High quality cements with over 50% fly-ash or quartz sand
Ladies & Gentlemen,
I thank Intercem for inviting me to speak here today. My attendance here will be divided into two presentations. In this first presentation I will address the issue of emissions from cement production, the challenge faced in reducing these emissions and how EMC proposes to address these challenges. In the second presentation, later today, I will share with the audience the challenges that are to be confronted in bringing new technologies to the markets and the progress that EMC has made and continues to make to overcome these.
Cement Production and CO2 Emissions
There are varying reports on the CO2 emissions from Portland cement production. The industry seems to have settled on a figure of around 5% of global emissions.
It is the view of EMC Cement that this is a far too conservative figure and that the figure is closer to 10%. To the extent that this figure is not already reached, with Chinas expected growth to 1 billion tons of cement production within a few years and the reduction of emissions from other sources, this figure will be reached very shortly. Indeed, in all likelihood it will be surpassed.
Our estimates are based on the following calculation:
Global cement production at present is about 1.9 mill tons and with estimated continued expansion of Chinas cement production it will exceed 2 billion tons in the next few years.
In the most modern cement plants about 970kg of CO2 is emitted for each ton of clinker produced.
With Portland cement consisting of about 95/96% ground Portland clinker, clinker emissions contribution to Portland cement emissions is about 926.4 kg per ton Portland cement produced.
In addition comes the energy consumed in the clinker grinding process which represent about 12% of total emissions placing total emissions at 1.0527 tons of CO2 for each ton of Portland cement produced.
On the basis of global production of 1.9 billion tons, emissions are then 2 billion tons.
However, with 70% of the cement produced in China coming from higher polluting vertical kilns and still significant existent of other old technology in other parts of the world, it is safe to estimate that there is at least another 100-200 million tons of emissions that can be referred back to cement production.
All in all this puts total emissions from cement production at about 2-2.2 billion tons or around 9% of global emissions.
And, this does not include the emissions resulting from quarrying activities and the transport of limestone to the cement plants.
Some may wish to take issue with the basis for this calculation, but if they are not 100% accurate, they are certainly indicative of the emissions as they presently are or shortly will be.
The Challenge of Reducing CO2 Emissions in Cement Production
According to data issued by Cembureau, about 54% of the CO2 emissions in cement production comes from the natural release of CO2 from the burning of the limestone in the kiln. Another 34% comes from energy consumed in the kiln and the final 12% comes from grinding the clinker into cement.
According to data issued by the Portland cement industry, there is very little scope for reducing energy consumption. Accordingly, it is reasonable to assert that the only way to reduce emissions from cement production in a meaningful way is to reduce the production of clinker and thus the production of Portland cement.
Obviously, one way to achieve this reduction is to find ways to produce cement that offers increased performance thus requiring reduced use of cement. A lot of research has gone in this direction, but apart from some niche applications, it has not met with success. The problems have ranged from unwillingness of the market to accept new materials to the inability to develop products that can compete with Portland cement on the important combination of performance and price.
Well Known Materials, Competitive Performance & Cost Critical Elements to Successfully Replacing Portland Clinker
As previously mentioned, many cement materials have been announced as replacement for Portland cement, but without exception they have always failed to meet all three of the critical requirements of (i) using well known raw materials the interaction of which over the long run is already well known, (ii) competitive performance with Portland cement and (iii) Competitive cost.
We shall today talk about a technology that meets all of these criteria.
INTRODUCING EMC
With the foregoing background, I am pleased to introduce the EMC method for the production cement and pozzolans.
The development of EMC technology started in 1992, when Dr Vladimir Ronin a guest researcher at Lule University of Technology, Sweden initiated a scientific project dealing with intergrinding in vibrating mills Portland cement with different supplementary materials. The first EMC patent was filed in 1993. Between 1997 and 2002 two additional patents were granted and another two patents are pending with respect to EMC cement and EMC-CemPozz.
EMC cements and pozzolans are produced through a patented process of high activation grinding of Portland cement together with pozzolans or fine quartz sand. In the process, the materials are exposed to high energy impacts that create submicro cracks in the particle surfaces, deform the particles, activate the surfaces, expand particle surface and, in the process, increase the reactivity of the materials.
It is important to note that while the materials are exposed to high energy impacts, energy consumption is low and the over all production cost highly competitive. Thus EMC products can be marketed at prices that are very competitive with Portland cement as well as today's blended materials while still leaving sufficient economic margins.
EMC today focuses on the production and sales of three principal products;
(i) Cement with about 70% fly ash content, a product that we market as EMC70f,
(ii) cement with about 50% fine quartz sand content, a product we market as EMC50q, and
(iii) a pozzolan consisting of 90-95% fly ash and 5-10% Portland cement and/or cement kiln dust, a product we market as EMC CemPozz.
It is also possible to make EMC cements based on Ground Granulated Blast Furnace Slag. This possibility will be developed further in the future.
As mentioned EMC has a significant experience in the industrial production. A pilot EMC plant has been in operation since 1994 and the total amount of EMC production to date exceeds 3500 tonnes.
A significant number of reference construction projects have taken place, including cement for two bridges in the far north of Sweden (projects with Swedish State Road Construction Commission) with very severe climate conditions with summer temperature up to +30 and winter temperature as low as -30 degrees C.
EMC Patents today cover over 70% of the global cement market, including China which by itself represents 40% of the global cement market.
The licensing rights to the EMC technology are today held by EMC Cement BV of the Netherlands.
The EMC activities are today divided into two principle activities (i) Joint ventures and licensing of the technology through EMC Cement BV and (ii) Research, Development and Testing, conducted through EMC Development AB and EMC Production AB, both of which are Swedish companies.
The products and technology presently being commercialised are the result of almost 13 years of research and testing. During this period, a number of pilot projects have been concluded, from heavy industrial floors to bridge construction for the Swedish Road Building Administration and extensive testing by independent experts from Europe and the USA, all of which confirm that EMC products perform better than existing cements.
At present a plant to produce EMC fly ash is under construction in the state of Texas in USA with production start-up in June of 2004. The plant is located in conjunction with a thermal power plant that produces about one million tons of fly ash and 500.000 tons of bottom ash per year.
Additional projects are under negotiation.
EMC VIZ PORTLAND CEMENT - A PERFORMANCE COMPARISON
Cement specifications vary from region to region and country to country. For example, until recently virtually only Portland cement were used in Norway and Sweden, while in Italy pozzolanic materials are used extensively for some 2000 years.
We shall here share with you a selection of the huge volumes of data that has been generated on EMC cement over the past 10 years, including by leading cement producers, concrete producers, and leading independent experts.
EMC CEMENT WITH 50-70% FLY ASH CONTENT
It is well known that from a durability point of view materials such as coal combustion fly ash provide far superior performance to that of Portland cement and that the only real limitation to the increased use of fly ash are (i) setting time, (ii) workability, (iii) finishability and (iv) early age strength development.
Compressive strength development of EN mortar with EMC50fa and EMC70fa 0 10 20 30 40 50 60 1 3 7 28 Curing time, days C o m p r e s s i v e
s t r e n g t h ,
M P a PC PC+20%FA EMC50fa EMC70fa
Above figure represents the strength development of EN mortars produced with EMC cements containing 50% and 70% of fly ash Class F in comparison with pure Portland cement and Portland cement with 20% FA. As can be seen, EMC50fa cement has strength development in line with pure OPC and EMC70fa performs in line with OPC with 20% FA.
CONCRETE WITH 50-60% CEMPOZZ CONTENT
Compressive Strength Development of EN mortar 0 10 20 30 40 50 60 1 3 7 28 Curing time, days C o p m r e s s i v e
s t r e n g t h ,
M P a PC PC+20%FA PC+50%E-CemPozz
Above information demonstrates strength development of EN mortars containing EMC-high reactive pozzolan: EMC-CemPozz in comparison with pure OPC and OPC containing 20% of Fly ash (OPC replacement). This product can be simply added to the concrete mixer in the same way as the concrete producer is doing today with fly ash in traditional recipes. The test results show that replacement OPC by EMC- CemPozz as high as 50% is equivalent to traditional 20% fly ash replacement level.
In USA, where an EMC pilot unit is in operation it has been confirmed by extensive industrial tests, that EMC-CemPozz performs even more effective when it is used in concrete. Below figure represents the strength development of housing concrete with ca 271 kg of binder content per m3 with replacement of OPC with EMC-CemPozz up to 60%, which performs in line with concrete containing only 20% of fly ash.
Strength Development of the Concrete Produced with EMC - CemPozz (binder content 271kg/m3, w/B = 0.60) 0 5 10 15 20 25 30 7 28 Curing time, days C o m p r e s s i v e
s t r e n g t h ,
M P a OPC+20%FA OPC+50%EMC-CemPozz_ OPC+60%EMC-CemPozz
As the data that we have shown demonstrate, EMC has resolved the strength development challenges and we are pleased to confirm that we have also resolved all of the other four critical criteria mentioned above.
EMC CEMENT WITH 50% FINE QUARTZ SAND CONTENT
The data on EMC cements, containing 50% of fine quartz sand content clearly demonstrate that concretes produced with these cements perform in line with or better than OPC based concretes. This applies to strength development and other properties, including setting time, workability, gas and liquid permeability, frost resistance, etc.
SUMMARY OF THE TEST RESULTS FOR EMC- 50q and EMC-20q CONCRETES (w/B ratios 0.45 and 0.60) (Test program performed by SINTEF, Norway)
Parameter Standardised method of testing k-value of quartz filler in EMC-blends Properties of fresh concrete NS 3662 (ISO 4109), NS 3664 (prEN 1015-13) 1) 28 days compressive strength ISO 4012 2) Capillary suction and porosity SINTEF-procedure, KS70 110 > 1.0 Carbonation Accelerated SINTEF Carbonation Test 0.5-0.8 (EMC-20), 0.5-0.6 (EMC-50) 3) Water vapour diffusion Nordtest Build 443 > 1.0 Resistance to water penetration ISO/DIS 7031 > 1.0 Chloride permeability Nordtest Build 443, ASTM C 1202 and Nordtest Build 355 > 1.0 Frost resistance Nordtest Build 376 4)
1) The tests showed that the concrete production properties of EMC cements did not differ significantly from OPC reference mixes.
2) The tests showed that EMC-20q performs better than OPC and EMC-50q performs in line with OPC.
3) Accelerated Carbonation Test showed that EMC cements perform in line with traditionally blended cements, which demonstrated excellent resistance to carbonation after decades of exploitation in real life conditions.
4) The tests showed that frost resistance may be achieved with proper air entrainment, in line with normal procedures for OPC-concrete.
Recent tests show that the customer can also introduce 20-30% fly ash in the concrete produced with EMC50q in the same manner as presently done with ordinary Portland cement and with similar performance results.
For cement experts this will not be a surprise.
WHY FINE QUARTZ SAND CAN REPLACE PORTLAND CEMENT
While the use of pozzolans dates back some 2000 years before the invention of Portland cement, the use of fine quartz sand has been first introduced by EMC.
How is the use of fine quartz sand in cement possible?
1. Typically, only about 50% of the Portland cement hydrates in the concreting process because that is the extent of the water's penetration into the cement particles. Through the EMC activation process, the hydration level is significantly improved with the result that more of the performance potential of the Portland cement is utilized.
2. Fine quartz sand consists of up to about 90% of silicon dioxide in a natural form. By comparison, silica fume consists of about 98% silicon dioxide. The EMC process also serves to activate the quartz sand particles. Tests done by SP Swedish National Testing and Research Institute show that fine quartz sand put through the EMC process attains a pozzolanic index above 25 (as required for CEM IV ). Obviously the index will depend on the chemical composition of the material. However, because of the effects of the EMC activation process, we can achieve the required performance with significantly lower pozzolanic indexes.
3. In the EMC grinding process, the fine quartz sand acts as a grinding media to further enhance performance.
4. The resulting size distribution and composition of the EMC provides for a very dense concrete, yet with excellent concreting characteristics.
It is important to note that through the EMC process, the sand and the resulting cement are both amorphous. The process is fully enclosed and automated and excludes any contacts with operating personal. This combined with the amorphization that takes place in the process means that there are no silicosis issues in the manufacturing process and in the final product.
EARLY AGE PERFORMANCE - THE CHALLENGE OF POZZOLANS
As we have mentioned previously, traditionally, the only disadvantage of high volume pozzolans such as fly ash and blast furnace slag compared to Portland cement are (i) workability, (ii) setting time, (iii) finishability and (iv) compressive strength development up to 28 days.
In all other aspects, notably the all important area of durability, these pozzolans outperform Portland cement.
This is a very important issue because it sets out clearly the challenge for increased use of pozzolans as one of proving short term performance. In other words, we will know in 28 days the performance of innovative cements that are based on the increased use of well known pozzolans.
As I hope to have shown in this presentation with EMC products we have resolved these challenges. Time is too short in this presentation to provide an overview of all aspects of the EMC Technolog but for those that are interested in further information, EMC has prepared a complete book with technical, economical and commercial information on its technology.
COST AND ENVIRONMENTAL CONSIDERATIONS
We stress that these products are all the result of a cost efficient and environmentally friendly grinding process, not expensive and harmful processes or admixtures.
For example:
The grinding process does not emit pollutants into the air or into water.
There is essentially no waste material.
The grinding takes place in an enclosed process with the required dust protection features.
Energy consumption ranges from 30-50 Kwh per ton product.
An EMC plant producing some 150,000 tons per annum can be operated by about 12 people in total.
For comparison, the grinding of EMC products costs less and with less environmental impact than that of grinding klinker.
It is also important to note that the EMC production process is not based on superfine grinding; indeed, our cements have only about 25% increase in fineness. Moreover, workability and finishability are improved.
REPLACING PORTLAND CEMENT WITH POZZOLANS AND FINE QUARTZ SAND - THE ONLY WAY IN WHICH MEANINGFUL REDUCTION IN CO2 EMISSIONS CAN BE ACHIEVED.
In March 2002, the World Business Council for Sustainable Development issued a report entitled Towards a Sustainable Cement Industry. The Climate Change Section of the WBCSD report identifies on page (vi) the principal areas that the cement industry must follow if it wants to achieve sustainability. Those areas are:
1. Expanding sales of cement with lower clinker content (e.g. composite cement with fly ash or blast furnace slag).
2. Increasing the use of alternative fuels (bio-based, low carbon, or waste fuels that provide a net carbon dioxide emissions reduction).
3. Initiating energy efficiency enhancements (improving equipment and phasing out inefficient plants.
4. Committing itself to innovation.
The report goes on to state that "without a commitment to long-term innovation, the industry will likely find itself facing growing emission liabilities as individual nations commit themselves to ever-tighter CO2 constraints in an attempt to stabilize atmospheric concentrations of greenhouse gases".
EMC agrees with this assessment and we have been working for the past 12 years to offer a technology that will achieve this objective. EMC understands the reluctance of the cement industry to adopt a technology that strongly reduces the need for clinker production. However, EMC would like to point out that when the cement industry adopts the technology it still produces a cement on which it can make a profit. When the cement does not adopt the technology, as our experience in the USA shows, others use the technology, producing a cement replacement material, that has the same reducing effect on clinker production and does nothing to enhance the profitability of the cement industry.