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AITS-FT-II-(Paper-2)PCM(S)-JEE(Advanced)/13

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1




ANSWERS, HINTS & SOLUTIONS
FULL TEST II
(Paper 2)



ANSWERS KEY
PHYSICS CHEMISTRY MATHEMATICS
Q. No. ANSWER ANSWER ANSWER
1.
C A C
2.
C D C
3.
B A C
4.
B B D
5.
B B B
6.
D B B
7.
A C A
8.
C A C
9.
B A C
10.
A D B
11.
B C D
12.
C A B
1.
(A) (r)
(B) (p)
(C) (q), (s)
(D) (q), (s)
(A) (p, q, t)
(B) (p, r, s)
(C) (p, q, t)
(D) (q, t)
(A) (s)
(B) (t)
(C) (p)
(D) (q)
2.
(A) (s)
(B) (q)
(C) (r)
(D) (q)
(A) (q, r)
(B) (q, r)
(C) (r, s)
(D) (p, t)
(A) (r)
(B) (r)
(C) (p)
(D) (r)
1.
5 3 3
2.
4 7 5
3.
2 3 9
4.
4 5 0
5.
4 4 3

A
L
L

I
N
D
I
A

T
E
S
T

S
E
R
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S

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AITS-FT-II-(Paper-2)PCM(S)-JEE(Advanced)/13

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
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2
P Ph hy ys si ic cs s PART I


SECTION A

3.
t
2CR
q 2CV 1 e

| |
| =
|
\ .
;
t
2
2CR
b
W 2CV 1 e

| |
| =
|
\ .


4. LC = 4/200 = 0.02

5. Gravitational potential inside a shell = constant


6. In nuclear, nuclear force play major role. They are charge independent forces.

SECTION C

1. Current is 2 = 0.1 A
current in circuit = 0.2 A
equivalent resistance about AB = 5
e = I R = 1 volts
and also
e = B V

e 1
V 5m/ s
B 2 0.1
= = =

.

2. Force on the rod
F F
m
= ma

B
F (B V E) ma
r
=



2 2
B E B V mdV
F
r r dt
+ =


solving

2 2
0 0
B
F mV sin( t) V cos t
r
= +
B E
r



Power expended by force is

2 2
2 2 2
0 0 0
B B E
FV mV sin( t)cos( t) V cos t V cos t
r r
= +


Its average over the cycle is

2 2 2
0
B V
2r

.

3. Let A
1
and A
2
be the crosssectional area of the pipe at points P and Q respectively.
Let v
1
and v
2
be the velocities of oil at the points P and Q respectively.
By conservation of mass,
Q = A
1
v
1
= A
2
v
2


1
2 1 1
2
A
v (v ) 4v
A
| |
= =
|
\ .

Applying Bernoulliss equation between points P and Q, we have
AITS-FT-II-(Paper-2)PCM(S)-JEE(Advanced)/13

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
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3

2 2
1 1 2 2
1 1
P v P v
2 2
+ = +

2 2
2 1 1 2
1
P P (v v )
2
= +

3
1
1
P 0.9[16 256] 10
2
= +

3 3
280 10 ( 108) 10 = +
P
2
= 172 10
3
Nm
2

P
2
= 172 (KN m
2
).

4. ( ) ( )
0 0
net 0 0 0 0
P v
W 2P v P v
4

=
( )
0 0 0 0
net 0 0
P v P v
W P v 4
4 4

= = ; Put = 3.14
( ) ( )
net 0 0 0 0
0.86
W P v 0.22 P v
4
= =
Now,

0 0
1
0 0
2
0 0
3
P v
T
R
4P v
T
R
2P v
T
R

=
`

)
Thus,
| |
| |
| |
1 2 2 1
2 3 3 2
3 1 1 3
3R
U 1 T T
2
3R
U 1 T T
2
3R
U 1 T T
2

=
=
=

( )( ) ( ) ( ) ( ) ( )
1 2 0 0 0 0 0 0
Q 4.5 P v 1.22 P v 5.72 P v

= + =
( )
2 3 0 0 0 0
Q 3P v 0 3 P v

= + =
( ) ( ) ( )
3 1 0 0 0 0 0 0
Q 1.5 P v P v 2.5 P v

= =
Thus efficiency
net
W
veheat
=
+


( )
( ) ( )
0 0
0 0
0.22 P v
0.04
5.72 P v
= =
Thus efficiency is 4%

5. The total momentum of the system in the horizontal
direction is conserved. We draw the F.B.D., assuming the
displacement of the block to be x
1
and x
2
in opposite
directions, and the total extension x is given by,
x = x
1
+ x
2

m
1
kx
x
1
m
2
kx
x
2
and m
1
x
1
= m
2
x
2


2
1
1 1 2
2
d x
m k(x x )
dt
= +
and
2
2
2 1 2
2
d x
m k(x x )
dt
= +
after suitably manipulating the equations,
we get,
AITS-FT-II-(Paper-2)PCM(S)-JEE(Advanced)/13

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4

2
2 1 2
2
1 2
d x k(m m )
.x
mm
dt
+
=
i.e. the frequency
1 2
1 2
k(m m ) 1
2 m m
+
=



1 300(2 3)
2 2 3
+
=


2.5Hz .
number of complete oscillations in 1 minute
60
24
2.5
= = .


AITS-FT-II-(Paper-2)PCM(S)-JEE(Advanced)/13

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C Ch he em mi is st tr ry y PART II


SECTION A

1. Gem-dihalides on substitution by
OH
produces carbonyl compound, which will reacts with
2,4-DNP but 1,2-dichloroethane will give vic-diol.

2.
2 2 3
4
MnO Fe 8H Mn Fe
0.1M
0.01M 0.09 M
+ + +
+ + +


2
4
2
2
0 0
MnO H
R.P.
R.P.
H
Mn
E E
+
+
| | | |
|
|
\ .
\ .
>

So permanganate electrode behave as cathode.
E
cell
= 1.51 0 = 1.51.
Using Nernsts equation :- (n = 5)

4
2
8
4
MnO 2
Mn
MnO H
0.059
E 1.51 log
5 Mn

+
+
+
( (

= +
(


= 1.51 + 0.11 = 1.4 V

3. Amine inversion will change the configuration of N only and not that of carbon.

5. Compound (A) will first undergo Cannizzaro reaction and the product B then will undergo esterification.

6. ( )
3 4
600 0.2
500 0.3
0 Moles
760 RT
760 RT
NH HCl NH Cl s

+ at room temperature.

150 120
760RT 760RT


30 120
0
760RT 760RT

Now total moles =
30 100 1
760RT 760RT

+
Total P =
130 RT
760RT 1.5

(Total volume = 1. 5 Litre)


P in torr =
130
86.66 torr
1.5
=

SECTION C

5. (S)-2,3-dimethylpentane, (R)-2,3-dimethylpentane, (S)-3-methylhexane and (R)-3-methylhexane.


AITS-FT-II-(Paper-2)PCM(S)-JEE(Advanced)/13

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M Ma at th he em ma at ti ic cs s PART III

SECTION A

1.
3
1 1 1 1
f(x) x x
2 4 2 2
| | | |
= + +
| |
\ . \ .


3 / 4
1/ 4
I g(x) dx =

let
1
x t
2
= +
1/ 4
1/ 4
1
I g t dt
2

| |
= +
|
\ .



3
1 1 1
f t t t
2 4 2
| |
+ = + +
|
\ .

3
3 3
1 1 1 1 1
f f t t t t t
2 4 4 4 2
| | | | | | | |
+ = + + + +
| | | |
\ . \ . \ . \ .


1 1
g t p(t)
2 2
| |
+ = +
|
\ .
where p(t) + p(t) = 0

1/ 4
1/ 4
1 1
I dt
2 4

= =



2. Required area is

( )
2
0 1
2 exlnx 1 1 (x 1) dx

(
( +
(



1 1
1

3.
( )
n r 1 n
n r t n r r
r t r
n n
n n
r 1 t o r 1
1 1
lim C C 3 lim C 4 3
5 5


= = =
| |
= |
|
\ .


=
( )
n n
n r n r n n
r r
n n
n n
r 1 r 1
1 1
lim C 4 C 3 lim 5 4 1
5 5

= =
| |
= = |
|
\ .

.

4. In triangle OA
1
A
2


2
2
2R 4 1
cos
4
2R 2
| |
= =
|
\ .


2
R 4 2 2 = +
Also

( ) ( )
2 2
r 1 r 1 4 2 2 + = +
4r 4 2 2 = +

1
r 1
2
| |
= +
|
\ .

A
8
A
3
R R
/4
O
A
1
A
2
Vertex of octagen

O
1

r
(r1)
O
1
R
1
1
A
2

5.
3
f 2
2
| |
=
|
\ .

AITS-FT-II-(Paper-2)PCM(S)-JEE(Advanced)/13

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( )
3
f ' g' 2 1
2
| |
=
|
\ .


( ) ( )
24 4
f ' x 25(2) 2x 3 sinx
3
= +

3 7
f '
2 3
| |
=
|
\ .

( )
3
g' 2
7
=

6. Let the age of friends be a, ar, ar
2
, r > 1 and money distributed is x, xr, xr
2
respectively.
(1 + r + r
2
)x = (a(1 + r + r
2
) + a)t
Also after 3 years ar
2
+ 3 = 2(a + 3)
a(r
2
2) = 3
x + 105 = (a + 3)t and xr + 15 = (ar + 3)t (given)
(1 + r)x + 120 = (a(1 + r) + 6)t 2(a + 3)t = r
2
x 120 = 2x + 210
(r
2
2)x = 330
Using (r
2
2)x = 330, a(r
2
2) = 3 x = 110a
110a + 105 = (a + 3)t 5(22a + 21) = (a + 3)t
and 110ar + 15 = (ar + 3)t 5(22ar + 3) = (ar + 3)t

22a 21 a 3
22ar 3 ar 3
+ +
=
+ +
5ar = 7a + 6
Where 5ar = 7a + 2(a(r
2
2)) {Using a(r
2
2) = 3}
2r
2
5r + 3 = 0
3
r
2
= . Hence a = 12 years

7. Given c
n
= a
1
+ a
2
+ a
3
+ .. + a
n

where a
1
, a
2
, .., a
n
are in A.P. with d = 2
and d
n
= b
1
+ b
2
+ b
3
+ + b
n

where b
1
, b
2
, b
3
, .., b
n
are in A.P. with d = 2
Also (a
n
, c
n
) lies on y = px
2
+ qx + r
Now c
n
=
2
n n
pa qa r + + .. (1)
c
n

1
=
2
n 1 n 1
pa qa r

+ + .. (2)
From (1) and (2), we get
c
n
c
n 1
= ( ) ( )
2 2
n n 1 n n 1
p a a q a a

+
( )( ) ( )
n n n 1 n n 1 n n 1
a p a a a a q a a

= + +
( ) ( )
n n n 1 n n 1
a a a p a a q

( = + +

.. (3)
( )
n n 1
a a d

=

10. y = t(1 3t
2
) t =
y
x
at A, t = 1
Slope of tangent at A, m =
2
1 9t 4
6t 3

.
Equation of tangent at A 3y + 4x + 2 = 0
Since tangent passes through the point B(t
1
) hence
3(t
1
3t
1
3
) + 4(1 3t
1
2
) + 2 = 0
(t
1
+ 1)
2
(3t
1
2) = 0 t
1
=
2
3

B
1 2
,
3 9
| |

|
\ .
.

AITS-FT-II-(Paper-2)PCM(S)-JEE(Advanced)/13

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11. Slope of tangents at x = 0 and m
1
=
1
3
and m
2
=
1
3

tan =
3

.

SECTION B

2. (A) We have
1
1
f(x)
lncos x

=
For domain of f(x),
( )
1
ln cos x 0

>
1
cos x 1

> and
1
cos x


cos x cos 1 1 x < cos 1
Hence number of integers in the domain of f(x) are 2 i.e., 1 and 0
(B) Vector normal to the plane is

n i 3j 2k = +

and vector along the line is



V 2i j 3k = +


Now
x v 2 3 6 7
sin
x v 14
14 14

= = =


Hence cosec = 2
(C) We have
( ) ( )
4
2 2
5
J 3 x tan 3 x dx

. Put (x + 5) = t, we get

( ) ( ) ( ) ( )
1
2 2
0
J 3 t 5 tan 3 t 5 dt =

=
( ) ( )
1
2 2
0
22 10t t tan 22 10t t dt + +


Now
( ) ( )
1
2 2
2
K 6 6x x tan 6x x 6 dx

= +

. Put (x + 2) = z, we get

( ) ( ) ( ) ( ) ( ) ( )
1
2 2
0
K 6 6 z 2 z 2 tan 6 z 2 z 2 6 dz = +



( ) ( )
1
2 2
0
22 10z z tan 22 10z z dz + +


Hence (J + K) = 0

SECTION C

1.
1
A , 4, 0
3
| |

|
\ .
,
7
B 0, , 1
2
| |

|
\ .
and
7
C , 0, 8
3
| |
|
\ .
.
Hence
56
V
18
=

2.
( )
10
r 10 10
r r
r 1
1 3 C r C

=
+ +

= 4
10
+ 10 2
9

= 1 and = 5
k > 4

3.
( ) ( )
6 n 6
n 1/ 3 1/ 3
6
x C 3 4


=

( ) ( )
x 6 6
n 1/ 3 1/ 3
n 6
y C 3 4

= and
x 1
y 12
=
( ) ( )
n 12/ 3 1
12 12

= n = 9
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4. z
2
+ z
3
= 0

5. Let
n
2n+1
r
r 0
y C
=
=

=
2n+1
2n+1
r
r n 1
C
= +



2n 1
2y 2
+
=
2n
y 2 =
n = 3

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