Fulltest II Main Paper Solution Sol Aits 2013 FT II Jeem

AITS-FT-II-PCM(S)-JEE(Main)/13
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1

ANSWERS, HINTS & SOLUTIONS
FULL TEST II
(Mains)

Q. No. PHYSICS CHEMISTRY MATHEMATICS
1.
D B D
2.
A B B
3.
A B C
4.
D C B
5.
B B A
6.
C A B
7.
A A C
8.
B C C
9.
B A B
10.
A B A
11.
C
B
D
12.
C
B
D
13.
B
A
A
14.
B
B
D
15.
C
D
D
16.
A
B
B
17.
B
B
D
18.
B
C
B
19.
B
C
C
20.
A
B
A
21.
B
A
A
22.
B
D
D
23.
C A C
24.
C B D
25.
B B A
26.
C B D
27.
A B C
28.
C D B
29.
B B C
30.
B A D

A
L
L

I
N
D
I
A

T
E
S
T

S
E
R
I
E
S

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AITS-FT-I-PCM(S)-JEE(Main)/13

2
P Ph hy ys si ic cs s PART I

1. L = 1/c (for resonance)

2
= 1/LC . . . (i)
for case (ii)
(2)
2
= 1/LC
1
. . . (ii)
(ii) divide (i) 4 = C/C
1

C
1
= C/4.
The capacitance is to be reduced by 75%.

2. The velocity of P along AP equals that of A along AP.

3.
eq
1 1 1 1 1 2
R R 3R 3R R 3R
= + + = +

3 2 5
3R 3R
+
= =

eq
3
R R
5
=

4. flux =
0
1 q
2 24
| |
|
\ .

5. Charge on the outside surface of conducting sphere is zero so field or potential at any point
outside the sphere is zero.

6. At time t = 0, the inductor will show infinite resistance, so the current will be zero. Hence emf
across L is with A at higher potential.

7. Force by liquid = Mg
(Av)v = Mg
But Av = 1 10
3
m
3
/s and

2
v (20) 2 10 5 10 m/ s = =

M = 1 kg

9. The motion of the particle within the tunnel is simple harmonic.

10. Total mechanical energy = gravitational P.E. + K.E., total mechanical energy is conserved.

11.
R
dQ n dT
1
| |
=
|

\ .
,
nR
dU dT
1
=

dW = nRdT
dQ : dW : dU
: 1 : 1

12. Using equation of Trajectory, we get
u = 152 m/s

14. From the free body diagram, we get,
N = mg cos + ma
0
cos
Mg sin + ma
0
sin = ma

3
a = (a
0
+ g)sin

2
0
1
L (a g)sin t
2
= +

0
2L
t
(a g)sin
=
+

15. F cos = N ..(A)
N = F sin + mg ..(B)
By (A) and (B)
F cos = (Fsin + mg)
F cos F sin = mg
F(cos sin ) = mg
if F is . Hence cos sin = 0
cos sin = 0 cot =
= cot
1
()

16. B at all the point lying on OP is zero so u will not be affected by the magnetic force. Hence K.E.
will remain unchanged.

17. We write Einsteins equation for the photoelectric effect,
hf W = E
K
(i)
3hf W = E
K
(ii)
from (i) and (ii), we get,
E
K
3E
K
= 2W > 0.

18.
( ) ( )
2 A A
nuc Z nuc Z 1
e
Q C m X m Y m
+
(
=

by definition.
Putting,

( ) ( )
A A
nuc Z Z e
m X m X Zm =
and similarly for
A
Z 1
Y
,
we get the final result.

19. Since rays are bending toward the normal
2
>
1
.

21. Stress = Y strain
force F =
A
Y
| |
|
\ .

2
A
F r Y
| |
=
|
\ .

22. ( ) ( )
2 1 0 0 0 2 0 1
t = +
By the condition given in the question,

2 1 0 0
=
( )
0 2 0 1
t 0 =

0
60 cm =

23.
max
2
max 0
f md =

max
0
mg g
md d

= =

4
24. y = x
PE =
2 2
1
m y
2

2 2 2
1
KE m (a y )
2
=
TE = PE + KE
=
2 2
1
m a
2

25.
1
B A BAcos60
2500
= = =

3
d 1
e 2 10 V
dt 2500 0.2

= = =

26. T = Kx = m
2
r
where r =
0
x +

2
0
Kx m ( x) = +

2
0
2
m
x
K m

0
0
2
K
r x
K m
= + =

.

27. V
max
= (2f) A
a
max
= (2f)
2
A

max
max
a
(2 f )
V
= .

28. Acceleration - displacement
29. In second harmonic of an organ pipe pressure antinode will be at
4
from the either side of the

open organ pipe and L = (length of the organ pipe).

30. W
agent =
K + U
for minimum work done K = 0
W
agent
= U = mgR

5
C Ch he em mi is st tr ry y PART II

1. 0.08; = So
| |
( )( ) ( )( )
3 3
c
3 3
H BO Glycerine
0.08
K 0.95
H BO Glycerine 0.1 0.08 a 0.08
= = =

So, a 4.29

2.
t
o
N N e ,
= where N = parent remaining (R) and N

o
= initial parent = parent remaining (R) +
daughter formed (d)
( )
t
R R d e
= + or
( ) R d
n t,
R
+
=
1 d
t n 1
R
| |
= +
|
\ .

3. S.A. and S. base show steeped rise in pH range.

4.
| |
+ -
3
2
RNH OH
K =
RNH
( (

-6 - -3
x x
810 = , OH = 210 M
0.5
(

pOH = 2.7, pH = 14 2.7 = 11.3

5. For a combine cell
o 1 1 2 2
cell
n E n E
E
n

6. ( ) ( )
4
4
6 6
K Fe CN 4K Fe CN

+
( ( +

So,
i 1 i 1
0.7
5 1 n 1

= =

Hence, n = no. of particles furnished by 1 molecule
n = 5

7. Let number of atoms of A used in packing = n
Number of tetrahedral voids = 2n
Number of atoms of B =
2
2n
3
=
4n
3

Formula of the compound A : B =
4
n : n
3
= 3 : 4
Formula of compound = A
3
B
4

8. Weight of Ag deposited = 80 5 10
4
10.8 = 0.432 g

0.432 96500
t
108 4
= 96.5 S

9.
1
T P constant

=
So for monoatomic gas 1.66 = and (300)
1.66
(200)
0.66
= (90)
1.66
(10)
0.66


6
10.
S
O O

11.
C C
H
H
Cl
Cl
A
60
o

Cl A sin60
o
= 2.35 0.866
= 2.035
o
A
Distance = 2.035 2 = 4.07 10
-8
cm

12.
( ) ( )
5 5
Mn Co e Mn Co
less stable EAN 36
+
=

13. Addition of H
2
O occurs according to Markonikovs rule.

CH
3
C = CH
2
+ H
2
O
+
H
CH
3
C - OH
CH
3
CH
3
CH
3

Hence, (A) is the correct answer.

15.
3 2 2
1
AgNO Ag NO O
2
+ +

3 3
Ag HNO AgNO +

2 2 2 3
NO H O HNO HNO + +

16. Mn, Fe and C

17. As NaBH
4
reduces only aldehyde and ketone group.

18.
O

*C will deactivate the benzene ring. So it will direct the upcoming
group at meta position.

19. It is planar, cyclic following ( ) 4n e
rule
Hence, n = 2.

20. COO
behaves as a strong base.

So, pH > 7 for this Zwitter ion.

21. Small surface area of conjugate base of A greater acidic.

7

22. As form 2 is more stable than form 1. So, concentration of 2 is greater than
concentration of 1. Due to hydrogen bonding.

23. In this reaction nitrine intermediate is not formed.

24.
N OH
2 5
H O/PCl
N O
H
NH O
Intermediate P
+
NH
O
Q

6 membered ring is none stable.

25. As 2
o
amine is more basic than 1
o
and the N of pyridine is highly crowded so the H
+
will attack on
position 2 as compare to 1 and H
2
N group of 3 position is involved in conjugation.

26. CH
2
+
form after removal of Cl

is more stabilized.

27. Cations with pseudo noble gas configuration possess more covalent character than noble gas
configuration according to Fajans Rule.
Also, smaller is size of cation more is covalent character according to Fajans Rule.

30. Conductivity of Na
2
SO
4
= 2. 6 10
-4

( )
4
2 1
m 2 4
2.6 10 1000
Na SO 260 S cm mol
0.001

=
( ) ( ) 2
4
2 1
m 2 4 m
SO
Na SO 2 Na 260 2 50 160 S cm mol
+
= = =
Conductivity of CaSO
4
solution = 7 10
-4
2.6 10
-4

= 4.4 10
-4
S cm
-1

( ) ( )
2 2
m 4 m m 4
CaSO Ca SO
+
= +
= 120 + 160 = 280 S cm
2
mole
-1

Solubility
4
m
1000 K 1000 4.4 10
C
280

3
C 1.57 10 M

2 3
Ca 1.57 10 M
+
( =

2 3
4
SO 2.57 10

(

2 2
sp 4
K Ca SO
+
( ( =

= 1.57 10
-3
2.57 10
-3

6
4 10


8
M Ma at th he em ma at ti ic cs s PART III

2.
( )
2
2
log 1 6x x 8 0 +

2
1 6x x 8 1 + 6x x
2
8 0
x
2
6x + 8 0
(x 2)(x 4) 0
2 x 4.
Now f(x) = x
2
+ 2x + 2 > 0 x R
f(x) is strictly increasing in [2, 4]
f(x) =
3
2
x
x 2x
3
+ +
= f(2) =
8
3
+ 4 + 4 =
32
3

= f(4) =
64
3
+ 16 + 8 =
136
3

| |max =
104
3
.

3. Given inequation is (a 1)x
2
(a + 1)x + a 1 0
a(x
2
x + 1) (x
2
+ x + 1) 0
a
2
2 2
x x 1 2x 2
1 1
1
x x 1 x x 1
x 1
x
+ +
= + = +
+ +
+
(1)
let y =
1
x
x
+
y is increasing in [2, )

2
1
1
x 1
x
+
+

7
1,
3
| (
(
\

for all x 2 (1) should be true
a
7
3
.

4.
5 2 2 1 1 1 16 3
A
7 5 0 4 2 1 24 5
( ( ( (
= =
( ( ( (

5. E
1
Person is accident person
E
2
Person is not accident person
A = person will have an accident with in a year
P(A) = P(E
1
) P(A/E
1
) + P(E
2
)P(A/E
2
) = 0.3 0.6 + 0.7 0.8 = 0.74

6. Normal vector to plane P
1
3
k
Normal vector to plane P
2

2i 4j 3k
( )

a 2i j = +

angle between a
and vector

i 2j 2k + is given by

9
cos =
( ) ( )

2i j i 2j 2k
0
5 9
+ +
=

=
2
.

7. Let
i 1 i
1 1
H H
+
= k

2n 2n i
i i i 1
i i 1 i 1 i
i 1 i 1
H H ( 1) 1 1
( 1) 2n
H H k H H
+
+ +
= =
| | | | +
= + =
| |
\ . \ .

8. Given that X = AB + BA X = X
T

and Y = AB BA Y = Y
T

Now (XY)
T
= Y
T
X
T
= YX.

9. We have
( ) ( )
p p
2 5 2 5 + +
= 2[2
p
+
p
C
2
2
p 2
5 +
p
C
4
2
p 4
5
2
+ +
p
C
p 1
2 . 5
(p 1)/2
] (1)
From (1),
( ) ( )
p p
2 5 2 5 + + is an integer and 1 <
( )
p
2 5 < 0
(as p is odd), so
( ) ( ) ( )
p p p
2 5 2 5 2 5
(
+ = +

= 2
p + 1
+
p
C
2
2
p 1
5 + +
p
C
p 1
2
2
5
(p 1)/2

( )
p
p 1
2 5 2
+ (
+

= 2[
p
C
2
2
p 2
5 +
p
C
4
2
p 4
5
2
+ +
p
C
p 1
2 . 5
(p 1 )/2
].
Now all the binomial coefficients
p
C
2
=
( ) p p 1
1 2
,
p
C
4
=
( )( )( ) p p 1 p 2 p 3
1 2 3 4

, ,
p
C
p 1
= p
are divisible by the prime p. Thus R.H.S is divisible by p.

10. Given determinant 2a (bc 4a
2
) + b (2ac b
2
) + c (2ab c
2
) = 0
6abc 8a
3
b
3
c
3
= 0
(2a + b + c) [(2a b)
2
+ (b c)
2
+ (c 2a)
2
] = 0
2a + b + c = 0 (as b c)
Let f (x) = 8ax
3
+ 2bx
2
+ cx
f (0) = 0
f
1 b c 2a b c
a 0
2 2 2 2
+ + | |
= + + = =
|
\ .
.
So, f (x) satisfies the Rolles Theorem condition so, f (x) = 0 has atleast one root in
1
0,
2
(
(

.

12.
2
1 x 10x 26 1 + x = 5 only and at x = 5
0
2
= which not possible. Hence a .

13.
2
2 2
z 2i 3i 7i

=

R
1
(R
1
+ R
3
) =
2 2
1 1 1
2i 3i 7i

=
( ) ( )
2 2 2
1 3 i 7 i 2 i 7 i +
( ) ( )
2 2
1 2 i 3 i 5i 5 2 + = =


10
14. According to Rolls theorem f(x) = 0
Atleast one
3 3 5
x , ,
2 2 2 2
| | | |

| |
\ . \ .

2
3
2

5
2

10

15. for 5 f(a) < 6 x [f(x)] = 5
Hence cont. at x = a

16. ( )
2
2
y 2 x 1
y = ax
2
1
2 3
4
O
(0, 2)
y = ax
2
, a > 0
(y 2)
2
x
2
= 1

17. f(x) = 6x
2
+ 2x +

t
2
3 3
6 3

= =

( ) t 1
3
3
+

=
f "(x) 12x 2 0 = + = at
5
x
2
=

( )
12 5/ 2
15
2
= =

(t 1)
3 5
+
=
( )
3
t 1 log 5 + =

3
5
t log
3
| |
=
|
\ .

18. Let
2
2
n 2
1
S log 1
n
=
| |
=
|
\ .
=
2 2
n 2
1 1
log 1 log 1
n n
=
| | | | | |
+ +
| | |
\ . \ . \ .
=
2 2
n 2
n 1 n
log log
n n 1
=
| | | | | |
| | |
\ . \ + . \ .

Let
r 2
r 1
V log
r
| |
=
|
\ .

r 1 2
r
V log
r 1
+
| |
=
|
\ + .

( )
r r 1
r 2
S V V
+
=
=
= V
2
=
2
1
log 1
2
| |
=
|
\ .

19.
( )
( )
2
f 2t
0
f ' 2t e dt 5 =

f (4) f (0)
e e 10 = f(4) = ln 11.

20. a + b = 20, a + c = 21

2 2 2
b c a
cosA
2bc
| |
+
=
|
\ .

2
2a 123a 1261 0 + =
a = 13

A
B
C b
c
a
x/3


11
21.
( )
sinx
1
f ' x log sinx
2
| |
= +
|
\ .

1
0 sinx 1
2
< + <
5 7 11
x 0, , , 2
6 6 6 6
| | | | | |

| | |
\ . \ . \ .

22. Sum of all possible ( )
n 2
n r n+1
i 2 4
r 2
a r C C
=
= =

23. Let X = x 3, Y = y 1
|X + Y| = 5, |X| + |Y| = 5
|X + Y| = |X| + |Y| X.Y 0
Hence number of points are 8

24. f(x, y) = 2y
2
(x + 2)
2
+ (x 1)
2
+ 3
least f(x, y) = 3 for x = 1 and y = 0

25. 9x
2
12x + n
2
8 4
x
x
+ is perfect square

2
2 2
3x 4 3x (n 12)
x x
| | | |
+ + +
| |
\ . \ .
is perfect square
n 12 = 4 n = 16

26. a, b are odd integers

10
i
i 1
b
=
=
odd integers
i
= odd integer

i
= even integer a
Hence
i
I

27. D.Rs of normal to plane x + y + z 1 = 0 and x + ky + 3z 1 = 0 is (1, 1, 1) and (1, k, 3)
respectively
D.R. of normal to a plane perpendicular to given planes
=

i j k

1 1 1 i(3 k) j(2) k(k 1)
1 k 3
= +

1 2 2 1 3
3 k 2 k 1
+ + +
= =

2 4 = 6 + 3 2k k and 2 6 = 2 + 2k + k
4 10 = 4 + 2 12 = 8 =
2
3

8
2 6 2 2k 2 k 3
3
+ = + =
2 4
4 k
3 3
=
10 4
k
3 3
= k =
5
2

28. ( ) ( ) ( )
2
n
1 2 n 1
x x x x ..... x

+ + =

( )
n
2
1
x x
x
+ +

= ( )( ) ( )
2 3 n 1
x x ..... x


12
( )( ) ( )
( )
1
n
1 2 1 3 1 n 1
2
x
1
x x
..... lim
a

| |
+ +
=
|
|

\ .
=
( )
n 2
1
n n 1
2

29. Favourable cases
X Y
GGGGG BBB
BBBGG GGG

Required probability =
5 5
5 3
8 8
5 3
C C 11
56
C C
+ =

30. f() = 4
1 0 1 2 3 4
r
y = x
y = x + 4

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AITS-FT-II-PCM(S)-JEE(Main)/13

from the either side of the

= where N = parent remaining (R) and N

behaves as a strong base.

= which not possible. Hence a .

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