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^ TARGET IIT JEE 2007

PHYSICAL CHEMISTRY
XII & XIII
FINAL PRA CTICE PROBLEMS
FOR IIT JEE-2007
(With Answers)
ALL THE BEST FOR JEE - 2007
Q. 1 Wave number of the second line of Paschen series of hydrogen atom is (R
H
= 109700 cm
!
)
(A) 18750 A (B) 3452 A (C) 7801 A (D) 1542656 A
Q.2 Radiation corresponding to the transition n = 4 to n = 2 in hydrogen atoms falls on a certain metal
(work function = 2.0 eY). The maximum kinetic energy of the photoelectrons will be
(A) 0.55 eV (B) 2.55 eV (C) 4.45 eY (D) none
Q.3 The maximum number of electrons in a subshell having the same value of spin quantum number is
given by
(A) 1 + 2 (B) 21 + 1 (C) 2(2/+1) (D) None
1
Q.4 When a graph is plotted with log (K
eq
) v/s , then intercept on log (K
eq
) axis will be
AH AH
0
AS AS
o
( A ) T ^ T ( B) - TTT^r ( Q (D)
2.303R
v 7
2.303RT R
v
' 2.303R
Q.5 For the synthesis of NH
3
from the Haber process starting with stoichiometric amount of N
2
and
H
2
, the attainment of equilibrium is predicted by which curve:
N
2
(g) + 3H
2
(g) >2NH,(g)
t:
t;
Nil,
(A) NH
3
( C ) l N ft ( D) L
I)' ' Hn 2
-NI I,
-
N
2
-H,
Q.6 The reaction A(g) + B(g) ^ C(g) + D(g) is elementry 2
nd
order reaction opposed by elementry
second order reaction. When started with equimolar amounts of A and R, at equilibrium, it is
found that the conc. of Ais twice that of C. Specific rate for forward reaction is 2 x 10"
3
mol
1
Lsec
!
. The specific rate constant for backward reaction is
(A) 5.0 x 10"
4
M"
1
sec"
1
(B) 8 x 10"
3
M"
1
sec"
1
(C) 1.5 x 10
2
M
1
sec"
!
(D) none of these
Question No. 7 to 8 ( 2 questions)
A 0.5 L reaction vessel which is equipped with a movable piston is filled completely with a IM
aqueous solution of H
2
0
2
.The H
2
0
2
decomposes to H
2
0 and 0
2
(g) in a first order process with
half life 10 hrs at 300 K. As gas decomposes, the piston moves up against constant external
pressure of 750 mm Hg.
Q.7 What is the net work done by the gas from the start of sixth hour till the end of 10 hrs?
(A) 100 J (B) 120 J (C) 130 J (D) 150 J
Q.8 If AH for decomposition of H
2
0
2
(aq.) is X K J/mole, how much heat has been exchanged with
surrounding to maintain temperature at 300 K (in KJ) from the start of 6
th
hour till the end of 10
th
hour.
(A) -0.1035 X (B)-0.2070 X
(C)-0.052 X (D) 0.026 X
Q.9 During study of a liquid phase reaction A (aq) > B (aq) + C (aq) the variation in concentration
of B with time is given
t/min 0 10 20 30 oo
conc. (B) mole/L 0 0.1 0.19 0.271 1
The initial rate of reaction was?
(A) 1.76 x lo-
4
M sec"
1
(B) 2.76 x lO^M sec"
1
(C) 3.86 x iO^M sec-
1
(D) 2 xi o^Msec-
1
(feBansal Classes Problems for JEE-2007 [7]
Q. IO
Q.ll
Q. 12
Q.13
Q.14
Q.15
Q.17
Q.18
A catalyst increases the
(A) rate of forward reaction only
(B) free energy change in the reaction
(C) rates of both forward and reverse reactions
(D) equilibrium constant of the reaction
The conductance of a salt solution (AB) measured by two parallel electrodes
of area 100 cm
2
separated by 10 cm was found to be 0.0001 Q
_1
. If volume
enclosed between two electrode contain 0.5 mole of salt, what is the molar
conductivity(Scm
2
mol
_1
) of salt at same conc.
(A) 0.01 (B) 0.02
(C) 2 x 10"
5
(D) none of these
X
Y-
X
400cm
2
10cm
Arrange the following electrolytes in the increasing order of coagulation power for the coagulation
of AS
2
S
3
solution.
(I) Na
3
P0
4
(II) MgCl
2
(III) A1C1
3
( A) I < II < III (B) III = II < I ( C) I <111 <11 (D) III < I < II
If Pd v/s P (where P denotes pressure in atm and d denotes density in gm/L) is plotted for H
2
gas
d
(ideal gas) at a particular temperature. If
(A) 40 K (B) 400 K
dP
(Pd)
P=8.21atm
( C) 20 K
10, then the temperature will be
(D) none
A sample of phosphorus that weighs 12.4 gm exerts a pressure 8 atm in a 0.821 litre closed vessel
at 527C. The molecular formula ofthe phosphorus vapour is
(A)P
2
( B) P
4
(C)P
6
(D)P
g
For a gas deviation from ideal behaviour is maximum at
(A) 0C and 1.0 atm (B) 100C and 2.0 atm
(C) -10C and 1.0 atm (D) -
1 0

c a n d 4 0 a t m
Q.16 An ideal gaseous mixture of ethane (C
2
H
6
) and ethene (C
2
H
4
) occupies 28 litre at STP. The
mixture reacts completely with 128 gm 0
2
to produce C0
2
and H
2
Q. Mole fraction at C
2
H
6
in the
mixture is
(A) 0.6 (B) 0.4 (C) 0.5 (D) 0.8
100 cm
3
of a solution of an acid (Molar mass = 82) containing 39 gm of the acid per litre were
completely neutralized by 95.0 cm
3
of aq. NaOH containing 20 gm of NaOH per 500 cm
3
. The
basicity of the acid is
(A) 1 (B) 2 (C) 3 (D) data insufficient
SPM
i
^
0.2 Ma q. ; 0 , 1 5 Ma q .
NaCl Solution I CaCl-, Solution
Study the following figure and choose the correct options.
(A) There will be no net moment of any substance across
the membrane
(B) CaCL will flow towards the NaCl solution.
(C) NaCl will flow towards the CaCl
2
solution.
(D) The osmotic pressure of 0.2 M NaCi is lower than the osmotic pressure of 0.15 M CaCl
2
,
assuming complete dissociation of electrolyte.
Q.19 What is [Ag' J in a solution made by dissolving both Ag
2
Cr0
4
and Ag
2
C
2
0
4
until saturation is
reached with respect to both salts. K
sp
(Ag
2
C
2
0
4
) = 2 x 10
n
, K
sp
(Ag
2
Cr0
4
)
:
(A) 2.80 x 10-
4
(B) 7.6 x 10"
5
(C) 6.63 x !0"
6
" (D) 3.52 x
x 10
! 2
(feBansal Classes Problems for JEE-2007
[7]
0,20 A
3
B
2
is a sparingly soluble salt of molar mass M (g moH) and solubility x g lit
-1
. The ratio ofthe
molar concentration of B
3
~ to the solubility product of the salt is
x
5
1 M
4
1 M
4
Q.21 A 1 litre solution containing NH
4
C1 and NH
4
OH has hydroxide ion concentration of 10~
6
mol/lit.
Which of the following hydroxides could be precipitated when the solution is added to 1 litre
solution of 0.1 M metal ions
i Ag(OH) (K
sp
= 5 x lCr
3
) II Ca(OH)
2
(K
sp
= 8 x l (r
6
)
ffl Mg(OH)
2
(K
sp
= 3 x 1CT
11
) IV Fe(OH)
2
(K
sp
= 8 x 10"
16
)
(A) I, II, IV " (B) IV (C) III and IV (D) II, III, IV
Q.22 From separate solutions of four sodium salts NaW, NaX, NaY and NaZ had pH 7.0, 9.0, 10.0 and
11.0 respectively. When each solution was 0.1 M, the strongest acid is:
(A) HW (B) HX (C) HY (D) HZ
Q.23 AG for the conversion of 2 mol of C
6
H
6
(f) at 80C (normal boiling point) to vapour at the same
temperature and a pressure of 0.2 atm is
(A) -9.44 Kcal/mol (B) -2.27 Kcal/nioi (C) -1.135 Kcal/moi (D) zero
Q.24 A certain ideal gas has C
vm
= a + bT, where a = 25.0 J/(mol. K) and b = 0.03 J (mol.K
2
), Let 2
mole of this gas go from 300 K and 2.0 litre volume to 600 K and 4.0 litre. AS,,.,. is
gdS
(A) 32.08 J/K (B)-1-2 08 J/K (C) 64.17 J/K (D) None
Q.25 What is A
r
G (KJ/mole) for synthesis of ammonia at 298 K at following sets of partial pressure:
N
2
(g) + 3H
2
(g) ^ 2NH
3
(g); A
r
G = -33 KJ/mole. [Take R = 8.3 J/K mole, log2 = 0.3; log3 = 0.48]
Gas N
2
H, NH
3
Pressure (atm) 1 3 0.02
(A)+ 6.5 (B) - 6.5 (C) + 60.5 (D)-60. 5
Q.26 Give the correct order of initials T (true) or F (false) for following statements.
(I) Two electrons in the same atom can have the same set of three quantum numbers
(II) The lowest energy configuration for an atom with electrons in a set of degenerate orbital s
is that having the maximum number of unpaired electrons with the same spin.
(III) The value of (PV) / (RT) at critical state is 0.325
T
r
8
(IV) The ratio of Critical Constants -- is
p Rxb
r
c
(A) TTFF (B) FTFT (C)FFTT (D) TTTF
Q.27 Give the correct order of initials T (true) or F (false) for following statements.
(i) The ratio of the radii of the first three Bohr orbit of hydrogen atom is 1 : 8 : 27
(ii)
A
m (molar conductivity) for a strong electrolyte decreases as the electrolyte concentraton
increases.
(iii) The frequency of a green light is 6 x io
14
Hz, then its wavelength is 500 nm
(iv) The mass of an equivalent of H
3
P0
4
when it combines with NaOH using the equation
H
3
PG
4
+ 2NaOH > Na2HP0
4
+ 2H
2
0 is 49 g.
( A)FFTT (B) FTFT * (C) TFTF (D)FTTT
^Bansa I Classes Problems for JEE-2007
[4]
Q.28 Give the correct order of initials T (true) or F (false) for following statements
I. An azeotropic solution of two liquids has a boiling point lower then either of them
when it shows negative deviation from Raoult's Law.
II. The fraction of volume occupied by atoms in a body centered cubic unit cell is 0.74.
III. In the face-centered cubic unit cell of closest packed atoms, the radius of atoms in terms
V'3a
of edge length (a) of unit cell is
IV. If the anions (Y) form hexagonal closest packing and cations (X) occupy only 2/3 octahedral
voids in it, then the general formula of the compound is X
0
Y
3
(present in 2 : 3).
(A)FFFT (B)FFTT (C) TFFT ' (D) TTFF
Q.29 Which of the following statement(s) is/are correct:
Statement (a) : For the reaction Br, + QH~ > Br + BrOT + H
2
G, The equivalent weight of
3M
Br
2
is - y where M = Molecular weight.
Statement (b) : For an aqueous solution to be neutral it must have pH = 7
Statement (c) : For the reaction
1 1
N
2
+ NO equilibrium constant is K
L
and 2NO ^ N
2
+ (X equilibrium constant is K
2
then K
2
. K
L
= 1
Statement (d) : If the partial orders are equal to corresponding coefficients in the balanced reaction,
the reaction must be elementary (simple)
(A) Statement a (B) Statement b, d (C) Statement a. b, d (D) All
Q.30 Give the correct order of initials T (true) or F (false) for following statements.
I. If the equilibrium constants for the reaction Br, ^ 2Br at 500 K and 700 K are 10"
10
and
10~
5
respectively, then reaction is exothermic.
II. When a solution prepared by mixing 90 ml of HQ solution (pH = 3), 10 mi solution of
NaOH (pH = 11) and 60 ml water will be 3.1.
III. In the nuclear reaction p
5
U
7
Pb. the total number of a and (3 particles lost would
bel l .
IV. An aqueous solution of an alcohol (B P 56C) in water (B.P. 100C) has vapour pressure
more than that of water.
(A)TFTT (B)FFFT (C) FFTF (D)FFTT
(feBansal Classes Problems for JEE-2007
[7]
ANSWER
Q.l
Q.2
Sol.
Q.3
Q.4
Q.5
Q.6
Sol.
Q.7
Sol.
V = - = R
t
_1 1_
3
2 _
5
2
y = 7801 cm"
1
A
13.6 13.6 13.6
E
n
= - eV ; E
2
= - ; = eV/atom
AE = E
4
- E
2
= 2.55 eV
Absorbed energy = work function of metal + K.E.
2.55 = 2 + K.E.
K.E. = 0.55 eV Ans.
B
D
A
B
k
= k
k
e
i
K
b
/
eq
c
At the end of 5 hours
A
A

at the end of 10
th
hours
\ , 2
=
~
\,2
2
An A
r V2- 1 0
1
~ 2 ~ V2
=> 0.2071 mole/L
amount decayed in 0.5 L = 0.2071/2
moles of 0
2
formed = ~ (
Aq = 0 . 2 0 7 ^
f 0.2071^ 0.2071"
I 2 j 4
mole
Q.8
Sol.
Q . 9
Q.10
Q.ll
W = -PAV = -nRT = - (0.2071/4) x 8.314 x 300 = -129.14 Joule
A
^0.2071
Heat exchanged (q )
A
C
B
x AH = -0.1035 X kJ/mole
Sol. G*
/ 10
a 100
0.1 ; G = 0.0001 S ; V = 100 x 10= 1000 cm
3
= 1 litre
K X I O O ( 0 . l x 0 . 0 0 0 1 ) x 1 0 0 0
M 0 . 5
K = G G * = 0. x 0. 0001 = 10-
5
= 0.02 Scm
2
moH Ans.
(feBansal Classes Problems for JEE-2007
[7]
Q.12
Sol.
Q.13
Sol.
As
2
S
3
is negativley charged sol., so coagulation power Al
3+
> Mg
2+
> Na
+
A
PM = dRt
f \
M
V RT J
d(Pd) _ 2PM
dP ~ RT
10
2x8. 21x2
0.0821xT
= 10
Q.14
Q.15
Q.16
Sol.
T = 40 K
B
D
B
C
2
H
6
+ 3.5 0
2
-> 2C0
2
+ 3H
2
0 ; C
2
H
4
+ 30, -> 2C0
2
+ 21^0
Let vol. of ethane is x
22.4 x 4 = 3.5 x +3( 28- x)
89.6 = 3.5 x + 84 - 3x
x = 11.2 litrE
at const. T & PV a n Mole fraction of C
2
H
6
in mixture
11.2
28
xlOO = 0.4
Q.17
Sol.
B
meq" + acid = meq
n
of base
Acid: 3.9 gm acid present in 100 cm
3
Base: 20 gm NaOH present in 500 cm
3
NIV, =N
2
V
2
3 9 f 20
x 1000 = 95 x I xlOO
()
I n J
V40500
n = 2
Q.18
Sol.
Q.19
Sol.
D
7tj = ij x CjRT ; 7t
2
= i
2
x C
2
RT [only solvent (H
2
0) molecules can passed through SPM]
= 2 x 0.2RT; =3xO."l5RT
h
<n
2
D
Ag
2
Cr0
4
(s) ^ 2Ag
+
(aq) + CrO
2
" (aq)
2x + 2y x
Ag
2
C
2
0
4
(s) ^ 2Ag
+
(aq) + C
2
0
2
- (aq)
2y + 2x y
K
s p , x 2x10" x
= - = ; t => - =0. 1
K
so
y 2xl 0
_
y
2 x 10"
11
= (2x + 2y)
2
.y
= (2.2y)
2
.y 2 x 10~
n
= 4.84 y
3
y= 1.6 x 10"
4
x = 0.16 x 10"
14
Total (Ag
+
) = 2x + 2y = (2 x 0.16 + 2 x 1.6) x 10^ = 3.52 x 10"
4
Ans.
(feBansal Classes Problems for JEE-2007
[7]
Q.20 C
Sol. Solubility S = x/M
A
3
B
2
( S) ^ 3 A
2
" ( a q ) + 2 B
3
" ( a q)
3 S 2 S
, . [ A
3 -
] 2 S 1 1 M
4
K
s p
= ( 3 S ) W = JOBS' ; L - J - ^ = ^
Q. 2 1 B
Sol. when 1 litre each are mixed
[OH"] = 10"
6
M (Buffer solution)
M
n+
= 0.05 M
for M
2+
= Q = [0.5][10-
6
]
2
= 5 x 10~
14
Q > K
sp
only for Fe
2+
only Fe(OH)
2
is ppt.
Q. 2 2 A
Q. 2 3 B
Sol. C
6
H
6
(/) -> C
6
H
6
(g)
At 1 atm, AG = 0
we know for reversible processes, dG = V
m
dP - SdT (Gibbs equation)
dT = 0, dG = V
m
dP
for a reaction, d(AG) = n(AV
m
)dP (for n moles)
P
2
P
2
Jd(AG) - n j(AV
m
)dP; P
t
= 1 atm and P
2
= 0.2 atm
Pi Pi
n = 2 and, AV
m
= V
g
- V
g
= ~
?
R T
H P
AG
0
.
2 atm
- AG,
a t m
=
n
J ^ ^
AG
1 atm
= 0
1
0.2
=> AG
0 2 atm
- 2 x RT In = - 2.27 Kcal/mol
Q.24 C
, r nC
v
dT r dT
f
( a + bT)dT
f
R
J W n
r (25 + 0.03T)dT
Sol. j ds = J + j nR = 2j + 2J - d V = 2j i ' + 2R^n2
= 2[25 ^n2 + 0.03 [T
2
- TJ] + 2Rin2 => 2[25 x 0.693 + 0.03 x 300] + 2 x 8.314 x 0.693
= 52.65 + 11.52
AS = 64.17 J/k
Q. 2 5 D
Sol. AG = AG
0
+ RT In
P
2
NH
3
Pn
2
xPH
2
(0.02)
AG = -33000+ 8.314 x 2.303 log f - = - 60.5 kJ/mole
1x3
Q.26 A Q.27 D Q.28 A Q.29 A Q.30 D
(feBansal Classes Problems for JEE-2007 [7]