whee CD is the dimensionless dag coefficient, and is velocity head. The dag c
oefficient is a function of the Reynolds numbe. In the lamina flow egion whe
e NRe<1, Stokes Law dominates and CD is given by (Geankoplis, 1993) (1) In sedime
ntation, the paticles expeience a peiod of acceleated fall and a peiod of c
onstant velocity fall (Geankoplis, 1993). The constant velocity peiod is usuall
y of moe impotance, as the acceleated fall peiod is vey shot elative to t
he constant velocity peiod. In the constant ate peiod, the paticles each a
maximum settling velocity known as the teminal velocity, vt. The teminal veloc
ity is detemined by solving the velocity at which the sum of the thee foces i
s equal to zeo. Geankoplis gives the equation fo the teminal velocity of sphe
es as (2) whee Dp is the paticle diamete.
RESULT AND ANALYSIS The mechanism of solid settling fom sluy can be best obse
ved in a glass cylinde as shown in Fig. 1 below.
90 80 70 60 50 40 30 20 10 0 0.00
Clea Liquid Inteface vs. Settling Time (Vaying Initial Heights)
Clea liquid inteface height, z, cm
tube 1 tube 2 tube 3
0.50
1.00 Settling time, , hr
1.50
2.00
Fig. 2. Clear Liuid Interface vs. Settling Time (same concentration, different
initial heights)
Fig.1 . Batch Sedimentation (Source: McCabe, 2001) Initially, the slurry is unif
ormly concentrated and the initial height is zo, as shown in Fig. 1a. The concen
tration of the slurry is high enough that the particles affect each others rate o
f fall to the extent that after a short time, all particles settle at the same v
elocity and are assumed to approach rapidly the terminal velocities under hinder
ed-settling conditions (Foust, 1980). The concentration is high enough to cause
settling as a matrix, that is, the particles remain in a fixed position relative
to each other as they settle (www.cee.cornell.edu). Heavier solids settle faste
r, thus forming zone D shown in Fig. 1b. Zone A is the region of clear liuid (F
oust, 1980). Zone B is a region of uniform concentration which is essentially e
ual to the initial slurry concentration (McCabe, 2001). In this zone, the partic
les settle by free settling and at a uniform rate (Geankoplis, 1993). Zone C is
the transition region wherein the concentration is nonuniform and the sizes of t
he particles are varied (Foust, 1980). As sedimentation goes on, the depth of zo
ne B decreases, the depths of zone A and D increase, while that of zone C remain
s constant, as shown in Fig. 1c (McCabe, 2001). Zone B eventually disappears, an
d the solids in zone C and D merge such that only zone D is distinct, as shown i
n Fig. 1d. During this stage, the matrix of particles gets constrained from the
bottom because of the bottom of the settling tank. Such a situation is called co
mpression settling (www.cee.cornell.edu). The moment (or height) at which zone B
and C disappear and all the solids appear in zone D is referred to as the criti
cal settling point. By definition, it is the point at which a single distinct in
terface forms between the clear liuid and sediment (Foust, 1980). Beyond the cr
itical settling point, sedimentation occurs by compression. The gradual accumula
tion of the upper particles compress the solids at the bottom and decrease the h
eight of zone D, and force the residual liuid in zone D out upward through the
solids into the clear liuid zone. The settling rates during compression settlin
g are very slow, and the rates may be estimated using hindered settling computat
ion methods. Fig. 1e shows the end state of the sedimentation process, in which
the weight of the solid is balanced by the compressive strength (McCabe, 2001).
Sedimentation design and calculations are based upon identifying the concentrati
on of the layer having the lowest capacity for the passage of solids through it.
This particular layer is called the rate-limiting layer, cL (Foust, 1980). One
of the objectives of this experiment is to determine the effect of varying initi
al slurry heights (or volume) on the sedimentation characteristics. Initially, t
he concentrations of the three samples were kept constant and their initial heig
ht was varied. The results for the first objective are presented first, followed
by the results for the varying concentration. As discussed earlier and shown in
Fig. 1, different zones appear during sedimentation. Fig. 2 is a plot of the de
pth of the clear zone versus time. The plot shows that during initial stages of
sedimentation, the depth of the clear zone decreases at a constant rate as sedim
entation goes along, as shown by the steep linear part of the plot. The plot als
o shows that the slope changes after a certain depth has been reached. The curve
of the plot during the later stages of sedimentation is almost horizontal yet s
till almost linear. The part of the plot that is almost horizontal represents th
e compression settling stage, wherein hindered settling dominates.
Fig. 3. Getting the zone settling velocity (Source: www.ceeserver.cee.cornell.ed
u)
As shown by Fig. 3, the settling velocity for the different regions can be deter
mined from the plot of liuid interface height versus time. The slope of the ste
ady interface subsidence rate represents zone settling velocity.
Tube 1: Determination of Velocity
900 800
Clear liuid interface height
700 600 500 400 300 200 100 0
-20
0
20
40
60 Settling time
80
100
120
140
Fig. 4. Determining the settling velocity
Fig. 4 shows the method used in this experiment to determine the settling veloci
ties at different points. The slopes of the tangent lines at each point, which i
s eual to the settling velocity at the point, were determined. In euation, (3)
The exact values of the settling velocities of each trial are shown in the appe
ndix. From the y-intercept of the tangent lines in Fig. 4, the height zi that th
e slurry would occupy at concentration cL is determined. The zi data can be used
to determine the minimum concentration cL at which boundary layer interferes, u
sing the euation (4) where co and zo are the initial concentration and height,
respectively. Exact values of cL are given in the appendix.
Settling velocity vs. Concentration
the nearer presence of the other particles slow each others settling velocity. Th
e velocity in the compression settling zone is significantly less than that in t
he earlier region. Fig. 5 also shows how the initial height (or volume) of the m
ixture affects the settling velocity of the mixture. The sample with the highest
initial height (namely, tube 1) had, in general, the fastest settling rates com
pared to rates of the other samples.
Tube 1: Height vs. Time
900
Clear liuid interace height, z, cm
800 700 600 500 400 300 200 100 0 0 20 40 60 Settling time, , hrs 80 100 120
200 180
Settling Velocity (cm/hr)
160 140 120 100 80 60 40 20 0 0.00 50.00 100.00 150.00 200.00 250.00
Fig. 7. Getting the critical settling point
Concentartion (g/L) tube 2 tube 3 tube 1
Fig. 5. Settling Velocity vs. Concentration (same height, different concentratio
n)
Time, mins
As the sedimentation process goes along, the concentration of
increasingly becomes more concentrated because the solids are
cted. As this happens, the settling velocity decreases as the
eases, as shown in Fig. 5. Notice that the velocity decreases
nt rate when the concentration is relatively low.
Settling Velocity vs. Settling Time
200 180 160 140
Additional information that can be determined from the z vs. plot is the critica
l settling point, as illustrated in Fig. 7. The critical point is the point wher
e a single distinct interface forms between the clear liuid and sediment can be
obtained. At the start of sedimentation, the solids have a concentration co and
free settling is observed. A tangent line is drawn at this part. On the other h
and, another linear behavior which is almost horizontal is observed at the other
end of the graph. A tangent line is also drawn at this part. These lines are ex
tended until they intersect. The angle between these two lines is measured and a
n angle bisector is used. The bisector is extended until it touches the curve. T
he point of intersection is the critical point. A tangent line is made at the cr
itical point. Extending this line gives the value of the concentration and time
at the critical point. (Foust, 1980)
100
50
0 Settling Time
Fig. 11. Settling Velocity vs. Settling Time (same initial height, different con
centrations)
In accordance with theory, the more concentrated sample had lower settling veloc
ity, as shown in Fig. 11. Greater number of solids block the water below from ri
sing up, thus the solids take longer to settle down. However, as the particles r
each the compression settling zone, the trend is reversed, that is, the more con
centrated sample had faster settling velocity. This is probably because the weig
ht of the solids that compress the particle matrix is the determining factor in
the compression