicable Oxidising properties Not Available
Upper Explosive Limit (%) Not Applicable
Surface Tension (dyn/cm or
mN/m)
Not Available
Lower Explosive Limit (%) Not Applicable Volatile Component (%vol) 80
Vapour pressure (kPa) Not Available Gas group Not Available
Solubility in water (g/L) Miscible pH as a solution(1%) Not Available
Vapour density (Air = 1) Not Available VOC g/L Not Available
SECTION 10 STABILITY AND REACTIVITY
Reactivity See section 7
Chemical stability Product is considered stable and hazardous polymerisation will not occur.
Possibility of hazardous
reactions
See section 7
Conditions to avoid See section 7
Incompatible materials See section 7
Hazardous decomposition
products
See section 5
SECTION 11 TOXICOLOGICAL INFORMATION
Chemwatch: 4886-98
Version No: 2.1.1.1
Page 5 of 8
Tracerco T-158c
Issue Date: 25/02/2014
Print Date: 16/05/2014
Continued...
Information on toxicological effects
Inhaled
Evidence shows, or practical experience predicts, that the material produces irritation of the respiratory system, in
a substantial number of individuals, following inhalation. In contrast to most organs, the lung is able to respond to
a chemical insult by first removing or neutralising the irritant and then repairing the damage. The repair process,
which initially evolved to protect mammalian lungs from foreign matter and antigens, may however, produce
further lung damage resulting in the impairment of gas exchange, the primary function of the lungs. Respiratory
tract irritation often results in an inflammatory response involving the recruitment and activation of many cell
types, mainly derived from the vascular system.
Ingestion
Accidental ingestion of the material may be damaging to the health of the individual.
Ingestion may result in nausea, abdominal irritation, pain and vomiting
Skin Contact
Evidence exists, or practical experience predicts, that the material either produces inflammation of the skin in a
substantial number of individuals following direct contact, and/or produces significant inflammation when applied to
the healthy intact skin of animals, for up to four hours, such inflammation being present twenty-four hours or
more after the end of the exposure period. Skin irritation may also be present after prolonged or repeated
exposure; this may result in a form of contact dermatitis (nonallergic). The dermatitis is often characterised by
skin redness (erythema) and swelling (oedema) which may progress to blistering (vesiculation), scaling and
thickening of the epidermis. At the microscopic level there may be intercellular oedema of the spongy layer of the
skin (spongiosis) and intracellular oedema of the epidermis.
Eye
Evidence exists, or practical experience predicts, that the material may cause eye irritation in a substantial
number of individuals and/or may produce significant ocular lesions which are present twenty-four hours or more
after instillation into the eye(s) of experimental animals.
Repeated or prolonged eye contact may cause inflammation characterised by temporary redness (similar to
windburn) of the conjunctiva (conjunctivitis); temporary impairment of vision and/or other transient eye
damage/ulceration may occur.
Chronic
Long-term exposure to respiratory irritants may result in disease of the airways involving difficult breathing and
related systemic problems.
Tracerco T-158c
TOXICITY IRRITATION
Not Available Not Available
sodium 2,6-difluorobenzoate
TOXICITY IRRITATION
Not Available Not Available
water
TOXICITY IRRITATION
Not Available Not Available
* Value obtained from manufacturer's msds
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances
Tracerco T-158c Not available.
SODIUM
2,6-DIFLUOROBENZOATE
Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This
may be due to a non-allergenic condition known as reactive airways dysfunction syndrome (RADS) which can
occur following exposure to high levels of highly irritating compound. Key criteria for the diagnosis of RADS
include the absence of preceding respiratory disease, in a non-atopic individual, with abrupt onset of persistent
asthma-like symptoms within minutes to hours of a documented exposure to the irritant. A reversible airflow
pattern, on spirometry, with the presence of moderate to severe bronchial hyperreactivity on methacholine
challenge testing and the lack of minimal lymphocytic inflammation, without eosinophilia, have also been
included in the criteria for diagnosis of RADS.
WATER No significant acute toxicological data identified in literature search.
Acute Toxicity Carcinogenicity
Skin Irritation/Corrosion Reproductivity
Serious Eye Damage/Irritation STOT - Single Exposure
Respiratory or Skin
sensitisation
STOT - Repeated Exposure
Mutagenicity Aspiration Hazard
Chemwatch: 4886-98
Version No: 2.1.1.1
Page 6 of 8
Tracerco T-158c
Issue Date: 25/02/2014
Print Date: 16/05/2014
Continued...
CMR STATUS
Not Applicable
SECTION 12 ECOLOGICAL INFORMATION
Toxicity
DO NOT discharge into sewer or waterways.
Persistence and degradability
Ingredient Persistence: Water/Soil Persistence: Air
Not Available Not Available Not Available
Bioaccumulative potential
Ingredient Bioaccumulation
Not Available Not Available
Mobility in soil
Ingredient Mobility
Not Available Not Available
SECTION 13 DISPOSAL CONSIDERATIONS
Waste treatment methods
Product / Packaging disposal
Recycle wherever possible.
Consult manufacturer for recycling options or consult local or regional waste management authority for
disposal if no suitable treatment or disposal facility can be identified.
Dispose of by: burial in a land-fill specifically licenced to accept chemical and / or pharmaceutical wastes or
incineration in a licenced apparatus (after admixture with suitable combustible material).
Decontaminate empty containers.
SECTION 14 TRANSPORT INFORMATION
Labels Required
Marine Pollutant NO
HAZCHEM Not Applicable
Land transport (): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
SECTION 15 REGULATORY INFORMATION
Safety, health and environmental regulations / legislation specific for the substance or mixture
sodium
2,6-difluorobenzoate(6185-28-0)
is found on the following
regulatory lists
water(7732-18-5) is found on the
following regulatory lists
"WHO Model List of Essential Medicines - Adults","Australia Inventory of Chemical Substances (AICS)","OECD
List of High Production Volume (HPV) Chemicals","OSPAR National List of Candidates for Substitution
Norway","IMO IBC Code Chapter 18: List of products to which the Code does not apply","Sigma-AldrichTransport
Information","Australia High Volume Industrial Chemical List (HVICL)","International Fragrance Association (IFRA)
Survey: Transparency List"
SECTION 16 OTHER INFORMATION
Other information
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the
Chemwatch: 4886-98
Version No: 2.1.1.1
Page 7 of 8
Tracerco T-158c
Issue Date: 25/02/2014
Print Date: 16/05/2014
Continued...
Chemwatch Classification committee using available literature references.
A list of reference resources used to assist the committee may be found at:
www.chemwatch.net/references
The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards
are Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current
or available engineering controls must be considered.
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from CHEMWATCH. TEL (+61 3) 9572 4700.
Chemwatch: 4886-98
Version No: 2.1.1.1
Page 8 of 8
Tracerco T-158c
Issue Date: 25/02/2014
Print Date: 16/05/2014
end of SDS
Tracerco Chemwatch Hazard Alert Code: 2
Tracerco T-158d
Chemwatch: 4886-99
Version No: 2.1.1.1
Safety Data Sheet according to WHS and ADG requirements
Issue Date: 25/02/2014
Print Date: 16/05/2014
Initial Date: Not Available
S.GHS.AUS.EN
SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING
Product Identifier
Product name Tracerco T-158d
Chemical Name Not Applicable
Synonyms Not Available
Proper shipping name Not Applicable
Chemical formula Not Applicable
Other means of identification Not Available
CAS number Not Applicable
Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses Use according to manufacturer's directions.
Details of the supplier of the safety data sheet
Registered company name Tracerco
Address
2 Harris Road Malaga 6090 WA
Australia
Telephone +61 8 9209 3905
Fax +61 8 9209 3725
Website www.tracerco.com
Email admin.aus@tracerco.com
Emergency telephone number
Association / Organisation Not Available
Emergency telephone numbers +61 8 9209 3905 (9am-5pm)
Other emergency telephone
numbers
+61 8 9209 3905 (9am-5pm)
SECTION 2 HAZARDS IDENTIFICATION
Classification of the substance or mixture
HAZARDOUS CHEMICAL. NON-DANGEROUS GOODS. According to the Model WHS Regulations and the ADG Code.
CHEMWATCH HAZARD RATINGS
Max Min
Flammability 0
Toxicity 2

Body Contact 2

Reactivity 0
Chronic 0
0 = Minimum
1 = Low
2 = Moderate
3 = High
4 = Extreme
Poisons Schedule Not Applicable
GHS Classification
[1]
Acute Toxicity (Oral) Category 4, Acute Toxicity (Inhalation) Category 4, Skin Corrosion/Irritation Category 2, Eye
Irrit. 2, STOT - SE (Resp. Irr.) Category 3
Continued...
Legend:
1. Classified by Chemwatch; 2. Classification drawn from HSIS ; 3. Classification drawn from EC Directive
1272/2008 - Annex VI
Label elements
GHS label elements
SIGNAL WORD WARNING
Hazard statement(s)
H302 Harmful if swallowed
H332 Harmful if inhaled
H315 Causes skin irritation
H319 Causes serious eye irritation
H335 May cause respiratory irritation
Precautionary statement(s): Prevention
P271 Use only outdoors or in a well-ventilated area.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Precautionary statement(s): Response
P321 Specific treatment (see advice on this label).
P305+P351+P338
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/attention.
P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor/physician/first aider/if you feel unwell.
Precautionary statement(s): Storage
P405 Store locked up.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
Precautionary statement(s): Disposal
P501 Dispose of contents/container to authorised chemical landfill or if organic to high temperature incineration
SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
Substances
See section below for composition of Mixtures
Mixtures
CAS No %[weight] Name
522651-44-1 10-30 sodium 3,4-difluorobenzoate
7732-18-5 >60 water
SECTION 4 FIRST AID MEASURES
Description of first aid measures
Eye Contact
If this product comes in contact with the eyes:
Wash out immediately with fresh running water.
Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids
by occasionally lifting the upper and lower lids.
Seek medical attention without delay; if pain persists or recurs seek medical attention.
Chemwatch: 4886-99
Version No: 2.1.1.1
Page 2 of 8
Tracerco T-158d
Issue Date: 25/02/2014
Print Date: 16/05/2014
Continued...
Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
Skin Contact
If skin contact occurs:
Immediately remove all contaminated clothing, including footwear.
Flush skin and hair with running water (and soap if available).
Seek medical attention in event of irritation.
Inhalation
If fumes, aerosols or combustion products are inhaled remove from contaminated area.
Other measures are usually unnecessary.
Ingestion
If swallowed do NOT induce vomiting.
If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain
open airway and prevent aspiration.
Observe the patient carefully.
Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming
unconscious.
Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink.
Seek medical advice.
Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5 FIREFIGHTING MEASURES
Extinguishing media
There is no restriction on the type of extinguisher which may be used.
Use extinguishing media suitable for surrounding area.
Special hazards arising from the substrate or mixture
Fire Incompatibility None known.
Advice for firefighters
Fire Fighting
Alert Fire Brigade and tell them location and nature of hazard.
Wear breathing apparatus plus protective gloves in the event of a fire.
Prevent, by any means available, spillage from entering drains or water courses.
Use fire fighting procedures suitable for surrounding area.
Fire/Explosion Hazard
Non combustible.
Not considered to be a significant fire risk.
Expansion or decomposition on heating may lead to violent rupture of containers.
Decomposes on heating and may produce toxic fumes of carbon monoxide (CO).
SECTION 6 ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Minor Spills
Clean up all spills immediately.
Avoid breathing vapours and contact with skin and eyes.
Control personal contact with the substance, by using protective equipment.
Contain and absorb spill with sand, earth, inert material or vermiculite.
Major Spills
Minor hazard.
Clear area of personnel.
Alert Fire Brigade and tell them location and nature of hazard.
Control personal contact with the substance, by using protective equipment as required.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
SECTION 7 HANDLING AND STORAGE
Precautions for safe handling
Safe handling
Limit all unnecessary personal contact.
Wear protective clothing when risk of exposure occurs.
Use in a well-ventilated area.
When handling DO NOT eat, drink or smoke.
Chemwatch: 4886-99
Version No: 2.1.1.1
Page 3 of 8
Tracerco T-158d
Issue Date: 25/02/2014
Print Date: 16/05/2014
Continued...
Other information
Store in original containers.
Keep containers securely sealed.
Store in a cool, dry, well-ventilated area.
Store away from incompatible materials and foodstuff containers.
Conditions for safe storage, including any incompatibilities
Suitable container
Polyethylene or polypropylene container.
Packing as recommended by manufacturer.
Check all containers are clearly labelled and free from leaks.
Storage incompatibility None known
PACKAGE MATERIAL INCOMPATIBILITIES
Not Available
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Control parameters
OCCUPATIONAL EXPOSURE LIMITS (OEL)
INGREDIENT DATA
Not Available
EMERGENCY LIMITS
Ingredient TEEL-0 TEEL-1 TEEL-2 TEEL-3
water 500(ppm) 500(ppm) 500(ppm) 500(ppm)
Ingredient Original IDLH Revised IDLH
Tracerco T-158d Not Available Not Available
Exposure controls
Appropriate engineering
controls
General exhaust is adequate under normal operating conditions.
Personal protection
Eye and face protection
Safety glasses with side shields.
Chemical goggles.
Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written
policy document, describing the wearing of lenses or restrictions on use, should be created for each workplace or
task.
Skin protection See Hand protection below
Hand protection
The selection of suitable gloves does not only depend on the material, but also on further marks of quality which
vary from manufacturer to manufacturer. Where the chemical is a preparation of several substances, the
resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the
application.
The exact break through time for substances has to be obtained from the manufacturer of the protective gloves
and.has to be observed when making a final choice.
Suitability and durability of glove type is dependent on usage.
Body protection See Other protection below
Other protection
Overalls.
Eyewash unit.
Thermal hazards Not Available
Recommended material(s)
GLOVE SELECTION INDEX
Glove selection is based on a modified presentation of the:
"Forsberg Clothing Performance Index".
The effect(s) of the following substance(s) are taken into account in the
computer-generated selection:
Respiratory protection
Particulate. (AS/NZS 1716 & 1715, EN 143:000 & 149:001, ANSI Z88 or
national equivalent)
Where the concentration of gas/particulates in the breathing zone,
approaches or exceeds the "Exposure Standard" (or ES), respiratory
Chemwatch: 4886-99
Version No: 2.1.1.1
Page 4 of 8
Tracerco T-158d
Issue Date: 25/02/2014
Print Date: 16/05/2014
Continued...
Tracerco T-158d
Material CPI
BUTYL A
NEOPRENE A
VITON A
* CPI - Chemwatch Performance Index
A: Best Selection
B: Satisfactory; may degrade after 4 hours continuous immersion
C: Poor to Dangerous Choice for other than short term immersion
NOTE: As a series of factors will influence the actual performance of the
glove, a final selection must be based on detailed observation. -
* Where the glove is to be used on a short term, casual or infrequent
basis, factors such as "feel" or convenience (e.g. disposability), may
dictate a choice of gloves which might otherwise be unsuitable following
long-term or frequent use. A qualified practitioner should be consulted.
protection is required.
Degree of protection varies with both face-piece and Class of filter;
the nature of protection varies with Type of filter.
Required
Minimum
Protection Factor
Half-Face
Respirator
Full-Face
Respirator
Powered Air
Respirator
up to 10 x ES -AUS P2 -
-PAPR-AUS /
Class 1 P2
up to 50 x ES -
-AUS / Class
1 P2
-
up to 100 x ES - -2 P2 -PAPR-2 P2 ^
^ - Full-face
A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 =
Acid gas or hydrogen cyanide(HCN), B3 = Acid gas or hydrogen
cyanide(HCN), E = Sulfur dioxide(SO2), G = Agricultural chemicals,
K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB =
Methyl bromide, AX = Low boiling point organic compounds(below
65 degC)
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Appearance Liquid; mixes with water.
Physical state Liquid Relative density (Water = 1) Not Available
Odour Not Available
Partition coefficient n-octanol /
water
Not Available
Odour threshold Not Available Auto-ignition temperature (C) Not Applicable
pH (as supplied) Not Available Decomposition temperature Not Available
Melting point / freezing point
(C)
Not Available Viscosity (cSt) Not Available
Initial boiling point and boiling
range (C)
Not Available Molecular weight (g/mol) Not Applicable
Flash point (C) Not Applicable Taste Not Available
Evaporation rate Not Available Explosive properties Not Available
Flammability Not Applicable Oxidising properties Not Available
Upper Explosive Limit (%) Not Applicable
Surface Tension (dyn/cm or
mN/m)
Not Available
Lower Explosive Limit (%) Not Applicable Volatile Component (%vol) 80
Vapour pressure (kPa) Not Available Gas group Not Available
Solubility in water (g/L) Miscible pH as a solution(1%) Not Available
Vapour density (Air = 1) Not Available VOC g/L Not Available
SECTION 10 STABILITY AND REACTIVITY
Reactivity See section 7
Chemical stability Product is considered stable and hazardous polymerisation will not occur.
Possibility of hazardous
reactions
See section 7
Conditions to avoid See section 7
Incompatible materials See section 7
Hazardous decomposition
products
See section 5
SECTION 11 TOXICOLOGICAL INFORMATION
Chemwatch: 4886-99
Version No: 2.1.1.1
Page 5 of 8
Tracerco T-158d
Issue Date: 25/02/2014
Print Date: 16/05/2014
Continued...
Information on toxicological effects
Inhaled
Evidence shows, or practical experience predicts, that the material produces irritation of the respiratory system, in
a substantial number of individuals, following inhalation. In contrast to most organs, the lung is able to respond to
a chemical insult by first removing or neutralising the irritant and then repairing the damage. The repair process,
which initially evolved to protect mammalian lungs from foreign matter and antigens, may however, produce
further lung damage resulting in the impairment of gas exchange, the primary function of the lungs. Respiratory
tract irritation often results in an inflammatory response involving the recruitment and activation of many cell
types, mainly derived from the vascular system.
Ingestion
Accidental ingestion of the material may be damaging to the health of the individual.
Ingestion may result in nausea, abdominal irritation, pain and vomiting
Skin Contact
Evidence exists, or practical experience predicts, that the material either produces inflammation of the skin in a
substantial number of individuals following direct contact, and/or produces significant inflammation when applied to
the healthy intact skin of animals, for up to four hours, such inflammation being present twenty-four hours or
more after the end of the exposure period. Skin irritation may also be present after prolonged or repeated
exposure; this may result in a form of contact dermatitis (nonallergic). The dermatitis is often characterised by
skin redness (erythema) and swelling (oedema) which may progress to blistering (vesiculation), scaling and
thickening of the epidermis. At the microscopic level there may be intercellular oedema of the spongy layer of the
skin (spongiosis) and intracellular oedema of the epidermis.
Eye
Evidence exists, or practical experience predicts, that the material may cause eye irritation in a substantial
number of individuals and/or may produce significant ocular lesions which are present twenty-four hours or more
after instillation into the eye(s) of experimental animals.
Repeated or prolonged eye contact may cause inflammation characterised by temporary redness (similar to
windburn) of the conjunctiva (conjunctivitis); temporary impairment of vision and/or other transient eye
damage/ulceration may occur.
Chronic
Long-term exposure to respiratory irritants may result in disease of the airways involving difficult breathing and
related systemic problems.
Tracerco T-158d
TOXICITY IRRITATION
Not Available Not Available
sodium 3,4-difluorobenzoate
TOXICITY IRRITATION
Not Available Not Available
water
TOXICITY IRRITATION
Not Available Not Available
* Value obtained from manufacturer's msds
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances
Tracerco T-158d Not available.
SODIUM
3,4-DIFLUOROBENZOATE
Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This
may be due to a non-allergenic condition known as reactive airways dysfunction syndrome (RADS) which can
occur following exposure to high levels of highly irritating compound. Key criteria for the diagnosis of RADS
include the absence of preceding respiratory disease, in a non-atopic individual, with abrupt onset of persistent
asthma-like symptoms within minutes to hours of a documented exposure to the irritant. A reversible airflow
pattern, on spirometry, with the presence of moderate to severe bronchial hyperreactivity on methacholine
challenge testing and the lack of minimal lymphocytic inflammation, without eosinophilia, have also been
included in the criteria for diagnosis of RADS.
WATER No significant acute toxicological data identified in literature search.
Acute Toxicity Carcinogenicity
Skin Irritation/Corrosion Reproductivity
Serious Eye Damage/Irritation STOT - Single Exposure
Respiratory or Skin
sensitisation
STOT - Repeated Exposure
Mutagenicity Aspiration Hazard
Chemwatch: 4886-99
Version No: 2.1.1.1
Page 6 of 8
Tracerco T-158d
Issue Date: 25/02/2014
Print Date: 16/05/2014
Continued...
CMR STATUS
Not Applicable
SECTION 12 ECOLOGICAL INFORMATION
Toxicity
DO NOT discharge into sewer or waterways.
Persistence and degradability
Ingredient Persistence: Water/Soil Persistence: Air
Not Available Not Available Not Available
Bioaccumulative potential
Ingredient Bioaccumulation
Not Available Not Available
Mobility in soil
Ingredient Mobility
Not Available Not Available
SECTION 13 DISPOSAL CONSIDERATIONS
Waste treatment methods
Product / Packaging disposal
Recycle wherever possible.
Consult manufacturer for recycling options or consult local or regional waste management authority for
disposal if no suitable treatment or disposal facility can be identified.
Dispose of by: burial in a land-fill specifically licenced to accept chemical and / or pharmaceutical wastes or
incineration in a licenced apparatus (after admixture with suitable combustible material).
Decontaminate empty containers.
SECTION 14 TRANSPORT INFORMATION
Labels Required
Marine Pollutant NO
HAZCHEM Not Applicable
Land transport (): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
SECTION 15 REGULATORY INFORMATION
Safety, health and environmental regulations / legislation specific for the substance or mixture
sodium
3,4-difluorobenzoate(522651-44-1)
is found on the following
regulatory lists
water(7732-18-5) is found on the
following regulatory lists
"WHO Model List of Essential Medicines - Adults","Australia Inventory of Chemical Substances (AICS)","OECD
List of High Production Volume (HPV) Chemicals","OSPAR National List of Candidates for Substitution
Norway","IMO IBC Code Chapter 18: List of products to which the Code does not apply","Sigma-AldrichTransport
Information","Australia High Volume Industrial Chemical List (HVICL)","International Fragrance Association (IFRA)
Survey: Transparency List"
SECTION 16 OTHER INFORMATION
Other information
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the
Chemwatch: 4886-99
Version No: 2.1.1.1
Page 7 of 8
Tracerco T-158d
Issue Date: 25/02/2014
Print Date: 16/05/2014
Continued...
Chemwatch Classification committee using available literature references.
A list of reference resources used to assist the committee may be found at:
www.chemwatch.net/references
The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards
are Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current
or available engineering controls must be considered.
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from CHEMWATCH. TEL (+61 3) 9572 4700.
Chemwatch: 4886-99
Version No: 2.1.1.1
Page 8 of 8
Tracerco T-158d
Issue Date: 25/02/2014
Print Date: 16/05/2014
end of SDS
Tracerco Chemwatch Hazard Alert Code: 1
Tracerco T-176c
Chemwatch: 4888-07
Version No: 2.1.1.1
Safety Data Sheet according to WHS and ADG requirements
Issue Date: 25/02/2014
Print Date: 16/05/2014
Initial Date: Not Available
S.GHS.AUS.EN
SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING
Product Identifier
Product name Tracerco T-176c
Chemical Name Not Applicable
Synonyms Not Available
Proper shipping name Not Applicable
Chemical formula Not Applicable
Other means of identification Not Available
CAS number Not Applicable
Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses Use according to manufacturer's directions.
Details of the supplier of the safety data sheet
Registered company name Tracerco
Address
2 Harris Road Malaga 6090 WA
Australia
Telephone +61 8 9209 3905
Fax +61 8 9209 3725
Website www.tracerco.com
Email admin.aus@tracerco.com
Emergency telephone number
Association / Organisation Not Available
Emergency telephone numbers +61 8 9209 3905 (9am-5pm)
Other emergency telephone
numbers
+61 8 9209 3905 (9am-5pm)
SECTION 2 HAZARDS IDENTIFICATION
Classification of the substance or mixture
NON-HAZARDOUS CHEMICAL. NON-DANGEROUS GOODS. According to the Model WHS Regulations and the ADG Code.
CHEMWATCH HAZARD RATINGS
Max Min
Flammability 0
Toxicity 1

Body Contact 1

Reactivity 0
Chronic 0
0 = Minimum
1 = Low
2 = Moderate
3 = High
4 = Extreme
Poisons Schedule Not Applicable
GHS Classification Not Applicable
Continued...
Label elements
GHS label elements
Not Applicable
SIGNAL WORD NOT APPLICABLE
Hazard statement(s)
Not Applicable
Precautionary statement(s): Prevention
Not Applicable
Precautionary statement(s): Response
Not Applicable
Precautionary statement(s): Storage
Not Applicable
Precautionary statement(s): Disposal
Not Applicable
SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
Substances
See section below for composition of Mixtures
Mixtures
CAS No %[weight] Name
522651-48-5 <10 sodium 2,4,5-trifluorobenzoate
7732-18-5 >60 water
SECTION 4 FIRST AID MEASURES
Description of first aid measures
Eye Contact
If this product comes in contact with the eyes:
Wash out immediately with fresh running water.
Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids
by occasionally lifting the upper and lower lids.
Seek medical attention without delay; if pain persists or recurs seek medical attention.
Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
Skin Contact
If skin contact occurs:
Immediately remove all contaminated clothing, including footwear.
Flush skin and hair with running water (and soap if available).
Seek medical attention in event of irritation.
Inhalation
If fumes, aerosols or combustion products are inhaled remove from contaminated area.
Other measures are usually unnecessary.
Ingestion
If swallowed do NOT induce vomiting.
If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain
open airway and prevent aspiration.
Observe the patient carefully.
Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming
unconscious.
Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink.
Seek medical advice.
Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5 FIREFIGHTING MEASURES
Extinguishing media
There is no restriction on the type of extinguisher which may be used.
Use extinguishing media suitable for surrounding area.
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Version No: 2.1.1.1
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Tracerco T-176c
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Print Date: 16/05/2014
Continued...
Special hazards arising from the substrate or mixture
Fire Incompatibility None known.
Advice for firefighters
Fire Fighting
Alert Fire Brigade and tell them location and nature of hazard.
Wear breathing apparatus plus protective gloves in the event of a fire.
Prevent, by any means available, spillage from entering drains or water courses.
Use fire fighting procedures suitable for surrounding area.
Fire/Explosion Hazard
Non combustible.
Not considered to be a significant fire risk.
Expansion or decomposition on heating may lead to violent rupture of containers.
Decomposes on heating and may produce toxic fumes of carbon monoxide (CO).
SECTION 6 ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Minor Spills
Clean up all spills immediately.
Avoid breathing vapours and contact with skin and eyes.
Control personal contact with the substance, by using protective equipment.
Contain and absorb spill with sand, earth, inert material or vermiculite.
Major Spills
Minor hazard.
Clear area of personnel.
Alert Fire Brigade and tell them location and nature of hazard.
Control personal contact with the substance, by using protective equipment as required.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
SECTION 7 HANDLING AND STORAGE
Precautions for safe handling
Safe handling
Limit all unnecessary personal contact.
Wear protective clothing when risk of exposure occurs.
Use in a well-ventilated area.
When handling DO NOT eat, drink or smoke.
Other information
Store in original containers.
Keep containers securely sealed.
Store in a cool, dry, well-ventilated area.
Store away from incompatible materials and foodstuff containers.
Conditions for safe storage, including any incompatibilities
Suitable container
Polyethylene or polypropylene container.
Packing as recommended by manufacturer.
Check all containers are clearly labelled and free from leaks.
Storage incompatibility None known
PACKAGE MATERIAL INCOMPATIBILITIES
Not Available
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Control parameters
OCCUPATIONAL EXPOSURE LIMITS (OEL)
INGREDIENT DATA
Not Available
EMERGENCY LIMITS
Ingredient TEEL-0 TEEL-1 TEEL-2 TEEL-3
water 500(ppm) 500(ppm) 500(ppm) 500(ppm)
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Tracerco T-176c
Issue Date: 25/02/2014
Print Date: 16/05/2014
Continued...
Ingredient Original IDLH Revised IDLH
Tracerco T-176c Not Available Not Available
Exposure controls
Appropriate engineering
controls
General exhaust is adequate under normal operating conditions.
Personal protection
Eye and face protection
Safety glasses with side shields.
Chemical goggles.
Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written
policy document, describing the wearing of lenses or restrictions on use, should be created for each workplace or
task.
Skin protection See Hand protection below
Hand protection
The selection of suitable gloves does not only depend on the material, but also on further marks of quality which
vary from manufacturer to manufacturer. Where the chemical is a preparation of several substances, the
resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the
application.
The exact break through time for substances has to be obtained from the manufacturer of the protective gloves
and.has to be observed when making a final choice.
Suitability and durability of glove type is dependent on usage.
Body protection See Other protection below
Other protection
Overalls.
Eyewash unit.
Thermal hazards Not Available
Recommended material(s)
GLOVE SELECTION INDEX
Glove selection is based on a modified presentation of the:
"Forsberg Clothing Performance Index".
The effect(s) of the following substance(s) are taken into account in the
computer-generated selection:
Tracerco T-176c
Material CPI
BUTYL A
NEOPRENE A
VITON A
* CPI - Chemwatch Performance Index
A: Best Selection
B: Satisfactory; may degrade after 4 hours continuous immersion
C: Poor to Dangerous Choice for other than short term immersion
NOTE: As a series of factors will influence the actual performance of the
glove, a final selection must be based on detailed observation. -
* Where the glove is to be used on a short term, casual or infrequent
basis, factors such as "feel" or convenience (e.g. disposability), may
dictate a choice of gloves which might otherwise be unsuitable following
long-term or frequent use. A qualified practitioner should be consulted.
Respiratory protection
Particulate. (AS/NZS 1716 & 1715, EN 143:000 & 149:001, ANSI Z88 or
national equivalent)
Where the concentration of gas/particulates in the breathing zone,
approaches or exceeds the "Exposure Standard" (or ES), respiratory
protection is required.
Degree of protection varies with both face-piece and Class of filter;
the nature of protection varies with Type of filter.
Required
Minimum
Protection Factor
Half-Face
Respirator
Full-Face
Respirator
Powered Air
Respirator
up to 10 x ES -AUS P2 -
-PAPR-AUS /
Class 1 P2
up to 50 x ES -
-AUS / Class
1 P2
-
up to 100 x ES - -2 P2 -PAPR-2 P2 ^
^ - Full-face
A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 =
Acid gas or hydrogen cyanide(HCN), B3 = Acid gas or hydrogen
cyanide(HCN), E = Sulfur dioxide(SO2), G = Agricultural chemicals,
K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB =
Methyl bromide, AX = Low boiling point organic compounds(below
65 degC)
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Appearance Liquid; mixes with water.
Physical state Liquid Relative density (Water = 1) Not Available
Chemwatch: 4888-07
Version No: 2.1.1.1
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Tracerco T-176c
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Print Date: 16/05/2014
Continued...
Odour Not Available
Partition coefficient n-octanol /
water
Not Available
Odour threshold Not Available Auto-ignition temperature (C) Not Applicable
pH (as supplied) Not Available Decomposition temperature Not Available
Melting point / freezing point
(C)
Not Available Viscosity (cSt) Not Available
Initial boiling point and boiling
range (C)
Not Available Molecular weight (g/mol) Not Applicable
Flash point (C) Not Applicable Taste Not Available
Evaporation rate Not Available Explosive properties Not Available
Flammability Not Applicable Oxidising properties Not Available
Upper Explosive Limit (%) Not Applicable
Surface Tension (dyn/cm or
mN/m)
Not Available
Lower Explosive Limit (%) Not Applicable Volatile Component (%vol) 90
Vapour pressure (kPa) Not Available Gas group Not Available
Solubility in water (g/L) Miscible pH as a solution(1%) Not Available
Vapour density (Air = 1) Not Available VOC g/L Not Available
SECTION 10 STABILITY AND REACTIVITY
Reactivity See section 7
Chemical stability Product is considered stable and hazardous polymerisation will not occur.
Possibility of hazardous
reactions
See section 7
Conditions to avoid See section 7
Incompatible materials See section 7
Hazardous decomposition
products
See section 5
SECTION 11 TOXICOLOGICAL INFORMATION
Information on toxicological effects
Inhaled
Not normally a hazard due to non-volatile nature of product
The material is not thought to produce adverse health effects or irritation of the respiratory tract (as classified by
EC Directives using animal models). Nevertheless, good hygiene practice requires that exposure be kept to a
minimum and that suitable control measures be used in an occupational setting.
Ingestion
Accidental ingestion of the material may be damaging to the health of the individual.
Ingestion may result in nausea, abdominal irritation, pain and vomiting
Skin Contact
Limited evidence exists, or practical experience predicts, that the material either produces inflammation of the
skin in a substantial number of individuals following direct contact, and/or produces significant inflammation when
applied to the healthy intact skin of animals, for up to four hours, such inflammation being present twenty-four
hours or more after the end of the exposure period. Skin irritation may also be present after prolonged or repeated
exposure; this may result in a form of contact dermatitis (nonallergic). The dermatitis is often characterised by
skin redness (erythema) and swelling (oedema) which may progress to blistering (vesiculation), scaling and
thickening of the epidermis. At the microscopic level there may be intercellular oedema of the spongy layer of the
skin (spongiosis) and intracellular oedema of the epidermis.
Eye
Limited evidence exists, or practical experience suggests, that the material may cause eye irritation in a
substantial number of individuals and/or is expected to produce significant ocular lesions which are present
twenty-four hours or more after instillation into the eye(s) of experimental animals. Repeated or prolonged eye
contact may cause inflammation characterised by temporary redness (similar to windburn) of the conjunctiva
(conjunctivitis); temporary impairment of vision and/or other transient eye damage/ulceration may occur.
Chronic
Long-term exposure to the product is not thought to produce chronic effects adverse to health (as classified by
EC Directives using animal models); nevertheless exposure by all routes should be minimised as a matter of
course.
Tracerco T-176c
TOXICITY IRRITATION
Not Available Not Available
Chemwatch: 4888-07
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Continued...
* Value obtained from manufacturer's msds
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances
Tracerco T-176c Not available.
SODIUM 2,4,5-
TRIFLUOROBENZOATE
Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This
may be due to a non-allergenic condition known as reactive airways dysfunction syndrome (RADS) which can
occur following exposure to high levels of highly irritating compound. Key criteria for the diagnosis of RADS
include the absence of preceding respiratory disease, in a non-atopic individual, with abrupt onset of persistent
asthma-like symptoms within minutes to hours of a documented exposure to the irritant. A reversible airflow
pattern, on spirometry, with the presence of moderate to severe bronchial hyperreactivity on methacholine
challenge testing and the lack of minimal lymphocytic inflammation, without eosinophilia, have also been
included in the criteria for diagnosis of RADS.
WATER No significant acute toxicological data identified in literature search.
Acute Toxicity Carcinogenicity
Skin Irritation/Corrosion Reproductivity
Serious Eye Damage/Irritation STOT - Single Exposure
Respiratory or Skin
sensitisation
STOT - Repeated Exposure
Mutagenicity Aspiration Hazard
CMR STATUS
Not Applicable
SECTION 12 ECOLOGICAL INFORMATION
Toxicity
DO NOT discharge into sewer or waterways.
Persistence and degradability
Ingredient Persistence: Water/Soil Persistence: Air
Not Available Not Available Not Available
Bioaccumulative potential
Ingredient Bioaccumulation
Not Available Not Available
Mobility in soil
Ingredient Mobility
Not Available Not Available
SECTION 13 DISPOSAL CONSIDERATIONS
Waste treatment methods
Product / Packaging disposal
Recycle wherever possible.
Consult manufacturer for recycling options or consult local or regional waste management authority for
disposal if no suitable treatment or disposal facility can be identified.
Dispose of by: burial in a land-fill specifically licenced to accept chemical and / or pharmaceutical wastes or
incineration in a licenced apparatus (after admixture with suitable combustible material).
Decontaminate empty containers.
SECTION 14 TRANSPORT INFORMATION
Labels Required
Marine Pollutant NO
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Print Date: 16/05/2014
Continued...
HAZCHEM Not Applicable
Land transport (): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
SECTION 15 REGULATORY INFORMATION
Safety, health and environmental regulations / legislation specific for the substance or mixture
sodium 2,4,5-
trifluorobenzoate(522651-48-5) is
found on the following
regulatory lists
water(7732-18-5) is found on the
following regulatory lists
"WHO Model List of Essential Medicines - Adults","Australia Inventory of Chemical Substances (AICS)","OECD
List of High Production Volume (HPV) Chemicals","OSPAR National List of Candidates for Substitution
Norway","IMO IBC Code Chapter 18: List of products to which the Code does not apply","Sigma-AldrichTransport
Information","Australia High Volume Industrial Chemical List (HVICL)","International Fragrance Association (IFRA)
Survey: Transparency List"
SECTION 16 OTHER INFORMATION
Other information
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the
Chemwatch Classification committee using available literature references.
A list of reference resources used to assist the committee may be found at:
www.chemwatch.net/references
The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards
are Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current
or available engineering controls must be considered.
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from CHEMWATCH. TEL (+61 3) 9572 4700.
Chemwatch: 4888-07
Version No: 2.1.1.1
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Tracerco T-176c
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Print Date: 16/05/2014
end of SDS
Tracerco Chemwatch Hazard Alert Code: 2
Tracerco T-190a
Chemwatch: 4888-08
Version No: 2.1.1.1
Safety Data Sheet according to WHS and ADG requirements
Issue Date: 25/02/2014
Print Date: 16/05/2014
Initial Date: Not Available
S.GHS.AUS.EN
SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING
Product Identifier
Product name Tracerco T-190a
Chemical Name Not Applicable
Synonyms Not Available
Proper shipping name Not Applicable
Chemical formula Not Applicable
Other means of identification Not Available
CAS number Not Applicable
Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses Use according to manufacturer's directions.
Details of the supplier of the safety data sheet
Registered company name Tracerco
Address
2 Harris Road Malaga 6090 WA
Australia
Telephone +61 8 9209 3905
Fax +61 8 9209 3725
Website www.tracerco.com
Email admin.aus@tracerco.com
Emergency telephone number
Association / Organisation Not Available
Emergency telephone numbers +61 8 9209 3905 (9am-5pm)
Other emergency telephone
numbers
+61 8 9209 3905 (9am-5pm)
SECTION 2 HAZARDS IDENTIFICATION
Classification of the substance or mixture
HAZARDOUS CHEMICAL. NON-DANGEROUS GOODS. According to the Model WHS Regulations and the ADG Code.
CHEMWATCH HAZARD RATINGS
Max Min
Flammability 0
Toxicity 2

Body Contact 2

Reactivity 0
Chronic 0
0 = Minimum
1 = Low
2 = Moderate
3 = High
4 = Extreme
Poisons Schedule Not Applicable
GHS Classification
[1]
Acute Toxicity (Oral) Category 4, Acute Toxicity (Inhalation) Category 4, Skin Corrosion/Irritation Category 2, Eye
Irrit. 2, STOT - SE (Resp. Irr.) Category 3
Continued...
Legend:
1. Classified by Chemwatch; 2. Classification drawn from HSIS ; 3. Classification drawn from EC Directive
1272/2008 - Annex VI
Label elements
GHS label elements
SIGNAL WORD WARNING
Hazard statement(s)
H302 Harmful if swallowed
H332 Harmful if inhaled
H315 Causes skin irritation
H319 Causes serious eye irritation
H335 May cause respiratory irritation
Precautionary statement(s): Prevention
P271 Use only outdoors or in a well-ventilated area.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Precautionary statement(s): Response
P321 Specific treatment (see advice on this label).
P305+P351+P338
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/attention.
P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor/physician/first aider/if you feel unwell.
Precautionary statement(s): Storage
P405 Store locked up.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
Precautionary statement(s): Disposal
P501 Dispose of contents/container to authorised chemical landfill or if organic to high temperature incineration
SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
Substances
See section below for composition of Mixtures
Mixtures
CAS No %[weight] Name
2966-44-1 10-30 sodium 2-(trifluoromethyl)benzoate
7732-18-5 >60 water
SECTION 4 FIRST AID MEASURES
Description of first aid measures
Eye Contact
If this product comes in contact with the eyes:
Wash out immediately with fresh running water.
Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids
by occasionally lifting the upper and lower lids.
Seek medical attention without delay; if pain persists or recurs seek medical attention.
Chemwatch: 4888-08
Version No: 2.1.1.1
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Tracerco T-190a
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Continued...
Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
Skin Contact
If skin contact occurs:
Immediately remove all contaminated clothing, including footwear.
Flush skin and hair with running water (and soap if available).
Seek medical attention in event of irritation.
Inhalation
If fumes, aerosols or combustion products are inhaled remove from contaminated area.
Other measures are usually unnecessary.
Ingestion
If swallowed do NOT induce vomiting.
If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain
open airway and prevent aspiration.
Observe the patient carefully.
Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming
unconscious.
Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink.
Seek medical advice.
Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5 FIREFIGHTING MEASURES
Extinguishing media
There is no restriction on the type of extinguisher which may be used.
Use extinguishing media suitable for surrounding area.
Special hazards arising from the substrate or mixture
Fire Incompatibility None known.
Advice for firefighters
Fire Fighting
Alert Fire Brigade and tell them location and nature of hazard.
Wear breathing apparatus plus protective gloves in the event of a fire.
Prevent, by any means available, spillage from entering drains or water courses.
Use fire fighting procedures suitable for surrounding area.
Fire/Explosion Hazard
Non combustible.
Not considered to be a significant fire risk.
Expansion or decomposition on heating may lead to violent rupture of containers.
Decomposes on heating and may produce toxic fumes of carbon monoxide (CO).
SECTION 6 ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Minor Spills
Clean up all spills immediately.
Avoid breathing vapours and contact with skin and eyes.
Control personal contact with the substance, by using protective equipment.
Contain and absorb spill with sand, earth, inert material or vermiculite.
Major Spills
Minor hazard.
Clear area of personnel.
Alert Fire Brigade and tell them location and nature of hazard.
Control personal contact with the substance, by using protective equipment as required.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
SECTION 7 HANDLING AND STORAGE
Precautions for safe handling
Safe handling
Limit all unnecessary personal contact.
Wear protective clothing when risk of exposure occurs.
Use in a well-ventilated area.
When handling DO NOT eat, drink or smoke.
Chemwatch: 4888-08
Version No: 2.1.1.1
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Tracerco T-190a
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Continued...
Other information
Store in original containers.
Keep containers securely sealed.
Store in a cool, dry, well-ventilated area.
Store away from incompatible materials and foodstuff containers.
Conditions for safe storage, including any incompatibilities
Suitable container
Polyethylene or polypropylene container.
Packing as recommended by manufacturer.
Check all containers are clearly labelled and free from leaks.
Storage incompatibility None known
PACKAGE MATERIAL INCOMPATIBILITIES
Not Available
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Control parameters
OCCUPATIONAL EXPOSURE LIMITS (OEL)
INGREDIENT DATA
Not Available
EMERGENCY LIMITS
Ingredient TEEL-0 TEEL-1 TEEL-2 TEEL-3
water 500(ppm) 500(ppm) 500(ppm) 500(ppm)
Ingredient Original IDLH Revised IDLH
Tracerco T-190a Not Available Not Available
Exposure controls
Appropriate engineering
controls
Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard.
Well-designed engineering controls can be highly effective in protecting workers and will typically be independent
of worker interactions to provide this high level of protection.
The basic types of engineering controls are:
Process controls which involve changing the way a job activity or process is done to reduce the risk.
Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker
and ventilation that strategically "adds" and "removes" air in the work environment.
Personal protection
Eye and face protection
Safety glasses with side shields.
Chemical goggles.
Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written
policy document, describing the wearing of lenses or restrictions on use, should be created for each workplace or
task.
Skin protection See Hand protection below
Hand protection
The selection of suitable gloves does not only depend on the material, but also on further marks of quality which
vary from manufacturer to manufacturer. Where the chemical is a preparation of several substances, the
resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the
application.
The exact break through time for substances has to be obtained from the manufacturer of the protective gloves
and.has to be observed when making a final choice.
Suitability and durability of glove type is dependent on usage.
Body protection See Other protection below
Other protection
Overalls.
Eyewash unit.
Thermal hazards Not Available
Recommended material(s) Respiratory protection
Chemwatch: 4888-08
Version No: 2.1.1.1
Page 4 of 8
Tracerco T-190a
Issue Date: 25/02/2014
Print Date: 16/05/2014
Continued...
GLOVE SELECTION INDEX
Glove selection is based on a modified presentation of the:
"Forsberg Clothing Performance Index".
The effect(s) of the following substance(s) are taken into account in the
computer-generated selection:
Tracerco T-190a
Material CPI
BUTYL A
NEOPRENE A
VITON A
* CPI - Chemwatch Performance Index
A: Best Selection
B: Satisfactory; may degrade after 4 hours continuous immersion
C: Poor to Dangerous Choice for other than short term immersion
NOTE: As a series of factors will influence the actual performance of the
glove, a final selection must be based on detailed observation. -
* Where the glove is to be used on a short term, casual or infrequent
basis, factors such as "feel" or convenience (e.g. disposability), may
dictate a choice of gloves which might otherwise be unsuitable following
long-term or frequent use. A qualified practitioner should be consulted.
Particulate. (AS/NZS 1716 & 1715, EN 143:000 & 149:001, ANSI Z88 or
national equivalent)
Where the concentration of gas/particulates in the breathing zone,
approaches or exceeds the "Exposure Standard" (or ES), respiratory
protection is required.
Degree of protection varies with both face-piece and Class of filter;
the nature of protection varies with Type of filter.
Required
Minimum
Protection Factor
Half-Face
Respirator
Full-Face
Respirator
Powered Air
Respirator
up to 10 x ES -AUS P2 -
-PAPR-AUS /
Class 1 P2
up to 50 x ES -
-AUS / Class
1 P2
-
up to 100 x ES - -2 P2 -PAPR-2 P2 ^
^ - Full-face
A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 =
Acid gas or hydrogen cyanide(HCN), B3 = Acid gas or hydrogen
cyanide(HCN), E = Sulfur dioxide(SO2), G = Agricultural chemicals,
K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB =
Methyl bromide, AX = Low boiling point organic compounds(below
65 degC)
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Appearance Liquid; mixes with water.
Physical state Liquid Relative density (Water = 1) Not Available
Odour Not Available
Partition coefficient n-octanol /
water
Not Available
Odour threshold Not Available Auto-ignition temperature (C) Not Applicable
pH (as supplied) Not Available Decomposition temperature Not Available
Melting point / freezing point
(C)
Not Available Viscosity (cSt) Not Available
Initial boiling point and boiling
range (C)
Not Available Molecular weight (g/mol) Not Applicable
Flash point (C) Not Applicable Taste Not Available
Evaporation rate Not Available Explosive properties Not Available
Flammability Not Applicable Oxidising properties Not Available
Upper Explosive Limit (%) Not Applicable
Surface Tension (dyn/cm or
mN/m)
Not Available
Lower Explosive Limit (%) Not Applicable Volatile Component (%vol) 80
Vapour pressure (kPa) Not Available Gas group Not Available
Solubility in water (g/L) Miscible pH as a solution(1%) Not Available
Vapour density (Air = 1) Not Available VOC g/L Not Available
SECTION 10 STABILITY AND REACTIVITY
Reactivity See section 7
Chemical stability Product is considered stable and hazardous polymerisation will not occur.
Possibility of hazardous
reactions
See section 7
Conditions to avoid See section 7
Incompatible materials See section 7
Chemwatch: 4888-08
Version No: 2.1.1.1
Page 5 of 8
Tracerco T-190a
Issue Date: 25/02/2014
Print Date: 16/05/2014
Continued...
Hazardous decomposition
products
See section 5
SECTION 11 TOXICOLOGICAL INFORMATION
Information on toxicological effects
Inhaled
Evidence shows, or practical experience predicts, that the material produces irritation of the respiratory system, in
a substantial number of individuals, following inhalation. In contrast to most organs, the lung is able to respond to
a chemical insult by first removing or neutralising the irritant and then repairing the damage. The repair process,
which initially evolved to protect mammalian lungs from foreign matter and antigens, may however, produce
further lung damage resulting in the impairment of gas exchange, the primary function of the lungs. Respiratory
tract irritation often results in an inflammatory response involving the recruitment and activation of many cell
types, mainly derived from the vascular system.
Ingestion
Accidental ingestion of the material may be damaging to the health of the individual.
Ingestion may result in nausea, abdominal irritation, pain and vomiting
Skin Contact
Evidence exists, or practical experience predicts, that the material either produces inflammation of the skin in a
substantial number of individuals following direct contact, and/or produces significant inflammation when applied to
the healthy intact skin of animals, for up to four hours, such inflammation being present twenty-four hours or
more after the end of the exposure period. Skin irritation may also be present after prolonged or repeated
exposure; this may result in a form of contact dermatitis (nonallergic). The dermatitis is often characterised by
skin redness (erythema) and swelling (oedema) which may progress to blistering (vesiculation), scaling and
thickening of the epidermis. At the microscopic level there may be intercellular oedema of the spongy layer of the
skin (spongiosis) and intracellular oedema of the epidermis.
Eye
Evidence exists, or practical experience predicts, that the material may cause eye irritation in a substantial
number of individuals and/or may produce significant ocular lesions which are present twenty-four hours or more
after instillation into the eye(s) of experimental animals.
Repeated or prolonged eye contact may cause inflammation characterised by temporary redness (similar to
windburn) of the conjunctiva (conjunctivitis); temporary impairment of vision and/or other transient eye
damage/ulceration may occur.
Chronic
Long-term exposure to respiratory irritants may result in disease of the airways involving difficult breathing and
related systemic problems.
Tracerco T-190a
TOXICITY IRRITATION
Not Available Not Available
sodium
2-(trifluoromethyl)benzoate
TOXICITY IRRITATION
Not Available Not Available
water
TOXICITY IRRITATION
Not Available Not Available
* Value obtained from manufacturer's msds
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances
Tracerco T-190a Not available.
SODIUM
2-(TRIFLUOROMETHYL)BENZOATE
Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This
may be due to a non-allergenic condition known as reactive airways dysfunction syndrome (RADS) which can
occur following exposure to high levels of highly irritating compound. Key criteria for the diagnosis of RADS
include the absence of preceding respiratory disease, in a non-atopic individual, with abrupt onset of
persistent asthma-like symptoms within minutes to hours of a documented exposure to the irritant. A
reversible airflow pattern, on spirometry, with the presence of moderate to severe bronchial hyperreactivity
on methacholine challenge testing and the lack of minimal lymphocytic inflammation, without eosinophilia,
have also been included in the criteria for diagnosis of RADS.
WATER No significant acute toxicological data identified in literature search.
Acute Toxicity Carcinogenicity
Chemwatch: 4888-08
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Tracerco T-190a
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Continued...
Skin Irritation/Corrosion Reproductivity
Serious Eye Damage/Irritation STOT - Single Exposure
Respiratory or Skin
sensitisation
STOT - Repeated Exposure
Mutagenicity Aspiration Hazard
CMR STATUS
Not Applicable
SECTION 12 ECOLOGICAL INFORMATION
Toxicity
DO NOT discharge into sewer or waterways.
Persistence and degradability
Ingredient Persistence: Water/Soil Persistence: Air
Not Available Not Available Not Available
Bioaccumulative potential
Ingredient Bioaccumulation
Not Available Not Available
Mobility in soil
Ingredient Mobility
Not Available Not Available
SECTION 13 DISPOSAL CONSIDERATIONS
Waste treatment methods
Product / Packaging disposal
Recycle wherever possible.
Consult manufacturer for recycling options or consult local or regional waste management authority for
disposal if no suitable treatment or disposal facility can be identified.
Dispose of by: burial in a land-fill specifically licenced to accept chemical and / or pharmaceutical wastes or
incineration in a licenced apparatus (after admixture with suitable combustible material).
Decontaminate empty containers.
SECTION 14 TRANSPORT INFORMATION
Labels Required
Marine Pollutant NO
HAZCHEM Not Applicable
Land transport (): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
SECTION 15 REGULATORY INFORMATION
Safety, health and environmental regulations / legislation specific for the substance or mixture
sodium
2-(trifluoromethyl)benzoate(2966-44-1)
is found on the following regulatory
lists
water(7732-18-5) is found on the
following regulatory lists
"WHO Model List of Essential Medicines - Adults","Australia Inventory of Chemical Substances
(AICS)","OECD List of High Production Volume (HPV) Chemicals","OSPAR National List of Candidates for
Substitution Norway","IMO IBC Code Chapter 18: List of products to which the Code does not
Chemwatch: 4888-08
Version No: 2.1.1.1
Page 7 of 8
Tracerco T-190a
Issue Date: 25/02/2014
Print Date: 16/05/2014
Continued...
apply","Sigma-AldrichTransport Information","Australia High Volume Industrial Chemical List
(HVICL)","International Fragrance Association (IFRA) Survey: Transparency List"
SECTION 16 OTHER INFORMATION
Other information
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the
Chemwatch Classification committee using available literature references.
A list of reference resources used to assist the committee may be found at:
www.chemwatch.net/references
The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards
are Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current
or available engineering controls must be considered.
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from CHEMWATCH. TEL (+61 3) 9572 4700.
Chemwatch: 4888-08
Version No: 2.1.1.1
Page 8 of 8
Tracerco T-190a
Issue Date: 25/02/2014
Print Date: 16/05/2014
end of SDS
Tracerco Chemwatch Hazard Alert Code: 2
Tracerco T-190b
Chemwatch: 4888-09
Version No: 2.1.1.1
Safety Data Sheet according to WHS and ADG requirements
Issue Date: 25/02/2014
Print Date: 16/05/2014
Initial Date: Not Available
S.GHS.AUS.EN
SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING
Product Identifier
Product name Tracerco T-190b
Chemical Name Not Applicable
Synonyms Not Available
Proper shipping name Not Applicable
Chemical formula Not Applicable
Other means of identification Not Available
CAS number Not Applicable
Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses Use according to manufacturer's directions.
Details of the supplier of the safety data sheet
Registered company name Tracerco
Address
2 Harris Road Malaga 6090 WA
Australia
Telephone +61 8 9209 3905
Fax +61 8 9209 3725
Website www.tracerco.com
Email admin.aus@tracerco.com
Emergency telephone number
Association / Organisation Not Available
Emergency telephone numbers +61 8 9209 3905 (9am-5pm)
Other emergency telephone
numbers
+61 8 9209 3905 (9am-5pm)
SECTION 2 HAZARDS IDENTIFICATION
Classification of the substance or mixture
HAZARDOUS CHEMICAL. NON-DANGEROUS GOODS. According to the Model WHS Regulations and the ADG Code.
CHEMWATCH HAZARD RATINGS
Max Min
Flammability 0
Toxicity 2

Body Contact 2

Reactivity 0
Chronic 0
0 = Minimum
1 = Low
2 = Moderate
3 = High
4 = Extreme
Poisons Schedule Not Applicable
GHS Classification
[1]
Acute Toxicity (Oral) Category 4, Acute Toxicity (Inhalation) Category 4, Skin Corrosion/Irritation Category 2, Eye
Irrit. 2, STOT - SE (Resp. Irr.) Category 3
Continued...
Legend:
1. Classified by Chemwatch; 2. Classification drawn from HSIS ; 3. Classification drawn from EC Directive
1272/2008 - Annex VI
Label elements
GHS label elements
SIGNAL WORD WARNING
Hazard statement(s)
H302 Harmful if swallowed
H332 Harmful if inhaled
H315 Causes skin irritation
H319 Causes serious eye irritation
H335 May cause respiratory irritation
Precautionary statement(s): Prevention
P271 Use only outdoors or in a well-ventilated area.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Precautionary statement(s): Response
P321 Specific treatment (see advice on this label).
P305+P351+P338
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/attention.
P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor/physician/first aider/if you feel unwell.
Precautionary statement(s): Storage
P405 Store locked up.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
Precautionary statement(s): Disposal
P501 Dispose of contents/container to authorised chemical landfill or if organic to high temperature incineration
SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
Substances
See section below for composition of Mixtures
Mixtures
CAS No %[weight] Name
69226-41-1 10-30 sodium 3-(trifluoromethyl)benzoate
7732-18-5 >60 water
SECTION 4 FIRST AID MEASURES
Description of first aid measures
Eye Contact
If this product comes in contact with the eyes:
Wash out immediately with fresh running water.
Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids
by occasionally lifting the upper and lower lids.
Seek medical attention without delay; if pain persists or recurs seek medical attention.
Chemwatch: 4888-09
Version No: 2.1.1.1
Page 2 of 8
Tracerco T-190b
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Print Date: 16/05/2014
Continued...
Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
Skin Contact
If skin contact occurs:
Immediately remove all contaminated clothing, including footwear.
Flush skin and hair with running water (and soap if available).
Seek medical attention in event of irritation.
Inhalation
If fumes, aerosols or combustion products are inhaled remove from contaminated area.
Other measures are usually unnecessary.
Ingestion
If swallowed do NOT induce vomiting.
If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain
open airway and prevent aspiration.
Observe the patient carefully.
Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming
unconscious.
Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink.
Seek medical advice.
Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5 FIREFIGHTING MEASURES
Extinguishing media
There is no restriction on the type of extinguisher which may be used.
Use extinguishing media suitable for surrounding area.
Special hazards arising from the substrate or mixture
Fire Incompatibility None known.
Advice for firefighters
Fire Fighting
Alert Fire Brigade and tell them location and nature of hazard.
Wear breathing apparatus plus protective gloves in the event of a fire.
Prevent, by any means available, spillage from entering drains or water courses.
Use fire fighting procedures suitable for surrounding area.
Fire/Explosion Hazard
Non combustible.
Not considered to be a significant fire risk.
Expansion or decomposition on heating may lead to violent rupture of containers.
Decomposes on heating and may produce toxic fumes of carbon monoxide (CO).
SECTION 6 ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Minor Spills
Clean up all spills immediately.
Avoid breathing vapours and contact with skin and eyes.
Control personal contact with the substance, by using protective equipment.
Contain and absorb spill with sand, earth, inert material or vermiculite.
Major Spills
Minor hazard.
Clear area of personnel.
Alert Fire Brigade and tell them location and nature of hazard.
Control personal contact with the substance, by using protective equipment as required.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
SECTION 7 HANDLING AND STORAGE
Precautions for safe handling
Safe handling
Limit all unnecessary personal contact.
Wear protective clothing when risk of exposure occurs.
Use in a well-ventilated area.
When handling DO NOT eat, drink or smoke.
Chemwatch: 4888-09
Version No: 2.1.1.1
Page 3 of 8
Tracerco T-190b
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Print Date: 16/05/2014
Continued...
Other information
Store in original containers.
Keep containers securely sealed.
Store in a cool, dry, well-ventilated area.
Store away from incompatible materials and foodstuff containers.
Conditions for safe storage, including any incompatibilities
Suitable container
Polyethylene or polypropylene container.
Packing as recommended by manufacturer.
Check all containers are clearly labelled and free from leaks.
Storage incompatibility None known
PACKAGE MATERIAL INCOMPATIBILITIES
Not Available
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Control parameters
OCCUPATIONAL EXPOSURE LIMITS (OEL)
INGREDIENT DATA
Not Available
EMERGENCY LIMITS
Ingredient TEEL-0 TEEL-1 TEEL-2 TEEL-3
water 500(ppm) 500(ppm) 500(ppm) 500(ppm)
Ingredient Original IDLH Revised IDLH
Tracerco T-190b Not Available Not Available
Exposure controls
Appropriate engineering
controls
Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard.
Well-designed engineering controls can be highly effective in protecting workers and will typically be independent
of worker interactions to provide this high level of protection.
The basic types of engineering controls are:
Process controls which involve changing the way a job activity or process is done to reduce the risk.
Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker
and ventilation that strategically "adds" and "removes" air in the work environment.
Personal protection
Eye and face protection
Safety glasses with side shields.
Chemical goggles.
Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written
policy document, describing the wearing of lenses or restrictions on use, should be created for each workplace or
task.
Skin protection See Hand protection below
Hand protection
The selection of suitable gloves does not only depend on the material, but also on further marks of quality which
vary from manufacturer to manufacturer. Where the chemical is a preparation of several substances, the
resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the
application.
The exact break through time for substances has to be obtained from the manufacturer of the protective gloves
and.has to be observed when making a final choice.
Suitability and durability of glove type is dependent on usage.
Body protection See Other protection below
Other protection
Overalls.
Eyewash unit.
Thermal hazards Not Available
Recommended material(s) Respiratory protection
Chemwatch: 4888-09
Version No: 2.1.1.1
Page 4 of 8
Tracerco T-190b
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Print Date: 16/05/2014
Continued...
GLOVE SELECTION INDEX
Glove selection is based on a modified presentation of the:
"Forsberg Clothing Performance Index".
The effect(s) of the following substance(s) are taken into account in the
computer-generated selection:
Tracerco T-190b
Material CPI
BUTYL A
NEOPRENE A
VITON A
* CPI - Chemwatch Performance Index
A: Best Selection
B: Satisfactory; may degrade after 4 hours continuous immersion
C: Poor to Dangerous Choice for other than short term immersion
NOTE: As a series of factors will influence the actual performance of the
glove, a final selection must be based on detailed observation. -
* Where the glove is to be used on a short term, casual or infrequent
basis, factors such as "feel" or convenience (e.g. disposability), may
dictate a choice of gloves which might otherwise be unsuitable following
long-term or frequent use. A qualified practitioner should be consulted.
Particulate. (AS/NZS 1716 & 1715, EN 143:000 & 149:001, ANSI Z88 or
national equivalent)
Where the concentration of gas/particulates in the breathing zone,
approaches or exceeds the "Exposure Standard" (or ES), respiratory
protection is required.
Degree of protection varies with both face-piece and Class of filter;
the nature of protection varies with Type of filter.
Required
Minimum
Protection Factor
Half-Face
Respirator
Full-Face
Respirator
Powered Air
Respirator
up to 10 x ES -AUS P2 -
-PAPR-AUS /
Class 1 P2
up to 50 x ES -
-AUS / Class
1 P2
-
up to 100 x ES - -2 P2 -PAPR-2 P2 ^
^ - Full-face
A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 =
Acid gas or hydrogen cyanide(HCN), B3 = Acid gas or hydrogen
cyanide(HCN), E = Sulfur dioxide(SO2), G = Agricultural chemicals,
K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB =
Methyl bromide, AX = Low boiling point organic compounds(below
65 degC)
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Appearance Liquid; mixes with water.
Physical state Liquid Relative density (Water = 1) Not Available
Odour Not Available
Partition coefficient n-octanol /
water
Not Available
Odour threshold Not Available Auto-ignition temperature (C) Not Applicable
pH (as supplied) Not Available Decomposition temperature Not Available
Melting point / freezing point
(C)
Not Available Viscosity (cSt) Not Available
Initial boiling point and boiling
range (C)
Not Available Molecular weight (g/mol) Not Applicable
Flash point (C) Not Applicable Taste Not Available
Evaporation rate Not Available Explosive properties Not Available
Flammability Not Applicable Oxidising properties Not Available
Upper Explosive Limit (%) Not Applicable
Surface Tension (dyn/cm or
mN/m)
Not Available
Lower Explosive Limit (%) Not Applicable Volatile Component (%vol) 80
Vapour pressure (kPa) Not Available Gas group Not Available
Solubility in water (g/L) Miscible pH as a solution(1%) Not Available
Vapour density (Air = 1) Not Available VOC g/L Not Available
SECTION 10 STABILITY AND REACTIVITY
Reactivity See section 7
Chemical stability Product is considered stable and hazardous polymerisation will not occur.
Possibility of hazardous
reactions
See section 7
Conditions to avoid See section 7
Incompatible materials See section 7
Chemwatch: 4888-09
Version No: 2.1.1.1
Page 5 of 8
Tracerco T-190b
Issue Date: 25/02/2014
Print Date: 16/05/2014
Continued...
Hazardous decomposition
products
See section 5
SECTION 11 TOXICOLOGICAL INFORMATION
Information on toxicological effects
Inhaled
Evidence shows, or practical experience predicts, that the material produces irritation of the respiratory system, in
a substantial number of individuals, following inhalation. In contrast to most organs, the lung is able to respond to
a chemical insult by first removing or neutralising the irritant and then repairing the damage. The repair process,
which initially evolved to protect mammalian lungs from foreign matter and antigens, may however, produce
further lung damage resulting in the impairment of gas exchange, the primary function of the lungs. Respiratory
tract irritation often results in an inflammatory response involving the recruitment and activation of many cell
types, mainly derived from the vascular system.
Ingestion
Accidental ingestion of the material may be damaging to the health of the individual.
Ingestion may result in nausea, abdominal irritation, pain and vomiting
Skin Contact
Evidence exists, or practical experience predicts, that the material either produces inflammation of the skin in a
substantial number of individuals following direct contact, and/or produces significant inflammation when applied to
the healthy intact skin of animals, for up to four hours, such inflammation being present twenty-four hours or
more after the end of the exposure period. Skin irritation may also be present after prolonged or repeated
exposure; this may result in a form of contact dermatitis (nonallergic). The dermatitis is often characterised by
skin redness (erythema) and swelling (oedema) which may progress to blistering (vesiculation), scaling and
thickening of the epidermis. At the microscopic level there may be intercellular oedema of the spongy layer of the
skin (spongiosis) and intracellular oedema of the epidermis.
Eye
Evidence exists, or practical experience predicts, that the material may cause eye irritation in a substantial
number of individuals and/or may produce significant ocular lesions which are present twenty-four hours or more
after instillation into the eye(s) of experimental animals.
Repeated or prolonged eye contact may cause inflammation characterised by temporary redness (similar to
windburn) of the conjunctiva (conjunctivitis); temporary impairment of vision and/or other transient eye
damage/ulceration may occur.
Chronic
Long-term exposure to respiratory irritants may result in disease of the airways involving difficult breathing and
related systemic problems.
Tracerco T-190b
TOXICITY IRRITATION
Not Available Not Available
sodium
3-(trifluoromethyl)benzoate
TOXICITY IRRITATION
Subcutaneous (Frog) LD50: 848
mg/kg
Not Available Not Available
water
TOXICITY IRRITATION
Not Available Not Available
* Value obtained from manufacturer's msds
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances
Tracerco T-190b Not available.
SODIUM
3-(TRIFLUOROMETHYL)BENZOATE
Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This
may be due to a non-allergenic condition known as reactive airways dysfunction syndrome (RADS) which can
occur following exposure to high levels of highly irritating compound. Key criteria for the diagnosis of RADS
include the absence of preceding respiratory disease, in a non-atopic individual, with abrupt onset of
persistent asthma-like symptoms within minutes to hours of a documented exposure to the irritant. A
reversible airflow pattern, on spirometry, with the presence of moderate to severe bronchial hyperreactivity
on methacholine challenge testing and the lack of minimal lymphocytic inflammation, without eosinophilia,
have also been included in the criteria for diagnosis of RADS.
WATER No significant acute toxicological data identified in literature search.
Chemwatch: 4888-09
Version No: 2.1.1.1
Page 6 of 8
Tracerco T-190b
Issue Date: 25/02/2014
Print Date: 16/05/2014
Continued...
Acute Toxicity Carcinogenicity
Skin Irritation/Corrosion Reproductivity
Serious Eye Damage/Irritation STOT - Single Exposure
Respiratory or Skin
sensitisation
STOT - Repeated Exposure
Mutagenicity Aspiration Hazard
CMR STATUS
Not Applicable
SECTION 12 ECOLOGICAL INFORMATION
Toxicity
DO NOT discharge into sewer or waterways.
Persistence and degradability
Ingredient Persistence: Water/Soil Persistence: Air
Not Available Not Available Not Available
Bioaccumulative potential
Ingredient Bioaccumulation
Not Available Not Available
Mobility in soil
Ingredient Mobility
Not Available Not Available
SECTION 13 DISPOSAL CONSIDERATIONS
Waste treatment methods
Product / Packaging disposal
Recycle wherever possible.
Consult manufacturer for recycling options or consult local or regional waste management authority for
disposal if no suitable treatment or disposal facility can be identified.
Dispose of by: burial in a land-fill specifically licenced to accept chemical and / or pharmaceutical wastes or
incineration in a licenced apparatus (after admixture with suitable combustible material).
Decontaminate empty containers.
SECTION 14 TRANSPORT INFORMATION
Labels Required
Marine Pollutant NO
HAZCHEM Not Applicable
Land transport (): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
SECTION 15 REGULATORY INFORMATION
Safety, health and environmental regulations / legislation specific for the substance or mixture
sodium
3-(trifluoromethyl)benzoate(69226-41-1)
is found on the following regulatory
lists
Chemwatch: 4888-09
Version No: 2.1.1.1
Page 7 of 8
Tracerco T-190b
Issue Date: 25/02/2014
Print Date: 16/05/2014
Continued...
water(7732-18-5) is found on the
following regulatory lists
"WHO Model List of Essential Medicines - Adults","Australia Inventory of Chemical Substances
(AICS)","OECD List of High Production Volume (HPV) Chemicals","OSPAR National List of Candidates for
Substitution Norway","IMO IBC Code Chapter 18: List of products to which the Code does not
apply","Sigma-AldrichTransport Information","Australia High Volume Industrial Chemical List
(HVICL)","International Fragrance Association (IFRA) Survey: Transparency List"
SECTION 16 OTHER INFORMATION
Other information
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the
Chemwatch Classification committee using available literature references.
A list of reference resources used to assist the committee may be found at:
www.chemwatch.net/references
The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards
are Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current
or available engineering controls must be considered.
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from CHEMWATCH. TEL (+61 3) 9572 4700.
Chemwatch: 4888-09
Version No: 2.1.1.1
Page 8 of 8
Tracerco T-190b
Issue Date: 25/02/2014
Print Date: 16/05/2014
end of SDS
Tracerco Chemwatch Hazard Alert Code: 2
Tracerco T-190c
Chemwatch: 4888-10
Version No: 2.1.1.1
Safety Data Sheet according to WHS and ADG requirements
Issue Date: 25/02/2014
Print Date: 16/05/2014
Initial Date: Not Available
S.GHS.AUS.EN
SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING
Product Identifier
Product name Tracerco T-190c
Chemical Name Not Applicable
Synonyms Not Available
Proper shipping name Not Applicable
Chemical formula Not Applicable
Other means of identification Not Available
CAS number Not Applicable
Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses Use according to manufacturer's directions.
Details of the supplier of the safety data sheet
Registered company name Tracerco
Address
2 Harris Road Malaga 6090 WA
Australia
Telephone +61 8 9209 3905
Fax +61 8 9209 3725
Website www.tracerco.com
Email admin.aus@tracerco.com
Emergency telephone number
Association / Organisation Not Available
Emergency telephone numbers +61 8 9209 3905 (9am-5pm)
Other emergency telephone
numbers
+61 8 9209 3905 (9am-5pm)
SECTION 2 HAZARDS IDENTIFICATION
Classification of the substance or mixture
HAZARDOUS CHEMICAL. NON-DANGEROUS GOODS. According to the Model WHS Regulations and the ADG Code.
CHEMWATCH HAZARD RATINGS
Max Min
Flammability 0
Toxicity 2

Body Contact 2

Reactivity 0
Chronic 0
0 = Minimum
1 = Low
2 = Moderate
3 = High
4 = Extreme
Poisons Schedule Not Applicable
GHS Classification
[1]
Acute Toxicity (Oral) Category 4, Acute Toxicity (Inhalation) Category 4, Skin Corrosion/Irritation Category 2, Eye
Irrit. 2, STOT - SE (Resp. Irr.) Category 3
Continued...
Legend:
1. Classified by Chemwatch; 2. Classification drawn from HSIS ; 3. Classification drawn from EC Directive
1272/2008 - Annex VI
Label elements
GHS label elements
SIGNAL WORD WARNING
Hazard statement(s)
H302 Harmful if swallowed
H332 Harmful if inhaled
H315 Causes skin irritation
H319 Causes serious eye irritation
H335 May cause respiratory irritation
Precautionary statement(s): Prevention
P271 Use only outdoors or in a well-ventilated area.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Precautionary statement(s): Response
P321 Specific treatment (see advice on this label).
P305+P351+P338
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/attention.
P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor/physician/first aider/if you feel unwell.
Precautionary statement(s): Storage
P405 Store locked up.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
Precautionary statement(s): Disposal
P501 Dispose of contents/container to authorised chemical landfill or if organic to high temperature incineration
SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
Substances
See section below for composition of Mixtures
Mixtures
CAS No %[weight] Name
25832-58-0 10-30 sodium 4-(trifluoromethyl)benzoate
7732-18-5 >60 water
SECTION 4 FIRST AID MEASURES
Description of first aid measures
Eye Contact
If this product comes in contact with the eyes:
Wash out immediately with fresh running water.
Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids
by occasionally lifting the upper and lower lids.
Seek medical attention without delay; if pain persists or recurs seek medical attention.
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Tracerco T-190c
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Continued...
Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
Skin Contact
If skin contact occurs:
Immediately remove all contaminated clothing, including footwear.
Flush skin and hair with running water (and soap if available).
Seek medical attention in event of irritation.
Inhalation
If fumes, aerosols or combustion products are inhaled remove from contaminated area.
Other measures are usually unnecessary.
Ingestion
If swallowed do NOT induce vomiting.
If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain
open airway and prevent aspiration.
Observe the patient carefully.
Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming
unconscious.
Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink.
Seek medical advice.
Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5 FIREFIGHTING MEASURES
Extinguishing media
There is no restriction on the type of extinguisher which may be used.
Use extinguishing media suitable for surrounding area.
Special hazards arising from the substrate or mixture
Fire Incompatibility None known.
Advice for firefighters
Fire Fighting
Alert Fire Brigade and tell them location and nature of hazard.
Wear breathing apparatus plus protective gloves in the event of a fire.
Prevent, by any means available, spillage from entering drains or water courses.
Use fire fighting procedures suitable for surrounding area.
Fire/Explosion Hazard
Non combustible.
Not considered to be a significant fire risk.
Expansion or decomposition on heating may lead to violent rupture of containers.
Decomposes on heating and may produce toxic fumes of carbon monoxide (CO).
SECTION 6 ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Minor Spills
Clean up all spills immediately.
Avoid breathing vapours and contact with skin and eyes.
Control personal contact with the substance, by using protective equipment.
Contain and absorb spill with sand, earth, inert material or vermiculite.
Major Spills
Minor hazard.
Clear area of personnel.
Alert Fire Brigade and tell them location and nature of hazard.
Control personal contact with the substance, by using protective equipment as required.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
SECTION 7 HANDLING AND STORAGE
Precautions for safe handling
Safe handling
Limit all unnecessary personal contact.
Wear protective clothing when risk of exposure occurs.
Use in a well-ventilated area.
When handling DO NOT eat, drink or smoke.
Chemwatch: 4888-10
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Continued...
Other information
Store in original containers.
Keep containers securely sealed.
Store in a cool, dry, well-ventilated area.
Store away from incompatible materials and foodstuff containers.
Conditions for safe storage, including any incompatibilities
Suitable container
Polyethylene or polypropylene container.
Packing as recommended by manufacturer.
Check all containers are clearly labelled and free from leaks.
Storage incompatibility None known
PACKAGE MATERIAL INCOMPATIBILITIES
Not Available
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Control parameters
OCCUPATIONAL EXPOSURE LIMITS (OEL)
INGREDIENT DATA
Not Available
EMERGENCY LIMITS
Ingredient TEEL-0 TEEL-1 TEEL-2 TEEL-3
water 500(ppm) 500(ppm) 500(ppm) 500(ppm)
Ingredient Original IDLH Revised IDLH
Tracerco T-190c Not Available Not Available
Exposure controls
Appropriate engineering
controls
Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard.
Well-designed engineering controls can be highly effective in protecting workers and will typically be independent
of worker interactions to provide this high level of protection.
The basic types of engineering controls are:
Process controls which involve changing the way a job activity or process is done to reduce the risk.
Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker
and ventilation that strategically "adds" and "removes" air in the work environment.
Personal protection
Eye and face protection
Safety glasses with side shields.
Chemical goggles.
Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written
policy document, describing the wearing of lenses or restrictions on use, should be created for each workplace or
task.
Skin protection See Hand protection below
Hand protection
The selection of suitable gloves does not only depend on the material, but also on further marks of quality which
vary from manufacturer to manufacturer. Where the chemical is a preparation of several substances, the
resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the
application.
The exact break through time for substances has to be obtained from the manufacturer of the protective gloves
and.has to be observed when making a final choice.
Suitability and durability of glove type is dependent on usage.
Body protection See Other protection below
Other protection
Overalls.
Eyewash unit.
Thermal hazards Not Available
Recommended material(s) Respiratory protection
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Continued...
GLOVE SELECTION INDEX
Glove selection is based on a modified presentation of the:
"Forsberg Clothing Performance Index".
The effect(s) of the following substance(s) are taken into account in the
computer-generated selection:
Tracerco T-190c
Material CPI
BUTYL A
NEOPRENE A
VITON A
* CPI - Chemwatch Performance Index
A: Best Selection
B: Satisfactory; may degrade after 4 hours continuous immersion
C: Poor to Dangerous Choice for other than short term immersion
NOTE: As a series of factors will influence the actual performance of the
glove, a final selection must be based on detailed observation. -
* Where the glove is to be used on a short term, casual or infrequent
basis, factors such as "feel" or convenience (e.g. disposability), may
dictate a choice of gloves which might otherwise be unsuitable following
long-term or frequent use. A qualified practitioner should be consulted.
Particulate. (AS/NZS 1716 & 1715, EN 143:000 & 149:001, ANSI Z88 or
national equivalent)
Where the concentration of gas/particulates in the breathing zone,
approaches or exceeds the "Exposure Standard" (or ES), respiratory
protection is required.
Degree of protection varies with both face-piece and Class of filter;
the nature of protection varies with Type of filter.
Required
Minimum
Protection Factor
Half-Face
Respirator
Full-Face
Respirator
Powered Air
Respirator
up to 10 x ES -AUS P2 -
-PAPR-AUS /
Class 1 P2
up to 50 x ES -
-AUS / Class
1 P2
-
up to 100 x ES - -2 P2 -PAPR-2 P2 ^
^ - Full-face
A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 =
Acid gas or hydrogen cyanide(HCN), B3 = Acid gas or hydrogen
cyanide(HCN), E = Sulfur dioxide(SO2), G = Agricultural chemicals,
K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB =
Methyl bromide, AX = Low boiling point organic compounds(below
65 degC)
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Appearance Liquid; mixes with water.
Physical state Liquid Relative density (Water = 1) Not Available
Odour Not Available
Partition coefficient n-octanol /
water
Not Available
Odour threshold Not Available Auto-ignition temperature (C) Not Applicable
pH (as supplied) Not Available Decomposition temperature Not Available
Melting point / freezing point
(C)
Not Available Viscosity (cSt) Not Available
Initial boiling point and boiling
range (C)
Not Available Molecular weight (g/mol) Not Applicable
Flash point (C) Not Applicable Taste Not Available
Evaporation rate Not Available Explosive properties Not Available
Flammability Not Applicable Oxidising properties Not Available
Upper Explosive Limit (%) Not Applicable
Surface Tension (dyn/cm or
mN/m)
Not Available
Lower Explosive Limit (%) Not Applicable Volatile Component (%vol) 80
Vapour pressure (kPa) Not Available Gas group Not Available
Solubility in water (g/L) Miscible pH as a solution(1%) Not Available
Vapour density (Air = 1) Not Available VOC g/L Not Available
SECTION 10 STABILITY AND REACTIVITY
Reactivity See section 7
Chemical stability Product is considered stable and hazardous polymerisation will not occur.
Possibility of hazardous
reactions
See section 7
Conditions to avoid See section 7
Incompatible materials See section 7
Chemwatch: 4888-10
Version No: 2.1.1.1
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Tracerco T-190c
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Continued...
Hazardous decomposition
products
See section 5
SECTION 11 TOXICOLOGICAL INFORMATION
Information on toxicological effects
Inhaled
Evidence shows, or practical experience predicts, that the material produces irritation of the respiratory system, in
a substantial number of individuals, following inhalation. In contrast to most organs, the lung is able to respond to
a chemical insult by first removing or neutralising the irritant and then repairing the damage. The repair process,
which initially evolved to protect mammalian lungs from foreign matter and antigens, may however, produce
further lung damage resulting in the impairment of gas exchange, the primary function of the lungs. Respiratory
tract irritation often results in an inflammatory response involving the recruitment and activation of many cell
types, mainly derived from the vascular system.
Ingestion
Accidental ingestion of the material may be damaging to the health of the individual.
Ingestion may result in nausea, abdominal irritation, pain and vomiting
Skin Contact
Evidence exists, or practical experience predicts, that the material either produces inflammation of the skin in a
substantial number of individuals following direct contact, and/or produces significant inflammation when applied to
the healthy intact skin of animals, for up to four hours, such inflammation being present twenty-four hours or
more after the end of the exposure period. Skin irritation may also be present after prolonged or repeated
exposure; this may result in a form of contact dermatitis (nonallergic). The dermatitis is often characterised by
skin redness (erythema) and swelling (oedema) which may progress to blistering (vesiculation), scaling and
thickening of the epidermis. At the microscopic level there may be intercellular oedema of the spongy layer of the
skin (spongiosis) and intracellular oedema of the epidermis.
Eye
Evidence exists, or practical experience predicts, that the material may cause eye irritation in a substantial
number of individuals and/or may produce significant ocular lesions which are present twenty-four hours or more
after instillation into the eye(s) of experimental animals.
Repeated or prolonged eye contact may cause inflammation characterised by temporary redness (similar to
windburn) of the conjunctiva (conjunctivitis); temporary impairment of vision and/or other transient eye
damage/ulceration may occur.
Chronic
Long-term exposure to respiratory irritants may result in disease of the airways involving difficult breathing and
related systemic problems.
Tracerco T-190c
TOXICITY IRRITATION
Not Available Not Available
sodium
4-(trifluoromethyl)benzoate
TOXICITY IRRITATION
Not Available Not Available
water
TOXICITY IRRITATION
Not Available Not Available
* Value obtained from manufacturer's msds
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances
Tracerco T-190c Not available.
SODIUM
4-(TRIFLUOROMETHYL)BENZOATE
Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This
may be due to a non-allergenic condition known as reactive airways dysfunction syndrome (RADS) which can
occur following exposure to high levels of highly irritating compound. Key criteria for the diagnosis of RADS
include the absence of preceding respiratory disease, in a non-atopic individual, with abrupt onset of
persistent asthma-like symptoms within minutes to hours of a documented exposure to the irritant. A
reversible airflow pattern, on spirometry, with the presence of moderate to severe bronchial hyperreactivity
on methacholine challenge testing and the lack of minimal lymphocytic inflammation, without eosinophilia,
have also been included in the criteria for diagnosis of RADS.
WATER No significant acute toxicological data identified in literature search.
Acute Toxicity Carcinogenicity
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Continued...
Skin Irritation/Corrosion Reproductivity
Serious Eye Damage/Irritation STOT - Single Exposure
Respiratory or Skin
sensitisation
STOT - Repeated Exposure
Mutagenicity Aspiration Hazard
CMR STATUS
Not Applicable
SECTION 12 ECOLOGICAL INFORMATION
Toxicity
DO NOT discharge into sewer or waterways.
Persistence and degradability
Ingredient Persistence: Water/Soil Persistence: Air
Not Available Not Available Not Available
Bioaccumulative potential
Ingredient Bioaccumulation
Not Available Not Available
Mobility in soil
Ingredient Mobility
Not Available Not Available
SECTION 13 DISPOSAL CONSIDERATIONS
Waste treatment methods
Product / Packaging disposal
Recycle wherever possible.
Consult manufacturer for recycling options or consult local or regional waste management authority for
disposal if no suitable treatment or disposal facility can be identified.
Dispose of by: burial in a land-fill specifically licenced to accept chemical and / or pharmaceutical wastes or
incineration in a licenced apparatus (after admixture with suitable combustible material).
Decontaminate empty containers.
SECTION 14 TRANSPORT INFORMATION
Labels Required
Marine Pollutant NO
HAZCHEM Not Applicable
Land transport (): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
SECTION 15 REGULATORY INFORMATION
Safety, health and environmental regulations / legislation specific for the substance or mixture
sodium
4-(trifluoromethyl)benzoate(25832-58-0)
is found on the following regulatory
lists
water(7732-18-5) is found on the
following regulatory lists
"WHO Model List of Essential Medicines - Adults","Australia Inventory of Chemical Substances
(AICS)","OECD List of High Production Volume (HPV) Chemicals","OSPAR National List of Candidates for
Substitution Norway","IMO IBC Code Chapter 18: List of products to which the Code does not
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Continued...
apply","Sigma-AldrichTransport Information","Australia High Volume Industrial Chemical List
(HVICL)","International Fragrance Association (IFRA) Survey: Transparency List"
SECTION 16 OTHER INFORMATION
Other information
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the
Chemwatch Classification committee using available literature references.
A list of reference resources used to assist the committee may be found at:
www.chemwatch.net/references
The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards
are Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current
or available engineering controls must be considered.
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from CHEMWATCH. TEL (+61 3) 9572 4700.
Chemwatch: 4888-10
Version No: 2.1.1.1
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Tracerco T-190c
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end of SDS
Tracerco Chemwatch Hazard Alert Code: 2
Tracerco T-194a
Chemwatch: 4888-11
Version No: 2.1.1.1
Safety Data Sheet according to WHS and ADG requirements
Issue Date: 25/02/2014
Print Date: 16/05/2014
Initial Date: Not Available
S.GHS.AUS.EN
SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING
Product Identifier
Product name Tracerco T-194a
Chemical Name Not Applicable
Synonyms Not Available
Proper shipping name Not Applicable
Chemical formula Not Applicable
Other means of identification Not Available
CAS number Not Applicable
Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses Use according to manufacturer's directions.
Details of the supplier of the safety data sheet
Registered company name Tracerco
Address
2 Harris Road Malaga 6090 WA
Australia
Telephone +61 8 9209 3905
Fax +61 8 9209 3725
Website www.tracerco.com
Email admin.aus@tracerco.com
Emergency telephone number
Association / Organisation Not Available
Emergency telephone numbers +61 8 9209 3905 (9am-5pm)
Other emergency telephone
numbers
+61 8 9209 3905 (9am-5pm)
SECTION 2 HAZARDS IDENTIFICATION
Classification of the substance or mixture
HAZARDOUS CHEMICAL. NON-DANGEROUS GOODS. According to the Model WHS Regulations and the ADG Code.
CHEMWATCH HAZARD RATINGS
Max Min
Flammability 0
Toxicity 1

Body Contact 2

Reactivity 0
Chronic 0
0 = Minimum
1 = Low
2 = Moderate
3 = High
4 = Extreme
Poisons Schedule Not Applicable
GHS Classification
[1]
Skin Corrosion/Irritation Category 2, Eye Irrit. 2, STOT - SE (Resp. Irr.) Category 3
Continued...
Legend:
1. Classified by Chemwatch; 2. Classification drawn from HSIS ; 3. Classification drawn from EC Directive
1272/2008 - Annex VI
Label elements
GHS label elements
SIGNAL WORD WARNING
Hazard statement(s)
H315 Causes skin irritation
H319 Causes serious eye irritation
H335 May cause respiratory irritation
Precautionary statement(s): Prevention
P271 Use only outdoors or in a well-ventilated area.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Precautionary statement(s): Response
P321 Specific treatment (see advice on this label).
P305+P351+P338
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P312 Call a POISON CENTER/doctor/physician/first aider/if you feel unwell.
P337+P313 If eye irritation persists: Get medical advice/attention.
Precautionary statement(s): Storage
P405 Store locked up.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
Precautionary statement(s): Disposal
P501 Dispose of contents/container to authorised chemical landfill or if organic to high temperature incineration
SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
Substances
See section below for composition of Mixtures
Mixtures
CAS No %[weight] Name
67852-79-3 10-30 2,3,4,5-tetrafluorobenzoic acid, sodium
7732-18-5 >60 water
SECTION 4 FIRST AID MEASURES
Description of first aid measures
Eye Contact
If this product comes in contact with the eyes:
Wash out immediately with fresh running water.
Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids
by occasionally lifting the upper and lower lids.
Seek medical attention without delay; if pain persists or recurs seek medical attention.
Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
Skin Contact
If skin contact occurs:
Immediately remove all contaminated clothing, including footwear.
Flush skin and hair with running water (and soap if available).
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Continued...
Seek medical attention in event of irritation.
Inhalation
If fumes, aerosols or combustion products are inhaled remove from contaminated area.
Other measures are usually unnecessary.
Ingestion
If swallowed do NOT induce vomiting.
If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain
open airway and prevent aspiration.
Observe the patient carefully.
Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming
unconscious.
Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink.
Seek medical advice.
Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5 FIREFIGHTING MEASURES
Extinguishing media
There is no restriction on the type of extinguisher which may be used.
Use extinguishing media suitable for surrounding area.
Special hazards arising from the substrate or mixture
Fire Incompatibility None known.
Advice for firefighters
Fire Fighting
Alert Fire Brigade and tell them location and nature of hazard.
Wear breathing apparatus plus protective gloves in the event of a fire.
Prevent, by any means available, spillage from entering drains or water courses.
Use fire fighting procedures suitable for surrounding area.
Fire/Explosion Hazard
Non combustible.
Not considered to be a significant fire risk.
Expansion or decomposition on heating may lead to violent rupture of containers.
Decomposes on heating and may produce toxic fumes of carbon monoxide (CO).
SECTION 6 ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Minor Spills
Clean up all spills immediately.
Avoid breathing vapours and contact with skin and eyes.
Control personal contact with the substance, by using protective equipment.
Contain and absorb spill with sand, earth, inert material or vermiculite.
Major Spills
Minor hazard.
Clear area of personnel.
Alert Fire Brigade and tell them location and nature of hazard.
Control personal contact with the substance, by using protective equipment as required.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
SECTION 7 HANDLING AND STORAGE
Precautions for safe handling
Safe handling
Limit all unnecessary personal contact.
Wear protective clothing when risk of exposure occurs.
Use in a well-ventilated area.
When handling DO NOT eat, drink or smoke.
Other information
Store in original containers.
Keep containers securely sealed.
Store in a cool, dry, well-ventilated area.
Store away from incompatible materials and foodstuff containers.
Conditions for safe storage, including any incompatibilities
Chemwatch: 4888-11
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Tracerco T-194a
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Continued...
Suitable container
Polyethylene or polypropylene container.
Packing as recommended by manufacturer.
Check all containers are clearly labelled and free from leaks.
Storage incompatibility None known
PACKAGE MATERIAL INCOMPATIBILITIES
Not Available
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Control parameters
OCCUPATIONAL EXPOSURE LIMITS (OEL)
INGREDIENT DATA
Not Available
EMERGENCY LIMITS
Ingredient TEEL-0 TEEL-1 TEEL-2 TEEL-3
water 500(ppm) 500(ppm) 500(ppm) 500(ppm)
Ingredient Original IDLH Revised IDLH
Tracerco T-194a Not Available Not Available
Exposure controls
Appropriate engineering
controls
Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard.
Well-designed engineering controls can be highly effective in protecting workers and will typically be independent
of worker interactions to provide this high level of protection.
The basic types of engineering controls are:
Process controls which involve changing the way a job activity or process is done to reduce the risk.
Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker
and ventilation that strategically "adds" and "removes" air in the work environment.
Personal protection
Eye and face protection
Safety glasses with side shields.
Chemical goggles.
Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written
policy document, describing the wearing of lenses or restrictions on use, should be created for each workplace or
task.
Skin protection See Hand protection below
Hand protection
The selection of suitable gloves does not only depend on the material, but also on further marks of quality which
vary from manufacturer to manufacturer. Where the chemical is a preparation of several substances, the
resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the
application.
The exact break through time for substances has to be obtained from the manufacturer of the protective gloves
and.has to be observed when making a final choice.
Suitability and durability of glove type is dependent on usage.
Body protection See Other protection below
Other protection
Overalls.
Eyewash unit.
Thermal hazards Not Available
Recommended material(s)
GLOVE SELECTION INDEX
Glove selection is based on a modified presentation of the:
"Forsberg Clothing Performance Index".
The effect(s) of the following substance(s) are taken into account in the
computer-generated selection:
Tracerco T-194a
Respiratory protection
Particulate. (AS/NZS 1716 & 1715, EN 143:000 & 149:001, ANSI Z88 or
national equivalent)
Where the concentration of gas/particulates in the breathing zone,
approaches or exceeds the "Exposure Standard" (or ES), respiratory
protection is required.
Degree of protection varies with both face-piece and Class of filter;
Chemwatch: 4888-11
Version No: 2.1.1.1
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Tracerco T-194a
Issue Date: 25/02/2014
Print Date: 16/05/2014
Continued...
Material CPI
BUTYL A
NEOPRENE A
VITON A
* CPI - Chemwatch Performance Index
A: Best Selection
B: Satisfactory; may degrade after 4 hours continuous immersion
C: Poor to Dangerous Choice for other than short term immersion
NOTE: As a series of factors will influence the actual performance of the
glove, a final selection must be based on detailed observation. -
* Where the glove is to be used on a short term, casual or infrequent
basis, factors such as "feel" or convenience (e.g. disposability), may
dictate a choice of gloves which might otherwise be unsuitable following
long-term or frequent use. A qualified practitioner should be consulted.
the nature of protection varies with Type of filter.
Required
Minimum
Protection Factor
Half-Face
Respirator
Full-Face
Respirator
Powered Air
Respirator
up to 10 x ES -AUS P2 -
-PAPR-AUS /
Class 1 P2
up to 50 x ES -
-AUS / Class
1 P2
-
up to 100 x ES - -2 P2 -PAPR-2 P2 ^
^ - Full-face
A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 =
Acid gas or hydrogen cyanide(HCN), B3 = Acid gas or hydrogen
cyanide(HCN), E = Sulfur dioxide(SO2), G = Agricultural chemicals,
K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB =
Methyl bromide, AX = Low boiling point organic compounds(below
65 degC)
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Appearance Liquid; mixes with water.
Physical state Liquid Relative density (Water = 1) Not Available
Odour Not Available
Partition coefficient n-octanol /
water
Not Available
Odour threshold Not Available Auto-ignition temperature (C) Not Applicable
pH (as supplied) Not Available Decomposition temperature Not Available
Melting point / freezing point
(C)
Not Available Viscosity (cSt) Not Available
Initial boiling point and boiling
range (C)
Not Available Molecular weight (g/mol) Not Applicable
Flash point (C) Not Applicable Taste Not Available
Evaporation rate Not Available Explosive properties Not Available
Flammability Not Applicable Oxidising properties Not Available
Upper Explosive Limit (%) Not Applicable
Surface Tension (dyn/cm or
mN/m)
Not Available
Lower Explosive Limit (%) Not Applicable Volatile Component (%vol) 80
Vapour pressure (kPa) Not Available Gas group Not Available
Solubility in water (g/L) Miscible pH as a solution(1%) Not Available
Vapour density (Air = 1) Not Available VOC g/L Not Available
SECTION 10 STABILITY AND REACTIVITY
Reactivity See section 7
Chemical stability Product is considered stable and hazardous polymerisation will not occur.
Possibility of hazardous
reactions
See section 7
Conditions to avoid See section 7
Incompatible materials See section 7
Hazardous decomposition
products
See section 5
SECTION 11 TOXICOLOGICAL INFORMATION
Information on toxicological effects
Chemwatch: 4888-11
Version No: 2.1.1.1
Page 5 of 8
Tracerco T-194a
Issue Date: 25/02/2014
Print Date: 16/05/2014
Continued...
Inhaled
Evidence shows, or practical experience predicts, that the material produces irritation of the respiratory system, in
a substantial number of individuals, following inhalation. In contrast to most organs, the lung is able to respond to
a chemical insult by first removing or neutralising the irritant and then repairing the damage. The repair process,
which initially evolved to protect mammalian lungs from foreign matter and antigens, may however, produce
further lung damage resulting in the impairment of gas exchange, the primary function of the lungs. Respiratory
tract irritation often results in an inflammatory response involving the recruitment and activation of many cell
types, mainly derived from the vascular system.
Ingestion
Accidental ingestion of the material may be damaging to the health of the individual.
Ingestion may result in nausea, abdominal irritation, pain and vomiting
Skin Contact
Evidence exists, or practical experience predicts, that the material either produces inflammation of the skin in a
substantial number of individuals following direct contact, and/or produces significant inflammation when applied to
the healthy intact skin of animals, for up to four hours, such inflammation being present twenty-four hours or
more after the end of the exposure period. Skin irritation may also be present after prolonged or repeated
exposure; this may result in a form of contact dermatitis (nonallergic). The dermatitis is often characterised by
skin redness (erythema) and swelling (oedema) which may progress to blistering (vesiculation), scaling and
thickening of the epidermis. At the microscopic level there may be intercellular oedema of the spongy layer of the
skin (spongiosis) and intracellular oedema of the epidermis.
Eye
Evidence exists, or practical experience predicts, that the material may cause eye irritation in a substantial
number of individuals and/or may produce significant ocular lesions which are present twenty-four hours or more
after instillation into the eye(s) of experimental animals.
Repeated or prolonged eye contact may cause inflammation characterised by temporary redness (similar to
windburn) of the conjunctiva (conjunctivitis); temporary impairment of vision and/or other transient eye
damage/ulceration may occur.
Chronic
Long-term exposure to respiratory irritants may result in disease of the airways involving difficult breathing and
related systemic problems.
Tracerco T-194a
TOXICITY IRRITATION
Not Available Not Available
2,3,4,5-tetrafluorobenzoic acid,
sodium
TOXICITY IRRITATION
Not Available Not Available
water
TOXICITY IRRITATION
Not Available Not Available
* Value obtained from manufacturer's msds
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances
Tracerco T-194a Not available.
2,3,4,5-TETRAFLUOROBENZOIC
ACID, SODIUM
Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This
may be due to a non-allergenic condition known as reactive airways dysfunction syndrome (RADS) which can
occur following exposure to high levels of highly irritating compound. Key criteria for the diagnosis of RADS
include the absence of preceding respiratory disease, in a non-atopic individual, with abrupt onset of persistent
asthma-like symptoms within minutes to hours of a documented exposure to the irritant. A reversible airflow
pattern, on spirometry, with the presence of moderate to severe bronchial hyperreactivity on methacholine
challenge testing and the lack of minimal lymphocytic inflammation, without eosinophilia, have also been
included in the criteria for diagnosis of RADS.
WATER No significant acute toxicological data identified in literature search.
Acute Toxicity Carcinogenicity
Skin Irritation/Corrosion Reproductivity
Serious Eye Damage/Irritation STOT - Single Exposure
Respiratory or Skin
sensitisation
STOT - Repeated Exposure
Mutagenicity Aspiration Hazard
Chemwatch: 4888-11
Version No: 2.1.1.1
Page 6 of 8
Tracerco T-194a
Issue Date: 25/02/2014
Print Date: 16/05/2014
Continued...
CMR STATUS
Not Applicable
SECTION 12 ECOLOGICAL INFORMATION
Toxicity
DO NOT discharge into sewer or waterways.
Persistence and degradability
Ingredient Persistence: Water/Soil Persistence: Air
Not Available Not Available Not Available
Bioaccumulative potential
Ingredient Bioaccumulation
Not Available Not Available
Mobility in soil
Ingredient Mobility
Not Available Not Available
SECTION 13 DISPOSAL CONSIDERATIONS
Waste treatment methods
Product / Packaging disposal
Recycle wherever possible.
Consult manufacturer for recycling options or consult local or regional waste management authority for
disposal if no suitable treatment or disposal facility can be identified.
Dispose of by: burial in a land-fill specifically licenced to accept chemical and / or pharmaceutical wastes or
incineration in a licenced apparatus (after admixture with suitable combustible material).
Decontaminate empty containers.
SECTION 14 TRANSPORT INFORMATION
Labels Required
Marine Pollutant NO
HAZCHEM Not Applicable
Land transport (): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
SECTION 15 REGULATORY INFORMATION
Safety, health and environmental regulations / legislation specific for the substance or mixture
2,3,4,5-tetrafluorobenzoic acid,
sodium(67852-79-3) is found on
the following regulatory lists
water(7732-18-5) is found on the
following regulatory lists
"WHO Model List of Essential Medicines - Adults","Australia Inventory of Chemical Substances (AICS)","OECD
List of High Production Volume (HPV) Chemicals","OSPAR National List of Candidates for Substitution
Norway","IMO IBC Code Chapter 18: List of products to which the Code does not apply","Sigma-AldrichTransport
Information","Australia High Volume Industrial Chemical List (HVICL)","International Fragrance Association (IFRA)
Survey: Transparency List"
SECTION 16 OTHER INFORMATION
Other information
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the
Chemwatch Classification committee using available literature references.
Chemwatch: 4888-11
Version No: 2.1.1.1
Page 7 of 8
Tracerco T-194a
Issue Date: 25/02/2014
Print Date: 16/05/2014
Continued...
A list of reference resources used to assist the committee may be found at:
www.chemwatch.net/references
The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards
are Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current
or available engineering controls must be considered.
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from CHEMWATCH. TEL (+61 3) 9572 4700.
Chemwatch: 4888-11
Version No: 2.1.1.1
Page 8 of 8
Tracerco T-194a
Issue Date: 25/02/2014
Print Date: 16/05/2014
end of SDS
300

21-Aug-2008

UK SDS 1 / 5


SAFETY DATA SHEET

1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF
THE COMPANY/UNDERTAKING

Product name: 300


Supplier:
Tracerco logo
PO Box 1
Belasis Hall Technology Park
Billingham
Cleveland
TS23 1LB
UK
Tel: +44 (0)1642 375500 Fax: +44 (0)1642 370704
www.tracerco.com
Emergency telephone:
+44 (0)1642 375500


Intended use: Diagnostic services Contact person:
Peter.Scaife@matthey.com


2 HAZARDS IDENTIFICATION

The product has been classified according to the legislation in force.

Classification: | Xi; R36/37/38 |

The full text for all R-phrases is displayed in Section 16.

Potential health effects

Inhalation: Irritating to respiratory system.

Eye contact: Irritating to eyes. Eye may become red, tear, and become painful.

Skin contact: Irritating to skin. May cause pain, redness and itching.

Ingestion: May cause discomfort if swallowed.

Other health effects: The toxicological properties of this compound have not been fully investigated.

Potential physical / chemical effects: This product is not flammable.

Environment: The product components are not classified as environmentally hazardous. However, this does not
300

21-Aug-2008

UK SDS 2 / 5

exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.

3 COMPOSITION/INFORMATION ON INGREDIENTS

Chemical name EC No. CAS-No. Concentration * Classification Notes
300
>= 99% Xi;R36/37/38 -
* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.

The full text for all R-phrases is displayed in Section 16.

4 FIRST-AID MEASURES

Inhalation: Move injured person into fresh air and keep person calm under observation. Get medical attention if
any discomfort continues.

Eye contact: Flush thoroughly with water for at least 15 minutes. Get medical assistance.

Skin contact: Wash contact areas with soap and water. Get medical attention promptly if symptoms occur after
washing.

Ingestion: Rinse mouth thoroughly with water and give large amounts of milk or water to people not unconscious.
Get medical attention if any discomfort continues.

5 FIRE-FIGHTING MEASURES

Extinguishing media: Extinguish with foam, carbon dioxide, dry powder or water fog.

Inappropriate extinguishing media: Not applicable.

Special fire fighting procedures: Use standard firefighting procedures and consider the hazards of other involved
materials.

Unusual fire & explosion hazards: During fire, gases hazardous to health may be formed.

Hazardous combustion products: Carbon oxides, Hydrogen fluoride

Protective measures: Selection of respiratory protection for fire fighting: follow the general fire precautions
indicated in the workplace. Self-contained breathing apparatus and full protective clothing must be worn in case of
fire.


6 ACCIDENTAL RELEASE MEASURES

Personal precautions: Avoid inhalation of vapours and spray mist and contact with skin and eyes. Provide
adequate ventilation. Wear suitable protective clothing. See Section 8 for personal protective equipment.

Spill cleanup methods: Absorb in vermiculite, dry sand or earth and place into containers. For waste disposal, see
section 13.

Environmental precautions: Avoid discharge into drains, water courses or onto the ground unless authorized by
300

21-Aug-2008

UK SDS 3 / 5

permit.

Notification procedures: In the event of a spill or accidental release, notify relevant authorities in accordance with all
applicable regulations.


7 HANDLING AND STORAGE

Handling: Avoid inhalation of vapours and spray mist and contact with skin and eyes. Wear appropriate personal
protective equipment. See Section 8 for personal protective equipment.

Storage: Store in a cool and well-ventilated place. Keep containers tightly closed. Store away from incompatible
materials.

8 EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure limit values: No exposure limits noted for ingredient(s).

Engineering controls: Use explosion-proof ventilation equipment. Provide adequate ventilation and minimize the
risk of inhalation of vapors and mists.

Respiratory protection: In case of inadequate ventilation use suitable respirator. Use respiratory equipment with
combination filter, type A2/P2. Personal protection equipment should be chosen according to the CEN standards and
in discussion with the supplier of the personal protective equipment.

Eye protection: Wear approved safety glasses or goggles.

Hand protection: Wear protective gloves. Neoprene, nitrile, polyethylene or PVC. Be aware that the liquid may
penetrate the gloves. Frequent change is advisable. The most suitable glove must be chosen in consultation with the
gloves supplier, who can inform about the breakthrough time of the glove material.

Skin protection: Wear suitable protective clothing.

Hygiene measures: Always observe good personal hygiene measures, such as washing after handling the material
and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove
contaminants.

9 PHYSICAL AND CHEMICAL PROPERTIES

Physical state: Liquid
Colour: Colourless
Odour: Odourless
Odour threshold: No data available.
pH: Not applicable
Melting point: No data available.
Freezing point: No data available.
Boiling Point: 45C (113F)
Relative density: 1.6
Vapour pressure: No data available.
Vapour density (air=1): No data available.
300

21-Aug-2008

UK SDS 4 / 5

Evaporation rate: No data available.
Solubility in water: Not miscible
Solubility (other): No data available.
Partition coefficient (n-octanol/water): No data available.
Viscosity: Not applicable
Flash point: No data available.
Autoignition temperature: No data available.
Flammability limit - lower(%): No data available.
Flammability limit - upper (%): No data available.

10 STABILITY AND REACTIVITY

Stability: This product is stable under expected conditions of use.

Conditions to avoid: Heat, sparks, flames.

Incompatible materials: Strong oxidising agents.

Hazardous decomposition products:
At elevated temperatures: Carbon oxides, Hydrogen fluoride

Possibility of hazardous reactions: Will not occur.

11 TOXICOLOGICAL INFORMATION

Inhalation: Irritating to respiratory system.

Eye contact: Irritating to eyes. Eye may become red, tear, and become painful.

Skin contact: Irritating to skin. May cause pain, redness and itching.

Ingestion: May cause discomfort if swallowed.

Sensitisation: None known.

Listed carcinogens: None

Mutagenesis: No data available.

Reproductive toxicity: No data available.

Other effects: The toxicological properties of this compound have not been fully investigated.

12 ECOLOGICAL INFORMATION

Ecotoxicity: The product components are not classified as environmentally hazardous. However, this does not
exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.

Mobility: The product is insoluble in water.

300

21-Aug-2008

UK SDS 5 / 5

Persistence and degradability: No data available.

Bioaccumulation potential: No data available.

13 DISPOSAL CONSIDERATIONS


Disposal methods: Dispose of waste and residues in accordance with local authority requirements.

European waste codes
Unused product: 16 05 08*

14 TRANSPORT INFORMATION

ADR/RID Not regulated.

IMDG Not regulated.

IATA Not regulated.

15 REGULATORY INFORMATION





Irritant.

R36/37/38; Irritating to eyes, respiratory system and skin.

16 OTHER INFORMATION

Wording of the R-phrases in sections 2 and 3: R36; Irritating to eyes. R37; Irritating to respiratory system. R38;
Irritating to skin.

Inventory status: All substances are listed on EINECS.

Issue date: 21-Aug-2008
Supercedes date:
SDS No.: 1015390
Disclaimer: This MSDS has been prepared using information from sources considered technically reliable. It should
not be relied upon as a product specification. The company makes no warranty of any kind, express or implied,
concerning the safe use of this material in your process or in combination with other chemical substances. Every user of
the product is responsible for evaluating its own processes and conditions of use and selecting appropriate protective
measures for employee exposure.

300a

21-Aug-2008

UK SDS 1 / 5


SAFETY DATA SHEET

1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF
THE COMPANY/UNDERTAKING

Product name: 300a


Supplier:
Tracerco logo
PO Box 1
Belasis Hall Technology Park
Billingham
Cleveland
TS23 1LB
UK
Tel: +44 (0)1642 375500 Fax: +44 (0)1642 370704
www.tracerco.com
Emergency telephone:
+44 (0)1642 375500


Intended use: Diagnostic services Contact person:
Peter.Scaife@matthey.com


2 HAZARDS IDENTIFICATION

Not classified as dangerous according to directive 1999/45/EC. The toxicological properties of this compound have
not been fully investigated.

Potential health effects

Inhalation: In high concentrations, vapours may be irritating to the respiratory system.

Eye contact: May cause minor irritation on eye contact.

Skin contact: Mildly irritating to skin with prolonged exposure.

Ingestion: May cause discomfort if swallowed.

Other health effects: The toxicological properties of this compound have not been fully investigated.

Potential physical / chemical effects: This product is not flammable.

Environment: The product components are not classified as environmentally hazardous. However, this does not
exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.

3 COMPOSITION/INFORMATION ON INGREDIENTS
300a

21-Aug-2008

UK SDS 2 / 5


Chemical name EC No. CAS-No. Concentration * Classification Notes
300a
>= 99% - -
* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.

4 FIRST-AID MEASURES

Inhalation: Move injured person into fresh air and keep person calm under observation. Get medical attention if
any discomfort continues.

Eye contact: Flush thoroughly with water. If irritation occurs, get medical assistance.

Skin contact: Wash contact areas with soap and water.

Ingestion: Rinse mouth thoroughly. Get medical attention if any discomfort continues.

5 FIRE-FIGHTING MEASURES

Extinguishing media: Extinguish with foam, carbon dioxide, dry powder or water fog.

Inappropriate extinguishing media: Not applicable.

Special fire fighting procedures: Use standard firefighting procedures and consider the hazards of other involved
materials.

Unusual fire & explosion hazards: During fire, gases hazardous to health may be formed.

Hazardous combustion products: Carbon oxides, Hydrogen fluoride

Protective measures: Selection of respiratory protection for fire fighting: follow the general fire precautions
indicated in the workplace. Self-contained breathing apparatus and full protective clothing must be worn in case of
fire.


6 ACCIDENTAL RELEASE MEASURES

Personal precautions: Avoid inhalation of vapours and spray mist and contact with skin and eyes. Provide
adequate ventilation. Wear suitable protective clothing. See Section 8 for personal protective equipment.

Spill cleanup methods: Absorb in vermiculite, dry sand or earth and place into containers. For waste disposal, see
section 13.

Environmental precautions: Avoid discharge into drains, water courses or onto the ground unless authorized by
permit.

Notification procedures: In the event of a spill or accidental release, notify relevant authorities in accordance with all
applicable regulations.


7 HANDLING AND STORAGE
300a

21-Aug-2008

UK SDS 3 / 5


Handling: Avoid inhalation of vapours and spray mist and contact with skin and eyes. Wear appropriate personal
protective equipment. See Section 8 for personal protective equipment.

Storage: Store in closed original container in a dry place. Store in a cool and well-ventilated place. Keep
containers tightly closed. Store away from incompatible materials.

8 EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure limit values: No exposure limits noted for ingredient(s).

Engineering controls: Use explosion-proof ventilation equipment. Provide adequate ventilation and minimize the
risk of inhalation of vapors and mists.

Respiratory protection: In case of inadequate ventilation use suitable respirator. Use respiratory equipment with
combination filter, type A2/P2. Personal protection equipment should be chosen according to the CEN standards and
in discussion with the supplier of the personal protective equipment.

Eye protection: Risk of contact: Wear approved safety glasses or goggles.

Hand protection: Risk of contact: Wear protective gloves. Neoprene, nitrile, polyethylene or PVC. The most
suitable glove must be chosen in consultation with the gloves supplier, who can inform about the breakthrough time of
the glove material.

Skin protection: If prolonged or repeated contact is likely, chemical resistant clothing is recommended.

Hygiene measures: Always observe good personal hygiene measures, such as washing after handling the material
and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove
contaminants.

9 PHYSICAL AND CHEMICAL PROPERTIES

Physical state: Liquid
Colour: Colourless
Odour: No data available.
Odour threshold: No data available.
pH: Not applicable
Melting point: No data available.
Freezing point: No data available.
Boiling Point: 48C (118F)
Relative density: No data available.
Vapour pressure: No data available.
Vapour density (air=1): No data available.
Evaporation rate: No data available.
Solubility in water: Insoluble
Solubility (other): No data available.
Partition coefficient (n-octanol/water): No data available.
Viscosity: Not applicable
Flash point: No data available.
Autoignition temperature: No data available.
300a

21-Aug-2008

UK SDS 4 / 5

Flammability limit - lower(%): No data available.
Flammability limit - upper (%): No data available.

10 STABILITY AND REACTIVITY

Stability: This product is stable under expected conditions of use.

Conditions to avoid: Heat, sparks, flames.

Incompatible materials: Oxidizing agents.

Hazardous decomposition products:
At elevated temperatures: Carbon oxides, Hydrogen fluoride

Possibility of hazardous reactions: Will not occur.

11 TOXICOLOGICAL INFORMATION

Inhalation: In high concentrations, vapours may be irritating to the respiratory system.

Eye contact: May cause minor irritation on eye contact.

Skin contact: Mildly irritating to skin with prolonged exposure.

Ingestion: May cause discomfort if swallowed.

Sensitisation: None known.

Listed carcinogens: None

Mutagenesis: No data available.

Reproductive toxicity: No data available.

Other effects: The toxicological properties of this compound have not been fully investigated.

12 ECOLOGICAL INFORMATION

Ecotoxicity: The product components are not classified as environmentally hazardous. However, this does not
exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.

Mobility: No data available.

Persistence and degradability: No data available.

Bioaccumulation potential: No data available.

13 DISPOSAL CONSIDERATIONS


300a

21-Aug-2008

UK SDS 5 / 5

Disposal methods: Dispose of waste and residues in accordance with local authority requirements.

European waste codes
Unused product: 16 05 09

14 TRANSPORT INFORMATION

ADR/RID Not regulated.

IMDG Not regulated.

IATA Not regulated.

15 REGULATORY INFORMATION





The product has not been classified as dangerous according to the legislation in force.

16 OTHER INFORMATION

Wording of the R-phrases in sections 2 and 3: None

Inventory status: All substances are listed on EINECS.

Issue date: 21-Aug-2008
Supercedes date:
SDS No.: 1014904
Disclaimer: This MSDS has been prepared using information from sources considered technically reliable. It should
not be relied upon as a product specification. The company makes no warranty of any kind, express or implied,
concerning the safe use of this material in your process or in combination with other chemical substances. Every user of
the product is responsible for evaluating its own processes and conditions of use and selecting appropriate protective
measures for employee exposure.

350

21-Aug-2008

UK SDS 1 / 5


SAFETY DATA SHEET

1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF
THE COMPANY/UNDERTAKING

Product name: 350


Supplier:
Tracerco logo
PO Box 1
Belasis Hall Technology Park
Billingham
Cleveland
TS23 1LB
UK
Tel: +44 (0)1642 375500 Fax: +44 (0)1642 370704
www.tracerco.com
Emergency telephone:
+44 (0)1642 375500


Intended use: Diagnostic services Contact person:
Peter.Scaife@matthey.com


2 HAZARDS IDENTIFICATION

Not classified as dangerous according to directive 1999/45/EC. The toxicological properties of this compound have
not been fully investigated.

Potential health effects

Inhalation: In high concentrations, vapours may be irritating to the respiratory system.

Eye contact: May cause minor irritation on eye contact.

Skin contact: Mildly irritating to skin with prolonged exposure.

Ingestion: May cause discomfort if swallowed.

Other health effects: The toxicological properties of this compound have not been fully investigated.

Potential physical / chemical effects: This product is not flammable.

Environment: The product components are not classified as environmentally hazardous. However, this does not
exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.

3 COMPOSITION/INFORMATION ON INGREDIENTS
350

21-Aug-2008

UK SDS 2 / 5


Chemical name EC No. CAS-No. Concentration * Classification Notes
350
>= 99% - -
* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.

4 FIRST-AID MEASURES

Inhalation: Move injured person into fresh air and keep person calm under observation. Get medical attention if
any discomfort continues.

Eye contact: Flush thoroughly with water. If irritation occurs, get medical assistance.

Skin contact: Wash contact areas with soap and water.

Ingestion: Rinse mouth thoroughly with water and give large amounts of milk or water to people not unconscious.
Rinse mouth thoroughly. Get medical attention if any discomfort continues.

5 FIRE-FIGHTING MEASURES

Extinguishing media: Extinguish with foam, carbon dioxide, dry powder or water fog.

Inappropriate extinguishing media: Not applicable.

Special fire fighting procedures: Use standard firefighting procedures and consider the hazards of other involved
materials.

Unusual fire & explosion hazards: During fire, gases hazardous to health may be formed.

Hazardous combustion products: Carbon oxides, Hydrogen fluoride

Protective measures: Selection of respiratory protection for fire fighting: follow the general fire precautions
indicated in the workplace. Self-contained breathing apparatus and full protective clothing must be worn in case of
fire.


6 ACCIDENTAL RELEASE MEASURES

Personal precautions: Avoid inhalation of vapours and spray mist and contact with skin and eyes. Provide
adequate ventilation. Wear suitable protective clothing. See Section 8 for personal protective equipment.

Spill cleanup methods: Absorb in vermiculite, dry sand or earth and place into containers. For waste disposal, see
section 13.

Environmental precautions: Avoid discharge into drains, water courses or onto the ground unless authorized by
permit.

Notification procedures: In the event of a spill or accidental release, notify relevant authorities in accordance with all
applicable regulations.


350

21-Aug-2008

UK SDS 3 / 5

7 HANDLING AND STORAGE

Handling: Avoid inhalation of vapours and spray mist and contact with skin and eyes. Wear appropriate personal
protective equipment. See Section 8 for personal protective equipment.

Storage: Store in closed original container in a dry place. Store in a cool and well-ventilated place. Keep
containers tightly closed. Store away from incompatible materials.

8 EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure limit values: No exposure limits noted for ingredient(s).

Engineering controls: Use explosion-proof ventilation equipment. Provide adequate ventilation and minimize the
risk of inhalation of vapors and mists.

Respiratory protection: In case of inadequate ventilation use suitable respirator. Use respiratory equipment with
combination filter, type A2/P2. Personal protection equipment should be chosen according to the CEN standards and
in discussion with the supplier of the personal protective equipment.

Eye protection: Risk of contact: Wear approved safety glasses or goggles.

Hand protection: Risk of contact: Wear protective gloves. Neoprene, nitrile, polyethylene or PVC. The most
suitable glove must be chosen in consultation with the gloves supplier, who can inform about the breakthrough time of
the glove material.

Skin protection: If prolonged or repeated contact is likely, chemical resistant clothing is recommended.

Hygiene measures: Always observe good personal hygiene measures, such as washing after handling the material
and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove
contaminants.

9 PHYSICAL AND CHEMICAL PROPERTIES

Physical state: Liquid
Colour: Colourless
Odour: No data available.
Odour threshold: No data available.
pH: Not applicable
Melting point: No data available.
Freezing point: No data available.
Boiling Point: 76C (169F)
Relative density: No data available.
Vapour pressure: No data available.
Vapour density (air=1): No data available.
Evaporation rate: No data available.
Solubility in water: No data available.
Solubility (other): No data available.
Partition coefficient (n-octanol/water): No data available.
Viscosity: Not applicable
Flash point: No data available.
350

21-Aug-2008

UK SDS 4 / 5

Autoignition temperature: No data available.
Flammability limit - lower(%): No data available.
Flammability limit - upper (%): No data available.

10 STABILITY AND REACTIVITY

Stability: This product is stable under expected conditions of use.

Conditions to avoid: Heat, sparks, flames.

Incompatible materials: Oxidizing agents.

Hazardous decomposition products:
At elevated temperatures: Carbon oxides, Hydrogen fluoride

Possibility of hazardous reactions: Will not occur.

11 TOXICOLOGICAL INFORMATION

Inhalation: In high concentrations, vapours may be irritating to the respiratory system.

Eye contact: May cause minor irritation on eye contact.

Skin contact: Mildly irritating to skin with prolonged exposure.

Ingestion: May cause discomfort if swallowed.

Sensitisation: None known.

Listed carcinogens: None

Mutagenesis: No data available.

Reproductive toxicity: No data available.

Other effects: The toxicological properties of this compound have not been fully investigated.

12 ECOLOGICAL INFORMATION

Ecotoxicity: The product components are not classified as environmentally hazardous. However, this does not
exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.

Mobility: No data available.

Persistence and degradability: No data available.

Bioaccumulation potential: No data available.

13 DISPOSAL CONSIDERATIONS

350

21-Aug-2008

UK SDS 5 / 5


Disposal methods: Dispose of waste and residues in accordance with local authority requirements.

European waste codes
Unused product: 16 05 09

14 TRANSPORT INFORMATION

ADR/RID Not regulated.

IMDG Not regulated.

IATA Not regulated.

15 REGULATORY INFORMATION





The product has not been classified as dangerous according to the legislation in force.

16 OTHER INFORMATION

Wording of the R-phrases in sections 2 and 3: None

Inventory status: All substances are listed on EINECS.

Issue date: 21-Aug-2008
Supercedes date:
SDS No.: 1014908
Disclaimer: This MSDS has been prepared using information from sources considered technically reliable. It should
not be relied upon as a product specification. The company makes no warranty of any kind, express or implied,
concerning the safe use of this material in your process or in combination with other chemical substances. Every user of
the product is responsible for evaluating its own processes and conditions of use and selecting appropriate protective
measures for employee exposure.

400b

21-Aug-2008

UK SDS 1 / 5


SAFETY DATA SHEET

1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF
THE COMPANY/UNDERTAKING

Product name: 400b


Supplier:
Tracerco logo
PO Box 1
Belasis Hall Technology Park
Billingham
Cleveland
TS23 1LB
UK
Tel: +44 (0)1642 375500 Fax: +44 (0)1642 370704
www.tracerco.com
Emergency telephone:
+44 (0)1642 375500


Intended use: Diagnostic services Contact person:
Peter.Scaife@matthey.com


2 HAZARDS IDENTIFICATION

The product has been classified according to the legislation in force.

Classification: | Xi; R36/37/38 |

The full text for all R-phrases is displayed in Section 16.

Potential health effects

Inhalation: Irritating to respiratory system.

Eye contact: Irritating to eyes. Eye may become red, tear, and become painful.

Skin contact: Irritating to skin. May cause pain, redness and itching.

Ingestion: May cause discomfort if swallowed.

Other health effects: The toxicological properties of this compound have not been fully investigated.

Potential physical / chemical effects: This product is not flammable.

Environment: The product components are not classified as environmentally hazardous. However, this does not
400b

21-Aug-2008

UK SDS 2 / 5

exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.

3 COMPOSITION/INFORMATION ON INGREDIENTS

Chemical name EC No. CAS-No. Concentration * Classification Notes
400b
>= 99% Xi;R36/37/38 -
* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.

The full text for all R-phrases is displayed in Section 16.

4 FIRST-AID MEASURES

Inhalation: Move injured person into fresh air and keep person calm under observation. Get medical attention if
any discomfort continues.

Eye contact: Flush thoroughly with water for at least 15 minutes. Get medical assistance.

Skin contact: Wash contact areas with soap and water. Get medical attention promptly if symptoms occur after
washing.

Ingestion: Rinse mouth thoroughly with water and give large amounts of milk or water to people not unconscious.
Get medical attention if any discomfort continues.

5 FIRE-FIGHTING MEASURES

Extinguishing media: Extinguish with foam, carbon dioxide, dry powder or water fog.

Inappropriate extinguishing media: Not applicable.

Special fire fighting procedures: Use standard firefighting procedures and consider the hazards of other involved
materials.

Unusual fire & explosion hazards: During fire, gases hazardous to health may be formed.

Hazardous combustion products: Carbon oxides, Hydrogen fluoride

Protective measures: Selection of respiratory protection for fire fighting: follow the general fire precautions
indicated in the workplace. Self-contained breathing apparatus and full protective clothing must be worn in case of
fire.


6 ACCIDENTAL RELEASE MEASURES

Personal precautions: Avoid inhalation of vapours and spray mist and contact with skin and eyes. Provide
adequate ventilation. Wear suitable protective clothing. See Section 8 for personal protective equipment.

Spill cleanup methods: Absorb in vermiculite, dry sand or earth and place into containers. For waste disposal, see
section 13.

Environmental precautions: Avoid discharge into drains, water courses or onto the ground unless authorized by
400b

21-Aug-2008

UK SDS 3 / 5

permit.

Notification procedures: In the event of a spill or accidental release, notify relevant authorities in accordance with all
applicable regulations.


7 HANDLING AND STORAGE

Handling: Avoid inhalation of vapours and spray mist and contact with skin and eyes. Wear appropriate personal
protective equipment. See Section 8 for personal protective equipment.

Storage: Store in a cool and well-ventilated place. Keep containers tightly closed. Store away from incompatible
materials.

8 EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure limit values: No exposure limits noted for ingredient(s).

Engineering controls: Use explosion-proof ventilation equipment. Provide adequate ventilation and minimize the
risk of inhalation of vapors and mists.

Respiratory protection: In case of inadequate ventilation use suitable respirator. Use respiratory equipment with
combination filter, type A2/P2. Personal protection equipment should be chosen according to the CEN standards and
in discussion with the supplier of the personal protective equipment.

Eye protection: Wear approved safety glasses or goggles.

Hand protection: Wear protective gloves. Neoprene, nitrile, polyethylene or PVC. Be aware that the liquid may
penetrate the gloves. Frequent change is advisable. The most suitable glove must be chosen in consultation with the
gloves supplier, who can inform about the breakthrough time of the glove material.

Skin protection: Wear suitable protective clothing.

Hygiene measures: Always observe good personal hygiene measures, such as washing after handling the material
and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove
contaminants.

9 PHYSICAL AND CHEMICAL PROPERTIES

Physical state: Liquid
Colour: Pale yellow
Odour: No data available.
Odour threshold: No data available.
pH: Not applicable
Melting point: -55C (-67F)
Freezing point: No data available.
Boiling Point: 101C (214F)
Relative density: No data available.
Vapour pressure: No data available.
Vapour density (air=1): No data available.
400b

21-Aug-2008

UK SDS 4 / 5

Evaporation rate: No data available.
Solubility in water: Not miscible
Solubility (other): No data available.
Partition coefficient (n-octanol/water): No data available.
Viscosity: Not applicable
Flash point: No data available.
Autoignition temperature: No data available.
Flammability limit - lower(%): No data available.
Flammability limit - upper (%): No data available.

10 STABILITY AND REACTIVITY

Stability: This product is stable under expected conditions of use.

Conditions to avoid: Heat, sparks, flames.

Incompatible materials: Strong oxidising agents.

Hazardous decomposition products:
At elevated temperatures: Carbon oxides, Hydrogen fluoride

Possibility of hazardous reactions: Will not occur.

11 TOXICOLOGICAL INFORMATION

Inhalation: Irritating to respiratory system.

Eye contact: Irritating to eyes. Eye may become red, tear, and become painful.

Skin contact: Irritating to skin. May cause pain, redness and itching.

Ingestion: May cause discomfort if swallowed.

Sensitisation: None known.

Listed carcinogens: None

Mutagenesis: No data available.

Reproductive toxicity: No data available.

Other effects: The toxicological properties of this compound have not been fully investigated.

12 ECOLOGICAL INFORMATION

Ecotoxicity: The product components are not classified as environmentally hazardous. However, this does not
exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.

Mobility: The product is insoluble in water.

400b

21-Aug-2008

UK SDS 5 / 5

Persistence and degradability: No data available.

Bioaccumulation potential: No data available.

13 DISPOSAL CONSIDERATIONS


Disposal methods: Dispose of waste and residues in accordance with local authority requirements.

European waste codes
Unused product: 16 05 08*

14 TRANSPORT INFORMATION

ADR/RID Not regulated.

IMDG Not regulated.

IATA Not regulated.

15 REGULATORY INFORMATION





Irritant.

R36/37/38; Irritating to eyes, respiratory system and skin.

S23; Do not breathe vapor or spray. S24/25; Avoid contact with skin and eyes. S26; In case of contact with eyes,
rinse immediately with plenty of water and seek medical advice. S60; This material and its container must be disposed
of as hazardous waste.

16 OTHER INFORMATION

Wording of the R-phrases in sections 2 and 3: R36; Irritating to eyes. R37; Irritating to respiratory system. R38;
Irritating to skin.

Inventory status: All substances are listed on EINECS.

Issue date: 21-Aug-2008
Supercedes date: 21-Aug-2008
SDS No.: 1014943
Disclaimer: This MSDS has been prepared using information from sources considered technically reliable. It should
not be relied upon as a product specification. The company makes no warranty of any kind, express or implied,
concerning the safe use of this material in your process or in combination with other chemical substances. Every user of
the product is responsible for evaluating its own processes and conditions of use and selecting appropriate protective
measures for employee exposure.

400c

21-Aug-2008

UK SDS 1 / 5


SAFETY DATA SHEET

1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF
THE COMPANY/UNDERTAKING

Product name: 400c


Supplier:
Tracerco logo
PO Box 1
Belasis Hall Technology Park
Billingham
Cleveland
TS23 1LB
UK
Tel: +44 (0)1642 375500 Fax: +44 (0)1642 370704
www.tracerco.com
Emergency telephone:
+44 (0)1642 375500


Intended use: Diagnostic services Contact person:
Peter.Scaife@matthey.com


2 HAZARDS IDENTIFICATION

The product has been classified according to the legislation in force.

Classification: | Xi; R36/37/38 |

The full text for all R-phrases is displayed in Section 16.

Potential health effects

Inhalation: Irritating to respiratory system.

Eye contact: Irritating to eyes. Eye may become red, tear, and become painful.

Skin contact: Irritating to skin. May cause pain, redness and itching.

Ingestion: May cause discomfort if swallowed.

Other health effects: The toxicological properties of this compound have not been fully investigated.

Potential physical / chemical effects: This product is not flammable.

Environment: The product components are not classified as environmentally hazardous. However, this does not
400c

21-Aug-2008

UK SDS 2 / 5

exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.

3 COMPOSITION/INFORMATION ON INGREDIENTS

Chemical name EC No. CAS-No. Concentration * Classification Notes
400c
>= 99% Xi;R36/37/38 -
* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.

The full text for all R-phrases is displayed in Section 16.

4 FIRST-AID MEASURES

Inhalation: Move injured person into fresh air and keep person calm under observation. Get medical attention if
any discomfort continues.

Eye contact: Flush thoroughly with water for at least 15 minutes. Get medical assistance.

Skin contact: Wash contact areas with soap and water. Get medical attention promptly if symptoms occur after
washing.

Ingestion: Rinse mouth thoroughly with water and give large amounts of milk or water to people not unconscious.
Get medical attention if any discomfort continues.

5 FIRE-FIGHTING MEASURES

Extinguishing media: Extinguish with foam, carbon dioxide, dry powder or water fog.

Inappropriate extinguishing media: Not applicable.

Special fire fighting procedures: Use standard firefighting procedures and consider the hazards of other involved
materials.

Unusual fire & explosion hazards: During fire, gases hazardous to health may be formed.

Hazardous combustion products: Carbon oxides, Hydrogen fluoride

Protective measures: Selection of respiratory protection for fire fighting: follow the general fire precautions
indicated in the workplace. Self-contained breathing apparatus and full protective clothing must be worn in case of
fire.


6 ACCIDENTAL RELEASE MEASURES

Personal precautions: Avoid inhalation of vapours and spray mist and contact with skin and eyes. Provide
adequate ventilation. Wear suitable protective clothing. See Section 8 for personal protective equipment.

Spill cleanup methods: Absorb in vermiculite, dry sand or earth and place into containers. For waste disposal, see
section 13.

Environmental precautions: Avoid discharge into drains, water courses or onto the ground unless authorized by
400c

21-Aug-2008

UK SDS 3 / 5

permit.

Notification procedures: In the event of a spill or accidental release, notify relevant authorities in accordance with all
applicable regulations.


7 HANDLING AND STORAGE

Handling: Avoid inhalation of vapours and spray mist and contact with skin and eyes. Wear appropriate personal
protective equipment. See Section 8 for personal protective equipment.

Storage: Store in a cool and well-ventilated place. Keep containers tightly closed. Store away from incompatible
materials.

8 EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure limit values: No exposure limits noted for ingredient(s).

Engineering controls: Use explosion-proof ventilation equipment. Provide adequate ventilation and minimize the
risk of inhalation of vapors and mists.

Respiratory protection: In case of inadequate ventilation use suitable respirator. Use respiratory equipment with
combination filter, type A2/P2. Personal protection equipment should be chosen according to the CEN standards and
in discussion with the supplier of the personal protective equipment.

Eye protection: Wear approved safety glasses or goggles.

Hand protection: Wear protective gloves. Neoprene, nitrile, polyethylene or PVC. Be aware that the liquid may
penetrate the gloves. Frequent change is advisable. The most suitable glove must be chosen in consultation with the
gloves supplier, who can inform about the breakthrough time of the glove material.

Skin protection: Wear suitable protective clothing.

Hygiene measures: Always observe good personal hygiene measures, such as washing after handling the material
and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove
contaminants.

9 PHYSICAL AND CHEMICAL PROPERTIES

Physical state: Liquid
Colour: No data available.
Odour: No data available.
Odour threshold: No data available.
pH: Not applicable
Melting point: No data available.
Freezing point: No data available.
Boiling Point: No data available.
Relative density: No data available.
Vapour pressure: No data available.
Vapour density (air=1): No data available.
400c

21-Aug-2008

UK SDS 4 / 5

Evaporation rate: No data available.
Solubility in water: Not miscible
Solubility (other): No data available.
Partition coefficient (n-octanol/water): No data available.
Viscosity: Not applicable
Flash point: No data available.
Autoignition temperature: No data available.
Flammability limit - lower(%): No data available.
Flammability limit - upper (%): No data available.

10 STABILITY AND REACTIVITY

Stability: This product is stable under expected conditions of use.

Conditions to avoid: Heat, sparks, flames.

Incompatible materials: Strong oxidising agents.

Hazardous decomposition products:
At elevated temperatures: Carbon oxides, Hydrogen fluoride

Possibility of hazardous reactions: Will not occur.

11 TOXICOLOGICAL INFORMATION

Inhalation: Irritating to respiratory system.

Eye contact: Irritating to eyes. Eye may become red, tear, and become painful.

Skin contact: Irritating to skin. May cause pain, redness and itching.

Ingestion: May cause discomfort if swallowed.

Sensitisation: None known.

Listed carcinogens: None

Mutagenesis: No data available.

Reproductive toxicity: No data available.

Other effects: The toxicological properties of this compound have not been fully investigated.

12 ECOLOGICAL INFORMATION

Ecotoxicity: The product components are not classified as environmentally hazardous. However, this does not
exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.

Mobility: The product is insoluble in water.

400c

21-Aug-2008

UK SDS 5 / 5

Persistence and degradability: No data available.

Bioaccumulation potential: No data available.

13 DISPOSAL CONSIDERATIONS


Disposal methods: Dispose of waste and residues in accordance with local authority requirements.

European waste codes
Unused product: 16 05 08*

14 TRANSPORT INFORMATION

ADR/RID Not regulated.

IMDG Not regulated.

IATA Not regulated.

15 REGULATORY INFORMATION





Irritant.

R36/37/38; Irritating to eyes, respiratory system and skin.

S23; Do not breathe vapor or spray. S24/25; Avoid contact with skin and eyes. S26; In case of contact with eyes,
rinse immediately with plenty of water and seek medical advice. S60; This material and its container must be disposed
of as hazardous waste.

16 OTHER INFORMATION

Wording of the R-phrases in sections 2 and 3: R36; Irritating to eyes. R37; Irritating to respiratory system. R38;
Irritating to skin.

Inventory status: Not all substances are listed on EINECS.

Issue date: 21-Aug-2008
Supercedes date:
SDS No.: 1014960
Disclaimer: This MSDS has been prepared using information from sources considered technically reliable. It should
not be relied upon as a product specification. The company makes no warranty of any kind, express or implied,
concerning the safe use of this material in your process or in combination with other chemical substances. Every user of
the product is responsible for evaluating its own processes and conditions of use and selecting appropriate protective
measures for employee exposure.

412

21-Aug-2008

UK SDS 1 / 5


SAFETY DATA SHEET

1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF
THE COMPANY/UNDERTAKING

Product name: 412


Supplier:
Tracerco logo
PO Box 1
Belasis Hall Technology Park
Billingham
Cleveland
TS23 1LB
UK
Tel: +44 (0)1642 375500 Fax: +44 (0)1642 370704
www.tracerco.com
Emergency telephone:
+44 (0)1642 375500


Intended use: Diagnostic services Contact person:
Peter.Scaife@matthey.com


2 HAZARDS IDENTIFICATION

Not classified as dangerous according to directive 1999/45/EC. The toxicological properties of this compound have
not been fully investigated.

Potential health effects

Inhalation: In high concentrations, vapours may be irritating to the respiratory system.

Eye contact: May cause minor irritation on eye contact.

Skin contact: Mildly irritating to skin with prolonged exposure.

Ingestion: May cause discomfort if swallowed.

Other health effects: The toxicological properties of this compound have not been fully investigated.

Potential physical / chemical effects: This product is not flammable.

Environment: The product components are not classified as environmentally hazardous. However, this does not
exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.

3 COMPOSITION/INFORMATION ON INGREDIENTS
412

21-Aug-2008

UK SDS 2 / 5


Chemical name EC No. CAS-No. Concentration * Classification Notes
412
>= 99% - -
* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.

4 FIRST-AID MEASURES

Inhalation: Move injured person into fresh air and keep person calm under observation. Get medical attention if
any discomfort continues.

Eye contact: Flush thoroughly with water. If irritation occurs, get medical assistance.

Skin contact: Wash contact areas with soap and water.

Ingestion: Rinse mouth thoroughly with water and give large amounts of milk or water to people not unconscious.
Get medical attention if any discomfort continues.

5 FIRE-FIGHTING MEASURES

Extinguishing media: Extinguish with foam, carbon dioxide, dry powder or water fog.

Inappropriate extinguishing media: Not applicable.

Special fire fighting procedures: Use standard firefighting procedures and consider the hazards of other involved
materials.

Unusual fire & explosion hazards: During fire, gases hazardous to health may be formed.

Hazardous combustion products: Carbon oxides, Hydrogen fluoride

Protective measures: Selection of respiratory protection for fire fighting: follow the general fire precautions
indicated in the workplace. Self-contained breathing apparatus and full protective clothing must be worn in case of
fire.


6 ACCIDENTAL RELEASE MEASURES

Personal precautions: Avoid inhalation of vapours and spray mist and contact with skin and eyes. Provide
adequate ventilation. Wear suitable protective clothing. See Section 8 for personal protective equipment.

Spill cleanup methods: Absorb in vermiculite, dry sand or earth and place into containers. For waste disposal, see
section 13.

Environmental precautions: Avoid discharge into drains, water courses or onto the ground unless authorized by
permit.

Notification procedures: In the event of a spill or accidental release, notify relevant authorities in accordance with all
applicable regulations.


412

21-Aug-2008

UK SDS 3 / 5

7 HANDLING AND STORAGE

Handling: Avoid inhalation of vapours and spray mist and contact with skin and eyes. Wear appropriate personal
protective equipment. See Section 8 for personal protective equipment.

Storage: Store in closed original container in a dry place. Store in a cool and well-ventilated place. Keep
containers tightly closed. Store away from incompatible materials.

8 EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure limit values: No exposure limits noted for ingredient(s).

Engineering controls: Use explosion-proof ventilation equipment. Provide adequate ventilation and minimize the
risk of inhalation of vapors and mists.

Respiratory protection: In case of inadequate ventilation use suitable respirator. Use respiratory equipment with
combination filter, type A2/P2. Personal protection equipment should be chosen according to the CEN standards and
in discussion with the supplier of the personal protective equipment.

Eye protection: Risk of contact: Wear approved safety glasses or goggles.

Hand protection: Risk of contact: Wear protective gloves. Neoprene, nitrile, polyethylene or PVC. The most
suitable glove must be chosen in consultation with the gloves supplier, who can inform about the breakthrough time of
the glove material.

Skin protection: If prolonged or repeated contact is likely, chemical resistant clothing is recommended.

Hygiene measures: Always observe good personal hygiene measures, such as washing after handling the material
and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove
contaminants.

9 PHYSICAL AND CHEMICAL PROPERTIES

Physical state: Liquid
Colour: Colourless
Odour: Odourless
Odour threshold: No data available.
pH: Not applicable
Melting point: No data available.
Freezing point: No data available.
Boiling Point: 121C (250F)
Relative density: No data available.
Vapour pressure: No data available.
Vapour density (air=1): No data available.
Evaporation rate: No data available.
Solubility in water: Not miscible
Solubility (other): No data available.
Partition coefficient (n-octanol/water): No data available.
Viscosity: Not applicable
Flash point: No data available.
412

21-Aug-2008

UK SDS 4 / 5

Autoignition temperature: No data available.
Flammability limit - lower(%): No data available.
Flammability limit - upper (%): No data available.

10 STABILITY AND REACTIVITY

Stability: This product is stable under expected conditions of use.

Conditions to avoid: Heat, sparks, flames.

Incompatible materials: Oxidizing agents.

Hazardous decomposition products:
At elevated temperatures: Carbon oxides, Hydrogen fluoride

Possibility of hazardous reactions: Will not occur.

11 TOXICOLOGICAL INFORMATION

Inhalation: In high concentrations, vapours may be irritating to the respiratory system.

Eye contact: May cause minor irritation on eye contact.

Skin contact: Mildly irritating to skin with prolonged exposure.

Ingestion: May cause discomfort if swallowed.

Sensitisation: None known.

Listed carcinogens: None

Mutagenesis: No data available.

Reproductive toxicity: No data available.

Other effects: The toxicological properties of this compound have not been fully investigated.

12 ECOLOGICAL INFORMATION

Ecotoxicity: The product components are not classified as environmentally hazardous. However, this does not
exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.

Mobility: No data available.

Persistence and degradability: No data available.

Bioaccumulation potential: No data available.

13 DISPOSAL CONSIDERATIONS

412

21-Aug-2008

UK SDS 5 / 5


Disposal methods: Dispose of waste and residues in accordance with local authority requirements.

European waste codes
Unused product: 16 05 09

14 TRANSPORT INFORMATION

ADR/RID Not regulated.

IMDG Not regulated.

IATA Not regulated.

15 REGULATORY INFORMATION





The product has not been classified as dangerous according to the legislation in force.

16 OTHER INFORMATION

Wording of the R-phrases in sections 2 and 3: None

Inventory status: Not all substances are listed on EINECS.

Issue date: 21-Aug-2008
Supercedes date:
SDS No.: 1015406
Disclaimer: This MSDS has been prepared using information from sources considered technically reliable. It should
not be relied upon as a product specification. The company makes no warranty of any kind, express or implied,
concerning the safe use of this material in your process or in combination with other chemical substances. Every user of
the product is responsible for evaluating its own processes and conditions of use and selecting appropriate protective
measures for employee exposure.

438

21-Aug-2008

UK SDS 1 / 5


SAFETY DATA SHEET

1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF
THE COMPANY/UNDERTAKING

Product name: 438


Supplier:
Tracerco logo
PO Box 1
Belasis Hall Technology Park
Billingham
Cleveland
TS23 1LB
UK
Tel: +44 (0)1642 375500 Fax: +44 (0)1642 370704
www.tracerco.com
Emergency telephone:
+44 (0)1642 375500


Intended use: Diagnostic services Contact person:
Peter.Scaife@matthey.com


2 HAZARDS IDENTIFICATION

Not classified as dangerous according to directive 1999/45/EC. The toxicological properties of this compound have
not been fully investigated.

Potential health effects

Inhalation: In high concentrations, vapours may be irritating to the respiratory system.

Eye contact: May cause minor irritation on eye contact.

Skin contact: Mildly irritating to skin with prolonged exposure.

Ingestion: May cause discomfort if swallowed.

Other health effects: The toxicological properties of this compound have not been fully investigated.

Potential physical / chemical effects: This product is not flammable.

Environment: The product components are not classified as environmentally hazardous. However, this does not
exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.

3 COMPOSITION/INFORMATION ON INGREDIENTS
438

21-Aug-2008

UK SDS 2 / 5


Chemical name EC No. CAS-No. Concentration * Classification Notes
438
>= 99% - -
* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.

4 FIRST-AID MEASURES

Inhalation: Move injured person into fresh air and keep person calm under observation. Get medical attention if
any discomfort continues.

Eye contact: Flush thoroughly with water. If irritation occurs, get medical assistance.

Skin contact: Wash contact areas with soap and water.

Ingestion: Rinse mouth thoroughly. Get medical attention if any discomfort continues.

5 FIRE-FIGHTING MEASURES

Extinguishing media: Extinguish with foam, carbon dioxide, dry powder or water fog.

Inappropriate extinguishing media: Not applicable.

Special fire fighting procedures: Use standard firefighting procedures and consider the hazards of other involved
materials.

Unusual fire & explosion hazards: During fire, gases hazardous to health may be formed.

Hazardous combustion products: Carbon oxides, Hydrogen fluoride

Protective measures: Selection of respiratory protection for fire fighting: follow the general fire precautions
indicated in the workplace. Self-contained breathing apparatus and full protective clothing must be worn in case of
fire.


6 ACCIDENTAL RELEASE MEASURES

Personal precautions: Avoid inhalation of vapours and spray mist and contact with skin and eyes. Provide
adequate ventilation. Wear suitable protective clothing. See Section 8 for personal protective equipment.

Spill cleanup methods: Absorb in vermiculite, dry sand or earth and place into containers. For waste disposal, see
section 13.

Environmental precautions: Avoid discharge into drains, water courses or onto the ground unless authorized by
permit.

Notification procedures: In the event of a spill or accidental release, notify relevant authorities in accordance with all
applicable regulations.


7 HANDLING AND STORAGE
438

21-Aug-2008

UK SDS 3 / 5


Handling: Avoid inhalation of vapours and spray mist and contact with skin and eyes. Wear appropriate personal
protective equipment. See Section 8 for personal protective equipment.

Storage: Store in closed original container in a dry place. Store in a cool and well-ventilated place. Keep
containers tightly closed. Store away from incompatible materials.

8 EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure limit values: No exposure limits noted for ingredient(s).

Engineering controls: Use explosion-proof ventilation equipment. Provide adequate ventilation and minimize the
risk of inhalation of vapors and mists.

Respiratory protection: In case of inadequate ventilation use suitable respirator. Use respiratory equipment with
combination filter, type A2/P2. Personal protection equipment should be chosen according to the CEN standards and
in discussion with the supplier of the personal protective equipment.

Eye protection: Risk of contact: Wear approved safety glasses or goggles.

Hand protection: Risk of contact: Wear protective gloves. Neoprene, nitrile, polyethylene or PVC. The most
suitable glove must be chosen in consultation with the gloves supplier, who can inform about the breakthrough time of
the glove material.

Skin protection: If prolonged or repeated contact is likely, chemical resistant clothing is recommended.

Hygiene measures: Always observe good personal hygiene measures, such as washing after handling the material
and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove
contaminants.

9 PHYSICAL AND CHEMICAL PROPERTIES

Physical state: Liquid
Colour: No data available.
Odour: No data available.
Odour threshold: No data available.
pH: Not applicable
Melting point: No data available.
Freezing point: No data available.
Boiling Point: No data available.
Relative density: No data available.
Vapour pressure: No data available.
Vapour density (air=1): No data available.
Evaporation rate: No data available.
Solubility in water: Not miscible
Solubility (other): No data available.
Partition coefficient (n-octanol/water): No data available.
Viscosity: Not applicable
Flash point: No data available.
Autoignition temperature: No data available.
438

21-Aug-2008

UK SDS 4 / 5

Flammability limit - lower(%): No data available.
Flammability limit - upper (%): No data available.

10 STABILITY AND REACTIVITY

Stability: This product is stable under expected conditions of use.

Conditions to avoid: Heat, sparks, flames.

Incompatible materials: Oxidizing agents.

Hazardous decomposition products:
At elevated temperatures: Carbon oxides, Hydrogen fluoride

Possibility of hazardous reactions: Will not occur.

11 TOXICOLOGICAL INFORMATION

Inhalation: In high concentrations, vapours may be irritating to the respiratory system.

Eye contact: May cause minor irritation on eye contact.

Skin contact: Mildly irritating to skin with prolonged exposure.

Ingestion: May cause discomfort if swallowed.

Sensitisation: None known.

Listed carcinogens: None

Mutagenesis: No data available.

Reproductive toxicity: No data available.

Other effects: The toxicological properties of this compound have not been fully investigated.

12 ECOLOGICAL INFORMATION

Ecotoxicity: The product components are not classified as environmentally hazardous. However, this does not
exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.

Mobility: No data available.

Persistence and degradability: No data available.

Bioaccumulation potential: No data available.

13 DISPOSAL CONSIDERATIONS


438

21-Aug-2008

UK SDS 5 / 5

Disposal methods: Dispose of waste and residues in accordance with local authority requirements.

European waste codes
Unused product: 16 05 09

14 TRANSPORT INFORMATION

ADR/RID Not regulated.

IMDG Not regulated.

IATA Not regulated.

15 REGULATORY INFORMATION





The product has not been classified as dangerous according to the legislation in force.

16 OTHER INFORMATION

Wording of the R-phrases in sections 2 and 3: None

Inventory status: Not all substances are listed on EINECS.

Issue date: 21-Aug-2008
Supercedes date:
SDS No.: 1015436
Disclaimer: This MSDS has been prepared using information from sources considered technically reliable. It should
not be relied upon as a product specification. The company makes no warranty of any kind, express or implied,
concerning the safe use of this material in your process or in combination with other chemical substances. Every user of
the product is responsible for evaluating its own processes and conditions of use and selecting appropriate protective
measures for employee exposure.

450a

21-Aug-2008

UK SDS 1 / 5


SAFETY DATA SHEET

1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF
THE COMPANY/UNDERTAKING

Product name: 450a


Supplier:
Tracerco logo
PO Box 1 Belasis
Hall Technology Park Billingham
Cleveland TS23
1LB UK
Tel: +44 (0)1642 375500 Fax: +44 (0)1642 370704
www.tracerco.com
Emergency telephone:
+44 (0)1642 375500


Intended use: Diagnostic services Contact person:
Peter.Scaife@matthey.com


2 HAZARDS IDENTIFICATION

Not classified as dangerous according to directive 1999/45/EC. The toxicological properties of this compound have not
been fully investigated.

Potential health effects

Inhalation: In high concentrations, vapours may be irritating to the respiratory system.

Eye contact: May cause minor irritation on eye contact.

Skin contact: Mildly irritating to skin with prolonged exposure.

Ingestion: May cause discomfort if swallowed.

Other health effects: The toxicological properties of this compound have not been fully investigated.

Potential physical / chemical effects: This product is not flammable.

Environment: The product components are not classified as environmentally hazardous. However, this does not exclude
the possibility that large or frequent spills can have a harmful or damaging effect on the environment.

3 COMPOSITION/INFORMATION ON INGREDIENTS

Chemical name EC No. CAS-No. Concentration * Classification Notes
450a

21-Aug-2008

UK SDS 2 / 5

450a
>= 99% - -
* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.

4 FIRST-AID MEASURES

Inhalation: Move injured person into fresh air and keep person calm under observation. Get medical attention if any
discomfort continues.

Eye contact: Flush thoroughly with water. If irritation occurs, get medical assistance.

Skin contact: Wash contact areas with soap and water.

Ingestion: Rinse mouth thoroughly with water and give large amounts of milk or water to people not unconscious. Rinse
mouth thoroughly. Get medical attention if any discomfort continues.

5 FIRE-FIGHTING MEASURES

Extinguishing media: Extinguish with foam, carbon dioxide, dry powder or water fog.

Inappropriate extinguishing media: Not applicable.

Special fire fighting procedures: Use standard firefighting procedures and consider the hazards of other involved
materials.

Unusual fire & explosion hazards: During fire, gases hazardous to health may be formed.

Hazardous combustion products: Carbon oxides, Hydrogen fluoride

Protective measures: Selection of respiratory protection for fire fighting: follow the general fire precautions indicated in
the workplace. Self-contained breathing apparatus and full protective clothing must be worn in case of fire.


6 ACCIDENTAL RELEASE MEASURES

Personal precautions: Avoid inhalation of vapours and spray mist and contact with skin and eyes. Provide adequate
ventilation. Wear suitable protective clothing. See Section 8 for personal protective equipment.

Spill cleanup methods: Absorb in vermiculite, dry sand or earth and place into containers. For waste disposal, see
section 13.

Environmental precautions: Avoid discharge into drains, water courses or onto the ground unless authorized by permit.

Notification procedures: In the event of a spill or accidental release, notify relevant authorities in accordance with all
applicable regulations.


7 HANDLING AND STORAGE

Handling: Avoid inhalation of vapours and spray mist and contact with skin and eyes. Wear appropriate personal
protective equipment. See Section 8 for personal protective equipment.
450a

21-Aug-2008

UK SDS 3 / 5


Storage: Store in closed original container in a dry place. Store in a cool and well-ventilated place. Keep containers
tightly closed. Store away from incompatible materials.

8 EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure limit values: No exposure limits noted for ingredient(s).

Engineering controls: Use explosion-proof ventilation equipment. Provide adequate ventilation and minimize the risk
of inhalation of vapors and mists.

Respiratory protection: In case of inadequate ventilation use suitable respirator. Use respiratory equipment with
combination filter, type A2/P2. Personal protection equipment should be chosen according to the CEN standards and in
discussion with the supplier of the personal protective equipment.

Eye protection: Risk of contact: Wear approved safety glasses or goggles.

Hand protection: Risk of contact: Wear protective gloves. Neoprene, nitrile, polyethylene or PVC. The most suitable
glove must be chosen in consultation with the gloves supplier, who can inform about the breakthrough time of the glove
material.

Skin protection: If prolonged or repeated contact is likely, chemical resistant clothing is recommended.

Hygiene measures: Always observe good personal hygiene measures, such as washing after handling the material and
before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove
contaminants.

9 PHYSICAL AND CHEMICAL PROPERTIES

Physical state: Liquid
Colour: No data available.
Odour: No data available.
Odour threshold: No data available.
pH: Not applicable
Melting point: No data available.
Freezing point: No data available.
Boiling Point: No data available.
Relative density: No data available.
Vapour pressure: No data available.
Vapour density (air=1): No data available.
Evaporation rate: No data available.
Solubility in water: Insoluble
Solubility (other): No data available.
Partition coefficient (n-octanol/water): No data available.
Viscosity: Not applicable
Flash point: No data available.
Autoignition temperature: No data available.
Flammability limit - lower(%): No data available.
Flammability limit - upper (%): No data available.

450a

21-Aug-2008

UK SDS 4 / 5

10 STABILITY AND REACTIVITY

Stability: This product is stable under expected conditions of use.

Conditions to avoid: Heat, sparks, flames.

Incompatible materials: Oxidising materials.

Hazardous decomposition products:
At elevated temperatures: Carbon oxides, Hydrogen fluoride

Possibility of hazardous reactions: Will not occur.

11 TOXICOLOGICAL INFORMATION

Inhalation: In high concentrations, vapours may be irritating to the respiratory system.

Eye contact: May cause minor irritation on eye contact.

Skin contact: Mildly irritating to skin with prolonged exposure.

Ingestion: May cause discomfort if swallowed.

Sensitisation: None known.

Listed carcinogens: None

Mutagenesis: No data available.

Reproductive toxicity: No data available.

Other effects: The toxicological properties of this compound have not been fully investigated.

12 ECOLOGICAL INFORMATION

Ecotoxicity: The product components are not classified as environmentally hazardous. However, this does not exclude
the possibility that large or frequent spills can have a harmful or damaging effect on the environment.

Mobility: No data available.

Persistence and degradability: No data available.

Bioaccumulation potential: No data available.

13 DISPOSAL CONSIDERATIONS


Disposal methods: Dispose of waste and residues in accordance with local authority requirements.

European waste codes
450a

21-Aug-2008

UK SDS 5 / 5

Unused product: 16 05 09

14 TRANSPORT INFORMATION

ADR/RID Not regulated.

IMDG Not regulated.

IATA Not regulated.

15 REGULATORY INFORMATION





The product has not been classified as dangerous according to the legislation in force.

16 OTHER INFORMATION

Wording of the R-phrases in sections 2 and 3: None

Inventory status: Not all substances are listed on EINECS.

Issue date: 21-Aug-2008
Supercedes date:
SDS No.: 1014967
Disclaimer: This MSDS has been prepared using information from sources considered technically reliable. It should not
be relied upon as a product specification. The company makes no warranty of any kind, express or implied, concerning the
safe use of this material in your process or in combination with other chemical substances. Every user of the product is
responsible for evaluating its own processes and conditions of use and selecting appropriate protective measures for
employee exposure.

450b

21-Aug-2008

UK SDS 1 / 5


SAFETY DATA SHEET

1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF
THE COMPANY/UNDERTAKING

Product name: 450b


Supplier:
Tracerco logo
PO Box 1
Belasis Hall Technology Park
Billingham
Cleveland
TS23 1LB
UK
Tel: +44 (0)1642 375500 Fax: +44 (0)1642 370704
www.tracerco.com
Emergency telephone:
+44 (0)1642 375500


Intended use: Diagnostic services Contact person:
Peter.Scaife@matthey.com


2 HAZARDS IDENTIFICATION

Not classified as dangerous according to directive 1999/45/EC. The toxicological properties of this compound have
not been fully investigated.

Potential health effects

Inhalation: In high concentrations, vapours may be irritating to the respiratory system.

Eye contact: May cause minor irritation on eye contact.

Skin contact: Mildly irritating to skin with prolonged exposure.

Ingestion: May cause discomfort if swallowed.

Other health effects: The toxicological properties of this compound have not been fully investigated.

Potential physical / chemical effects: This product is not flammable.

Environment: The product components are not classified as environmentally hazardous. However, this does not
exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.

3 COMPOSITION/INFORMATION ON INGREDIENTS
450b

21-Aug-2008

UK SDS 2 / 5


Chemical name EC No. CAS-No. Concentration * Classification Notes
450b
>= 99% - -
* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.

4 FIRST-AID MEASURES

Inhalation: Move injured person into fresh air and keep person calm under observation. Get medical attention if
any discomfort continues.

Eye contact: Flush thoroughly with water. If irritation occurs, get medical assistance.

Skin contact: Wash contact areas with soap and water.

Ingestion: Rinse mouth thoroughly with water and give large amounts of milk or water to people not unconscious.
Get medical attention if any discomfort continues.

5 FIRE-FIGHTING MEASURES

Extinguishing media: Extinguish with foam, carbon dioxide, dry powder or water fog.

Inappropriate extinguishing media: Not applicable.

Special fire fighting procedures: Use standard firefighting procedures and consider the hazards of other involved
materials.

Unusual fire & explosion hazards: During fire, gases hazardous to health may be formed.

Hazardous combustion products: Carbon oxides, Hydrogen fluoride

Protective measures: Selection of respiratory protection for fire fighting: follow the general fire precautions
indicated in the workplace. Self-contained breathing apparatus and full protective clothing must be worn in case of
fire.


6 ACCIDENTAL RELEASE MEASURES

Personal precautions: Avoid inhalation of vapours and spray mist and contact with skin and eyes. Provide
adequate ventilation. Wear suitable protective clothing. See Section 8 for personal protective equipment.

Spill cleanup methods: Absorb in vermiculite, dry sand or earth and place into containers. For waste disposal, see
section 13.

Environmental precautions: Avoid discharge into drains, water courses or onto the ground unless authorized by
permit.

Notification procedures: In the event of a spill or accidental release, notify relevant authorities in accordance with all
applicable regulations.


450b

21-Aug-2008

UK SDS 3 / 5

7 HANDLING AND STORAGE

Handling: Avoid inhalation of vapours and spray mist and contact with skin and eyes. Wear appropriate personal
protective equipment. See Section 8 for personal protective equipment.

Storage: Store in closed original container in a dry place. Store in a cool and well-ventilated place. Keep
containers tightly closed. Store away from incompatible materials.

8 EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure limit values: No exposure limits noted for ingredient(s).

Engineering controls: Use explosion-proof ventilation equipment. Provide adequate ventilation and minimize the
risk of inhalation of vapors and mists.

Respiratory protection: In case of inadequate ventilation use suitable respirator. Use respiratory equipment with
combination filter, type A2/P2. Personal protection equipment should be chosen according to the CEN standards and
in discussion with the supplier of the personal protective equipment.

Eye protection: Risk of contact: Wear approved safety glasses or goggles.

Hand protection: Risk of contact: Wear protective gloves. Neoprene, nitrile, polyethylene or PVC. The most
suitable glove must be chosen in consultation with the gloves supplier, who can inform about the breakthrough time of
the glove material.

Skin protection: If prolonged or repeated contact is likely, chemical resistant clothing is recommended.

Hygiene measures: Always observe good personal hygiene measures, such as washing after handling the material
and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove
contaminants.

9 PHYSICAL AND CHEMICAL PROPERTIES

Physical state: Liquid
Colour: Colourless
Odour: Odourless
Odour threshold: No data available.
pH: Not applicable
Melting point: No data available.
Freezing point: No data available.
Boiling Point: 130C (266F)
Relative density: No data available.
Vapour pressure: No data available.
Vapour density (air=1): No data available.
Evaporation rate: No data available.
Solubility in water: Not miscible
Solubility (other): No data available.
Partition coefficient (n-octanol/water): No data available.
Viscosity: 2 mPa.s (Approximate)
Flash point: No data available.
450b

21-Aug-2008

UK SDS 4 / 5

Autoignition temperature: No data available.
Flammability limit - lower(%): No data available.
Flammability limit - upper (%): No data available.

10 STABILITY AND REACTIVITY

Stability: This product is stable under expected conditions of use.

Conditions to avoid: Heat, sparks, flames.

Incompatible materials: Potassium Sodium. Lithium. Calcium. Barium.

Hazardous decomposition products:
At elevated temperatures: Carbon oxides, Hydrogen fluoride

Possibility of hazardous reactions: Will not occur.

11 TOXICOLOGICAL INFORMATION

Inhalation: In high concentrations, vapours may be irritating to the respiratory system.

Eye contact: May cause minor irritation on eye contact.

Skin contact: Mildly irritating to skin with prolonged exposure.

Ingestion: May cause discomfort if swallowed.

Sensitisation: None known.

Listed carcinogens: None

Mutagenesis: No data available.

Reproductive toxicity: No data available.

Other effects: The toxicological properties of this compound have not been fully investigated.

12 ECOLOGICAL INFORMATION

Ecotoxicity: The product components are not classified as environmentally hazardous. However, this does not
exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.

Mobility: No data available.

Persistence and degradability: No data available.

Bioaccumulation potential: No data available.

13 DISPOSAL CONSIDERATIONS

450b

21-Aug-2008

UK SDS 5 / 5


Disposal methods: Dispose of waste and residues in accordance with local authority requirements.

European waste codes
Unused product: 16 05 09

14 TRANSPORT INFORMATION

ADR/RID Not regulated.

IMDG Not regulated.

IATA Not regulated.

15 REGULATORY INFORMATION





The product has not been classified as dangerous according to the legislation in force.

16 OTHER INFORMATION

Wording of the R-phrases in sections 2 and 3: None

Inventory status: Not all substances are listed on EINECS.

Issue date: 21-Aug-2008
Supercedes date:
SDS No.: 1015419
Disclaimer: This MSDS has been prepared using information from sources considered technically reliable. It should
not be relied upon as a product specification. The company makes no warranty of any kind, express or implied,
concerning the safe use of this material in your process or in combination with other chemical substances. Every user of
the product is responsible for evaluating its own processes and conditions of use and selecting appropriate protective
measures for employee exposure.

450c

21-Aug-2008

UK SDS 1 / 5


SAFETY DATA SHEET

1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF
THE COMPANY/UNDERTAKING

Product name: 450c


Supplier:
Tracerco logo
PO Box 1
Belasis Hall Technology Park
Billingham
Cleveland
TS23 1LB
UK
Tel: +44 (0)1642 375500 Fax: +44 (0)1642 370704
www.tracerco.com
Emergency telephone:
+44 (0)1642 375500


Intended use: Diagnostic services Contact person:
Peter.Scaife@matthey.com


2 HAZARDS IDENTIFICATION

Not classified as dangerous according to directive 1999/45/EC. The toxicological properties of this compound have
not been fully investigated.

Potential health effects

Inhalation: In high concentrations, vapours may be irritating to the respiratory system.

Eye contact: May cause minor irritation on eye contact.

Skin contact: Mildly irritating to skin with prolonged exposure.

Ingestion: May cause discomfort if swallowed.

Other health effects: The toxicological properties of this compound have not been fully investigated.

Potential physical / chemical effects: This product is not flammable.

Environment: The product components are not classified as environmentally hazardous. However, this does not
exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.

3 COMPOSITION/INFORMATION ON INGREDIENTS
450c

21-Aug-2008

UK SDS 2 / 5


Chemical name EC No. CAS-No. Concentration * Classification Notes
450c
>= 99% - -
* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.

4 FIRST-AID MEASURES

Inhalation: Move injured person into fresh air and keep person calm under observation. Get medical attention if
any discomfort continues.

Eye contact: Flush thoroughly with water. If irritation occurs, get medical assistance.

Skin contact: Wash contact areas with soap and water.

Ingestion: Rinse mouth thoroughly with water and give large amounts of milk or water to people not unconscious.
Rinse mouth thoroughly. Get medical attention if any discomfort continues.

5 FIRE-FIGHTING MEASURES

Extinguishing media: Extinguish with foam, carbon dioxide, dry powder or water fog.

Inappropriate extinguishing media: Not applicable.

Special fire fighting procedures: Use standard firefighting procedures and consider the hazards of other involved
materials.

Unusual fire & explosion hazards: During fire, gases hazardous to health may be formed.

Hazardous combustion products: Carbon oxides, Hydrogen fluoride

Protective measures: Selection of respiratory protection for fire fighting: follow the general fire precautions
indicated in the workplace. Self-contained breathing apparatus and full protective clothing must be worn in case of
fire.


6 ACCIDENTAL RELEASE MEASURES

Personal precautions: Avoid inhalation of vapours and spray mist and contact with skin and eyes. Provide
adequate ventilation. Wear suitable protective clothing. See Section 8 for personal protective equipment.

Spill cleanup methods: Absorb in vermiculite, dry sand or earth and place into containers. For waste disposal, see
section 13.

Environmental precautions: Avoid discharge into drains, water courses or onto the ground unless authorized by
permit.

Notification procedures: In the event of a spill or accidental release, notify relevant authorities in accordance with all
applicable regulations.


450c

21-Aug-2008

UK SDS 3 / 5

7 HANDLING AND STORAGE

Handling: Avoid inhalation of vapours and spray mist and contact with skin and eyes. Wear appropriate personal
protective equipment. See Section 8 for personal protective equipment.

Storage: Store in closed original container in a dry place. Store in a cool and well-ventilated place. Keep
containers tightly closed. Store away from incompatible materials.

8 EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure limit values: No exposure limits noted for ingredient(s).

Engineering controls: Use explosion-proof ventilation equipment. Provide adequate ventilation and minimize the
risk of inhalation of vapors and mists.

Respiratory protection: In case of inadequate ventilation use suitable respirator. Use respiratory equipment with
combination filter, type A2/P2. Personal protection equipment should be chosen according to the CEN standards and
in discussion with the supplier of the personal protective equipment.

Eye protection: Risk of contact: Wear approved safety glasses or goggles.

Hand protection: Risk of contact: Wear protective gloves. Neoprene, nitrile, polyethylene or PVC. The most
suitable glove must be chosen in consultation with the gloves supplier, who can inform about the breakthrough time of
the glove material.

Skin protection: If prolonged or repeated contact is likely, chemical resistant clothing is recommended.

Hygiene measures: Always observe good personal hygiene measures, such as washing after handling the material
and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove
contaminants.

9 PHYSICAL AND CHEMICAL PROPERTIES

Physical state: Liquid
Colour: Colourless
Odour: Odourless
Odour threshold: No data available.
pH: Not applicable
Melting point: No data available.
Freezing point: No data available.
Boiling Point: 127C (261F)
Relative density: No data available.
Vapour pressure: No data available.
Vapour density (air=1): No data available.
Evaporation rate: No data available.
Solubility in water: Not miscible
Solubility (other): No data available.
Partition coefficient (n-octanol/water): No data available.
Viscosity: 2.28 mPa.s
Flash point: No data available.
450c

21-Aug-2008

UK SDS 4 / 5

Autoignition temperature: No data available.
Flammability limit - lower(%): No data available.
Flammability limit - upper (%): No data available.

10 STABILITY AND REACTIVITY

Stability: This product is stable under expected conditions of use.

Conditions to avoid: Heat, sparks, flames.

Incompatible materials: Potassium Sodium. Lithium. Calcium. Barium.

Hazardous decomposition products:
At elevated temperatures: Carbon oxides, Hydrogen fluoride

Possibility of hazardous reactions: Will not occur.

11 TOXICOLOGICAL INFORMATION

Inhalation: In high concentrations, vapours may be irritating to the respiratory system.

Eye contact: May cause minor irritation on eye contact.

Skin contact: Mildly irritating to skin with prolonged exposure.

Ingestion: May cause discomfort if swallowed.

Sensitisation: None known.

Listed carcinogens: None

Mutagenesis: No data available.

Reproductive toxicity: No data available.

Other effects: The toxicological properties of this compound have not been fully investigated.

12 ECOLOGICAL INFORMATION

Ecotoxicity: The product components are not classified as environmentally hazardous. However, this does not
exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.

Mobility: No data available.

Persistence and degradability: No data available.

Bioaccumulation potential: No data available.

13 DISPOSAL CONSIDERATIONS

450c

21-Aug-2008

UK SDS 5 / 5


Disposal methods: Dispose of waste and residues in accordance with local authority requirements.

European waste codes
Unused product: 16 05 09

14 TRANSPORT INFORMATION

ADR/RID Not regulated.

IMDG Not regulated.

IATA Not regulated.

15 REGULATORY INFORMATION





The product has not been classified as dangerous according to the legislation in force.

16 OTHER INFORMATION

Wording of the R-phrases in sections 2 and 3: None

Inventory status: All substances are listed on EINECS.

Issue date: 21-Aug-2008
Supercedes date:
SDS No.: 1015373
Disclaimer: This MSDS has been prepared using information from sources considered technically reliable. It should
not be relied upon as a product specification. The company makes no warranty of any kind, express or implied,
concerning the safe use of this material in your process or in combination with other chemical substances. Every user of
the product is responsible for evaluating its own processes and conditions of use and selecting appropriate protective
measures for employee exposure.

462a

21-Aug-2008

UK SDS 1 / 6


SAFETY DATA SHEET

1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF
THE COMPANY/UNDERTAKING

Product name: 462a


Supplier:
Tracerco logo
PO Box 1
Belasis Hall Technology Park
Billingham
Cleveland
TS23 1LB
UK
Tel: +44 (0)1642 375500 Fax: +44 (0)1642 370704
www.tracerco.com
Emergency telephone:
+44 (0)1642 375500


Intended use: Diagnostic services Contact person:
Peter.Scaife@matthey.com


2 HAZARDS IDENTIFICATION

The product has been classified according to the legislation in force.

Classification: | R10 |

The full text for all R-phrases is displayed in Section 16.

Potential health effects

Inhalation: In high concentrations, vapours may be irritating to the respiratory system.

Eye contact: May cause minor irritation on eye contact.

Skin contact: Mildly irritating to skin with prolonged exposure.

Ingestion: May cause discomfort if swallowed.

Other health effects: The toxicological properties of this compound have not been fully investigated.

Potential physical / chemical effects: The product is flammable, and heating may generate vapours which may form
explosive vapour/air mixtures.

462a

21-Aug-2008

UK SDS 2 / 6

Environment: The product components are not classified as environmentally hazardous. However, this does not
exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.

3 COMPOSITION/INFORMATION ON INGREDIENTS

Chemical name EC No. CAS-No. Concentration * Classification Notes
462a
>= 99% R10 -
* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.

4 FIRST-AID MEASURES

General: Burns: Flush with water immediately. While flushing, remove clothes which do not adhere to affected area.
Call an ambulance. Continue flushing during transport to hospital.

Inhalation: Move injured person into fresh air and keep person calm under observation. Get medical attention if
any discomfort continues.

Eye contact: Flush thoroughly with water. If irritation occurs, get medical assistance.

Skin contact: Wash contact areas with soap and water.

Ingestion: Rinse mouth thoroughly with water and give large amounts of milk or water to people not unconscious.
Get medical attention if any discomfort continues.

5 FIRE-FIGHTING MEASURES

Extinguishing media: Extinguish with foam, carbon dioxide, dry powder or water fog.

Inappropriate extinguishing media: Not applicable.

Special fire fighting procedures: Use standard firefighting procedures and consider the hazards of other involved
materials.

Unusual fire & explosion hazards: During fire, gases hazardous to health may be formed.

Hazardous combustion products: Carbon oxides, Hydrogen fluoride

Protective measures: Selection of respiratory protection for fire fighting: follow the general fire precautions
indicated in the workplace. Self-contained breathing apparatus and full protective clothing must be worn in case of
fire.


6 ACCIDENTAL RELEASE MEASURES

Personal precautions: Do not smoke, use open fire or other sources of ignition. Avoid inhalation of vapours and
spray mist and contact with skin and eyes. Provide adequate ventilation. Wear suitable protective clothing. See
Section 8 for personal protective equipment.

Spill cleanup methods: Remove sources of ignition. Beware of the explosion danger. Absorb in vermiculite, dry
sand or earth and place into containers. For waste disposal, see section 13.
462a

21-Aug-2008

UK SDS 3 / 6


Environmental precautions: Avoid discharge into drains, water courses or onto the ground unless authorized by
permit.

Notification procedures: In the event of a spill or accidental release, notify relevant authorities in accordance with all
applicable regulations.


7 HANDLING AND STORAGE

Handling: Local exhaust is recommended. Avoid inhalation of vapours and spray mist and contact with skin and
eyes. Do not smoke and do not spray near a naked flame or other sources of ignition. The product is flammable, and
heating may generate vapours which may form explosive vapour/air mixtures. Wear appropriate personal protective
equipment. See Section 8 for personal protective equipment.

Storage: Follow rules for flammable liquids. Keep away from heat, sparks and open flame. Store in a cool and
well-ventilated place. Keep containers tightly closed. Store away from incompatible materials.

8 EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure limit values: No exposure limits noted for ingredient(s).

Engineering controls: Use explosion-proof ventilation equipment. Provide adequate ventilation and minimize the
risk of inhalation of vapors and mists.

Respiratory protection: In case of inadequate ventilation use suitable respirator. Use respiratory equipment with
combination filter, type A2/P2. Personal protection equipment should be chosen according to the CEN standards and
in discussion with the supplier of the personal protective equipment.

Eye protection: Risk of contact: Wear approved safety glasses or goggles.

Hand protection: Risk of contact: Wear protective gloves. Neoprene, nitrile, polyethylene or PVC. The most
suitable glove must be chosen in consultation with the gloves supplier, who can inform about the breakthrough time of
the glove material.

Skin protection: If prolonged or repeated contact is likely, chemical resistant clothing is recommended.

Hygiene measures: Always observe good personal hygiene measures, such as washing after handling the material
and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove
contaminants.

9 PHYSICAL AND CHEMICAL PROPERTIES

Physical state: Liquid
Colour: Colourless
Odour: No data available.
Odour threshold: No data available.
pH: Not applicable
Melting point: -10C (14F)
Freezing point: No data available.
462a

21-Aug-2008

UK SDS 4 / 6

Boiling Point: 142C (288F)
Relative density: No data available.
Vapour pressure: No data available.
Vapour density (air=1): 17.5
Evaporation rate: No data available.
Solubility in water: No data available.
Solubility (other): No data available.
Partition coefficient (n-octanol/water): No data available.
Viscosity: Not applicable
Flash point: 48C (118F)
Autoignition temperature: No data available.
Flammability limit - lower(%): No data available.
Flammability limit - upper (%): No data available.

10 STABILITY AND REACTIVITY

Stability: This product is stable under expected conditions of use.

Conditions to avoid: Heat, sparks, flames.

Incompatible materials: Oxidizing agents.

Hazardous decomposition products:
At elevated temperatures: Carbon oxides, Hydrogen fluoride

Possibility of hazardous reactions: Will not occur.

11 TOXICOLOGICAL INFORMATION

Inhalation: In high concentrations, vapours may be irritating to the respiratory system.

Eye contact: May cause minor irritation on eye contact.

Skin contact: Mildly irritating to skin with prolonged exposure.

Ingestion: May cause discomfort if swallowed.

Sensitisation: None known.

Listed carcinogens: None

Mutagenesis: No data available.

Reproductive toxicity: No data available.

Other effects: The toxicological properties of this compound have not been fully investigated.

12 ECOLOGICAL INFORMATION

Ecotoxicity: The product components are not classified as environmentally hazardous. However, this does not
462a

21-Aug-2008

UK SDS 5 / 6

exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.

Mobility: No data available.

Persistence and degradability: No data available.

Bioaccumulation potential: No data available.

13 DISPOSAL CONSIDERATIONS


Disposal methods: Dispose of waste and residues in accordance with local authority requirements.

European waste codes
Unused product: 16 05 08*

14 TRANSPORT INFORMATION

ADR/RID
UN No.: UN1993
Proper shipping name: Flammable liquid, n.o.s. (Perfluorodecalin)
Class: 3
Packing group: III
Label(s): 3

IMDG
UN No.: UN1993
Proper shipping name: Flammable liquid, n.o.s. (Perfluorodecalin )
Class: 3
Packing group: III
EmS No.: F-E, S-E

IATA
UN No.: UN1993
Proper shipping name: Flammable liquid, n.o.s. ( Perfluorodecalin )
Class: 3
Packing group: III
Label(s): 3

15 REGULATORY INFORMATION





R10; Flammable.

S23; Do not breathe vapor or spray. S24/25; Avoid contact with skin and eyes.

16 OTHER INFORMATION

462a

21-Aug-2008

UK SDS 6 / 6

Wording of the R-phrases in sections 2 and 3: R10; Flammable.

Inventory status: All substances are listed on EINECS.

Issue date: 21-Aug-2008
Supercedes date:
SDS No.: 1014900
Disclaimer: This MSDS has been prepared using information from sources considered technically reliable. It should
not be relied upon as a product specification. The company makes no warranty of any kind, express or implied,
concerning the safe use of this material in your process or in combination with other chemical substances. Every user of
the product is responsible for evaluating its own processes and conditions of use and selecting appropriate protective
measures for employee exposure.

1 of 2 MSDS_IR192-ZW
MANUFACTURER Rev. 4/20/09
SPECTRATEK SERVICES
2726 AZTEC N.E. BUILDING B
ALBUQUERQUE, NM 87107
PHONE : (505) 888-0144
24 HOUR EMERGENCY RESPONSE:
(Within US) 1 800 535 5053 (Outside US) 1 352 323 3500 Collect
MATERIAL SAFETY DATA SHEET
IDENTIFICATION
PRODUCT NAME IRIDIUM ZERO WASH BEAD TRACER
RADIONUCLIDE IRIDIUM-192 (IR-192)
CHEMICAL FORM IRIDIUM OXIDE
PHYSICAL FORM SOLID
TOXICITY HAZARDS
IRIDIUM192 Bead Tracer has short termtoxicity hazards if ingested. Data on lethal concentrations
and doses are not presently available.
HEALTH HAZARD DATA
ACUTE EFFECTS
May cause Eye and Mucous membrane irritation.
ZERO WASH particle is too large to inhale. Ingestion is the only method of internal consumption.
PREGNANT WOMEN SHOULD NOT BE ALLOWED TO WORK WITH
RADIOACTIVE MATERIAL OR BE IN THE EXPOSURE AREA.
FIRST AID
IF SWALLOWED, OBTAIN COMPETENT MEDICAL ATTENTION
IMMEDIATELY. The physician should be qualified in Nuclear Medicine and/or Health Physics.
In case of skin contact, wash area with water and a detergent. SURVEY skin area with a Geiger-
Mueller instrument and end-window G-M probe to determine cleaning effectiveness. Survey all
personnel who may have come in contact with ZERO WASH Bead Tracer. Locate the ZERO
WASH bead using GM survey instrument. Use adhesive tape to remove bead from clothing. Treat
tape containing bead as RADWASTE. If numerous beads are found on clothing, remove and place
in a container for later cleaning or disposal. SURVEY THE AREA near the spill and the areas the
worker has been transferred to for the presence of radioactive material.
In case of contact with eyes, flush with copious amounts of water for at least 15 minutes. Assure that
adequate flushing occurs by separating eyelids with fingers. Obtain services of a qualified physician.
PHYSICAL DATA
SPECIFIC GRAVITY 1.25 grams/ml - Low Density ZERO WASH bead
2.65 grams/ml - ZERO WASH bead
2 of 2 MSDS_IR192-ZW
WASHOFF < 0.005% Washoff
APPEARANCE black/dark brown (low density ZW) and gray to beige spheres (ZW)
ODOR no odor
HALF LIFE 74.2 Days
FIRE AND EXPLOSION HAZARD DATA
Fire and Explosion Hazard is Negligible
Autoignition Temperature not Applicable
EXTINGUISHING MEDIA - Carbon Dioxide or Halon (This reduces the spread of radioactive
material).
SPECIAL FIRE FIGHTING PROCEDURES
Self Contained Breathing Apparatus and fire protective clothing is sufficient when extinguishing a
fire involving this product.
UNUSUAL FIRE AND EXPLOSION HAZARDS
NONE
REACTIVITY DATA
STABILITY - STABLE
CONDITION TO AVOID - NONE
INCOMPATIBILITIES - NONE
HAZARDOUS COMBUSTION OR DECOMPOSITION PRODUCTS IRIDIUM 192 MAY
CONTAIN VAPORS OR PARTICULATES
HAZARDOUS POLYMERIZATIONS - NONE
SPILL AND LEAK PROCEDURES
SPILL PROCEDURES
CONTROLTHE AREA. Do Not Move Personnel fromthe area until theyhave been surveyed using
a G-M survey instrument. The personnel may survey themselves and if no radioactive material is
indicated they may leave the area. This will help eliminate spread of radioactive material. WEAR
PROTECTIVECLOTHING, SAFETYEYEWEAR, IMPERVIOUS BOOTS, ANDRUBBER
GLOVES. Clean up spill area by scooping up spilled material and transfer to a container. It maybe
necessary to remove some soil or other items indicating the presence of radioactive material. If
clothing indicates the presence of radioactive material, remove the bead with adhesive tape, hold tape
containing bead for decay in proper storage area and treat as RAD WASTE. If numerous beads are
found on clothing, remove clothing and place in a container for later cleaning or disposal. Contain
all spilled material and treat as radioactive waste as per regulatory requirements.
The material presented above is believed to be correct, but does not purport to be all inclusive and shall be used as a guide
only. SpectraTek shall not be liable for any damage resulting from the use of this information.
1 of 2 MSDS_IR192-ZW
MANUFACTURER Rev. 4/20/09
SPECTRATEK SERVICES
2726 AZTEC N.E. BUILDING B
ALBUQUERQUE, NM 87107
PHONE : (505) 888-0144
24 HOUR EMERGENCY RESPONSE:
(Within US) 1 800 535 5053 (Outside US) 1 352 323 3500 Collect
MATERIAL SAFETY DATA SHEET
IDENTIFICATION
PRODUCT NAME ANTIMONY ZERO WASH BEAD TRACER
RADIONUCLIDE ANTIMONY-124 (Sb-124)
CHEMICAL FORM ANTIMONY OXIDE
PHYSICAL FORM SOLID
TOXICITY HAZARDS
ANTIMONY 124 Bead Tracer has short term toxicity hazards if ingested. Data on lethal
concentrations and doses are not presently available.
HEALTH HAZARD DATA
ACUTE EFFECTS
May cause Eye and Mucous membrane irritation.
ZERO WASH particle is too large to inhale. Ingestion is the only method of internal consumption.
PREGNANT WOMEN SHOULD NOT BE ALLOWED TO WORK WITH
RADIOACTIVE MATERIAL OR BE IN THE EXPOSURE AREA.
FIRST AID
IF SWALLOWED, OBTAIN COMPETENT MEDICAL ATTENTION
IMMEDIATELY. The physician should be qualified in Nuclear Medicine and/or Health Physics.
In case of skin contact, wash area with water and a detergent. SURVEY skin area with a Geiger-
Mueller instrument and end-window G-M probe to determine cleaning effectiveness. Survey all
personnel who may have come in contact with ZERO WASH Bead Tracer. Locate the ZERO
WASH bead using GM survey instrument. Use adhesive tape to remove bead from clothing. Treat
tape containing bead as RADWASTE. If numerous beads are found on clothing, remove and place
in a container for later cleaning or disposal. SURVEY THE AREA near the spill and the areas the
worker has been transferred to for the presence of radioactive material.
In case of contact with eyes, flush with copious amounts of water for at least 15 minutes. Assure that
adequate flushing occurs by separating eyelids with fingers. Obtain services of a qualified physician.
PHYSICAL DATA
SPECIFIC GRAVITY 1.25 grams/ml - Low Density ZERO WASH bead
2.65 grams/ml - ZERO WASH bead
2 of 2 MSDS_IR192-ZW
WASHOFF < 0.1% Washoff
APPEARANCE black/dark brown (low density ZW) and gray to beige spheres (ZW)
ODOR no odor
HALF LIFE 60.4 Days
FIRE AND EXPLOSION HAZARD DATA
Fire and Explosion Hazard is Negligible
Autoignition Temperature not Applicable
EXTINGUISHING MEDIA - Carbon Dioxide or Halon (This reduces the spread of radioactive
material).
SPECIAL FIRE FIGHTING PROCEDURES
Self Contained Breathing Apparatus and fire protective clothing is sufficient when extinguishing a
fire involving this product.
UNUSUAL FIRE AND EXPLOSION HAZARDS
NONE
REACTIVITY DATA
STABILITY - STABLE
CONDITION TO AVOID - NONE
INCOMPATIBILITIES - NONE
HAZARDOUS COMBUSTION OR DECOMPOSITION PRODUCTS IRIDIUM 192 MAY
CONTAIN VAPORS OR PARTICULATES
HAZARDOUS POLYMERIZATIONS - NONE
SPILL AND LEAK PROCEDURES
SPILL PROCEDURES
CONTROLTHE AREA. Do Not Move Personnel fromthe area until theyhave been surveyed using
a G-M survey instrument. The personnel may survey themselves and if no radioactive material is
indicated they may leave the area. This will help eliminate spread of radioactive material. WEAR
PROTECTIVECLOTHING, SAFETYEYEWEAR, IMPERVIOUS BOOTS, ANDRUBBER
GLOVES. Clean up spill area by scooping up spilled material and transfer to a container. It maybe
necessary to remove some soil or other items indicating the presence of radioactive material. If
clothing indicates the presence of radioactive material, remove the bead with adhesive tape, hold tape
containing bead for decay in proper storage area and treat as RAD WASTE. If numerous beads are
found on clothing, remove clothing and place in a container for later cleaning or disposal. Contain
all spilled material and treat as radioactive waste as per regulatory requirements.
The material presented above is believed to be correct, but does not purport to be all inclusive and shall be used as a guide
only. SpectraTek shall not be liable for any damage resulting from the use of this information.
1 of 2 MSDS_IR192-ZW
MANUFACTURER Rev. 4/20/09
SPECTRATEK SERVICES
2726 AZTEC N.E. BUILDING B
ALBUQUERQUE, NM 87107
PHONE : (505) 888-0144
24 HOUR EMERGENCY RESPONSE:
(Within US) 1 800 535 5053 (Outside US) 1 352 323 3500 Collect
MATERIAL SAFETY DATA SHEET
IDENTIFICATION
PRODUCT NAME SCANDIUM ZERO WASH BEAD TRACER
RADIONUCLIDE SCANDIUM-46 (Sc-46)
CHEMICAL FORM SCANDIUM OXIDE
PHYSICAL FORM SOLID
TOXICITY HAZARDS
SCANDIUM 46 Bead Tracer has short term toxicity hazards if ingested. Data on lethal
concentrations and doses are not presently available.
HEALTH HAZARD DATA
ACUTE EFFECTS
May cause Eye and Mucous membrane irritation.
ZERO WASH particle is too large to inhale. Ingestion is the only method of internal consumption.
PREGNANT WOMEN SHOULD NOT BE ALLOWED TO WORK WITH
RADIOACTIVE MATERIAL OR BE IN THE EXPOSURE AREA.
FIRST AID
IF SWALLOWED, OBTAIN COMPETENT MEDICAL ATTENTION
IMMEDIATELY. The physician should be qualified in Nuclear Medicine and/or Health Physics.
In case of skin contact, wash area with water and a detergent. SURVEY skin area with a Geiger-
Mueller instrument and end-window G-M probe to determine cleaning effectiveness. Survey all
personnel who may have come in contact with ZERO WASH Bead Tracer. Locate the ZERO
WASH bead using GM survey instrument. Use adhesive tape to remove bead from clothing. Treat
tape containing bead as RADWASTE. If numerous beads are found on clothing, remove and place
in a container for later cleaning or disposal. SURVEY THE AREA near the spill and the areas the
worker has been transferred to for the presence of radioactive material.
In case of contact with eyes, flush with copious amounts of water for at least 15 minutes. Assure that
adequate flushing occurs by separating eyelids with fingers. Obtain services of a qualified physician.
2 of 2 MSDS_IR192-ZW
PHYSICAL DATA
SPECIFIC GRAVITY 1.25 grams/ml - Low Density ZERO WASH bead
2.65 grams/ml - ZERO WASH bead
WASHOFF < 0.005% Washoff
APPEARANCE black/dark brown (low density ZW) and gray to beige spheres (ZW)
ODOR no odor
HALF LIFE 84 Days
FIRE AND EXPLOSION HAZARD DATA
Fire and Explosion Hazard is Negligible
Autoignition Temperature not Applicable
EXTINGUISHING MEDIA - Carbon Dioxide or Halon (This reduces the spread of radioactive
material).
SPECIAL FIRE FIGHTING PROCEDURES
Self Contained Breathing Apparatus and fire protective clothing is sufficient when extinguishing a
fire involving this product.
UNUSUAL FIRE AND EXPLOSION HAZARDS
NONE
REACTIVITY DATA
STABILITY - STABLE
CONDITION TO AVOID - NONE
INCOMPATIBILITIES - NONE
HAZARDOUS COMBUSTION OR DECOMPOSITION PRODUCTS IRIDIUM 192 MAY
CONTAIN VAPORS OR PARTICULATES
HAZARDOUS POLYMERIZATIONS - NONE
SPILL AND LEAK PROCEDURES
SPILL PROCEDURES
CONTROLTHE AREA. Do Not Move Personnel fromthe area until theyhave been surveyed using
a G-M survey instrument. The personnel may survey themselves and if no radioactive material is
indicated they may leave the area. This will help eliminate spread of radioactive material. WEAR
PROTECTIVECLOTHING, SAFETYEYEWEAR, IMPERVIOUS BOOTS, ANDRUBBER
GLOVES. Clean up spill area by scooping up spilled material and transfer to a container. It maybe
necessary to remove some soil or other items indicating the presence of radioactive material. If
clothing indicates the presence of radioactive material, remove the bead with adhesive tape, hold tape
containing bead for decay in proper storage area and treat as RAD WASTE. If numerous beads are
found on clothing, remove clothing and place in a container for later cleaning or disposal. Contain
all spilled material and treat as radioactive waste as per regulatory requirements.
The material presented above is believed to be correct, but does not purport to be all inclusive and shall be used as a guide
only. SpectraTek shall not be liable for any damage resulting from the use of this information.