6.5 Sample Program Chemistry Stage 6 Syllabus: Module 8.4
Water (! i"di#ati$e hours% 6.5.& Co"te'tual (utli"e )rom Syllabus The first astronauts who viewed the Earth from space commented on the beauty of our water-rich blue planet Earth!s position in the solar system enables its retention of water in solid" li#uid and gaseous forms on and around its surface The particular properties of the water molecule assisted the evolution of life and continue to support life processes The concepts of bonding and intermolecular forces are used to increase understanding of the special nature of the water molecule The chemistry of solutions is e$amined in greater detail to e$plain the differences between bodies of fresh and saline water as well as assisting in the e$planation of common chemical reactions that occur in an a#ueous medium! 6.5.* Co"#ept Map 11% Water Solutions Energy Structure Shape Physical properties &mportance to 'ife Endothermic and e$othermic reactions Specific heat (olarity Precipitation E#uilibrium introduced 'ewis diagrams Polar )ature Science Stage 6 Support Document Part 1 6.5. S+ills During this module" teaching*learning activities should allow time to move from the macroscopic and observed world of the student into the microscopic and abstract world of theoretical chemistry where visualisation at the atomic and molecular levels is necessary to enhance conceptual understanding S+ill development relies on teacher input to revise and review s+ills that students have been taught in earlier modules This process will identify s+ills that students may need further assistance in refining during the module The s+ill development in this program focuses on, - safe wet lab wor+ with independent ris+ assessment" efficient use of resources" micro-techni#ues to minimise wastage and appropriate disposal of waste materials - calculations, . of concentration including molarity . re#uired to dilute solutions . re#uired to predict product yield in precipitation reactions S+ills that need to be taught during the module have been identified with a T after the code for the s+ill in the Suggested Teaching*'earning /ctivities The need to teach a s+ill will have been identified several times in the module 0owever" it is e$pected that the level of support re#uired should decrease during the module as students increase their e$pertise 6.5.4 ,alues a"d -ttitudes /s this module leads to students having an increased understanding of solubility and the pivotal role of water as a lin+ between the living and non-living worlds" it raises students! awareness of the need for the safe and thoughtful disposal of wastes / study of this module will" assist the development of positive values about and attitudes towards the safe" and efficient use of resources so that the purity of water resources is maintained and conserved 111 Science Stage 6 Support Document Part 1 6.5.5 Some .e)ere"#es )or /his Sample Program 111 Science Stage 6 Support Document Part 1 Texts 1 /t+ins" P 2 3ones '" Chemistry: Molecules, Matter and Change" 4 rd edn, 5reeman" )ew 6or+" 1778" &S9) % 8168 1:41 ; with <D-=>( 1 /ubusson P" ?ennedy" E 2 Snyder @" Biology: The Spectrum of Life" 1 nd edn, 1776" >$ford Aniversity Press /ustralia" &S9) % 17BB 4:1% ; 4 9ucat" = 9 Elements of Chemistry, Vol 2, 17:C" /ustralian /cademy of Science &S9) % :B:C8 11C % C Deretic D 2 @are D" Senior Chemistry ractical Manual, 177B" =igby 0einemann &S9) % :B:B7 8:7 6 B 3oesten" (D 2 @ood" 3'" !orld of Chemistry" 1 nd edn" 1771" Saunders 5ort @orth" Te$as" 1777" &S9) % %4%% CC64 C 6 ?otE" 3< 2 Treichel P" Chemistry and Chemical "eacti#ity, C th edn" 1777 Saunders &S9) % %4%1 4861 7 8 (udie" ? 2 9rotherton" 3" Core Biology ractical, 17:C 0einemann Education /ustralia" =ichmond" F&<" 17:C" &S9) % 7B7% B77% 4 : )/T</P" Chemistry 2 $nit: L The Mole Set 2: $sing the mole %ith mass and concentration 177C 'earning (aterials Production <entre" Strathfield" 177C" &S9) % 841% 4116 1 7 )/T</P" Chemistry 2 $nit Structure and Bonding Set &: Structure and 'onds in co#alent 'onding 177C 'earning (aterials Production <entre" Strathfield &S9) % 841% 6B41 ; 1% Plummer" << 2 (cDeary" D" hysical (eology, @< 9rown Publishers 1776" &S9) % 6781 6686 1 11 Stralow" D" ractical )n#estigations in Chemistry, >$ford Aniversity Press" (elbourne" 177B" &S9) % 17BB 468C 6 11 Thic+ett D" ath%ays to Chemistry" 1776" (acmillan Education /ustralia &S9) % 8417 C1%6 8 14 Thomson"D= 2 Tur+" 3" )ntroduction to hysical (eology" Saunders" 5ort @orth" Te$as" 177:" &S9) % %4%1 C4C: 4 1C @are" D" Deretic" D 2 @est" /" *undamentals of Senior Chemistry ractical La'oratory Manual, 0einemann Educational /ustralia" =ichmond" F&<" 17:1" &S9) % :B:B 7184 : 1B @il+inson" 3@ 2 )ash" 93" Chemistry Today, ractical Manual" 177% (acmillan /ustralia" South (elbourne" 1777" &S9) % 8417 %41C 8 !e'sites 16 http,**wwwepanswgovau*beach*inde$asp This website has daily readings and forecasts of water temperature readings as well as ocean pollution information 18 http,**globefslnoaagov*fsl*welcomehtml The Dlobe program is an international system where schools and groups across the world are providing data on many physical factors in the environment @ith easy prompts" students can find surface water temperatures for many locations in and out of /ustralia 1: http,**wwwcatalinaconservancyorg*marine*physical*seaGtemphtm The <atalina <onservancy Divers H<<DI undertoo+ a research proJect to collect ocean temperature data from several different depths using bathythermographs 114 Science Stage 6 Support Document Part 1 placed at selected sites along the coast of <atalina &sland The data represented shows the daily average ocean temperature in the marine refuge at the @rigley AS< (arine Science <enter at a depth of 1B metres from 3uly through >ctober of 177C 17 http,**www1austincct$us*rvsmthsc*chem*boo+htm This site has a range of e$periments related to the physical characteristics of substances" including density and specific heat 1% http,**ostraconbiologieuni-+lde*bGonline*e1:*1:chtm Properties and energy contents of covalent bondsK describes the wea+ interactions" includes hydrogen bonds and uses the water molecule as an e$ample 11 http,**wwwbiologyariEonaedu*biochemistry*tutorials*chemistry*page4html This tutorial on the chemistry of water describes the polarity of water and its cause" the solution of water-soluble substances" acids and bases and the ionisation of water 11 http,**wwwo+stateedu*Jgelder*bondpage6html This website contains a laboratory activity about physical properties and chemical bonding in solids &t has both a student version and a teacher version and ta+es the students through a practical activity" with safety issues discussed Demonstrations and some history included within this site 14 http,**wwwdunningcomau*B1%1%1html This has one page on the lowered (P and raised 9P achieved by anti-freeEe and some information about its composition" properties" and uses 1C http,**octopusgmaorg*surfing*antarctica*salthtml Starting with the #uestion" how do cold-blooded animals survive sub-freeEing water temperaturesL the four-page site discusses salt concentrations in cold water" identifies and describes the range of organisms found in /ntarctic waters and includes an e$periment to see how the sea freeEes! /lthough this deals with /ntarctic conditions" the site is AS-based and the te$t will need slight adJustment to be useful in )S@ 1B http,**wwwfedcuh+eduh+*MJohnson*teaching*biologyGlesson*molecules*labChtml This site provides lessons for ?.: teachers but includes much of the vocabulary revised and*or introduced in this module &t will be useful for 6ears 8.: but some of the practicals on diffusion and osmosis could be adapted for use in 6ear 11 16 http,**wwwnwforg*nw+*greatla+es*pp*mercuryhtml This contains a 16-page document on Mercury Contamination in !aters of the $nited States &t discusses the problems caused by mercury in the environment" its origins from industrial sources and strategies to reduce mercury contamination The te$t uses and thus illustrates alternative methods of describing concentrations +ote , students need to 'e good readers to use the %hole text- 18 http,**wwwoEemailcomau*Mtblac+*selGsummhtm Selenium and .ea#y Metals from *ish in La/e Mac0uarie- /n /ustralian e$ample . the te$t uses simpler language" and describes studies conducted by a steering committee managed by the 0unter Public 0ealth <ommittee <oncentration levels are described in mg*+g The te$t discusses the role of selenium in living things" its origins and reasons for limiting inta+e of selenium-affected fish /rticle 11C Science Stage 6 Support Document Part 1 is short and would be useful for less able readers 1: Monitoring the +ation1s Estuaries: 2 rogram in rogress- This is an e$tensive site with information on the sampling of water and wildlife in estuaries in the AS 17 http,**wwwde#statemius*ogl*sagbay*sprtfishhtm / three-page section of a sports fishing site with brief descriptions of issues associated with catching and eating fish from the Saginaw @atershed in (ichigan Aseful as issues associated with bioaccumulation of pollutants are clearly e$plained 4% http,**wwwinfohuntnswgovau*la+emac*environ*soe*soehtm / 64-page report on the State of the Environment with reference to 'a+e (ac#uarie pages 11.44 focus on water issues Videos &3- Chemical Bonding Series: )nner *orces- Fideo Education /ustralasia Pty 'td" 111 (itchell St 9endigo 4BB% / four-program series with a comprehensive coverage of chemical bonding The programs use computer-generated graphic models and footage of e$amples from everyday life to illustrate and e$plain the principles of chemical bonding Titles are, aI 9onding in (etals bI &onic 9onding cI 9onding in (olecules dI 9onding between (olecules &2- The lanet !ater, 177%" @ater 9oard" 11B 9athurst St Sydney This is part of a +it . !ater: State of the "esource developed by the community education team at the @ater 9oard The video gives information on water as a molecule and water!s impact in the environment &t also includes material on water pollution &&- The VisChem "esources- These lin+ the three thin+ing levels! . molecular" laboratory and symbolic They contain molecular*ionic animations which portray substances in the solid" li#uid and gaseous states" during phase changes and when reacting There are three videos in the series, aI The (olecular @orld of @ater . this portrays the dynamic arrangement of water molecules in solid" li#uid and gaseous water" and the changes that occur in melting" evaporation and boiling bI The (olecular @orld of =eactions in @ater . part 1 . this portrays sodium chloride dissolving in water" hydrated ions in solution" precipitation of silver chloride and formation of a copperH&&I comple$ cI The (olecular @orld of =eactions in @ater . part 1 . This video covers e$amples of ionic e#uilibrium" acid*base and o$idation*reduction chemistry /ll three are distributed by Fideo Education /ustralasia Pty 'td" 111/ (itchell St" 9endigo C45"6M &7- Chemical Bonding: )nner *orces, Fideo Education /ustralasia Pty 'td" 111 (itchell St 9endigo 4BB% The <D-=>( includes video footage" animations with accompanying dialogue and tests at the end of each module &t includes material on, aI /tomic structure bI &onic compounds 11B Science Stage 6 Support Document Part 1 cI (etallic substances dI (olecular compounds eI <ovalent substances fI 9onding revision &8- The 4ynamic Coast , processes, landforms and human impacts, Distributed by FE/ Pty 'td 111 (itchell St" 9endigo 4BB% This is a static <D-=>( that includes still visuals with te$ts to e$plain a range of coastal processes &t includes material on, aI @aves bI 0ow the coast is worn away cI =easons why some parts of the coastline wear faster than others dI 'andforms due to erosion eI (ovement of material fI Depositional landforms gI 'andforms produced by changes in sea level hI 0umans and the coast iI 5ield wor+ &9- Chemistry : Science Series Produced and published by ?nowledge 9oo+s and Software email, ordersN+bscomau This <D includes animated and 4-D footage with dialogue and te$t &t includes material on, aI Elements and the periodic table bI /toms" molecules and ions cI Electronic structure dI <hemical bonding &;- The VisChem "esources: Su'stances and "eactions in !ater uses animation to portray pure substances such as sodium chloride" copper and o$ygenK phase changes such as ice meltingK and reactions in solution such as dissolving" precipitation" comple$ation and acid*base hydrolysis The <D has a short description for each animation and a flow chart to show the relationship between the animations This is distributed by Fideo Education /ustralasia Pty 'td" 111/ (itchell St" 9endigo 116 Science Stage 6 Support Document Part 1 6.5.6 -ssessme"t /as+s (ut#omes about 0hi#h i")ormatio" is bei"g gathered - ra"ge o) possible diag"osti# a"d1or )ormati$e assesme"t tas+s P6.1% Pre-test or concept map developed to ascertain prior +nowledge P1C P6 P11 P14 =esearch assignment to identify cause and effect relationships between the properties of water and a geological" biological or physical phenomenon This could ta+e the form of a guided open-ended in#uiry involving a media search or use of a range of resources The findings could then be presented to the class in an oral or multi-media presentation To ensure that the full range of outcomes is assessed" it is important to collect evidence of research in the form of rough notes" photocopied resources and summaries The presentation can be assessed on the effectiveness of the presentation" choice of oral te$t used as well as accompanying notes provided Part of this tas+ would be the identification by the student of the actual cause and effect relationship presented This would re#uire a wor+ing +nowledge of the investigated property of water and an e$planation of how it results in the phenomenon discussed H/s 1C1g is to be taught in this module" it would be important that the teacher models and gives ample opportunity for practice of this s+ill before it is assessed This tas+ could be used as a diagnostic assessment tas+ with a view to providing feedbac+ towards better development of this range of s+ills Students! prior e$periences would determine the use of this tas+I P: P11 P11 P1C P1%" P14 Practical test to identify un+nown ionHsI in solution &f students are given time to prepare for this assessment" they could design" plan" choose e#uipment and carry out the procedure The assessment could include the identification of the ions that precipitated" Justification of inferences and writing of correct ionic e#uations Students would need to be given a table of solubility rules 5ormulas for ions could be included in the table if +nowledge of correct formulas was not re#uired in their development at this stage Part of the assessment could cover the safety issues and wor+ practices used by the students during the tas+ HThis assessment tas+ could be summative only if students have had prior e$perience in this type of tas+ and have had at least one diagnostic tas+ to ensure that any misconceptions about the routine or gaps in their +nowledge have been addressedI PC P14 &n the last bloc+ of the module is the following dot point, in groups or through class discussion" propose an e$planation for the importance of water!s high specific heat for a#uatic organisms and for life on earth in general &f there has been sufficient class discussion and collection of data throughout the module" this could become an assessment #uestion Students would need to generate an e$position te$t type to answer this #uestion HThis could be used as a diagnostic or summative assessment tas+ collecting information about a range of outcomes but it is emphasised that students would need prior teaching and practice with this essay style of #uestionI 118 Science Stage 6 Support Document Part 1 Syllabus 2'tra#t ($er$ie0 @ater is distributed on Earth as a solid" li#uid and gas! &t is found in both the living and non-living worlds and its physical properties determine many of the conditions that form Earth!s environments (5 i"di#ati$e hours% Syllabus .e)ere"#e Students learn to: Students: recall the terms" solute" solvent and solution recall the importance of water as a solvent compare the state" percentage and distribution of water in the biosphere" lithosphere" hydrosphere and atmosphere outline the significance of the different states of water on Earth in terms of water as, a constituent of cells and its role as both a solvent and a raw material in metabolism a habitat in which temperature e$tremes are less than nearby terrestrial habitats an agent of weathering of roc+s both as li#uid and solid a natural resource for humans and other organisms perform an investigation and gather data to solve problems and analyse information involving calculations of the density of water as a li#uid and a solid using density < mass=#olume analyse information by using models to account for the differing densities of ice and li#uid water plan and perform an investigation to identify and describe the effect of anti- freeEe and salt on the freeEing point and*or boiling point of water Preparatio" 1 &dentify and photocopy data for graphing abundance" percentage and state 1 &dentify reference resources for use by students HPrepare summary scaffold" diagnostic test on summary*collate s+illsI 4 &dentify prac" order e#uipment and consumables C <ollect data on daily air temperature versus daily water temperature Possible sources include, . weather reports HTF and newspaperI . websites 11: Science Stage 6 Support Document Part 1 Suggested /ea#hi"g a"d 3ear"i"g -#ti$ities S + i l l s
< o n t e n t
= e g i s t e r Students: using teacher-supplied tabulated data" construct pie graphs that compare the abundance and state of water in the biosphere" lithosphere" hydrosphere and atmosphere 141 f using a teacher-provided cloEe tas+" use the words solute" solvent and solution in conte$t 1C4 b initiate a class discussion using prior +nowledge reviewing the number and types of chemical substances that do and do not dissolve in water 1C4 b outline the significance of different states of water by, using teacher-supplied reference te$ts" Journal articles and prior +nowledge" collate information about water!s importance in cells and as a transport medium for dissolved nutrients in living things 1
114 d accessing an appropriate website or other resource material to compare temperatures in an a#uatic environment with those in a terrestrial environment over a period of time 1 1C1 a"e" 114 a"b in the light of a teacher-led discussion of the cause*effect e$planation for phenomena" describing the benefits to a living organism of a habitat with low temperature variation" and comparing them with the problems faced by organisms that reside in an environment with high temperature fluctuations 1C1 g / 1C4 b using supplied reference te$ts or other sources" identify and summarise the various ways water acts as a weathering agent in both solid and li#uid form & 114 d after class discussions and use of appropriate teacher-selected resources" identifying and summarising the importance of fresh water as a resource for humans and other organisms 1 1C1 a 114 d brainstorm and draw on prior +nowledge to define density 1C4 b investigate the differing densities of ice and water by, carrying out a teacher-planned procedure to gather data on the mass and volume of water in li#uid and solid form C
111 a 111 b using first-hand data calculate the density of both ice and li#uid water using the formulae density < mass=#olume B 11C b using appropriate models of ice and li#uid water to account for the differing densities of ice and li#uid water 6 1C1 f 1 Fideo The lanet !ater, /ubusson et al" section 17 1 wwwepanswgovau*beach*inde$asp" 5o$tel @eather etcK http,**globefslnoaagov*fsl*welcomehtml would be useful as both terrestrial and a#uatic temperatures are already graphed for comparison 4 Thomson 2 Tur+: )ntroduction to hysical (eology- 177:K <D =>( The 4ynamic Coast , processes, landforms and human impacts> Fideo The lanet !ater 9ucat =9, Elements of Chemistry Vol 2 17:C 1 C @il+inson p1K http,**www1austincct$us*rvsmthsc*chem*boo+htm B @are et al, *oschem Senior rac Manual 17:1" @il+inson and )ash, p4 6 Fis<hem The Molecular !orld of !ater 117 Science Stage 6 Support Document Part 1 with teacher assistance if necessary" identifying and using cause and effect relationships to relate these results to the e$istence and effects of icebergs" and the effects on living organisms living in cold waters 8
1C1 g / identify and describe the effect of adding additives to water by, designing an investigation that allows valid and reliable data or information to be collected about the effect of anti-freeEe and salt on the freeEing and*or boiling points of water : 111 c carrying out the planned procedure" recognising where modifications may be needed with the use of anti-freeEe and then salt as the additives in water 111 a selecting and drawing appropriate graphs to show the effect of the above chemicals on the boiling point and*or freeEing points of water 7 141 f identifying and e$plaining how this data supports the use of anti- freeEe for prevention of freeEing in car radiators 1% and the use of salt to +eep roads open in cold climates affected by ice and snow 1C1 b 8 http,**octopusgmaorg*surfing*antarctica*salthtmlK ?otE 3<" Treichel P p 44 : http,**octopusgmaorg*surfing*antarctica*salthtml 7 Thic+ett p 11-11 1% http,**wwwdunningcomau*B1%1%1html 11% Science Stage 6 Support Document Part 1 6.5.6 Syllabus 2'tar#t ($er$ie0 The wide distribution and importance of water on Earth is a conse#uence of its molecular structure! >ther molecules of a similar mass do not have the same properties (6 i"di#ati$e hours% Sylabus .e)ere"#e Students learn to: Students: construct 'ewis electron dot structures of water" ammonia and hydrogen sulfide to identify the distribution of electrons compare the molecular structure of water" ammonia and hydrogen sulfide" the differences in their molecular shapes" and in their melting and boiling points describe the model which accounts for the une#ual distribution of electrons in the water molecule identify the water molecule as a polar molecule describe the attractive forces between polar molecules as dipole-dipole forces describe hydrogen bonding between water molecules as an e$ample of a particularly strong form of dipole- dipole force e$plain the following properties of water in terms of its intermolecular forces, surface tension adhesion cohesion viscosity boiling and melting points hardness and brittleness process information from secondary sources to graph and compare the boiling and melting points of water with other similar siEed molecules identify data and process information from secondary sources to model the structure of the water molecule and effects of forces between water molecules choose e#uipment and perform first- hand investigations to demonstrate the following properties of water, surface tension adhesion cohesion viscosity gather and process information from secondary sources and use the available evidence to analyse the implications of one of the properties of water for plants or animals Preparatio" 1 &dentify and photocopy data for graphing mp and bp 1 &dentify reference resources to be used by students . boo+ library or space to use videos" &nternet or <D-=>(s for data collection and information gathering 4 Prepare models or other resources to show the molecular structure of various compounds 111 Science Stage 6 Support Document Part 1 C &dentify reference material and develop notes on bonds and molecule shapes Suggested /ea#hi"g a"d 3ear"i"g -#ti$ities S + i l l s < o n t e n t = e g i s t e r Students: demonstrate and collect information about the following properties of water, surface tension" adhesion" cohesion" viscosity" boiling and melting points and hardness and brittleness by, identifying and setting up the most appropriate e#uipment to underta+e the investigation into the properties of water 114 a carrying out a teacher-planned procedure or set of procedures to identify and describe some of the properties of water 11 111 a-d graphing the melting and boiling points of a variety of compounds" including water" of similar molecular mass from teacher-supplied data 11 11C c identifying and describing any trend or pattern in the data 1C1 a predicting a possible e$planation for the differences between water and other compounds of similar molecular mass 1C1 c use teacher-selected resources" notes and molecular model +its to compare the structure of water" ammonia" hydrogen sulfide 14 Hand carbon dio$ide used as an e$ample of a small linear moleculeI 1C1 f following teacher modelling" ma+e appropriate generalisations to e$plain these shapes with respect to 'ewis electron dot diagrams 1C 1C1 e use teacher-selected resources and notes to develop an e$planation of molecular shapes using the Falence Shell Electron Pair =epulsion HFSEP=I model 1B 1C1 d / optional extension: discuss the usefulness and limitations of VSE" model in descri'ing molecular shapes 37-& c use the Periodic Table and a table of electronegativity values to compare the relative polarities of bonds between 0 . )K 0 . >K 0 . S and < . > 16 1C4 b account for the une#ual sharing of electrons in a polar bond 18 1C1 f use the information about the polarity of bonds and the shape of 1C4 c 11 Stralow pC%K 11 S& <hemical Data 9oo+ 14 /t+ins et al <haps 7"1%K <D =>( <hemical 9ondingK Fideo <hemical 9ondingK )/T</P Chemistry 2 $nit Structure and Bonding Set & 1C /t+ins et al <haps 7"1%K 3oesten (D" @ood 3'K Thic+ett p 164K @il+inson p 47-C1K )/T</P Chemistry 2 $nit Structure and Bonding Set & K 1B /t+ins et al <haps 7"1%K Thic+ett p 167-18%K )/T</P Chemistry 2 $nit Structure and Bonding Set & 16 /t+ins et al <haps 7"1%K <D =>( <hemical 9ondingK Fideo <hemical 9ondingK http,**ostraconbiologieuni-+lde*bGonline*e1:*1:chtmK http,**wwwbiologyariEonaedu*biochemistry*tutorials*chemistry*page4htmlK Thic+ett p 181K )/T</P Chemistry 2 $nit Structure and Bonding Set & 18 3oesten (D" @ood 3'K ?otE 3<" Treichel P p C%: 111 Science Stage 6 Support Document Part 1 molecules to predict the polarity of a series of molecules including water" ammonia" hydrogen sulfide and carbon dio$ide use teacher-selected resources and notes to list and describe the variety of intermolecular forces 1: 114 a-d use the term dipole-dipole force! to describe the attraction between polar molecules 17 use appropriate secondary sources to visualise the formation of hydrogen bonds between water molecules 1% 114 c describe hydrogen bonding between water molecules as a particularly strong form of dipole-dipole force 11 1C1 a relate the formation of ice crystals and the decreased density of water as a solid to the formation of hydrogen bonds 1C4 b in groups" as a Jigsaw activity" assess the reliability of information by comparing several resources and the above practical procedureHsI to describe and analyse the effect of forces between water molecules in determining the following properties of water 11 , 11C e melting point boiling point surface tension 14 adhesion 1C cohesion 1B viscosity hardness 16 brittleness present to the class the findings of the group in the form of an oral and*or written report Each student*group prepares a summary about one property of water so that the class is given a summary of all the properties of water in terms of intermolecular forces HThis could be used as a diagnostic assessment tas+ if students have had practice in this s+ill in earlier modules /lternatively it could be used as a summative assessment tas+" provided students have been taught 141a 1: /t+ins et al <haps 7"1%K <D =>( <hemical 9ondingK Fideo <hemical 9ondingK Thic+ett p 18:- 187 http,**wwwbiologyariEonaedu*biochemistry*tutorials*chemistry*page4html 17 /t+ins et al <haps 7"1%K )/T</P Chemistry 2 $nit Structure and Bonding Set & 1% /t+ins et al <haps 7"1%K 3oesten (D" @ood 3'K Fis<hem Fideo The Molecular !orld of !ater> <D =>( Su'stances and "eactions in !ater 11 /t+ins et al <haps 7"1%K 3oesten (D" @ood 3'K Thic+ett p 1:%-1:1 11 /t+ins et al <hap 1%K Fideo The lanet !ater 14 /ubusson et al section 17K 5or 9iology students" the properties of water and their importance in movement of materials through plants could be combined through the following article, <anny (3 Transporting !ater in lants /merican Scientist Fol :6 (arch-/pril 177: p 1B1-1B7 1C /ubusson et al section 17 1B /ubusson et al section 17 16 Earth and Environmental Science students could use the following article to combine their wor+ on dating and past climates, /lley =9" 9ender (' (reenland )ce Cores: *ro?en in Time 177: Scientific /merican Fol 18: )o 1 p 66-81 114 Science Stage 6 Support Document Part 1 and have practised the s+ills involved on several earlier occasionsI analyse the implications of one of these properties of water for plants and*or animals by, establishing the reliability" validity and relevance of the information in identified data sources 11C e summarise and collate information from the identified range of resources about the implications of the selected property of water on plants and*or animals 18 114 d propose ideas about the implications of the selected property of water" demonstrating" wherever possible" logical progression and the correct use of chemical principles and ideas about water 1C4 b establish and describe cause and effect relationships between the selected property of water and the proposed implications to plants and*or animals 1: HThis se#uence of tas+s could also form a diagnostic or summative assessment tas+ The use of the tas+ in this way would depend on students! prior e$periences in these s+ills in earlier modulesI 1C4 d 1C1 g 18 /ubusson et alK http,**octopusgmaorg*surfing*antarctica*salthtml 1: http,**octopusgmaorg*surfing*antarctica*salthtml 11C Science Stage 6 Support Document Part 1 6.5.4 Syllabus 2'tra#t ($er$ie0 @ater is an important solvent in biological systems transporting materials into and out of cells &t is the medium through which a#uatic organisms obtain gases as well as other nutrients! &t is also an important solvent in many geological chemical reactions &ts ability to both act as a solvent and as a medium for many chemical reactions as well as a reactant in corrosion reactions must be considered in the design of static and mobile structures (5 i"di#ati$e hours% Syllabus .e)ere"#e Students learn to: Students: e$plain changes" if any" to particles and give reasons for those changes when the following types of chemicals interact with water a soluble ionic compound such as sodium chloride a soluble molecular compound such as sucrose a soluble or partially soluble molecular element or compound such as iodine" o$ygen or hydrogen chloride a covalent networ+ structure substance such as silicon or silicon dio$ide a substance with large molecules" such as cellulose or HpolyIethene summarise the relationships between the bonding types in common substances and their solubilities in water analyse the relationship between the solubility of substances in water and the polar nature of the water molecule e$plain the relationship between the ionisation of some molecules in water and the formation of acids and al+aline solutions distinguish between diffusion and osmosis involved in the movement of substances in and out of cells and relate this movement to the particle theory of matter perform a first-hand investigation to test the solubilities in water of a range of substances that include ionic" soluble molecular" insoluble molecular" covalent networ+s and large molecules process information from secondary sources to visualise the dissolution in water of various types of substances and solve problems by using models to show the changes that occur in particle arrangement as dissolution occurs Preparatio" 1 &dentify appropriate practical e$periments and order consumables as well as e#uipment 1 9oo+ space to use video" <D-=>( or &nternet to view animations suggested 4 &dentify useful graphics or resources to demonstrate activities at the 11B Science Stage 6 Support Document Part 1 molecular level in plants and animals Suggested /ea#hi"g a"d 3ear"i"g -#ti$ities S + i l l s < o n t e n t = e g i s t e r Students: review prior +nowledge through brainstorming or concept map development about ionic" covalent and macromolecular compounds" e$amples and structure carry out a teacher-planned procedure to test the solubility of a variety of compounds including ionic" soluble molecular" insoluble molecular" covalent networ+s and large molecules 17 111 a from e$perimental results construct a table of solubility for a variety of compounds including ionic" soluble molecular" insoluble molecular" covalent networ+s and large molecules 4%
111 b use a suitable e$perimental method or prior +nowledge to identify which solutions from the group above contain ions 41
111 a with teacher guidance and class discussion develop a model portraying bonding that e$plains why some compounds dissolve while others do not 41 1C1 f identify the relationship between the solubility of substances in water and the polar nature of the water molecule 44 1C4 b using teacher-selected resources and notes" e$plain the changes that occur on a molecular level as a substance dissolves 4C
1C1 a use appropriate problem-solving strategies to develop" from prior +nowledge" appropriate resources and class brainstorming" ways to identify substances that form acids and al+alis when they dissolve in water 1C1 relate the ionisation of the above molecules and solids in water to the formation of acids and al+alis" thus formulating a cause and effect relationship 4B 1C4 d with teacher guidance and modelling if necessary" write word and formula e#uations and then ionic e#uations to summarise the processes that occur when ionisation occurs during dissolution 46 141 d 17 9ucat =9, Fol 1P 4%K 3oesten (D 2 @ood 3'K http,**wwwo+stateedu*Jgelder*bondpage6html 4% <D-=>( <hemical 9ondingK Fideo <hemical 9onding 41 9ucat =9, Fol 1P 4%K http,**wwwo+stateedu*Jgelder*bondpage6html 41 <D-=>( <hemical 9ondingK Fideo <hemical 9ondingK /t+ins p :1-:4K Thic+ett p 1%4-1%6" 1CB 44 3oesten (D" @ood 3'K )/T</P Chemistry 2 $nit Structure and Bonding Set & 4C <D-=>( <hemical 9ondingK Fideo <hemical 9ondingK Fis<hem video The Molecular !orld of "eactions in !aterK Fis<hem <D-=>( Su'stances and "eactions in !ater 4B Thic+ett p 4CB 46 /t+ins p:B-:: 116 Science Stage 6 Support Document Part 1 in class discussion review particle theory of matter and the idea that matter is composed of particles that are continuously moving and interacting 1C4 b distinguish between diffusion and osmosis by, carrying out a teacher-planned procedure to observe the diffusion of a substance through water 48 111 a using appropriate animated models or graphics to visualise the diffusion process at a particle level 114 b 1C1 f predicting the impact of a molecular sieve! on the movement of particles during diffusion 1C4 c using brainstorming" prior +nowledge and*or appropriate animation to visualise the cell membrane as a sieve" predict how this may affect the movement of materials in and out of the cell 4: 1C4 c predict and test" which of the chemicals investigated earlier is able to move in and out of living cells and use logical arguments or a planned procedure to support the predictions made 47 1C4 c 48 (udie e$ercise 114K http,**wwwfedcuh+eduh+*MJohnson*teaching*biologyGlesson*molecules*labChtml 4: ?otE 3<" Treichel P p117 47 (udie e$ercise 11C could be used here )9 use plant cells only eg rhubarb cells and e$clude use of blood and chee+ cells 118 Science Stage 6 Support Document Part 1 6.5.4 Syllabus 2'tra#t ($er$ie0 The concentration of salts in water will vary according to their solubility and precipitation will occur when the ions of an insoluble salt are in solution together! &t is possible to apply solubility rules to identify and predict precipitates and the yield of a precipitate (8 i"di#ati$e hours% Syllabus .e)ere"#e Students learn to: Students: recall #ualitative descriptions of reactants and products in precipitation reactions identify some combinations of solutions which will produce precipitates" using solubility data describe a model that traces the movement of ions when solution and precipitation occur identify the dynamic nature of ion movement in a saturated dissolution describe an e$ample of a reversible reaction" not involving a saturated solution" that eventually reaches e#uilibrium describe the molarity of a solution as the number of moles of solute per litre of water using c<n=# e$plain why different measurements of concentration are important recall the relationship between pollution and contamination by unwanted substances e$plain why the concentrations of mercury and other heavy metals are monitored in natural waterways solve problems and analyse information to write ionic e#uations to represent the dissolution and precipitation of ionic compounds in water present information in balanced chemical e#uations and identify the appropriate phase descriptors .HsI" HlI" HgI" and Ha#I . for all chemical species perform a first-hand investigation" using micro-techni#ues" to compare the solubility of appropriate salts in solution through precipitation reactions process information to carry out simple calculations to describe the concentration of given solutions" given masses of solute and volumes of solution perform a first-hand investigation to ma+e solutions to specified volume-to- volume and mass-to-volume specifications and dilute them to specified concentrations using cFOconstant gather and process information from first-hand investigations or secondary sources to calculate mass and concentration relationships in precipitation reactions as they are encountered gather and process information from first-hand investigations or secondary sources and use available evidence to discuss the importance of monitoring concentrations of heavy metals in industrial wastes or gather and process information from first-hand investigations or secondary sources and use available evidence to e$plain why care must be ta+en in choosing sites for disposal of to$ic wastes 11: Science Stage 6 Support Document Part 1 Preparatio" 1 Photocopy a class set of solubility tables for common ions 1 &dentify appropriate practical e$periences and order solutions re#uired Ensure that there is sufficient distilled water available for dilutions 4 9oo+ library" &nternet or other resources for research e$ercises on contamination and pollution C <ollect model +its" animation videos or boo+ computers to use <D-=>(s for visualisations and modelling e$ercises 117 Science Stage 6 Support Document Part 1 Suggested /ea#hi"g a"d 3ear"i"g -#ti$ities Students: S + i l l s < o n t e n t = e g i s t e r through brainstorming and class discussion" review and write a summary of their current +nowledge about solutions use a teacher-selected resource to visualise what is meant by the term concentration when referring to particles in a solution C% 1C1 f use teacher-selected resources to identify and e$plain why different situations call for different measurements of concentration C1 1C1 a through class discussion" research and teacher assistance if necessary" e$plain" using e$amples such as food labels and pharmaceutical products" why different measurements of concentration may be important C1 1C4 d with teacher input" discuss the use of molarity as a concentration descriptor C4
1C1 f describe the molarity of a solution as the number of moles of solute per litre of water use the formula c<n=# to calculate the molarity of given and re#uired solutions 11C b safely carry out a planned procedure" minimising haEards and resource wastage" to prepare solutions to specified volume-to-volume and mass-to- volume concentrations CC 111 a" b" d with teacher guidance" calculate the concentration of dilute solutions by recognising that when dilution occurs" the number of moles remains constant HcFOconstantI and the e#uation c 1 F 1 Oc 1 F 1 may be applied to dilutions 111 a with teacher input" predict situations that will re#uire the dilution of solution samples and orders of magnitude to be decided before analysis is carried out 111c / using teacher-supplied revision e$ercises" review #ualitative descriptions of reactants and products in precipitation reactions 1C4 b use teacher-supplied reference te$ts and notes to identify the appropriate phase descriptors and discuss the use of these in balanced chemical e#uations 114 a carry out a teacher-planned procedure to compare the solubility of a variety of salts using micro-techni#ues CB or to develop a solubility table 111 a 114 a 37-3 a C% Fis<hem <D-=>(K Fis<hem video The Molecular !orld of "eactions in !ater C1 http,**wwwoEemailcomau*Mtblac+*selGsummhtm as a case study or http,**wwwnwforg*nw+*greatla+es*pp*mercuryhtml C1 http,**wwwoEemailcomau*Mtblac+*selGsummhtm or http,**wwwnwforg*nw+*greatla+es*pp*mercuryhtml could be used a case study here as the concentrations of mercury are reportedK )/T</P Chemistry 2unit The Mole Set 2 C4 )/T</P Chemistry 2 $nit The Mole Set 2 CC Stralow p:B CB 5>S<hem p 64K Deretic et al p4:K Stralow p71"71K @il+inson et al p6B 14% Science Stage 6 Support Document Part 1 from observations and compare with established tables design and use a results table to record results so that comparison of solubilities is possible 11C c 141 a with teacher assistance if necessary and using a provided solubility table or set of solubility rules" determine the name of the precipitate formed in each case of precipitation" Justifying the identification made 1C1 a with teacher guidance if necessary" write ionic e#uations to represent the precipitation reactions" using the appropriate phase descriptors in the e#uations 141 a describe and select a strategy that could be used to identify the components of an un+nown solution C6 1C1 b design a procedure that allows valid and reliable data about the components of solution to be collected C8 111 c plan and carry out a procedure to apply solubility rules to solving a problem about un+nowns in solution C: 114 111 possible ope"5e"ded i"$estigatio" given the molarity of two solutions" predict the theoretical yield of solid from a precipitation reaction and compare it to the practical yield achieved during a first-hand investigation This would provide e$tra s+ills in manipulating e#uipment and materials and calculating while reinforcing the solubility rules and mole concept &t also allows further practice for the syllabus re#uirement, use data from appropriate precipitation reactions to calculate mass and concentration relationships alter"ati$ely use data from secondary sources about appropriate precipitation reactions" to calculate mass and concentration relationships r a n g e
o f
s / i l l s
% o u l d
' e
p r a c t i s e d
review the modelHsI of solution used earlier to describe the changes that occur when solutions mi$ and precipitation occurs C7 1C1 f review the particle theory of matter and identify the dynamic nature of particle movement in a mi$ture of a solid and its ions in solution 1C1 f relate the dynamic nature of precipitation and dissolution to a saturated solution and use the term e#uilibrium! to describe the condition when both are occurring at the same rate B%
1C4 b use teacher-selected resources to identify e$amples of reversible reactions and define what is meant by a reversible reaction 114 b propose and discuss reasons why e#uilibrium could be reached wherever a reversible reaction is involved 1C4 b use a range of resources to identify and describe an e$ample of a reversible reaction" not involving a saturated solution" that eventually reaches e#uilibrium B1 114 c during class discussion" review and define pollution in terms of contamination by unwanted substances 1Ca 4 b C6 Stralow p 71 C8 Stralow p 71 C: Stralow p 71 C7 ?otE 3<" Treichel P p 1:6K Fis<hem videoK Fis<hem <D-=>(K B% 3oesten (D" @ood 3' p 11: B1 @il+inson p 1%1-1%4" p 1%B-1%: 141 Science Stage 6 Support Document Part 1 using the range of s+ills involved in gathering information from first-hand or secondary information" identify the range and concentrations of heavy metals that can occur in industrial and to$ic wastes B1 114 a-d using the range of s+ills involved in gathering information from first-hand or secondary information" and the range of s+ills involved in processing information" identify e$amples and concentrations of heavy metals which can impact on natural environments and describe the effects of named e$amples on living things B4 114 a-d 11C d-f use the above information to propose e$planations for the monitoring of mercury and other heavy metal concentrations in natural waterways 1C4 b apply critical thin+ing about the above to discuss and e$plain the importance of either monitoring concentrations of heavy metals in industrial wastes >= carefully choosing sites for disposal of to$ic wastes HThe above four dot points could be incorporated into an open-ended investigation involving a media and library search (. the above four dot points could be incorporated into a formative or summative assessment tas+ . if students have had opportunities to practise the range of s+ills involved and have had prior diagnostic assessment of their s+illsI 1C4 c B1 http,**wwwoEemailcomau*Mtblac+*selGsummhtm, http,**wwwde#statemius*ogl*sagbay*sprtfishhtmK or http,**wwwnwforg*nw+*greatla+es*pp*mercuryhtml B4 http,**wwwinfohuntnswgovau*la+emac*environ*soe*soehtm 141 Science Stage 6 Support Document Part 1 6.5.&& Syllabus 2'tra#t ($er$ie0 @ater has a higher heat capacity than many other li#uids! This property of water has contributed to the relatively mild conditions e$perienced on Earth compared to other planets &t also e$plains the differences in climate between coastal and inland areas on large continents <hemically" this property is important because water is able to absorb or provide energy during chemical reactions (6 i"di#ati$e hours% Syllabus .e)ere"#e Students learn to: Students: e$plain what is meant by the specific heat of a substance compare the specific heat of water with a range of other solvents e$plain and use the e#uation 0Om<T e$plain how water!s ability to absorb heat is used to measure energy changes in chemical reactions describe dissolutions which release heat as e$othermic! and give e$amples describe dissolutions which absorb heat as endothermic! and give e$amples e$plain endothermic and e$othermic dissolutions in terms of bond brea+ing and bond ma+ing e$plain why water!s ability to absorb heat is important to a#uatic organisms and to life on earth generally e$plain what is meant by thermal pollution and discuss the implications for life if a body of water is affected by thermal pollution choose resources and perform a first- hand investigation to measure the change in temperature when substances such as ammonium chloride and sodium hydro$ide dissolve in water" and calculate the molar heat of solution process and present information from secondary sources to assess the limitations of calorimetry e$periments" and design modifications to e#uipment used process and present information from secondary sources to compare the specific heat of water with that of other solvents and discuss the importance of this property of water to a#uatic life Preparatio" 1 &dentify appropriate practical activities and order both e#uipment and consumables 1 &nvestigate the possibility of using sensors and data loggers Design a circuit of activities to incorporate the use of temperature sensors if resources are limited <onsider the repetition of the same e$periment using thermometers and temperature sensors to demonstrate differences in accuracy 4 Prepare*obtain references on thermal pollution C &f necessary" photocopy e$ercises to provide practice on the use of 0Om<T 144 Science Stage 6 Support Document Part 1 14C Science Stage 6 Support Document Part 1 Suggested /ea#hi"g a"d 3ear"i"g -#ti$ities Students: S + i l l s < o n t e n t = e g i s t e r review the discussions earlier in the module about the significance of the different states of water for the living and non-living worlds and prepare a summary of information available so far review the variations in temperature graphed earlier in the module and summarise the difference between land and water BC with teacher guidance if necessary" suggest*predict a reason for the smaller temperature range e$perienced in water and support this prediction with a plausible e$planation BB 1C1d / use teacher selected resources and notes to e$plain what is meant by the specific heat of a substance 114 access information from a range of resources to prepare a comparison of the specific heat of water with other substances of similar molecular siEe and*or weight and with a range of other solvents 114 141 use the above information to demonstrate a cause and effect relationship between water!s high specific heat and the difference in temperature variations between a#uatic and terrestrial environments 1C g / Hif still necessaryI in groups or through class discussion" propose an e$planation for the importance of water!s high specific heat to a#uatic organisms and to life on earth in general 1C4 b with teacher assistance or input" e$plain how water!s ability to absorb heat is used to measure energy select appropriate sensors and data-capture technology and set up the most appropriate combination of e#uipment to measure temperature changes in water 114 a" c perform first-hand teacher-organised investigations that measure the change in temperature during dissolutions B6 111 a review" through appropriate animations or visualisations" the processes that occur when an ionic substance dissolves in water B8 1C1 f identify that during the processes that occur when an ionic substance dissolves, the brea+ing of ionic bonds as the substance dissolves absorbs energy the ma+ing of bonds between water molecules and the separated ions during hydration releases energy the net energy product from these processes can be measured BC http,**globefslnoaagov*fsl*welcomehtml has prepared graphs that could be used at this point BB 3oesten (D" @ood 3' p171K B6 5>S<hem p C1KStralow pB1KDeretic et al pCCK @il+inson p:8 B8 Fis <hem video . The Molecular !orld of "eactions in !ater> Fis <hem <D=>( Su'stances and "eactions in !ater 14B Science Stage 6 Support Document Part 1 as temperature increase or decrease in the reaction vessel use the terms endothermic! and e$othermic! correctly to describe the above reactions B:
114 use teacher-selected resources and notes to e$plain and use the e#uation 0Om<T B7 11C b evaluate the validity of collected data on the heat of solutions compared with standard values 11C d select and use appropriate formats such as comparison tables to present the differences between practical and theoretical results for the above e$periments 141 c generate plausible e$planations for the differences in obtained and theoretical results" thus identifying the limitations of calorimetry e$periments 1C1 d identify and e$plain the nature of the problem with calorimetry e$periments 1C1 a design possible solutions or modifications which could reduce the limitations of calorimetry e$periments" with teacher guidance if necessary 1C4 a / participate in a class discussion to predict scenarios in which the temperature of natural bodies of water may rise 1C4 b discuss the possible outcome of such temperature changes on the living thing in these environments 6% 1C4 use teacher-identified resources to e$plain what is meant by thermal pollution 61 and identify situations in which thermal pollution may occur 114 d discuss the reasons why environmental protection agencies put such importance on preventing thermal pollution of water bodies B: Thic+ett p1:7 B7 Thic+ett p 141-144" Stralow p B4-BC Hfurther practical e$erciseI 6% /t+ins p CC6-CC8 61 http,**wwwrpiedu*dept*env-energy-eng*publicGhtml*courses*9ungay*(&S<*(anagementhtml 146 Science Stage 6 Support Document Part 1 6.5.&* 2$aluatio" Sample 6uestio"s that #ould be i"#luded i" a" e$aluatio" sheet to be #ompleted by tea#hers i"$ol$ed i" the deli$ery o) this u"it "esources identified 1 @hat resources would you recommend using againL 1 @hat resources should definitely be deleted from the listL 4 /ny new and better resources identifiedL C /re there areas of content where further or different resources would be useful or are neededL *irst5hand experiences 1 (ention any particular difficulties or problems with e#uipment or other resources 1 /ny better practical e$periences identifiedL 4 /ny better ideas for illustrating the s+ills re#uired by the syllabusL S/ills de#elopment 1 Did any s+ills need more attention than others in this moduleL 1 Does the program allow practice of the s+ills that students need most practice inL 4 @as the selection of content from each maJor s+ill area appropriate for the students involvedL C @as the selection of content from each maJor s+ill area appropriate for the dot point addressedL Teaching and learning strategies 1 @ere the teaching and learning strategies used appropriate for the cohort involvedL 1 @ere the strategies suggested effective in achieving conceptual development for all studentsL 4 @ere the strategies suggested efficient in achieving conceptual development for all studentsL C @hat was the student response to the unitL B @hat problems arose for studentsL 6 Did this teaching program provide sufficient variation in learning opportunities for the range of different types of learners in the groupL 8 Did this unit provide choice for students with different interests*abilities within the constraints of syllabus re#uirementsL 2ssessment tas/s 1 @hich outcomes need further assessmentL )ndicati#e timing 1 &s the indicative time for each section appropriateL &f not" which areas need more*less timeL 148 Science Stage 6 Support Document Part 1 2$aluatio" 4ate Commenced:@@@@@@@@@@@@@@@@@@ 4ate Completed:@@@@@@@@@@@@@@@@@@@@ 0ow well did the program address the development of s+ills identifiedL @hich activities wor+ed wellL @hich activities need to be changedL Suggestions for additional resources @hich outcomes did students display to a high standard during this moduleL @hich outcomes need additional attention following the completion of this unitL >ther <omments, 14: Science Stage 6 Support Document Part 1 147